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WO2008153143A1 - 熱可塑性樹脂組成物とそれを用いた樹脂成形品および偏光子保護フィルムならびに樹脂成形品の製造方法 - Google Patents

熱可塑性樹脂組成物とそれを用いた樹脂成形品および偏光子保護フィルムならびに樹脂成形品の製造方法 Download PDF

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Publication number
WO2008153143A1
WO2008153143A1 PCT/JP2008/060884 JP2008060884W WO2008153143A1 WO 2008153143 A1 WO2008153143 A1 WO 2008153143A1 JP 2008060884 W JP2008060884 W JP 2008060884W WO 2008153143 A1 WO2008153143 A1 WO 2008153143A1
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Prior art keywords
articles
resin composition
production
ultraviolet absorber
film made
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Ceased
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PCT/JP2008/060884
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English (en)
French (fr)
Inventor
Hidetaka Nakanishi
Akio Naka
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Nippon Shokubai Co Ltd
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Nippon Shokubai Co Ltd
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Priority to CN2008800201056A priority Critical patent/CN101679710B/zh
Priority to US12/664,167 priority patent/US20100182689A1/en
Priority to KR1020117020080A priority patent/KR101175511B1/ko
Publication of WO2008153143A1 publication Critical patent/WO2008153143A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4286Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones prepared from a combination of hydroxycarboxylic acids and/or lactones with polycarboxylic acids or ester forming derivatives thereof and polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/12Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/105
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/208Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66Substances characterised by their function in the composition
    • C08L2666/70Organic dyes or pigments; Optical brightening agents
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Toxicology (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polarising Elements (AREA)

Abstract

 熱可塑性アクリル樹脂と紫外線吸収剤(UVA)とを含む樹脂組成物であって、ガラス転移温度の高さに基づく優れた耐熱性を有しながら、高温での成形時においても、発泡、ブリードアウトなどの発生が抑制され、UVAの蒸散による問題の発生を低減できる樹脂組成物を提供する。熱可塑性アクリル樹脂と、分子量が700以上の紫外線吸収剤とを含み、110°C以上のガラス転移温度を有する熱可塑性樹脂組成物とする。紫外線吸収剤は、ヒドロキシフェニルトリアジン骨格を有することが好ましい。アクリル樹脂は、主鎖に環構造を有することが好ましく、環構造は、例えば、ラクトン環構造、無水グルタル酸構造、グルタルイミド構造、N-置換マレイミド構造および無水マレイン酸構造から選ばれる少なくとも1種である。
PCT/JP2008/060884 2007-06-14 2008-06-13 熱可塑性樹脂組成物とそれを用いた樹脂成形品および偏光子保護フィルムならびに樹脂成形品の製造方法 Ceased WO2008153143A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2008800201056A CN101679710B (zh) 2007-06-14 2008-06-13 热塑性树脂组合物和使用其的树脂成型品及偏振片保护膜以及树脂成型品的制造方法
US12/664,167 US20100182689A1 (en) 2007-06-14 2008-06-13 Thermoplastic resin composition, resin molded article and polarizer protective film each using the same, and method of producing the resin molded article
KR1020117020080A KR101175511B1 (ko) 2007-06-14 2008-06-13 열가소성 수지 조성물과 그것을 이용한 수지 성형품 및 편광자 보호 필름 및 수지 성형품의 제조 방법

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2007157991 2007-06-14
JP2007-157991 2007-06-14
JP2007-200689 2007-08-01
JP2007200689 2007-08-01
JP2007-200693 2007-08-01
JP2007200693 2007-08-01
JP2008-006030 2008-01-15
JP2008006030 2008-01-15

Publications (1)

Publication Number Publication Date
WO2008153143A1 true WO2008153143A1 (ja) 2008-12-18

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PCT/JP2008/060884 Ceased WO2008153143A1 (ja) 2007-06-14 2008-06-13 熱可塑性樹脂組成物とそれを用いた樹脂成形品および偏光子保護フィルムならびに樹脂成形品の製造方法

Country Status (5)

Country Link
US (1) US20100182689A1 (ja)
KR (3) KR20110114688A (ja)
CN (2) CN101679710B (ja)
TW (1) TWI444424B (ja)
WO (1) WO2008153143A1 (ja)

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JP2010065109A (ja) * 2008-09-10 2010-03-25 Nippon Shokubai Co Ltd 熱可塑性樹脂組成物とそれを用いたフィルム
KR101182468B1 (ko) 2009-12-15 2012-09-12 주식회사 엘지화학 편광판, 그 제조방법 및 이를 이용한 화상 표시 장치
JP2013083956A (ja) * 2011-09-30 2013-05-09 Nippon Shokubai Co Ltd 位相差フィルム、偏光板、および画像表示装置

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US10597524B2 (en) 2015-11-20 2020-03-24 Asahi Kasei Kabushiki Kaisha Methacrylic resin, methacrylic resin composition, film, and production method
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KR20180018334A (ko) 2016-08-09 2018-02-21 주식회사 엘지화학 광학 재료용 수지 조성물 및 이를 포함하는 광학 필름
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JP6771525B2 (ja) * 2017-11-09 2020-10-21 住友化学株式会社 光学積層体
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EP3812421A4 (en) * 2018-06-21 2021-09-15 Toppan Printing Co., Ltd. PROTECTIVE FILM AND SHEET
KR102378972B1 (ko) * 2018-07-10 2022-03-25 주식회사 엘지화학 위상차 필름 및 위상차 필름의 용도
KR102268269B1 (ko) * 2018-07-10 2021-06-23 주식회사 엘지화학 위상차 필름 및 위상차 필름의 용도
KR102366379B1 (ko) * 2018-08-20 2022-02-22 주식회사 엘지화학 위상차 필름 형성용 조성물, 위상차 필름, 이를 포함하는 편광판 및 이를 포함하는 액정표시장치
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WO2020138368A1 (ja) * 2018-12-27 2020-07-02 日東電工株式会社 位相差層付偏光板
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JP2019066884A (ja) * 2019-01-21 2019-04-25 株式会社日本触媒 光学フィルムおよびその利用
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TW200911907A (en) 2009-03-16
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