WO2008016169A1 - Process for production of aluminum alloy formings, aluminum alloy formings and production system - Google Patents
Process for production of aluminum alloy formings, aluminum alloy formings and production system Download PDFInfo
- Publication number
- WO2008016169A1 WO2008016169A1 PCT/JP2007/065331 JP2007065331W WO2008016169A1 WO 2008016169 A1 WO2008016169 A1 WO 2008016169A1 JP 2007065331 W JP2007065331 W JP 2007065331W WO 2008016169 A1 WO2008016169 A1 WO 2008016169A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mass
- aluminum alloy
- heat treatment
- forging
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/045—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds for horizontal casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J1/00—Preparing metal stock or similar ancillary operations prior, during or post forging, e.g. heating or cooling
- B21J1/02—Preliminary treatment of metal stock without particular shaping, e.g. salvaging segregated zones, forging or pressing in the rough
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
- B21K1/00—Making machine elements
- B21K1/18—Making machine elements pistons or plungers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
- B22D11/003—Aluminium alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/16—Controlling or regulating processes or operations
- B22D11/18—Controlling or regulating processes or operations for pouring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/002—Castings of light metals
- B22D21/007—Castings of light metals with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F3/00—Pistons
- F02F3/0084—Pistons the pistons being constructed from specific materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/02—Light metals
- F05C2201/021—Aluminium
Definitions
- the present invention relates to a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, an aluminum alloy molded article, and a production system thereof.
- automobiles have adopted the use of forged aluminum for internal combustion engine pistons in order to improve performance and respond to environmental problems. It has been studied. This is because the driving parts of the internal combustion engine, such as Biston, can be reduced, and the load when the internal combustion engine is operated can be reduced, the output can be improved, and the fuel consumption can be reduced.
- Forged internal combustion engine pistons made of aluminum alloy have been widely used forged products. However, it is difficult to control internal defects that occur during forged products, and there is a surplus in order to safely design strength. It was necessary to install it, and it was difficult to reduce the weight.
- a conventional method for producing a material for forging an aluminum alloy includes a step of preparing a molten aluminum alloy by a normal molten metal manufacturing method, followed by a continuous forging method, a semi-continuous forging method (DC Manufacturing method), forging by any one of so-called continuous forging methods such as hot top forging method, and the like, and producing a lump of aluminum alloy, After that, the mass was subjected to a homogenization heat treatment to homogenize the aluminum alloy crystals. Then, forging is performed on the aluminum alloy forging material (ingot), and further, JIS (Japanese Industrial Standards) T 6 heat treatment is performed, so that an aluminum / nium alloy forged molded product is manufactured.
- DC Manufacturing method semi-continuous forging method
- Patent Document 1 JP-A-2002-294383
- Patent Document 1 does not discuss the mechanical characteristics at high temperatures.
- Patent Document 2 Japanese Patent Application Laid-Open Publication No. 2005-29054 5
- Patent Document 2 Is a method for producing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, and the aluminum alloy has a content of 10.5 mass% to 13.5 mass 0 /. Si, 0.15 mass% to 0.6 5 mass%? 6, 2.5% to 5.5% by mass. 11 and 0.3 mass. /.
- Pre-heat treatment process including heating process
- a manufacturing method which includes a treatment of holding at 2 ° C to 6 hours at ° C to 480 ° C.
- the present invention has been made in view of the above, and provides a method for manufacturing an aluminum alloy molded article, an aluminum alloy molded article, and a production system that are superior in mechanical strength at higher temperatures than conventional aluminum alloy forging. The purpose is to do. Disclosure of the invention
- a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a material 10.5 mass% to 13.5 mass% Si, 2.5 mass% to 6 mass% Cu, 0.3 mass 0 /. ⁇ 1.5 wt% Mg and 0.8 wt% to 4 wt% Ni, and Ni (wt%) ⁇ [-0.6 8 XCu (wt%) +4.2 ( (Mass%)) satisfying the following relational expression, a heat treatment comprising a preheating process for the material, a preheating process for the material before forging, and a post-heat treatment process for the aluminum alloy molded product. (1) It includes a treatment of holding at 10 ° C. to 480 ° C. for 2 hours to 6 hours.
- the second invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article according to the first invention, the heat treatment temperature in the pre-heat treatment step is 200 ° C to 370 ° C. To do.
- the third invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article according to the first invention, the heat treatment temperature in the pre-heat treatment step is 110 ° C. to 200 ° C.
- a fourth invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article of the first invention, the heat treatment temperature in the pre-heat treatment step is 370 ° C. to 480 ° C.
- the fifth invention of the present invention is the aluminum alloy of the first to fourth inventions described above.
- the post-heat treatment step is maintained at 170 ° C. to 230 ° C. for 1 hour to 10 hours without performing a solution treatment.
- the aluminum alloy in the method for producing an aluminum alloy molded article according to any one of the first to fifth inventions, contains 0.15% by mass to 0.65% by mass of Fe, It is characterized by that.
- a seventh invention of the present invention is the method for producing an aluminum alloy molded article according to the first to sixth inventions, wherein the aluminum alloy contains 0.003 mass% to 0.02 mass% of P. It is characterized by that.
- the eighth invention of the present invention is the method for producing an aluminum alloy molded article according to the first to seventh inventions, wherein the aluminum alloy is 0.003 mass% to 0.03 mass 0 /. Sr, 0.1 mass% to 0.35 mass% 313, 0.0005 mass 0 /. It is characterized by containing any one kind or a combination of two or more kinds of ⁇ 0.015 mass% Na and 0.001 mass% ⁇ 0.02 mass% Ca.
- Ninth aspect of the present invention is the manufacturing method of an aluminum alloy molded product of the first invention to eighth invention, the aluminum alloy, 0.1 wt% to 1. 0 mass 0/0 of Mn, 0.05 wt% to 0. 5 wt% of ⁇ 1 :, 0.04 wt% to 0. 3 mass 0/0 Z r, 0. 01 wt% to 0. 1 5 wt% of V, 0. 01 wt% to 0. including any one or more combinations of a 2 wt 0/0 T i, characterized in that.
- the processing rate of a portion requiring high temperature fatigue strength in the forging step is 90%. It is the following, It is characterized by the above-mentioned.
- the first invention of the present invention is the method for producing an aluminum alloy molded article according to the first invention to the tenth invention, wherein the preheating temperature before processing in the forging process is 380 ° C. to 480 ° It is C.
- the first invention of the present invention is the aluminum of the first invention to the first invention.
- a continuous forging rod is made of an aluminum alloy with an average molten metal temperature of liquidus + 40 ° C to + 230 ° C, and a forging speed of 80 (mm / min) to 2 It is obtained by forging by a continuous forging method at 000 (mm / min).
- the first invention of the present invention is an aluminum alloy molded product manufactured by any one of the above-described methods for manufacturing an aluminum alloy molded product of the first to first inventions.
- a network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed at the time of continuous fabrication in the structure partially remain after molding and heat treatment. To do.
- a fourteenth aspect of the present invention is an aluminum alloy molded article produced by any one of the above-described methods for producing an aluminum alloy molded article of the first to the first inventions.
- Eutectic S i area occupancy is 8% or more
- eutectic S i average particle size is 5 ⁇ or less
- eutectic S i needle ratio 1 The area occupation ratio is 1.2% or more
- the average particle size of the intermetallic compound is 1.5 m or more
- the length of the intermetallic compound or the length of the aggregate of the intermetallic compounds in contact is 3 / im or more. 30% or more.
- the 15th invention of the present invention is the aluminum alloy molded product of the 13th invention or the 14th invention formed as an engine alloy made of aluminum alloy having a crown surface portion and a skirt portion.
- the high-temperature fatigue strength of the crown surface portion is 5 OMPa or more.
- the sixteenth invention of the present invention is a production system in which a series of processes from a molten metal to an aluminum alloy molded product is constructed as a continuous line, wherein the aluminum alloy of the first invention to the first invention is used.
- the method includes any one of the manufacturing methods of the molded product.
- the aluminum alloy is made of Si, Cu, Mg and Since Ni is contained, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness. Further, the composition of the N i and Cu, N i (mass 0/0) ⁇ [one 0. 68 X Cu (mass%) +4. 2 (wt%)] Since satisfying the relational expression, at higher temperatures The fatigue strength characteristics of the steel are improved.
- the alloy composition using the above relational expression of the present invention as an index, it is possible to easily obtain an alloy having fatigue strength characteristics at a higher temperature, and from 350 ° C. An aluminum alloy molded product having excellent mechanical strength can be obtained even at high temperatures.
- the fatigue strength at 350 ° C after holding at 350 ° C for 100 hours is 33 MPa or more.
- These characteristics are, for example, characteristics required for the crown portion of the internal combustion engine piston that is in contact with a high-temperature atmosphere. Therefore, by using the aluminum alloy molded article of the present invention, it is possible to make the wall thinner than the conventional internal combustion engine piston, and it is possible to reduce the weight of the internal combustion engine piston. In addition, it is possible to answer the weight reduction demanded by the market, and to realize a reduction in fuel consumption and an increase in output of the internal combustion engine.
- the heat treatment temperature in the pre-heat treatment step is set to 200 ° C to 370 ° C, the high temperature fatigue strength and forgeability, ductility, and toughness are more balanced. Thus, a better molded product can be obtained.
- the heat treatment temperature in the pre-heat treatment step is set to 10 ° C. to 20 ° C.
- a molded article with better high-temperature fatigue strength can be obtained.
- the forgeability, ductility and toughness are lower than those with heat treatment temperatures of 200 ° C to 370 ° C.
- the heat treatment temperature in the pre-heat treatment step is 370 ° C to 4 ° C. Since the temperature is set to 80 ° C., it is possible to obtain a molded product having better forgeability, ductility, and toughness. However, the high-temperature fatigue strength is lower than that at a heat treatment temperature of 200 ° C to 370 ° C.
- the high temperature fatigue strength is better because it is maintained at 170 ° C to 230 ° C for 1 hour to 10 hours without performing solution treatment in the post heat treatment step.
- a favorable molded product can be obtained.
- the ductility and toughness are lower than those obtained after solution treatment and maintained at 170 to 230 ° C for 1 to 10 hours.
- the aluminum alloy contains 0.15 mass% to 0.65 mass% of e
- the A 1—F e system and the A 1—F e—Si system And A 1—N i _F e particles are crystallized to improve high-temperature mechanical strength.
- the Fe content of 0.15 mass% to 0.65 mass% suppresses an increase in coarse crystals, and improves forgeability, high temperature fatigue strength, and toughness.
- the aluminum alloy contains 0.003 mass% to 0.02 mass% of P
- P since the aluminum alloy contains 0.003 mass% to 0.02 mass% of P, P generates primary crystal Si and gives priority to wear resistance. Further, P has an effect of refining the primary crystal Si, and functions to suppress a decrease in forgeability, ductility and high temperature fatigue strength due to the generated primary crystal Si. And the content of 0.03 mass% to 0.02 mass% of soot suppresses the increase of coarse primary crystals Si, and improves forgeability, high temperature fatigue strength, and toughness.
- the aluminum alloy is 0.003 mass 0 /. ⁇ 0.03 mass% 3]: 0.1 mass% ⁇ 0.35 mass% 315, 0.005 mass% ⁇ 0.01 5 mass% Na, 0.00 1 mass% ⁇ 0 02% by mass. Since one or a combination of two or more of & is included, the generation of primary crystals Si can be suppressed, which is preferable when forgeability, ductility, and toughness are prioritized. And the contents of Sr, Sb, Na, and Ca in this range suppress the generation of primary crystals Si and improve forgeability, toughness, and high-temperature fatigue strength.
- the aluminum alloy is 0.1 mass% to 1. 0% by mass 1 ⁇ 111, 0.05% by mass to 0.5% by mass ⁇ ]: 0.04% by mass to 0.3% by mass Zr, 0.0 1% by mass to 0.15% Since it includes one or more combinations of V 1% by mass, 0.0 1% by mass to 0.2% by mass Ti, or A 1— Mn system or A 1— F e -Mn- S i, A 1 —C r, A 1 —F e— C r—S i, A 1—Z r, k ⁇ HA 1—T i compounds are crystallized or precipitated. Improves the high temperature mechanical strength of rum alloys. And the contents of Mn, Cr, Zr, V and Ti in this range suppress the increase of coarse crystals and improve forgeability, high temperature fatigue strength and toughness.
- the network structure or needle of the crystallized product Since the texture and aggregates are appropriately divided and remain moderately, a molded product having good ductility, toughness and high-temperature fatigue strength can be obtained.
- the average temperature of the molten metal is a liquidus + 40 ° C to + 230 ° C
- the forging speed is 80 (mm / min) to 2000 (mm / min) and forging by a continuous forging method to obtain a continuous forging rod, a uniform and fine crystallized network structure, needle-like structure and aggregate are obtained, and high-temperature fatigue strength and forgeability, A molded product with good ductility and toughness can be obtained.
- the network structure of the crystallized product or the acicular crystallized product or the aggregate of crystallized product formed during continuous forging in the structure is partly formed after molding and heat treatment. Therefore, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness.
- the area occupancy of the eutectic Si is 8% or more
- the average particle size of crystal Si is 5 ⁇ m or less
- the eutectic Si needle shape ratio is 1.4 or more, 25% or more
- the area occupation ratio of intermetallic compounds is 1.2% or more
- the average particle size is 1.5 ⁇ m or more
- the length of intermetallic compounds or the length of the aggregate of intermetallic compounds in contact is 3 / m or more is 30% or more. It is possible to more reliably obtain a molded article having good properties, ductility, and toughness.
- the crown surface portion of the internal combustion engine piston has a sufficient high temperature fatigue strength. Etc. can be used suitably.
- a series of processes from the molten metal to the aluminum alloy molded product is constructed as a continuous line, and at least the process includes the production of any one of the aluminum alloy molded products described above. Since the method includes a process, fatigue strength characteristics at higher temperatures are improved.
- the fatigue strength at 35 ° C. after holding at 350 ° C. for 100 hours is 33 MPa or more.
- These characteristics are, for example, the characteristics required for the crown surface portion of the internal combustion engine piston in contact with the high temperature atmosphere. Therefore, by using the aluminum alloy molded product of the present invention, it is possible to reduce the thickness of the conventional internal combustion engine piston, and to reduce the weight of the internal combustion engine piston. And it can answer the weight reduction demanded by the market, and achieves reduction in fuel consumption and output of internal combustion engines. be able to.
- FIG. 1 is a view showing a forging production system which is an example of a production line for realizing the production process of the present invention.
- FIG. 2 is a diagram showing an example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention.
- FIG. 3 is a view showing another example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention.
- FIG. 4 is a view showing the effective mold length of the continuous forging apparatus used in the present invention.
- FIG. 5 is a view showing another example of the continuous forging apparatus used in the present invention.
- FIG. 6 is a diagram for explaining the relationship between the content ratios of Ni and Cu in an aluminum alloy.
- FIG. 7 (a) is a plan view of a piston having the shapes of Examples 17 and 18 and Comparative Examples 11 to 13 of the present invention.
- Fig. 7 (b) is a front view of the piston shown in Fig. 7 (a).
- FIG. 8 is a cross-sectional view taken along the line M-VDI of FIG. 7 (a).
- the molten aluminum alloy used in the present invention ranges from 10.5 mass% to 1 3.
- Si increases the high-temperature mechanical strength and wear resistance due to the distribution of eutectic S i, and coexists with Mg to precipitate Mg 2 Si particles and improve the high-temperature mechanical strength. If the Si force is less than 1 0.5% by mass, the above effect is small. If it exceeds 13.5% by mass, the crystallization of the primary crystal Si increases and the high-temperature fatigue strength, ductility and toughness are reduced.
- N i generates A 1 ⁇ N i and A 1 _N i _Cu crystals, thereby improving the high-temperature mechanical strength. If the Ni force is less than 0.8% by mass, the above effect is small, and if it exceeds 4% by mass, coarse crystals increase and forgeability, high-temperature fatigue strength, ductility, and toughness decrease.
- Cu precipitates Cu A 1 2 particles, and further generates crystallized A 1—Cu and A 1—Ni—Cu crystals, improving the high-temperature mechanical strength.
- Cu is less than 2.5% by mass, the above effect is small.
- it exceeds 6% by mass coarse crystals of A 1-1 Cu system increase and forgeability, high temperature fatigue strength, ductility, and toughness decrease.
- Mg coexists with Si and precipitates Mg 2 Si particles to improve high-temperature mechanical strength.
- Mg is less than 0.3% by mass, the above effect is small, and when it exceeds 1.5% by mass, coarse crystals of Mg 2 Si increase and forgeability, high-temperature fatigue strength, ductility, and toughness are reduced. Let me down.
- N i and C composition u is N i (wt%) ⁇ [one 0. 68 XC u (mass 0/0) + AA (mass 0/0)] (where, AA is a constant Therefore, it is necessary to satisfy the relational expression AA 4.2, preferably AA ⁇ 4.7. This is because the fatigue strength characteristics at higher temperatures are improved when Ni and Cu satisfy this relational expression.
- An aluminum alloy molded article prepared so that the constant AA is 4.7 or more is preferable because the amount of network-like or acicular intermetallic compounds that contribute to high-temperature strength increases.
- the mechanism for improving the fatigue strength characteristics described above is not clear, but can be estimated as follows.
- a molded article using such an aluminum alloy has a fatigue strength at 350 ° C, which is a preferable value, of 33 MPa or more, and more preferably 43 MPa or more. Furthermore, the fatigue strength at 300 ° C is 55 MPa or more.
- Mn, C r, Z r, V, and T i include A 1—M n system, A 1—F e—M n—S i system, A l—C r system, and A 1—F e— C. rSi-based, Al-Zr-based, Al-V-based, and A1-Ti-based compounds crystallize or precipitate, improving the high-temperature mechanical strength of the aluminum alloy.
- F e a 0.1 5 wt% to 0. 65 wt% preferably comprises (preferably 0.3% to 0.5 mass 0/0), A 1- F e system and A 1-F e—S i system or A 1 1. Crystallize Ni-Fe particles to improve high-temperature mechanical strength. When Fe is less than 0.15% by mass, the above effect is small. When it exceeds 0.65% by mass, the A 1—F e system, A 1 -F e -S i system, or A 1—N i _F e The coarse crystals of the system increase and the forgeability, high temperature fatigue strength, ductility, and toughness decrease.
- P is 0.003 mass% to 0.02 mass% (preferably 0.007 mass%
- P generates primary crystal S i and is therefore preferred when wear resistance is prioritized, and has the effect of refinement of primary crystal S i, and the forgeability, ductility, and high-temperature fatigue strength of the generated primary crystal S i are high. It works to suppress the decline. If P is less than 0.003 mass%, the effect of refining primary crystal 3 i is small, and coarse primary crystal S i is generated at the center of the ingot, reducing forgeability, high-temperature fatigue strength, ductility, and toughness. When P exceeds 0.02 mass%, the generation of primary crystals Si increases and forgeability, high temperature fatigue strength, ductility, and toughness deteriorate.
- 0.003% to 0.03% by mass 31: 0.1% by mass to 0.35% by mass (preferably 0.00% by mass).
- 1 5 wt% to 0. S b of 25 wt%) 0.0005 wt% to 0. 0 1 5 mass 0/0 (preferably 0.00 1 wt% to 0. Na, 01 mass%) 0 .00 1 mass% to 0.02 mass 0 /.
- composition ratio of the alloy components of the aluminum alloy molded product and the ingot lump is, for example, a photoelectric photometric emission spectroscopic analyzer as described in JISH 1 305 (Example: Shimadzu) It can be confirmed by the method according to Sakusho PDA—5 5 0 0).
- FIG. 1 is a diagram showing a production system that is an example of a production line that realizes the production process of the present invention.
- the forged product production system consists of a continuous forging device 8 1 that horizontally forges a continuous forging bar from a molten metal and cuts it to a predetermined length, and a continuous forging forged by this continuous forging device 8 1.
- the post heat treatment apparatus 8 9 includes, for example, a solution heating apparatus 90 that performs solution treatment on the forged product, a quenching apparatus 9 1 that quenches the forged product heated by the solution heating apparatus 90, and this quenching apparatus.
- An aging treatment device 9 2 that performs aging treatment on the forged product quenched by the charging device 9 1 can be used.
- the solution treatment is omitted, it is preferable not to provide the solution heating apparatus 90 and the quenching apparatus 91 but to provide the aging treatment apparatus 92 after the forging apparatus 88.
- the peeling device 84 and the upsetting device can be omitted.
- transfer between each device can be performed by an automatic transfer device.
- Lubricant coating treatment can be replaced with bonder (phosphate coating treatment) equipment 8 6 C.
- the pre-heat treatment apparatus 8 2 has a function of holding the material temperature at 110 ° C. to 48 ° C. for 2 hours to 6 hours.
- the preheating device 87 has a function of setting the material temperature to 3800 ° C. to 48 ° C.
- Post-heat treatment equipment 8 9 solution heat-heating equipment 90 and quenching equipment 9 1 are quenched after the temperature for solution treatment of forged products (molded products) is set to 48 0 ° C to 5 20 ° C It has a function to do.
- the aging treatment device 9 2 of the post heat treatment device 89 has a function of maintaining the temperature of the forged product (molded product) at 1700 ° C. to 230 ° C.
- the production method using the production system of the present invention is a method in which a round bar obtained by forging an aluminum alloy by a continuous forging method is subjected to a pre-heat treatment, and the pre-heat-treated material is used as a raw material by hot plastic working. And a post-heat treatment step after plastic working, wherein the temperature of the pre-heat treatment is 10 to 48 ° C., and the material temperature during hot plastic working In the post-heat treatment process, solution heat is applied directly to the material temperature from 48 ° C to 52 ° C or without solution treatment. The temperature is controlled so as to satisfy the temperature conditions from 1700 ° C to 230 ° C, and the molded products are manufactured consistently from the forging process to each heat treatment process. As a result, a molded product having preferable mechanical strength can be stably produced.
- the force that can give a forging process as the plastic process is a rolling process as long as it satisfies the conditions of the pre-heat treatment temperature, the material temperature during hot plastic working, and the post-heat treatment temperature. It can also be combined with extrusion. This is because, in any case, the effects of the present invention can be obtained in controlling the network of tissue crystals.
- the aluminum alloy molded article of the present invention can be suitably used as a part that requires mechanical strength at high temperatures. For this reason, for example, molded products such as engine pistons, valve lifters, valve retainers, and cylinder liners are The molded product can be manufactured into a desired shape by further machining on a lathe, machining center, etc. as necessary, and used as a part for various products.
- any of the known hot top continuous forging method, vertical continuous forging method, horizontal continuous forging method, and DC forging method should be used.
- Can do for example, one or two or more fluids selected from gas, liquid lubricant, and thermally decomposed gas on the inner wall surface of a cylindrical bowl with forced cooling held so that the central axis is in the horizontal direction
- a columnar metal melt is formed by supplying a molten aluminum alloy containing Si to one end of the cylindrical saddle mold, and the soot mass formed by solidifying the columnar metal melt in the cylindrical saddle mold is formed. It can be a horizontal continuous forging method in which it is pulled out from the other end of the cylindrical saddle type. Below, the case where this invention is applied to the horizontal continuous forging method is demonstrated.
- FIG. 2 is a view showing an example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention.
- a product-made plate-like body 2 1 0 and a cylindrical saddle shape 2 0 1 are arranged.
- the cylindrical saddle mold 20 1 is held so that the saddle mold central axis 2 2 0 is substantially horizontal.
- Forced cooling means is provided inside the cylindrical bowl 2 0 1 so that the molten alloy 2 5 5 becomes the solidified lump 2 1 6, and solidified lump 2 1 6 is provided at the outlet of the cylindrical bowl 2 0 1.
- the forced cooling means is provided.
- a cooling water shower device 205 is provided as an example of means for forcibly cooling the solidified slag 2 16.
- a drive unit (not shown) is installed near the outlet of the cylindrical saddle mold 20 1 so that the solidified clot 2 1 6 that has been forcibly cooled is drawn out at a constant speed and continuously produced. Has been.
- a synchronous cutting machine (not shown) for cutting the drawn forged bar into a predetermined length is provided.
- FIG. Fig. 3 shows a schematic cross-sectional view of an example of a DC forging machine.
- This DC forging machine In this case, the molten aluminum alloy 1 is introduced into the fixed water-cooled mold 5 made of aluminum alloy or copper via the pot 2, the dip tube 3 and the float distributor 4. The water cooling mold 5 is cooled by cooling water 5A. The molten aluminum alloy 6 introduced into the water-cooled mold 5 shrinks by forming a solidified shell 7 at the portion in contact with the water-cooled mold 5, and the solidified aluminum alloy mass 7 A is cooled by the lower mold 9 with the water-cooled mold 5. Pulled down from.
- the aluminum alloy ingot 7 A is further cooled by the water cooling jet 8 supplied from the water cooling mold 5 and is completely solidified.
- the aluminum alloy ingot 7A is cut at a predetermined position and taken out.
- the cylindrical bowl 20 1 is held so that the bowl center axis 2 2 0 is almost horizontal (in the shape), and in the bowl cooling water cavity 2 0 4
- Cooling water shower device 2 0 for forced cooling means of cylindrical bowl 20 1 that forms a shell, and solidified slag 2 1 6 at the outlet end of cylindrical bowl 20 1 This is a cylindrical saddle mold 201 having a forced cooling means for discharging cooling water from 5 to solidify the columnar metal melt 2 15 in the cylindrical saddle mold 210.
- the cylindrical saddle mold 20 1 is connected to the tundish 2 5 0 through a refractory plate-like body 2 1 0 at one end opposite to the jet port of the cooling water shower device 2 0 5. .
- the cooling water for forced cooling of the cylindrical bowl 20 1 and the cooling water for forced cooling of the solidified lumps 2 1 6 are supplied through the cooling water supply pipe 20 3.
- Power S can be supplied separately for each.
- this effective mold length is less than 15 mm, it is impossible to forge because a good film is not formed, and if it exceeds 7 Omm, there is no effect of forced cooling, and solidification by the vertical wall dominates and the cylindrical vertical mold 2 0 1 and molten columnar metal 2 1 5 or the contact resistance with the solidified shell increases, causing cracks in the skin, and tearing at the inner part of the cylindrical saddle 20 1 Since it becomes stable, it is not preferable.
- the material of the cylindrical saddle mold 201 is preferably one or a combination of two or more selected from aluminum, copper, or alloys thereof.
- a combination of materials can be selected in terms of thermal conductivity, heat resistance, and mechanical strength.
- the cylindrical bowl-shaped mold 201 is a bowl-shaped mold in which a permeable porous material 2 2 2 having a self-lubricating property is loaded in a ring shape on the surface in contact with the columnar molten metal 2 15. .
- the ring shape is a state in which the inner surface 2 2 1 of the cylindrical saddle 201 is attached to the entire circumferential direction.
- the permeability of the permeable porous material 2 2 2 is 0.005 [L (liter) / (cm2 / min)] to 0.03 [L / (c 2 / min)], more preferably 0.0. 7 [L / (cm2 / min)] to 0.02 [L / (cm2 / min)) is preferable.
- the thickness of the permeable porous material 2 2 2 to be attached is not particularly limited, but 2 mn! ⁇ 1 Omm, more preferably 3 mm to 8 mm.
- graphite having an air permeability of 0.008 [L / (c m2 / min)] to 0.0 1 2 [L / (c m2 / min)] is used as the permeable porous material 2 2 2.
- the air permeability is measured by measuring the air flow rate per minute of air with a pressure of 2 kgZ cn ⁇ on a test piece with a thickness of 5 mm.
- Cylindrical saddle 20 1 fitted with raw porous material 2 2 2 is preferably used. Cylindrical saddle 20 1, refractory plate 2 10 It is preferable to place an O-ring 2 1 3 on the mating surface of the permeable porous material 2 2 2.
- the shape of the inner wall surface 2 2 1 of the radial cross section of the cylindrical bowl 2 0 1 is triangular, in addition to the circular shape. It may be a shape, a rectangular cross-sectional shape, or a shape having an irregular cross-sectional shape having no symmetry axis or symmetry plane. Alternatively, in the case of forming a hollow gob mass, a core holding a core inside the saddle shape may be used.
- the cylindrical saddle mold 20 1 1 is a cylindrical saddle mold with both ends open, and is formed from one end through a pouring port 2 1 1 drilled in the refractory plate-like body 2 10 1. The molten alloy 2 5 5 enters the inside of the bowl mold 20 1, and the solid clot 2 1 6 is pushed out or pulled out from the other end.
- the inner wall surface 2 2 1 of the cylindrical saddle mold 2 0 1 faces the vertical axis of the bowl 2 2 0 in the direction of pulling out the solidified lump 2 1 6 0 to 3 degrees, more preferably 0 to 1 degree It is formed at an elevation angle of.
- the solidified clot 2 1 6 is not able to be forged because it receives resistance at the outlet of the cylindrical bowl 2 0 1 when it is pulled out of the cylindrical bowl 2 0 1, while it exceeds 3 degrees
- the inner wall surface 2 2 1 of the cylindrical bowl 2 0 1 is insufficiently in contact with the molten metal 2 1 5, and the molten metal 2 1 5 and the solidified shell to the cylindrical bowl 2 0 1
- Solidification becomes insufficient due to the reduced heat removal effect.
- remelted skin may occur on the surface of the solidified lumps 2 16, or it may lead to smoldering traps such as the unsolidified molten alloy 2 5 5 ejecting from the ends of the cylindrical saddle mold 2 0 1. Since it becomes high, it is not preferable.
- the tundish 2 5 0 is supplied to the molten metal inflow part 2 5 1, the molten metal holding part 2 5 2, and the cylindrical vertical mold 2 0 1 that receives the molten aluminum alloy adjusted to the specified alloy composition by an external melting furnace, etc.
- Outflow part 2 5 3 The tundish 2 5 0 maintains the liquid level 2 5 4 of the molten metal 2 5 5 at a position higher than the upper surface of the cylindrical mold 2 0 1, and in the case of multiple frames, each tubular shape
- the molten alloy 2 5 5 is stably distributed to the vertical mold 2 0 1.
- Molten metal holding part 2 5 2 in tundish 2 5 0 2 5 5 is a molten metal plate 2 5 5 is a pouring hole provided in a refractory plate 2 1 0 2 1 1 to a cylindrical bowl 2 0 1 Be poured into hot water.
- the refractory plate-like body 2 1 0 is for separating the tundish 2 5 0 and the cylindrical bowl 2 1 0 1 and can be made of a material having fire and heat insulation, Example For example, Lumi board manufactured by Etias Co., Ltd., Insular manufactured by Foseco Co., Ltd., and fiber blanket board manufactured by Ibiden Co., Ltd. may be mentioned.
- the refractory plate-like body 2 1 0 has such a shape that the pouring port 2 1 1 can be formed.
- One or more pouring spouts 21 1 1 can be formed on the part where the refractory plate-like body 2 10 1 protrudes inward from the inner wall surface 2 2 1 of the cylindrical saddle mold 2 0 1.
- Reference numeral 20 8 denotes a fluid supply pipe for supplying a fluid.
- Lubricating fluid can be listed as the fluid.
- the fluid may be any one or two or more fluids selected from gas and liquid lubricant. It is preferable to separately provide gas and liquid lubricant supply pipes. .
- the fluid pressurized and supplied from the fluid supply pipe 2 0 8 passes through the annular passage 2 2 4 and is supplied to the gap between the cylindrical basket 2 0 1 and the refractory plate-like body 2 1 0. It is preferable that a gap of 200 Aim or less is formed in a portion where the cylindrical saddle mold 20 1 faces the refractory plate-like body 2 10. This gap is so large that the molten alloy 2 5 5 cannot be inserted, and the fluid can flow out to the inner wall surface 2 2 1 of the cylindrical mold 2 0 1.
- the annular passage 2 2 4 is perforated on the outer peripheral surface side of the permeable porous material 2 2 2 attached to the cylindrical saddle mold 20 1, and the fluid is applied to it.
- the corner space 230 is formed by any one or two or more kinds selected from the supplied gas, liquid lubricant, and gas decomposed from the liquid lubricant.
- the forging process included in the production method of the present invention will be described.
- the molten alloy 255 in the tundish 250 passes through the refractory plate 210, and is supplied to the cylindrical bowl 201 held so that the bowl central shaft 220 is substantially horizontal. It is forcibly cooled at the outlet of the cylindrical bowl 201 and becomes a solidified lump 21 6. Since the solidified lumps 2 16 are pulled out at a constant speed by a driving device installed near the outlet of the cylindrical mold 201, they are continuously formed into a forged bar. The drawn forged bar is cut into a predetermined length by a synchronous cutting machine.
- the continuous forging rod is made of an aluminum alloy whose average temperature of molten alloy 255 is liquidus + 40 ° C to + 230 ° C, and the forging speed is set to 300 (mm / min) to 2000 (mm / min).
- the crystallized product is finely dispersed, resulting in a molded product having excellent forging formability and excellent high-temperature mechanical strength.
- a forging speed of 80 (mm / min) to 400 (mm / min) is preferable. Therefore, the forging speed is preferably 80 (mm / m ⁇ ) to 2000 (mm / min).
- the composition of the molten aluminum alloy 255 stored in the tundish 250 will be described.
- the molten alloy 255 has a Si of 10.5 mass% to 13.5 mass% (preferably 11.5 mass% to 13 mass%), 2.5 mass% to 6 mass% (preferably 3. 5 wt% to 5. Cu 5 wt 0/0), 0.3 wt% ⁇ 1. Mg of 5 wt% (preferably 0.5 mass% to 1. 3 mass 0/0), 0.8 mass % to 4 wt% (preferably 1.8% to 3.5 mass 0/0) a N i of, and N i (mass 0/0) ⁇ [chromatography 0. 68 XC u (mass 0/0) + AA (mass 0/0)] (where, AA is a constant, AA ⁇ 4. 2. preferably AA ⁇ 4. 7.) an aluminum alloy that satisfies a relational expression made.
- the molten alloy 25 5, 0.1 wt% to 1 wt% (preferably 0.2 mass% to 0. 5 wt 0/0) Mn of 0.05 wt% to 0. 5 wt 0/0 ( Preferably 0.1 quality
- Fe is contained in an amount of 0.15 mass% / 0 to 0.65 mass% (preferably 0.3 mass% to 0.5 mass%).
- P is 0.003 mass% to 0.02 mass.
- / 0 (preferably 0.007 wt% to 0. 0 1 6 mass 0/0) preferably includes.
- the difference between the height of the liquid level 254 of the molten alloy stored in the tundish 250 and the height of the top surface of the inner wall surface 21 of the cylindrical saddle 20 1 is more preferably 5 ⁇ ! ⁇ 17 Omm.
- liquid lubricant vegetable oil which is a lubricating oil can be used.
- rapeseed oil, castor oil, salad oil can be mentioned. These are less harmful to the environment Is preferable.
- the amount of the lubricating oil supplied is preferably 0.05 (mL / m i r!) To 5 (mL / m i n) [more preferably 0.1 (mL / m i n) to l (m L i n)]. If the supply amount is too small, the breakthrough of the lump will occur due to insufficient lubrication, and if it is excessive, the excess may be mixed in the lump and hinder the uniformity of the grain size distribution.
- the forging speed which is the speed for pulling the solidified lumps 2 1 6 from the cylindrical mold 2 0 1, is 3 0 0 (mm / min) to 2 0 0 0 (mm / min) [more preferably 6 00 (m / min) to 20 00 (mm / min)].
- This is preferable because the network structure of the crystallized product formed by forging becomes uniform and fine, resistance to deformation of the aluminum fabric at high temperatures increases, and high-temperature mechanical strength improves.
- the working effect of the present invention is not limited to the forging speed, but the effect becomes remarkable when the forging speed is increased.
- the amount of cooling water discharged from the cooling water shower device 20 5 is 5 (L / min) to 30 (LZmin) per mold (more preferably 25 (L / min) to 30 (L / min)). Preferably there is. If the amount of cooling water is too small, breakout may occur or the surface of the solidified lumps 2 16 may be remelted to form a non-uniform structure, hindering the uniformity of the crystal grain size distribution. On the other hand, if the amount of cooling water is excessive, the heat removal of the cylindrical saddle 201 will be so large that it becomes impossible to forge.
- the effect of the present invention is not limited to the amount of cooling water, but the effect becomes remarkable when the cooling ability is increased to increase the temperature gradient from the solidification interface into the cylindrical saddle 201.
- the average temperature of the molten alloy 2 5 5 flowing from the tundish 2 5 0 into the cylindrical bowl 2 0 1 is the liquidus + 40 ° C to + 2 3 0 ° C (more preferably the liquidus + 6 0 ° C to 1020 ° C) is preferable. If the temperature of the molten alloy 2 55 is too low, a coarse crystallized product may be formed before and after the cylindrical saddle mold 20 1, which may hinder the uniformity of the crystal grain size distribution. On the other hand, if the temperature of the molten alloy 2 5 5 is too high, a large amount of hydrogen gas will be contained in the molten alloy 2 5 5. This is because the slag is taken in as a single porosity in the solidified lumps 2 1 6 and may hinder the uniformity of the crystal grain size distribution.
- these forging conditions are such that the eutectic Si or intermetallic compound of the structure of the forged product is hardly agglomerated and spheroidized, and the network structure of the crystallized product formed during continuous forging or the needle-like crystallized product or Since it is controlled so as to be an aggregate of crystallized substances, the effect of each subsequent heat treatment is effectively exhibited, which is preferable.
- the forged rod after forging is used as a pre-heat treatment at a temperature of 110 ° C. to 48 ° C. (preferably 110 ° C. to 37 ° C. It is important to hold for 2 to 6 hours.
- the temperature condition is more preferably room temperature, but the effect can be obtained even if the temperature is less than that.
- the pre-heat treatment is performed as described above, a network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed during continuous forging in a structure is formed and an aluminum molded article partially remaining after heat treatment.
- the crystallized material of these shapes acts as a resistance to deformation of the aluminum fabric at high temperatures, and as a result, excellent mechanical strength is obtained even at high temperatures of 250 ° C to 400 ° C. can get. That is, since the network structure of the crystallized material or the acicular crystallized material or the aggregate of crystallized materials becomes resistant to deformation at a high temperature at which the aluminum fabric is softened, the aluminum molded product is excellent in high-temperature mechanical strength.
- the pre-heat treatment temperature is high and the forming ratio is high, the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product is divided and aggregated into particles, and the crystallized product is softened at high temperature. It will be in the state disperse
- the present invention has the alloy composition described above, and the aluminum base material softens and becomes very deformable. Crystallization that resists deformation of the aluminum base material at a further high temperature range of 250 ° C. to 400 ° C. Partially leave a network structure, needle-like structure or aggregate of things This increases the high-temperature mechanical strength.
- the homogenization treatment is suppressed or omitted, such as a low-concentration alloy with a relatively low crystallized content, such as a network of crystallized products and a relatively small amount of crystallized material, it is difficult to recrystallize.
- This is a high Si-based alloy that has many crystallized materials as in the present invention and has a network and a needle-like structure that can be seen during fabrication, and maintains the network and needle-like structure as much as possible. Therefore, it is different from those for improving the temperature.
- Patent Document 1 Japanese Patent Laid-Open No. 2 0 0 2-2 9 4 3 8 relates to a 6 0 0 0 series alloy.
- the reason for suppressing or omitting the temperature of the homogenization treatment is not to obtain high temperature characteristics, but to suppress recrystallization and improve mechanical properties at room temperature.
- the alloy system is different, and it is a low-concentration alloy with relatively few crystallized substances, and the network structure and needle-like structure of the crystallized substances are hardly seen.
- a 1 — M n system, 1–O is used to precipitate system compounds finely. It is a high Si system alloy with many crystallized materials as in the present invention, and a network structure and needle-like structure can be seen at the time of fabrication, and it is intended to improve the high temperature by maintaining the network structure and needle-like structure. Is different.
- the holding temperature of the preheating treatment is 20 ° C. to 3700 ° C.
- eutectic Si and intermetallic compounds during the pre-heat treatment are less likely to agglomerate and spheroidize, and a network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed during continuous fabrication.
- the body remains partially after forging and post-heat treatment, resulting in an aluminum molded product with excellent high-temperature mechanical strength.
- the holding temperature of the pre-heat treatment is preferably 10 ° C. to 200 ° C.
- eutectic Si and intermetallic compounds during pre-heat treatment hardly form agglomerated spheroids and are formed during continuous fabrication.
- the network structure of the crystallized product or the acicular crystallized product or the aggregate of the crystallized product partially remains even after forging and post-heat treatment, resulting in an aluminum molded product having excellent high-temperature mechanical strength.
- the holding temperature of the pre-heat treatment is 370 ° C. to 48 ° C.
- the eutectic Si and the intermetallic compound during the pre-heat treatment are agglomerated to some extent and the deformation resistance during forging is reduced, so that an aluminum molded product with excellent forging formability is obtained.
- the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product formed during continuous forging partially remains after forging and post-heat treatment. Aluminum molded products with excellent mechanical properties can be obtained.
- the pre-heat treatment process may be provided between the forging process after forging. For example, after forging
- the manufacturing method includes a step of forging into a mold and forging and 5) a step of discharging a forged product from the mold by a knockout mechanism.
- Lubricant can be applied to the forging material and heated before the upsetting process.
- the upsetting process can be omitted.
- Lubricant treatment may be water-soluble lubricant application or ponde treatment.
- preheated to 3800 ° C to 4800 ° C the deformation of the material is improved and it becomes easy to form a complex shape.
- a water-based lubricant is preferred as the lubricant, and a water-soluble graphite lubricant is more preferred. Good. This is because graphite is well baked on the material. In this case, for example, after applying a lubricant to a material at 70 ° C. to 35 ° C., after cooling the material to room temperature (for example, holding for 2 hours to 4 hours), It is preferable to heat to 480C to 480 ° C and put into a forging device.
- a water-based lubricant is preferable as the lubricant, and a water-soluble graphite lubricant is more preferably used. This is because black ⁇ sticks well to the material.
- the amount of lubricant can be adjusted to a more appropriate state according to the combination of the upper mold and the die by adjusting the spraying time. It is preferable to use an oil-based lubricant as the lubricant.
- an oil-based lubricant for example, mineral oil can be used. This is because water-based lubricants can lower the mold temperature, but this can be suppressed. It is more preferable that the oil-based lubricant is a mixture of graphite and mineral oil because the lubricating effect is enhanced.
- the heating temperature of the mold is preferably 1550 ° C to 2500 ° C. This is because sufficient plastic flow can be obtained.
- the processing rate of the portion requiring high temperature fatigue strength in forging is 90% or less (preferably 70% or less). Below this processing rate, the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product is suppressed, and a molded product having excellent high-temperature mechanical strength is obtained.
- the processing rate per processing is 10. /. It is preferable to set it to multiple times (preferably twice) at ⁇ 80% (more preferably from 10% to 50%).
- the first time is preferably 10% to 50% (more preferably 10% to 30%).
- Machining rate (Thickness before plastic working-Thickness after plastic working) / (Thickness before plastic working) X 1 00%
- Post-heat treatment is applied to the forged product.
- a solution treatment and an aging treatment can be used in combination.
- Post heat treatment can be done within one week after processing.
- the forged product can be subjected to a solution treatment, for example, under the condition of holding at 480 ° C to 520 ° C (preferably 490 ° C to 510 ° C) for 3 hours.
- forged products can be subjected to J IS standard T5 heat treatment or T6 heat treatment.
- the forged product taken out is not subjected to solution solution and quenching, but is maintained at 1 70 ° C to 230 ° C (preferably 190 ° C to 220 ° C) for 1 hour to 10 hours as an aging treatment. It is preferable. This is preferable because the crystallized product network, the acicular crystallized product, or the aggregate of crystallized product can be prevented from being divided and agglomerated, and the molded product has excellent high-temperature mechanical strength.
- the alloy structure of the molded product produced by such a method is difficult to progress in the aggregation and spheroidization of eutectic Si and intermetallic compounds, and the crystal structure or ⁇ " A crystallized product or an aggregate of crystallized products partially remains even after forging and post-heat treatment, resulting in an aluminum molded product having excellent high-temperature mechanical strength.
- the alloy composition is, S i of 1 0.5 wt% to 1 3.5% by weight (preferably 1 1.5 mass% to 1 3 mass 0/0), 2.5 wt% to 6 wt% (Preferably 3.5 wt% to 5.5 wt%) Cu, 0.3 wt% to 1.5 wt% (preferably 0.5 wt% to 1.3 wt%) Mg, 0.8 wt% to 4 wt 0/0 (preferably 1.8 mass 0 /. ⁇ 3.5 wt%) a N i of, and N i (mass.
- the alloy composition is 0.1 mass% to 1 mass% (preferably 0.2 mass% to 0.5 mass%) of Mn, 0.05 mass% to 0.5 mass% (preferably 0.1 mass%). % ⁇ 0. C r of 3 wt%), 0.04 wt ° / 0 ⁇ 0. Z r of 3 mass% (preferably 0.1% to 0.2 mass 0/0), 0.0 1 mass% to 0. 1 5 mass 0/0 (preferably 0.0 5 wt% to 0. 1 wt%) V of 0.01 mass% to 0. 2% by weight (preferably 0.02% to It is preferable to contain one or more of 0.1 mass% Ti.
- Fe 0.15 mass. / 0 to 0.6 5% by mass (preferably 0.3% to 0.5% by mass) / 0 is preferable.
- P is set to 0.003 mass ° / 0 to 0.02 mass% (preferably 0.007 mass ° / 0.
- 0.003 wt% to 0. 03 wt% (preferably 0.01 mass% to 0. 02 wt 0/0) S r of 0.1% to 0.35 mass 0/0 (preferably 0.1 5 wt% to 0. S b of 25 wt%), 0.0005 wt% to 0. 01 5 wt% (preferably 0.001 wt% to 0. 0 1 weight 0 /.) of Na, 0.00 1 wt% to 0. 02 mass 0/0 (preferably 0.005 wt% to 0. 01 wt%) may contain one or more of the C a of the eutectic There is an effect of miniaturizing Si, which is preferable.
- Example 1 370 50% Ding 6 10.5 0.25 2.7 One 0.95 3.8 ⁇ ⁇ 0.015 60 45 5.64
- Example 2 370 50% Ding 6 10.5 0.25 2.7 ⁇ 0.95 3.8 ⁇ 0.015 ⁇ 59 44 5.64
- Example 3 370 50% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 ⁇ 59 43 5.04
- Example 4 370 50% T5 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 One 62 44 5.04
- Example 5 370 50% T6 11.8 0.33 3.2 ⁇ 0.72 2.2 ⁇ 0.005 ⁇ 54 39 4.38
- Example 6 370 50% T6 12.8 0.25 3.8 ⁇ 0.95 1.8 ⁇ 0.018 ⁇ 53 38 4.38
- Example 7 370 50% T6 13.4 0.25 4.1 ⁇ 1.10 2.2 ⁇ 0.018 ⁇ 57 43 4.99
- Example 8 370 50% Ding 6 13.4 0.61 4.1 0.32 1.21 2.2 One 0.010
- the hot top continuous forging machine shown in FIG. 5 was used, and the comparisons shown in Examples 1 to 16 and Table 2 having the compositions shown in Table 1 were made.
- Examples 1 to 10 Aluminum alloy round bars of 85 mm (mm) were fabricated respectively.
- the above hot top continuous forging machine is a forging machine using the gas pressure hot top forging method, in which gas and lubricating oil are introduced into the clearance between the header and the mold, and the molten alloy supplied into the mold is made of The pressure and the lubricating oil and the gas from which the lubricating oil is vaporized are suitably balanced. With this configuration, the area where the molten aluminum comes into contact with the mold becomes narrow, so that the molten alloy can be rapidly cooled and solidified with cooling water, and an aluminum alloy continuous forged rod can be stably produced. '
- each continuous forged round bar was homogenized at the temperatures shown in Tables 1 and 2.
- Each continuous forged round bar was cut to a thickness of 20 mm or 8 O mm to obtain a forging material.
- the forging material was preheated to 4220 ° C., and then an upsetting process was performed at predetermined upsetting rates shown in Tables 1 and 2 to perform plastic processing into a predetermined shape.
- Example 5 to 7 and 10 to 13 the crack generation rate was evaluated when the upsetting rate was set to 55%.
- the evaluation results are shown in Table 3.
- Table 3 the ⁇ and ⁇ marks indicate that the cracking rate during the installation process was less than 1% and 1% or more, respectively.
- the plastic-processed product is water-quenched and held for 2 hours at 10 ° C.
- T5 heat treatment or the plastic-processed product is held at 500 ° C for 2.5 hours and then water-baked.
- the heat treatment was performed by either T 6 heat treatment, which was put in and held at 210 ° C for 6 hours.
- the fatigue strength was evaluated by the following method. Test pieces from each of the examples and comparative examples were manufactured by machining and pre-heated at 30.0 ° C or 350 ° C for 100 hours using an Ono-type rotary bending fatigue tester, then 300 ° C The fatigue strength of the specimen was evaluated in each environment at 350 ° C and 350 ° C. Stress that was not damaged was measured by applying 10 million cycles of stress.
- Examples 1 to 16 were all produced by the production method of the present invention and, as can be seen from Table 1, have a fatigue strength of 33 MPa or more at 350 ° C. Thus, since Examples 1 to 16 manufactured by the manufacturing method of the present invention all have a target fatigue strength, they are preferably used for parts that require mechanical strength at high temperatures. be able to.
- the aluminum alloy used in the production method of the present invention must have a composition in which the Ni and Cu contents are included in the region surrounded by A—B—C and D—E—A in FIG. Let's say.
- Comparative Examples 1 to 5 and 7 to 10 having compositions outside the range of the alloy composition defined in the manufacturing method of the present invention are all targeted fatigue strengths as shown in Table 2. Did not have. Comparative Examples 8 and 10 were further inferior in plastic workability, and cracks occurred during upsetting. The “* 1” displayed in Table 2 indicates that the comparative test specimen could not be collected. In addition, the A A value of Comparative Examples 1 to 4 was less than 4.2. Further, Comparative Example 6 in which the pre-heat treatment step was performed at a temperature outside the temperature range defined in the production method of the present invention did not have the target fatigue strength.
- Example metallographic structures were evaluated.
- the area occupancy of the eutectic S i is 8% or more, the average grain size of the eutectic S i is 5 ⁇ m or less, and the eutectic S i needle ratio is 2.4 or more.
- % Of the intermetallic compound is 1.2% or more, the average particle size of the intermetallic compound is 1.5 ⁇ m or more, the length of the intermetallic compound or the aggregate of the intermetallic compounds in contact Those with a length of 3 ⁇ m or more were 30% or more.
- the average particle diameter of the eutectic Si is 2.5 ⁇ or less. It can be seen that about 80% of the eutectic Si needle-like ratio is 1.4 or more, and about 90% of the intermetallic compound aggregate length is 3 ⁇ or more.
- Example 3 has a larger amount of network-like or acicular intermetallic compounds that contribute to high-temperature strength compared to Example 10 where the constant ⁇ ⁇ is less than 4.7, and the fatigue strength is higher than Example 10. I understand that.
- an aluminum alloy molded article prepared so that the constant ⁇ is 4.7 or more is preferable.
- Comparative Example 6 has only about 22% of eutectic Si needle-like ratios of 1 and 4 or more, and the length of the intermetallic compound or the intermetallic compound in contact with it. Only about 28% of the aggregates were 3 xm or longer.
- Example 10 8.6% 2.4 m 78% 7.4% 2.6 m 88%
- Example 13 8.5% 2.5 jWm 80% 7.8% 2.7 jU 89% Comparative Example 6 8.5% 2.0 m 22% 7.2 % 1.9 im 28%
- Examples 17 and 18 and Comparative Examples 1 1 and 12 were respectively produced in the same manner as in Examples 1 to 16 and Comparative Examples 1 to 10 with the compositions and production conditions shown in Table 5.
- Manufactured. Comparative Examples 1 and 3 were formed from powdered extruded forged material, except that they were not formed from an aluminum alloy continuous forged round bar and were not homogenized. It was manufactured by the same manufacturing method.
- Examples 1 7 and 1 8 and Comparative Examples 1 1 to 1 3 are all screws having a crown surface of 1 ° having a diameter of 8 O mm and a thickness of 8 mm as shown in FIGS. 7 (a) to (c). It was formed as an aluminum alloy molded product having the shape of Ton 1.
- Examples 17 and 18 fatigue strength at 3500 ° C is preferred for parts that require mechanical strength at high temperatures. Furthermore, the fatigue strength at 300 ° C exceeds 55 MPa. In addition, Examples 17 and 18 correspond to Examples 10 and 13 in which the same manufacturing conditions are used except for the shape. Stable mechanical strength at high temperatures is used regardless of the evaluation method. Have Homogenization Aluminum alloy composition (mass. / 0 ) Fatigue strength stress
- Comparative Example 11 corresponds to Comparative Example 2 in which the AA value is less than 4.2 and the same manufacturing conditions except for the shape are used. From the fatigue strength evaluation results of Comparative Example 2 in Table 2 and Comparative Example 11 in Table 5, Comparative Example 11 is considered to lack the reliability of mechanical strength at high temperatures.
- the fine part for example, the skirt part 12 tends to become brittle.
- the molded product using the powder extruded material is compared with the aluminum alloy molded product having a forging process using a continuous forged rod made of an aluminum alloy as a material. Ductility and toughness are inferior.
- the aluminum alloy molded article produced by the production method of the present invention is excellent in ductility, toughness and fatigue strength, and can be suitably used for a crown surface portion of an internal combustion engine biston. Industrial applicability
- the present invention is a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, wherein the aluminum alloy is Si, Cu, Since it contains Mg and Ni, according to the present invention, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness. Also, and the N i and C u, N i (mass 0/0) ⁇ [one 0. 6 8 XC u (mass 0/0) + 4.2 (wt%)] Since satisfying the relational expression, The fatigue strength characteristics at higher temperatures can be improved.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Forging (AREA)
- Continuous Casting (AREA)
Abstract
Description
明 細 書 アルミ -ゥム合金成形品の製造方法、 アルミユウム合金成形品及び生産シス テム 技術分野 Description Aluminum-um alloy molded product manufacturing method, aluminum alloy molded product and production system Technical Field
本発明は、 アルミニウム合金からなる連続铸造棒を素材として用いた鍛造成 形工程を有するアルミニウム合金成形品の製造方法、 アルミニウム合金成形品及 ぴその生産システムに関する。 背景技術 The present invention relates to a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, an aluminum alloy molded article, and a production system thereof. Background art
近年、 四輪、 二輪自動車等の車両 (以下、 単に 「自動車」 と言う。) では、 高 性能化の為、 又、 環境問題に対応する為、 内燃機関ピス トンにアルミニウム鍛造 製のものの採用が検討されてきている。 ビストンなどの内燃機関の駆動部品を軽 量化することができ、 内燃機関を運転した時の負荷の低減、 出力向上、 燃費低減 が図られるからである。 アルミニウム合金製の内燃機関ピス トンには、 従来から 铸造品が多く採用されているが、 铸造品では铸造時に発生する内部欠陥を抑える ことが困難であり、 強度を安全設計する為に余肉を設ける必要があり、 軽量化が 困難であった。 In recent years, automobiles such as automobiles and motorcycles (hereinafter simply referred to as “automobiles”) have adopted the use of forged aluminum for internal combustion engine pistons in order to improve performance and respond to environmental problems. It has been studied. This is because the driving parts of the internal combustion engine, such as Biston, can be reduced, and the load when the internal combustion engine is operated can be reduced, the output can be improved, and the fuel consumption can be reduced. Forged internal combustion engine pistons made of aluminum alloy have been widely used forged products. However, it is difficult to control internal defects that occur during forged products, and there is a surplus in order to safely design strength. It was necessary to install it, and it was difficult to reduce the weight.
そこで、 内部欠陥の発生を抑えることのできるアルミニウム合金鍛造品によ るビス トンの軽量化が検討されてきた。 Therefore, the weight reduction of the biston using aluminum alloy forgings that can suppress the occurrence of internal defects has been studied.
従来のアルミニウム合金鍛造用素材の製造方法は、 通常の溶湯製法にてアル ミニゥム合金溶湯を調製する工程と、 続いてこのアルミ二ゥム合金溶湯を連続铸 造法、半連続铸造法(D C鑤造法)、 ホットトップ铸造法等のいわゆる連続铸造法 の内、何れかの方法によって铸造し、アルミニウム合金の鑤塊を製造する工程と、 その後、 この铸塊に均質化熱処理を施してアルミニウム合金結晶の均質化を行な う工程とからなつていた。 そして、 アルミニウム合金鍛造用素材 (铸塊) に鍛造 を施し、 更に、 J I S (日本工業規格) の T 6熱処理を施すことにより、 アルミ ニゥム合金鍛造成形品が製造されることとなる。 A conventional method for producing a material for forging an aluminum alloy includes a step of preparing a molten aluminum alloy by a normal molten metal manufacturing method, followed by a continuous forging method, a semi-continuous forging method (DC Manufacturing method), forging by any one of so-called continuous forging methods such as hot top forging method, and the like, and producing a lump of aluminum alloy, After that, the mass was subjected to a homogenization heat treatment to homogenize the aluminum alloy crystals. Then, forging is performed on the aluminum alloy forging material (ingot), and further, JIS (Japanese Industrial Standards) T 6 heat treatment is performed, so that an aluminum / nium alloy forged molded product is manufactured.
尚、 6000系合金に関するもので、 均質化熱処理の温度を抑制したり省略 したりしているものが、 特開 2002— 294383号公報 (特許文献 1 ) に開 示されている。 Incidentally, the one relating to the 6000 series alloy, in which the temperature of the homogenization heat treatment is suppressed or omitted, is disclosed in JP-A-2002-294383 (Patent Document 1).
しかし、 特許文献 1においては、 高温時の機械的特性についての検討がなさ れていない。 However, Patent Document 1 does not discuss the mechanical characteristics at high temperatures.
一方、 従来のアルミニウム鍛造よりも高温での機械的強度の優れたアルミ二 ゥム合金成形品を製造できるようにすることを目的とした下記の特開 200 5- 29054 5号公報 (特許文献 2) には、 アルミニウム合金からなる連続铸造棒 を素材として用いた鍛造成形工程を有するアルミニウム合金成形品の製造方法で あり、 アルミェゥム合金が、 10. 5質量%〜1 3. 5質量0 /。の S i、 0. 1 5 質量%〜0. 6 5質量%の? 6、 2. 5質量%〜5. 5質量%の。 11及び0. 3 質量。/。〜 1. 5質量%の Mgを含み、 素材に対する前熱処理工程、 素材に対する 鍛造加工時加熱工程、 アルミニゥム合金成形品に対する後熱処理工程からなる熱 処理■加熱工程を含み、 前熱処理工程が一 1 0°C〜480°Cで 2時間〜 6時間保 持する処理を含む製造方法が開示されている。 On the other hand, the following Japanese Patent Application Laid-Open Publication No. 2005-29054 5 (Patent Document 2) is aimed at making it possible to produce an aluminum alloy molded article having excellent mechanical strength at a higher temperature than conventional aluminum forging. ) Is a method for producing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, and the aluminum alloy has a content of 10.5 mass% to 13.5 mass 0 /. Si, 0.15 mass% to 0.6 5 mass%? 6, 2.5% to 5.5% by mass. 11 and 0.3 mass. /. 〜1.5 Containing 5% by mass of Mg, heat treatment consisting of pre-heat treatment process for raw material, heating process for forging process for raw material, post-heat treatment process for aluminum alloy molded product ■ Pre-heat treatment process including heating process A manufacturing method is disclosed which includes a treatment of holding at 2 ° C to 6 hours at ° C to 480 ° C.
ところで、 近年さらなる内燃機関の効率向上や出力の向上が求められ、 その 結果、 そこに用いられる部品にはより高温での機械的強度が求められるようにな つてきた。 By the way, in recent years, further improvements in efficiency and output of internal combustion engines have been demanded, and as a result, the mechanical strength at higher temperatures has been demanded for the components used there.
したがって、 より軽量化を狙えるアルミニウム合金鍛造品において、 従来の アルミニウム合金鍛造品より、 更に高温時の機械的強度 (例えば、 350°Cにお ける疲労強度) を向上させたアルミニウム合金成形品の製造方法が求められてい る。 Therefore, for aluminum alloy forgings that aim to reduce weight, manufacture of aluminum alloy moldings with improved mechanical strength at higher temperatures (for example, fatigue strength at 350 ° C) than conventional aluminum alloy forgings. A method is sought The
本発明は、上記に鑑みてなされたもので、従来のアルミニウム合金鍛造より、 更に高温での機械的強度の優れたアルミニウム合金成形品の製造方法、 アルミ- ゥム合金成形品及び生産システムを提供することを目的とする。 発明の開示 The present invention has been made in view of the above, and provides a method for manufacturing an aluminum alloy molded article, an aluminum alloy molded article, and a production system that are superior in mechanical strength at higher temperatures than conventional aluminum alloy forging. The purpose is to do. Disclosure of the invention
(1) 上記目的を達成するために、 本発明の第 1の発明は、 アルミニウム合金 からなる連続錄造棒を素材として用いた鍛造成形工程を有するアルミニゥム合金 成形品の製造方法において、 アルミニウム合金が、 10. 5質量%〜1 3. 5質 量%の S i、 2. 5質量%〜6質量%の Cu、 0. 3質量0/。〜 1. 5質量%の M g及び 0. 8質量%〜4質量%の N iを含み、 かつ N i (質量%) ≥ 〔― 0. 6 8 XC u (質量%) +4. 2 (質量%)〕 なる関係式を満足し、 素材に対する前熱 処理工程、 素材に対する鍛造加工前予備加熱工程、 アルミニウム合金成形品に対 する後熱処理工程からなる熱処理■加熱工程を含み、 前熱処理工程が一 10°C〜 480°Cに 2時間〜 6時間保持する処理を含む、 ことを特徴とする。 (1) In order to achieve the above object, according to a first aspect of the present invention, there is provided a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a material. 10.5 mass% to 13.5 mass% Si, 2.5 mass% to 6 mass% Cu, 0.3 mass 0 /. ~ 1.5 wt% Mg and 0.8 wt% to 4 wt% Ni, and Ni (wt%) ≥ [-0.6 8 XCu (wt%) +4.2 ( (Mass%)) satisfying the following relational expression, a heat treatment comprising a preheating process for the material, a preheating process for the material before forging, and a post-heat treatment process for the aluminum alloy molded product. (1) It includes a treatment of holding at 10 ° C. to 480 ° C. for 2 hours to 6 hours.
(2) 本発明の第 2の発明は、 上記第 1発明のアルミ-ゥム合金成形品の製造 方法において、 前熱処理工程の熱処理温度が 200°C〜370°Cである、 ことを 特徴とする。 (2) The second invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article according to the first invention, the heat treatment temperature in the pre-heat treatment step is 200 ° C to 370 ° C. To do.
(3) 本発明の第 3の発明は、 上記第 1発明のアルミニウム合金成形品の製造 方法において、 前熱処理工程の熱処理温度が一 10°C〜200°Cである、 ことを 特徴とする。 (3) The third invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article according to the first invention, the heat treatment temperature in the pre-heat treatment step is 110 ° C. to 200 ° C.
(4) 本発明の第 4の発明は、 上記第 1発明のアルミニウム合金成形品の製造 方法において、 前熱処理工程の熱処理温度が 370°C〜480°Cである、 ことを 特徴とする。 (4) A fourth invention of the present invention is characterized in that, in the method for producing an aluminum alloy molded article of the first invention, the heat treatment temperature in the pre-heat treatment step is 370 ° C. to 480 ° C.
(5) 本発明の第 5の発明は、 上記第 1発明乃至第 4発明のアルミニウム合金 成形品の製造方法において、後熱処理工程が、溶体化処理を施すことなく 1 70°C 〜 230 °Cに 1時間〜 10時間保持する、 ことを特徴とする。 (5) The fifth invention of the present invention is the aluminum alloy of the first to fourth inventions described above. In the method for producing a molded article, the post-heat treatment step is maintained at 170 ° C. to 230 ° C. for 1 hour to 10 hours without performing a solution treatment.
(6) 本発明の第 6の発明は、 上記第 1発明乃至第 5発明のアルミニウム合金 成形品の製造方法において、アルミニウム合金が 0. 15質量%〜0. 65質量% の F eを含む、 ことを特徴とする。 (6) According to a sixth invention of the present invention, in the method for producing an aluminum alloy molded article according to any one of the first to fifth inventions, the aluminum alloy contains 0.15% by mass to 0.65% by mass of Fe, It is characterized by that.
(7) 本発明の第 7の発明は、 上記第 1発明乃至第 6発明のアルミニウム合金 成形品の製造方法において、 アルミニウム合金が 0. 003質量%〜0. 02質 量%の Pを含む、 ことを特徴とする。 (7) A seventh invention of the present invention is the method for producing an aluminum alloy molded article according to the first to sixth inventions, wherein the aluminum alloy contains 0.003 mass% to 0.02 mass% of P. It is characterized by that.
(8) 本発明の第 8の発明は、 上記第 1発明乃至第 7発明のアルミニウム合金 成形品の製造方法において、 アルミニウム合金が、 0. 003質量%〜0. 03 質量0/。の S r、 0. 1質量%〜0. 35質量%の313、 0. 0005質量0/。〜 0. 015質量%のNa、 0. 001質量%〜0. 02質量%の C aの何れか 1種又 は 2種以上の組み合わせを含む、 ことを特徴とする。 (8) The eighth invention of the present invention is the method for producing an aluminum alloy molded article according to the first to seventh inventions, wherein the aluminum alloy is 0.003 mass% to 0.03 mass 0 /. Sr, 0.1 mass% to 0.35 mass% 313, 0.0005 mass 0 /. It is characterized by containing any one kind or a combination of two or more kinds of ˜0.015 mass% Na and 0.001 mass% ˜0.02 mass% Ca.
(9) 本発明の第 9の発明は、 上記第 1発明乃至第 8発明のアルミニウム合金 成形品の製造方法において、 アルミニウム合金が、 0. 1質量%〜1. 0質量0 /0 の Mn、 0. 05質量%〜0. 5質量%の〇 1:、 0. 04質量%〜0. 3質量0 /0 の Z r、 0. 01質量%〜0. 1 5質量%の V、 0. 01質量%〜0. 2質量0 /0 の T iの何れか 1種又は 2種以上の組み合わせを含む、 ことを特徴とする。 (9) Ninth aspect of the present invention is the manufacturing method of an aluminum alloy molded product of the first invention to eighth invention, the aluminum alloy, 0.1 wt% to 1. 0 mass 0/0 of Mn, 0.05 wt% to 0. 5 wt% of 〇 1 :, 0.04 wt% to 0. 3 mass 0/0 Z r, 0. 01 wt% to 0. 1 5 wt% of V, 0. 01 wt% to 0. including any one or more combinations of a 2 wt 0/0 T i, characterized in that.
(10) 本発明の第 10の発明は、 上記第 1発明乃至第 9発明のアルミニウム 合金成形品の製造方法において、 鍛造成形工程における、 耐高温疲労強度の要求 される部位の加工率が 90%以下である、 ことを特徴とする。 (10) According to a tenth aspect of the present invention, in the method for producing an aluminum alloy molded article according to any one of the first to ninth aspects, the processing rate of a portion requiring high temperature fatigue strength in the forging step is 90%. It is the following, It is characterized by the above-mentioned.
(1 1) 本発明の第 1 1の発明は、 上記第 1発明乃至第 10発明のアルミニゥ ム合金成形品の製造方法において、 鍛造成形工程における、 加工前予備加熱温度 が 380°C〜480°Cである、 ことを特徴とする。 (1 1) The first invention of the present invention is the method for producing an aluminum alloy molded article according to the first invention to the tenth invention, wherein the preheating temperature before processing in the forging process is 380 ° C. to 480 ° It is C.
(12) 本発明の第 1 2の発明は、 上記第 1発明乃至第 1 1発明のアルミニゥ ム合金成形品の製造方法において、 連続錄造棒は、 溶湯の平均温度が液相線 +4 0°C〜+ 230°Cのアルミニウム合金を、 鎵造速度を 80 (mm/m i n) 〜2 000 (mm/m i n) にして連続铸造法により铸造して得られたものである、 ことを特徴とする。 (12) The first invention of the present invention is the aluminum of the first invention to the first invention. In the method of manufacturing a molded alloy product, a continuous forging rod is made of an aluminum alloy with an average molten metal temperature of liquidus + 40 ° C to + 230 ° C, and a forging speed of 80 (mm / min) to 2 It is obtained by forging by a continuous forging method at 000 (mm / min).
(1 3) 本発明の第 1 3の発明は、 上記第 1発明乃至第 1 2発明のアルミニゥ ム合金成形品の製造方法のうち、 何れか 1つの製造方法で製造されたアルミニゥ ム合金成形品であって、 組織において連続鍀造時に形成された晶出物のネットヮ ーク組織又は針状晶出物又は晶出物の集合体が成形 ·熱処理後にも部分的に残留 する、 ことを特徴とする。 (1 3) The first invention of the present invention is an aluminum alloy molded product manufactured by any one of the above-described methods for manufacturing an aluminum alloy molded product of the first to first inventions. A network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed at the time of continuous fabrication in the structure partially remain after molding and heat treatment. To do.
(14) 本発明の第 14の発明は、 上記第 1発明乃至第 1 2発明のアルミユウ ム合金成形品の製造方法のうち、 何れか 1つの製造方法で製造されたアルミニゥ ム合金成形品であって、 共晶 S iの面積占有率が 8%以上、 共晶 S iの平均粒径 が 5 μπι以下、 共晶 S i針状比 1. 4以上のものが 25%以上、 金属間化合物の 面積占有率が 1. 2%以上、 金属間化合物の平均粒径が 1. 5 m以上、 金属間 化合物の長さ又は接触する金属間化合物の集合体の長さが 3 /im以上のものが 3 0%以上である、 ことを特徴とする。 (14) A fourteenth aspect of the present invention is an aluminum alloy molded article produced by any one of the above-described methods for producing an aluminum alloy molded article of the first to the first inventions. Eutectic S i area occupancy is 8% or more, eutectic S i average particle size is 5 μπι or less, eutectic S i needle ratio 1. The area occupation ratio is 1.2% or more, the average particle size of the intermetallic compound is 1.5 m or more, the length of the intermetallic compound or the length of the aggregate of the intermetallic compounds in contact is 3 / im or more. 30% or more.
(1 5) 本発明の第 1 5の発明は、 冠面部位、 スカート部を有するアルミニゥ ム合金製エンジンビストンとして成形された第 1 3発明若しくは第 14発明のァ ルミ-ゥム合金成形品であって、 前記冠面部位の高温疲労強度が 5 OMP a以上 である、 ことを特徴とする。 (15) The 15th invention of the present invention is the aluminum alloy molded product of the 13th invention or the 14th invention formed as an engine alloy made of aluminum alloy having a crown surface portion and a skirt portion. The high-temperature fatigue strength of the crown surface portion is 5 OMPa or more.
(1 6) 本発明の第 1 6の発明は、 溶湯からアルミニウム合金成形品までの一 連の工程を連続ラインとして構築した生産システムであって、 上記第 1発明乃至 第 1 2発明のアルミニウム合金成形品の製造方法のうち、 何れか 1つの製造方法 による工程を含む、 ことを特徴とする。 (16) The sixteenth invention of the present invention is a production system in which a series of processes from a molten metal to an aluminum alloy molded product is constructed as a continuous line, wherein the aluminum alloy of the first invention to the first invention is used. The method includes any one of the manufacturing methods of the molded product.
(1) に記載の第 1発明によれば、 アルミニウム合金が S i、 C u、 Mg及び N iを含んでいるので、 高温疲労強度と鍛造性、 延性、 靱性が良好な成形品を得 ることができる。 又、 N i及びCuの組成が、 N i (質量0 /0) ≥ 〔一 0. 68 X Cu (質量%) +4. 2 (質量%)〕 なる関係式を満足するので、 より高温での疲 労強度特性が向上する。 According to the first invention described in (1), the aluminum alloy is made of Si, Cu, Mg and Since Ni is contained, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness. Further, the composition of the N i and Cu, N i (mass 0/0) ≥ [one 0. 68 X Cu (mass%) +4. 2 (wt%)] Since satisfying the relational expression, at higher temperatures The fatigue strength characteristics of the steel are improved.
尚、 従来は合金組成を変化させて多水準の合金から.成形品を試作せねばなら ず、 又、 高温疲労強度の評価も複雑な設備と多くの時間を必要とする評価であつ た為、 特に高温での疲労強度を有する合金設計は困難であった。 Conventionally, it has been necessary to make a prototype of a molded product from various levels of alloy by changing the alloy composition, and because the evaluation of high temperature fatigue strength requires complicated equipment and a lot of time, In particular, it has been difficult to design an alloy having fatigue strength at high temperatures.
し力、し、 本発明の上記関係式を指標として用いて合金組成を設計することに より、 更なる高温での疲労強度特性を有する合金を容易に得ることができ、 又、 350°Cより高温時であっても優れた機械的強度を有するアルミニウム合金成形 品を得ることができる。 By designing the alloy composition using the above relational expression of the present invention as an index, it is possible to easily obtain an alloy having fatigue strength characteristics at a higher temperature, and from 350 ° C. An aluminum alloy molded product having excellent mechanical strength can be obtained even at high temperatures.
より具体的には、 例えば、 350°C、 100時間保持後の 350°Cでの疲労 強度が 33MP a以上となる。 これらの特性は、 例えば、 高温雰囲気に接する内 燃機関ピストンの冠面部位に求められる特性である。 従って、 本発明のアルミ二 ゥム合金成形品を用いることにより、 従来の内燃機関ピストンよりも薄肉化する ことができ、 内燃機関ピストンの軽量化が可能になる。 そして、 市場から求めら れている軽量化に答えることができ、 内燃機関の燃費低減、 出力向上が実現する ことができる。 More specifically, for example, the fatigue strength at 350 ° C after holding at 350 ° C for 100 hours is 33 MPa or more. These characteristics are, for example, characteristics required for the crown portion of the internal combustion engine piston that is in contact with a high-temperature atmosphere. Therefore, by using the aluminum alloy molded article of the present invention, it is possible to make the wall thinner than the conventional internal combustion engine piston, and it is possible to reduce the weight of the internal combustion engine piston. In addition, it is possible to answer the weight reduction demanded by the market, and to realize a reduction in fuel consumption and an increase in output of the internal combustion engine.
(2) に記載の第 2発明によれば、 前熱処理工程の熱処理温度を 200°C〜 3 70°Cにしたので、 高温疲労強度と鍛造性、 延性、 靱性がより兼合ったものとな り、 より良好な成形品を得ることができる。 According to the second invention described in (2), since the heat treatment temperature in the pre-heat treatment step is set to 200 ° C to 370 ° C, the high temperature fatigue strength and forgeability, ductility, and toughness are more balanced. Thus, a better molded product can be obtained.
(3) に記載の第 3発明によれば、 前熱処理工程の熱処理温度を一 10°C〜 2 0 o°cにしたので、高温疲労強度がより良好な成形品を得ることができる。但し、 鍛造性、 延性、 靭性は熱処理温度が 200 °C〜 370 °Cのものよりも低下する。 According to the third invention described in (3), since the heat treatment temperature in the pre-heat treatment step is set to 10 ° C. to 20 ° C., a molded article with better high-temperature fatigue strength can be obtained. However, the forgeability, ductility and toughness are lower than those with heat treatment temperatures of 200 ° C to 370 ° C.
(4) に記載の第 4発明によれば、 前熱処理工程の熱処理温度を 370°C〜 4 80°Cにしたので、鍛造性、延性、靭性が更に良好な成形品を得ることができる。 但し、 高温疲労強度は熱処理温度が 200°C〜3 70°Cのものよりも低下する。 According to the fourth invention described in (4), the heat treatment temperature in the pre-heat treatment step is 370 ° C to 4 ° C. Since the temperature is set to 80 ° C., it is possible to obtain a molded product having better forgeability, ductility, and toughness. However, the high-temperature fatigue strength is lower than that at a heat treatment temperature of 200 ° C to 370 ° C.
(5) に記載の第 5発明によれば、 後熱処理工程で、 溶体化処理を施すことな く 1 70 °C〜 230 °Cに 1時間〜 10時間保持するので、 高温疲労強度がより良 好な成形品を得ることができる。 但し、 延性、 靭性は、 溶体化処理を施し、 1 7 0°C〜2 30°Cに 1時間〜 1 0時間保持したものよりも低下する。 According to the fifth invention described in (5), the high temperature fatigue strength is better because it is maintained at 170 ° C to 230 ° C for 1 hour to 10 hours without performing solution treatment in the post heat treatment step. A favorable molded product can be obtained. However, the ductility and toughness are lower than those obtained after solution treatment and maintained at 170 to 230 ° C for 1 to 10 hours.
(6) に記載の第 6発明によれば、 アルミニウム合金が 0. 1 5質量%〜0. 65質量%の eを含むので、 A 1— F e系や A 1—F e— S i系や A 1— N i _F e系の粒子を晶出させ、 高温機械的強度を向上させる。 そして、 0. 1 5質 量%〜0. 65質量%の F eの含有量は、 粗大な晶出物の増加を抑え、 鍛造性、 高温疲労強度、 靱性を向上させる。 According to the sixth invention described in (6), since the aluminum alloy contains 0.15 mass% to 0.65 mass% of e, the A 1—F e system and the A 1—F e—Si system And A 1—N i _F e particles are crystallized to improve high-temperature mechanical strength. The Fe content of 0.15 mass% to 0.65 mass% suppresses an increase in coarse crystals, and improves forgeability, high temperature fatigue strength, and toughness.
(7)に記載の第 7発明によれば、アルミユウム合金が 0. 003質量%〜0. 02質量%の Pを含むので、 Pは初晶 S iを発生させ、 耐摩耗性を優先する場合 に好ましく、 又、 Pは初晶 S iの微細化効果があり、 発生した初晶 S iによる鍛 造性や延性や高温疲労強度の低下を抑制する働きをする。 そして、 0. 003質 量%〜0. 02質量%の卩の含有量は、 粗大な初晶 S iの増加を抑え、 鍛造性、 高温疲労強度、 靱性を向上させる。 According to the seventh invention described in (7), since the aluminum alloy contains 0.003 mass% to 0.02 mass% of P, P generates primary crystal Si and gives priority to wear resistance. Further, P has an effect of refining the primary crystal Si, and functions to suppress a decrease in forgeability, ductility and high temperature fatigue strength due to the generated primary crystal Si. And the content of 0.03 mass% to 0.02 mass% of soot suppresses the increase of coarse primary crystals Si, and improves forgeability, high temperature fatigue strength, and toughness.
(8) に記載の第 8発明によれば、 アルミニウム合金が、 0. 003質量0/。〜 0. 03質量%の3 ]:、 0. 1質量%〜0. 35質量%の315、 0. 0005質 量%~0. 01 5質量%のN a、 0. 00 1質量%~0. 02質量%の。 &の何 れか 1種又は 2種以上の組み合わせを含むので、 初晶 S iの発生を抑制でき、 鍛 造性、 延性、 靭性を優先する場合に好ましい。 そして、 この範囲の S r、 S b、 Na、 C aの含有量は、 初晶 S iの発生を抑え、 鍛造性、 靱性、 高温疲労強度を 向上させる。 According to the eighth invention described in (8), the aluminum alloy is 0.003 mass 0 /. ~ 0.03 mass% 3]: 0.1 mass% ~ 0.35 mass% 315, 0.005 mass% ~ 0.01 5 mass% Na, 0.00 1 mass% ~ 0 02% by mass. Since one or a combination of two or more of & is included, the generation of primary crystals Si can be suppressed, which is preferable when forgeability, ductility, and toughness are prioritized. And the contents of Sr, Sb, Na, and Ca in this range suppress the generation of primary crystals Si and improve forgeability, toughness, and high-temperature fatigue strength.
(9) に記載の第 9発明によれば、 アルミェゥム合金が、 0. 1質量%〜1. 0質量%の1\111、 0. 05質量%〜0. 5質量%の〇 ]:、 0. 04質量%〜0. 3質量%の Z r、 0. 0 1質量%~0. 1 5質量%の V、 0. 0 1質量%〜0. 2質量%の T iの何れか 1種又ほ 2種以上の組み合わせを含むので、 A 1— Mn 系や A 1— F e -Mn - S i系、 A 1 —C r系や A 1 — F e— C r— S i系、 A 1— Z r系、 k \ H A 1—T i系の化合物が晶出又は析出し、 アルミ-ゥ ム合金の高温機械的強度を向上させる。 そして、 この範囲の Mn、 C r、 Z r、 V、 T iの含有量は、 粗大な晶出物の増加を抑え、 鍛造性、 高温疲労強度、 靱性 を向上させる。 According to the ninth invention described in (9), the aluminum alloy is 0.1 mass% to 1. 0% by mass 1 \ 111, 0.05% by mass to 0.5% by mass ○]: 0.04% by mass to 0.3% by mass Zr, 0.0 1% by mass to 0.15% Since it includes one or more combinations of V 1% by mass, 0.0 1% by mass to 0.2% by mass Ti, or A 1— Mn system or A 1— F e -Mn- S i, A 1 —C r, A 1 —F e— C r—S i, A 1—Z r, k \ HA 1—T i compounds are crystallized or precipitated. Improves the high temperature mechanical strength of rum alloys. And the contents of Mn, Cr, Zr, V and Ti in this range suppress the increase of coarse crystals and improve forgeability, high temperature fatigue strength and toughness.
(1 0) に記載の第 1 0発明によれば、 鍛造成形工程における、 耐高温疲労強 度の要求される部位の加工率を 90%以下にしたので、 晶出物のネットワーク組 織や針状組織や集合体を、 適度に分断し、 適度に残る為、 延性、 靭性と高温疲労 強度が良好な成形品を得ることができる。 According to the tenth aspect of the invention described in (10), since the processing rate of the portion requiring high-temperature fatigue resistance in the forging process is reduced to 90% or less, the network structure or needle of the crystallized product Since the texture and aggregates are appropriately divided and remain moderately, a molded product having good ductility, toughness and high-temperature fatigue strength can be obtained.
(1 1) に記載の第 1 1発明によれば、 鍛造成形工程における、 加工前予備加 熱温度を 3 80°C〜480°Cにしたので、 高温疲労強度と鍛造性、 延性、 靱性が 良好な成形品を得ることができる。 (1 1) According to the first invention described in (1 1), since the preheating temperature before processing in the forging process is set to 380 ° C to 480 ° C, high temperature fatigue strength, forgeability, ductility, and toughness are achieved. A good molded product can be obtained.
(1 2) に記載の第 1 2発明によれば、 溶湯の平均温度が液相線 +40°C〜 + 230°Cのアルミニウム合金を、铸造速度を 80 (mm/m i n)〜2000 (m m/m i n) にして連続铸造法により铸造して連続铸造棒を得たので、 均一で微 細な晶出物のネットワーク組織や針状組織や集合体が得られると共に、 高温疲労 強度と鍛造性、 延性、 靱性が良好な成形品を得ることができる。 According to the first and second inventions described in (1 2), the average temperature of the molten metal is a liquidus + 40 ° C to + 230 ° C, and the forging speed is 80 (mm / min) to 2000 (mm / min) and forging by a continuous forging method to obtain a continuous forging rod, a uniform and fine crystallized network structure, needle-like structure and aggregate are obtained, and high-temperature fatigue strength and forgeability, A molded product with good ductility and toughness can be obtained.
(1 3) に記載の第 1 3発明によれば、 組織において連続铸造時に形成された 晶出物のネットワーク組織又は針状晶出物又は晶出物の集合体が成形 ·熱処理後 にも部分的に残留しているので、 高温疲労強度と鍛造性、 延性、 靱性の良好な成 形品を得ることができる。 According to the first and third inventions described in (1 3), the network structure of the crystallized product or the acicular crystallized product or the aggregate of crystallized product formed during continuous forging in the structure is partly formed after molding and heat treatment. Therefore, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness.
(14) に記載の第 14発明によれば、 共晶 S iの面積占有率が 8%以上、 共 晶 S iの平均粒径が 5 μ m以下、共晶 S i針状比 1 . 4以上のものが 2 5 %以上、 金属間化合物の面積占有率が 1 . 2 %以上、 金属間化合物の平均粒径が 1 . 5 μ m以上、 金属間化合物の長さ又は接触する金属間化合物の集合体の長さが 3 / m 以上のものが 3 0 %以上であるので、 高温疲労強度と鍛造性、 延性、 靱性の良好 な成形品をより確実に得ることができる。 According to the fourteenth invention described in (14), the area occupancy of the eutectic Si is 8% or more, The average particle size of crystal Si is 5 μm or less, the eutectic Si needle shape ratio is 1.4 or more, 25% or more, the area occupation ratio of intermetallic compounds is 1.2% or more, The average particle size is 1.5 μm or more, the length of intermetallic compounds or the length of the aggregate of intermetallic compounds in contact is 3 / m or more is 30% or more. It is possible to more reliably obtain a molded article having good properties, ductility, and toughness.
( 1 5 ) に記載の第 1 5発明によれば、 冠面部位の高温疲労強度が 5 O M P a 以上であるので、 十分な高温疲労強度を有しており、 内燃機関ピス トンの冠面部 位等に好適に使用することができる。 According to the fifteenth aspect of the invention described in (15), since the high temperature fatigue strength of the crown surface portion is 5 OMPa or more, the crown surface portion of the internal combustion engine piston has a sufficient high temperature fatigue strength. Etc. can be used suitably.
( 1 6 ) に記載の第 1 6発明によれば、 溶湯からアルミニウム合金成形品まで の一連の工程を連続ラインとして構築し、 少なくともその工程に、 上記した何れ か 1つのアルミニウム合金成形品の製造方法による工程を含むので、 より高温で の疲労強度特性が向上する。 According to the sixteenth aspect of the invention described in (16), a series of processes from the molten metal to the aluminum alloy molded product is constructed as a continuous line, and at least the process includes the production of any one of the aluminum alloy molded products described above. Since the method includes a process, fatigue strength characteristics at higher temperatures are improved.
尚、 従来は合金組成を変化させて多水準の合金から成形品を試作せねばなら ず、 又、 高温疲労強度の評価も複雑な設備と多くの時間を必要とする評価であつ た為、 特に高温での疲労強度を有する合金設計は困難であった。 In the past, it was necessary to make a prototype of a molded product from a multi-level alloy by changing the alloy composition, and the evaluation of high temperature fatigue strength was also an evaluation requiring complicated equipment and a lot of time. Designing alloys with fatigue strength at high temperatures has been difficult.
しかし、 本発明の上記関係式を指標として用いて合金組成を設計することに より、 更なる高温での疲労強度特性を有する合金を容易に得ることができ、 又、 3 5 0 °Cより高温時であっても優れた機械的強度を有するアルミニウム合金成形 品を得ることができる。 However, by designing the alloy composition using the above relational expression of the present invention as an index, it is possible to easily obtain an alloy having fatigue strength characteristics at a higher temperature, and at a temperature higher than 3500 ° C. Even at that time, an aluminum alloy molded product having excellent mechanical strength can be obtained.
より具体的には、 例えば、 3 5 0 °C、 1 0 0時間保持後の 3 5 0 °Cでの疲労 強度が 3 3 M P a以上となる。 これらの特性は、 例えば、 高温雰囲気に接する内 燃機関ピス トンの冠面部位に求められる特性である。 従って、 本発明のアルミ二 ゥム合金成形品を用いることにより、 従来の内燃機関ビストンよりも薄肉化する ことができ、 内燃機関ピス トンの軽量化が可能になる。 そして、 市場から求めら れている軽量化に答えることができ、 内燃機関の燃費低減、 出力向上が実現する ことができる。 図面の簡単な説明 More specifically, for example, the fatigue strength at 35 ° C. after holding at 350 ° C. for 100 hours is 33 MPa or more. These characteristics are, for example, the characteristics required for the crown surface portion of the internal combustion engine piston in contact with the high temperature atmosphere. Therefore, by using the aluminum alloy molded product of the present invention, it is possible to reduce the thickness of the conventional internal combustion engine piston, and to reduce the weight of the internal combustion engine piston. And it can answer the weight reduction demanded by the market, and achieves reduction in fuel consumption and output of internal combustion engines. be able to. Brief Description of Drawings
第 1図は、 本発明の製造工程を実現する生産ラインの一例である鍛造生産シ ステムを示す図である。 FIG. 1 is a view showing a forging production system which is an example of a production line for realizing the production process of the present invention.
第 2図は、 本発明に用いる連続铸造装置の铸型付近の一例を示す図である。 第 3図は、 本発明に用いる連続鐯造装置の铸型付近の他の一例を示す図であ る。 FIG. 2 is a diagram showing an example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention. FIG. 3 is a view showing another example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention.
第 4図は、 本発明に用いる連続铸造装置の有効モールド長を示す図である。 第 5図は、 本発明に用いる連続铸造装置の他の例を示す図である。 FIG. 4 is a view showing the effective mold length of the continuous forging apparatus used in the present invention. FIG. 5 is a view showing another example of the continuous forging apparatus used in the present invention.
第 6図は、 アルミニウム合金中の N i と C uの含有率の関係を説明する図で ある。 FIG. 6 is a diagram for explaining the relationship between the content ratios of Ni and Cu in an aluminum alloy.
第 7図 ( a ) は、 本発明の実施例 1 7、 1 8及び比較例 1 1〜 1 3の形状を 有するピス トンの平面図である。 第 7図 (b) は第 7図 (a) に示すピス トンの 正面図である。 FIG. 7 (a) is a plan view of a piston having the shapes of Examples 17 and 18 and Comparative Examples 11 to 13 of the present invention. Fig. 7 (b) is a front view of the piston shown in Fig. 7 (a).
第 8図は、 第 7図 (a) の M— VDI線断面図である。 発明を実施するための最良の形態 FIG. 8 is a cross-sectional view taken along the line M-VDI of FIG. 7 (a). BEST MODE FOR CARRYING OUT THE INVENTION
本発明の成形品の合金組成について説明する。 The alloy composition of the molded article of the present invention will be described.
本発明において使用されるアルミニウム合金溶湯は、 10. 5質量%〜1 3. The molten aluminum alloy used in the present invention ranges from 10.5 mass% to 1 3.
5質量% (好ましくは 1 1. 5質量%~ 1 3質量0/。) の S i、 2. 5質量%〜6 質量% (好ましくは 3. 5質量%〜5. 5質量%) の Cu、 0. 3質量。/。〜 1. 5質量% (好ましくは 0. 5質量%~1. 3質量%) の Mg、 0. 8質量%〜4 質量% (好ましくは 1. 8質量%〜3. 5質量%) の N iを含み、 かつ N i (質 量0 ) ≥ 〔一 0. 68 X C u (質量0 /0) +AA (質量0 /0)〕 (但し、 AAは定数で あって、 AA 4. 2であり、 好ましくは AA≥4. 7。) なる関係式を満足する 組成に調整される。 5 mass% (preferably 11.5 mass% to 13 mass 0 /.) Si, 2.5 mass% to 6 mass% (preferably 3.5 mass% to 5.5 mass%) Cu , 0.3 mass. /. ~ 1.5 wt% (preferably 0.5 wt% to 1.3 wt%) Mg, 0.8 wt% to 4 wt% (preferably 1.8 wt% to 3.5 wt%) N It includes i, and N i (mass 0) ≥ [one 0. 68 XC u (mass 0/0) + AA (mass 0/0)] (where, AA is a constant AA 4.2, preferably AA≥4.7. The composition is adjusted to satisfy the following relational expression.
S iは共晶 S iの分布により高温機械的強度、 耐摩耗性を高め、 Mgと共存 して Mg 2S i粒子を析出して高温機械的強度を向上させる。 S i力 1 0. 5 質量%未満では上記した効果が小さく、 1 3. 5質量%を超えると初晶 S iの晶 出が多くなり、 高温疲労強度、 延性、 靱性を低下させる。 Si increases the high-temperature mechanical strength and wear resistance due to the distribution of eutectic S i, and coexists with Mg to precipitate Mg 2 Si particles and improve the high-temperature mechanical strength. If the Si force is less than 1 0.5% by mass, the above effect is small. If it exceeds 13.5% by mass, the crystallization of the primary crystal Si increases and the high-temperature fatigue strength, ductility and toughness are reduced.
N iはA l—N i系、 A 1 _N i _C u系晶出物を発生させ、 それによつて 高温機械的強度を向上させる。 N i力 0. 8質量%未満では上記した効果は小 さく、 4質量%を超えると粗大な晶出物が増加して鍛造性や高温疲労強度、延性、 靱性を低下させる。 N i generates A 1−N i and A 1 _N i _Cu crystals, thereby improving the high-temperature mechanical strength. If the Ni force is less than 0.8% by mass, the above effect is small, and if it exceeds 4% by mass, coarse crystals increase and forgeability, high-temperature fatigue strength, ductility, and toughness decrease.
C uは C u A 12粒子を析出させ、 更に、 A l— C u系、 A 1— N i— C u 系晶出物を発生させ、 高温機械的強度を向上させる。 Cuが、 2. 5質量%未満 では上記した効果は小さく、 6質量%を超えると A 1一 C u系の粗大晶出物が増 加して鍛造性や高温疲労強度、 延性、 靱性を低下させる。 Cu precipitates Cu A 1 2 particles, and further generates crystallized A 1—Cu and A 1—Ni—Cu crystals, improving the high-temperature mechanical strength. When Cu is less than 2.5% by mass, the above effect is small. When it exceeds 6% by mass, coarse crystals of A 1-1 Cu system increase and forgeability, high temperature fatigue strength, ductility, and toughness decrease. Let
Mgは S i と共存して Mg 2S i粒子を析出して高温機械的強度を向上させ る。 Mgが、 0. 3質量%未満では上記した効果は小さく、 1. 5質量%を超え ると Mg 2S iの粗大晶出物が増加して鍛造性や高温疲労強度、 延性、 靱性を低 下させる。 Mg coexists with Si and precipitates Mg 2 Si particles to improve high-temperature mechanical strength. When Mg is less than 0.3% by mass, the above effect is small, and when it exceeds 1.5% by mass, coarse crystals of Mg 2 Si increase and forgeability, high-temperature fatigue strength, ductility, and toughness are reduced. Let me down.
更に、 本発明では、 N i及びC uの組成がN i (質量%) ≥ 〔一 0. 68 X C u (質量0 /0) +AA (質量0 /0)〕 (但し、 A Aは定数であって、 A A 4. 2。 好ましくは AA≥4. 7。) の関係式を満たしていることが必要である。 N i及び C uがこの関係式を満たすことにより、 より高温での疲労強度特性が向上するか らである。 尚、 定数 AAが 4. 7以上になるように調製されたアルミニウム合金 成形品は、 高温強度に寄与するネットワーク状又は針状の金属間化合物の発生量 が多くなるので好ましい。 上記した疲労強度特性向上のメカュズムは明確ではないが、 以下のように推 定できる。 高温機械的強度の向上に最も寄与しているものは、 八 1ー1^ 1系、 A 1一 N i—C u、 A 1—C u系晶出物と高温環境下で、 アルミニウム生地に固溶 する C uと考えられる。 これらの晶出物と Cuの固溶による高温機械的強度の向 上が効果的に生じる Cu量と N i量の関係が上式で導かれた。 Further, in the present invention, N i and C composition u is N i (wt%) ≥ [one 0. 68 XC u (mass 0/0) + AA (mass 0/0)] (where, AA is a constant Therefore, it is necessary to satisfy the relational expression AA 4.2, preferably AA≥4.7. This is because the fatigue strength characteristics at higher temperatures are improved when Ni and Cu satisfy this relational expression. An aluminum alloy molded article prepared so that the constant AA is 4.7 or more is preferable because the amount of network-like or acicular intermetallic compounds that contribute to high-temperature strength increases. The mechanism for improving the fatigue strength characteristics described above is not clear, but can be estimated as follows. What contributes most to the improvement of high-temperature mechanical strength is the 8 1-1 ^ 1 system, A 1 1 N i—C u, A 1—C u system crystallized materials and aluminum fabric under high temperature environment. It is thought that Cu is a solid solution. The relationship between the amount of Cu and the amount of Ni that effectively increases the high-temperature mechanical strength due to the solid solution of these crystals and Cu was derived from the above equation.
このようなアルミニウム合金を用いた成形品は、 好ましい値である 350°C での疲労強度が 33MP a以上となり、さらに好ましくは 43MP a以上となる。 更に、 300°Cでの疲労強度が 5 5 MP a以上となる。 A molded article using such an aluminum alloy has a fatigue strength at 350 ° C, which is a preferable value, of 33 MPa or more, and more preferably 43 MPa or more. Furthermore, the fatigue strength at 300 ° C is 55 MPa or more.
この溶湯は、 0. 1質量%〜1質量% (好ましくは 0. 2質量%~0. 5質 量0 /0) の M n、 0. 05質量0/。〜 0. 5質量% (好ましくは 0. 1質量%〜 0. 3質量0 /0) のじで、 0. 04質量%〜0. 3質量% (好ましくは 0. 1質量%~ 0. 2質量0 /0) の Z r、 0. 0 1質量%〜0. 1 5質量0 /0 (好ましくは 0. 05 質量%〜0. 1質量%) の V、 0. 0 1質量%〜0. 2質量% (好ましくは 0. 02質量%〜0. 1質量%) の T iの内の 1種又は 2種以上を含有することが好 ましい。 Mn、 C r、 Z r、 V、 T iの含有は、 A 1— M n系や A 1— F e— M n— S i系、 A l— C r系や A 1— F e— C r一 S i系、 A l — Z r系、 A l— V系、 A 1— T i系の化合物が晶出又は析出し、 アルミニウム合金の高温機械的 強度を向上させるからである。 Mnが 0. 1質量%未満、 C rが 0. 0 5質量 °/0 未満、 Z rが 0. 04質量%未満、 Vが 0. 0 1質量%未満、 T iが 0. 0 1質 量%未満では上記した効果は小さく、 Mnが 1. 0質量%を超え、 C rが 0. 5 質量%を超え、 ∑ :が0. 3質量%を超え、 Vが 0. 1 5質量%を超え、 T iが 0. 2質量%を超えると粗大な晶出物が増加して鍛造性、 高温疲労強度、 靱性を 低下させる。 The molten metal, M n of 0.1 wt% to 1 wt% (preferably 0.2% to 0.5 mass 0/0), 0.05 weight 0 /. ~ 0.5 wt% (preferably 0.1% to 0.3 mass 0/0) Noji, 0.04 wt% to 0. 3% by weight (preferably 0.1% to 0.2 mass 0/0) of Z r, 0.0 1 wt% to 0. 1 5 mass 0/0 (preferably 0.05 mass% to 0. V 1 wt%), 0.0 1 wt% to 0 It is preferable to contain one or more of 2 mass% (preferably 0.02 mass% to 0.1 mass%) of Ti. The contents of Mn, C r, Z r, V, and T i include A 1—M n system, A 1—F e—M n—S i system, A l—C r system, and A 1—F e— C. rSi-based, Al-Zr-based, Al-V-based, and A1-Ti-based compounds crystallize or precipitate, improving the high-temperature mechanical strength of the aluminum alloy. Mn of 0.1 less than 1 mass%, C r is 0.5 less than 0 5 wt ° / 0, Z r is 0.1 less than 04 wt%, V is 0.0 less than 1 wt%, T i is 0. 0 1 Quality When the amount is less than% by mass, the above effect is small, Mn exceeds 1.0% by mass, Cr exceeds 0.5% by mass, :: exceeds 0.3% by mass, and V is 0.15% by mass. When Ti exceeds 0.2% by mass, coarse crystallization increases and forgeability, high temperature fatigue strength, and toughness decrease.
更に、 F eを0. 1 5質量%〜0. 65質量% (好ましくは 0. 3質量%〜 0. 5質量0 /0) 含むことが好ましく、 A 1—F e系や A 1—F e— S i系や A 1 一 N i— F e系の粒子を晶出させ、 高温機械的強度を向上させる。 F eが、 0. 1 5質量%未満では上記した効果が小さく、 0. 65質量%を超えると A 1— F e系や A 1 -F e - S i系や A 1— N i _F e系の粗大晶出物が増加して鍛造性 や高温疲労強度、 延性、 靱性を低下させる。 Further, F e a 0.1 5 wt% to 0. 65 wt% preferably comprises (preferably 0.3% to 0.5 mass 0/0), A 1- F e system and A 1-F e—S i system or A 1 1. Crystallize Ni-Fe particles to improve high-temperature mechanical strength. When Fe is less than 0.15% by mass, the above effect is small. When it exceeds 0.65% by mass, the A 1—F e system, A 1 -F e -S i system, or A 1—N i _F e The coarse crystals of the system increase and the forgeability, high temperature fatigue strength, ductility, and toughness decrease.
又、 Pを 0. 003質量%〜0. 02質量% (好ましくは 0. 00 7質量% Also, P is 0.003 mass% to 0.02 mass% (preferably 0.007 mass%
〜0. 01 6質量%) 含むことが好ましい。 Pは初晶 S iを発生させるので、 耐 摩耗性を優先する場合に好ましく、 又、 初晶 S iの微細化効果があり、 発生した 初晶 S iよる鍛造性や延性や高温疲労強度の低下を抑制する働きをする。 Pが 0. 003質量%未満では初晶3 iの微細化効果が少なく、 鍀塊の中心に粗大な初晶 S iが発生し、 鍛造性や高温疲労強度、 延性、 靱性を低下させる。 Pが 0. 02 質量%を超えると初晶 S iの発生が多くなり、 鍛造性や高温疲労強度、 延性、 靱 性を低下させる。 ~ 0.01 6% by mass). P generates primary crystal S i and is therefore preferred when wear resistance is prioritized, and has the effect of refinement of primary crystal S i, and the forgeability, ductility, and high-temperature fatigue strength of the generated primary crystal S i are high. It works to suppress the decline. If P is less than 0.003 mass%, the effect of refining primary crystal 3 i is small, and coarse primary crystal S i is generated at the center of the ingot, reducing forgeability, high-temperature fatigue strength, ductility, and toughness. When P exceeds 0.02 mass%, the generation of primary crystals Si increases and forgeability, high temperature fatigue strength, ductility, and toughness deteriorate.
又、 0. 003質量%〜0. 03質量% (好ましくは 0. 0 1質量%~0. 02質量%) の31:、 0. 1質量%〜0. 3 5質量% (好ましくは 0. 1 5質量% 〜0. 25質量%) の S b、 0. 0005質量%〜0. 0 1 5質量0 /0 (好ましく は 0. 00 1質量%〜0. 01質量%) の Na、 0. 00 1質量%〜0. 02質 量0/。 (好ましくは 0. 00 5質量%〜0. 0 1質量%) の C aの内の 1種又は 2 種以上を含有することが、 共晶 S iの微細化効果があり、 好ましい。 S rが 0. 003質量%未満、 S b力 S 0. 1質量%未満、 N aが 0. 0005質量%未満、 C aが 0. 00 1質量%未満では上記した効果が小さく、 S rが 0. 0 3質量% を超え、 313が0. 35質量%を超え、 N aが0. 01 5質量%を超え、 C aが 0.02質量%を超えると粗大な晶出物が増加し又は鎊造欠陥が発生し、鍛造性、 高温疲労強度、 靱性を低下させる。 Further, 0.003% to 0.03% by mass (preferably 0.01% by mass to 0.02% by mass) 31: 0.1% by mass to 0.35% by mass (preferably 0.00% by mass). 1 5 wt% to 0. S b of 25 wt%), 0.0005 wt% to 0. 0 1 5 mass 0/0 (preferably 0.00 1 wt% to 0. Na, 01 mass%) 0 .00 1 mass% to 0.02 mass 0 /. It is preferable to contain one or more of Ca (preferably 0.005 mass% to 0.0 1 mass%) because of the effect of refining the eutectic Si. When S r is less than 0.003 mass%, S b force S is less than 0.1 mass%, N a is less than 0.0005 mass%, and C a is less than 0.001 mass%, the above effects are small, and S r Is greater than 0.03 mass%, 313 is greater than 0.35 mass%, Na is greater than 0.01 mass%, and Ca is greater than 0.02 mass%. Forging defects occur, reducing forgeability, high-temperature fatigue strength, and toughness.
アルミニウム合金成形品、 铸塊の合金成分の組成比は、 例えば、 J I S H 1 305に記載されているような光電測光式発光分光分析装置 (装置例:島津製 作所製 P D A— 5 5 0 0 ) による方法により確認できる。 The composition ratio of the alloy components of the aluminum alloy molded product and the ingot lump is, for example, a photoelectric photometric emission spectroscopic analyzer as described in JISH 1 305 (Example: Shimadzu) It can be confirmed by the method according to Sakusho PDA—5 5 0 0).
以下にこの発明の実施の形態を図面に基づいて詳細に説明する。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
第 1図は本発明の製造工程を実現する生産ラインの一例である生産システム を示す図である。 第 1図において、 鍛造品の生産システムは、 溶湯から連続铸造 棒を水平に铸造して所定の長さに切断する連続铸造装置 8 1と、 この連続鐯造装 置 8 1で铸造した連続铸造棒に熱処理を施す前熱処理装置 8 2と、 この前熱処理 装置 8 2で熱処理されて連続鎳造棒が曲がつた場合に連続铸造棒の曲がりを矯正 する矯正装置 8 3と、 この矯正装置 8 3で曲がりを矯正された連続铸造棒の外周 部分を除去するピーリング装置 8 4と、 ごのピーリング装置 8 4で外周部分が除 去された連続铸造棒を、 成形品を鍛造するのに必要な長さの切断片に切断する切 断装置 8 5と、 この切断装置 8 5で切断された切断片を予備加熱して据え込み加 ェする据え込み装置 (図示省略) と、 この据え込み装置で据え込みされた素材に 潤滑剤を被覆する為に予備加熱した素材に黒鉛系潤滑剤を塗布又は予備加熱した 素材を黒鉛系潤滑剤に浸漬する、 又は、 被覆させる潤滑装置 8 6 A, 8 6 Bと、 更に予備加熱装置 8 7で加熱された潤滑剤を付着させた素材から鍛造製品 (素形 材) を鍛造する鍛造装置 8 8と、 この鍛造装置 8 8で鍛造した鍛造済品 (鍛造製 品) に後熱処理を施す後熱処理装置 8 9と、 で構成されている。 FIG. 1 is a diagram showing a production system that is an example of a production line that realizes the production process of the present invention. In Fig. 1, the forged product production system consists of a continuous forging device 8 1 that horizontally forges a continuous forging bar from a molten metal and cuts it to a predetermined length, and a continuous forging forged by this continuous forging device 8 1. Pre-heat treatment device 8 2 for heat treatment of the rod, and straightening device 8 3 for correcting the bending of the continuous forged rod when the continuous forged rod is bent by heat treatment in this pre-heat treatment device 8 2, and this straightening device 8 It is necessary to forge the molded product with the peeling device 8 4 that removes the outer peripheral part of the continuous forged bar whose curvature has been corrected in step 3 and the continuous forged bar whose outer peripheral part has been removed with the peeling device 8 4. A cutting device 8 5 for cutting into length-cut pieces, an upsetting device (not shown) for preheating and cutting the cut pieces cut by the cutting device 85, and this upsetting device Element that has been pre-heated to cover the upset material with lubricant Lubricator 8 6 A, 8 6 B and a lubricant heated by pre-heater 8 7 are attached to the material which is coated or preheated with graphite lubricant. Forging device 8 8 forging forged products (molded material) from the processed material, and post-heat treatment device 8 9 for subjecting the forged product (forged product) forged with this forging device 8 8 to post-heat treatment 8 9 Has been.
後熱処理装置 8 9は、 例えば、 鍛造済品に溶体化処理を施す溶体化加熱装置 9 0と、 この溶体化加熱装置 9 0で加熱した鍛造製品を焼入れする焼入装置 9 1 と、 この焼入装置 9 1で焼入れした鍛造製品に時効処理を施す時効処理装置 9 2 とで構成することができる。 溶体化処理を省略する場合は、 溶体化加熱装置 9 0 と、 焼入装置 9 1を設けず、 鍛造装置 8 8の後に、 時効処理装置 9 2を設けるこ とが好ましい。 The post heat treatment apparatus 8 9 includes, for example, a solution heating apparatus 90 that performs solution treatment on the forged product, a quenching apparatus 9 1 that quenches the forged product heated by the solution heating apparatus 90, and this quenching apparatus. An aging treatment device 9 2 that performs aging treatment on the forged product quenched by the charging device 9 1 can be used. When the solution treatment is omitted, it is preferable not to provide the solution heating apparatus 90 and the quenching apparatus 91 but to provide the aging treatment apparatus 92 after the forging apparatus 88.
尚、 ピーリング装置 8 4、 据え込み装置は省略することができる。 又、 各装 置間の搬送は自動搬送装置で行うことができる。 又、 潤滑装置 8 6 A, 8 6 Bに おける潤滑剤被覆処理は、 ボンデ処理 (りん酸塩皮膜処理) 装置 8 6 Cに置き換 えることができる。 The peeling device 84 and the upsetting device can be omitted. In addition, transfer between each device can be performed by an automatic transfer device. Lubricators 8 6 A, 8 6 B Lubricant coating treatment can be replaced with bonder (phosphate coating treatment) equipment 8 6 C.
ここで、 前熱処理装置 8 2は、 素材温度を一 1 0 °C〜4 8 0 °Cに 2時間〜 6 時間保持する機能を有している。 予備加熱装置 8 7は、 素材温度を 3 8 0 °C〜4 8 0 °Cとする機能を有している。 後熱処理装置 8 9の溶体化加熱装置 9 0及び焼 入装置 9 1は、 鍛造済品 (成形品) の溶体化の為の温度を 4 8 0 °C~ 5 2 0 °Cと した後に焼入れする機能を有している。後熱処理装置 8 9の時効処理装置 9 2は、 鍛造済品 (成形品) の温度を 1 7 0 °C〜2 3 0 °Cに保持する機能を有している。 Here, the pre-heat treatment apparatus 8 2 has a function of holding the material temperature at 110 ° C. to 48 ° C. for 2 hours to 6 hours. The preheating device 87 has a function of setting the material temperature to 3800 ° C. to 48 ° C. Post-heat treatment equipment 8 9 solution heat-heating equipment 90 and quenching equipment 9 1 are quenched after the temperature for solution treatment of forged products (molded products) is set to 48 0 ° C to 5 20 ° C It has a function to do. The aging treatment device 9 2 of the post heat treatment device 89 has a function of maintaining the temperature of the forged product (molded product) at 1700 ° C. to 230 ° C.
本発明の生産システムを用いた製造方法は、 アルミニウム合金を連続铸造法 により铸造して得られた丸棒に、 前熱処理を施す工程、 前熱処理したものを素材 として熱間塑性加工により素形材を成形する工程、 塑性加工後に後熱処理するェ 程、 を含む成形品の製造方法であって、 前熱処理の温度が一 1 0 °C~ 4 8 0 °C、 熱間塑性加工時の素材温度が 3 8 0 °C〜4 8 0 °C、 後熱処理工程では、 溶体化加 熱は素形材温度を 4 8 0 °C〜 5 2 0 °Cに、 又は溶体化処理を施さずに直接 1 7 0 °C〜2 3 0 °Cの温度条件を満足する温度管理をし、 成形品を铸造工程から各熱 処理工程を含めて一貫して製造する。 その結果、 好ましい機械的強度を有する成 形品を安定して製造することができる。 The production method using the production system of the present invention is a method in which a round bar obtained by forging an aluminum alloy by a continuous forging method is subjected to a pre-heat treatment, and the pre-heat-treated material is used as a raw material by hot plastic working. And a post-heat treatment step after plastic working, wherein the temperature of the pre-heat treatment is 10 to 48 ° C., and the material temperature during hot plastic working In the post-heat treatment process, solution heat is applied directly to the material temperature from 48 ° C to 52 ° C or without solution treatment. The temperature is controlled so as to satisfy the temperature conditions from 1700 ° C to 230 ° C, and the molded products are manufactured consistently from the forging process to each heat treatment process. As a result, a molded product having preferable mechanical strength can be stably produced.
上記塑性加ェとして鍛造加ェを挙げることができる力 本発明の製造方法は、 前熱処理の温度、 熱間塑性加工時の素材温度、 後熱処理の温度の条件を満たすも のであれば転造加工、 押出し加工と組み合わせることもできる。 何れの場合も、 組織ゃ晶出物のネットワークの制御において、 本発明の作用効果を得ることがで きるからである。 The force that can give a forging process as the plastic process. The manufacturing method of the present invention is a rolling process as long as it satisfies the conditions of the pre-heat treatment temperature, the material temperature during hot plastic working, and the post-heat treatment temperature. It can also be combined with extrusion. This is because, in any case, the effects of the present invention can be obtained in controlling the network of tissue crystals.
本発明のアルミニゥム合金成形品は、 高温時の機械的強度を要求される部品 として好適に使用することができる。 そのため、 例えば、 エンジンピストン、 バ ルブリフタ一、 バルブリテーナ一、 シリンダーライナー等の形状の成形品を本発 明により製造し、 該成型品を必要に応じて旋盤、 マシエングセンター等で更に機 械加工を行うことにより所望の形状に成形し、 各種製品用の部品として使用する ことができる。 The aluminum alloy molded article of the present invention can be suitably used as a part that requires mechanical strength at high temperatures. For this reason, for example, molded products such as engine pistons, valve lifters, valve retainers, and cylinder liners are The molded product can be manufactured into a desired shape by further machining on a lathe, machining center, etc. as necessary, and used as a part for various products.
本発明で用いる製造方法の、 基本的な凝固方法の部分には、 公知のホットト ップ連続鎵造法、 縦型連続踌造法、 水平連続铸造法、 D C铸造法の何れかを用い ることができる。 例えば、 中心軸が横方向になるように保持された強制冷却を有 した筒状铸型の内壁面に気体、 液体潤滑剤、 その加熱分解気体から選ばれる何れ か 1種又は 2種以上の流体を供給し、 筒状鏺型の一端に S iを含有するアルミ二 ゥム合金溶湯を供給して柱状金属溶湯を形成し、 柱状金属溶湯を筒状鎊型で凝固 させて形成した铸塊を、 筒状铸型の他端から引き抜く水平連続銬造法とすること ができる。 以下に、 本発明を水平連続铸造法に適用した場合について説明する。 For the basic solidification method part of the production method used in the present invention, any of the known hot top continuous forging method, vertical continuous forging method, horizontal continuous forging method, and DC forging method should be used. Can do. For example, one or two or more fluids selected from gas, liquid lubricant, and thermally decomposed gas on the inner wall surface of a cylindrical bowl with forced cooling held so that the central axis is in the horizontal direction A columnar metal melt is formed by supplying a molten aluminum alloy containing Si to one end of the cylindrical saddle mold, and the soot mass formed by solidifying the columnar metal melt in the cylindrical saddle mold is formed. It can be a horizontal continuous forging method in which it is pulled out from the other end of the cylindrical saddle type. Below, the case where this invention is applied to the horizontal continuous forging method is demonstrated.
第 2図は本発明に用いる連続錄造装置の铸型付近の一例を示す図である。 タ ンディッシュ 2 5 0中に貯留された合金溶湯 2 5 5が耐火物製板状体 2 1 0を経 て筒状錄型 2 0 1に供給されるように、 タンディッシュ 2 5 0、 耐火物製板状体 2 1 0、 筒状铸型 2 0 1が配置されている。 筒状鐯型 2 0 1は铸型中心軸 2 2 0 がほぼ水平になるように保持されている。 合金溶湯 2 5 5が凝固铸塊 2 1 6とな るように、 筒状铸型 2 0 1の内部には強制冷却手段、 筒状鎵型 2 0 1の出口には 凝固鍩塊 2 1 6の強制冷却手段が配設されている。 図 2では、 凝固铸塊 2 1 6を 強制冷却する手段の例として、 冷却水シャワー装置 2 0 5が設けられている。 筒 状鎵型 2 0 1の出口の近くには、 強制冷却された凝固铸塊 2 1 6が一定速度で引 き出されて連続的に铸造されるように駆動装置 (図示せず) が設置されている。 更に、 引き出された錡造棒を所定の長さに切断する同調切断機 (図示せず) が配 設されている。 FIG. 2 is a view showing an example of the vicinity of the vertical shape of the continuous forging apparatus used in the present invention. Tundish 2 5 0, refractory so that molten alloy 2 5 5 stored in tundish 2 5 0 is supplied to cylindrical saddle 2 0 1 via plate 2 1 0 made of refractory A product-made plate-like body 2 1 0 and a cylindrical saddle shape 2 0 1 are arranged. The cylindrical saddle mold 20 1 is held so that the saddle mold central axis 2 2 0 is substantially horizontal. Forced cooling means is provided inside the cylindrical bowl 2 0 1 so that the molten alloy 2 5 5 becomes the solidified lump 2 1 6, and solidified lump 2 1 6 is provided at the outlet of the cylindrical bowl 2 0 1. The forced cooling means is provided. In FIG. 2, a cooling water shower device 205 is provided as an example of means for forcibly cooling the solidified slag 2 16. A drive unit (not shown) is installed near the outlet of the cylindrical saddle mold 20 1 so that the solidified clot 2 1 6 that has been forcibly cooled is drawn out at a constant speed and continuously produced. Has been. Furthermore, a synchronous cutting machine (not shown) for cutting the drawn forged bar into a predetermined length is provided.
本発明に用いる装置の鍀型付近の他の一例を第 3図を用いて説明する。 第 3 図は、 D C铸造機の一例が概略的な断面図で示されている。 この D C铸造機にお いては、 アルミニウム合金溶湯 1が樋 2、 ディップ'チューブ 3及びフロート分 配器 4を介してアルミ二ゥム合金製又は銅製の固定の水冷錄型 5内に導入される。 水冷铸型 5は、 冷却水 5 Aによって冷却されている。 水冷鐯型 5内に導入された アルミニウム合金溶湯 6は、 水冷铸型 5に接する部分において凝固殻 7を形成し て収縮し、 凝固したアルミニウム合金铸塊 7 Aは下型 9によって水冷铸型 5から 下方に引き出される。 このとき、 アルミニウム合金铸塊 7 Aは水冷铸型 5から供 給される水冷ジェット 8によって更に冷却され、 完全に凝固させられる。 下型 9 が動き得る下端部に達すれば、 アルミニウム合金鍚塊 7 Aは所定の位置で切断さ れて取り出される。 Another example of the vicinity of the saddle shape of the apparatus used in the present invention will be described with reference to FIG. Fig. 3 shows a schematic cross-sectional view of an example of a DC forging machine. This DC forging machine In this case, the molten aluminum alloy 1 is introduced into the fixed water-cooled mold 5 made of aluminum alloy or copper via the pot 2, the dip tube 3 and the float distributor 4. The water cooling mold 5 is cooled by cooling water 5A. The molten aluminum alloy 6 introduced into the water-cooled mold 5 shrinks by forming a solidified shell 7 at the portion in contact with the water-cooled mold 5, and the solidified aluminum alloy mass 7 A is cooled by the lower mold 9 with the water-cooled mold 5. Pulled down from. At this time, the aluminum alloy ingot 7 A is further cooled by the water cooling jet 8 supplied from the water cooling mold 5 and is completely solidified. When the lower end 9 where the lower mold 9 can move is reached, the aluminum alloy ingot 7A is cut at a predetermined position and taken out.
第 2図に戻って説明を続けると、 筒状鎵型 2 0 1は、 铸型中心軸 2 2 0がほ ぼ水平 (状) になるように保持され、 铸型冷却水キヤビティ 2 0 4内に冷却水 2 0 2を通して錄型壁面を冷却することにより、 筒状铸型 2 0 1内に充満した柱状 金属溶湯 2 1 5の熱を铸型壁に接触する面から奪ってその表面に凝固殻を形成す る筒状铸型 2 0 1の強制冷却手段と、 筒状錡型 2 0 1の出口側端末において凝固 铸塊 2 1 6に直接冷却水を当てるように冷却水シャワー装置 2 0 5から冷却水を 放出して筒状铸型 2 1 0内の柱状金属溶湯 2 1 5を凝固させる強制冷却手段を有 した筒状鍀型 2 0 1である。 更に、 筒状鍀型 2 0 1は、 その冷却水シャワー装置 2 0 5の噴出口と反対側の一端が耐火物製板状体 2 1 0を介してタンディッシュ 2 5 0に接続されている。 Returning to FIG. 2, the description will be continued. The cylindrical bowl 20 1 is held so that the bowl center axis 2 2 0 is almost horizontal (in the shape), and in the bowl cooling water cavity 2 0 4 By cooling the vertical wall surface with cooling water 2 0 2, the columnar molten metal 2 1 5 filled in the cylindrical vertical wall 2 0 1 is removed from the surface contacting the vertical wall and solidified on the surface. Cooling water shower device 2 0 for forced cooling means of cylindrical bowl 20 1 that forms a shell, and solidified slag 2 1 6 at the outlet end of cylindrical bowl 20 1 This is a cylindrical saddle mold 201 having a forced cooling means for discharging cooling water from 5 to solidify the columnar metal melt 2 15 in the cylindrical saddle mold 210. Further, the cylindrical saddle mold 20 1 is connected to the tundish 2 5 0 through a refractory plate-like body 2 1 0 at one end opposite to the jet port of the cooling water shower device 2 0 5. .
第 2図では、 冷却水供給管 2 0 3を介して筒状錡型 2 0 1の強制冷却の為の 冷却水、凝固錡塊 2 1 6の強制冷却の為の冷却水を供給している力 S、それぞれ別々 に冷却水を供することもできる。 In FIG. 2, the cooling water for forced cooling of the cylindrical bowl 20 1 and the cooling water for forced cooling of the solidified lumps 2 1 6 are supplied through the cooling water supply pipe 20 3. Power S can be supplied separately for each.
冷却水シャワー装置 2 0 5の噴出口の中心軸の延長線が铸造された凝固铸塊 2 1 6表面に当たる位置から、 筒状錶型 2 0 1と耐火物製板状体 2 1 0との接触 面までの長さを有効モールド長 (図 4の符合 L参照) と言い、 1 5 πιπ!〜 7 0 m mであるのが好ましい。 この有効モールド長が 1 5 mm未満では良好な皮膜が形 成されない等から铸造不可となり、 7 Ommを超えると強制冷却の効果が無く、 铸型壁による凝固が支配的になって筒状鍩型 2 0 1と柱状金属溶湯 2 1 5若しく は凝固殻との接触抵抗が大きくなつて鎵肌に割れが生じたり、 筒状铸型 20 1内 ' 部で千切れたりする等、 铸造が不安定になるので好ましくはない。 From the position where the extension line of the central axis of the jet outlet of the cooling water shower device 2 0 5 hits the surface of the solidified lump 2 1 6, the cylindrical saddle shape 2 0 1 and the refractory plate 2 1 0 The length to the contact surface is called the effective mold length (see symbol L in Fig. 4), and 1 5 πιπ! ~ 70 m m is preferred. If this effective mold length is less than 15 mm, it is impossible to forge because a good film is not formed, and if it exceeds 7 Omm, there is no effect of forced cooling, and solidification by the vertical wall dominates and the cylindrical vertical mold 2 0 1 and molten columnar metal 2 1 5 or the contact resistance with the solidified shell increases, causing cracks in the skin, and tearing at the inner part of the cylindrical saddle 20 1 Since it becomes stable, it is not preferable.
筒状铸型 2 0 1の材質はアルミニウム、 銅、 若しくはそれらの合金から選ば れる 1種又は 2種以上の組み合わせであるのが好ましい。 熱伝導性、 耐熱性、 機 械強度の点から材質の組み合わせを選ぶことができる。 The material of the cylindrical saddle mold 201 is preferably one or a combination of two or more selected from aluminum, copper, or alloys thereof. A combination of materials can be selected in terms of thermal conductivity, heat resistance, and mechanical strength.
更に、 筒状铸型 2 0 1の柱状金属溶湯 2 1 5と接触する面にリング状に、 自 己潤滑性を保有した浸透性多孔質材 2 2 2を装填した铸型であるのが好ましい。 リング状とは、 筒状铸型 20 1の内壁面 2 2 1の円周方向の全体に装着した状態 である。 浸透性多孔質材 2 2 2の通気度が 0. 00 5 〔L (リットル) / (cm2 /m i n)〕 〜0. 0 3 〔L/ ( c 2/m i n)〕、 より好ましくは 0. 0 7 [L / ( c m2/m i n)〕 〜0. 0 2 [L/ ( c m2/m i n)) であるのが好ましい。 装着する浸透性多孔質材 2 2 2の厚さは特に限定されないが、 2 mn!〜 1 Omm、 より好ましくは 3mm〜 8mmであることが好ましい。 浸透性多孔質材 2 2 2と して、 例えば、 通気度が 0. 00 8 [L/ (c m2/m i n)] 〜0. 0 1 2 〔L / (c m2/m i n)] の黒鉛を用いることができる。 ここで、 通気度とは 5 mm の厚さの試験片に対して圧力 2 k gZ cn^ の空気の、 毎分の通気量を測定した ものである。 Further, it is preferable that the cylindrical bowl-shaped mold 201 is a bowl-shaped mold in which a permeable porous material 2 2 2 having a self-lubricating property is loaded in a ring shape on the surface in contact with the columnar molten metal 2 15. . The ring shape is a state in which the inner surface 2 2 1 of the cylindrical saddle 201 is attached to the entire circumferential direction. The permeability of the permeable porous material 2 2 2 is 0.005 [L (liter) / (cm2 / min)] to 0.03 [L / (c 2 / min)], more preferably 0.0. 7 [L / (cm2 / min)] to 0.02 [L / (cm2 / min)) is preferable. The thickness of the permeable porous material 2 2 2 to be attached is not particularly limited, but 2 mn! ˜1 Omm, more preferably 3 mm to 8 mm. For example, graphite having an air permeability of 0.008 [L / (c m2 / min)] to 0.0 1 2 [L / (c m2 / min)] is used as the permeable porous material 2 2 2. Can be used. Here, the air permeability is measured by measuring the air flow rate per minute of air with a pressure of 2 kgZ cn ^ on a test piece with a thickness of 5 mm.
有効モーノレド長の内の 5 πιπ!〜 1 5 mmに浸透' 1"生多孔質材 2 2 2が装着され ている筒状铸型 20 1を用いることが好ましい。 筒状铸型 20 1、 耐火物製板状 体 2 1 0、 浸透性多孔質材 2 2 2の合わせ面に Oリング 2 1 3を配設するのが好 ましい。 5 πιπ of the effective monoredo length! ~ 15 mm infiltration '1 "cylindrical saddle 20 1 fitted with raw porous material 2 2 2 is preferably used. Cylindrical saddle 20 1, refractory plate 2 10 It is preferable to place an O-ring 2 1 3 on the mating surface of the permeable porous material 2 2 2.
筒状錡型 2 0 1の半径方向断面の内壁面 2 2 1の形状は、 円状以外に、 三角 形や矩形断面形状若しくは対称軸や対称面を持たない異形断面形状を有した形状 でも良い。 或いは、 中空铸塊を成形する場合は、 铸型内部に中子を保持したもの でも良い。 そして、 筒状铸型 2 0 1は、 両端が開放された筒状の铸型であって、 耐火物製板状体 2 1 0に穿設された注湯口 2 1 1を介して一端から筒状鐯型 2 0 1の内部へ合金溶湯 2 5 5が進入し、 他端から凝固錄塊 2 1 6が押し出され、 又 は引き出される。 The shape of the inner wall surface 2 2 1 of the radial cross section of the cylindrical bowl 2 0 1 is triangular, in addition to the circular shape. It may be a shape, a rectangular cross-sectional shape, or a shape having an irregular cross-sectional shape having no symmetry axis or symmetry plane. Alternatively, in the case of forming a hollow gob mass, a core holding a core inside the saddle shape may be used. The cylindrical saddle mold 20 1 1 is a cylindrical saddle mold with both ends open, and is formed from one end through a pouring port 2 1 1 drilled in the refractory plate-like body 2 10 1. The molten alloy 2 5 5 enters the inside of the bowl mold 20 1, and the solid clot 2 1 6 is pushed out or pulled out from the other end.
筒状铸型 2 0 1の内壁面 2 2 1は凝固鐯塊 2 1 6の引き出じ方向に向けて鎊 型中心軸 2 2 0と 0度〜 3度、 より好ましくは 0度〜 1度の仰角で形成されてい る。 仰角 0度未満では凝固鎵塊 2 1 6が筒状铸型 2 0 1から引き出される際に筒 状铸型 2 0 1の出口で抵抗を受ける為に铸造が不可能となり、 一方 3度を越える と、 筒状錄型 2 0 1の内壁面 2 2 1の柱状金属溶湯 2 1 5への接触が不充分にな り、 柱状金属溶湯 2 1 5や凝固殻から筒状铸型 2 0 1への抜熱効果が低下するこ とによって凝固が不充分となる。 その結果、 凝固铸塊 2 1 6の表面に再溶融肌が 生じ又は筒状铸型 2 0 1の端部から未凝固の合金溶湯 2 5 5が噴出するなどの铸 造トラプルにつながる可能性が高くなるので好ましくない。 The inner wall surface 2 2 1 of the cylindrical saddle mold 2 0 1 faces the vertical axis of the bowl 2 2 0 in the direction of pulling out the solidified lump 2 1 6 0 to 3 degrees, more preferably 0 to 1 degree It is formed at an elevation angle of. If the elevation angle is less than 0 degree, the solidified clot 2 1 6 is not able to be forged because it receives resistance at the outlet of the cylindrical bowl 2 0 1 when it is pulled out of the cylindrical bowl 2 0 1, while it exceeds 3 degrees And the inner wall surface 2 2 1 of the cylindrical bowl 2 0 1 is insufficiently in contact with the molten metal 2 1 5, and the molten metal 2 1 5 and the solidified shell to the cylindrical bowl 2 0 1 Solidification becomes insufficient due to the reduced heat removal effect. As a result, remelted skin may occur on the surface of the solidified lumps 2 16, or it may lead to smoldering traps such as the unsolidified molten alloy 2 5 5 ejecting from the ends of the cylindrical saddle mold 2 0 1. Since it becomes high, it is not preferable.
タンディッシュ 2 5 0は、 外部の溶解炉等によって規定の合金成分に調整さ れたアルミニウム合金溶湯を受ける溶湯流入部 2 5 1、 溶湯保持部 2 5 2、 筒状 铸型 2 0 1への流出部 2 5 3から構成されている。 タンディッシュ 2 5 0は、 合 金溶湯 2 5 5の液面レベル 2 5 4を筒状錄型 2 0 1の上面より高い位置に維持し、 かつ多連鎵造の場合には、 各筒状铸型 2 0 1に合金溶湯 2 5 5を安定的に分配す るものである。 タンディッシュ 2 5 0内の溶湯保持部 2 5 2に保持された合金溶 湯 2 5 5は耐火物製板状体 2 1 0に設けられた注湯口 2 1 1から筒状鎵型 2 0 1 に注湯される。 The tundish 2 5 0 is supplied to the molten metal inflow part 2 5 1, the molten metal holding part 2 5 2, and the cylindrical vertical mold 2 0 1 that receives the molten aluminum alloy adjusted to the specified alloy composition by an external melting furnace, etc. Outflow part 2 5 3 The tundish 2 5 0 maintains the liquid level 2 5 4 of the molten metal 2 5 5 at a position higher than the upper surface of the cylindrical mold 2 0 1, and in the case of multiple frames, each tubular shape The molten alloy 2 5 5 is stably distributed to the vertical mold 2 0 1. Molten metal holding part 2 5 2 in tundish 2 5 0 2 5 5 is a molten metal plate 2 5 5 is a pouring hole provided in a refractory plate 2 1 0 2 1 1 to a cylindrical bowl 2 0 1 Be poured into hot water.
耐火物製板状体 2 1 0は、 タンディッシュ 2 5 0と筒状铸型 2 0 1とを隔て る為のものであり、 耐火断熱性を備えている材質のものを用いることができ、 例 えば、 (株)ェチアス製ルミボード、フォセコ (株)製ィンシュラル、ィビデン(株) 製ファイバーブランケットボードを挙げることができる。 耐火物製板状体 2 1 0 は注湯口 2 1 1を形成できるような形状を有している。 注湯口 2 1 1は耐火物製 板状体 2 1 0が筒状铸型 2 0 1の内壁面 2 2 1より内側に張り出した部分に 1個 又は 1個以上形成することができる。 The refractory plate-like body 2 1 0 is for separating the tundish 2 5 0 and the cylindrical bowl 2 1 0 1 and can be made of a material having fire and heat insulation, Example For example, Lumi board manufactured by Etias Co., Ltd., Insular manufactured by Foseco Co., Ltd., and fiber blanket board manufactured by Ibiden Co., Ltd. may be mentioned. The refractory plate-like body 2 1 0 has such a shape that the pouring port 2 1 1 can be formed. One or more pouring spouts 21 1 1 can be formed on the part where the refractory plate-like body 2 10 1 protrudes inward from the inner wall surface 2 2 1 of the cylindrical saddle mold 2 0 1.
符号 2 0 8は流体を供給する流体供給管である。 流体としては潤滑流体を挙 げることができる。 流体は、 気体、 液体潤滑剤から選ばれる何れか 1種又は 2種 以上の流体とすることができる。 気体、 液体潤滑剤の供給管は別々に設けること が好ましい。 . Reference numeral 20 8 denotes a fluid supply pipe for supplying a fluid. Lubricating fluid can be listed as the fluid. The fluid may be any one or two or more fluids selected from gas and liquid lubricant. It is preferable to separately provide gas and liquid lubricant supply pipes. .
流体供給管 2 0 8から加圧供給された流体は環状通路 2 2 4を通って筒状铸 型 2 0 1と耐火物製板状体 2 1 0との間の隙間に供給される。 筒状錄型 2 0 1が 耐火物製板状体 2 1 0に面する部位に 2 0 0 Ai m以下の隙間が形成されているの が好ましい。 この隙間は、 合金溶湯 2 5 5が差し込まない程度で、 流体が筒状铸 型 2 0 1の内壁面 2 2 1へ流出できる程度の大きさである。 図 2に示した形態で は、 環状通路 2 2 4は筒状铸型 2 0 1に装着された浸透性多孔質材 2 2 2の外周 面側に対峙して穿設され、 流体はかけられた圧力によって浸透性多孔質材 2 2 2 の内部に浸透して柱状合金溶湯 2 1 5と接触する浸透性多孔質材 2 2 2の全面に 送られ、 筒状铸型 2 0 1の內壁面 2 2 1に供給される。 液体潤滑剤は加熱されて 分解気体となり、 筒状铸型 2 0 1の内壁面 2 2 1に供給される場合もある。 The fluid pressurized and supplied from the fluid supply pipe 2 0 8 passes through the annular passage 2 2 4 and is supplied to the gap between the cylindrical basket 2 0 1 and the refractory plate-like body 2 1 0. It is preferable that a gap of 200 Aim or less is formed in a portion where the cylindrical saddle mold 20 1 faces the refractory plate-like body 2 10. This gap is so large that the molten alloy 2 5 5 cannot be inserted, and the fluid can flow out to the inner wall surface 2 2 1 of the cylindrical mold 2 0 1. In the form shown in FIG. 2, the annular passage 2 2 4 is perforated on the outer peripheral surface side of the permeable porous material 2 2 2 attached to the cylindrical saddle mold 20 1, and the fluid is applied to it. Pressure penetrates the inside of the permeable porous material 2 2 2 and is sent to the entire surface of the permeable porous material 2 2 2 in contact with the molten columnar alloy 2 1 5 Supplied to 2 2 1 The liquid lubricant is heated to be decomposed gas and may be supplied to the inner wall surface 2 21 of the cylindrical saddle mold 20 1.
その結果、 筒状铸型 2 0 1の浸透性多孔質面と、 柱状金属溶湯 2 1 5外周面 及び凝固殻外周面と間の潤滑を良くすることができる。 浸透性多孔質材 2 2 2を リング状に装着することにより、 より良好な潤滑効果が得られ、 アルミニウム合 金連続鏡造棒を容易に铸造することができる。 As a result, it is possible to improve the lubrication between the permeable porous surface of the cylindrical saddle mold 201 and the outer peripheral surface of the columnar molten metal 2 15 and the outer peripheral surface of the solidified shell. By mounting the permeable porous material 2 2 2 in a ring shape, a better lubrication effect can be obtained, and an aluminum alloy continuous mirror rod can be easily fabricated.
供給された気体、 液体潤滑剤、 液体潤滑剤の分解した気体から選ばれる何れ か 1種又は 2種以上により、 隅部空間 2 3 0が形成される。 本発明の製造方法に含まれる铸造工程について説明する。 The corner space 230 is formed by any one or two or more kinds selected from the supplied gas, liquid lubricant, and gas decomposed from the liquid lubricant. The forging process included in the production method of the present invention will be described.
第 2図において、 タンディッシュ 250中の合金溶湯 25 5は耐火物製板状 体 21 0を経て、 錄型中心軸 220がほぼ水平になるように保持された筒状铸型 201に供給され、 筒状鎳型 20 1の出口にて強制冷却されて凝固鐯塊 21 6と なる。 凝固鎳塊 2 16は筒状铸型 20 1の出口近くに設置された駆動装置によつ て一定速度で引き出される為、 連続的に铸造されて錄造棒になる。 引き出された 錄造棒は同調切断機によって所定の長さに切断される。 即ち、 連続铸造棒は、 合 金溶湯 25 5の平均温度が液相線 +40°C〜+ 230 °Cのアルミェゥム合金を、 铸造速度を 300 (mm/m i n) 〜2000 (mm/m i n) にして連続铸造 法により铸造して得られる。 この条件範囲にすると晶出物が微細分散し、 鍛造成 形性に優れ、 かつ高温機械的強度に優れた成形品となる。 ホットトップ連続铸造 法、 縦型連続鑤造法、 DC铸造法の場合は、 80 (mm/m i n) 〜400 (m m/m i n) の铸造速度が好ましい。 従って、 铸造速度は 80 (mm/m ί η) 〜 2000 (mm/m i n) が好ましい。 In FIG. 2, the molten alloy 255 in the tundish 250 passes through the refractory plate 210, and is supplied to the cylindrical bowl 201 held so that the bowl central shaft 220 is substantially horizontal. It is forcibly cooled at the outlet of the cylindrical bowl 201 and becomes a solidified lump 21 6. Since the solidified lumps 2 16 are pulled out at a constant speed by a driving device installed near the outlet of the cylindrical mold 201, they are continuously formed into a forged bar. The drawn forged bar is cut into a predetermined length by a synchronous cutting machine. That is, the continuous forging rod is made of an aluminum alloy whose average temperature of molten alloy 255 is liquidus + 40 ° C to + 230 ° C, and the forging speed is set to 300 (mm / min) to 2000 (mm / min). Forged by a continuous forging method. Within this condition range, the crystallized product is finely dispersed, resulting in a molded product having excellent forging formability and excellent high-temperature mechanical strength. In the case of the hot top continuous forging method, the vertical continuous forging method and the DC forging method, a forging speed of 80 (mm / min) to 400 (mm / min) is preferable. Therefore, the forging speed is preferably 80 (mm / m η) to 2000 (mm / min).
タンディッシュ 250内に貯留するアルミニウム合金の合金溶湯 2 55の組 成について説明する。 The composition of the molten aluminum alloy 255 stored in the tundish 250 will be described.
合金溶湯 255は、 10. 5質量%〜1 3. 5質量% (好ましくは 1 1. 5 質量%〜1 3質量%) の S i、 2. 5質量%〜6質量% (好ましくは 3. 5質量% 〜5. 5質量0 /0) の Cu、 0. 3質量%~1. 5質量% (好ましくは 0. 5質量% 〜1. 3質量0 /0) の Mg、 0. 8質量%〜4質量% (好ましくは 1. 8質量%〜 3. 5質量0 /0) の N i含み、 かつ N i (質量0 /0) ≥ 〔ー0. 68 XC u (質量0 /0) + AA (質量0 /0)〕 (但し、 AAは定数であって、 AA≥4. 2。 好ましくは AA ≥4. 7。) なる関係式を満足するアルミニウム合金である。 The molten alloy 255 has a Si of 10.5 mass% to 13.5 mass% (preferably 11.5 mass% to 13 mass%), 2.5 mass% to 6 mass% (preferably 3. 5 wt% to 5. Cu 5 wt 0/0), 0.3 wt% ~ 1. Mg of 5 wt% (preferably 0.5 mass% to 1. 3 mass 0/0), 0.8 mass % to 4 wt% (preferably 1.8% to 3.5 mass 0/0) a N i of, and N i (mass 0/0) ≥ [chromatography 0. 68 XC u (mass 0/0) + AA (mass 0/0)] (where, AA is a constant, AA≥4. 2. preferably AA ≥4. 7.) an aluminum alloy that satisfies a relational expression made.
この合金溶湯 25 5は、 0. 1質量%〜1質量% (好ましくは 0. 2質量% 〜0. 5質量0 /0) の Mn、 0. 05質量%〜0. 5質量0 /0 (好ましくは 0. 1質 量%〜0. 3質量0 /0) の C r、 0. 04質量%〜0. 3質量% (好ましくは 0. 1質量0/。〜 0. 2質量%) の Z r、 0. 0 1質量%〜 0. 1 5質量0 /0 (好ましく は 0. 05質量%〜0. 1質量%) の V、 0. 0 1質量%〜0. 2質量% (好ま しくは 0. 02質量。/。〜 0. 1質量。/。) の T iの内の 1種又は 2種以上を含有す ることが好ましい。 The molten alloy 25 5, 0.1 wt% to 1 wt% (preferably 0.2 mass% to 0. 5 wt 0/0) Mn of 0.05 wt% to 0. 5 wt 0/0 ( Preferably 0.1 quality The amount% to 0. 3 mass 0/0) of C r, 0. 04 wt% to 0. Z r of 3 mass% (preferably 0.1 mass 0 /.~ 0.2 wt%), 0.0 1% to 0.1 5 weight 0/0 (preferably 0.05 mass% to 0. 1 wt%) V of 0.0 1 wt% to 0. 2% by weight (the preferred properly 0.02 mass It is preferable to contain one or more of T i of ./. To 0.1 mass /.).
更に、 F eを0. 1 5質量°/0〜0. 65質量% (好ましくは 0. 3質量%〜 0. 5質量%) 含むことが好ましい。 Further, it is preferable that Fe is contained in an amount of 0.15 mass% / 0 to 0.65 mass% (preferably 0.3 mass% to 0.5 mass%).
又、 Pを 0. 003質量%〜0. 02質量。 /0 (好ましくは 0. 007質量% 〜0. 0 1 6質量0 /0) 含むことが好ましい。 Moreover, P is 0.003 mass% to 0.02 mass. / 0 (preferably 0.007 wt% to 0. 0 1 6 mass 0/0) preferably includes.
又、 0. 003質量%〜0. 03質量% (好ましくは 0. 01質量%〜0. Further, 0.003 mass% to 0.03 mass% (preferably 0.01 mass% to 0.03 mass%).
02質量°/0) の3;^ 0. 1質量%〜0. 3 5質量% (好ましくは 0. 1 5質量。 /0 〜0. 25質量%) の S b、 0. 0005質量%〜0. 0 1 5質量% (好ましく は 0. 00 1質量%〜0. 0 1質量%) の Na、 0. 00 1質量%〜0. 0 2質 量0 /0 (好ましくは 0. 005質量%〜0. 01質量0 /0) の C aの内の 1種又は 2 種以上を含有することが、 共晶 S iの微細化効果があり、 好ましい。 02 mass ° / 0 ) 3; ^ 0.1 mass% to 0.3 5 mass% (preferably 0.1 5 mass% / 0 to 0.25 mass%) Sb, 0.005 mass% to 0.0 1 5% by weight (preferably 0.00 1 wt% to 0. 0 1 wt%) Na of 0.00 1 wt% to 0. 0 2 mass 0/0 (preferably 0.005 mass % to 0. 01 wt 0/0) may contain one or more of the C a of, there are refining effect of the eutectic S i, preferred.
タンディッシュ 250内に貯留された合金溶湯 255の液面レベル 254の 高さと筒状铸型 20 1の内壁面 2 21における上面との高さの差を Omm〜 25 Omm より好ましくは 5 Οιηπ!〜 1 7 Ommとする。 両者に差を持たせること により、 筒型錡型 201内に供給される合金溶湯 25 5の圧力と潤滑油及び潤滑 油が気化したガスとが好適にバランスする為、 铸造性が安定し、 アルミニウム合 金連続鐯造棒を容易に製造できるからである。 合金溶湯 25 5の液面レベル 25 4の高さを測定し、 モニターする為のレベルセンサーをタンディッシュ 250に 設けることにより、精度良くこの差を管理して所定の値に維持することができる。 The difference between the height of the liquid level 254 of the molten alloy stored in the tundish 250 and the height of the top surface of the inner wall surface 21 of the cylindrical saddle 20 1 is more preferably 5 Οιηπ! ~ 17 Omm. By providing a difference between the two, the pressure of the molten alloy 255 supplied to the cylindrical saddle mold 201 and the lubricating oil and the gas from which the lubricating oil has been vaporized are suitably balanced. This is because it is possible to easily produce a continuous alloy forged bar. By providing the tundish 250 with a level sensor for measuring and monitoring the height of the liquid level 254 of the molten alloy 255, this difference can be accurately controlled and maintained at a predetermined value.
液体潤滑剤は、潤滑油である植物油を用いることができる。例えば、菜種油、 ひまし油、 サラダ油を挙げることができる。 これらは環境への悪影響が小さいの で好ましい。 As the liquid lubricant, vegetable oil which is a lubricating oil can be used. For example, rapeseed oil, castor oil, salad oil can be mentioned. These are less harmful to the environment Is preferable.
潤滑油供給量は 0. 0 5 (mL/m i r!) 〜 5 (mL/m i n) 〔より好まし くは 0. 1 (mL/m i n) 〜l (m L i n )〕 であるのが好ましい。 供給量 が過少だと潤滑不足によって铸塊のブレークァゥトが発生し、 .過多だと余剰分が 铸塊中に混入して結晶粒径分布の均一性を妨げる恐れがある為である。 The amount of the lubricating oil supplied is preferably 0.05 (mL / m i r!) To 5 (mL / m i n) [more preferably 0.1 (mL / m i n) to l (m L i n)]. If the supply amount is too small, the breakthrough of the lump will occur due to insufficient lubrication, and if it is excessive, the excess may be mixed in the lump and hinder the uniformity of the grain size distribution.
筒状鍩型 2 0 1から凝固铸塊 2 1 6を引き抜く速度である錄造速度は 3 0 0 (mm/m i n) 〜 2 0 0 0 (mm/m i n) 〔より好ましくは 6 00 {m /m i n) 〜 20 00 (mm/m i n)〕 であるのが好ましい。 铸造で形成される晶出 物のネットワーク組織が均一微細となり、 高温下でのアルミニウム生地の変形に 対する抵抗が増し、 高温機械的強度が向上する為に好ましい。 勿論、 本発明の作 用効果は铸造速度に限定されないが、 铸造速度を速く したときにその効果が顕著 になる。 The forging speed, which is the speed for pulling the solidified lumps 2 1 6 from the cylindrical mold 2 0 1, is 3 0 0 (mm / min) to 2 0 0 0 (mm / min) [more preferably 6 00 (m / min) to 20 00 (mm / min)]. This is preferable because the network structure of the crystallized product formed by forging becomes uniform and fine, resistance to deformation of the aluminum fabric at high temperatures increases, and high-temperature mechanical strength improves. Of course, the working effect of the present invention is not limited to the forging speed, but the effect becomes remarkable when the forging speed is increased.
冷却水シャワー装置 20 5から放出される冷却水量は铸型当り 5 (L/m i n) 〜 3 0 (LZm i n) 〔より好ましくは 2 5 (L/m i n) 〜 3 0 (L/m i n)〕 であるのが好ましい。冷却水量が過少だとブレークァゥトが生じたり、凝固 铸塊 2 1 6の表面が再溶融して不均一な組織が形成され、 結晶粒径分布の均一性 を妨げる恐れがある。 一方、 冷却水量が過多だと筒状铸型 20 1の抜熱が大き過 ぎて铸造不可になる為である。 勿論、 本発明の作用効果は冷却水量に限定されな いが、 冷却能を大きくして凝固界面から筒状铸型 20 1内への温度勾配を大きく したときにその効果が顕著になる。 The amount of cooling water discharged from the cooling water shower device 20 5 is 5 (L / min) to 30 (LZmin) per mold (more preferably 25 (L / min) to 30 (L / min)). Preferably there is. If the amount of cooling water is too small, breakout may occur or the surface of the solidified lumps 2 16 may be remelted to form a non-uniform structure, hindering the uniformity of the crystal grain size distribution. On the other hand, if the amount of cooling water is excessive, the heat removal of the cylindrical saddle 201 will be so large that it becomes impossible to forge. Of course, the effect of the present invention is not limited to the amount of cooling water, but the effect becomes remarkable when the cooling ability is increased to increase the temperature gradient from the solidification interface into the cylindrical saddle 201.
タンディッシュ 2 5 0内から筒状鎵型 2 0 1へ流入する合金溶湯 2 5 5の平 均温度は液相線 + 40°C〜+ 2 3 0°C (より好ましくは液相線 + 6 0°C〜十 20 0°C) であるのが好ましい。 合金溶湯 2 5 5の温度が低すぎると筒状铸型 2 0 1 及ぴそれ以前で粗大な晶出物を形成して結晶粒径分布の均一性を妨げる恐れがあ る。 一方、 合金溶湯 2 5 5の温度が高すぎると合金溶湯 2 5 5中に大量の水素ガ スが取り込まれ、 凝固铸塊 2 1 6中にポロシティ一として取り込まれ、 結晶粒径 分布の均一性を妨げる恐れがあるからである。 The average temperature of the molten alloy 2 5 5 flowing from the tundish 2 5 0 into the cylindrical bowl 2 0 1 is the liquidus + 40 ° C to + 2 3 0 ° C (more preferably the liquidus + 6 0 ° C to 1020 ° C) is preferable. If the temperature of the molten alloy 2 55 is too low, a coarse crystallized product may be formed before and after the cylindrical saddle mold 20 1, which may hinder the uniformity of the crystal grain size distribution. On the other hand, if the temperature of the molten alloy 2 5 5 is too high, a large amount of hydrogen gas will be contained in the molten alloy 2 5 5. This is because the slag is taken in as a single porosity in the solidified lumps 2 1 6 and may hinder the uniformity of the crystal grain size distribution.
本発明では、 これらの铸造条件は、 铸造品の組織の共晶 S iや金属間化合物 がほとんど凝集球状化せず、 連続铸造時に形成された晶出物のネットワーク組織 又は針状晶出物又は晶出物の集合体となるように制御されるので、 この後の各熱 処理の効果が有効に発揮され、 好ましい。 In the present invention, these forging conditions are such that the eutectic Si or intermetallic compound of the structure of the forged product is hardly agglomerated and spheroidized, and the network structure of the crystallized product formed during continuous forging or the needle-like crystallized product or Since it is controlled so as to be an aggregate of crystallized substances, the effect of each subsequent heat treatment is effectively exhibited, which is preferable.
本発明では、 錡造後の铸造棒は、 素材として鍛造成形工程に投入する前に前 熱処理として一 1 0 °C〜4 8 0 °C (好ましくは一 1 0 °C〜 3 7 0 °C) に 2時間〜 6時間保持することが肝要である。 温度条件は室温であるのがより好ましいが、 それ以下であってもその効果を得ることができる。 In the present invention, the forged rod after forging is used as a pre-heat treatment at a temperature of 110 ° C. to 48 ° C. (preferably 110 ° C. to 37 ° C. It is important to hold for 2 to 6 hours. The temperature condition is more preferably room temperature, but the effect can be obtained even if the temperature is less than that.
前熱処理を上記のようにすると、 組織において連続铸造時に形成された晶出 物のネットワーク組織又は針状晶出物又は晶出物の集合体が成形 ·熱処理後にも 部分的に残留するアルミニゥム成形品となり、 これらの形状の晶出物が高温下で のアルミニウム生地の変形に対する抵抗として働き、 その結果、 2 5 0 °C〜4 0 0 °Cの高温時であっても優れた機械的強度が得られる。 即ち、 アルミニウム生地 が軟化する高温下で晶出物のネットワーク組織又は針状晶出物又は晶出物の集合 体が変形に対する抵抗となる為、 高温機械的強度に優れたアルミニウム成形品と なる。 一方、 前熱処理温度が高く、 成形率が高いと晶出物のネットワーク組織又 は針状晶出物又は晶出物の集合体が分断され、 粒状に凝集し、 晶出物が高温下で 軟化したアルミニウム生地中に均一に分散している状態となる。 この為、 高温下 でのアルミニウム生地の変形に対する晶出物の抵抗力が低下し、 高温機械的強度 も上げられなくなる。 When the pre-heat treatment is performed as described above, a network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed during continuous forging in a structure is formed and an aluminum molded article partially remaining after heat treatment. Thus, the crystallized material of these shapes acts as a resistance to deformation of the aluminum fabric at high temperatures, and as a result, excellent mechanical strength is obtained even at high temperatures of 250 ° C to 400 ° C. can get. That is, since the network structure of the crystallized material or the acicular crystallized material or the aggregate of crystallized materials becomes resistant to deformation at a high temperature at which the aluminum fabric is softened, the aluminum molded product is excellent in high-temperature mechanical strength. On the other hand, if the pre-heat treatment temperature is high and the forming ratio is high, the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product is divided and aggregated into particles, and the crystallized product is softened at high temperature. It will be in the state disperse | distributed uniformly in the finished aluminum cloth. For this reason, the resistance of the crystallized material to the deformation of the aluminum dough at high temperatures is reduced, and the high temperature mechanical strength cannot be increased.
本発明は、 前述した合金組成であって、 アルミニウム生地が軟化し、 非常に 変形しやすくなる 2 5 0 °C〜4 0 0 °Cの更なる高温域でアルミニウム生地の変形 に抵抗する晶出物のネットワーク組織や針状組織や集合体を部分的に残留させる ことによって高温機械的強度を高めているものである。 The present invention has the alloy composition described above, and the aluminum base material softens and becomes very deformable. Crystallization that resists deformation of the aluminum base material at a further high temperature range of 250 ° C. to 400 ° C. Partially leave a network structure, needle-like structure or aggregate of things This increases the high-temperature mechanical strength.
晶出物のネットワークや針状組織があまり見られない比較的晶出物の少ない 低濃度合金である 6 0 0 0系合金などで、均質化処理を抑制したり省略する場合、 それは再結晶の抑制や工程の簡素化を図るものであり、 本発明のような晶出物が 多く、 铸造時にネットワークや針状組織が見られる高 S i系合金で、 ネットヮー クや針状組織をなるべく維持して高温の改良を図るものとは異なる。 If the homogenization treatment is suppressed or omitted, such as a low-concentration alloy with a relatively low crystallized content, such as a network of crystallized products and a relatively small amount of crystallized material, it is difficult to recrystallize. This is a high Si-based alloy that has many crystallized materials as in the present invention and has a network and a needle-like structure that can be seen during fabrication, and maintains the network and needle-like structure as much as possible. Therefore, it is different from those for improving the temperature.
上記の背景技術の欄で述べたように、 特許文献 1 (特開 2 0 0 2— 2 9 4 3 8 3号公報) に開示されているものは、 6 0 0 0系合金に関するものであり、 均 質化処理の温度を抑制したり省略しているのは、 高温特性を得る為ではなく、 再 結晶を抑制して常温の機械的特性を改良する為である。もともと合金系も異なり、 比較的晶出物の少ない低濃度合金で、 晶出物のネットワーク組織や針状組織はあ まり見られない。 均質化処理を低温化し抑制することで、 再結晶を抑制する A 1 — M n系、 1ー〇で系化合物を、 微細に析出させる為のものである。 本発明の ような晶出物が多く、 铸造時にネットワーク組織や針状組織が見られる高 S i系 合金で、 ネットワーク組織や針状組織をなるベく維持して高温の改良を図るもの とは異なっている。 As described in the background section above, what is disclosed in Patent Document 1 (Japanese Patent Laid-Open No. 2 0 0 2-2 9 4 3 8 3) relates to a 6 0 0 0 series alloy. The reason for suppressing or omitting the temperature of the homogenization treatment is not to obtain high temperature characteristics, but to suppress recrystallization and improve mechanical properties at room temperature. Originally, the alloy system is different, and it is a low-concentration alloy with relatively few crystallized substances, and the network structure and needle-like structure of the crystallized substances are hardly seen. By controlling the homogenization process at a low temperature, it suppresses recrystallization. A 1 — M n system, 1–O is used to precipitate system compounds finely. It is a high Si system alloy with many crystallized materials as in the present invention, and a network structure and needle-like structure can be seen at the time of fabrication, and it is intended to improve the high temperature by maintaining the network structure and needle-like structure. Is different.
特に、 素材の高温機械的強度を高め、 鍛造性を向上させる場合には、 前熱処 理の保持温度が 2 0 0 °C〜3 7 0 °Cであることが好ましい。 この温度範囲にする と前熱処理時の共晶 S iや金属間化合物の凝集球状化が進み難く、 連続铸造時に 形成された晶出物のネットワーク組織又は針状晶出物又は晶出物の集合体が鍛造 成形、 後熱処理後でも部分的に残存しており、 高温機械的強度に優れたアルミ二 ゥム成形品となる。 In particular, when increasing the high-temperature mechanical strength of the material and improving the forgeability, it is preferable that the holding temperature of the preheating treatment is 20 ° C. to 3700 ° C. Within this temperature range, eutectic Si and intermetallic compounds during the pre-heat treatment are less likely to agglomerate and spheroidize, and a network structure of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed during continuous fabrication. The body remains partially after forging and post-heat treatment, resulting in an aluminum molded product with excellent high-temperature mechanical strength.
又、 特に、 素材の高温機械的強度をより高める場合には、 前熱処理の保持温 度が一 1 0 °C〜 2 0 0 °Cであることが好ましい。 この温度範囲にすると前熱処理 時の共晶 S iや金属間化合物がほとんど凝集球状化せず、 連続铸造時に形成され た晶出物のネットワーク組織又は針状晶出物又は晶出物の集合体が鍛造成形、 後 熱処理後でも部分的に残存しており、 高温機械的強度に優れたアルミニウム成形 品となる。 In particular, when the high-temperature mechanical strength of the material is further increased, the holding temperature of the pre-heat treatment is preferably 10 ° C. to 200 ° C. Within this temperature range, eutectic Si and intermetallic compounds during pre-heat treatment hardly form agglomerated spheroids and are formed during continuous fabrication. The network structure of the crystallized product or the acicular crystallized product or the aggregate of the crystallized product partially remains even after forging and post-heat treatment, resulting in an aluminum molded product having excellent high-temperature mechanical strength.
更に、 素材の鍛造成形性をより高める場合には、 前熱処理の保持温度が 3 7 0 °C~ 4 8 0 °Cであることが好ましい。 この温度範囲にすると前熱処理時の共晶 S iや金属間化合物がある程度凝集球状化し、 铸造時の変形抵抗が低下する為、 鍛造成形性に優れたアルミェゥム成形品となる。 かつ、 この温度範囲では、 連続 鍛造時に形成された晶出物のネットワーク組織又は針状晶出物又は晶出物の集合 体が鍛造成形、 後熱処理後でも部分的に残存しており、 高温機械的性質に優れた アルミ-ゥム成形品が得られる。 Furthermore, in order to further improve the forging formability of the material, it is preferable that the holding temperature of the pre-heat treatment is 370 ° C. to 48 ° C. Within this temperature range, the eutectic Si and the intermetallic compound during the pre-heat treatment are agglomerated to some extent and the deformation resistance during forging is reduced, so that an aluminum molded product with excellent forging formability is obtained. In this temperature range, the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product formed during continuous forging partially remains after forging and post-heat treatment. Aluminum molded products with excellent mechanical properties can be obtained.
前熱処理工程は、 铸造後から鍛造工程の間に設ければ良く、 例えば、 铸造後 The pre-heat treatment process may be provided between the forging process after forging. For example, after forging
1日以内に処理する、 又は処理後 1週間以内に鍛造工程に投入すれば良い。 その 間に矯正処理、 ピーリング処理を施すことができる。 It can be processed within one day or put into the forging process within one week after processing. In the meantime, correction and peeling can be performed.
次に、 本発明に含まれる鍛造工程の一例を説明する。 1 ) 連続铸造丸棒を所 定の長さに切断する工程と、 2 ) 切断した素材を予備加熱して据え込みする工程 と、 3 ) 据え込んだ素材を潤滑する工程と、 4 ) 素材を金型に投入して鍛造成形 する工程と、 5 ) ノックアウト機構により鍛造製品を金型内から排出する工程と を含む製造方法である。 Next, an example of the forging process included in the present invention will be described. 1) a process of cutting a continuous forged round bar to a predetermined length; 2) a process of preheating the cut material; 3) a process of lubricating the installed material; 4) The manufacturing method includes a step of forging into a mold and forging and 5) a step of discharging a forged product from the mold by a knockout mechanism.
鍛造用素材に潤滑剤を塗布し、 更に据え込み処理の投入前に加熱しておくこ ともできる。 尚、 据え込み工程を省略することができる。 Lubricant can be applied to the forging material and heated before the upsetting process. The upsetting process can be omitted.
潤滑剤処理は水溶性潤滑剤の塗布、 又はポンデ処理とすることができる。 例 えば、 素材にボンデ処理を施した後、 予備加熱として 3 8 0 °C〜4 8 0 °Cに加熱 して鍛造装置に投入するのが好ましい。 3 8 0 °C〜4 8 0 °Cに予備加熱すると、 素材の変形態が向上し、 複雑な形状に成形するのが容易になる。 Lubricant treatment may be water-soluble lubricant application or ponde treatment. For example, it is preferable that after the material is subjected to a bondage treatment, it is heated to 3880 ° C. to 480 ° C. as a preheating and then put into a forging device. When preheated to 3800 ° C to 4800 ° C, the deformation of the material is improved and it becomes easy to form a complex shape.
潤滑剤として水性潤滑剤が好ましく、 水溶性黒鉛潤滑剤を用いるのがより好 ましい。 黒鉛が素材に良く焼き付くからである。 この場合、 例えば、 7 0 °C〜3 5 0 °Cの素材に潤滑剤を塗布した後、 素材を常温に冷ました後 (例えば、 2時間 〜4時間保持した後)、素材を 3 8 0 °C〜4 8 0 °Cに加熱して鍛造装置に投入する のが好ましい。 潤滑剤として水性潤滑剤が好ましく、 水溶性黒鉛潤滑剤を用いる のがより好ましい。 黒^^が素材に良く焼き付くからである。 A water-based lubricant is preferred as the lubricant, and a water-soluble graphite lubricant is more preferred. Good. This is because graphite is well baked on the material. In this case, for example, after applying a lubricant to a material at 70 ° C. to 35 ° C., after cooling the material to room temperature (for example, holding for 2 hours to 4 hours), It is preferable to heat to 480C to 480 ° C and put into a forging device. A water-based lubricant is preferable as the lubricant, and a water-soluble graphite lubricant is more preferably used. This is because black ^^ sticks well to the material.
素材を投入する前に、 金型表面へ潤滑剤を塗布する。 潤滑剤量はスプレーの 吹き付け時間を調整することで、 上金型とダイスの組み合わせに合わせてより適 切な状態にすることができる。 潤滑剤として油性潤滑剤を用いるのが好ましい。 例えば、 鉱物油を用いることができる。 水性潤滑油では金型温度が下がることが あるが、 それを抑えることができるからである。 油性潤滑剤が黒鉛と鉱物油混合 物であるのが潤滑効果が高まるのでより好ましい。 Apply lubricant to the mold surface before loading the material. The amount of lubricant can be adjusted to a more appropriate state according to the combination of the upper mold and the die by adjusting the spraying time. It is preferable to use an oil-based lubricant as the lubricant. For example, mineral oil can be used. This is because water-based lubricants can lower the mold temperature, but this can be suppressed. It is more preferable that the oil-based lubricant is a mixture of graphite and mineral oil because the lubricating effect is enhanced.
金型の加熱温度は 1 5 0 °C〜2 5 0 °Cとするのが好ましい。 充分な塑性流動 を得ることができるからである。 The heating temperature of the mold is preferably 1550 ° C to 2500 ° C. This is because sufficient plastic flow can be obtained.
本発明では、 鍛造成形における、 耐高温疲労強度の要求される部位の加工率 が 9 0 %以下 (好ましくは 7 0 %以下) であることが好ましい。 この加工率以下 にすると晶出物のネットワーク組織又は針状晶出物又は晶出物の集合体の分断を 抑制し、 高温機械的強度に優れた成形品となる。 In the present invention, it is preferable that the processing rate of the portion requiring high temperature fatigue strength in forging is 90% or less (preferably 70% or less). Below this processing rate, the network structure of crystallized matter or acicular crystallized product or aggregate of crystallized product is suppressed, and a molded product having excellent high-temperature mechanical strength is obtained.
尚、 成形品において、 高温機械的強度が要求される部位がこの加工率を満た していれば良い。 In the molded product, it is sufficient that the portion requiring high-temperature mechanical strength satisfies this processing rate.
尚、 鍛造前に据え込み工程などの塑性加工が施された場合は、 加工率はそれ らのトータルとして考えるのが好ましい。 例えば、 複雑な形状を有する成形品の 場合、 1回の加工当たりの加工率が 1 0。/。〜 8 0 % (より好ましくは 1 0 %〜 5 0 %) で、複数回 (好ましくは 2回) とするのが好ましい。例えば、 1回目 1 0 % 〜5 0 % (より好ましくは 1 0 %〜3 0 %) とするのが好ましい。 If plastic working such as an upsetting process is performed before forging, it is preferable to consider the processing rate as the total of these. For example, in the case of a molded product having a complicated shape, the processing rate per processing is 10. /. It is preferable to set it to multiple times (preferably twice) at ˜80% (more preferably from 10% to 50%). For example, the first time is preferably 10% to 50% (more preferably 10% to 30%).
ここで加工率とは、 次のように定義する。 加工率 = (塑性加工前の厚さー塑性加工後の厚さ) / (塑性加工前の厚さ) X 1 00 % Here, the processing rate is defined as follows. Machining rate = (Thickness before plastic working-Thickness after plastic working) / (Thickness before plastic working) X 1 00%
鍛造済品に後熱処理を施す。 後熱処理としては、 溶体化処理、 時効処理を組 み合わせて用いることができる。 後熱処理は、 加工後 1週間以内とすることがで きる。 Post-heat treatment is applied to the forged product. As the post heat treatment, a solution treatment and an aging treatment can be used in combination. Post heat treatment can be done within one week after processing.
具体的には、例えば、 480°C〜5 20°C (好ましくは 490°C〜5 1 0°C) で 3時間保持の条件で、 鍛造済品を溶体化処理することができる。 Specifically, the forged product can be subjected to a solution treatment, for example, under the condition of holding at 480 ° C to 520 ° C (preferably 490 ° C to 510 ° C) for 3 hours.
上記以外の後熱処理として、 J I S規格の T 5熱処理或いは T 6熱処理を鍛 造済品に対して施すことができる。 As post-heat treatment other than the above, forged products can be subjected to J IS standard T5 heat treatment or T6 heat treatment.
本発明では、 取り出した鍛造製品を溶体化、 焼入れを施すことなく、 時効処 理として 1 70 °C〜 230 °C (好ましくは 1 90 °C〜 220°C) に 1時間〜 10 時間保持することが好ましい。 晶出物ネットワーク又は針状晶出物又は晶出物の 集合体の分断、 凝集を抑えることができ、 高温機械的強度に優れた成形品となる ので好ましい。 In the present invention, the forged product taken out is not subjected to solution solution and quenching, but is maintained at 1 70 ° C to 230 ° C (preferably 190 ° C to 220 ° C) for 1 hour to 10 hours as an aging treatment. It is preferable. This is preferable because the crystallized product network, the acicular crystallized product, or the aggregate of crystallized product can be prevented from being divided and agglomerated, and the molded product has excellent high-temperature mechanical strength.
このような方法で製造された、 成形品の合金組織は、 共晶 S iや金属間化合 物の凝集球状化が進み難く、 連続铸造に形成された晶出物のネットワーク組織又 は^ "状晶出物又は晶出物の集合体が鍛造成形、 後熱処理後でも部分的に残存して おり、 高温機械的強度に優れたアルミニゥム成形品となる。 The alloy structure of the molded product produced by such a method is difficult to progress in the aggregation and spheroidization of eutectic Si and intermetallic compounds, and the crystal structure or ^ " A crystallized product or an aggregate of crystallized products partially remains even after forging and post-heat treatment, resulting in an aluminum molded product having excellent high-temperature mechanical strength.
又、 合金組成は、 1 0. 5質量%〜1 3. 5質量% (好ましくは 1 1. 5質 量%〜1 3質量0 /0) の S i、 2. 5質量%〜6質量% (好ましくは 3. 5質量% 〜5. 5質量%) の Cu、 0. 3質量%〜1. 5質量% (好ましくは 0. 5質量% 〜1. 3質量%) の Mg、 0. 8質量%〜4質量0 /0 (好ましくは 1. 8質量0/。〜 3. 5質量%) の N iを含み、 かつ N i (質量。 /0) ≥ 〔ー0. 68 11 (質量%) + AA (質量%)〕 (伹し、 AAは定数であって、 AA 4. 2。 好ましくは AA ≥4. 7ο) なる関係式を満足するアルミユウム合金である。 合金組成は、 0. 1質量%〜1質量% (好ましくは 0. 2質量%〜0. 5質 量%) の Mn、 0. 05質量%〜0. 5質量% (好ましくは 0. 1質量%〜0. 3質量%) の C r、 0. 04質量°/0〜0. 3質量% (好ましくは 0. 1質量%〜 0. 2質量0 /0) の Z r、 0. 0 1質量%〜0. 1 5質量0 /0 (好ましくは 0. 0 5 質量%〜0. 1質量%) の V、 0. 01質量%〜0. 2質量% (好ましくは 0. 02質量%〜0. 1質量%) の T iの内の 1種又は 2種以上を含有することが好 ましい。 Moreover, the alloy composition is, S i of 1 0.5 wt% to 1 3.5% by weight (preferably 1 1.5 mass% to 1 3 mass 0/0), 2.5 wt% to 6 wt% (Preferably 3.5 wt% to 5.5 wt%) Cu, 0.3 wt% to 1.5 wt% (preferably 0.5 wt% to 1.3 wt%) Mg, 0.8 wt% to 4 wt 0/0 (preferably 1.8 mass 0 /.~ 3.5 wt%) a N i of, and N i (mass. / 0) ≥ [chromatography 0.68 11 (wt% ) + AA (mass%)] (Also, AA is a constant, and is an aluminum alloy satisfying the relational expression AA 4.2. AA ≥ 4.7 7). The alloy composition is 0.1 mass% to 1 mass% (preferably 0.2 mass% to 0.5 mass%) of Mn, 0.05 mass% to 0.5 mass% (preferably 0.1 mass%). % ~0. C r of 3 wt%), 0.04 wt ° / 0 ~0. Z r of 3 mass% (preferably 0.1% to 0.2 mass 0/0), 0.0 1 mass% to 0. 1 5 mass 0/0 (preferably 0.0 5 wt% to 0. 1 wt%) V of 0.01 mass% to 0. 2% by weight (preferably 0.02% to It is preferable to contain one or more of 0.1 mass% Ti.
更に、 F eを 0. 1 5質量。/ 0〜0. 6 5質量% (好ましくは 0. 3質量%〜 0. 5質量。 /0) 含むことが好ましい。 Furthermore, Fe 0.15 mass. / 0 to 0.6 5% by mass (preferably 0.3% to 0.5% by mass) / 0 is preferable.
又、 Pを 0. 003質量°/0〜0. 02質量% (好ましくは 0. 00 7質量°/0 Further, P is set to 0.003 mass ° / 0 to 0.02 mass% (preferably 0.007 mass ° / 0.
〜0. 0 16質量%) 含むことが好ましい。 ~ 0.016% by mass).
又、 0. 003質量%〜0. 03質量% (好ましくは 0. 01質量%〜0. 02質量0 /0)の S r、 0. 1質量%〜 0. 35質量0 /0 (好ましくは 0. 1 5質量% 〜0. 25質量%) の S b、 0. 0005質量%〜0. 01 5質量% (好ましく は 0. 001質量%〜0. 0 1質量0/。) の Na、 0. 00 1質量%〜0. 02質 量0 /0 (好ましくは 0. 005質量%〜0. 01質量%) の C aの内の 1種又は 2 種以上を含有することが、 共晶 S iの微細化効果があり、 好ましい。 Further, 0.003 wt% to 0. 03 wt% (preferably 0.01 mass% to 0. 02 wt 0/0) S r of 0.1% to 0.35 mass 0/0 (preferably 0.1 5 wt% to 0. S b of 25 wt%), 0.0005 wt% to 0. 01 5 wt% (preferably 0.001 wt% to 0. 0 1 weight 0 /.) of Na, 0.00 1 wt% to 0. 02 mass 0/0 (preferably 0.005 wt% to 0. 01 wt%) may contain one or more of the C a of the eutectic There is an effect of miniaturizing Si, which is preferable.
(実施例) (Example)
以下、 実施例により、 本発明を具体的に説明するが、 本発明はこれらの実施 例に限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples.
(実施例 1〜 16 ) (Examples 1 to 16)
〔製造条件〕 [Production conditions]
第: LI1に示す生産システムを用いて、 表 1に示す実施例 1〜1 6及ぴ表 2に 示す比較例 1〜10のアルミニウム合金成形品を製造した。 アルミニウム合金の組成(質量%) 疲労強度応力 均質化 (単位: MPa) 微 据込 後熱処理 No .: Using the production system shown in LI1, aluminum alloy molded articles of Examples 1 to 16 shown in Table 1 and Comparative Examples 1 to 10 shown in Table 2 were produced. Aluminum alloy composition (mass%) Fatigue strength stress Homogenization (Unit: MPa) Fine heat treatment after upsetting
処理温度 AA値 Processing temperature AA value
加工率 (丁 6 Machining rate (Ding 6
(°C) , T5) (° C), T5)
Si Fe Cu Mn Mg i Ti P Sr 温度条件温度条件 Si Fe Cu Mn Mg i Ti P Sr Temperature conditions Temperature conditions
300°C 350°C 300 ° C 350 ° C
実施例 1 370 50% 丁 6 10.5 0.25 2.7 一 0.95 3.8 ― ― 0.015 60 45 5.64 実施例 2 370 50% 丁 6 10.5 0.25 2.7 ― 0.95 3.8 ― 0.015 ― 59 44 5.64 実施例 3 370 50% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 ― 59 43 5.04 実施例 4 370 50% T5 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 一 62 44 5.04 実施例 5 370 50% T6 11.8 0.33 3.2 ― 0.72 2.2 ― 0.005 ― 54 39 4.38 実施例 6 370 50% T6 12.8 0.25 3.8 ― 0.95 1.8 ― 0.018 ― 53 38 4.38 実施例 7 370 50% T6 13.4 0.25 4.1 ― 1.10 2.2 ― 0.018 ― 57 43 4.99 実施例 8 370 50% 丁 6 13.4 0.61 4.1 0.32 1.21 2.2 一 0.010 ― 58 43 4.99 実施例 9 200以下 50% T6 13.4 0.61 4.1 0.32 1.21 2.2 ― 0.010 一 59 44 4.99 実施例 1 0 370 50% T6 12.8 0.48 4.5 0.23 0.95 1.5 0.075 0.018 ― 55 40 4.56 実施例" 370 50% 丁 6 12.5 0.28 5.1 0.21 1.14 1.1 ― 0.007 一 55 39 4.57 実施例 1 2 370 50% T6 12.8 0.25 5.5 ― 0.95 1.0 一 0.018 ― 57 43 4.74 実施例 1 3 370 50% 丁 6 12.8 0.48 5.5 0.23 0.95 1.0 0.075 0.018 ― 58 44 4.74 実施例 1 4 370 50% T6 10.5 0.25 5.7 一 0.95 3.5 ― 0.010 一 62 47 7.38 実施例 1 5 370 88% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 一 58 41 5.04 実施例 1 6 470 50% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 一 58 41 5.04 Example 1 370 50% Ding 6 10.5 0.25 2.7 One 0.95 3.8 ― ― 0.015 60 45 5.64 Example 2 370 50% Ding 6 10.5 0.25 2.7 ― 0.95 3.8 ― 0.015 ― 59 44 5.64 Example 3 370 50% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 ― 59 43 5.04 Example 4 370 50% T5 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 One 62 44 5.04 Example 5 370 50% T6 11.8 0.33 3.2 ― 0.72 2.2 ― 0.005 ― 54 39 4.38 Example 6 370 50% T6 12.8 0.25 3.8 ― 0.95 1.8 ― 0.018 ― 53 38 4.38 Example 7 370 50% T6 13.4 0.25 4.1 ― 1.10 2.2 ― 0.018 ― 57 43 4.99 Example 8 370 50% Ding 6 13.4 0.61 4.1 0.32 1.21 2.2 One 0.010 ― 58 43 4.99 Example 9 200 or less 50% T6 13.4 0.61 4.1 0.32 1.21 2.2 ― 0.010 One 59 44 4.99 Example 1 0 370 50% T6 12.8 0.48 4.5 0.23 0.95 1.5 0.075 0.018 ― 55 40 4.56 Example '' 370 50 % Ding 6 12.5 0.28 5.1 0.21 1.14 1.1 ― 0.007 One 55 39 4.57 Example 1 2 370 50% T6 12.8 0.25 5.5 ― 0.95 1.0 One 0.018 ― 57 43 4.74 Example 1 3 370 50% Ding 6 12.8 0.48 5.5 0.23 0.95 1.0 0.075 0.018 ― 58 44 4.74 Example 1 4 370 50% T6 10.5 0.25 5.7 One 0.95 3.5 ― 0.010 One 62 47 7.38 Example 1 5 370 88% T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 One 58 41 5.04 Example 1 6 470 50 % T6 12.8 0.48 3.0 0.23 0.95 3.0 0.075 0.018 One 58 41 5.04
¾2 該生産システムを構成する連続錡造装置 8 1として、 第 5図に示すホット ト ップ連続鎊造機を用いて、 表 1に示す組成を有する実施例 1〜1 6及び表 2に示 す比較例 1〜1 0のアルミニウム合金の 8 5 φ (mm) の連続鏡造丸棒をそれぞ れ铸造した。 上記ホットトップ連続鑤造機は、 気体加圧ホットトップ铸造法を用 いた铸造機であって、 ヘッダーと鎵型とのクリアランスに気体及び潤滑油を導入 し、 铸型内に供給される合金溶湯の圧力と潤滑油及び潤滑油が気化したガスとが 好適にバランスするように構成されている。 この構成によって、 アルミニウム溶 湯が铸型と接触する領域が狭くなるため、 合金溶湯を冷却水による急冷凝固する ことができ、 安定的にアルミ-ゥム合金連続铸造棒を铸造できる。 ' ¾2 As the continuous forging device 8 1 constituting the production system, the hot top continuous forging machine shown in FIG. 5 was used, and the comparisons shown in Examples 1 to 16 and Table 2 having the compositions shown in Table 1 were made. Examples 1 to 10 Aluminum alloy round bars of 85 mm (mm) were fabricated respectively. The above hot top continuous forging machine is a forging machine using the gas pressure hot top forging method, in which gas and lubricating oil are introduced into the clearance between the header and the mold, and the molten alloy supplied into the mold is made of The pressure and the lubricating oil and the gas from which the lubricating oil is vaporized are suitably balanced. With this configuration, the area where the molten aluminum comes into contact with the mold becomes narrow, so that the molten alloy can be rapidly cooled and solidified with cooling water, and an aluminum alloy continuous forged rod can be stably produced. '
次いで、 前熱処理工程として、 各連続铸造丸棒に対して表 1及び表 2に示す 温度で均質化処理を行った。 各連続錄造丸棒は、 2 0 mm、 又は 8 O mmの厚さ に切断されて、 鍛造用素材とした。 次いで、 該鍛造用素材を 4 2 0 °Cに予備加熱 した後、 表 1及び表 2に示す所定の据え込み加工率で据え込み工程を行い、 所定 の形状に塑性加工した。 Next, as a pre-heat treatment step, each continuous forged round bar was homogenized at the temperatures shown in Tables 1 and 2. Each continuous forged round bar was cut to a thickness of 20 mm or 8 O mm to obtain a forging material. Next, the forging material was preheated to 4220 ° C., and then an upsetting process was performed at predetermined upsetting rates shown in Tables 1 and 2 to perform plastic processing into a predetermined shape.
尚、 実施例 5〜7、 1 0〜1 3に対し、 据込加工率を 5 5 %とした場合の割 れ発生率を評価した。 この評価結果を表 3に示す。 表 3中、 〇印及ぴ厶印は、 据 え込み工程による割れ発生率がそれぞれ 1 %未満及び 1 %以上であったことを示 す。 In Examples 5 to 7 and 10 to 13, the crack generation rate was evaluated when the upsetting rate was set to 55%. The evaluation results are shown in Table 3. In Table 3, the 〇 and 厶 marks indicate that the cracking rate during the installation process was less than 1% and 1% or more, respectively.
(表 3 ) 均質化 据込 アルミニウム合金中の含有量 (wt%) 割れ (Table 3) Homogenization Upset Content in aluminum alloy (wt%) Cracking
AA値 AA value
処理温度 (°c) 加工率 Cu Ni 発生率 実施例 5 370 55% 3.2 2.2 4.38 厶 実施例 6 370 55% 3.8 1.8 4.38 〇 実施例 7 370 55% 4.1 2.2 4.99 厶 実施例 1 0 370 55% 4.5 1.5 4.56 〇 実施例 1 1 370 55% 5.1 1.1 4.57 〇 実施例 1 2 370 55% 5.5 1.0 4.74 〇 実施例 1 3 370 55% 5.5 1.0 4.74 〇 その後、 塑性加工された上記素材に対して、 表 1及び表 2に示す所定の後熱 処理工程を行い、 上記各実施例及び上記各比較例をそれぞれ製造した。 Processing temperature (° c) Processing rate Cu Ni generation rate Example 5 370 55% 3.2 2.2 4.38 厶 Example 6 370 55% 3.8 1.8 4.38 〇 Example 7 370 55% 4.1 2.2 4.99 厶 Example 1 0 370 55% 4.5 1.5 4.56 Yes Example 1 1 370 55% 5.1 1.1 4.57 Yes Example 1 2 370 55% 5.5 1.0 4.74 Yes Example 1 3 370 55% 5.5 1.0 4.74 Yes Thereafter, predetermined post-heat treatment steps shown in Table 1 and Table 2 were performed on the plastically processed material, and the above Examples and Comparative Examples were respectively produced.
尚、 上記後熱処理工程は、 塑性加工品を水焼き入れし、 2 10°Cで 6時間保 持する T 5熱処理、 或いは、 塑性加工品を 500°Cで 2. 5時間保持後、 水焼き 入れし、 210°Cで 6時間保持する T 6熱処理のいずれかにより行われた。 In the post-heat treatment step, the plastic-processed product is water-quenched and held for 2 hours at 10 ° C. T5 heat treatment, or the plastic-processed product is held at 500 ° C for 2.5 hours and then water-baked. The heat treatment was performed by either T 6 heat treatment, which was put in and held at 210 ° C for 6 hours.
〔疲労強度評価〕 [Fatigue strength evaluation]
上記各実施例及び各比較例に対し、 次の方法により疲労強度を評価した。 各実施例及び各比較例から試験片を機械加工で製作し、 小野式回転曲げ疲労 試験機により、 試験片に 30.0°C或いは 350°Cで 100時間の予備加熱を施し た後に、 300°C及び 350°Cのそれぞれの環境下において、 試験片に対し疲労 強度を評価した。 1000万回の繰り返し応力を付与して、 破損しない応力を測 定した。 For each of the above examples and comparative examples, the fatigue strength was evaluated by the following method. Test pieces from each of the examples and comparative examples were manufactured by machining and pre-heated at 30.0 ° C or 350 ° C for 100 hours using an Ono-type rotary bending fatigue tester, then 300 ° C The fatigue strength of the specimen was evaluated in each environment at 350 ° C and 350 ° C. Stress that was not damaged was measured by applying 10 million cycles of stress.
各実施例及び各比較例における組成、 熱処理条件、 据込加工率、 疲労強度評 価結果及び N i (質量%) = 〔一 0. 68 XC u (質量%) +AA (質量。/。)〕 で 定義される関係式を満たす定数 A Aを表 1及び表 2に示す。 また、 各実施例及び 各比較例の組成中の N i と Cuの含有率の関係を第 6図に示す。 尚、 第 6図中、 実施例 1 ~ 14の各 A A値をそれぞれ S 1〜 S 14の符号で表し、 比較例 1〜 1 0 (比較例 6を除く。) の各八 値をそれぞれじ 1〜じ 10の符号で表した。 Composition, heat treatment conditions, upsetting rate, fatigue strength evaluation result and Ni (mass%) = [0.68 XC u (mass%) + AA (mass./.) In each example and comparative example. Tables 1 and 2 show the constants AA that satisfy the relational expression defined by Fig. 6 shows the relationship between the Ni and Cu contents in the compositions of the examples and comparative examples. In FIG. 6, the AA values of Examples 1 to 14 are represented by the symbols S 1 to S 14 respectively, and the eight values of Comparative Examples 1 to 10 (excluding Comparative Example 6) are respectively 1 It is represented by the sign of ~ 10.
実施例 1〜16は、 いずれも本発明の製造方法により製造されたものであつ て、 表 1から分かるように、 350°Cにおいて 33MP a以上の疲労強度を有す る。 このように、 本発明の製造方法により製造された実施例 1〜16は、 いずれ も目標とする疲労強度を有しているので、 高温時の機械的強度を要求される部品 に好適に使用することができる。 Examples 1 to 16 were all produced by the production method of the present invention and, as can be seen from Table 1, have a fatigue strength of 33 MPa or more at 350 ° C. Thus, since Examples 1 to 16 manufactured by the manufacturing method of the present invention all have a target fatigue strength, they are preferably used for parts that require mechanical strength at high temperatures. be able to.
本発明の製造方法において用いられるアルミニウム合金は、 N i及び C uの 含有量が第 6図中の A— B— C一 D— E— Aで囲まれる領域に含まれる組成を必 須とする。 The aluminum alloy used in the production method of the present invention must have a composition in which the Ni and Cu contents are included in the region surrounded by A—B—C and D—E—A in FIG. Let's say.
N i及び C uの含有量が D— E— H— I一 Dで囲まれる領域に含まれる実施 例 6、 実施例 1 0〜 1 3は、 表 3に示すように、 いずれも 5 5 %超の据込加工率 にて良好に加工することができる。 このように、 本発明において、 N iの含有量 が 2 . 0 w t %以下であって A A≥ 4 . 2となるように C uを含有するアルミ- ゥム合金を使用することが、 より好ましい。 Examples 6 and 10 in which the contents of Ni and Cu are included in the region surrounded by D—E—H—I and D are all 5 5% as shown in Table 3. It can be processed well at an ultra-upsetting rate. Thus, in the present invention, it is more preferable to use an aluminum alloy containing Cu such that the Ni content is 2.0 wt% or less and AA≥4.2. .
これに対して、 本発明の製造方法において定められる合金組成の範囲外の組 成を有する比較例 1〜5、 7〜1 0は、 表 2に示されるように、 いずれも目標と する疲労強度を有していなかった。 比較例 8及び 1 0は更に塑性加工性が劣り、 据込時に割れが発生した。 表 2に表示された" * 1 " は、 比較例の試験片を採取 できなかったことを示す。 尚、 比較例 1〜4の A A値は 4 . 2未満であった。 ま た、 本発明の製造方法において定められる温度範囲外の温度で前熱処理工程が施 された比較例 6も、 目標とする疲労強度を有していなかった。 In contrast, Comparative Examples 1 to 5 and 7 to 10 having compositions outside the range of the alloy composition defined in the manufacturing method of the present invention are all targeted fatigue strengths as shown in Table 2. Did not have. Comparative Examples 8 and 10 were further inferior in plastic workability, and cracks occurred during upsetting. The “* 1” displayed in Table 2 indicates that the comparative test specimen could not be collected. In addition, the A A value of Comparative Examples 1 to 4 was less than 4.2. Further, Comparative Example 6 in which the pre-heat treatment step was performed at a temperature outside the temperature range defined in the production method of the present invention did not have the target fatigue strength.
〔金属組織の評価〕 [Evaluation of metal structure]
表 1の各実施例及び表 2の各比較例の縦断面中央部から組織観察サンプルを 切り出し、 ミクロ研磨し、 ミクロ写真から晶出物のネットワーク組織を観察する ことにより、 各実施例及び各比較例の金属組織を評価した。 Each example and each comparison were made by cutting out the structure observation sample from the center of the longitudinal section of each Example in Table 1 and each Comparative Example in Table 2, micropolishing, and observing the network structure of the crystallized product from the microphotograph. Example metallographic structures were evaluated.
実施例の組織においては、 連続鎵造時に形成された晶出物のネットワーク耝 織又は針状晶出物又は晶出物の集合体が成形 ·熱処理後にも部分的に残留してい るのが確認できた。 In the structures of the examples, it was confirmed that the network texture of crystallized substances or acicular crystallized substances or aggregates of crystallized substances formed during continuous fabrication remained partially after molding and heat treatment. did it.
又、 実施例においては、 共晶 S iの面積占有率が 8 %以上、 共晶 S iの平均 粒径が 5 μ m以下、 共晶 S i針状比 1 . 4以上のものが 2 5 %以上、 金属間化合 物の面積占有率が 1 . 2 %以上、 金属間化合物の平均粒径が 1 . 5 μ m以上、 金 属間化合物の長さ又は接触する金属間化合物の集合体の長さが 3 μ m以上のもの が 3 0 %以上となっていた。 特に、 N i及び Cuを上記好適な濃度で含有する実施例 1 0及び 1 3は、 表 4に示すように、 いずれも、 共晶 S iの平均粒径が 2. 5 μπι以下であって、 共 晶 S i針状比 1. 4以上のものを 80 %程度有しており、 金属間化合物の集合体 の長さが 3 μηι以上のものを 90%程度有していることが分かる。 In the examples, the area occupancy of the eutectic S i is 8% or more, the average grain size of the eutectic S i is 5 μm or less, and the eutectic S i needle ratio is 2.4 or more. % Of the intermetallic compound is 1.2% or more, the average particle size of the intermetallic compound is 1.5 μm or more, the length of the intermetallic compound or the aggregate of the intermetallic compounds in contact Those with a length of 3 μm or more were 30% or more. In particular, in Examples 10 and 13 containing Ni and Cu at the above-mentioned preferable concentrations, as shown in Table 4, the average particle diameter of the eutectic Si is 2.5 μπι or less. It can be seen that about 80% of the eutectic Si needle-like ratio is 1.4 or more, and about 90% of the intermetallic compound aggregate length is 3 μηι or more.
また、 表 1及び表 4の結果によると、 定数 ΑΑが 4. 7より大きい実施例 1 In addition, according to the results in Table 1 and Table 4, the constant ΑΑ is larger than 4.7 Example 1
3は、 定数 ΑΑが 4. 7未満の実施例 10に比較して高温強度に寄与するネット ワーク状又は針状の金属間化合物の発生量が多く、 疲労強度も実施例 10を上回 つていることが分かる。 このように、 本発明において、 定数 ΑΑが 4. 7以上に なるように調製されたアルミニウム合金成形品が、 好ましい。 3 has a larger amount of network-like or acicular intermetallic compounds that contribute to high-temperature strength compared to Example 10 where the constant 未 満 is less than 4.7, and the fatigue strength is higher than Example 10. I understand that. Thus, in the present invention, an aluminum alloy molded article prepared so that the constant ΑΑ is 4.7 or more is preferable.
これに対して、上記各比較例は、共晶 S i針状比 1 , 4以上のものの含有率、 金属間化合物の長さ又は接触する金属間化合物の集合体の長さが、 実施例に比べ て小さかった。例えば、表 4に示されるように、比較例 6は、共晶 S i針状比 1 · 4以上のものを 22%程度しか有さず、 金属間化合物の長さ又は接触する金属間 化合物の集合体の長さが 3 xm以上のものを 28%程度しか有していなかった。 On the other hand, in each of the above comparative examples, the content of the eutectic Si needle-like ratio of 1 or 4 or more, the length of the intermetallic compound, or the length of the aggregate of the intermetallic compound in contact with each other is described in the examples It was small compared. For example, as shown in Table 4, Comparative Example 6 has only about 22% of eutectic Si needle-like ratios of 1 and 4 or more, and the length of the intermetallic compound or the intermetallic compound in contact with it. Only about 28% of the aggregates were 3 xm or longer.
(表 4) 共晶 Si 金属間化合物 (Table 4) Eutectic Si intermetallic compound
卤積占有卓 針状比 E積占有率 針状比 平均粒径 平均粒径 Soil occupation table Needle ratio E Product occupation ratio Needle ratio Average particle diameter Average particle diameter
(%) 1.4以上 (%) 1.4以上 実施例 10 8.6% 2.4 m 78% 7.4% 2.6 m 88% 実施例 13 8.5% 2.5 jWm 80% 7.8% 2.7 jU 89% 比較例 6 8.5% 2.0 m 22% 7.2% 1.9 im 28% (%) 1.4 or more (%) 1.4 or more Example 10 8.6% 2.4 m 78% 7.4% 2.6 m 88% Example 13 8.5% 2.5 jWm 80% 7.8% 2.7 jU 89% Comparative Example 6 8.5% 2.0 m 22% 7.2 % 1.9 im 28%
(実施例 1 7、 1 8 ) (Examples 1 7, 1 8)
〔製造条件〕 . [Production conditions]
実施例 1 7、 1 8及び比較例 1 1、 1 2をそれぞれ、 表 5に示す組成及び製 造条件で、実施例 1〜1 6及び比較例 1〜1 0と同様の製造方法にて、製造した。 尚、 比較例 1 3は粉末状の押出铸造材から成形されており、 アルミニウム合金の 連続铸造丸棒から成形されず、 均質化処理が行われなかった点を除き、 比較例 1 1及び 1 2と同様の製造方法で製造された。 実施例 1 7、 1 8及び比較例 1 1〜 1 3はいずれも、 第 7図 (a ) 〜 (c ) に示すように直径 8 O mm, 厚さ 8 mm の冠面 1◦を有するビス トン 1の形状を有するアルミニウム合金成形品として成 形された。 Examples 17 and 18 and Comparative Examples 1 1 and 12 were respectively produced in the same manner as in Examples 1 to 16 and Comparative Examples 1 to 10 with the compositions and production conditions shown in Table 5. Manufactured. Comparative Examples 1 and 3 were formed from powdered extruded forged material, except that they were not formed from an aluminum alloy continuous forged round bar and were not homogenized. It was manufactured by the same manufacturing method. Examples 1 7 and 1 8 and Comparative Examples 1 1 to 1 3 are all screws having a crown surface of 1 ° having a diameter of 8 O mm and a thickness of 8 mm as shown in FIGS. 7 (a) to (c). It was formed as an aluminum alloy molded product having the shape of Ton 1.
〔疲労強度評価〕 [Fatigue strength evaluation]
実施例 1 7、 1 8及ぴ比較例 1 1〜 1 3に対し、 次の方法により疲労強度を 評価した。 For Examples 17 and 18 and Comparative Examples 1 1 to 13, fatigue strength was evaluated by the following method.
まず、 各実施例及び各比較例のビストン 1に対し、 3 0 0 °C或いは 3 5 0 °C で 1 0 0時間の予備加熱を施した後、 各実施例及び各比較例の冠面 1 0の中心部 から試験片 1 1を切り出した。 上記予備加熱温度に対応するそれぞれの温度環境 下において、 片振り引張疲労試験により、 各試験片 1 1に対し疲労強度を評価し た。 上記疲労試験において、 応力比 R =—0 . 1とし、 1 0 0 0万回で未破断の 最大応力を疲労強度とした。 実施例 1 7、 1 8及び比較例 1 1〜1 3の疲労強度 評価結果を表 5に示す。 First, after preheating for 300 hours at 30 ° C. or 35 ° C. to the biston 1 of each example and each comparative example, the crown 1 of each example and each comparative example 1 A test piece 1 1 was cut out from the center of 0. Under each temperature environment corresponding to the preheating temperature, the fatigue strength of each test piece 11 was evaluated by a single swing tensile fatigue test. In the above fatigue test, the stress ratio was R = −0.1, and the unscored maximum stress was defined as the fatigue strength after 100 thousand times. Table 5 shows the fatigue strength evaluation results of Examples 17 and 18 and Comparative Examples 11 to 13.
表 5から分かるように、 実施例 1 7、 1 8は、 3 5 0 °Cでの疲労強度が、 高 温時の機械的強度を要求する部品において好ましいとされ.る 4 3 M P aを超えて おり、 更に、 3 0 0 °Cでの疲労強度が 5 5 M P aを超えている。 また、 実施例 1 7及び 1 8は、 形状を除き同じ製造条件が用いられている実施例 1 0及び 1 3に 対応しており、 評価方法によらず、 高温時において安定的な機械的強度を有する 均質化 アルミニウム合金の組成 (質量。 /0) 疲労強度応力 As can be seen from Table 5, in Examples 17 and 18, fatigue strength at 3500 ° C is preferred for parts that require mechanical strength at high temperatures. Furthermore, the fatigue strength at 300 ° C exceeds 55 MPa. In addition, Examples 17 and 18 correspond to Examples 10 and 13 in which the same manufacturing conditions are used except for the shape. Stable mechanical strength at high temperatures is used regardless of the evaluation method. Have Homogenization Aluminum alloy composition (mass. / 0 ) Fatigue strength stress
後熱処理 (単位: MPa) 材料 処理温度 AA Post heat treatment (Unit: MPa) Material Processing temperature AA
(T6, T5) 値 (T6, T5) value
(°C) Si Fe Cu n Mg Ni Ti P /皿' 条 温度条件 (° C) Si Fe Cu n Mg Ni Ti P / dish 'Article Temperature conditions
件 300。C 350°C 比較例 1 1 連続錶造棒 370 T6 12.3 0.3 3.3 0.15 0.85 1.8 0.05 0.005 64 45 4.04 比較例 1 2 連続錶造棒 370 T6 12.4 0.3 1.0 ― 1.04 1.0 ― 0.010 45 33 1.66 比較例 1 3 粉末押出材 ― T6 1 1.7 5.3 2.5 ― 1.1 ― ― ― 80 59 1J0 実施例 1 7 連 ¾錶 棒 370 T6 12.8 0.48 4.5 0.23 0.95 1.5 0.075 0.018 70 52 4.56 実施例 1 8 連続錶造棒 370 T6 12.8 0.48 5.5 0.23 0.95 1.0 0.075 0.018 73 54 4J4 300 cases. C 350 ° C Comparative Example 1 1 Continuous Forging Bar 370 T6 12.3 0.3 3.3 0.15 0.85 1.8 0.05 0.005 64 45 4.04 Comparative Example 1 2 Continuous Forging Bar 370 T6 12.4 0.3 1.0 ― 1.04 1.0 ― 0.010 45 33 1.66 Comparative Example 1 3 Extruded powder ― T6 1 1.7 5.3 2.5 ― 1.1 ― ― ― 80 59 1J0 Example 1 7 ¾ 錶 Bar 370 T6 12.8 0.48 4.5 0.23 0.95 1.5 0.075 0.018 70 52 4.56 Example 1 8 Continuous forged rod 370 T6 12.8 0.48 5.5 0.23 0.95 1.0 0.075 0.018 73 54 4J4
これに対し、 比較例 1 1は、 AA値が 4 . 2未満であり、 形状を除き同じ製 造条件が用いられている比較例 2に対応する。 表 2の比較例 2及び表 5の比較例 1 1の疲労強度評価結果から、 比較例 1 1は、 高温時の機械的強度の信頼性に欠 けると考えられる。 On the other hand, Comparative Example 11 corresponds to Comparative Example 2 in which the AA value is less than 4.2 and the same manufacturing conditions except for the shape are used. From the fatigue strength evaluation results of Comparative Example 2 in Table 2 and Comparative Example 11 in Table 5, Comparative Example 11 is considered to lack the reliability of mechanical strength at high temperatures.
また、 比較例 1 2は AA = 1 . 6 8であり、 3 5 0 °Cでの疲労強度が 4 3 M Comparative Example 1 2 has AA = 1.6 8 and the fatigue strength at 3500 ° C is 4 3 M
P aよりも著しく低い。 Significantly lower than Pa.
尚、 粉末状の押出铸造材から成形された比較例 1 3は A A = 1 . 7であるに も関わらず、 実施例 1 7、 1 8よりも高い疲労強度を有するが、 押し固めにより 成形されたものは細かい部分、 例えば、 スカート部 1 2が脆くなりやすいという 欠点がある。 このように、 粉末状の押出錶造材が用いられた成形品は、 アルミ二 ゥム合金からなる連続铸造棒を素材として用いた鍛造成形工程を有するアルミ二 ゥム合金成形品に比べて、 延性及び靱性が劣る。 In addition, although Comparative Example 13 formed from the powdered extruded forged material has higher fatigue strength than Examples 17 and 18 although AA = 1.7, it was formed by compaction. There is a disadvantage that the fine part, for example, the skirt part 12 tends to become brittle. In this way, the molded product using the powder extruded material is compared with the aluminum alloy molded product having a forging process using a continuous forged rod made of an aluminum alloy as a material. Ductility and toughness are inferior.
本発明の製造方法により製造されたアルミニウム合金成形品は、 延性、 靱性 及び疲労強度に優れており、 内燃機関ビストンの冠面部位等に好適に使用するこ とができる。 産業上の利用可能性 The aluminum alloy molded article produced by the production method of the present invention is excellent in ductility, toughness and fatigue strength, and can be suitably used for a crown surface portion of an internal combustion engine biston. Industrial applicability
以上説明したように、 本発明は、 アルミニウム合金からなる連続鍀造棒を素 材として用いた鍛造成形工程を有するアルミニウム合金成形品の製造方法であつ て、 上記アルミニウム合金が S i、 C u、 M g及ぴ N iを含んでいるので、 本発 明によれば、 高温疲労強度と鍛造性、 延性、 靱性が良好な成形品を得ることがで きる。 又、 N i と C uとが、 N i (質量0 /0) ≥ 〔一 0 . 6 8 X C u (質量0 /0) + 4 . 2 (質量%)〕 なる関係式を満足するので、 より高温での疲労強度特性を向上 させることができる。 As described above, the present invention is a method for manufacturing an aluminum alloy molded article having a forging process using a continuous forged rod made of an aluminum alloy as a raw material, wherein the aluminum alloy is Si, Cu, Since it contains Mg and Ni, according to the present invention, it is possible to obtain a molded article having high-temperature fatigue strength and good forgeability, ductility, and toughness. Also, and the N i and C u, N i (mass 0/0) ≥ [one 0. 6 8 XC u (mass 0/0) + 4.2 (wt%)] Since satisfying the relational expression, The fatigue strength characteristics at higher temperatures can be improved.
本発明のアルミニウム合金成形品を用いることにより、 従来の内燃機関ビス 7 065331 By using the aluminum alloy molded product of the present invention, a conventional internal combustion engine screw 7 065331
39 39
トンよりも薄肉化することができ、 内燃機関ピス トンの軽量化が可能になる。 そ して、市場から求められている軽量化に答えることができ、内燃機関の燃費低減、 出力向上が実現することができる。 It is possible to reduce the thickness of the internal combustion engine piston. And, it can answer the weight reduction demanded by the market, and can realize reduction in fuel consumption and improvement in output of the internal combustion engine.
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/376,044 US20100006192A1 (en) | 2006-08-01 | 2007-07-31 | Method for producing aluminum-alloy shaped product, aluminum-alloy shaped product and production system |
| JP2008527820A JPWO2008016169A1 (en) | 2006-08-01 | 2007-07-31 | Aluminum alloy molded product manufacturing method, aluminum alloy molded product and production system |
| CN2007800364415A CN101522935B (en) | 2006-08-01 | 2007-07-31 | Manufacturing method of aluminum alloy formed product, aluminum alloy formed product, and production system |
| EP07792004.9A EP2048259A4 (en) | 2006-08-01 | 2007-07-31 | Process for production of aluminum alloy formings, aluminum alloy formings and production system |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006209898 | 2006-08-01 | ||
| JP2006-209898 | 2006-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008016169A1 true WO2008016169A1 (en) | 2008-02-07 |
Family
ID=38997339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/065331 Ceased WO2008016169A1 (en) | 2006-08-01 | 2007-07-31 | Process for production of aluminum alloy formings, aluminum alloy formings and production system |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100006192A1 (en) |
| EP (1) | EP2048259A4 (en) |
| JP (1) | JPWO2008016169A1 (en) |
| KR (1) | KR20090046868A (en) |
| CN (1) | CN101522935B (en) |
| WO (1) | WO2008016169A1 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010012470A (en) * | 2008-06-30 | 2010-01-21 | Nippon Light Metal Co Ltd | CASTING METHOD OF HYPER-EUTECTIC Al-Si BASED ALLOY, AND INGOT THEREOF |
| WO2011052708A1 (en) * | 2009-10-30 | 2011-05-05 | 昭和電工株式会社 | Method for producing near-net-shape material for engine piston |
| JP2015086445A (en) * | 2013-10-31 | 2015-05-07 | スズキ株式会社 | Aluminum alloy |
| JP2016017181A (en) * | 2014-07-04 | 2016-02-01 | 昭和電工株式会社 | Aluminum alloy for continuous casting and method for producing continuous casting material |
| JP2016079419A (en) * | 2014-10-10 | 2016-05-16 | 昭和電工株式会社 | Aluminum alloy continuous cast material and manufacturing method therefor |
| JP2017115169A (en) * | 2015-12-21 | 2017-06-29 | 昭和電工株式会社 | Manufacturing method for forged piston |
| WO2018042494A1 (en) * | 2016-08-29 | 2018-03-08 | 日本軽金属株式会社 | High-strength aluminum alloy, internal combustion engine piston comprising said alloy, and method for producing internal combustion engine piston |
| KR20190077451A (en) * | 2016-10-27 | 2019-07-03 | 노벨리스 인크. | Metal-roll |
| JP2020200512A (en) * | 2019-06-12 | 2020-12-17 | 昭和電工株式会社 | Aluminum alloy material |
| CN113862532A (en) * | 2021-09-06 | 2021-12-31 | 国网青海省电力公司 | Aluminum alloy for pipe bus fitting and preparation method of pipe bus fitting |
| US11692255B2 (en) | 2016-10-27 | 2023-07-04 | Novelis Inc. | High strength 7XXX series aluminum alloys and methods of making the same |
| US11821065B2 (en) | 2016-10-27 | 2023-11-21 | Novelis Inc. | High strength 6XXX series aluminum alloys and methods of making the same |
| CN118218566A (en) * | 2024-05-27 | 2024-06-21 | 成都新航工业科技股份有限公司 | Casting process for aluminum alloy sensor housing casting with embedded heating wire |
| CN120839035A (en) * | 2025-09-19 | 2025-10-28 | 中北大学 | A method for preparing aluminum-iron composite material based on microtexture and aluminum-iron composite material |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102482752B (en) * | 2009-07-03 | 2013-09-11 | 昭和电工株式会社 | Process for production of roughly shaped material for engine piston |
| EP2467456B2 (en) * | 2009-08-18 | 2023-08-09 | The Lubrizol Corporation | Lubricating method |
| JP5355320B2 (en) * | 2009-09-10 | 2013-11-27 | 日産自動車株式会社 | Aluminum alloy casting member and manufacturing method thereof |
| CN102844456B (en) * | 2010-04-16 | 2014-10-15 | 昭和电工株式会社 | Process for production of forged aluminum alloy member |
| KR101309720B1 (en) * | 2010-06-24 | 2013-09-25 | (주)제물포금속 | Al-Si alloy for piston of car added vanadium and manufacturing method of the same |
| CN103003458B (en) * | 2010-07-16 | 2015-11-25 | 日本轻金属株式会社 | Aluminum alloy excellent in high-temperature strength and thermal conductivity and manufacturing method thereof |
| CN102181758B (en) * | 2011-06-17 | 2013-05-15 | 重庆协成汽车零部件有限公司 | Novel casting aluminium alloy and preparation method thereof |
| BR112014010030B1 (en) * | 2011-10-28 | 2018-11-06 | Alcoa Usa Corp | aluminum alloys |
| US10174409B2 (en) | 2011-10-28 | 2019-01-08 | Alcoa Usa Corp. | High performance AlSiMgCu casting alloy |
| DE102012220765A1 (en) * | 2012-11-14 | 2014-05-15 | Federal-Mogul Nürnberg GmbH | Method for producing an engine component, engine component and use of an aluminum alloy |
| KR101243436B1 (en) * | 2012-11-19 | 2013-03-13 | 삼양금속공업 주식회사 | Cuni 90/10 flange and its production method using forge |
| CN103469021B (en) * | 2013-08-12 | 2016-02-10 | 安徽盛达前亮铝业有限公司 | A kind of Engine piston aluminum alloy and preparation method thereof |
| CN105874090A (en) | 2013-12-20 | 2016-08-17 | 美铝公司 | High performance AlSiMgCu casting alloy |
| CN104233016A (en) * | 2014-09-25 | 2014-12-24 | 福州钜全汽车配件有限公司 | Gasoline engine piston material and preparation method thereof |
| CN106350706A (en) * | 2016-08-19 | 2017-01-25 | 徐州飞轮活塞制造有限公司 | Aluminum-alloy cushion sleeve for round-log multiblade saw and preparation method of aluminum-alloy cushion sleeve |
| CN106078231B (en) * | 2016-08-30 | 2018-02-16 | 浙江中屹建设集团有限公司 | A kind of round steel capsule for building |
| CN109504881A (en) * | 2018-12-14 | 2019-03-22 | 广东省海洋工程装备技术研究所 | A kind of Al-Si-Cu-Mg-Ni-Sr alloy material and preparation method thereof and piston |
| CN109355534A (en) * | 2018-12-14 | 2019-02-19 | 广东省海洋工程装备技术研究所 | A kind of multi-element eutectic Al-Si alloy material and preparation method thereof and piston |
| CN109735748B (en) * | 2019-01-31 | 2021-04-16 | 中国兵器科学研究院宁波分院 | Heat-resistant cast aluminum alloy piston material and preparation method thereof |
| JP6942151B2 (en) * | 2019-02-06 | 2021-09-29 | Bbsジャパン株式会社 | Aluminum alloy forged wheel and its manufacturing method |
| CN110129631B (en) * | 2019-05-24 | 2020-08-11 | 西安康博新材料科技有限公司 | High-strength and high-toughness heat-resistant aluminum alloy material for internal combustion engine and preparation method thereof |
| CN113897520A (en) * | 2020-07-06 | 2022-01-07 | 济南科为达新材料科技有限公司 | High-strength heat-resistant cast aluminum-silicon alloy for engine piston |
| CN112048649A (en) * | 2020-09-18 | 2020-12-08 | 江西寰球新材料科技有限公司 | Aluminum alloy, preparation method thereof and automobile casting |
| CN112662919A (en) * | 2020-12-18 | 2021-04-16 | 广东省科学院智能制造研究所 | Al-Si-Cu-Mg-Ni alloy material and preparation method thereof |
| CN113278854B (en) * | 2021-05-24 | 2022-05-10 | 河北新立中有色金属集团有限公司 | SiCp/Al-Si-Cu composite powder material and preparation method thereof |
| CN113846241A (en) * | 2021-09-18 | 2021-12-28 | 栋梁铝业有限公司 | Production method of high-performance special aluminum alloy section |
| CN115125421B (en) * | 2022-07-19 | 2023-04-28 | 西安工业大学 | Quasicrystal reinforced low-expansion aluminum alloy for internal combustion engine and preparation method thereof |
| WO2024048895A1 (en) * | 2022-09-01 | 2024-03-07 | 한국재료연구원 | Aluminum alloy casting material and brake disc comprising same |
| CN117363909B (en) * | 2023-10-12 | 2024-04-05 | 河南亿水源净水材料科技有限公司 | A method for recovering aluminum from aluminum ash to prepare aluminum alloy |
| CN117535568B (en) * | 2024-01-09 | 2024-04-19 | 北京魏桥国科新能源技术研究院有限公司 | High-strength heat-resistant aluminum alloy, single wire, production method thereof, and conductor |
| CN117867342B (en) * | 2024-01-15 | 2024-07-19 | 南京工业大学 | QP-II-based aluminum alloy with main strengthening phase and preparation method and application thereof |
| CN118703847B (en) * | 2024-08-29 | 2024-12-17 | 山东海化集团有限公司 | Renewable heat treatment-free integrated die-casting aluminum alloy and preparation method thereof |
| CN119392128B (en) * | 2025-01-03 | 2025-04-08 | 中南大学 | Preparation method of aluminum alloy single crystal |
| CN119956176B (en) * | 2025-04-11 | 2025-07-08 | 湖南卓创精材科技股份有限公司 | A high performance aluminum alloy and preparation method |
| CN120311079B (en) * | 2025-06-17 | 2025-08-26 | 湖南卓创精材科技股份有限公司 | A high silicon aluminum alloy material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112674A (en) * | 1997-06-30 | 1999-01-19 | Aisin Seiki Co Ltd | Aluminum alloy and aluminum alloy piston for internal combustion engine piston |
| JP2002294383A (en) | 2001-03-30 | 2002-10-09 | Showa Denko Kk | Aluminum alloy ingot for plastic working, method for producing aluminum alloy ingot for plastic working, method for producing aluminum alloy plastic worked product and aluminum alloy plastic worked product |
| JP2005290545A (en) | 2003-12-18 | 2005-10-20 | Showa Denko Kk | Method for producing shaped-product of aluminum alloy, shaped-product of aluminum alloy and production system |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1607261A (en) * | 2003-10-13 | 2005-04-20 | 合金材料实验室 | A New Die Casting Aluminum Alloy |
| DE602004004028T2 (en) * | 2003-10-17 | 2007-07-05 | Kabushiki Kaisha Toyota Chuo Kenkyusho, Nagakute | Aluminum casting alloy, aluminum casting alloys and their manufacturing processes |
| EP1716265B1 (en) * | 2003-12-18 | 2012-06-13 | Showa Denko K.K. | Method for producing shaped article of aluminum alloy and shaped aluminum alloy articl |
-
2007
- 2007-07-31 US US12/376,044 patent/US20100006192A1/en not_active Abandoned
- 2007-07-31 JP JP2008527820A patent/JPWO2008016169A1/en active Pending
- 2007-07-31 CN CN2007800364415A patent/CN101522935B/en not_active Expired - Fee Related
- 2007-07-31 EP EP07792004.9A patent/EP2048259A4/en not_active Withdrawn
- 2007-07-31 KR KR1020097003877A patent/KR20090046868A/en not_active Ceased
- 2007-07-31 WO PCT/JP2007/065331 patent/WO2008016169A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1112674A (en) * | 1997-06-30 | 1999-01-19 | Aisin Seiki Co Ltd | Aluminum alloy and aluminum alloy piston for internal combustion engine piston |
| JP2002294383A (en) | 2001-03-30 | 2002-10-09 | Showa Denko Kk | Aluminum alloy ingot for plastic working, method for producing aluminum alloy ingot for plastic working, method for producing aluminum alloy plastic worked product and aluminum alloy plastic worked product |
| JP2005290545A (en) | 2003-12-18 | 2005-10-20 | Showa Denko Kk | Method for producing shaped-product of aluminum alloy, shaped-product of aluminum alloy and production system |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP2048259A4 |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010012470A (en) * | 2008-06-30 | 2010-01-21 | Nippon Light Metal Co Ltd | CASTING METHOD OF HYPER-EUTECTIC Al-Si BASED ALLOY, AND INGOT THEREOF |
| WO2011052708A1 (en) * | 2009-10-30 | 2011-05-05 | 昭和電工株式会社 | Method for producing near-net-shape material for engine piston |
| JP5689423B2 (en) * | 2009-10-30 | 2015-03-25 | 昭和電工株式会社 | Manufacturing method of engine piston profile |
| JP2015086445A (en) * | 2013-10-31 | 2015-05-07 | スズキ株式会社 | Aluminum alloy |
| JP2016017181A (en) * | 2014-07-04 | 2016-02-01 | 昭和電工株式会社 | Aluminum alloy for continuous casting and method for producing continuous casting material |
| JP2016079419A (en) * | 2014-10-10 | 2016-05-16 | 昭和電工株式会社 | Aluminum alloy continuous cast material and manufacturing method therefor |
| JP2017115169A (en) * | 2015-12-21 | 2017-06-29 | 昭和電工株式会社 | Manufacturing method for forged piston |
| WO2018042494A1 (en) * | 2016-08-29 | 2018-03-08 | 日本軽金属株式会社 | High-strength aluminum alloy, internal combustion engine piston comprising said alloy, and method for producing internal combustion engine piston |
| JPWO2018042494A1 (en) * | 2016-08-29 | 2019-03-14 | 日本軽金属株式会社 | High strength aluminum alloy, piston for internal combustion engine made of the alloy, and method for manufacturing piston for internal combustion engine |
| US11549461B2 (en) | 2016-08-29 | 2023-01-10 | Nippon Light Metal Company, Ltd. | High strength aluminum alloy, internal combustion engine piston comprising said alloy, and method for manufacturing internal combustion engine piston |
| JP2021000661A (en) * | 2016-10-27 | 2021-01-07 | ノベリス・インコーポレイテッドNovelis Inc. | Metal casting and rolling line |
| JP2023085318A (en) * | 2016-10-27 | 2023-06-20 | ノベリス・インコーポレイテッド | metal casting and rolling line |
| JP2020503173A (en) * | 2016-10-27 | 2020-01-30 | ノベリス・インコーポレイテッドNovelis Inc. | Metal casting and rolling line |
| US10913107B2 (en) | 2016-10-27 | 2021-02-09 | Novelis Inc. | Metal casting and rolling line |
| KR102259548B1 (en) * | 2016-10-27 | 2021-06-07 | 노벨리스 인크. | Metal Casting and Rolling Line |
| JP2021185000A (en) * | 2016-10-27 | 2021-12-09 | ノベリス・インコーポレイテッドNovelis Inc. | Metal casting and rolling line |
| US12410500B2 (en) | 2016-10-27 | 2025-09-09 | Novelis Inc. | High strength 6xxx series aluminum alloys and methods of making the same |
| KR20190077451A (en) * | 2016-10-27 | 2019-07-03 | 노벨리스 인크. | Metal-roll |
| US11590565B2 (en) | 2016-10-27 | 2023-02-28 | Novelis Inc. | Metal casting and rolling line |
| JP7485813B2 (en) | 2016-10-27 | 2024-05-16 | ノベリス・インコーポレイテッド | Metal Casting and Rolling Lines |
| US11692255B2 (en) | 2016-10-27 | 2023-07-04 | Novelis Inc. | High strength 7XXX series aluminum alloys and methods of making the same |
| US11806779B2 (en) | 2016-10-27 | 2023-11-07 | Novelis Inc. | Systems and methods for making thick gauge aluminum alloy articles |
| US11821065B2 (en) | 2016-10-27 | 2023-11-21 | Novelis Inc. | High strength 6XXX series aluminum alloys and methods of making the same |
| JP2020200512A (en) * | 2019-06-12 | 2020-12-17 | 昭和電工株式会社 | Aluminum alloy material |
| CN113862532A (en) * | 2021-09-06 | 2021-12-31 | 国网青海省电力公司 | Aluminum alloy for pipe bus fitting and preparation method of pipe bus fitting |
| CN118218566A (en) * | 2024-05-27 | 2024-06-21 | 成都新航工业科技股份有限公司 | Casting process for aluminum alloy sensor housing casting with embedded heating wire |
| CN120839035A (en) * | 2025-09-19 | 2025-10-28 | 中北大学 | A method for preparing aluminum-iron composite material based on microtexture and aluminum-iron composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090046868A (en) | 2009-05-11 |
| EP2048259A4 (en) | 2015-03-18 |
| CN101522935B (en) | 2012-09-26 |
| CN101522935A (en) | 2009-09-02 |
| JPWO2008016169A1 (en) | 2009-12-24 |
| US20100006192A1 (en) | 2010-01-14 |
| EP2048259A1 (en) | 2009-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2008016169A1 (en) | Process for production of aluminum alloy formings, aluminum alloy formings and production system | |
| JP5027844B2 (en) | Method for producing aluminum alloy molded product | |
| JP4359231B2 (en) | Method for producing aluminum alloy molded product, and aluminum alloy molded product | |
| JP7722174B2 (en) | Aluminum alloy forgings | |
| JP7533746B2 (en) | Aluminum alloy forging material, aluminum alloy forging product and manufacturing method thereof | |
| JP7533745B2 (en) | Aluminum alloy forging material, aluminum alloy forging product and manufacturing method thereof | |
| JP6670603B2 (en) | Manufacturing method of forged piston | |
| JP7722172B2 (en) | Aluminum alloy forgings | |
| JP4764094B2 (en) | Heat-resistant Al-based alloy | |
| JP7533743B2 (en) | Aluminum alloy forging material, aluminum alloy forging product and its manufacturing method | |
| RU2378405C1 (en) | Method of casting receiving from leaded bronze | |
| JP2023161784A (en) | Aluminum alloy forging and method for manufacturing the same | |
| JP7722173B2 (en) | Aluminum alloy forgings | |
| JP7750334B2 (en) | Aluminum alloy castings, aluminum alloy forgings, and their manufacturing methods | |
| JP2025000887A (en) | Material for aluminum alloy forging, aluminum alloy forged product and method for producing the same | |
| JP2024086591A (en) | Aluminum alloy forging material, aluminum alloy forging product and its manufacturing method | |
| JP2025000890A (en) | Material for aluminum alloy forging, aluminum alloy forged product and method for producing the same | |
| WO2025169601A1 (en) | Material for aluminum alloy forging, aluminum alloy forged product, and method for manufacturing same | |
| JP2024093725A (en) | Aluminum alloy forgings and their manufacturing method | |
| JP2024086593A (en) | Aluminum alloy forging material, aluminum alloy forging product and its manufacturing method | |
| JP2024085793A (en) | Aluminum alloy forgings and their manufacturing method | |
| WO2025126920A1 (en) | Aluminum alloy material for cold working, method for producing aluminum alloy material for cold working, aluminum alloy material for hot working, and method for producing aluminum alloy material for hot working | |
| JP2025125977A (en) | Aluminum alloy material for forging, aluminum alloy forged article, and method for producing the same | |
| JP2025120647A (en) | Aluminum alloy forging material, aluminum alloy forging product and manufacturing method thereof | |
| JP2024085797A (en) | Aluminum alloy forgings and their manufacturing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 200780036441.5 Country of ref document: CN |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07792004 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2008527820 Country of ref document: JP |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2007792004 Country of ref document: EP |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 1020097003877 Country of ref document: KR Ref document number: KR |
|
| NENP | Non-entry into the national phase |
Ref country code: RU |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 12376044 Country of ref document: US |