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WO2008149661A1 - Method for production of fatty acid ester - Google Patents

Method for production of fatty acid ester Download PDF

Info

Publication number
WO2008149661A1
WO2008149661A1 PCT/JP2008/059190 JP2008059190W WO2008149661A1 WO 2008149661 A1 WO2008149661 A1 WO 2008149661A1 JP 2008059190 W JP2008059190 W JP 2008059190W WO 2008149661 A1 WO2008149661 A1 WO 2008149661A1
Authority
WO
WIPO (PCT)
Prior art keywords
fatty acid
catalyst
acid ester
production
transesterification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/059190
Other languages
French (fr)
Japanese (ja)
Inventor
Atsushi Abiko
Yusuke Obata
Atsuko Matsunami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyoto Institute of Technology NUC
Original Assignee
Kyoto Institute of Technology NUC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyoto Institute of Technology NUC filed Critical Kyoto Institute of Technology NUC
Priority to JP2009517773A priority Critical patent/JPWO2008149661A1/en
Publication of WO2008149661A1 publication Critical patent/WO2008149661A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

Disclosed is a method for producing a fatty acid ester, which does not require any catalyst separation process, and enables to allow the transesterification to proceed under mild conditions and at a high reaction rate to thereby produce the fatty acid ester with a high degree of efficiency. A fatty acid ester is produced by the transesterification of an oil-and-fat with an alcohol by using an organic onium salt of sulfonic acid as a catalyst. The organic onium salt which is used as a catalyst can be used in the reaction repeatedly. Unlike a conventional homogeneous alkaline catalyst method, this method does not require any catalyst separation process or any alkaline catalyst and therefore produces no fatty acid soap.
PCT/JP2008/059190 2007-05-31 2008-05-20 Method for production of fatty acid ester Ceased WO2008149661A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009517773A JPWO2008149661A1 (en) 2007-05-31 2008-05-20 Method for producing fatty acid ester

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-145231 2007-05-31
JP2007145231 2007-05-31

Publications (1)

Publication Number Publication Date
WO2008149661A1 true WO2008149661A1 (en) 2008-12-11

Family

ID=40093486

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/059190 Ceased WO2008149661A1 (en) 2007-05-31 2008-05-20 Method for production of fatty acid ester

Country Status (2)

Country Link
JP (1) JPWO2008149661A1 (en)
WO (1) WO2008149661A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009087910A1 (en) * 2008-01-09 2009-07-16 National University Corporation Kyoto Institute Of Technology Process for production of biodegradable polymer
JP2013503947A (en) * 2009-09-04 2013-02-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー Stable alkoxylated fatty acid alkyl esters from transesterification alkoxylation of vegetable oils

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035099A (en) * 1983-05-30 1985-02-22 ヘンケル・コマンデイツトゲゼルシヤフト・アウフ・アクチエン Manufacture of fatty acid ester of short chain fatty alcohol
WO2005085172A1 (en) * 2004-03-08 2005-09-15 Nagoya Industrial Science Research Institute Method for producing ester and esterification catalyst

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6035099A (en) * 1983-05-30 1985-02-22 ヘンケル・コマンデイツトゲゼルシヤフト・アウフ・アクチエン Manufacture of fatty acid ester of short chain fatty alcohol
WO2005085172A1 (en) * 2004-03-08 2005-09-15 Nagoya Industrial Science Research Institute Method for producing ester and esterification catalyst

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FUNATOMI T.: "Pentafluorophenylammonium triflate(PFPAT): an efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation", GREEN CHEMISTRY, vol. 8, no. 12, 2006, pages 1022 - 1027, XP002536303, DOI: doi:10.1039/B609181B *
GELBARD G.: "Polynitrogen strong bases as immobilized catalysts for the transesterification of vegetable oils", COMPTES RENDUS DE L'ACADEMIE DES SCIENCES, SERIE IIC: CHIMIE, vol. 3, no. 7, 2000, pages 563 - 567, XP008049478 *
WAKASUGI K.: "Diphenylammonium triflate (DPAT): efficient catalyst for esterification of carboxylic acids and for transesterification of carboxylic esters with nearly equimolar amounts of alcohols", TETRAHEDRON LETTERS, vol. 41, 2000, pages 5249 - 5252, XP004222048 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009087910A1 (en) * 2008-01-09 2009-07-16 National University Corporation Kyoto Institute Of Technology Process for production of biodegradable polymer
JP2013503947A (en) * 2009-09-04 2013-02-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー Stable alkoxylated fatty acid alkyl esters from transesterification alkoxylation of vegetable oils

Also Published As

Publication number Publication date
JPWO2008149661A1 (en) 2010-08-26

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