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WO2008145424A1 - Agent de lavage ou de nettoyage à consistance liquide, gélifiée ou pâteuse - Google Patents

Agent de lavage ou de nettoyage à consistance liquide, gélifiée ou pâteuse Download PDF

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Publication number
WO2008145424A1
WO2008145424A1 PCT/EP2008/052999 EP2008052999W WO2008145424A1 WO 2008145424 A1 WO2008145424 A1 WO 2008145424A1 EP 2008052999 W EP2008052999 W EP 2008052999W WO 2008145424 A1 WO2008145424 A1 WO 2008145424A1
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WO
WIPO (PCT)
Prior art keywords
acid
textiles
weight
washing
cleaning agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/052999
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German (de)
English (en)
Inventor
Georg Meine
Bernhard Guckenbiehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO2008145424A1 publication Critical patent/WO2008145424A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0063—Photo- activating compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention relates to a liquid, gel or pasty detergent or cleaning agent which comprises (a) photocatalytic material, (b) anionic surfactant, in particular fatty alcohol sulphate and / or alkylbenzenesulphonate, (c) nonionic surfactant, in particular fatty alcohol alcoholate and / or alkylpolyglycoside, (d) electrolyte (e) selected from acid (s), base (s) and / or salts (s). It also relates to a process for the preparation of a corresponding washing or cleaning agent and to processes for applying photocatalytic material to textiles. It further relates to methods of treatment, in particular cleaning, of textiles and hard surfaces.
  • photocatalytic materials to control soil and / or unwanted microorganisms is desirable because the photocatalytic material may utilize electromagnetic radiation of a suitable wavelength range to degrade or deactivate debris and / or unwanted microorganisms by photocatalytic or photochemical reaction.
  • suitable photocatalytic material is very finely divided substances, for example in the size range of at least ⁇ 500 nm.
  • the incorporation of such photocatalytic material in detergents and cleaners of non-solid consistency can lead to problems. For example, it may be possible for the photocatalytic material to settle or float in a liquid detergent or cleaning agent. The consumer would then, for example, shake the liquid detergent or cleaning agent in question before use in order to homogenize it again, which is not a problem, but still uncomfortable.
  • the consumer generally desires detergents and cleaners of non-solid consistency, which can also be used directly after storage and transport at the time of application.
  • anionic surfactant in particular fatty alcohol sulfate and / or alkylbenzenesulfonate
  • nonionic surfactants in particular fatty alcohol ethoxylates and / or alkyl polyglycosides, and
  • the detergents or cleaners according to the invention can be used for cleaning textiles and / or hard surfaces, in particular also tableware.
  • the contained photocatalytic material which is preferably finely divided, in particular has particle sizes in the range ⁇ 500 nm, makes use of electromagnetic radiation of a suitable wavelength range, by means of which e.g. Soils or microbes by photocatalytic or photochemical reaction, e.g. by oxidation or reduction, degradable, deactivatable or reducible.
  • the photocatalytic material is in particular a daylight-active material, in particular a daylight-active bleach, thus uses the electromagnetic radiation of daylight.
  • the presence of preferably oxygen and / or water is required.
  • the photocatalytic activity of the photocatalytic material advantageously relates to natural or artificial light in the wavelength range of 10-1200 nm, advantageously 300-1200 nm, preferably between 380-800 nm. If the photocatalytic material in particular the visible to the human eye radiation of the visible region of the Spectrum is used with wavelengths between 380 to 800 nm for the above purposes of degradation, deactivation or reduction of impurities, then there is a preferred embodiment of the invention.
  • even the light incident through glass windows in closed living spaces (diffused daylight) suffices to ensure the desired photocatalytic activity of the photocatalytic material.
  • the photocatalytic material can be effective in several ways during and after the textile treatment.
  • the effect in the textile treatment bath is called. If you e.g. the textiles to be treated are placed in a tub containing a wash liquor into which the washing or cleaning agent according to the invention has previously been added and then exposing this textile treatment bath, for example light, e.g. in the sun, then the photocatalytic material in the textile treatment bath develops a general cleaning performance.
  • the textile treatment in an automatic washing machine, which has a viewing window (porthole), as is customary at least in front loaders and / or in a washing machine with an internal light source.
  • the photocatalytic material applied to the textiles to be dried as part of the textile treatment can develop a general cleaning performance in conjunction with light irradiation, for example by sunlight when drying on a line outdoors. Such is also possible in the textile drying in an automatic clothes dryer with internal light source.
  • the dried textiles are not really dry in the true sense, but contain a residual moisture, which is in balance with the ambient humidity (room humidity, body moisture). These conditions are sufficient to develop a general cleaning performance, caused by the deposited on the textiles photocatalytic material under light irradiation, for example by sunlight.
  • This latter effect is particularly advantageous because the treated garments are as it were provided with a long-term protection, so that the clothing is equipped with a self-cleaning ability.
  • This self-cleaning power is advantageous, for example, to counteract the development of fetid odors, which quickly form on clothing, for example after sweat-inducing activities (eg sports activities).
  • This self-cleaning capability is advantageous, for example, to prevent or at least complicate the colonization of microbes on textiles.
  • This self-cleaning capability is advantageous, for example, to prevent or aggravate the build-up and sticking of, in particular, colored stains on fibers.
  • the photocatalytically active material is advantageous in order to improve the Wiederschwasberry of colored stains.
  • the photocatalytically active material is capable of destroying the structure of, in particular, colored stains (dyes), for example by oxidation, under the action of light.
  • the conjugated double bonds, which are responsible for the absorption of visible light in the dyes and thus for the coloring are cleaved or hydroxylated.
  • the dye loses its coloring properties and also its strong fiber adhesion. At the same time the water solubility is increased. Thus it can be prevented that a colored spot "eats" into the textile and destroys it permanently.
  • stain pre- or post-treatment thus make it possible to produce an improved overall washing performance.
  • stain pretreatment agents with liquid detergents
  • stain removal can be significantly increased.
  • Bleachable stains which often appear as residual stains after washing with liquid detergents, can subsequently be lightened significantly until they are completely removed.
  • the Wiederauswaschles color stains from textiles that have been washed with the washing or cleaning agent according to the invention facilitated.
  • quick action is the top priority, because the fresher a stain is, the easier it is to remove.
  • a drying of stains or other contaminants, such as blood, coffee, tea, pen, fruit, red wine or tar stains, especially over several days should usually be avoided so that it does not come to a possibly irreversible fiber adhesion.
  • the present invention brings relief here, because textiles treated with detergents according to the invention showed that the fiber adhesion of stains or other contaminants was weakened so that they could be washed out more easily.
  • the washing or cleaning agent according to the invention also makes possible a very textile-sparing textile treatment, e.g. Stain treatment.
  • Noxa is understood to mean factors that can damage the human organism, or at least impair people's well-being. These are in particular the just mentioned factors, especially microbiological factors such as viruses, bacteria, fungi, etc.
  • Another advantage of the washing or cleaning agent according to the invention is that it contributes to the reduction, elimination or neutralization of fetid odors.
  • the fetid odor can advantageously be reduced so that a previously existing odor nuisance is no longer present.
  • the development of fetid odors can be prevented for a longer period of time.
  • This is also a great advantage since, overall, a general cleaning performance can be combined with the elimination of harmful microbes in one treatment step and, in addition, a blocking or prevention of foul odors with long-term effect is provided. This goes beyond the function of previous washing or cleaning agents significantly. The formation of bad odors can thus be reduced.
  • the development of the general cleaning effect which can be observed in the use of the washing or cleaning agent according to the invention is particularly effective with regard to colored impurities, in particular due to red to blue anthocyanin dyes, e.g. Cyanidin, e.g. from cherries or blueberries, red betanidine from beetroot, orange-red carotenoids, e.g. Lycopene, beta-carotene, e.g. from tomatoes or carrots, yellow curcuma dyes, e.g. Curcumin, e.g. curry and mustard, brown tannins, e.g. from tea, fruit, red wine, deep brown humic acid, e.g.
  • red to blue anthocyanin dyes e.g. Cyanidin, e.g. from cherries or blueberries, red betanidine from beetroot, orange-red carotenoids, e.g. Lycopene, beta-carotene, e.g. from tomatoes or carrots, yellow curcuma dyes
  • the washing or cleaning agent according to the invention also meets today's washing habits of consumers. This increasingly prefer washing at lower temperatures, eg ⁇ 4O 0 C. A clear death of germs but only starts at temperatures> 4O 0 C, only above a temperature of 55 0 C, most bacteria are killed. Therefore, if washed for a long time only at 3O 0 C, under certain circumstances can no longer guarantee sufficient hygienic purity. In particular, products containing lipases can have an unpleasant side effect. Since the lipases are absorbed by the tissue and remain there after washing, they can lead to unpleasant, rancid odors with not yet completely removed oils / fats.
  • washing or cleaning agent allows the consumer the consistent washing at T ⁇ 40 0 C with improved hygiene effect and elimination of bad odors.
  • the present invention enables the provision of storage and transport stable detergents or cleaners.
  • a big advantage of this washing or cleaning agent is that it too can be provided with increased, even significantly increased viscosities without the need for the use of (significant) viscosity increasing agents, such as clay minerals, in particular of viscosity increasing polymers such as polyacrylates, xanthan gum, guar gum, hydroxycelluloses needed.
  • a great disadvantage of such viscosity-increasing agents is the high costs associated with their use, and secondly, these viscosity-increasing agents are not wash-active or, if at all, only a small contribution to the washing performance. In some soiling such as loam or engine oil, the washing performance is even reduced by the use of viscosity increasing agents or polymers.
  • Examples are here frequently used thickeners such. Guar gum, locust bean gum or tara gum, which is described e.g. are incompatible with mannanases.
  • the aforesaid viscosity-increasing agents are usually only a formulation that increases the cost of the formulation, which often has a negative effect on the formulation.
  • a viscosity increase to be realized is effected according to the invention by the surfactant system in interaction with the electrolyte.
  • the viscosity can be flexibly varied in a very wide range, from normal liquid system over gel system to very viscous, paste-like and dough-like systems.
  • the washing or cleaning agent according to the invention enables a flexible viscosity adjustment over a very wide viscosity range and thus also a stable incorporation of the photocatalytic material into the detergent formulations without having to use polymer-based or other conventional thickeners.
  • the washing or cleaning agent according to the invention comes without the use of thickening systems based on a) polyacrylate (derivatives), preferably crosslinked polyacrylates b) structuring gums, preferably xanthan gum, guar gum, locust bean gum, gellan gum, wellan gum or carrageenan, c) Mixtures of the kind mentioned above.
  • the washing or cleaning agent according to the invention is free of such thickening systems, ie it contains ⁇ 1, 5 wt .-%, preferably ⁇ 1, 0 wt .-%, advantageously ⁇ 0.75 wt .-%, in particular 0% by weight thereof.
  • the photocatalytic activity of the photocatalytic material is retained and a uniform distribution of the photocatalytic material in the product is made possible.
  • the washing or cleaning agents according to the invention necessarily contain nonionic surfactants, in particular fatty alcohol alkoxylates and / or alkylpolyglycosides.
  • the fatty alcohol alkoxylates used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and preferably on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals may be present in the mixture, as they are usually present in Oxoalkoholresten.
  • EO ethylene oxide
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 C atoms, for example coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • Preferred ethoxylated alcohols include, for example, C t2 - U - alcohols containing 3 EO, 4 EO or 7 EO, C 9 n-alcohol with 7 EO, C-ms alcohols containing 3 EO, 5 EO, 7 EO or 8 EO , C 12 -i 8 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12 -i 4 -alcohol with 3 EO and C 12 -i 8 -alcohol with 7 EO.
  • the stated degrees of ethoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • NRE narrow rank ethoxylates
  • fatty alcohols with more than 12 EO. Examples of these are tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
  • block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
  • mixed alkoxylated nonionic surfactants in which EO and PO units are not distributed in blocks, but randomly. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
  • the preferably usable alkyl polyglycosides can be obtained by the relevant methods of preparative organic chemistry. Here is an extensive literature.
  • the alkyl polyglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • RO- [G] P Preferred alkyl polyglycosides, RO- [G] P , are now described in more detail:
  • G is a glycose unit having 5 or 6 C atoms, preferably glucose.
  • R may be an alkyl radical.
  • the alkyl radical R can be derived from primary saturated alcohols.
  • Typical examples are butanol-1, caproic, eananthic, caprylic, pelargonic, capric alcohol, undecanol-1, lauryl alcohol, tridecanol-1, myristyl alcohol, pentadecanol-1, cetyl alcohol, palmityl alcohol, heptadecanol-1, stearyl alcohol, isostearyl alcohol, nonadecanol -1, arachidyl alcohol, heneicosanol-1, and behenyl alcohol and their technical mixtures.
  • R may be an alkylene radical.
  • the alkenyl radical R can also be derived from primary unsaturated alcohols.
  • unsaturated alcohols are undecene-1-ol, oleyl alcohol, elaidyl alcohol, ricinoleic alcohol, linoleyl alcohol, linolenyl alcohol, gadoleyl alcohol, arachidonic alcohol, erucalcohol, brassidyl alcohol, palmoleyl alcohol, petroselinyl alcohol, arachyl alcohol, and technical mixtures thereof.
  • alkyl or alkenyl radicals R which are derived from primary alcohols having 6 to 16 carbon atoms.
  • alkyl polyglycosides of chain length C8-C10 e.g. incurred as a preliminary to the separation by distillation of technical C8-C18 coconut fatty alcohol and may be contaminated with a proportion of less than 6 wt .-% C12 alcohol and alkyl polyglycosides based on technical C9 / 11-oxo alcohols.
  • the alkyl or alkenyl radical R can also be derived from primary alcohols having 12 to 14 carbon atoms.
  • alkyl polyglycosides having a mean degree of oligomerization p of 1, 1 to 2.0 are used.
  • alkylpolyglycosides whose degree of oligomerization is less than 2.0 and in particular between 1.2 and 1.7 are preferred.
  • detergents or cleaning agents according to the invention necessarily contain anionic surfactant and in particular fatty alcohol sulfate and / or alkylbenzenesulfonate.
  • fatty alcohol sulfate are the alkali metal salts and in particular the sodium salts of sulfuric acid half esters of C 12 -C 18 fatty alcohols, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or C 10 -C 2 o-oxo alcohols and those half esters secondary alcohols of these chain lengths are preferred.
  • alk (en) ylsulfates of said chain length which contain a synthetic, straight-chain alkyl radical produced on a petrochemical basis, which have an analogous degradation behavior as the adequate compounds on the Base of oleochemical raw materials.
  • alk (en) ylsulfates of said chain length which contain a synthetic, straight-chain alkyl radical produced on a petrochemical basis, which have an analogous degradation behavior as the adequate compounds on the Base of oleochemical raw materials.
  • C 12 -C 16 -AIkVl- sulfate and Ci ⁇ C-is-alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred.
  • 2,3-alkyl sulfates which may for example be obtained as commercial products from Shell Oil Company under the name DAN ®, are suitable anionic surfactants.
  • fatty alcohol sulfate as the anionic surfactant is highly preferred according to the invention, it is also possible to use, in addition to the fatty alcohol sulphate or else another or other anionic surfactants, especially alkylbenzenesulphonates, in particular linear alkylbenzenesulphonates. However, the use of fatty alcohol sulfate and / or alkyl benzene sulfonate is most preferred. Other suitable anionic surfactants will be described below.
  • the washing or cleaning agents according to the invention necessarily contain electrolyte, namely in the form of acid (s) base (s) and / or salts (s).
  • Electrolyte is the name given to substances dissociated into solutions or melts in ions, where the dissociation into ions need not be complete.
  • the washing or cleaning agent according to the invention comprises acid, preferably in amounts of 0.0001% by weight to 5% by weight, advantageously selected from organic and / or inorganic acids, organic acids being more preferred, here especially alpha-hydroxy acids and acids selected from glycolic acid, D-lactic acid, L-lactic acid, D / L-lactic acid, citric acid, tartaric acid, mandelic acid, salicylic acid, ascorbic acid, pyruvic acid, oligooxa mono- and dicarboxylic acids, fumaric acid, retinoic acid, aliphatic and organic Sulfonic acids, benzoic acid, fruit acid, malic acid, gluconic acid and / or galacturonic acid.
  • organic acids being more preferred, here especially alpha-hydroxy acids and acids selected from glycolic acid, D-lactic acid, L-lactic acid, D / L-lactic acid, citric acid, tartaric acid, mandelic acid, salicylic acid, ascorbic acid, pyruvic acid, oligooxa
  • Sensible lower limits for the use of the acid may also be present at values of 0.0005% by weight, 0.001% by weight, 0.005% by weight, 0.01% by weight or 0.05% by weight, Wt .-% based on the total agent.
  • Useful upper limits for the use of the acid can even at values of 4 wt .-%, 3
  • Wt .-%, 2 wt .-%, 1 wt .-%, 0.1 wt .-% or 0.05 wt .-% are, wt .-% based on the total agent.
  • the most advantageous amounts of acid from 0.001 wt .-% to 0.1 wt .-%, wt .-% based on the total agent.
  • the washing or cleaning agent according to the invention contains salts, preferably in amounts of 0.0001 wt .-% to 5 wt .-%, advantageously selected from organic and / or inorganic salts, with inorganic salts being more preferred .
  • inorganic salts particular preference is given to ammonium or metal salts, preferably halides, oxides, carbonates, Hydrogen carbonates, phosphates, sulfates, nitrates preferred, in particular sodium chloride, sodium sulfate and magnesium sulfate may be mentioned.
  • ammonium salts or metal salts are also preferred, in particular salts of glycolic acid, D-lactic acid, L-lactic acid, D / L-lactic acid, citric acid, tartaric acid, mandelic acid, salicylic acid, ascorbic acid, pyruvic acid, fumaric acid, retinoic acid, Sulfonic acids, benzoic acid, fruit acid, malic acid, gluconic acid and / or galacturonic acid.
  • Mg, Ca, Na, K, Al, Zn, Ag and Mn salts can be used to advantage.
  • Sensible lower limits for the use of the salts may also be values of 0.0005% by weight, 0.001% by weight, 0.005% by weight, 0.01% by weight or 0.05% by weight, Wt .-% based on the total agent.
  • Useful upper limits for the use of the salts can even at values of 4 wt .-%, 3
  • Wt .-%, 2 wt .-%, 1 wt .-%, 0.1 wt .-% or 0.05 wt .-% are, wt .-% based on the total agent. Salts of salts of from 0.1% by weight to 3.0% by weight, based on the total agent, are most advantageous.
  • bases are, in particular, water-soluble metal hydroxides, in particular the hydroxides of the alkali metals.
  • the washing or cleaning agent according to the invention contains, in addition to the preferred fatty alcohol alkoxylates and / or alkyl polyglycosides, additional nonionic surfactant, in particular fatty amines, amine oxides, sugar surfactants and / or nonionic polymeric surfactants.
  • additional nonionic surfactant in particular fatty amines, amine oxides, sugar surfactants and / or nonionic polymeric surfactants.
  • the preferred sugar surfactants include fatty acid glucamides, sucrose esters, sorbitans and / or polysorbates.
  • nonionic polymer surfactants in particular N-containing, P-containing, Si-containing, Al-containing, S-containing, Se-containing polymer surfactants are preferred.
  • washing or cleaning agent according to the invention comprises paraffins, in particular branched paraffins, a further preferred embodiment of the invention is present.
  • the advantages lie in an improved fat and oil dissolving power such as engine, bicycle oil or butter / margarine / lard / frying fat.
  • the washing or cleaning agent according to the invention contains
  • fatty alcohol sulfate and / or alkylbenzenesulfonate preferably in amounts of 0.01-40% by weight, advantageously 2-30% by weight, in particular 5-25% by weight
  • optionally further anionic surfactants in particular alkylbenzenesulfonates.
  • / or fatty alcohol ether sulfates preferably in amounts of 0.01-30% by weight, advantageously 3-20% by weight, in particular 5-15
  • nonionic surfactants in particular fatty amines, amine oxides and / or nonionic polymeric surfactants
  • organic solvents preferably 1,2-propylene glycol, advantageously in amounts of 0.1-20% by weight, in particular 1-10% by weight,
  • fragrances preferably in amounts of 0.01-5% by weight, in particular 0.1-1% by weight
  • preservatives preferably (ethylenedioxy) dimethanol, 1, 3-bis- (Hydroxymethyl) urea, methylchloroisothiazolinone, methylisothiazolinone).
  • a preferred and particularly environmentally friendly washing or cleaning agent according to the invention comprises:
  • alkylpolyglycoside in amounts of 1-40% by weight, advantageously 2-30% by weight, in particular 5-25% by weight,
  • Another particularly preferred washing or cleaning agent according to the invention comprises:
  • fatty alcohol sulfate preferably in amounts of 1-40% by weight, advantageously 2-30% by weight, in particular 5-25% by weight
  • fatty alcohol ethoxylates in amounts of 1-40% by weight, advantageously 2-30% by weight, in particular 5-25% by weight
  • 0.1 wt .-% and / or salt (s) in amounts of 0.0001 wt .-% to 5 wt .-%, preferably 0.1 wt .-% to 3.0 wt .-%.
  • Another particularly preferred washing or cleaning agent according to the invention comprises:
  • the washing or cleaning agent according to the invention contains microcapsules or speckles, with a diameter along their largest spatial extent of 0.01 to 10,000 .mu.m, as dispersed particles, these microcapsules or speckles preferably containing nanoscale photocatalytic material, preferably the entire photocatalytic Material included.
  • the detergent or cleaning agent of the present invention may contain both photocatalytic material dispersed as such, it may contain photocatalytic material contained in microcapsules or speckles, photocatalytic material may be dispersedly contained as such, and at the same time photocatalytic material may be contained in microcapsules or speckles. It may also contain microcapsules or speckles that contain no photocatalytic material, but other active ingredients.
  • Nanoscale photocatalytic material has a particle size (based on the diameter along the largest spatial extent) of ⁇ 500 nm.
  • the use of microcapsules or speckles enables a particularly homogeneous distribution of the photocatalytic material in the liquid matrix. This also results in a still further improved stability of the washing or cleaning agent according to the invention.
  • possible decomposition processes which otherwise might at least hypothetically result from the activity of the photocatalytic material in the detergent matrix, can be suppressed to the greatest extent possible.
  • microcapsules or speckles and the use of opaque containers for packaging the laundry detergents or cleaning agents according to the invention is very advantageous, because thereby the activity of the photocatalytic material in the washing or cleaning agent for the period of storage and transport safely inhibited or completely is suppressed.
  • the use of opaque containers for packaging the detergents or cleaners according to the invention is very advantageous.
  • disposable portions eg pouches.
  • the washing or cleaning agent according to the invention is contained in an opaque container (packaging), the container being in particular impermeable to electromagnetic radiation in the wavelength range of 10-1200 nm, preferably 380-800 nm, then a preferred embodiment of the invention is present.
  • microcapsules or speckles optionally in combination with the use of opaque containers for packaging, ensures inter alia that the washing or cleaning agent according to the invention to the consumer at the time of application with full vigilance and cleaning power and in visually appealing form for Available.
  • microcapsule is understood to mean aggregates which contain at least one solid or liquid core which is enclosed by at least one continuous shell, in particular a shell of polymer (s). These are usually finely dispersed liquid or solid phases coated with film-forming polymers, during the production of which the polymers precipitate on the material to be enveloped after emulsification and coacervation or interfacial polymerization.
  • the microscopic capsules can be dried like powder.
  • multinuclear aggregates also called microspheres, are known, which contain two or more cores distributed in the continuous shell material.
  • Mono- or polynuclear microcapsules can also be enclosed by an additional second, third, etc., sheath.
  • the shell may be made of natural, semi-synthetic or synthetic materials.
  • shell materials are, for example, gum arabic, agar agar, agarose, maltodextrins, alginic acid or its salts, for example sodium or calcium alginate, fats and fatty acids, cetyl alcohol, collagen, chitosan, lecithins, gelatin, albumin, shellac, polysaccharides, such as starch or dextran , Sucrose and Waxes.
  • Semi-synthetic shell materials include chemically modified celluloses, in particular cellulose esters and ethers, for example cellulose acetate, ethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose and carboxymethylcellulose, and also starch derivatives, in particular starch ethers and esters.
  • Synthetic shell materials are, for example, polymers such as polyacrylates, polyamides, polyvinyl alcohol or polyvinylpyrrolidone.
  • microcapsules for example, optical brighteners, surfactants, complexing agents, bleaching agents, bleach activators, dyes and fragrances, antioxidants, builders, enzymes, enzyme stabilizers, antimicrobial agents, grayness inhibitors, anti redeposition agents, pH adjusters, electrolyte ⁇ , foam inhibitors and UV- Absorber are located.
  • microcapsules may also contain cationic surfactants, vitamins, proteins, preservatives, detergency boosters or pearlescing agents.
  • the fillings of the microcapsules may be solids or liquids in the form of solutions or emulsions or suspensions. Preference is given to microcapsules containing the photocatalytic material as a suspension.
  • the usable microcapsules may have any shape in the production-related framework, but they are preferably approximately spherical. Their diameter along their largest spatial extent, depending on the components contained in their interior and the application between 0.01 microns (not visually recognizable as a capsule) and 10,000 microns. Preference is given to visible microcapsules having a diameter in the range from 100 ⁇ m to 7000 ⁇ m, in particular from 400 ⁇ m to 5000 ⁇ m.
  • the microcapsules are accessible by methods known in the art, with coacervation and interfacial polymerization being the most important.
  • microcapsules all surfactant-stable microcapsules available on the market can be used, for example the commercial products (the shell material is indicated in parentheses) Hallcrest microcapsules (gelatin, gum arabic), Coletica thalaspheres (marine collagen), Lipotec millicapsules (alginic acid, agar-agar) , Also unispheres (lactose, microcrystalline cellulose, hydroxypropyl methylcellulose); Unicerin C30 (lactose, microcrystalline cellulose, hydroxypropyl methylcellulose), Kobo Glycospheres (modified starch, fatty acid esters, phospholipids), Softspheres (modified Agar Agar) and Kuhs Probiol Nanospheres (phospholipids).
  • Hallcrest microcapsules gelatin, gum arabic
  • Coletica thalaspheres marine collagen
  • Lipotec millicapsules alginic acid, agar-agar
  • unispheres lactose, microcrystalline cellulose,
  • microcapsules and particles which have no core-shell structure, but in which the active ingredient, in particular the photocatalytic material, distributed in a matrix of a matrix-forming material.
  • Such particles are also referred to as "speckies".
  • a preferred matrix-forming material is alginate.
  • an aqueous alginate solution which also contains the active ingredient to be enclosed or the active ingredients to be enclosed, is dripped off and then cured in a precipitation bath containing Ca 2+ ions or Al 3+ ions.
  • the alginate-based speckles are subsequently washed with water and then washed in an aqueous solution with a complexing agent to free Ca 2+ - ions or free Al 3+ ions, which undesirable interactions with ingredients of the washing according to the invention - And detergent, such as the fatty acid soaps, can go out, wash out. Subsequently, the alginate-based speckles are washed again with water to remove excess complexing agent.
  • matrix-forming materials can be used instead of alginate.
  • matrix-forming materials include polyethylene glycol, polyvinylpyrrolidone, polymethacrylate, polylysine, poloxamer, polyvinyl alcohol, polyacrylic acid, polyethylene oxide, polyethoxyoxazoline, albumin, gelatin, acacia, chitosan, cellulose, dextran, Ficoll®, starch, hydroxyethyl cellulose, Hydroxypropylcellulose, hydroxypropylmethylcellulose, hyaluronic acid, carboxymethylcellulose, carboxymethylcellulose, deacetylated chitosan, dextran sulfate and derivatives of these materials.
  • the matrix formation in these materials takes place for example via gelation, polyanion-polycation interactions or polyelectrolyte-metal ion interactions and is well known in the art as well as the production of particles with these matrix-forming materials.
  • the usable microcapsules, speckles and / or the photocatalytic material as such can be stably dispersed in the washing and cleaning compositions according to the invention.
  • Stable means that the agent at room temperature and at 4O 0 C for a period of at least 4 weeks and preferably for at least 6 weeks are stable, with no creaming or sedimenting means.
  • the release of the active ingredients, in particular the photocatalytic material, from the microcapsules or speckles is usually carried out during the application of the agents containing them by destruction of the shell or the matrix due to mechanical, thermal, chemical or enzymatic action.
  • the washing or cleaning agents according to the invention contain identical or different microcapsules or Speckies in amounts of from 0.01 to 30% by weight or up to 20% by weight or up to 10% by weight, in particular from 0.2 to 8% by weight and very preferably from 0.5 to 5% by weight ,
  • the photocatalytic material comprises titanium dioxide, in particular a modified titanium dioxide, preferably a carbon-modified titanium dioxide.
  • the photocatalytic material in particular the (preferably modified) titanium dioxide, according to a preferred embodiment of the invention in the washing or cleaning agent according to the invention in amounts of advantageously 0.0001 to 30 wt .-%, preferably 0.001 to 20 wt .-%, advantageously 0.01 to 15 wt .-%, in a further advantageous manner 0.1 to 10 wt .-%, more preferably 1 to 5 wt .-%, wt .-% based on the total washing or cleaning agent.
  • the titanium dioxide (preferably modified) is a carbon-modified titanium dioxide.
  • titanium dioxides for example nitrogen-modified titanium dioxide or e.g. Titanium dioxide doped with rhodium and / or platinum ions.
  • the carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1, 5 wt. -%, in particular from 0.4 to 0.8 wt .-% are.
  • the TiO 2 content of the carbon-modified titanium dioxide is, for example, more than 95% by weight, 96% by weight, 97% by weight, 98% by weight or 99% by weight, based on the total with carbon modified titanium dioxide.
  • the modified titanium dioxide may advantageously additionally contain nitrogen.
  • the specific surface of the titanium dioxide preferably of the modified titanium dioxide, according to BET (BET advantageously determined according to DIN ISO 9277: 2003-05, preferably also simplified according to DIN 66132: 1975-07) preferably 50 to 500 m 2 / g, advantageously 100 to 400 m 2 / g, in a further advantageous manner 200 to 350 m 2 / g, in particular 250 to 300 m 2 / g, so is also a preferred embodiment.
  • the carbon-modified titanium dioxide can be obtained according to a preferred embodiment, for example, by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m 2 / g according to BET, with an organic carbon compound and the mixture at a temperature of up to is thermally treated to 35O 0 C.
  • the carbonaceous substance which can be used in this case can, according to a preferred embodiment, be a carbon compound which contains at least one functional group, preferably selected from OH, CHO, COOH, NHx, SHx.
  • the carbon compound may be a compound selected from ethylene glycol, glycerol, succinic acid, pentaerythritol, carbohydrates, sugars, starch, alkypolyglycosides, organoammonium hydroxides or mixtures thereof. It is also possible for carbon black or activated carbon to be used as the carbonaceous substance.
  • the carbonaceous substance which is advantageously mixed with the titanium compound to arrive after the thermal treatment to the modified titanium dioxide, a decomposition temperature of at most 400 0 C preferably ⁇ 35O 0 C and particularly preferably ⁇ 300 0 C. having.
  • the titanium compound which is preferably used for producing the modified titanium dioxide and intimately mixed with an organic carbon compound according to the aforementioned preferred embodiment may be an amorphous, partially crystalline or crystalline titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate, which in turn corresponds to a preferred embodiment ,
  • the thermal treatment of the mixture of the titanium compound and the carbon compound can, according to a preferred embodiment, advantageously be carried out in a continuously operated calcining unit, preferably a rotary kiln.
  • the modified titanium dioxide can be obtained, in particular in the context of what has been described above, preferably by adding a titanium dioxide (eg having a particle size in the range from 2 to 500 nm or eg 3 to 150 nm or eg 4 to 100 nm or eg 5 to 75 nm or, for example, 10 to 30 nm or, for example, 200 to 400 nm), such as commercially available in powder or slurry form, and from this produces a suspension in a liquid, such as preferably water.
  • a titanium dioxide eg having a particle size in the range from 2 to 500 nm or eg 3 to 150 nm or eg 4 to 100 nm or eg 5 to 75 nm or, for example, 10 to 30 nm or, for example, 200 to
  • a carbonaceous substance is then advantageously added to the suspension.
  • Mixing can be assisted by the use of ultrasound.
  • the mixing process (eg stirring) may preferably last several hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer.
  • the amount of the carbon compound is advantageously 1-40% by weight, accordingly, the amount of the titanium compound is preferably 60-99% by weight.
  • the liquid is removed, for example by filtration, evaporation in vacuo or decantation, and the residue is preferably dried (eg, preferably at temperatures of 70-200 0 C, advantageously over several hours, for example at least 12 hours) and then calcined, for example a temperature of at least 26O 0 C, preferably for example at 300 0 C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours.
  • the calcination may advantageously take place in a closed vessel.
  • the calcination temperature for example 300 0 C, is reached within one hour (slow heating to 300 0 C).
  • a color change of the powder from white to dark brown to beige or slightly yellowish-brownish is preferably observed. Too long a heating leads to inactive, colorless powders. The expert can estimate this with a few routine experiments.
  • the calcination may e.g. advantageously take place until after a color change of the powder from white to dark brown another color change takes place on beige or slightly yellowish-brownish.
  • a maximum temperature of 35O 0 C should preferably not be exceeded.
  • decomposition of the organic carbon compound occurs on the surface of the titanium compound, so that it is preferable to form a modified titanium dioxide containing preferably 0.005-4% by weight of carbon.
  • the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill.
  • the grain fineness to be achieved depends on the grain size of the starting titanium compound.
  • the particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt.
  • the desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as in TiO 2 - pigments, but may also be below or above.
  • the photocatalytic material, preferably modified titanium dioxide, contained in the washing or cleaning agent according to the invention may advantageously have a particle size in the range from 2 to 500 nm, eg 3 to 150 nm or eg 4 to 100 nm or eg 5 to 75 nm or for example 10 to 30 nm or eg 200 to 400 nm.
  • the particle size of the photocatalytic material, preferably modified titanium dioxide may preferably be in the range from 100 to 500 nm, advantageously 200-400 nm. It may also be preferred that the
  • Particle size is very small, e.g. in the range of 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or e.g. 5-50 nm or e.g. 8-30 nm or e.g. 10-20 nm.
  • Very small particles e.g. with a particle size of in particular 2, 3, 4, 5 or 10 nm are preferably included, these can also form together agglomerates, which are then correspondingly larger, e.g. up to 600 nm or up to 500 nm or up to 400 nm or up to 300 nm in size, etc.
  • the particle size may e.g. advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm,
  • Titanium dioxide ie of very small particle size titanium dioxide, e.g. between 2 and
  • the particle size can then be e.g. advantageously at
  • the bulk density of the preferably modified titanium dioxide is preferably in the range from 100 to 800 g / l, advantageously from 200 to 600 g / l, in particular from 300 to 500 g / l.
  • the bulk density may be 350 g / l, 400 g / l or 500 g / l.
  • the (preferably modified) titanium dioxide is present in the anatase crystal modification.
  • the modified titanium dioxide described above is characterized by a very good photocatalytic activity, in particular using daylight.
  • the human eye visible radiation of the visible region of the spectrum with wavelengths between 380 to 800 nm are used very well for the purposes of degradation, deactivation or reduction of impurities from the described modified titanium dioxide.
  • the washing or cleaning agent according to the invention contains a humectant, preferably glycerol, dimers and trimers of glycerol, ethylene glycol, propylene glycol, sugar alcohols such as preferably glucitol, xylitol, mannitol, alkypolyglycosides, fatty acid glucamides, sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol , preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, hydrogenated glucose syrup and / or mixtures of the abovementioned, preferably in amounts of from 0.01 to 10% by weight, advantageously from 0.1 to 5% by weight, in particular from 0.5 to 2% by weight , Wt .-% in each case based on the total washing or cleaning agent.
  • a humectant preferably glycerol, dimers and trimers of g
  • the detergent or cleaning agent comprises at least one, preferably organic, humectant
  • improved deposition and action of the finely divided photoactive material on the substrates to be treated in a cleaning process resulted.
  • a particularly suitable humectant is glycerin as well as its dimers and trimers and / or mixtures thereof.
  • washing or cleaning agents according to the invention have a non-solid consistency, that is to say of a liquid, gelatinous or paste-like consistency, they preferably contain water and / or other solvents.
  • washing or cleaning agent according to the invention is aqueous, ie contains at least> 5% by weight, preferably> 10% by weight, in particular> 15% by weight of water, then a preferred embodiment of the invention is present.
  • Such detergents or cleaners can also be inexpensively and easily produced in existing facilities.
  • larger water contents are possible, e.g. > 20% by weight,> 25% by weight,> 30% by weight,> 35% by weight,> 40% by weight,> 45% by weight or else> 50% by weight.
  • Useful water upper limits may e.g. at 90 wt .-%, 80 wt .-%, 70 wt .-% or 60 wt .-% are.
  • the amount of optionally usable solvent (excluding water) is preferably 0.5 to 25 wt .-% and in particular 2 to 15 wt .-%, based on the total agent.
  • Useful upper limits of optionally usable solvent (excluding water) may e.g. also at 30 wt .-%, 20 wt .-% or 10 wt .-%, meaningful lower limits of optionally usable solvent (except water) can, for. also at 1 wt .-%, 5 wt .-% or 10 wt .-% are.
  • the washing or cleaning agent according to the invention has a viscosity of> 30 mPas, preferably> 1000 mPas, advantageously> 10000 mPas, more preferably> 15000 mPas, even more advantageously> 20,000 mPas and in particular> 25,000 mPas ( measured with Brookfield viscometer DV1 plus at 20 rpm and 2O 0 C, spindle 4).
  • Useful Viskosticiansobergenzen may be at 250000 mPas, preferably 200,000 mPas, in particular 150,000 mPas.
  • skin care products or skin-care active substances are also contained in the washing or cleaning agent according to the invention, in particular in amounts of> 0.01% by weight, based on the total washing or cleaning agent.
  • Skin care agents may in particular be those which give the skin a sensory benefit, e.g. by delivering lipids and / or moisturizing factors.
  • Skin care agents may e.g. Proteins, amino acids, lecithins, lipids, phosphatides, plant extracts, vitamins; Likewise, fatty alcohols, fatty acids, fatty acid esters, waxes, petrolatum, paraffins can act as skin care agents.
  • Skin-care active substances are all those active substances which give the skin a sensory and / or cosmetic advantage.
  • Skin-care active substances are preferably selected from the following substances: a) waxes such as, for example, carnauba, spermaceti, beeswax, lanolin and / or derivatives thereof and others.
  • Hydrophobic plant extracts c) Hydrocarbons such as squalene and / or squalanes
  • Hydrocarbons such as squalene and / or squalanes
  • Higher fatty acids preferably those having at least 12 carbon atoms, for example lauric acid, stearic acid, behenic acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and / or polyunsaturated fatty acids and other.
  • Higher fatty alcohols preferably those having at least 12 carbon atoms, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cholesterol and / or 2-hexadecanol and others.
  • esters preferably such as cetyloctanoates, lauryl lactates, myristyl lactates, cetyl lactates, isopropyl myristates, myristyl myristates, isopropyl palmitates, isopropyl adipates, butyl stearates, decyl oleates, cholesterol stearates, glycerol monostearates, glycerol distearates, glyceryl tristearates, alkyl lactates, alkyl citrates and / or alkyl tartrates and others.
  • lipids such as cholesterol, ceramides and / or sucrose esters and other h) vitamins such as vitamins A and E, vitamin C esters, including vitamin
  • Preferred skin care active substances are preferably also essential oils, in particular selected from the group of Angelica fine - Angelica archangelica, Anis - Pimpinella anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus, Cajeput - Melaleuca leucadendron, Cistrose - Cistrus ladaniferus, Copaiba - Balsam - Copaifera reticulata, Costus root - Saussurea discolor, Edeltann needle - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce Spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho- leaves - Cinnamonum camphora, Immortelle Helichrysum ang., Ginger Extra - Zingiber off., St.
  • essential oils in particular selected from the group of Angelica fine - Angelica ar
  • Preferred skin care active ingredients are preferably also skin-protecting oils, in particular selected from the group algae oil Oleum Phaeophyceae, Aloe vera oil Aloe vera brasiliana, apricot kernel oil Prunus armeniaca, arnica montana Arnica, avocado Persea americana, borage Borago officinalis, Calendulaoil Calendula officinalis, camellia oil Camellia oleifera , Safflower oil Carthamus tinctorius, peanut oil Arachis hypogaea, hemp oil Cannabis sativa, hazelnut oil Corylus avellana, hypericum perforatum, Jojoba oil Simondsia chinensis, caraway oil Daucus carota, coconut oil Cocos nucifera, pumpkin seed oil Curcubita pepo, kukui nut oil Aleurites moluccana, macadamia nut oil Macadamia ternifolia, almond oil Pru
  • the optional skin care actives may be applied to the textile during a textile treatment with an agent of the invention and then transferred from the textile to the skin in turn when the fabric is in contact with the skin, e.g. while wearing clothes.
  • skin-care active ingredients in the washing or cleaning agents according to the invention are beneficial to the skin of the consumer.
  • detergents or cleaners according to the invention which optionally contain skin-care active substances
  • the skin-care active ingredients of the skin of the consumer are of immediate advantage, namely when the hand is in contact with the wash liquor.
  • the use of skin-care active ingredients is purely optional.
  • the washing or cleaning agent according to the invention is contained in a capped, flexible or ductile elongated container (tube), which container preferably has a sponge or a brush at the product outlet.
  • the optional sponge / brush enables the consumer to apply the contained agent without further ado to the target / target substrate.
  • the particularly suitable viscosity is in the range of 5000-50000 mPas, more preferably in the range of 10000 - 25000 mPas (measured with Brookfield viscometer DV1 plus at 20 rev / min and 2O 0 C, spindle 4).
  • Another object of the invention is a process for the preparation of a storage-stable liquid detergent or cleaning agent containing photocatalytic material and other conventional ingredients of detergents or cleaning agents, wherein a system of Aniotensid (preferably fatty alcohol sulfate and / or alkylbenzenesulfonate), nonionic surfactant, preferably fatty alcohol ethoxylate and / or alkyl polyglycoside, and electrolyte (preferably citric acid) as previously described.
  • Aniotensid preferably fatty alcohol sulfate and / or alkylbenzenesulfonate
  • nonionic surfactant preferably fatty alcohol ethoxylate and / or alkyl polyglycoside
  • electrolyte preferably citric acid
  • Another object of the invention is a method for applying photocatalytic material to textiles by treating these textiles in a textile treatment bath containing a washing or cleaning agent according to the invention.
  • a modification of this method provides to contact the textile directly with a washing or cleaning agent according to the invention, without requiring a textile treatment bath for this purpose.
  • Another object of the invention is a method for cleaning, care, equipment, finishing and / or conditioning of textiles by treating these textiles in a textile treatment bath containing a detergent according to the invention, at and / or followed by exposure of the textiles to light in the Wavelength range of 10-1200 nm.
  • the visible of the human eye radiation of the visible range of the spectrum with wavelengths between 380 and 800 nm is particularly suitable.
  • Another object of the invention is a method for cleaning, care, equipment, finishing and / or conditioning of textiles by contacting the textiles with a detergent or cleaning agent according to the invention, at and / or followed by exposure of the textiles to light in the wavelength range of 10 -1200 nm.
  • the visible of the human eye radiation of the visible range of the spectrum with wavelengths between 380 and 800 nm is particularly suitable.
  • the contacting takes place with the aid of a capped, flexible or ductile elongated container (tube), in which the washing or cleaning agent is contained, which container preferably at the product outlet via a sponge or a brush features.
  • the optional sponge / brush enables the consumer to apply the contained agent without further ado to the target / target substrate.
  • Another object of the invention is a method for the local cleaning of textiles, wherein a washing or cleaning agent according to the invention is applied to the soiled areas, rubbed in and washed after a period of exposure in the washing machine or by hand, at and / or followed by exposure
  • the textiles are sensitive to light in the wavelength range of 10-1200 nm.
  • the visible to the human eye radiation of the visible range of the spectrum with wavelengths between 380 and 800 nm is particularly suitable.
  • the application is carried out with the aid of a closure provided with a flexible or ductile elongated container (tube), in which the washing or cleaning agent is contained, said container at the product outlet preferably via a sponge or a Brush has.
  • the optional sponge / brush enables the consumer to apply the contained agent without further ado to the target / target substrate.
  • the method according to the invention is directed to the elimination, deactivation or reduction of microorganisms, in particular bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm, preferably 380 and 800 nm, then a preferred embodiment of the invention is provided .
  • An inventive method for finishing textiles with photocatalytic material to facilitate the removability of colored dirt (colored spots) of textiles using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, also represents a preferred embodiment of the invention.
  • An inventive method for finishing textiles with photocatalytic material to reduce the fiber adhesion of dirt, preferably colored spots, on textiles using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, also represents a preferred embodiment of the invention.
  • An inventive method for finishing textiles with photocatalytic material to prevent the formation of fetid odors on the textiles, using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, corresponds to a further preferred embodiment of the invention.
  • An inventive method for finishing textiles with photocatalytic material to furnish the textiles with a self-cleaning ability, using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, also represents a preferred embodiment of the invention.
  • a method according to the invention for the removal or reduction of colored soils or stains on textiles which in particular originate from: red to blue anthocyanin dyes, such as e.g. Cyanidin, e.g. from cherries or
  • Red betanidine from beetroot orange-red carotenoids such as lycopene, beta-carotene, eg from tomatoes or carrots
  • yellow curcuma dyes such as curcumin, for example from curry and mustard, brown tannins, eg from tea, fruit, red wine, deep brown humic acid, eg from coffee, tea, cocoa, green chlorophyll, eg, from green grasses, technical dyes from cosmetics, inks, colored pencils colored metabolites and / or excretory products of mold or other Mirkoflora or microbial growth or microbes, using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, again constitutes a preferred embodiment of the invention.
  • a method according to the invention which is a manual process carried out in an open tub, in particular hand washing and / or soaking, wherein the tub, after the textiles to be treated have penetrated with the wash liquor, light in the wavelength range of 10 -1200 nm, preferably 380 to 800 nm exposes, in particular sunlight, preferably for a period> 5 minutes, also represents a preferred embodiment of the invention.
  • Another object of the invention is a method for cleaning hard surfaces, comprising:
  • hard surfaces are surfaces of the inside area, wet spaces and / or the outside area, preferably around
  • Sanitary products such as sanitary basin and furniture, bathtubs and wash basins, shower curtains, bathroom fixtures, tiles
  • kitchen furnishings and utensils such as, preferably, ovens, glass ceramic hobs, hobs, kitchen furniture, kitchen fittings, porcelain items, ceramics, grills (including garden barbecues)
  • structure and property such as preferably masonry, wallpapered, painted, painted walls and / or ceilings, bricks, bricks, plaster, floor slabs, joints, preferably cement and silicone joints, laminate, plastic surfaces, garage doors, plasterboard
  • outdoor furnishings and garden accessories preferably garden furniture, stair treads, swimming pools, walkway fixtures of wood and stone, e.g. Path plates, garden sheds, wooden fences, ornamental and fruit trees, so is a preferred embodiment of the invention.
  • the hard surface treated with a washing or cleaning agent according to the invention is subjected to a mechanical treatment after completion of light exposure, such as preferably brushing, suction or abrasion, in particular spraying, preferably by means of high-pressure cleaner, a preferred embodiment of the invention is provided.
  • the application of the washing or cleaning agent according to the invention by brushing, rubbing, spraying, wiping or in particular by spraying, preferably by means of high-pressure cleaner, so there is a preferred embodiment of the invention.
  • the application is carried out by means of a closure provided with a flexible or ductile elongated container (tube), in which the washing or cleaning agent is contained, which container preferably has a sponge or a brush at the product outlet.
  • the optional sponge / brush enables the consumer to apply the contained agent without further ado to the target / target substrate.
  • the method is directed to the defense against or inhibition of algae, moss, lichens, fungi, especially molds, spores, bacteria and other microflora and other microbial growth on hard surfaces, by treating these surfaces with detergents or cleaning agents according to the invention and / or followed by exposure of the substrate to light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, so is a preferred embodiment of the invention.
  • Another object of the invention is the use of a detergent or cleaner according to the invention for the removal of mold stains and / or foxing of hard surfaces such as tile surfaces, cement and silicone joints, wallpapered, painted, painted walls and / or ceilings, wood, shower curtains, sanitary products under Use of light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm.
  • red to blue anthocyanin dyes e.g. Cyanidin, e.g. from cherries or blueberries, red betanidine from beetroot, orange-red carotenoids, e.g. Lycopene, beta-carotene, e.g. from tomatoes or carrots, yellow curcuma dyes, e.g. Curcumin, e.g. curry and mustard, brown tannins, e.g. from tea, fruit, red wine, deep brown humic acid, e.g.
  • red to blue anthocyanin dyes e.g. Cyanidin, e.g. from cherries or blueberries, red betanidine from beetroot, orange-red carotenoids, e.g. Lycopene, beta-carotene, e.g. from tomatoes or carrots
  • yellow curcuma dyes e.g. Curcumin, e.g. curry and mustard
  • brown tannins e.g. from tea, fruit, red wine, deep brown hum
  • a detergent or cleaner according to the invention is directed to the removal of paint stains (graffiti) from sprayed objects, such as preferably house walls, railway vehicles and traffic structures such as underpasses and highway bridges using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, so is a preferred embodiment of the invention.
  • the use of a detergent or cleaner according to the invention is directed to a prophylactic treatment of hard surfaces in the form of an anticipatory defense and inhibition of stains and stains, especially mold stains and / or foxing using light in the wavelength range of 10-1200 nm, preferably 380 to 800 nm, so is a preferred embodiment of the invention.
  • a detergent or cleaner according to the invention is directed to the denaturation or growth inhibition of molds, mold spores and lichens or other microflora or other microbial growth or microbes on hard surfaces using light in the wavelength range of 10-1200 nm, preferably 380-800 nm , so is a preferred embodiment of the invention.
  • washing or cleaning agents according to the invention may contain, in addition to the mandatory constituents, further optional ingredients.
  • further optional ingredients include, in addition to the mandatory constituents, further optional ingredients.
  • % By weight information always refers to the entire detergent or cleaning agent, unless otherwise specified.
  • the detergents or cleaners according to the invention may contain, in particular, further surfactant (s), it being possible in particular additionally to use cationic and / or amphoteric surfactants.
  • the total surfactant content of the washing or cleaning agent according to the invention is preferably below 40% by weight and more preferably below 35% by weight, based on the total washing or cleaning agent.
  • washing or cleaning agent according to the invention contains, in addition to the preferred fatty alcohol alkoxylate and / or alkyl polyglycoside, additional nonionic surfactants, then a preferred embodiment is present.
  • nonionic surfactants which can additionally be used in addition to fatty alcohol alkoxylate and / or alkyl polyglycoside are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl ester.
  • Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be used, preferably in addition to fatty alcohol alkoxylate and / or alkylpolyglycoside.
  • Further surfactants which can additionally be used in addition to fatty alcohol alkoxylate and / or alkyl polyglycoside are polyhydroxy fatty acid amides of the formula (2)
  • RCO is an aliphatic acyl radical having 6 to 22 carbon atoms
  • R ⁇ is hydrogen
  • [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the formula (3), R 1 -OR 2
  • R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms
  • R 1 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms
  • R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms
  • Ci_ 4 alkyl or phenyl radicals are preferred
  • [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted with at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives thereof residue.
  • [Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
  • additional nonionic surfactants in addition to fatty alcohol alkoxylate and / or alkyl polyglycoside leads to a particularly good cleaning performance and corresponds to a preferred embodiment of the invention.
  • the content of additional nonionic surfactants in addition to fatty alcohol alkoxylate and / or alkyl polyglycoside can preferably be 1 to 20% by weight, preferably 2 to 15% by weight and in particular 3 to 10% by weight, in the detergents or cleaners according to the invention. in each case based on the total mean. It is particularly preferred if the amount of these additional nonionic surfactants is not greater than that of the preferably present fatty alcohol alkoxylate and / or alkyl polyglycoside, in particular not more than half or one-fourth thereof.
  • washing or cleaning agent according to the invention is free of additional nonionic surfactant (except preferably fatty alcohol alkoxylate and / or alkylpolyglycoside), that is less than 5 wt .-%, 4 wt .-%, 3 wt. Contains%, 2% by weight or less than 1 wt .-% of additional nonionic surfactant, in particular no, so 0 wt .-% additional nonionic surfactant contains.
  • additional nonionic surfactant except preferably fatty alcohol alkoxylate and / or alkylpolyglycoside
  • the washing or cleaning agent according to the invention contains anionic surfactants, with fatty alcohol sulfate and / or alkylbenzenesulfonate being the most preferred.
  • anionic surfactants which can be used are, for example, those of the sulfonate and sulfates type.
  • surfactants of the sulfonate type preferably come C 9 - 13 - alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, such as those from C 12 -i 8 monoolefins with terminal or internal double bond by sulfonation with gaseous Sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation obtained.
  • alkanesulfonates which from C
  • esters of .alpha.-sulfo fatty acids for example the .alpha.-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • sulfated fatty acid glycerol esters are to be understood as meaning the mono-, di- and triesters and mixtures thereof, as in the preparation by esterification of a monoglycerol with 1 to 3 mol of fatty acid or in the transesterification of triglycerides with 0.3 to 2 mol Glycerol can be obtained.
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • sulfuric acid monoesters of straight-chain or branched C 7 ethoxylated with 1 to 6 moles of ethylene oxide are suitable.
  • 2 i-alcohols such as 2-methyl-branched Cg-n-alcohols having on average 3.5 mol of ethylene oxide (EO) or C 12 -i 8 -fatty alcohols having 1 to 4 EO, are suitable. You will be in cleaning Because of their high performance m s only in relatively small amounts, for example in amounts of 1 to 5 wt .-%, used.
  • alkylsulfosuccinic acid which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and which are monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C 8 -i 8 -fatty alcohol residues or mixtures of these.
  • Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants (see description below).
  • Sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred.
  • alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
  • Particularly preferred anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably in the form of their sodium or potassium salts, Ca or Mg salts, in particular in the form of the sodium salts or magnesium salts or mixtures of the two.
  • the content of preferred washing or cleaning agents to anionic surfactants may advantageously be 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total agent. It is particularly preferred that the amount of fatty acid soap is at least 1% by weight, and more preferably at least 3% by weight, and most preferably at least 4% by weight.
  • the detergents or cleaning agents according to the invention may also contain further optional ingredients which can further improve in particular the performance and / or aesthetic properties of the washing or cleaning agent according to the invention, for example from the group of builders, bleaches, bleach activators, enzymes, nonaqueous solvents, pH adjusters, fragrances, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, Antiredeposition agents, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, corrosion inhibitors, antistatic agents, ironing auxiliaries, repellents and impregnating agents, swelling and anti-slip agents and UV absorbers.
  • further optional ingredients which can further improve in particular the performance and / or aesthetic properties of the washing or cleaning agent according to the invention, for example from the group of builders, bleaches, bleach activators, enzymes, nonaqueous solvents, pH adjusters, fragrances, perfume carriers, fluoresc
  • washing or cleaning agent according to the invention contains builders, then a preferred embodiment is present.
  • Suitable builders which may be present in the washing or cleaning agents according to the invention are, in particular, silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
  • Suitable crystalline, layered sodium silicates have the general formula NaMSi x O 2x + I H 2 O, where M is sodium or hydrogen, x is a number from 1, 9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are.
  • Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3.
  • both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 yH 2 O are preferred.
  • the washing or cleaning agent according to the invention may also contain only small amounts, that is to say less than 5% by weight, 4% by weight, 3% by weight, 2% by weight or less than 1 % By weight, in particular no crystalline layered sodium silicates, ie 0% by weight.
  • amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
  • the dissolution delay compared to conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compacting / compacting or by overdrying.
  • the term "amorphous" is also understood to mean "X-ray amorphous”.
  • the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Such so-called X-ray amorphous silicates also have a dissolution delay compared to conventional water glasses.
  • the washing or cleaning agent according to the invention may also contain only small amounts, ie less than 5% by weight, 4% by weight, 3% by weight, 2% by weight or less than 1% by weight. %, in particular no, ie 0 wt .-%, contain amorphous sodium silicate.
  • the optionally usable finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P.
  • zeolite P zeolite MAP ® commercial product from Crosfield
  • zeolite X and mixtures of A, X and / or P are particularly preferred.
  • commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) which is sold by SASOL under the brand name VEGOBOND AX ® and by the formula),
  • the zeolite can be used as a spray-dried powder or else as an undried, stabilized suspension which is still moist from its production.
  • the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols.
  • Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22
  • the washing or cleaning agent according to the invention may e.g. but also only small amounts, that is less than 5 wt .-%, 4 wt .-%, 3 wt .-%, 2 wt .-% or less than 1 wt .-%, in particular also no, ie 0 wt. -%, containing zeolite.
  • the washing or cleaning agent according to the invention may, for example, also small amounts, that is less than 5 wt .-%, 4 wt .-%, 3 Wt .-%, 2 wt .-% or less than 1 wt .-%, in particular also no, so 0 wt .-%, phosphate (s) included.
  • bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
  • the washing or cleaning agent according to the invention may also contain only small amounts, that is to say less than 5% by weight, 4% by weight, 3% by weight, 2% by weight or less than 1 % By weight, in particular none, ie 0% by weight, of the bleaching agent just mentioned.
  • bleach activators can be incorporated into the detergents or cleaning agents.
  • bleach activators it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid.
  • Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
  • polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxo-hexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2, 5-diacetoxy-2,5-dihydrofuran.
  • TAED tetraacety
  • the washing or cleaning agent according to the invention may also contain only small amounts, that is to say less than 5% by weight, 4% by weight, 3% by weight, 2% by weight or less than 1 Wt .-%, in particular no, so 0 wt .-%, bleach activators.
  • bleach catalysts can also be incorporated into the detergents or cleaners according to the invention.
  • These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or - carbonyl complexes.
  • Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
  • the inventive Washing or cleaning agents for example, but also only small amounts, in particular no, so 0 wt .-%, bleach catalysts.
  • Suitable enzymes are, in particular, those from the classes of the hydrolases, such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of said enzymes. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. In addition, cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils. Oxireductases can also be used for bleaching or inhibiting color transfer.
  • hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of said enzymes. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
  • Bacillus subtilis Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • Bacillus subtilis Bacillus subtilis
  • Bacillus licheniformis Bacillus licheniformis
  • Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
  • enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. In specific embodiments, tannases can also be used.
  • Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • As cellulases are preferably cellobiohydrolases, endoglucanases and ß-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases. It is particularly advantageous if the washing or cleaning agents according to the invention contain mannanase, in particular incorporated in microcapsules and / or speckles.
  • mannanase in combination with the photocatalytic material has a particularly good effect in the soil release of galactomannan ambiencen residues on textiles and hard surfaces.
  • tannase is particularly preferred and corresponds to a preferred embodiment of the invention.
  • the enzymes may be adsorbed to carriers to protect against premature degradation.
  • the proportion of enzymes, enzyme liquid formulations, enzyme mixtures or enzyme granules may for example be about 0.1 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.
  • the washing or cleaning agent according to the invention may also contain, for example, only small amounts, in particular none, ie 0% by weight, of enzymes.
  • Optional nonaqueous solvents which can be used in the detergents or cleaners according to the invention are derived, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers.
  • the solvents are preferably selected from ethanol, n- or i-propanol, butanols, glycol, butanediol, glycerol, diglycol, butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, di-propylene glycol monomethyl or ethyl ether, di-isopropylene glycol monomethyl or ethyl ether, methoxy, e
  • nonaqueous solvents can be used in detergents or cleaners according to the invention, e.g. in amounts between 0.5 and 8 wt .-%, but preferably below 5 wt .-% and in particular below 3 wt .-% are used.
  • pH adjusters In order to bring the pH value of the detergents or cleaners according to the invention into the desired range, the use of pH adjusters may be indicated.
  • hydrotropes include the sulfonated hydrotropes, such as the alkylaryl sulfonates or alkylaryl sulfonic acids.
  • Preferred hydrotropes are selected from xylene, toluene, cumene, naphthalenesulfonate or sulfonic acid and mixtures thereof. Counterions are preferably selected from sodium, calcium and ammonium.
  • the detergents or cleaners of the invention may comprise from 0.01% to 20% by weight of a hydrotrope, more preferably from 0.05% to 10%, and most preferably from 0.1% to 5% by weight.
  • Suitable dyes In order to improve the aesthetic impression of the washing or cleaning agents according to the invention, they can be dyed with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • Suitable foam inhibitors which can be used in the detergents or cleaners according to the invention are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
  • Suitable anti-redeposition agents which are also referred to as "soil repellents" are, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion of methoxy groups of 15 to 30% by weight and of hydroxypropyl groups of 1 to 15% by weight, based in each case on nonionic cellulose ethers and the polymers of phthalic acid and / or terephthalic acid known from the prior art or of derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionically and / or nonionically modified derivatives thereof, particularly preferred of these are the sulphonated derivatives the phthalic and terephthalic acid polymers.
  • Optical brighteners may be added to the detergents or cleaners of the present invention to eliminate graying and yellowing of the treated fabrics
  • the fabrics soak onto the fiber and cause lightening and fake bleaching by causing invisible ultraviolet radiation convert visible light of longer wavelength, the absorbed from sunlight ultraviolet light is radiated as a pale blue fluorescence and the yellow shade of the grayed or yellowed laundry pure white.
  • Suitable compounds originate for example from the substance classes of the 4,4-diamino-2, 2 stilbenedisulfonic acids (flavonic), 4,4 'biphenylene -Distyryl-, Methylumbelliferone, coumarins, dihydroquinolinones, 1, 3-diaryl pyrazolines, naphthalimides, benzoxazole, benzisoxazole, and benzimidazole systems, and pyrene derivatives substituted by heterocycles.
  • the optical brighteners can usually be used in amounts, for example, between 0.03 and 0.3 wt .-%, based on the finished composition.
  • Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
  • Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
  • cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, for example in amounts of from 0.1 to 5% by weight, based on the compositions used. Since fabrics, particularly rayon, rayon, cotton and blends thereof, can tend to wrinkle because the individual fibers are susceptible to flexing, buckling, squeezing and squeezing across the grain, the compositions may contain synthetic crease inhibitors.
  • detergents or cleaners according to the invention may contain antimicrobial agents.
  • antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostats and bactericides, fungistatics and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenolmercuric acetate, and the compounds according to the invention can be completely dispensed with.
  • compositions may contain antioxidants.
  • This class of compounds includes, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites and phosphonates.
  • Antistatic agents increase the surface conductivity and thus allow an improved drainage of formed charges.
  • External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
  • External antistatic agents are, for example, lauryl (or stearyl) dimethylbenzylammonium chlorides, which are suitable as antistatic agents for textile fabrics or as an additive to laundry detergents, with an additional finishing effect being achieved.
  • silicone derivatives be used. These additionally improve the rinsing behavior of the agents by their foam-inhibiting properties.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the detergents or cleaners according to the invention may optionally also contain UV absorbers which are absorbed by the treated textile fabrics and improve the light fastness of the fibers.
  • UV absorbers which are absorbed by the treated textile fabrics and improve the light fastness of the fibers.
  • Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid.
  • Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
  • EDTA ethylenediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • anionic polyelectrolytes such as polymaleates and polysulfonates.
  • a preferred class of complexing agents are the phosphonates found in preferred detergents or cleaners according to the invention, e.g. in amounts of 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1, 5 wt .-% are included.
  • organophosphonates such as, for example, 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriaminepenta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1 , 2,4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
  • organophosphonates such as, for example, 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriaminepenta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1 , 2,4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
  • Preferred complexing agents are tertiary amines, in particular tertiary alkanolamines (amino alcohols).
  • the alkanolamines have both amino and hydroxy and / or ether groups as functional groups.
  • Particularly preferred tertiary alkanolamines are tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis (2-hydroxy-propyl) ethylenediamine).
  • Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art.
  • a particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1, 1-diphosphonic acid, 1-hydroxyethyl-1, 1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts.
  • the textile treatment agent according to the invention accordingly contains etidronic acid and / or one or more of its salts as complexing agent.
  • the resulting washing or cleaning agents according to the invention are clear in a preferred embodiment of the invention, that is to say they have no sediment and are preferably transparent or at least translucent.
  • the detergents or cleaners according to the invention without addition of a dye have a transmission of the visible light (410 to 800 nm) of at least 30%, preferably at least 50% and especially preferably at least 75%.
  • the textile treatment agent optionally contains one or more perfumes (perfume oils, fragrances), for example in an amount of usually up to 10% by weight, preferably 0.01 to 5% by weight, in particular 0.05 to 3% by weight. %, more preferably 0.1 to 2 wt .-% and most preferably 0.4 to 0.8 wt .-%. The amount of perfume used depends on the type of application.
  • perfume oils fragments, fragrances
  • individual fragrance compounds e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used.
  • mixtures of different fragrances are used, which together produce an attractive fragrance.
  • perfume oils may also contain natural fragrance mixtures as are available from plant sources.
  • perfume oil is meant preferably self-contained perfume compositions which are commonly used for product scenting and are fragrant in particular at the human discretion. This will be explained with an example. If an expert wants to To make a cleanser fragrant, he usually adds to it not only a (well) smelling substance but a collective (well) smelling substance. Such a collective usually consists of a plurality of individual fragrances, e.g. more than 10 or 15, preferably up to 100 or more. These fragrances cooperatively form a desired fragrant, harmonious odor image.
  • a usable perfume oil may contain individual fragrance compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate (DMBCA), phenylethyl acetate, benzyl acetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate.
  • DMBCA dimethylbenzylcarbinyl acetate
  • the ethers include, for example, benzyl ethyl ether and ambroxane, to the aldehydes, for example, the linear alkanals with 8 - 18 carbon atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones such as the ionone, ° c-
  • the terpenes can be next to the Fragrance impression at the same time as a washing power
  • the perfume oils may also contain natural fragrance mixtures, such as are available from vegetable sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroliol, orange peel oil and sandalwood oil.
  • a fragrance must be volatile, with molecular weight also playing an important role in addition to the nature of the functional groups and the structure of the chemical compound.
  • odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note”, “middle note or body” and “base note “(end note or dry out) divided.
  • Adhesive-resistant fragrances which can advantageously be used in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, Champacablütenöl, Edeltannenöl, Edeltannenzapfenöl, Elemiöl, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil , Gurjunbalsamöl, Helichrysumöl, Ho oil, ginger oil, iris oil, Kajeputöl, calamus oil, chamomile oil, camphor oil, Kanagaöl, cardamom oil, cassia oil, pine oil, Kopa ⁇ vabalsamöl, coriander oil, spearmint oil, caraway oil, cumin oil, lemongrass oil, musk oil, myrrh oil, clove oil, neroliol, niaouli oil , Olibanum oil
  • fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures.
  • These compounds include the following compounds and mixtures thereof: ambrettolide, ⁇ -amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, ⁇ -bromostyrene, n Decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotro
  • the lower-boiling fragrances include natural or synthetic origin, which can be used alone or in mixtures.
  • Examples of more readily volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.
  • Condensation products of amines and aldehydes may preferably be present in the washing or cleaning agent according to the invention.
  • Preferred examples of condensation products of amines and aldehydes are anisaldehyde methyl anthranilate, aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde methyl anthranilate), vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalcyl anthranilate, hydroxycitronellinallylanthranilate, methyl -N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) -anthranilate, methylnaphthyl-ketone-methyl-anthranilate, methyl nonyl-acetaldehyde
  • fragrances such as, for example, adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2 , 3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6,6,9A tetramethyl-naphtho [2.1B] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexylsalicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionalde
  • adoxal 2,
  • the washing or cleaning agent according to the invention contains certain minimum values of perfume oil (fragrances), namely at least 0.00001% by weight, advantageously at least 0.0001% by weight, considerably advantageously at least 0.001% by weight, more preferably at least 0.01% by weight, more preferably at least 0.1% by weight, even more advantageously at least 0.2% by weight, most preferably at least 0.3% by weight.
  • perfume oil fragments
  • % in a particularly advantageous manner at least 0.4% by weight, in a particularly advantageous manner at least 0.45% by weight, in a significantly advantageous manner at least 0.5% by weight, in a very advantageous manner at least 0, 55 wt .-%, in an extremely advantageous manner at least 0.6 wt .-%, most advantageously at least 0.65 wt .-%, most advantageously at least 0.7 wt .-%, in an exceptionally advantageous manner at least 0, 75 wt .-%, in an exceptionally advantageous manner at least 0.8 wt .-%, in an extremely advantageous manner, at least 0.85 wt .-%, in particular at least 0.9 wt .-% of perfume oil, based on the total washing or cleaning agent.
  • the perfume oils contain less than 8, advantageously less than 7, more preferably less than 6, more preferably less than 5, more preferably less than 4, more preferably less than 3, preferably less than 2, especially no fragrances from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexene carboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, farnesol, hexyl cinnamaldehyde, lilial, d-limonene, linalool, methylheptincarbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-
  • the washing or cleaning agent according to the invention can be completely free of perfume oil (fragrances). However, it is much more preferred that fragrances are included.
  • the liquid washing or cleaning agent may preferably be provided per conventional methods, wherein the material to be dispersed (photocatalytic material, optionally speckles, microcapsules if necessary) before adjusting the final viscosity (preferably homogeneous or in special embodiments, also hetereogen (at least 2-phase)) is added and introduced by mixing in the washing or cleaning agent according to the invention.
  • the setting of the desired viscosity is then advantageously carried out by slowly stirring in the electrolyte, preferably salt and / or acid.

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  • Wood Science & Technology (AREA)
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Abstract

L'invention décrit des agents de lavage ou de nettoyage à consistance liquide, gélifiée ou pâteuse, qui contiennent un matériau photocatalytique, un tensioactif anionique et un tensioactif non ionique, ainsi qu'un ou des acide(s), une ou des base(s) et/ou un ou des sel(s) en tant qu'électrolyte. Ces agents de lavage ou de nettoyage dispensent d'employer des épaississants classiques, tout en permettant d'obtenir des viscosités élevées, allant jusqu'à une consistance pâteuse. Ces agents permettent le nettoyage, l'entretien, le finissage, l'avivage et/ou le conditionnement durables de textiles par exposition à de la lumière. Ils permettent aussi de nettoyer durablement des surfaces dures.
PCT/EP2008/052999 2007-05-31 2008-03-13 Agent de lavage ou de nettoyage à consistance liquide, gélifiée ou pâteuse Ceased WO2008145424A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200710025562 DE102007025562A1 (de) 2007-05-31 2007-05-31 Wasch- oder Reinigungsmittel mit flüssiger, gelförmiger oder pastenartiger Konsistenz
DE102007025562.6 2007-05-31

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WO2008145424A1 true WO2008145424A1 (fr) 2008-12-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2688996B1 (fr) 2011-03-22 2015-05-06 Henkel AG&Co. KGAA Lessive liquide comprenant des capsules
CN113564613A (zh) * 2021-08-26 2021-10-29 王霞 一种用于清洗激光全息模压版的清洗剂

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3053897B1 (fr) 2016-07-13 2022-05-20 Commissariat Energie Atomique Gel de decontamination adsorbant et photocatalytique et procede de decontamination de surfaces utilisant ce gel

Citations (8)

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US4695394A (en) * 1984-04-20 1987-09-22 The Clorox Company Thickened aqueous cleanser
US5507968A (en) * 1994-12-14 1996-04-16 Minnesota Mining And Manufacturing Company Cleansing articles with controlled detergent release and method for their manufacture
FR2729673A1 (fr) * 1995-01-25 1996-07-26 Rhone Poulenc Chimie Composition detergente contenant du dioxyde de titane a fonction bactericide et photo-oxydante
WO1998000517A2 (fr) * 1996-06-28 1998-01-08 The Procter & Gamble Company Compositions detergentes liquides non aqueuses
US6767878B1 (en) * 2003-07-23 2004-07-27 Colgate-Palmolive Company Light duty liquid cleaning composition with suspended solid particles
US20050079983A1 (en) * 2003-10-09 2005-04-14 Colgate-Palmolive Company Zinc oxide containing surfactant solution
WO2008003632A1 (fr) * 2006-07-07 2008-01-10 Henkel Ag & Co. Kgaa Produit de traitement pour la peau désinfectant
WO2008003631A1 (fr) * 2006-07-07 2008-01-10 Henkel Ag & Co. Kgaa Agent de lavage, de nettoyage et d'entretien

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4695394A (en) * 1984-04-20 1987-09-22 The Clorox Company Thickened aqueous cleanser
US5507968A (en) * 1994-12-14 1996-04-16 Minnesota Mining And Manufacturing Company Cleansing articles with controlled detergent release and method for their manufacture
FR2729673A1 (fr) * 1995-01-25 1996-07-26 Rhone Poulenc Chimie Composition detergente contenant du dioxyde de titane a fonction bactericide et photo-oxydante
WO1998000517A2 (fr) * 1996-06-28 1998-01-08 The Procter & Gamble Company Compositions detergentes liquides non aqueuses
US6767878B1 (en) * 2003-07-23 2004-07-27 Colgate-Palmolive Company Light duty liquid cleaning composition with suspended solid particles
US20050079983A1 (en) * 2003-10-09 2005-04-14 Colgate-Palmolive Company Zinc oxide containing surfactant solution
WO2008003632A1 (fr) * 2006-07-07 2008-01-10 Henkel Ag & Co. Kgaa Produit de traitement pour la peau désinfectant
WO2008003631A1 (fr) * 2006-07-07 2008-01-10 Henkel Ag & Co. Kgaa Agent de lavage, de nettoyage et d'entretien

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2688996B1 (fr) 2011-03-22 2015-05-06 Henkel AG&Co. KGAA Lessive liquide comprenant des capsules
CN113564613A (zh) * 2021-08-26 2021-10-29 王霞 一种用于清洗激光全息模压版的清洗剂

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