WO2008016011A1 - Inorganic plate and method for producing the same - Google Patents
Inorganic plate and method for producing the same Download PDFInfo
- Publication number
- WO2008016011A1 WO2008016011A1 PCT/JP2007/064904 JP2007064904W WO2008016011A1 WO 2008016011 A1 WO2008016011 A1 WO 2008016011A1 JP 2007064904 W JP2007064904 W JP 2007064904W WO 2008016011 A1 WO2008016011 A1 WO 2008016011A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- inorganic
- mat
- less
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/52—Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/14—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
- B28B1/16—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted for producing layered articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/04—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00603—Ceiling materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the present invention relates to a cosmetic inorganic board suitable for use as a base material for interior materials, ceiling materials, eave roof materials, etc. of buildings such as houses, and a method for producing the same.
- a board for a decorative surface material such as furniture
- a wood board such as plywood or MDF
- an inorganic board such as a plaster board or calcium silicate board.
- Patent Document 1 a wet material obtained by mixing and dispersing a raw material containing mineral fibers, an inorganic powder, and a binder as essential components to form a slurry and wet papermaking
- a method for producing an inorganic board that can obtain a decorative layer satisfactorily by drying a mat and sanding it, followed by heating and compression to cure the binder.
- Patent Document 1 Japanese Patent Laid-Open No. 2005-289784
- the present invention has been made in view of such points, and an object of the present invention is to make it possible to produce with high productivity an inorganic board from which a good decorative layer having high smoothness can be obtained.
- the inorganic board of the first invention comprises an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight; a lightweight aggregate of 10 to 70% by weight; and an inorganic powder. 10 to 70% by weight of a solid body, 5 to 15% by weight of a binder, and 10 to 70% by weight of inorganic fibers having a length of 1 mm or less and a lightweight aggregate having a particle size of 500 ⁇ 111 or less 10 It is characterized in that a surface layer having ⁇ 50 wt%, inorganic powder 10-70 wt%, and binder 3 ⁇ ; 10 wt% is integrally formed.
- fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer of the inorganic board.
- the back layer is made of an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powdery material of 10 to 70% by weight, and a binder. Since this is a layer having 5 to 15% by weight, this back layer is stronger as a plate than the front layer. As a result, the surface layer can be supported by the back surface layer (by integrating the back surface layer with the surface layer, the relatively low strength surface layer can be reinforced and supplemented). A strong inorganic plate can be obtained by integrating the above.
- This back layer uses inorganic fibers with a length of 3 to 15 mm, and therefore has a good mixing balance with other components such as lightweight aggregates, inorganic powders and binders. It is possible to uniformly disperse and mix inorganic fibers that do not easily become lumps (fiber lump). For this reason, a back layer having higher strength and hardness can be obtained, and the surface layer can be supported and supported.
- the sheet-like material is integrated with the back surface of the inorganic board according to the first invention. According to this configuration, since the sheet-like material is integrated with the back surface layer, it is difficult to break and is strong. An inorganic plate with a thickness of 10 mm is obtained.
- the third and fourth inventions relate to a method for producing an inorganic plate.
- the length of 3 to 15 mm of inorganic fibers To 10 wt%, lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% And forming a back surface layer mat by forming a mixture having a binder of 5 to 15% by weight and water added to adjust the water content to 5 to 15%, Furthermore, 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ⁇ 111 or less, 10 to 70% by weight of an inorganic powder, and a binder of 3 to Forming a surface layer mat by forming a mixture having a water content of 5 to 10% and having a water content of 5 to 15% adjusted to 15%, and two layers of the back layer and the surface layer. It is characterized by comprising a step of forming the mat integrally
- the back surface layer of the inorganic board manufactured through the above steps uses inorganic fibers having a length of 3 to 15 mm.
- the inorganic fiber which has a good mixing balance with the material, the inorganic powder, and the binder and does not easily become a lump (fiber lump), is uniformly dispersed and mixed. For this reason, an inorganic board with higher strength and hardness can be obtained.
- the binder can be reacted by performing heat compression at a high temperature for a short time. Moreover, since it is under high temperature and high pressure, the fluidity
- the moisture content of each mat of the back surface layer and the front surface layer is adjusted to 5 to 15%, so that the productivity in which puncture hardly occurs at the time of hot press is good.
- the length of 3 to 15 mm inorganic fiber To 10 wt%, light aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% And forming a back surface mat by forming a mixture adjusted to a water content of 5 to 15% by adding water and forming a mixture on a sheet-like material.
- the sheet-like material is also formed by hot-pressing integrally with the two-layer mat, so that it is difficult to break and is a strong inorganic material. A board is obtained. Further, it can be manufactured with good productivity with fewer steps than when a sheet-like material is pasted later. Furthermore, in the manufacturing process, the mat-like material, which is a mixture, can be transported more easily because the sheet-like material is laid underneath.
- An inorganic plate according to a fifth invention comprises a core layer, a surface layer integrated on the surface of the core layer, and a back layer integrated on the back surface of the core layer.
- the core layer is an inorganic fiber having a length of 3 to 15 mm;!
- fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer and the back layer, respectively. And can gain the back layer.
- the core layer between the surface layer and the back layer is composed of 3 to 15 mm in length of inorganic fiber 1 to 10% by weight, light aggregate 10 to 70% by weight, and inorganic powder 10 to 10%. Since the layer has 70% by weight and a binder of 5 to 15% by weight, the core layer is stronger as a plate than the surface layer and the back layer. Supports the layer (by integrating the core layer with the back layer and the surface layer, the relatively low strength surface layer and back layer can be reinforced and supplemented), and the core layer, the surface layer and the back layer are integrated. Thus, a strong inorganic plate can be obtained.
- the core layer uses inorganic fibers with a length of 3 to 15 mm, the mixing balance with other components such as lightweight aggregates, inorganic powders, and binders is good. Inorganic fibers that are difficult to become (fiber aggregates) can be uniformly dispersed and mixed. For this reason, a core layer having higher strength and hardness can be obtained, and the surface layer and the back layer can be further supported and supported. [0024] By these synergistic actions, it is possible to obtain a high-strength inorganic board that is excellent in nonflammability, handleability, workability, and workability as a whole.
- the sixth invention is characterized in that in the inorganic plate according to the fifth invention, a sheet-like material is bonded and integrated on at least one (at least one side) of the front and back surfaces. According to this configuration, since the sheet-like material is adhered to at least one of the front and back surfaces, an inorganic plate that is hard to break and strong is obtained.
- the seventh and eighth inventions relate to a method for producing an inorganic plate.
- the core layer of the inorganic board manufactured through the above steps uses inorganic fibers having a length of 3 to 15 mm, so that lightweight bone which is another component is used.
- the inorganic fibers which have a good mixing balance with materials, inorganic powders, and binders and do not easily become lumps (fiber lump), are uniformly dispersed and mixed. Therefore, a core layer having higher strength and hardness can be obtained, and the surface layer and the back layer can be supported and supported.
- the binder can be reacted by heating and compressing at a high temperature in a short time.
- the fluidity of the binder can be increased and distributed throughout, and the water can be evaporated in a short time. This maximizes the performance of the binder.
- the amount of the binder can be made relatively small, and a strong inorganic board excellent in incombustibility can be obtained in a short time.
- the method for producing an inorganic board according to the eighth invention comprises 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ⁇ 111 or less, and an inorganic powder. 10% to 70% by weight of a compact and 3% to 10% by weight of a binder, and a mixture adjusted to a water content of 5% to 15% by adding water is formed on a sheet and back. Step of forming a layer mat, on this back layer mat, 3 to 15 mm long inorganic fiber;!
- lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 Forming a second core layer mat by forming a mixture having 5% by weight and a binder of 5 to 15% by weight and water added to adjust the water content to 5 to 15% And 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ⁇ 111 or less, and inorganic powders 10 to 70 on these two-layer mats.
- % By weight and binder 3 Forming a third-layer surface mat by forming a mixture having a water content of 5 to 10% by weight and having a water content of 5 to 15%; 15%, and the three-layer mat And a step of integrally forming the sheet-like material with a hot press.
- the sheet-like material is also integrally formed by hot-pressing together with the three-layer mat, it is hard to break and is a strong inorganic material. A board is obtained. Further, it can be manufactured with good productivity with fewer steps than when a sheet-like material is pasted later. Furthermore, in the manufacturing process, the mat-like material, which is a mixture, can be transported more easily because the sheet-like material is laid underneath.
- the inorganic plate is formed by combining two layers of the back surface layer and the surface layer, and the back surface layer has a length of 3 to; ⁇ ; 10% by weight, lightweight aggregate 10-70% by weight, inorganic powder 10-70% by weight, binder 5 ⁇ ; 15% by weight, and the surface layer has a length of lmm or less 10 to 70% by weight of fine inorganic fibers, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ⁇ 111 or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder
- the sheet-like material integrated with the back surface layer provides an inorganic plate that is hard to crack.
- a length of 3 to 15 mm inorganic fiber To 10 wt%, lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% Agent 5 ⁇ ; Add water to 15% by weight and form a mixture adjusted to a moisture content 5 ⁇ ; 15% to form a back surface layer mat.
- a fine lmm or less in length Add water to 10 to 70% by weight of inorganic fiber, 10 to 50% by weight of light aggregate with particle size of 500 m or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder.
- Surface smoothness is achieved by forming a surface layer mat by forming a mixture adjusted to a moisture content of 5 to 15%, and forming the back layer and the surface layer in one piece by hot pressing. High-strength inorganic plates with excellent nonflammability, handleability, workability and workability can be obtained with high productivity.
- the mixture for the back surface layer mat is formed on a sheet to form a back surface layer mat, and the mixture for the surface layer mat is formed on the back surface layer mat.
- the surface layer mat is hard to crack and has a high strength.
- a certain inorganic board is obtained.
- the number of processes is less than when sheet-like materials are attached later, and the inorganic board can be manufactured with high productivity, and the carrying power of the mat becomes easy in the manufacturing process.
- the inorganic plate is formed by integrating three layers of a back layer, a surface layer, and a core layer located between them, and the core layer has an inorganic fiber length of 3 to 15 mm.
- 10% by weight, lightweight aggregate 10 ⁇ 70% by weight, inorganic powder 10 ⁇ 70% by weight, binder 5 ⁇ ; 15% by weight, surface and back layers are length 10 to 70% by weight of fine inorganic fibers of lmm or less, 10 to 50% by weight of light aggregate having a particle size of 500 ⁇ 111 or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder Therefore, a high-strength inorganic board excellent in surface smoothness, non-flammability, handleability, workability and workability can be obtained.
- an inorganic plate having strength that is difficult to break can be obtained by the sheet-like material integrated with at least one of the front and back surfaces.
- 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light aggregate having a particle size of 500 ⁇ 111 or less, and an inorganic powder 10 to 70% The mixture was adjusted to a water content of 5% to 15% by adding water to 3% by weight; a binder of 3 to; 10% by weight to form a back layer mat.
- a mixture for a back layer mat similar to that of the above seventh invention is formed on a sheet to form a back layer mat, and the seventh invention is formed on the back layer mat.
- a core layer mat is formed by forming a core layer mat similar to the above, and a surface mat is formed on the core layer mat by forming the same surface mat mixture as the back layer mat.
- an inorganic plate that is hard to break and strong is obtained by integrally molding these three-layer mat and sheet-like material with a hot press.
- the number of steps is smaller than when a sheet-like material is attached later, and the inorganic board can be manufactured with high productivity, and the mat can be transported more easily in the manufacturing process.
- FIG. 1 is a cross-sectional view of an inorganic plate according to Embodiment 1 of the present invention.
- FIG. 2 is a cross-sectional view of an inorganic plate according to Embodiment 2.
- FIG. 3 is a cross-sectional view of an inorganic plate according to Embodiment 3.
- FIG. 4 is a cross-sectional view of an inorganic plate according to Embodiment 4.
- FIG. 5 is a diagram showing various characteristics of Examples;! To 6 and Comparative Example;! To 4;
- FIG. 6 is a graph showing various characteristics of Examples 7 and 8 and Comparative Examples 5 to 8.
- a inorganic board [0041] A inorganic board
- FIG. 1 shows an inorganic plate A according to Embodiment 1 of the present invention.
- This inorganic plate A is formed by integrating a surface layer 1 located on the front surface side (upper side in FIG. 1) and a back surface layer 2 located on the rear surface side (lower side in FIG. 1). .
- the surface layer 1 is composed of 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 m or less, and 10 to 70% by weight of an inorganic powder. 3 to 10% by weight of the agent.
- the fine inorganic fibers are added to form a mat and have high stickiness and strength while obtaining high surface properties.
- pulverized rock wool, slag wool, glass fibers, etc. Can be mentioned.
- the fine inorganic fibers are added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the entire solid component. If the added amount of the inorganic fiber is less than 10% by weight, it becomes difficult to form a mat and the stickiness is lost. On the other hand, if the added amount exceeds 70% by weight, other lightweight aggregates and inorganic powders are relatively reduced. This is because the desired strength cannot be obtained.
- it is desirable that the length of the fiber is as fine as 1 mm or less.
- the “fine inorganic fibers” added to the surface layer 1 are those having a small size while retaining the properties and functions of the fibers.
- the lightweight aggregate is added to increase the bulk while securing the compressive strength, and examples thereof include perlite, shirasu foam, silica flour, and glass foam.
- the size of the lightweight aggregate used is 500 Hm or less, preferably 10 to 500 m (10 m or more and 500 m or less). This lightweight aggregate is less than 10 m in size! On the other hand, when the size of the lightweight aggregate is larger than 500 m, the workability of the inorganic board A is deteriorated as well as the surface property is deteriorated.
- This lightweight aggregate is added in an amount of 10 to 50% by weight (more than 10% by weight and less than 50% by weight) of the total solid components. If the amount of light aggregate added is less than 10% by weight, the bulk will be low and it will be difficult to spread uniformly during spraying, while if it exceeds 50% by weight, the pressure during pressing will be too high and production will occur. This is because the property decreases.
- the inorganic powder is added in order to ensure fire resistance and hardness, and examples thereof include calcium carbonate, aluminum hydroxide, magnesium hydroxide, fly ash, mic port silica, and slag.
- This inorganic powder is added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the entire solid component. If the added amount of the inorganic powder is less than 10% by weight, the desired surface hardness cannot be obtained. On the other hand, if the added amount exceeds 70% by weight, the addition rate of other materials becomes relatively small, and the desired amount of the desired surface hardness is reduced. It is difficult to obtain the strength of
- the binder is added to bind the fine inorganic fibers, lightweight aggregates, and inorganic powders.
- melamine resin, phenol resin, MDI, urethane resin, attal resin, epoxy resin examples include poval and starch, which can be used alone or in combination.
- the amount of the binder that satisfies both the strength and nonflammability of the inorganic board A is 3 to 10% by weight (more than 3% by weight and less than 10% by weight) of the total solid components. That is, if the added amount of the binder is less than 3% by weight, the strength is insufficient, whereas if it exceeds 10% by weight, the nonflammability is impaired.
- a sizing agent As an auxiliary additive, a sizing agent, a coupling agent and the like may be added as necessary.
- the back layer 2 is composed of an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powdery material of 10 to 70% by weight, and a binder of 5 to; 15% by weight.
- the inorganic fiber is added in order to form a mat and to have stickiness and strength, and examples thereof include glass fiber and wollastonite.
- This inorganic fiber is added from! To 10 wt% (1 wt% or more and 10 wt% or less) of the total solid components. If the added amount of the inorganic fiber is less than 1% by weight, it becomes difficult to form a mat and the stickiness is lost. On the other hand, if it exceeds 10% by weight, separation occurs during mixing. For example, in the case of glass fibers, it is preferable to use bundles such as chopped strands for easy handling.
- the thickness of the fiber is preferably 6 to 13 m (6 m or more and 13 m or less). If the thickness is less than 6 mm, the fiber becomes too thin and the viscosity becomes low, and the strength is lowered. On the other hand, if it exceeds 13 ⁇ 111, the surface property is deteriorated.
- the length of the fiber is preferably 3 to 15 mm (3 mm or more and 15 mm or less). If the length is shorter than 3 mm, the fiber will become less sticky, and if it exceeds 15 mm, it will be detrimental (fiber lump) and adversely affect the surface properties. Further, when the fiber length is 3 to 15 mm, the balance during mixing with the lightweight aggregate, the inorganic powder, and the binder does not become dull and can be uniformly dispersed and mixed. For this reason, the back layer 2 having higher strength and hardness can be obtained.
- the lightweight aggregate is added to increase the bulk while securing the compressive strength, and examples thereof include perlite, shirasu foam, silica flour, and glass foam.
- the size of this light aggregate is preferably 2000,1 m or less! /. This is because when the size force is larger than 000 ⁇ m, the processability of the inorganic plate A is lowered.
- the lightweight aggregate is added in an amount of 10 to 70% by weight (not less than 10% by weight and not more than 70% by weight) of the total solid components. If this amount is less than 10% by weight, the bulk will be low and even when spraying. On the other hand, when it exceeds 70% by weight, the pressure at the time of compression becomes too high and productivity is lowered.
- the inorganic powder is added in order to ensure fire resistance and hardness, and examples thereof include calcium carbonate, aluminum hydroxide, magnesium hydroxide, fly ash, mic port silica, and slag.
- This inorganic powder is added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the total solid components. If the amount added is less than 10% by weight, the desired surface hardness cannot be obtained, and if it exceeds 70% by weight, the addition rate of other materials becomes relatively small, making it difficult to obtain the desired strength. It is.
- the binder is added to bind the above-mentioned lightweight aggregate, inorganic fiber, and inorganic powder.
- melamine resin, phenol resin, MDI, urethane resin, acrylic resin, epoxy resin, poval, starch, etc. can be used alone or in combination.
- As an addition amount satisfying both the strength and nonflammability of the inorganic board A 5 to 15% by weight (5% by weight or more and 15% by weight or less) of the whole solid component is added. This is because if the amount added is less than 5% by weight, the strength is insufficient, while if it exceeds 15% by weight, the nonflammability is impaired.
- auxiliary additive functional materials such as silica gel or diatomaceous earth can be mixed to impart moisture absorption and desorption, or a deodorant or VOC adsorbent can be added.
- This method includes a back surface layer mat forming step, a surface layer mat forming step, and a molding step.
- the material for the back surface layer 2 that is, inorganic fiber having a length of 3 to 15 mm;!
- To 10% by weight, lightweight aggregate 10 to 70% by weight, and inorganic powder 10 ⁇ 70 wt%, binder 5 ⁇ ; 15 wt% and auxiliary additives are put into a mixer and mixed while spraying water to obtain a mixture adjusted to water content 5 ⁇ ; 15% . Formin this mixture To form a back layer mat.
- the water added when mixing these materials is preferably 5 to 15 wt% (5 wt% or more and 15 wt% or less) of the solid component.
- the reason for this is that if it is less than 5% by weight, the powder is scattered during mixing and molding, resulting in poor workability. It is because it becomes easy to do.
- the material for the surface layer 1 that is, 10 to 70% by weight of fine inorganic fibers having a length of lm m or less and a lightweight aggregate having a particle size of 500 m or less and 10 to 50% by weight.
- 10 to 70% by weight of an inorganic powder 3 to 10% by weight of a binder, and mixed with spraying water to adjust the water content to 5 to 15%.
- the mixture is formed on the back surface layer mat formed in the back surface layer mat forming step to form a surface layer mat.
- the added water is preferably 5 to 15% by weight of the solid component.
- the reason for this is the same as in the backside layer mat forming step.
- the amount is less than 5% by weight, the powder scatters much during mixing and molding, and the workability deteriorates. 'This is because it takes time to press and it becomes easy to puncture.
- the two mats for the back layer 2 and the front layer 1 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C.) to be integrally molded.
- This hot press machine can be either a continuous press machine or a multi-stage press machine!
- an inorganic plate A having a density of 0.3 to 1.5 g / cm 3 is formed. If this density is lower than 0.3 g / cm 3 , the desired strength cannot be obtained. On the other hand, if it exceeds 1.5 g / cm 3 , the workability and workability are deteriorated. Equipment is required and productivity is poor
- the surface layer 1 of the inorganic plate A fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer 1 of the inorganic plate A. Therefore, the dense surface layer 1 Is obtained.
- the back layer 2 has a length of 3 to; 15 mm of inorganic fiber 1 to 10% by weight Since it is a layer having 10 to 70% by weight of lightweight aggregate, 10 to 70% by weight of an inorganic powder, and 5 to 15% by weight of a binder, the surface layer 1 can be supported.
- the back layer 2 uses inorganic fibers with a length of 3 to 15 mm, it has a good mixing balance with other lightweight aggregates, inorganic powders, and binders, making it difficult to become lumps (fiber clumps). Can be uniformly dispersed and mixed. For this reason, the back layer 2 having higher strength and hardness can be obtained, and the force S for firmly supporting the front surface layer 1 can be obtained. As a result, it is possible to obtain a high-strength inorganic board A that is excellent in nonflammability, handling, workability, and workability as a whole.
- the back layer and the surface layer mat are adjusted to a moisture content of 5 to 15%! /. Therefore, the binder is reacted by performing heat compression for a short time and at a high temperature. You can force S.
- the flowability of the binder can be increased so that it can spread throughout, and the moisture can be evaporated in a short time, thus maximizing the performance of the binder.
- the amount of the binder that can be pulled out to a relatively low level can be made relatively small, and a strong inorganic board A excellent in incombustibility can be obtained in a short time.
- FIG. 2 shows an inorganic plate A according to Embodiment 2 of the present invention (in the following embodiments, the same parts as those in FIG. 1 are denoted by the same reference numerals and detailed description thereof is omitted).
- the sheet-like material 4 is integrated on the back surface of the inorganic plate A. Others are the same as in the first embodiment.
- the sheet-like material 4 is not particularly limited, and may be a non-woven fabric, a veneer, an impregnated paper, a resin sheet, a fiber sheet or the like, and may be a cosmetic one.
- a method for manufacturing the inorganic plate A of Embodiment 2 will be described.
- a sheet-like material 4 is prepared. And like the back surface layer mat formation process of Embodiment 1, length 3 ⁇ ; 15mm inorganic fiber;! ⁇ 10wt%, lightweight aggregate 10 ⁇ 70wt%, inorganic powder 10 ⁇ 70 and weight% binder 5; was charged with 15 wt% to the mixer, and mixed with spraying water to obtain a mixture which is adjusted to hydrous rate of 5 to 15 percent, the sheet material and the mixture 4 Form on top to form the back layer mat.
- the two-layer mat of the back layer and the front layer and the sheet-like material 4 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C) to be integrally formed.
- an adhesive is applied to the sheet-like material 4 in advance in order to improve the adhesion of the sheet-like material 4.
- the adhesive include phenol resin, melamine resin, urethane resin, acrylic resin, MDI, and butyl acetate resin, but it is desirable to select one having high water resistance when used for exterior use.
- the coating amount is preferably 50 g / m 2 or less for solid formation! /. This is because if the solid component exceeds 50 g / m 2 , the nonflammability decreases.
- the sheet-like material 4 is also integrally molded by hot-pressing, it can be produced with high productivity with fewer steps than when the sheet-like material 4 is attached later. Further, in the manufacturing process, the mat 4 as a mixture can be more easily transported because the sheet-like material 4 is laid underneath.
- FIG. 3 shows an inorganic plate A according to Embodiment 3 of the present invention.
- the inorganic plate A has a surface layer 11 located on the front surface side (upper side in FIG. 3) and a back surface located on the back side (lower side in FIG. 3).
- the layer 12 and the core layer 3 positioned between the surface layer 11 and the back layer 12 are integrally formed.
- the inorganic plate A includes the core layer 3, the surface layer 11 integrated on the surface of the core layer 3, and the back layer 12 integrated on the back surface of the core layer 3.
- each of the surface layer 11 and the back layer 12 is composed of 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 111 or less, 10 to 70% by weight of body and 3 to 10% by weight of binder.
- the fine inorganic fibers are the same as the “fine inorganic fibers” in the surface layer 1 of the first embodiment.
- the lightweight aggregate is the same as the “lightweight aggregate” in the surface layer 1 of the first embodiment (see the description of “lightweight aggregate” in the surface layer 1 of the first embodiment).
- the inorganic powder is the same as the “inorganic powder” in the surface layer 1 of the first embodiment (see the description of “inorganic powder” in the surface layer 1 of the first embodiment).
- the binder is the same as the “binder” in the surface layer 1 of the first embodiment (see the description of the “binder” in the surface layer 1 of the first embodiment).
- a sizing agent As an auxiliary additive, a sizing agent, a coupling agent and the like may be added as necessary.
- the core layer 3 is the same as the back layer 2 in Embodiment 1, and has a length of 3 to; 15 mm of inorganic fiber;! To 10% by weight, lightweight aggregate of 10 to 70% by weight, and an inorganic powder. 10 to 70% by weight and 5 to 15% by weight of binder.
- the inorganic fiber is the same as the “inorganic fiber” in the back layer 2 of Embodiment 1 (see the description of “Inorganic fiber” in the back layer 2 of Embodiment 1).
- the lightweight aggregate is the same as the “lightweight aggregate” in the back surface layer 2 of Embodiment 1 (see the description of “Lightweight aggregate” in the back surface layer 2 of Embodiment 1). [0090] (3) Inorganic powder
- the inorganic powder is the same as the “inorganic powder” in the back layer 2 of Embodiment 1 (see the description of “Inorganic powder” in the back layer 2 of Embodiment 1).
- the binder is the same as the “binder” in the back layer 2 of Embodiment 1 (see the description of the “binder” in the back layer 2 of Embodiment 1).
- auxiliary additive functional materials such as silica gel or diatomaceous earth can be mixed to impart moisture absorption and desorption, or a deodorant or VOC adsorbent can be added.
- This method comprises a back layer mat forming step, a core layer mat forming step, a surface layer mat forming step, and a forming step.
- the composition material for the back layer 12 that is, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less and a lightweight aggregate having a particle size of 500 Hm or less 10 to 50 10% by weight, 10 to 70% by weight of an inorganic powder, 3 to 10% by weight of binder, 10% by weight and auxiliary additives are added to the mixer and mixed while spraying water to obtain a water content of 5 to 5%; A mixture adjusted to 15% is obtained. This mixture is formed to form a backing mat.
- the water added when mixing these materials is preferably 5 to 15% by weight of the solid component (more than 5% by weight and not more than 15% by weight) (moisture content 5 to 15%). ).
- moisture content 5 to 15%.
- the material for the core layer 3 that is, the inorganic fiber having a length of 3 to 15 mm;!
- To 10% by weight, lightweight aggregate 10 to 70% by weight, and inorganic powder 10 to 70% by weight, binder 5 to 5%; 15% by weight and auxiliary additives are put into a mixer and sprayed with water.
- This mixture is formed on the back layer mat formed in the back layer mat forming step to form a second core layer mat.
- the added water is preferably 5 to 15% by weight of the solid component (water content 5 to 15%).
- the reason for this is the same as in the above-mentioned back layer mat forming process. If the amount is less than 5% by weight, the scattering of the powder during mixing or molding deteriorates the workability, while if it exceeds 15% by weight. This is because it takes time to heat and press, and it becomes easy to puncture.
- the same material as that for the surface layer 11, that is, the material for the back layer 12 is 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less and a particle size of 500 m or less.
- Light weight aggregate 10-50% by weight, inorganic powder 10-70% by weight, binder 3-10% by weight, auxiliary additives are added to the mixer and mixed while spraying water, moisture content A mixture adjusted to 5-15% is obtained. This mixture is formed on the core layer mat formed in the core layer mat forming step to form a third surface mat.
- the added water is preferably 5 to 15% by weight of the solid component (moisture content 5 to 15%).
- moisture content 5 to 15%.
- the amount is less than 5% by weight, powder scattering is large at the time of mixing or molding, while workability is deteriorated. 'It takes time to press and it becomes easy to puncture.
- the three layers of mats laminated for the back layer 12, the core layer 3, and the surface layer 11 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C.) to be integrally molded.
- This hot press machine can be a continuous press machine or a multi-stage press machine!
- an inorganic sheet A having a density of 0.3 to 1.5 g / cm 3 is formed. If this density is lower than 0.3 g / cm 3 , the desired strength cannot be obtained. On the other hand, if it exceeds 1.5 g / cm 3 , the workability and workability are deteriorated. Equipment is required and productivity is poor
- the core layer 3 comprises an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powder 10 to 70% by weight, and a binder 5 Since the layer has 15 wt%, the force S can be supported to support the surface layer 11 and the back layer 12.
- the core layer 3 uses a length of 3 to 15 mm of inorganic fibers, so it has a good mixing balance with other lightweight aggregates, inorganic powders and binders (fiber lump). Can be uniformly dispersed and mixed. Therefore, the core layer 3 having higher strength and hardness can be obtained, and the surface layer 11 and the back layer 12 can be supported and supported. As a result, it is possible to obtain a high-strength inorganic board A that is excellent in incombustibility, handling, workability, and workability as a whole.
- the mats of the back layer, the core layer, and the surface layer are adjusted to a moisture content of 5 to 15%. Power to react S.
- the fluidity of the binder can be increased and distributed throughout, and the water can be evaporated in a short time, so that the performance of the binder can be maximized.
- the amount of the binder can be made relatively small, and a strong inorganic board A having excellent nonflammability can be obtained in a short time.
- FIG. 4 shows an inorganic board A according to Embodiment 4 of the present invention.
- the sheet-like material 4 is integrated on the back surface of the inorganic plate A. Others are the same as in the third embodiment.
- the sheet-like material 4 is not particularly limited, and may be a non-woven fabric, a veneer, an impregnated paper, a resin sheet, a fiber sheet, or the like, and may be a cosmetic one.
- a sheet 4 is prepared. And, similarly to the back layer mat forming step of Embodiment 3, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 111 or less, 10 to 70% by weight of powdery substance and 3 to 10% by weight of binder are put into a mixer and water is injected. Mix with mist to obtain a mixture adjusted to a moisture content of 5 to 15%, and form the mixture on the sheet 4 to form a back layer mat.
- inorganic fiber 1 to 10% in length 3 to 15 mm, light aggregate 10 to 70% by weight, inorganic powder 10 ⁇ 70 wt% and binder 5 ⁇ ; 15 wt% are put into a mixer and mixed while spraying water to obtain a mixture adjusted to a water content of 5 ⁇ ; 15%. Form on the mat to form the second core mat.
- the three-layer mat of the back layer, the core layer and the surface layer and the sheet-like material 4 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C) to be integrally formed.
- an adhesive may be applied to the sheet-like material 4 in advance in order to improve the adhesion of the sheet-like material 4.
- the adhesive include phenol resin, melamine resin, urethane resin, acrylic resin, MDI, and butyl acetate resin.
- the coating amount is preferably 50 g / m 2 or less as a solid component! /. This is because non-flammability decreases when the solid component exceeds 50 g / m 2 .
- the sheet-like material 4 is also integrally formed by hot-pressing, it can be manufactured with less productivity than the case where the sheet-like material 4 is attached later. Further, in the manufacturing process, the mat 4 as a mixture can be more easily transported because the sheet-like material 4 is laid underneath. [0114] [Other Embodiments]
- the sheet-like material 4 is molded and integrated together with the mats of the back surface layer and the surface layer.
- the sheet-like material 4 is formed and integrated together with the mats of the back layer, the core layer, and the surface layer.
- the back layer, the core layer, and the surface layer are integrated. After forming each mat, a sheet-like material may be bonded and integrated on the back surface thereof.
- the sheet-like material 4 is molded and integrated only using the lower side of the back layer mat.
- the sheet-like material is placed on the upper side of the surface layer mat, and this sheet-like material 3 Simultaneously with the formation of the mat of the layer and the lower sheet-like material 4, it can be formed by hot-pressing integrally. It is also possible to apply an adhesive to the sheet-like material used on the upper side. In this way, when the sheet-like materials are integrated up and down, an inorganic plate A having higher strength and balance can be obtained.
- the sheet-like material can be molded and integrated only by using it on the upper side of the three-layer mat.
- the sheet-like material is attached to at least one of the front and back surfaces of the inorganic plate (at least one surface).
- a glass nonwoven fabric (sheet-like material) with a basis weight of 50 g / m 2 coated with acrylic resin 30 g / m 2 (solid component) is pasted, and an inorganic plate with a thickness of 3 mm and a density of 1.2 g / cm 3 is attached. Obtained.
- the first mixture obtained by mixing in the same manner as described above was formed on the core layer mat to form a surface layer mat.
- the three-layer mat performs hot press of 210 ° C5 minutes to obtain 9mm thickness, the inorganic board of density 0. 8 g / cm 3.
- the first mixture obtained by mixing in the same manner as described above was formed on the core layer mat to form a surface layer mat.
- the three-layer mat performs hot press of 210 ° C5 minutes to obtain 9mm thickness, the inorganic board of density 0. 8 g / cm 3.
- the moisture absorption / release performance was measured in accordance with JIS A 1470-1, and it was 18 g / m 2 in Example 7, but 72 g / m 2 was measured in Example 8. I was able to.
- the three-layer mat was hot-pressed at 210 ° C for 3 minutes to obtain an inorganic plate having a thickness of 9 mm and a density of 0.8 g / cm 3 .
- this comparative example 5 had a low surface hardness and a poor smoothness.
- the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface mat.
- the three-layer mat was hot-pressed at 210 ° C for 3 minutes to obtain an inorganic plate having a thickness of 9 mm and a density of 0.8 g / cm 3 .
- fiber lumps fiber clumps
- the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface layer mat.
- the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface layer mat.
- the present invention provides a high-strength inorganic plate excellent in surface smoothness, nonflammability, handleability, workability, and workability, and thus is extremely useful and highly industrially applicable.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Description
明 細 書 Specification
無機質板及びその製造方法 Inorganic board and method for producing the same
技術分野 Technical field
[0001] 本発明は、住宅等建築物の内装材、天井材、軒天材等の基材として用いるのに好 適な化粧用の無機質板及びその製造方法に関する。 [0001] The present invention relates to a cosmetic inorganic board suitable for use as a base material for interior materials, ceiling materials, eave roof materials, etc. of buildings such as houses, and a method for producing the same.
背景技術 Background art
[0002] 従来より、住宅等建築物の内装仕上げ材ゃ家具等の化粧面材の基板としては、合 板や MDF等の木質系ボード、石膏ボードゃ珪酸カルシウム板等の無機系ボードが ある。これらの表面に良好に化粧層を設けるには、サンディング等で平滑性を得るよ うにするか、或いは塗料を厚く重ねて塗る塗装を施すことが考えられる。 [0002] Conventionally, as an interior finishing material of a building such as a house, a board for a decorative surface material such as furniture, there is a wood board such as plywood or MDF, and an inorganic board such as a plaster board or calcium silicate board. In order to satisfactorily provide a decorative layer on these surfaces, it is conceivable to obtain smoothness by sanding or the like, or to apply a coating with a thick layer of paint.
[0003] そして、塗装や印刷によって鏡面状仕上げのような平滑な化粧層を形成しょうとす る場合、基板表面にさらに高レベルの平滑性を必要とする力 サンディング等では必 ずしも十分な平滑性が得られるものではなかった。また、塗料を厚く重ねて塗る塗装 を施す場合、その塗装工程によって生産性が低くなり、コストも上昇する。 [0003] And, when trying to form a smooth decorative layer such as a mirror-like finish by painting or printing, force sanding that requires a higher level of smoothness on the substrate surface is always sufficient. Smoothness was not obtained. Also, when applying paints that are thickly layered, the coating process reduces productivity and increases costs.
[0004] そこで、例えば特許文献 1に示されるように、鉱物質繊維と無機質粉状体と結合剤 とを必須成分として含む原料を混合分散させてスラリーを形成し、湿式抄造して得た ウエットマットを乾燥させてサンデイングした後、加熱圧縮して結合剤を硬化させて、 良好に化粧層を得ることができる無機質板の製造方法が提案されている。 [0004] Therefore, for example, as shown in Patent Document 1, a wet material obtained by mixing and dispersing a raw material containing mineral fibers, an inorganic powder, and a binder as essential components to form a slurry and wet papermaking There has been proposed a method for producing an inorganic board that can obtain a decorative layer satisfactorily by drying a mat and sanding it, followed by heating and compression to cure the binder.
特許文献 1 :特開 2005— 289784号公報 Patent Document 1: Japanese Patent Laid-Open No. 2005-289784
発明の開示 Disclosure of the invention
発明が解決しょうとする課題 Problems to be solved by the invention
[0005] しかしながら、上記従来の特許文献 1のものでは、ドライボードを加熱圧縮前にサン デイングして平滑にして!/、るので、鉱物質繊維や無機質粉状体が結合剤に対ししつ 力、りと硬化固着しておらず、サンディング時に基材が全体的又は部分的に剥がれ易 いという問題がある。そのため、所望の厚さの無機質板が得られ難ぐまた、材料歩留 まりが低くなりがちで、生産効率が高くなぐ改良の余地がある。 [0005] However, in the above-mentioned conventional Patent Document 1, since the dry board is sanded and smoothed before heating and compression! /, Mineral fibers and inorganic powders are resistant to the binder. There is a problem that the base material is easily peeled off completely or partially during sanding because it is not hardened and fixed firmly. Therefore, it is difficult to obtain an inorganic plate having a desired thickness, and there is room for improvement in which the material yield tends to be low and the production efficiency is high.
[0006] また、より平滑性を得るためには、微細な無機質繊維や微細な無機質粉状体を使 用することも考えられる。しかし、その場合、結合剤も多く必要となり、そのため、不燃 性が低下するという問題がある。 [0006] In order to obtain more smoothness, fine inorganic fibers or fine inorganic powders are used. It is also possible to use it. However, in this case, a large amount of binder is required, which causes a problem that nonflammability is reduced.
[0007] 本発明は斯かる点に鑑みてなされたもので、その目的は、平滑性が高ぐ良好な化 粧層が得られる無機質板を生産性よく製造できるようにすることにある。 [0007] The present invention has been made in view of such points, and an object of the present invention is to make it possible to produce with high productivity an inorganic board from which a good decorative layer having high smoothness can be obtained.
課題を解決するための手段 Means for solving the problem
[0008] 上記の目的を達成するために、第 1の発明の無機質板は、長さ 3〜; 15mmの無機 繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、 結合剤 5〜; 15重量%とを有する裏面層、及び、長さ lmm以下の無機繊維 10〜70 重量%と、粒径 500 ^ 111以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70 重量%と、結合剤 3〜; 10重量%とを有する表面層が一体化されて成形されてなること を特徴とする。 [0008] In order to achieve the above object, the inorganic board of the first invention comprises an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight; a lightweight aggregate of 10 to 70% by weight; and an inorganic powder. 10 to 70% by weight of a solid body, 5 to 15% by weight of a binder, and 10 to 70% by weight of inorganic fibers having a length of 1 mm or less and a lightweight aggregate having a particle size of 500 ^ 111 or less 10 It is characterized in that a surface layer having ˜50 wt%, inorganic powder 10-70 wt%, and binder 3˜; 10 wt% is integrally formed.
[0009] この第 1の発明の構成によると、無機質板の表面層に、長さ lmm以下の微細な無 機繊維と、粒径 500 m以下の軽量骨材とが使用されているので、緻密な表面層を 得ること力 Sでさる。 [0009] According to the configuration of the first invention, fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer of the inorganic board. A force S to obtain a good surface layer.
[0010] また、裏面層は、長さ 3〜; 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重 量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを有する層である ので、この裏面層の方が表面層と比較して板として強度があるものとなる。このことで 、裏面層により表面層を支える(裏面層を表面層と一体化することで、相対的には強 度の低い表面層を補強 ·補完する)ことができ、裏面層と表面層との一体化により強 度のある無機質板を得ることができる。 [0010] Further, the back layer is made of an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powdery material of 10 to 70% by weight, and a binder. Since this is a layer having 5 to 15% by weight, this back layer is stronger as a plate than the front layer. As a result, the surface layer can be supported by the back surface layer (by integrating the back surface layer with the surface layer, the relatively low strength surface layer can be reinforced and supplemented). A strong inorganic plate can be obtained by integrating the above.
[0011] し力、も、この裏面層は、長さ 3〜; 15mmの無機繊維を使用するので、他の成分であ る軽量骨材や無機質粉状体や結合剤との混合バランスがよくてダマ (繊維の塊)にな り難ぐ無機繊維を均一に分散混合することができる。このため、より強度や硬度のあ る裏面層を得ることができ、表面層をしつ力、り支えることができる。 [0011] This back layer uses inorganic fibers with a length of 3 to 15 mm, and therefore has a good mixing balance with other components such as lightweight aggregates, inorganic powders and binders. It is possible to uniformly disperse and mix inorganic fibers that do not easily become lumps (fiber lump). For this reason, a back layer having higher strength and hardness can be obtained, and the surface layer can be supported and supported.
[0012] これらの相乗的な作用により、全体として不燃性、取扱性、加工性、施工性に優れ 、高強度の無機質板を得ることができる。 [0012] By these synergistic actions, it is possible to obtain a high-strength inorganic plate that is excellent in incombustibility, handleability, workability, and workability as a whole.
[0013] 第 2の発明では、上記第 1の発明に係る無機質板の裏面にシート状物を一体化す る。この構成によると、裏面層にシート状物が一体化されているので、割れ難くて強度 のある無機質板が得られる。 In the second invention, the sheet-like material is integrated with the back surface of the inorganic board according to the first invention. According to this configuration, since the sheet-like material is integrated with the back surface layer, it is difficult to break and is strong. An inorganic plate with a thickness of 10 mm is obtained.
[0014] 第 3及び第 4の発明は無機質板の製造方法に係るものである。第 3の発明の無機 質板の製造方法では、長さ 3〜; 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜7 0重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを有し、水が加 えられて含水率 5〜; 15%に調整された混合物をフォーミングして裏面層マットを形成 する工程、この裏面層マットの上に、さらに長さ lmm以下の無機繊維 10〜70重量 %と、粒径 500 ^ 111以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量 %と、結合剤 3〜; 10重量%とを有し、水が加えられて含水率 5〜; 15%に調整された 混合物をフォーミングして表面層マットを形成する工程、及び、上記裏面層及び表面 層の 2層のマットを熱圧プレスして一体に成形する工程を備えたことを特徴とする。 [0014] The third and fourth inventions relate to a method for producing an inorganic plate. In the method for producing an inorganic board of the third invention, the length of 3 to 15 mm of inorganic fibers;! To 10 wt%, lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% And forming a back surface layer mat by forming a mixture having a binder of 5 to 15% by weight and water added to adjust the water content to 5 to 15%, Furthermore, 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ^ 111 or less, 10 to 70% by weight of an inorganic powder, and a binder of 3 to Forming a surface layer mat by forming a mixture having a water content of 5 to 10% and having a water content of 5 to 15% adjusted to 15%, and two layers of the back layer and the surface layer. It is characterized by comprising a step of forming the mat integrally by hot pressing.
[0015] この第 3の発明の構成によると、上記工程を経て製造された無機質板の裏面層は、 長さ 3〜; 15mmの無機繊維が使用されているので、他の成分である軽量骨材や無機 質粉状体、結合剤との混合バランスがよくてダマ (繊維の塊)になり難ぐその無機繊 維が均一に分散混合する。このため、より強度や硬度がある無機質板を得ることがで きる。 [0015] According to the configuration of the third aspect of the invention, the back surface layer of the inorganic board manufactured through the above steps uses inorganic fibers having a length of 3 to 15 mm. The inorganic fiber, which has a good mixing balance with the material, the inorganic powder, and the binder and does not easily become a lump (fiber lump), is uniformly dispersed and mixed. For this reason, an inorganic board with higher strength and hardness can be obtained.
[0016] また、裏面層及び表面層の各マットは含水率 5〜; 15%に調整されているので、短 時間かつ高温で加熱圧縮を行って結合剤を反応させることができる。また、高温及び 高圧下であるので、結合剤の流動性が上がって全体に行き渡らせることができ、かつ 、水分を短時間で蒸発させることができる。このことで、結合剤の性能を最大限に引き 出すことができるだけでなぐ結合剤の量も比較的少なくでき、不燃性に優れた強固 な無機質板が短時間で得られる。 [0016] Further, since the mats of the back layer and the surface layer are adjusted to a moisture content of 5 to 15%, the binder can be reacted by performing heat compression at a high temperature for a short time. Moreover, since it is under high temperature and high pressure, the fluidity | liquidity of a binder can go up and it can spread over the whole, and a water | moisture content can be evaporated in a short time. As a result, the amount of the binder can be made relatively small in order to maximize the performance of the binder, and a strong inorganic board excellent in incombustibility can be obtained in a short time.
[0017] さらに、裏面層及び表面層の各マットの含水率が 5〜; 15%に調整されていることで 、熱圧プレス時にパンクが発生し難ぐ生産性もよい。 [0017] Further, the moisture content of each mat of the back surface layer and the front surface layer is adjusted to 5 to 15%, so that the productivity in which puncture hardly occurs at the time of hot press is good.
[0018] 第 4の発明の無機質板の製造方法では、長さ 3〜; 15mmの無機繊維;!〜 10重量% と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量 %とを有し、水が加えられて含水率 5〜; 15%に調整された混合物をシート状物上で フォーミングして裏面層マットを形成する工程、上記裏面層マットの上に、さらに長さ 1 mm以下の無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜50重量 %と、無機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とを有し、水が加えられ て含水率 5〜; 15%に調整された混合物をフォーミングして表面層マットを形成するェ 程、及び、上記裏面層及び表面層の 2層のマットとシート状物とを熱圧プレスして一 体に成形する工程を備えたことを特徴とする。 [0018] In the method for producing an inorganic plate of the fourth invention, the length of 3 to 15 mm inorganic fiber;! To 10 wt%, light aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% And forming a back surface mat by forming a mixture adjusted to a water content of 5 to 15% by adding water and forming a mixture on a sheet-like material. On the back layer mat, 10 to 70% by weight of inorganic fibers with a length of 1 mm or less and lightweight aggregate with a particle size of 500 m or less 10 to 50% Surface layer by forming a mixture of 10% to 70% by weight of inorganic powder, 10% to 70% by weight of binder, and 10% by weight of water and adjusted to a water content of 5 to 15% by adding water. The step of forming the mat and the step of hot pressing the two mats of the back layer and the front layer and the sheet-like material to form them together.
[0019] この第 4の発明の構成によると、上記第 3の発明の効果に加え、シート状物も 2層の マットと共に一体的に熱圧プレスして成形するので、割れ難く強度のある無機質板が 得られる。また、後でシート状物を貼着する場合よりも工程が少なぐ生産性よく製造 できる。さらに、製造工程上においても、シート状物が下に敷いてあることで、混合物 であるマット運搬がより容易となる。 [0019] According to the configuration of the fourth invention, in addition to the effect of the third invention, the sheet-like material is also formed by hot-pressing integrally with the two-layer mat, so that it is difficult to break and is a strong inorganic material. A board is obtained. Further, it can be manufactured with good productivity with fewer steps than when a sheet-like material is pasted later. Furthermore, in the manufacturing process, the mat-like material, which is a mixture, can be transported more easily because the sheet-like material is laid underneath.
[0020] 第 5の発明に係る無機質板は、芯層と、この芯層の表面に一体化された表層と、芯 層の裏面に一体化された裏層とを備えてなり、上記表層及び裏層が、長さ lmm以下 の無機繊維 10〜70重量%と、粒径 500 111以下の軽量骨材 10〜50重量%と、無 機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とを有し、上記芯層が、長さ 3〜 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10 〜70重量%と、結合剤 5〜; 15重量%とを有するものとする。 [0020] An inorganic plate according to a fifth invention comprises a core layer, a surface layer integrated on the surface of the core layer, and a back layer integrated on the back surface of the core layer. 10 to 70% by weight of inorganic fiber with a length of lmm or less, 10 to 50% by weight of light-weight aggregate with a particle size of 500 111 or less, 10 to 70% by weight of organic powder, and binder 3 10% by weight, and the core layer is an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, lightweight aggregate 10 to 70% by weight, and inorganic powder 10 to 70% by weight And 5 to 15% by weight of a binder.
[0021] この第 5の発明の構成によると、表層及び裏層にそれぞれ長さ lmm以下の微細な 無機繊維と、粒径 500 m以下の軽量骨材とが使用されているので、緻密な表層及 び裏層を得ること力できる。 [0021] According to the configuration of the fifth aspect of the invention, fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer and the back layer, respectively. And can gain the back layer.
[0022] また、これら表層及び裏層間にある芯層は、長さ 3〜; 15mmの無機繊維 1〜; 10重 量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15 重量%とを有する層であるので、この芯層の方が表層及び裏層と比較して板として強 度があるものとなり、芯層により表層及び裏層を支える(芯層を裏層及び表層と一体 化することで、相対的には強度の低い表層及び裏層を補強 ·補完する)ことができ、 芯層と表層及び裏層との一体化により強度のある無機質板を得ることができる。 [0022] Further, the core layer between the surface layer and the back layer is composed of 3 to 15 mm in length of inorganic fiber 1 to 10% by weight, light aggregate 10 to 70% by weight, and inorganic powder 10 to 10%. Since the layer has 70% by weight and a binder of 5 to 15% by weight, the core layer is stronger as a plate than the surface layer and the back layer. Supports the layer (by integrating the core layer with the back layer and the surface layer, the relatively low strength surface layer and back layer can be reinforced and supplemented), and the core layer, the surface layer and the back layer are integrated. Thus, a strong inorganic plate can be obtained.
[0023] し力、も、芯層は、長さ 3〜; 15mmの無機繊維を使用するので、他の成分である軽量 骨材や無機質粉状体、結合剤との混合バランスが良くてダマ (繊維の塊)になり難ぐ 無機繊維を均一に分散混合することができる。このため、より強度や硬度のある芯層 を得ることができ、表層及び裏層をより一層しつ力、り支えることができる。 [0024] これらの相乗的な作用により、全体として不燃性、取扱性、加工性、施工性に優れ 、高強度の無機質板を得ることができる。 [0023] Since the core layer uses inorganic fibers with a length of 3 to 15 mm, the mixing balance with other components such as lightweight aggregates, inorganic powders, and binders is good. Inorganic fibers that are difficult to become (fiber aggregates) can be uniformly dispersed and mixed. For this reason, a core layer having higher strength and hardness can be obtained, and the surface layer and the back layer can be further supported and supported. [0024] By these synergistic actions, it is possible to obtain a high-strength inorganic board that is excellent in nonflammability, handleability, workability, and workability as a whole.
[0025] 第 6の発明では、上記第 5の発明に係る無機質板において、その表裏面の少なくと も一方 (少なくとも片面)にシート状物が貼着一体化されていることを特徴とする。この 構成によると、表裏面の少なくとも一方にシート状物が貼着されているので、割れ難く て強度のある無機質板が得られる。 [0025] The sixth invention is characterized in that in the inorganic plate according to the fifth invention, a sheet-like material is bonded and integrated on at least one (at least one side) of the front and back surfaces. According to this configuration, since the sheet-like material is adhered to at least one of the front and back surfaces, an inorganic plate that is hard to break and strong is obtained.
[0026] 第 7及び第 8の発明は無機質板の製造方法に係るものである。第 7の発明の無機 質板の製造方法では、長さ lmm以下の無機繊維 10〜70重量%と、粒径 500 μ m 以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜; 10 重量%とを有し、水が加えられて含水率 5〜; 15%に調整された混合物をフォーミング して裏層マットを形成する工程、この裏層マットの上に、長さ 3〜; 15mmの無機繊維 1 〜; 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合 剤 5〜; 15重量%とを有し、水が加えられて含水率 5〜; 15%に調整された混合物をフ ォーミングして 2層目の芯層マットを形成する工程、これら 2層のマットの上に、さらに 長さ lmm以下の無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜5 0重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とを有し、水が加 えられて含水率 5〜; 15%に調整された混合物をフォーミングして 3層目の表層マット を形成する工程、及び、上記 3層のマットを熱圧プレスで一体に成形する工程を備え たことを特徴とする。 [0026] The seventh and eighth inventions relate to a method for producing an inorganic plate. In the method for producing an inorganic board of the seventh invention, 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 μm or less, and 10 to Forming a back layer mat by forming a mixture having 70% by weight and a binder of 3 to 10% by weight and water added to adjust the water content to 5 to 15%, the back layer On a mat, 3 to 15 mm in length, 1 to 10% inorganic fiber, 10 to 70% light-weight aggregate, 10 to 70% inorganic powder, and 5 to 15% binder Forming a second-layer core mat by forming a mixture adjusted to a water content of 5 to 15% by adding water to 15%, and on the two-layer mat, 10 to 70% by weight of inorganic fibers with a length of lmm or less, 10 to 50% by weight of light aggregate with a particle size of 500 m or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder And have water And forming a third layer mat by forming a mixture adjusted to a moisture content of 5 to 15% and forming the third layer mat integrally with a hot press. It is characterized by that.
[0027] この第 7の発明の構成によると、上記工程を経て製造された無機質板の芯層は、長 さ 3〜; 15mmの無機繊維が使用されているので、他の成分である軽量骨材や無機質 粉状体、結合剤との混合バランスが良くてダマ (繊維の塊)になり難ぐその無機繊維 が均一に分散混合する。このため、より強度や硬度のある芯層を得ることができ、表 層及び裏層をしつ力、り支えることができる。 [0027] According to the structure of the seventh invention, the core layer of the inorganic board manufactured through the above steps uses inorganic fibers having a length of 3 to 15 mm, so that lightweight bone which is another component is used. The inorganic fibers, which have a good mixing balance with materials, inorganic powders, and binders and do not easily become lumps (fiber lump), are uniformly dispersed and mixed. Therefore, a core layer having higher strength and hardness can be obtained, and the surface layer and the back layer can be supported and supported.
[0028] また、各層のマットは含水率が 5〜; 15%に調整されているので、短時間かつ高温で 加熱圧縮を行って結合剤を反応させることができる。また、高温及び高圧下であるの で、結合剤の流動性が上がって全体に行き渡らせることができ、かつ、水分を短時間 で蒸発させること力できる。このことで、結合剤の性能を最大限に引き出すことができ るだけでなぐ結合剤の量も比較的少なくでき、不燃性に優れた強固な無機質板が 短時間で得られる。 [0028] Further, since the moisture content of each mat is adjusted to 5 to 15%, the binder can be reacted by heating and compressing at a high temperature in a short time. In addition, because of high temperature and high pressure, the fluidity of the binder can be increased and distributed throughout, and the water can be evaporated in a short time. This maximizes the performance of the binder. As a result, the amount of the binder can be made relatively small, and a strong inorganic board excellent in incombustibility can be obtained in a short time.
[0029] さらに、各層のマットの含水率が 5〜; 15%に調整されていることで、熱圧プレス時に パンクが発生し難くなり、生産性も良くなる。 [0029] Further, by adjusting the moisture content of the mat of each layer to 5 to 15%, puncture hardly occurs at the time of hot press, and productivity is improved.
[0030] 第 8の発明に係る無機質板の製造方法は、長さ lmm以下の無機繊維 10〜70重 量%と、粒径 500 ^ 111以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重 量%と、結合剤 3〜; 10重量%とを有し、水が加えられて含水率 5〜; 15%に調整され た混合物をシート状物上でフォーミングして裏層マットを形成する工程、この裏層マツ トの上に、長さ 3〜; 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、 無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを有し、水が加えられて含 水率 5〜; 15%に調整された混合物をフォーミングして 2層目の芯層マットを形成する 工程と、これら 2層のマットの上に、さらに長さ lmm以下の無機繊維 10〜70重量% と、粒径 500 ^ 111以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量% と、結合剤 3〜; 10重量%とを有し、水が加えられて含水率 5〜; 15%に調整された混 合物をフォーミングして 3層目の表層マットを形成する工程、及び、上記 3層のマットと シート状物とを熱圧プレスで一体に成形する工程を備えたことを特徴とする。 [0030] The method for producing an inorganic board according to the eighth invention comprises 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ^ 111 or less, and an inorganic powder. 10% to 70% by weight of a compact and 3% to 10% by weight of a binder, and a mixture adjusted to a water content of 5% to 15% by adding water is formed on a sheet and back. Step of forming a layer mat, on this back layer mat, 3 to 15 mm long inorganic fiber;! To 10 wt%, lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 Forming a second core layer mat by forming a mixture having 5% by weight and a binder of 5 to 15% by weight and water added to adjust the water content to 5 to 15% And 10 to 70% by weight of inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ^ 111 or less, and inorganic powders 10 to 70 on these two-layer mats. % By weight and binder 3 Forming a third-layer surface mat by forming a mixture having a water content of 5 to 10% by weight and having a water content of 5 to 15%; 15%, and the three-layer mat And a step of integrally forming the sheet-like material with a hot press.
[0031] この第 8の発明の構成によると、上記第 7の発明の効果に加え、シート状物も 3層の マットと共に一体的に熱圧プレスして成形するので、割れ難く強度のある無機質板が 得られる。また、後でシート状物を貼着する場合よりも工程が少なぐ生産性よく製造 できる。さらに、製造工程上においても、シート状物が下に敷いてあることで、混合物 であるマット運搬がより容易となる。 [0031] According to the configuration of the eighth invention, in addition to the effect of the seventh invention, since the sheet-like material is also integrally formed by hot-pressing together with the three-layer mat, it is hard to break and is a strong inorganic material. A board is obtained. Further, it can be manufactured with good productivity with fewer steps than when a sheet-like material is pasted later. Furthermore, in the manufacturing process, the mat-like material, which is a mixture, can be transported more easily because the sheet-like material is laid underneath.
発明の効果 The invention's effect
[0032] 以上説明したように、第 1の発明によると、無機質板を裏面層と表面層との 2層を一 体に成形したものとし、裏面層は長さ 3〜; 15mmの無機繊維 1〜; 10重量%と、軽量 骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを 有するものとし、表面層は長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 ^ 111以下の軽量骨材10〜50重量%と、無機質粉状体 10〜70重量%と、結合 剤 3〜; 10重量%とを有するものとしたことにより、表面平滑性、不燃性、取扱性、加工 性及び施工性に優れた高強度の無機質板が得られる。 [0032] As described above, according to the first invention, it is assumed that the inorganic plate is formed by combining two layers of the back surface layer and the surface layer, and the back surface layer has a length of 3 to; ~; 10% by weight, lightweight aggregate 10-70% by weight, inorganic powder 10-70% by weight, binder 5 ~; 15% by weight, and the surface layer has a length of lmm or less 10 to 70% by weight of fine inorganic fibers, 10 to 50% by weight of light-weight aggregate having a particle size of 500 ^ 111 or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder By adopting, surface smoothness, nonflammability, handleability, processing A high-strength inorganic plate excellent in workability and workability is obtained.
[0033] 第 2の発明によると、上記第 1の発明の効果に加えて、裏面層に一体化されたシー ト状物により、割れ難ぐ強度のある無機質板が得られる。 [0033] According to the second invention, in addition to the effects of the first invention, the sheet-like material integrated with the back surface layer provides an inorganic plate that is hard to crack.
[0034] 第 3の発明によると、長さ 3〜; 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜7 0重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とに水を加えて 含水率 5〜; 15%に調整された混合物をフォーミングして裏面層マットを形成し、この 裏面層マット上に、長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜1 0重量%とに水を加えて含水率 5〜; 15%に調整された混合物をフォーミングして表面 層マットを形成し、これら裏面層及び表面層の 2層のマットを熱圧プレスで一体に成 形することにより、表面平滑性、不燃性、取扱性、加工性及び施工性に優れた高強 度の無機質板が生産性よく得られる。 [0034] According to the third invention, a length of 3 to 15 mm inorganic fiber;! To 10 wt%, lightweight aggregate 10 to 70 wt%, and inorganic powder 10 to 70 wt% Agent 5 ~; Add water to 15% by weight and form a mixture adjusted to a moisture content 5 ~; 15% to form a back surface layer mat. On this back surface layer mat, a fine lmm or less in length Add water to 10 to 70% by weight of inorganic fiber, 10 to 50% by weight of light aggregate with particle size of 500 m or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder. Surface smoothness is achieved by forming a surface layer mat by forming a mixture adjusted to a moisture content of 5 to 15%, and forming the back layer and the surface layer in one piece by hot pressing. High-strength inorganic plates with excellent nonflammability, handleability, workability and workability can be obtained with high productivity.
[0035] 第 4の発明によると、上記裏面層マット用の混合物をシート状物上でフォーミングし て裏面層マットを形成し、その裏面層マット上に表面層マット用の混合物をフォーミン グして表面層マットを形成し、これら裏面層及び表面層の 2層のマットとシート状物と を熱圧プレスで一体に成形することにより、第 3の発明の効果に加えて、割れ難く強 度のある無機質板が得られる。また、後でシート状物を貼着する場合よりも工程が少 なくて、無機質板を生産性よく製造できるとともに、製造工程においてもマットの運搬 力はり容易となる。 [0035] According to the fourth invention, the mixture for the back surface layer mat is formed on a sheet to form a back surface layer mat, and the mixture for the surface layer mat is formed on the back surface layer mat. By forming a surface layer mat and integrally forming the back surface layer and the two surface layer mats with a sheet-like material by a hot press, in addition to the effects of the third invention, the surface layer mat is hard to crack and has a high strength. A certain inorganic board is obtained. In addition, the number of processes is less than when sheet-like materials are attached later, and the inorganic board can be manufactured with high productivity, and the carrying power of the mat becomes easy in the manufacturing process.
[0036] 第 5の発明によると、無機質板を裏層と表層とこれらの間に位置する芯層との 3層を 一体化したものとし、芯層は長さ 3〜; 15mmの無機繊維 1〜; 10重量%と、軽量骨材 1 0〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを有する ものとし、表層及び裏層は長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 ^ 111以下の軽量骨材10〜50重量%と、無機質粉状体 10〜70重量%と、結合 剤 3〜; 10重量%とを有するものとしたことにより、表面平滑性、不燃性、取扱性、加工 性及び施工性に優れた高強度の無機質板が得られる。 [0036] According to the fifth invention, the inorganic plate is formed by integrating three layers of a back layer, a surface layer, and a core layer located between them, and the core layer has an inorganic fiber length of 3 to 15 mm. ~; 10% by weight, lightweight aggregate 10 ~ 70% by weight, inorganic powder 10 ~ 70% by weight, binder 5 ~; 15% by weight, surface and back layers are length 10 to 70% by weight of fine inorganic fibers of lmm or less, 10 to 50% by weight of light aggregate having a particle size of 500 ^ 111 or less, 10 to 70% by weight of inorganic powder, and 3 to 10% by weight of binder Therefore, a high-strength inorganic board excellent in surface smoothness, non-flammability, handleability, workability and workability can be obtained.
[0037] 第 6の発明によると、第 5の発明の効果に加えて、表裏面の少なくとも一方に一体 化されたシート状物により、割れ難ぐ強度のある無機質板が得られる。 [0038] 第 7の発明によると、長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 ^ 111以下の軽量骨材10〜50重量%と、無機質粉状体 10〜70重量%と、結合剤 3 〜; 10重量%とに水を加えて含水率 5〜; 15%に調整された混合物をフォーミングして 裏層マットを形成し、この裏層マット上に、長さ 3〜; 15mmの無機繊維 1〜; 10重量% と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量 %とに水を加えて含水率 5〜; 15%に調整された混合物をフォーミングして芯層マット を形成し、この芯層マット上に、裏層マットと同様の表層マットを形成し、これら 3層の マットを熱圧プレスで一体に成形することにより、表面平滑性、不燃性、取扱性、加工 性及び施工性に優れた高強度の無機質板が生産性よく得られる。 [0037] According to the sixth invention, in addition to the effects of the fifth invention, an inorganic plate having strength that is difficult to break can be obtained by the sheet-like material integrated with at least one of the front and back surfaces. [0038] According to the seventh invention, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of light aggregate having a particle size of 500 ^ 111 or less, and an inorganic powder 10 to 70% The mixture was adjusted to a water content of 5% to 15% by adding water to 3% by weight; a binder of 3 to; 10% by weight to form a back layer mat. 3 ~; 15mm inorganic fiber 1 ~; 10% by weight, light aggregate 10 ~ 70% by weight, inorganic powder 10 ~ 70% by weight, binder 5 ~; A mixture adjusted to a moisture content of 5 to 15% is formed to form a core layer mat. On the core layer mat, a surface layer mat similar to the back layer mat is formed, and these three layer mats are hot-pressed. By integrally forming with a press, a high-strength inorganic plate excellent in surface smoothness, incombustibility, handleability, workability and workability can be obtained with high productivity.
[0039] 第 8の発明によると、上記第 7の発明と同様の裏層マット用の混合物をシート状物上 でフォーミングして裏層マットを形成し、その裏層マット上に第 7の発明と同様の芯層 マット用の混合物をフォーミングして芯層マットを形成し、この芯層マット上に、裏層マ ット用混合物と同じ表層マット用の混合物をフォーミングして表層マットを形成し、これ ら 3層のマットとシート状物とを熱圧プレスで一体に成形することにより、第 7の発明の 効果に加えて、割れ難く強度のある無機質板が得られる。また、後でシート状物を貼 着する場合よりも工程が少なくて、無機質板を生産性よく製造できるとともに、製造ェ 程においてもマットの運搬がより容易となる。 [0039] According to the eighth invention, a mixture for a back layer mat similar to that of the above seventh invention is formed on a sheet to form a back layer mat, and the seventh invention is formed on the back layer mat. A core layer mat is formed by forming a core layer mat similar to the above, and a surface mat is formed on the core layer mat by forming the same surface mat mixture as the back layer mat. In addition to the effects of the seventh invention, an inorganic plate that is hard to break and strong is obtained by integrally molding these three-layer mat and sheet-like material with a hot press. In addition, the number of steps is smaller than when a sheet-like material is attached later, and the inorganic board can be manufactured with high productivity, and the mat can be transported more easily in the manufacturing process.
図面の簡単な説明 Brief Description of Drawings
[0040] [図 1]図 1は、本発明の実施形態 1に係る無機質板の断面図である。 FIG. 1 is a cross-sectional view of an inorganic plate according to Embodiment 1 of the present invention.
[図 2]図 2は、実施形態 2に係る無機質板の断面図である。 FIG. 2 is a cross-sectional view of an inorganic plate according to Embodiment 2.
[図 3]図 3は、実施形態 3に係る無機質板の断面図である。 FIG. 3 is a cross-sectional view of an inorganic plate according to Embodiment 3.
[図 4]図 4は、実施形態 4に係る無機質板の断面図である。 FIG. 4 is a cross-sectional view of an inorganic plate according to Embodiment 4.
[図 5]図 5は、実施例;!〜 6及び比較例;!〜 4の諸特性を示す図である。 FIG. 5 is a diagram showing various characteristics of Examples;! To 6 and Comparative Example;! To 4;
[図 6]図 6は、実施例 7, 8及び比較例 5〜8の諸特性を示す図である。 FIG. 6 is a graph showing various characteristics of Examples 7 and 8 and Comparative Examples 5 to 8.
符号の説明 Explanation of symbols
[0041] A 無機質板 [0041] A inorganic board
1 表面層 1 Surface layer
2 裏面層 3 芯層 2 Back layer 3 core layer
4 シート状物 4 Sheet
11 表層 11 Surface
12 裏層 12 Back layer
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
[0042] 以下、本発明の実施形態を図面に基づいて詳細に説明する。以下の好ましい実施 形態の説明は、本質的に例示に過ぎず、本発明、その適用物或いはその用途を制 限することを意図するものでは全くなレ、。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. The following description of preferred embodiments is merely exemplary in nature and is not intended to limit the present invention, its application, or its use.
[0043] [実施形態 1] [0043] [Embodiment 1]
図 1は本発明の実施形態 1に係る無機質板 Aを示す。この無機質板 Aは、その表面 側(図 1上側)に位置する表面層 1と、裏面側(図 1下側)に位置する裏面層 2とが一 体化されて成形されてなるものである。 FIG. 1 shows an inorganic plate A according to Embodiment 1 of the present invention. This inorganic plate A is formed by integrating a surface layer 1 located on the front surface side (upper side in FIG. 1) and a back surface layer 2 located on the rear surface side (lower side in FIG. 1). .
[0044] (表面層) [0044] (Surface layer)
上記表面層 1は、長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜1 0重量%とを有する。 The surface layer 1 is composed of 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 m or less, and 10 to 70% by weight of an inorganic powder. 3 to 10% by weight of the agent.
[0045] (1)微細な無機繊維 [0045] (1) Fine inorganic fibers
上記微細な無機繊維は、マットを形成し、粘りと強度とを持たせつつ、高い表面性 を得るために添加されるものであり、例えば粉砕されたロックウール、スラグウール、ガ ラス繊維等が挙げられる。この微細な無機繊維は、固形成分全体の 10〜70重量%( 10重量%以上でかつ 70重量%以下)添加される。この無機繊維の添加量が 10重量 %未満であると、マットの形成が難しくなり、粘りがなくなる一方、 70重量%を超えると 、相対的に他の軽量骨材や無機質粉状体が少なくなり、所望の強度が得られないた めである。また、繊維の長さとしては lmm以下の微細なものが望ましい。 lmmを超え ると、ダマ (繊維の塊)になり易ぐ表面性に悪影響を及ぼすためである。この表面層 1に加えられる「微細な無機繊維」とは、繊維としての性質や機能を残存しながらも大 きさの小さいものをいう。 The fine inorganic fibers are added to form a mat and have high stickiness and strength while obtaining high surface properties. For example, pulverized rock wool, slag wool, glass fibers, etc. Can be mentioned. The fine inorganic fibers are added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the entire solid component. If the added amount of the inorganic fiber is less than 10% by weight, it becomes difficult to form a mat and the stickiness is lost. On the other hand, if the added amount exceeds 70% by weight, other lightweight aggregates and inorganic powders are relatively reduced. This is because the desired strength cannot be obtained. In addition, it is desirable that the length of the fiber is as fine as 1 mm or less. This is because if it exceeds lmm, it will adversely affect the surface properties that tend to become lumps (fiber lump). The “fine inorganic fibers” added to the surface layer 1 are those having a small size while retaining the properties and functions of the fibers.
[0046] (2)軽量骨材 軽量骨材は、圧縮強度を確保しつつ、嵩を持たせるために添加されるものであり、 例えばパーライト、シラス発泡体、シリカフラワー、ガラス発泡体が挙げられる。軽量骨 材の使用される大きさは 500 H m以下、望ましくは 10〜500 m (10 m以上でか つ 500 m以下)である。この軽量骨材の大きさが 10 mよりも小さ!/、と、所定の嵩を 得ること力 Sできない。一方、軽量骨材の大きさが 500 mよりも大きくなると、表面性が 悪くなるだけでなぐ無機質板 Aの加工性も低下する。 [0046] (2) Lightweight aggregate The lightweight aggregate is added to increase the bulk while securing the compressive strength, and examples thereof include perlite, shirasu foam, silica flour, and glass foam. The size of the lightweight aggregate used is 500 Hm or less, preferably 10 to 500 m (10 m or more and 500 m or less). This lightweight aggregate is less than 10 m in size! On the other hand, when the size of the lightweight aggregate is larger than 500 m, the workability of the inorganic board A is deteriorated as well as the surface property is deteriorated.
[0047] この軽量骨材は固形成分全体の 10〜50重量% (10重量%以上でかつ 50重量% 以下)添加される。軽量骨材の添加量が 10重量%未満であると、嵩が低くなり、散布 時に均一に撒くことが難しくなる一方、 50重量%を超えると、圧締時の圧力が高くな り過ぎ、生産性が低下するためである。 [0047] This lightweight aggregate is added in an amount of 10 to 50% by weight (more than 10% by weight and less than 50% by weight) of the total solid components. If the amount of light aggregate added is less than 10% by weight, the bulk will be low and it will be difficult to spread uniformly during spraying, while if it exceeds 50% by weight, the pressure during pressing will be too high and production will occur. This is because the property decreases.
[0048] (3)無機質粉状体 [0048] (3) Inorganic powder
無機質粉状体は、防火性及び硬度を確保するために添加されるものであり、例え ば炭酸カルシウム、水酸化アルミニウム、水酸化マグネシウム、フライアッシュ、マイク 口シリカ、スラグ等が挙げられる。この無機質粉状体は、固形成分全体の 10〜70重 量% (10重量%以上でかつ 70重量%以下)が添加される。この無機質粉状体の添 加量が 10重量%未満であると、所望の表面硬度が得られない一方、 70重量%を超 えると、他の材料の添加率が相対的に少なくなり、所望の強度を得難くなるためであ The inorganic powder is added in order to ensure fire resistance and hardness, and examples thereof include calcium carbonate, aluminum hydroxide, magnesium hydroxide, fly ash, mic port silica, and slag. This inorganic powder is added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the entire solid component. If the added amount of the inorganic powder is less than 10% by weight, the desired surface hardness cannot be obtained. On the other hand, if the added amount exceeds 70% by weight, the addition rate of other materials becomes relatively small, and the desired amount of the desired surface hardness is reduced. It is difficult to obtain the strength of
[0049] (4)結合剤 [0049] (4) Binder
結合剤は、上記微細な無機繊維、軽量骨材、無機質粉状体を結合するために添 カロされるものであり、例えばメラミン樹脂、フエノール樹脂、 MDI、ウレタン樹脂、アタリ ル樹脂、エポキシ樹脂、ポバール、スターチ等が挙げられ、これらは単体又は組み合 わせで使用すること力できる。無機質板 Aの強度及び不燃性の両方を満足する結合 剤の添加量として、固形成分全体の 3〜; 10重量% (3重量%以上でかつ 10重量% 以下)が添加される。つまり、結合剤の添加量が 3重量%未満であると、強度が不足 する一方、 10重量%を越えると、不燃性が損なわれるからである。 The binder is added to bind the fine inorganic fibers, lightweight aggregates, and inorganic powders. For example, melamine resin, phenol resin, MDI, urethane resin, attal resin, epoxy resin, Examples include poval and starch, which can be used alone or in combination. The amount of the binder that satisfies both the strength and nonflammability of the inorganic board A is 3 to 10% by weight (more than 3% by weight and less than 10% by weight) of the total solid components. That is, if the added amount of the binder is less than 3% by weight, the strength is insufficient, whereas if it exceeds 10% by weight, the nonflammability is impaired.
[0050] 尚、無機質板 Aを外装用として用いる場合は耐水性の高い結合剤を選択すること が好ましい。 [0051] (5)補助添加剤 [0050] When the inorganic plate A is used for an exterior, it is preferable to select a binder having high water resistance. [0051] (5) Auxiliary additive
補助添加剤として、必要に応じてサイズ剤、カップリング剤等を添加してもよい。 As an auxiliary additive, a sizing agent, a coupling agent and the like may be added as necessary.
[0052] (裏面層) [0052] (Back layer)
上記裏面層 2は、長さ 3〜; 15mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重 量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量%とを有する。 The back layer 2 is composed of an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powdery material of 10 to 70% by weight, and a binder of 5 to; 15% by weight.
[0053] (1)無機繊維 [0053] (1) Inorganic fiber
上記無機繊維は、マットを形成し、粘りと強度とを持たせるために添加されるもので あり、例えばガラス繊維、ワラストナイト等が挙げられる。この無機繊維は、固形成分 全体の;!〜 10重量% (1重量%以上でかつ 10重量%以下)添加される。無機繊維の 添加量が 1重量%未満であると、マットの形成が難しくなり、粘りがなくなる一方、 10 重量%を超えると、混合時に分離が起こるためである。例えばガラス繊維では、チヨッ プドストランドのような束状のものを使用すると、扱い易ぐ生産上好ましい。 The inorganic fiber is added in order to form a mat and to have stickiness and strength, and examples thereof include glass fiber and wollastonite. This inorganic fiber is added from! To 10 wt% (1 wt% or more and 10 wt% or less) of the total solid components. If the added amount of the inorganic fiber is less than 1% by weight, it becomes difficult to form a mat and the stickiness is lost. On the other hand, if it exceeds 10% by weight, separation occurs during mixing. For example, in the case of glass fibers, it is preferable to use bundles such as chopped strands for easy handling.
[0054] 繊維の太さとしては 6〜 13 m (6 m以上でかつ 13 m以下)が望ましい。 6〃 m 未満であると、繊維が細くなり過ぎて粘りが小さくなり、強度が低下する一方、 13 ^ 111 を超えると、表面性が悪くなるためである。 [0054] The thickness of the fiber is preferably 6 to 13 m (6 m or more and 13 m or less). If the thickness is less than 6 mm, the fiber becomes too thin and the viscosity becomes low, and the strength is lowered. On the other hand, if it exceeds 13 ^ 111, the surface property is deteriorated.
[0055] また、繊維の長さとしては 3〜 15mm (3mm以上でかつ 15mm以下)が望ましい。こ の長さが 3mmよりも短いと、繊維としての粘りが少なくなり、 15mmを越えると、ダマ( 繊維の塊)になり易ぐ表面性に悪影響を及ぼすためである。また、繊維長さが 3〜1 5mmであると、軽量骨材や無機質粉状体、結合剤との混合時のバランスがよぐダマ になり難く均一に分散混合することができる。このため、より強度や硬度のある裏面層 2が得られる。 [0055] The length of the fiber is preferably 3 to 15 mm (3 mm or more and 15 mm or less). If the length is shorter than 3 mm, the fiber will become less sticky, and if it exceeds 15 mm, it will be detrimental (fiber lump) and adversely affect the surface properties. Further, when the fiber length is 3 to 15 mm, the balance during mixing with the lightweight aggregate, the inorganic powder, and the binder does not become dull and can be uniformly dispersed and mixed. For this reason, the back layer 2 having higher strength and hardness can be obtained.
[0056] (2)軽量骨材 [0056] (2) Lightweight aggregate
軽量骨材は、圧縮強度を確保しつつ、嵩を持たせるために添加されるものであり、 例えばパーライト、シラス発泡体、シリカフラワー、ガラス発泡体が挙げられる。この軽 量骨材の使用される大きさは 2000 ,1 m以下が望まし!/、。大きさ力 000 μ mよりも大 きくなると、無機質板 Aの加工性が低下するためである。 The lightweight aggregate is added to increase the bulk while securing the compressive strength, and examples thereof include perlite, shirasu foam, silica flour, and glass foam. The size of this light aggregate is preferably 2000,1 m or less! /. This is because when the size force is larger than 000 μm, the processability of the inorganic plate A is lowered.
[0057] 軽量骨材は固形成分全体の 10〜70重量% (10重量%以上でかつ 70重量%以下 )添加される。この添加量が 10重量%未満であると、嵩が低くなり、散布時に均一に 撒くことが難しくなる一方、 70重量%を超えると、圧縮時の圧力が高くなり過ぎ、生産 性が低下するためである。 [0057] The lightweight aggregate is added in an amount of 10 to 70% by weight (not less than 10% by weight and not more than 70% by weight) of the total solid components. If this amount is less than 10% by weight, the bulk will be low and even when spraying. On the other hand, when it exceeds 70% by weight, the pressure at the time of compression becomes too high and productivity is lowered.
[0058] (3)無機質粉状体 [0058] (3) Inorganic powder
無機質粉状体は、防火性及び硬度を確保するために添加されるものであり、例え ば炭酸カルシウム、水酸化アルミニウム、水酸化マグネシウム、フライアッシュ、マイク 口シリカ、スラグ等が挙げられる。この無機質粉状体は、固形成分全体の 10〜70重 量%(10重量%以上でかっ70重量%以下)が添加される。この添加量が 10重量% 未満であると、所望の表面硬度が得られず、また 70重量%を超えると、他の材料の 添加率が相対的に少なくなり、所望の強度を得難くなるためである。 The inorganic powder is added in order to ensure fire resistance and hardness, and examples thereof include calcium carbonate, aluminum hydroxide, magnesium hydroxide, fly ash, mic port silica, and slag. This inorganic powder is added in an amount of 10 to 70% by weight (10% by weight or more and 70% by weight or less) of the total solid components. If the amount added is less than 10% by weight, the desired surface hardness cannot be obtained, and if it exceeds 70% by weight, the addition rate of other materials becomes relatively small, making it difficult to obtain the desired strength. It is.
[0059] (4)結合剤 [0059] (4) Binder
結合剤は、上記軽量骨材、無機繊維、無機質粉状体を結合するために添加される ものであり、例えばメラミン樹脂、フエノール樹脂、 MDI、ウレタン樹脂、アクリル樹脂 、エポキシ樹脂、ポバール、スターチ等が挙げられ、これらは単体又は組み合わせで 使用することができる。無機質板 Aの強度及び不燃性の両方を満足する添加量とし て、固形成分全体の 5〜; 15重量%(5重量%以上でかつ 15重量%以下)が添加され る。この添加量が 5重量%未満であると、強度が不足する一方、 15重量%を越えると 、不燃性が損なわれるからである。 The binder is added to bind the above-mentioned lightweight aggregate, inorganic fiber, and inorganic powder. For example, melamine resin, phenol resin, MDI, urethane resin, acrylic resin, epoxy resin, poval, starch, etc. These can be used alone or in combination. As an addition amount satisfying both the strength and nonflammability of the inorganic board A, 5 to 15% by weight (5% by weight or more and 15% by weight or less) of the whole solid component is added. This is because if the amount added is less than 5% by weight, the strength is insufficient, while if it exceeds 15% by weight, the nonflammability is impaired.
[0060] (5)補助添加剤 [0060] (5) Auxiliary additive
補助添加剤として、機能性のある材料、例えばシリカゲルや珪藻土等を混入させて 吸放湿性を付与したり、消臭剤や VOC吸着剤等を添加したりすることもできる。 As an auxiliary additive, functional materials such as silica gel or diatomaceous earth can be mixed to impart moisture absorption and desorption, or a deodorant or VOC adsorbent can be added.
[0061] (無機質板の製造方法) [0061] (Method for producing inorganic board)
以上の構成を持つ無機質板 Aの製造方法につ!/、て説明する。この方法は裏面層 マット形成工程と、表面層マット形成工程と、成形工程とからなる。 The manufacturing method of the inorganic board A having the above configuration will be described below. This method includes a back surface layer mat forming step, a surface layer mat forming step, and a molding step.
[0062] (1)裏面層マット形成工程 [0062] (1) Back surface layer mat forming step
最初の裏面層マット形成工程では、上記裏面層 2用の材料、すなわち、長さ 3〜15 mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜7 0重量%と、結合剤 5〜; 15重量%と、補助添加剤とをミキサーに投入し、水を噴霧し ながら混合して含水率 5〜; 15%に調整された混合物を得る。この混合物をフォーミン グして裏面層マットを形成する。 In the first back surface layer mat forming step, the material for the back surface layer 2, that is, inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, lightweight aggregate 10 to 70% by weight, and inorganic powder 10 ~ 70 wt%, binder 5 ~; 15 wt% and auxiliary additives are put into a mixer and mixed while spraying water to obtain a mixture adjusted to water content 5 ~; 15% . Formin this mixture To form a back layer mat.
[0063] これらの材料を混合するときに添加される水は固形成分の 5〜; 15重量% (5重量% 以上でかつ 15重量%以下)であることが好ましい。その理由は、 5重量%未満である と、混合時や成形時に粉体の散乱が多ぐ作業性が悪くなるためであり、 15重量%を 超えると、加熱'圧締に時間がかかり、パンクし易くなるためである。 [0063] The water added when mixing these materials is preferably 5 to 15 wt% (5 wt% or more and 15 wt% or less) of the solid component. The reason for this is that if it is less than 5% by weight, the powder is scattered during mixing and molding, resulting in poor workability. It is because it becomes easy to do.
[0064] (2)表面層マット形成工程 [0064] (2) Surface layer mat forming step
次の表面層マット形成工程では、さらに上記表面層 1用の材料、すなわち、長さ lm m以下の微細な無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜50 重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とをミキサーに投 入し、水を噴霧しながら混合して含水率 5〜; 15%に調整された混合物を得る。この混 合物を、上記裏面層マット形成工程で形成された裏面層マットの上にフォーミングし て表面層マットを形成する。 In the next surface layer mat forming step, the material for the surface layer 1, that is, 10 to 70% by weight of fine inorganic fibers having a length of lm m or less and a lightweight aggregate having a particle size of 500 m or less and 10 to 50% by weight. , 10 to 70% by weight of an inorganic powder, 3 to 10% by weight of a binder, and mixed with spraying water to adjust the water content to 5 to 15%. Get. The mixture is formed on the back surface layer mat formed in the back surface layer mat forming step to form a surface layer mat.
[0065] これらの材料を混合するときにおいても、添加される水は固形成分の 5〜; 15重量% であることが好ましい。その理由は、上記裏面層マット形成工程と同様であり、 5重量 %未満であると、混合時や成形時に粉体の散乱が多ぐ作業性が悪くなる一方、 15 重量%を超えると、加熱'圧締に時間がかかり、パンクし易くなるためである。 [0065] Even when these materials are mixed, the added water is preferably 5 to 15% by weight of the solid component. The reason for this is the same as in the backside layer mat forming step. When the amount is less than 5% by weight, the powder scatters much during mixing and molding, and the workability deteriorates. 'This is because it takes time to press and it becomes easy to puncture.
[0066] (3)成形工程 [0066] (3) Molding process
成形工程では、上記裏面層 2用及び表面層 1用の 2層のマットを所定の圧力及び 温度(150〜250°C)で熱圧プレスして一体に成形する。この熱圧プレス装置は、連 続プレス装置でも多段プレス装置でもよ!/、。 In the molding step, the two mats for the back layer 2 and the front layer 1 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C.) to be integrally molded. This hot press machine can be either a continuous press machine or a multi-stage press machine!
[0067] このような工程を経て、密度 0. 3〜; 1. 5g/cm3の無機質板 Aが成形される。この密 度が 0. 3g/cm3よりも低いと、所望の強度が得られない一方で、 1. 5g/cm3を超え ると、加工性や施工性が悪くなるだけでなぐ高圧力の設備が必要となり生産性も劣 [0067] Through such steps, an inorganic plate A having a density of 0.3 to 1.5 g / cm 3 is formed. If this density is lower than 0.3 g / cm 3 , the desired strength cannot be obtained. On the other hand, if it exceeds 1.5 g / cm 3 , the workability and workability are deteriorated. Equipment is required and productivity is poor
[0068] <実施形態 1の効果〉 <Effect of Embodiment 1>
したがって、この実施形態においては、無機質板 Aの表面層 1に、長さ lmm以下の 微細な無機繊維と、粒径 500 m以下の軽量骨材とが使用されているので、緻密な 表面層 1が得られる。一方、裏面層 2は、長さ 3〜; 15mmの無機繊維 1〜; 10重量%と 、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合剤 5〜; 15重量 %とを有する層であるので、上記表面層 1を支えることができる。しかも、裏面層 2は、 長さ 3〜; 15mmの無機繊維を使用するので、他の軽量骨材や無機質粉状体や結合 剤との混合バランスがよくてダマ (繊維の塊)になり難ぐ均一に分散混合することが できる。このため、より強度や硬度のある裏面層 2を得ることができ、表面層 1をしつか り支えること力 Sできる。これらにより、全体として不燃性、取扱性、加工性、施工性に優 れ、高強度の無機質板 Aを得ることができる。 Therefore, in this embodiment, fine inorganic fibers having a length of 1 mm or less and lightweight aggregates having a particle diameter of 500 m or less are used for the surface layer 1 of the inorganic plate A. Therefore, the dense surface layer 1 Is obtained. On the other hand, the back layer 2 has a length of 3 to; 15 mm of inorganic fiber 1 to 10% by weight Since it is a layer having 10 to 70% by weight of lightweight aggregate, 10 to 70% by weight of an inorganic powder, and 5 to 15% by weight of a binder, the surface layer 1 can be supported. Moreover, since the back layer 2 uses inorganic fibers with a length of 3 to 15 mm, it has a good mixing balance with other lightweight aggregates, inorganic powders, and binders, making it difficult to become lumps (fiber clumps). Can be uniformly dispersed and mixed. For this reason, the back layer 2 having higher strength and hardness can be obtained, and the force S for firmly supporting the front surface layer 1 can be obtained. As a result, it is possible to obtain a high-strength inorganic board A that is excellent in nonflammability, handling, workability, and workability as a whole.
[0069] また、無機質板 Aの製造に当たり、裏面層及び表面層マットは含水率 5〜; 15%に 調整されて!/、るので、短時間かつ高温で加熱圧縮を行って結合剤を反応させること 力 Sできる。また、高温及び高圧下であるので、結合剤の流動性が上がって全体に行 き渡らせること力 Sでき、かつ、水分を短時間で蒸発させることができるので、結合剤の 性能を最大限に引き出すことができるだけでなぐ結合剤の量も比較的少なくでき、 不燃性に優れた強固な無機質板 Aが短時間で得られる。 [0069] Further, in the production of the inorganic board A, the back layer and the surface layer mat are adjusted to a moisture content of 5 to 15%! /. Therefore, the binder is reacted by performing heat compression for a short time and at a high temperature. You can force S. In addition, because of the high temperature and high pressure, the flowability of the binder can be increased so that it can spread throughout, and the moisture can be evaporated in a short time, thus maximizing the performance of the binder. As a result, the amount of the binder that can be pulled out to a relatively low level can be made relatively small, and a strong inorganic board A excellent in incombustibility can be obtained in a short time.
[0070] さらに、裏面層及び表面層マットが含水率 5〜; 15%に調整されているので、熱圧プ レス時にパンクが発生し難ぐ生産性もよい。 [0070] Further, since the back surface layer and the surface layer mat are adjusted to have a water content of 5 to 15%, the productivity that puncture hardly occurs at the time of hot press is good.
[0071] [実施形態 2] [0071] [Embodiment 2]
図 2は本発明の実施形態 2に係る無機質板 Aを示す(尚、以下の実施形態では、図 1と同じ部分については同じ符号を付してその詳細な説明は省略する)。 FIG. 2 shows an inorganic plate A according to Embodiment 2 of the present invention (in the following embodiments, the same parts as those in FIG. 1 are denoted by the same reference numerals and detailed description thereof is omitted).
[0072] この実施形態では、無機質板 Aの裏面にシート状物 4が一体化されている。その他 は実施形態 1と同じである。 In this embodiment, the sheet-like material 4 is integrated on the back surface of the inorganic plate A. Others are the same as in the first embodiment.
[0073] このシート状物 4は特に限定されるものではなぐ不織布、単板、含浸紙、樹脂シー ト、繊維シート等であり、化粧用のものでもよい。 [0073] The sheet-like material 4 is not particularly limited, and may be a non-woven fabric, a veneer, an impregnated paper, a resin sheet, a fiber sheet or the like, and may be a cosmetic one.
[0074] この実施形態 2の無機質板 Aを製造する方法につ!/、て説明すると、まず、シート状 物 4を用意する。そして、実施形態 1の裏面層マット形成工程と同様に、長さ 3〜; 15m mの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70 重量%と、結合剤 5〜; 15重量%とをミキサーに投入し、水を噴霧しながら混合して含 水率 5〜 15%に調整された混合物を得、この混合物を上記シート状物 4上でフォーミ ングして裏面層マットを形成する。 [0075] 次いで、実施形態 1の表面層マット形成工程と同様に、さらに長さ lmm以下の微細 な無機繊維 10〜70重量%と、粒径 500 111以下の軽量骨材 10〜50重量%と、無 機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とをミキサーに投入し、水を噴 霧しながら混合して含水率 5〜; 15%に調整された混合物を得、この混合物を上記裏 面層マットの上にフォーミングして表面層マットを形成する。 [0074] A method for manufacturing the inorganic plate A of Embodiment 2 will be described. First, a sheet-like material 4 is prepared. And like the back surface layer mat formation process of Embodiment 1, length 3 ~; 15mm inorganic fiber;! ~ 10wt%, lightweight aggregate 10 ~ 70wt%, inorganic powder 10 ~ 70 and weight% binder 5; was charged with 15 wt% to the mixer, and mixed with spraying water to obtain a mixture which is adjusted to hydrous rate of 5 to 15 percent, the sheet material and the mixture 4 Form on top to form the back layer mat. [0075] Next, similarly to the surface layer mat forming step of Embodiment 1, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less and 10 to 50% by weight of lightweight aggregate having a particle size of 500 111 or less. A mixture of 10 to 70% by weight of organic powder and 3 to 10% by weight of binder and mixed with water spray while mixing to adjust the water content to 5 to 15% The mixture is formed on the back layer mat to form a surface layer mat.
[0076] そして、上記裏面層及び表面層の 2層のマットと上記シート状物 4とを所定の圧力 及び温度(150〜250°C)で熱圧プレスして一体に成形する。 [0076] Then, the two-layer mat of the back layer and the front layer and the sheet-like material 4 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C) to be integrally formed.
[0077] このフォーミングされたマットと同時に熱圧プレスでシート状物 4を一体化させる場 合において、シート状物 4の密着性を向上させるために、予めシート状物 4に接着剤 を塗布することも可能である。この接着剤としては、フエノール樹脂、メラミン樹脂、ゥ レタン樹脂、アクリル樹脂、 MDI、酢酸ビュル樹脂等が挙げられるが、外装用として 用いる場合は耐水性の高いものを選択することが望ましい。その塗布量としては、固 形成分として 50g/m2以下が望まし!/、。固形成分が 50g/m2を超える場合は不燃 性が低下するためである。 [0077] In the case where the sheet-like material 4 is integrated with a hot-press press at the same time as the formed mat, an adhesive is applied to the sheet-like material 4 in advance in order to improve the adhesion of the sheet-like material 4. It is also possible. Examples of the adhesive include phenol resin, melamine resin, urethane resin, acrylic resin, MDI, and butyl acetate resin, but it is desirable to select one having high water resistance when used for exterior use. The coating amount is preferably 50 g / m 2 or less for solid formation! /. This is because if the solid component exceeds 50 g / m 2 , the nonflammability decreases.
[0078] <実施形態 2の効果〉 <Effect of Embodiment 2>
したがって、この実施形態の場合、無機質板 Aの裏面層 2にシート状物 4がー体的 に熱圧プレスされて貼着されているので、割れ難ぐ強度のある無機質板 Aが得られ Therefore, in the case of this embodiment, since the sheet-like material 4 is physically hot-pressed and adhered to the back surface layer 2 of the inorganic plate A, an inorganic plate A having a strength that is difficult to break is obtained.
[0079] また、シート状物 4も一体的に熱圧プレスして成形するので、後でシート状物 4を貼 着する場合よりも工程が少なぐ生産性よく製造できる。さらに、製造工程上において も、シート状物 4が下に敷いてあることで、混合物であるマット運搬がより容易となる。 [0079] Further, since the sheet-like material 4 is also integrally molded by hot-pressing, it can be produced with high productivity with fewer steps than when the sheet-like material 4 is attached later. Further, in the manufacturing process, the mat 4 as a mixture can be more easily transported because the sheet-like material 4 is laid underneath.
[0080] [実施形態 3] [0080] [Embodiment 3]
図 3は本発明の実施形態 3に係る無機質板 Aを示し、この無機質板 Aは、その表面 側(図 3上側)に位置する表層 11と、裏面側(図 3下側)に位置する裏層 12と、これら 表層 11及び裏層 12間に位置する芯層 3とが一体化されて成形されてなるものである 。換言すると、無機質板 Aは、芯層 3と、該芯層 3の表面に一体化された表層 11と、 芯層 3の裏面に一体化された裏層 12とを備えている。 FIG. 3 shows an inorganic plate A according to Embodiment 3 of the present invention. The inorganic plate A has a surface layer 11 located on the front surface side (upper side in FIG. 3) and a back surface located on the back side (lower side in FIG. 3). The layer 12 and the core layer 3 positioned between the surface layer 11 and the back layer 12 are integrally formed. In other words, the inorganic plate A includes the core layer 3, the surface layer 11 integrated on the surface of the core layer 3, and the back layer 12 integrated on the back surface of the core layer 3.
[0081] (表層及び裏層) 上記表層 11及び裏層 12はいずれも同じものであり、上記実施形態 1における表面 層 1と同じである。すなわち、表層 1 1及び裏層 12はいずれも、長さ lmm以下の微細 な無機繊維 10〜70重量%と、粒径 500 111以下の軽量骨材 10〜50重量%と、無 機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とを有する。 [0081] (surface layer and back layer) The surface layer 11 and the back layer 12 are the same, and are the same as the surface layer 1 in the first embodiment. That is, each of the surface layer 11 and the back layer 12 is composed of 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 111 or less, 10 to 70% by weight of body and 3 to 10% by weight of binder.
[0082] (1)微細な無機繊維 [0082] (1) Fine inorganic fiber
上記微細な無機繊維は、上記実施形態 1の表面層 1における「微細な無機繊維」と 同じものである。 The fine inorganic fibers are the same as the “fine inorganic fibers” in the surface layer 1 of the first embodiment.
[0083] (2)軽量骨材 [0083] (2) Lightweight aggregate
軽量骨材は、上記実施形態 1の表面層 1における「軽量骨材」と同じものである(実 施形態 1の表面層 1における「軽量骨材」の記載参照)。 The lightweight aggregate is the same as the “lightweight aggregate” in the surface layer 1 of the first embodiment (see the description of “lightweight aggregate” in the surface layer 1 of the first embodiment).
[0084] (3)無機質粉状体 [0084] (3) Inorganic powder
無機質粉状体は、上記実施形態 1の表面層 1における「無機質粉状体」と同じもの である(実施形態 1の表面層 1における「無機質粉状体」の記載参照)。 The inorganic powder is the same as the “inorganic powder” in the surface layer 1 of the first embodiment (see the description of “inorganic powder” in the surface layer 1 of the first embodiment).
[0085] (4)結合剤 [0085] (4) Binder
結合剤は、上記実施形態 1の表面層 1における「結合剤」と同じものである(実施形 態 1の表面層 1における「結合剤」の記載参照)。 The binder is the same as the “binder” in the surface layer 1 of the first embodiment (see the description of the “binder” in the surface layer 1 of the first embodiment).
[0086] (5)補助添加剤 [0086] (5) Auxiliary additive
補助添加剤として、必要に応じてサイズ剤、カップリング剤等を添加してもよい。 As an auxiliary additive, a sizing agent, a coupling agent and the like may be added as necessary.
[0087] (芯層) [0087] (Core layer)
上記芯層 3は、実施形態 1における裏面層 2と同じであり、長さ 3〜; 15mmの無機繊 維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結 合剤 5〜; 15重量%とを有する。 The core layer 3 is the same as the back layer 2 in Embodiment 1, and has a length of 3 to; 15 mm of inorganic fiber;! To 10% by weight, lightweight aggregate of 10 to 70% by weight, and an inorganic powder. 10 to 70% by weight and 5 to 15% by weight of binder.
[0088] (1)無機繊維 [0088] (1) Inorganic fiber
上記無機繊維は、実施形態 1の裏面層 2における「無機繊維」と同じものである(実 施形態 1の裏面層 2における「無機繊維」の記載参照)。 The inorganic fiber is the same as the “inorganic fiber” in the back layer 2 of Embodiment 1 (see the description of “Inorganic fiber” in the back layer 2 of Embodiment 1).
[0089] (2)軽量骨材 [0089] (2) Lightweight aggregate
軽量骨材は、実施形態 1の裏面層 2における「軽量骨材」と同じものである(実施形 態 1の裏面層 2における「軽量骨材」の記載参照)。 [0090] (3)無機質粉状体 The lightweight aggregate is the same as the “lightweight aggregate” in the back surface layer 2 of Embodiment 1 (see the description of “Lightweight aggregate” in the back surface layer 2 of Embodiment 1). [0090] (3) Inorganic powder
無機質粉状体は、実施形態 1の裏面層 2における「無機質粉状体」と同じものである (実施形態 1の裏面層 2における「無機質粉状体」の記載参照)。 The inorganic powder is the same as the “inorganic powder” in the back layer 2 of Embodiment 1 (see the description of “Inorganic powder” in the back layer 2 of Embodiment 1).
[0091] (4)結合剤 [0091] (4) Binder
結合剤は、実施形態 1の裏面層 2における「結合剤」と同じものである(実施形態 1 の裏面層 2における「結合剤」の記載参照)。 The binder is the same as the “binder” in the back layer 2 of Embodiment 1 (see the description of the “binder” in the back layer 2 of Embodiment 1).
[0092] (5)補助添加剤 [0092] (5) Auxiliary additive
補助添加剤として、機能性のある材料、例えばシリカゲルや珪藻土等を混入させて 吸放湿性を付与したり、消臭剤や VOC吸着剤等を添加したりすることもできる。 As an auxiliary additive, functional materials such as silica gel or diatomaceous earth can be mixed to impart moisture absorption and desorption, or a deodorant or VOC adsorbent can be added.
[0093] (無機質板の製造方法) [0093] (Method for producing inorganic plate)
以上の構成を持つ実施形態 3に係る無機質板 Aの製造方法について説明する。こ の方法は裏層マット形成工程、芯層マット形成工程、表層マット形成工程及び成形 工程からなる。 A method for manufacturing the inorganic plate A according to Embodiment 3 having the above configuration will be described. This method comprises a back layer mat forming step, a core layer mat forming step, a surface layer mat forming step, and a forming step.
[0094] (1)裏層マット形成工程 [0094] (1) Back layer mat forming process
最初の裏層マット形成工程では、上記裏層 12用の組成材料、すなわち、長さ lmm 以下の微細な無機繊維 10〜70重量%と、粒径 500 H m以下の軽量骨材 10〜50重 量%と、無機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%と、補助添加剤とをミ キサ一に投入し、水を噴霧しながら混合して含水率 5〜; 15%に調整された混合物を 得る。この混合物をフォーミングして裏層マットを形成する。 In the first back layer mat forming step, the composition material for the back layer 12, that is, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less and a lightweight aggregate having a particle size of 500 Hm or less 10 to 50 10% by weight, 10 to 70% by weight of an inorganic powder, 3 to 10% by weight of binder, 10% by weight and auxiliary additives are added to the mixer and mixed while spraying water to obtain a water content of 5 to 5%; A mixture adjusted to 15% is obtained. This mixture is formed to form a backing mat.
[0095] これらの材料を混合するときに添加される水は固形成分の 5〜; 15重量% (5重量% 以上でかつ 15重量%以下)であることが好ましい(含水率 5〜; 15%)。その理由は、 5 重量%未満であると、混合時や成形時に粉体の散乱が多ぐ作業性が悪くなるため であり、 15重量%を超えると、加熱'圧締に時間がかかり、パンクし易くなるためであ [0095] The water added when mixing these materials is preferably 5 to 15% by weight of the solid component (more than 5% by weight and not more than 15% by weight) (moisture content 5 to 15%). ). The reason for this is that if it is less than 5% by weight, the scattering of the powder during mixing or molding deteriorates the workability, and if it exceeds 15% by weight, it takes time for heating and pressing, and puncture is caused. Because it becomes easier to do
[0096] (2)芯層マット形成工程 [0096] (2) Core layer mat forming step
次の芯層マット形成工程では、さらに上記芯層 3用の材料、すなわち、長さ 3〜; 15 mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜7 0重量%と、結合剤 5〜; 15重量%と、補助添加剤とをミキサーに投入し、水を噴霧し ながら混合して含水率 5〜; 15%に調整された混合物を得る。この混合物を、上記裏 層マット形成工程で形成された裏層マットの上にフォーミングして 2層目の芯層マット を形成する。 In the next core layer mat forming step, the material for the core layer 3, that is, the inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, lightweight aggregate 10 to 70% by weight, and inorganic powder 10 to 70% by weight, binder 5 to 5%; 15% by weight and auxiliary additives are put into a mixer and sprayed with water. To obtain a mixture adjusted to a water content of 5 to 15%. This mixture is formed on the back layer mat formed in the back layer mat forming step to form a second core layer mat.
[0097] これらの材料を混合するときにおいても、添加される水は固形成分の 5〜; 15重量% であることが好ましい (含水率 5〜; 15%)。その理由は、上記裏層マット形成工程と同 様であり、 5重量%未満であると、混合時や成形時に粉体の散乱が多ぐ作業性が悪 くなる一方、 15重量%を超えると、加熱'圧締に時間がかかり、パンクし易くなるため である。 [0097] When mixing these materials, the added water is preferably 5 to 15% by weight of the solid component (water content 5 to 15%). The reason for this is the same as in the above-mentioned back layer mat forming process. If the amount is less than 5% by weight, the scattering of the powder during mixing or molding deteriorates the workability, while if it exceeds 15% by weight. This is because it takes time to heat and press, and it becomes easy to puncture.
[0098] (3)表層マット形成工程 [0098] (3) Surface mat forming process
次の表層マット形成工程では、さらに上記表層 11用の材料、すなわち上記裏層 12 用の材料と同じで、長さ lmm以下の微細な無機繊維 10〜70重量%と、粒径 500 m以下の軽量骨材 10〜50重量%と、無機質粉状体 10〜70重量%と、結合剤 3〜1 0重量%と、補助添加剤をミキサーに投入し、水を噴霧しながら混合して含水率 5〜1 5%に調整された混合物を得る。この混合物を、上記芯層マット形成工程で形成され た芯層マットの上にフォーミングして 3層目の表層マットを形成する。 In the next surface mat forming step, the same material as that for the surface layer 11, that is, the material for the back layer 12, is 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less and a particle size of 500 m or less. Light weight aggregate 10-50% by weight, inorganic powder 10-70% by weight, binder 3-10% by weight, auxiliary additives are added to the mixer and mixed while spraying water, moisture content A mixture adjusted to 5-15% is obtained. This mixture is formed on the core layer mat formed in the core layer mat forming step to form a third surface mat.
[0099] これらの材料を混合するときも、添加される水は固形成分の 5〜; 15重量%であるこ とが好ましい (含水率 5〜; 15%)。その理由は、上記各層マット形成工程と同じであり 、 5重量%未満であると、混合時や成形時に粉体の散乱が多ぐ作業性が悪くなる一 方、 15重量%を超えると、加熱'圧締に時間がかかり、パンクし易くなる。 [0099] When these materials are mixed, the added water is preferably 5 to 15% by weight of the solid component (moisture content 5 to 15%). The reason for this is the same as the mat forming process for each layer described above. When the amount is less than 5% by weight, powder scattering is large at the time of mixing or molding, while workability is deteriorated. 'It takes time to press and it becomes easy to puncture.
[0100] (4)成形工程 [0100] (4) Molding process
成形工程では、上記裏層 12用、芯層 3用及び表層 11用に積層された 3層のマット を所定の圧力及び温度(150〜250°C)で熱圧プレスして一体に成形する。この熱圧 プレス装置は、連続プレス装置でも多段プレス装置でもよ!/、。 In the molding step, the three layers of mats laminated for the back layer 12, the core layer 3, and the surface layer 11 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C.) to be integrally molded. This hot press machine can be a continuous press machine or a multi-stage press machine!
[0101] このような工程を経て、密度 0. 3〜; 1. 5g/cm3の無機質板 Aが成形される。この密 度が 0. 3g/cm3よりも低いと、所望の強度が得られない一方で、 1. 5g/cm3を超え ると、加工性や施工性が悪くなるだけでなぐ高圧力の設備が必要となり生産性も劣 [0101] Through these steps, an inorganic sheet A having a density of 0.3 to 1.5 g / cm 3 is formed. If this density is lower than 0.3 g / cm 3 , the desired strength cannot be obtained. On the other hand, if it exceeds 1.5 g / cm 3 , the workability and workability are deteriorated. Equipment is required and productivity is poor
[0102] <実施形態 3の効果〉 したがって、この実施形態においては、無機質板 Aの表層 11及び裏層 12の双方 に、長さ lmm以下の微細な無機繊維と、粒径 500 in以下の軽量骨材とが使用さ れているので、緻密な表層 11及び裏層 12が得られる。一方、芯層 3は、長さ 3〜; 15 mmの無機繊維;!〜 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜7 0重量%と、結合剤 5〜; 15重量%とを有する層であるので、上記表層 11及び裏層 12 を支えること力 Sできる。し力、も、芯層 3は、長さ 3〜; 15mmの無機繊維を使用するので 、他の軽量骨材や無機質粉状体や結合剤との混合バランスがよくてダマ (繊維の塊) になり難ぐ均一に分散混合することができる。このため、より強度や硬度のある芯層 3を得ることができ、表層 11及び裏層 12をしつ力、り支えることができる。これらにより、 全体として不燃性、取扱性、加工性、施工性に優れ、高強度の無機質板 Aを得ること ができる。 [0102] <Effects of Embodiment 3> Therefore, in this embodiment, fine inorganic fibers having a length of 1 mm or less and lightweight aggregate having a particle size of 500 in or less are used for both the surface layer 11 and the back layer 12 of the inorganic plate A. Thus, a dense surface layer 11 and back layer 12 are obtained. On the other hand, the core layer 3 comprises an inorganic fiber having a length of 3 to 15 mm;! To 10% by weight, a lightweight aggregate of 10 to 70% by weight, an inorganic powder 10 to 70% by weight, and a binder 5 Since the layer has 15 wt%, the force S can be supported to support the surface layer 11 and the back layer 12. However, the core layer 3 uses a length of 3 to 15 mm of inorganic fibers, so it has a good mixing balance with other lightweight aggregates, inorganic powders and binders (fiber lump). Can be uniformly dispersed and mixed. Therefore, the core layer 3 having higher strength and hardness can be obtained, and the surface layer 11 and the back layer 12 can be supported and supported. As a result, it is possible to obtain a high-strength inorganic board A that is excellent in incombustibility, handling, workability, and workability as a whole.
[0103] また、無機質板 Aの製造に当たり、裏層、芯層及び表層の各マットは含水率 5〜; 15 %に調整されているので、短時間かつ高温で加熱圧縮を行って結合剤を反応させる こと力 Sできる。また、高温及び高圧下であるので、結合剤の流動性が上がって全体に 行き渡らせること力でき、かつ、水分を短時間で蒸発させることができるので、結合剤 の性能を最大限に引き出すことができるだけでなぐ結合剤の量も比較的少なくでき 、不燃性に優れた強固な無機質板 Aが短時間で得られる。 [0103] Further, in the production of the inorganic board A, the mats of the back layer, the core layer, and the surface layer are adjusted to a moisture content of 5 to 15%. Power to react S. In addition, because it is under high temperature and high pressure, the fluidity of the binder can be increased and distributed throughout, and the water can be evaporated in a short time, so that the performance of the binder can be maximized. As a result, the amount of the binder can be made relatively small, and a strong inorganic board A having excellent nonflammability can be obtained in a short time.
[0104] さらに、各層のマットが含水率 5〜; 15%に調整されているので、熱圧プレス時にパ ンクが発生し難ぐ生産性もよい。 [0104] Furthermore, since the mat of each layer is adjusted to a moisture content of 5 to 15%, the productivity is low because it is difficult for the tank to occur during hot press.
[0105] [実施形態 4] [Embodiment 4]
図 4は本発明の実施形態 4に係る無機質板 Aを示す。この実施形態では、無機質 板 Aの裏面にシート状物 4が一体化されている。その他は実施形態 3と同じである。 FIG. 4 shows an inorganic board A according to Embodiment 4 of the present invention. In this embodiment, the sheet-like material 4 is integrated on the back surface of the inorganic plate A. Others are the same as in the third embodiment.
[0106] このシート状物 4は特に限定されるものではなぐ不織布、単板、含浸紙、樹脂シー ト、繊維シート等であり、化粧用のものでもよい。 [0106] The sheet-like material 4 is not particularly limited, and may be a non-woven fabric, a veneer, an impregnated paper, a resin sheet, a fiber sheet, or the like, and may be a cosmetic one.
[0107] この実施形態 4の無機質板 Aを製造する方法について説明すると、シート状物 4を 用意する。そして、実施形態 3の裏層マット形成工程と同様に、長さ lmm以下の微細 な無機繊維 10〜70重量%と、粒径 500 111以下の軽量骨材 10〜50重量%と、無 機質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とをミキサーに投入し、水を噴 霧しながら混合して含水率 5〜; 15%に調整された混合物を得、この混合物を上記シ 一ト状物 4上でフォーミングして裏層マットを形成する。 [0107] The method for producing the inorganic plate A of Embodiment 4 will be described. A sheet 4 is prepared. And, similarly to the back layer mat forming step of Embodiment 3, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, 10 to 50% by weight of lightweight aggregate having a particle size of 500 111 or less, 10 to 70% by weight of powdery substance and 3 to 10% by weight of binder are put into a mixer and water is injected. Mix with mist to obtain a mixture adjusted to a moisture content of 5 to 15%, and form the mixture on the sheet 4 to form a back layer mat.
[0108] 次いで、実施形態 3の芯層マット形成工程と同様に、長さ 3〜; 15mmの無機繊維 1 〜; 10重量%と、軽量骨材 10〜70重量%と、無機質粉状体 10〜70重量%と、結合 剤 5〜; 15重量%とをミキサーに投入し、水を噴霧しながら混合して含水率 5〜; 15% に調整された混合物を得、この混合物を上記裏層マットの上にフォーミングして 2層 目の芯層マットを形成する。 [0108] Next, in the same manner as in the core layer mat forming step of Embodiment 3, inorganic fiber 1 to 10% in length 3 to 15 mm, light aggregate 10 to 70% by weight, inorganic powder 10 ~ 70 wt% and binder 5 ~; 15 wt% are put into a mixer and mixed while spraying water to obtain a mixture adjusted to a water content of 5 ~; 15%. Form on the mat to form the second core mat.
[0109] 次いで、実施形態 3の表層マット形成工程と同様に、さらに長さ lmm以下の微細な 無機繊維 10〜70重量%と、粒径 500 111以下の軽量骨材 10〜50重量%と、無機 質粉状体 10〜70重量%と、結合剤 3〜; 10重量%とをミキサーに投入し、水を噴霧し ながら混合して含水率 5〜; 15%に調整された混合物を得、この混合物を上記芯層マ ットの上にフォーミングして表層マットを形成する。 [0109] Next, similarly to the surface mat forming step of Embodiment 3, 10 to 70% by weight of fine inorganic fibers having a length of 1 mm or less, and 10 to 50% by weight of light-weight aggregate having a particle size of 500 111 or less, 10 to 70% by weight of an inorganic powder and 3 to 10% by weight of a binder are put into a mixer and mixed while spraying water to obtain a mixture adjusted to a moisture content of 5 to 15%. This mixture is formed on the core layer mat to form a surface mat.
[0110] そして、上記裏層、芯層及び表層の 3層のマットと上記シート状物 4とを所定の圧力 及び温度(150〜250°C)で熱圧プレスして一体に成形する。 [0110] Then, the three-layer mat of the back layer, the core layer and the surface layer and the sheet-like material 4 are hot-pressed at a predetermined pressure and temperature (150 to 250 ° C) to be integrally formed.
[0111] このフォーミングされたマットとシート状物 4とを熱圧プレスで一体化させるときには、 シート状物 4の密着性を向上させるために、予めシート状物 4に接着剤を塗布するこ とも可能である。この接着剤としては、フエノール樹脂、メラミン樹脂、ウレタン樹脂、ァ クリル樹脂、 MDI、酢酸ビュル樹脂等が挙げられるが、外装用として用いる場合は耐 水性の高いものを選択することが望ましい。その塗布量としては、固形成分として 50g /m2以下が望まし!/、。固形成分が 50g/m2を超える場合は不燃性が低下するため である。 [0111] When the formed mat and the sheet-like material 4 are integrated by a hot press, an adhesive may be applied to the sheet-like material 4 in advance in order to improve the adhesion of the sheet-like material 4. Is possible. Examples of the adhesive include phenol resin, melamine resin, urethane resin, acrylic resin, MDI, and butyl acetate resin. However, it is desirable to select one having high water resistance when used for exterior use. The coating amount is preferably 50 g / m 2 or less as a solid component! /. This is because non-flammability decreases when the solid component exceeds 50 g / m 2 .
[0112] <実施形態 4の効果〉 <Effect of Embodiment 4>
したがって、この実施形態の場合、無機質板 Aの裏層 12にシート状物 4がー体的 に熱圧プレスされて貼着されているので、割れ難ぐ強度のある無機質板 Aが得られ Therefore, in this embodiment, since the sheet-like material 4 is physically hot-pressed and adhered to the back layer 12 of the inorganic plate A, an inorganic plate A having a strength that is difficult to break is obtained.
[0113] また、シート状物 4も一体的に熱圧プレスして成形するので、後でシート状物 4を貼 着する場合よりも工程が少なぐ生産性よく製造できる。さらに、製造工程上において も、シート状物 4が下に敷いてあることで、混合物であるマット運搬がより容易となる。 [0114] [その他の実施形態] [0113] Further, since the sheet-like material 4 is also integrally formed by hot-pressing, it can be manufactured with less productivity than the case where the sheet-like material 4 is attached later. Further, in the manufacturing process, the mat 4 as a mixture can be more easily transported because the sheet-like material 4 is laid underneath. [0114] [Other Embodiments]
尚、上記実施形態 2では、シート状物 4を裏面層及び表面層の各マットと共に成形 一体しているが、上記実施形態 1のように裏面層及び表面層の各マットを成形した後 に、その裏面にシート状物を貼着一体化するようにしてもよい。 In the second embodiment, the sheet-like material 4 is molded and integrated together with the mats of the back surface layer and the surface layer. However, after the mats of the back surface layer and the surface layer are molded as in the first embodiment, You may make it stick and integrate a sheet-like material on the back.
[0115] また、上記実施形態 4では、シート状物 4を裏層、芯層及び表層の各マットと共に成 形一体しているが、上記実施形態 3のように裏層、芯層及び表層の各マットを成形し た後に、その裏面にシート状物を貼着一体化するようにしてもよい。 [0115] Further, in Embodiment 4 described above, the sheet-like material 4 is formed and integrated together with the mats of the back layer, the core layer, and the surface layer. However, as in Embodiment 3, the back layer, the core layer, and the surface layer are integrated. After forming each mat, a sheet-like material may be bonded and integrated on the back surface thereof.
[0116] また、実施形態 4では、シート状物 4を裏層マットの下側のみ使用して成形一体化し ているが、表層マットの上側にもシート状物を載せ、このシート状物を 3層のマットと下 側のシート状物 4との成形と同時に一体的に熱圧プレスして成形することもできる。ま た、この上側に使用するシート状物に接着剤を塗布することも可能である。このように 上下にシート状物を一体化する場合は、より強度があってバランスのよい無機質板 A が得られる。 [0116] In Embodiment 4, the sheet-like material 4 is molded and integrated only using the lower side of the back layer mat. However, the sheet-like material is placed on the upper side of the surface layer mat, and this sheet-like material 3 Simultaneously with the formation of the mat of the layer and the lower sheet-like material 4, it can be formed by hot-pressing integrally. It is also possible to apply an adhesive to the sheet-like material used on the upper side. In this way, when the sheet-like materials are integrated up and down, an inorganic plate A having higher strength and balance can be obtained.
[0117] さらに、シート状物は 3層マットの上側のみに使用して成形一体化することもできる。 [0117] Furthermore, the sheet-like material can be molded and integrated only by using it on the upper side of the three-layer mat.
つまり、無機質板の表裏面の少なくとも一方 (少なくとも片面)にシート状物が貼着一 体化されていればよい。 That is, it is only necessary that the sheet-like material is attached to at least one of the front and back surfaces of the inorganic plate (at least one surface).
実施例 Example
[0118] 次に、具体的に実施した例について説明する。尚、以下の実施例;!〜 6及び比較 例;!〜 4は上記実施形態 1及び 2に係るものであり、実施例 7, 8及び比較例 5〜8は 上記実施形態 3及び 4に係るものである。そして、実施例;!〜 6及び比較例;!〜 4の諸 特性等を図 5に、また実施例 7, 8及び比較例 5〜8の諸特性等を図 6にそれぞれ示 す。 [0118] Next, a specific example will be described. The following Examples;! To 6 and Comparative Examples;! To 4 relate to Embodiments 1 and 2 above, and Examples 7, 8 and Comparative Examples 5 to 8 relate to Embodiments 3 and 4 above. Is. The characteristics of Examples ;! to 6 and Comparative Examples ;! to 4 are shown in FIG. 5, and the characteristics of Examples 7 and 8 and Comparative Examples 5 to 8 are shown in FIG.
[0119] (実施例 1) [Example 1]
無機繊維として繊維長 6mm、繊維径 l O ^ mのガラス繊維 7重量%と、無機質粉状 体として炭酸カルシウム 63重量%と、補助剤としてポリエステル繊維 2重量%とをミキ サ一に入れて 1分間撹拌 ·解繊を行い、そこへ軽量骨材として大きさ (粒径) lmm以 下のシラス発泡体 20重量%と、結合剤として粉体フエノール 8重量%と、水とを加え て 30秒撹拌し、含水率 7%の混合物を得た。これを均一にフォーミングして裏面層マ ットを成形した。 Mix 7% by weight of glass fiber with a fiber length of 6mm and fiber diameter lO ^ m as inorganic fiber, 63% by weight of calcium carbonate as inorganic powder, and 2% by weight of polyester fiber as an auxiliary agent in a mixer 1 Stirring and defibration for 30 minutes, add 20% by weight of shirasu foam with a size (particle size) of 1mm or less as a lightweight aggregate, 8% by weight of powdered phenol as a binder, and water for 30 seconds The mixture was stirred to obtain a mixture having a water content of 7%. This is uniformly formed and the back layer A mold was formed.
[0120] これとは別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 5 0重量%と、軽量骨材として大きさ (粒径) 500 a m以下のシラス発泡体 30重量%と、 無機質粉状体として水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 1 0重量%とに水を加えて混合し、含水率 7%の混合物を得た。これを上記裏面層マツ ト上にフォーミングして表面層マットを成形した。そして、 2層のマットを 220°Cで 120 秒の熱圧プレスを行い、 3mm厚さで密度 1. 2g/cm3の無機質板を得た。 [0120] Separately, 50% by weight of rock wool crushed to a length of 850 Hm or less as a fine inorganic fiber, and a shirasu foam with a size (particle size) of 500 am or less as a lightweight aggregate 30 weight %, Aluminum hydroxide 10% by weight as an inorganic powder, and powder phenol 10% by weight as a binder were mixed with water to obtain a mixture having a water content of 7%. This was formed on the back surface layer mat to form a surface layer mat. Then, the two-layer mat was hot-pressed at 220 ° C. for 120 seconds to obtain an inorganic plate having a thickness of 3 mm and a density of 1.2 g / cm 3 .
[0121] (実施例 2) [0121] (Example 2)
無機繊維として繊維長 6mm、繊維径 l O ^ mのガラス繊維 7重量%と、無機質粉状 体として炭酸カルシウム 63重量%と、補助剤としてポリエステル繊維 2重量%とをミキ サ一に入れて 1分間撹拌 ·解繊を行い、そこへ軽量骨材として大きさ lmm以下のシ ラス発泡体 20重量%と、結合剤として粉体フエノール 8重量%と、水とを加えて 30秒 攪拌し、含水率 7%の混合物を得た。この混合物を、アクリル樹脂 30g/m2 (固形成 分)を塗布した坪量 50g/m2のガラス不織布(シート状物)の上に均一にフォーミング して裏面層マットを成形した。 Mix 7% by weight of glass fiber with a fiber length of 6mm and fiber diameter lO ^ m as inorganic fiber, 63% by weight of calcium carbonate as inorganic powder, and 2% by weight of polyester fiber as an auxiliary agent in a mixer 1 Stir for minutes and defiltrate, add 20% by weight of glass foam with a size of lmm or less as a lightweight aggregate, 8% by weight of powdered phenol as a binder, and water and stir for 30 seconds to contain water A mixture with a rate of 7% was obtained. This mixture was uniformly formed on a glass nonwoven fabric (sheet-like material) having a basis weight of 50 g / m 2 coated with acrylic resin 30 g / m 2 (solid component) to form a back layer mat.
[0122] 別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 50重量% と、軽量骨材として大きさ 500 ^ 111以下のシラス発泡体 30重量%と、無機質粉状体と して水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とに水を 加えて混合し、含水率 7%の混合物を得た。これを上記裏面層マット上にフォーミン グして表面層マットを成形し、これら 2層のマットを 220°Cで 120秒の熱圧プレスを行 い、 3mm厚さで密度 1. 2g/cm3の無機質板を得た。 [0122] Separately, 50% by weight of rock wool ground to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam having a size of 500 ^ 111 or less as a lightweight aggregate, and an inorganic powder As a binder, 10% by weight of aluminum hydroxide and 10% by weight of powdered phenol as a binder were mixed with water to obtain a mixture having a water content of 7%. This is formed on the back surface layer mat to form a surface layer mat, and these two layer mats are hot-pressed at 220 ° C for 120 seconds, with a thickness of 3 mm and a density of 1.2 g / cm 3 An inorganic plate was obtained.
[0123] (実施例 3) [0123] (Example 3)
無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、軽量骨材と して大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸カルシゥ ム 16重量%と、結合剤として粉体フエノール 7重量%とを、水を噴霧しながらミキサー で 2分間撹拌して、含水率 10%の混合物を得た。これを均一にフォーミングして裏面 層マットを成形した。 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10m as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and 16% by weight of calcium carbonate as inorganic powder. Then, 7% by weight of powdered phenol as a binder was stirred with a mixer for 2 minutes while spraying water to obtain a mixture having a water content of 10%. This was uniformly formed to form a back surface layer mat.
[0124] 別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 50重量% と、軽量骨材として大きさ δΟΟ ^ ιη以下のシラス発泡体 30重量%と、無機質粉状体と して水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とを、水 を噴霧して加えながら 1分間撹拌混合し、含水率 7%の混合物を得た。これを上記裏 面層マット上にフォーミングして表面層マットを成形し、これら 2層のマットを 210°Cで 3分の熱圧プレスを行い、 6mm厚さで密度 0. 8g/cm3の無機質板を得た。 [0124] Separately, 50% by weight of rock wool crushed to a length of 850 Hm or less as fine inorganic fibers And 30% by weight of shirasu foam with a size of δΟΟ ^ ιη or less as a lightweight aggregate, 10% by weight of aluminum hydroxide as an inorganic powder, 10% by weight of powdered phenol as a binder, water While spraying, the mixture was stirred and mixed for 1 minute to obtain a mixture having a water content of 7%. This was formed on the above back surface layer mat to form a surface layer mat, and these two layer mats were hot-pressed for 3 minutes at 210 ° C, with a thickness of 6 g and a density of 0.8 g / cm 3 . An inorganic board was obtained.
[0125] (実施例 4) [0125] (Example 4)
ガラス繊維 7重量%と、シラス発泡体 16重量%と、炭酸カルシウム 70重量%と、粉 体フエノール 7重量%とを、水を噴霧しながらミキサーで 2分間攪拌して、含水率 7% の混合物を得た。これを均一にフォーミングして裏面層マットを成形した。 7% by weight of glass fiber, 16% by weight of shirasu foam, 70% by weight of calcium carbonate, and 7% by weight of powdered phenol are stirred with a mixer for 2 minutes while spraying water, and a mixture with a moisture content of 7% Got. This was uniformly formed to form a back surface layer mat.
[0126] 別途、長さ 850 m以下に粉砕したロックウールを 70重量%と、大きさ 500 m以 下のシラス発泡体 10重量%と、水酸化アルミニウム 10重量%と、粉体フエノール 10 重量%とを、水を噴霧して加えながら 1分間攪拌混合し、含水率 7%の混合物を得た 。これを上記裏面層マット上にフォーミングして表面層マットを成形し、 2層のマットを 210°Cで 3分の熱圧プレスを行い、 3mm厚さで密度 1. 5g/cm3の無機質板を得た [0126] Separately, 70% by weight of rock wool pulverized to a length of 850 m or less, 10% by weight of shirasu foam having a size of 500 m or less, 10% by weight of aluminum hydroxide, and 10% by weight of powdered phenol Were mixed with stirring for 1 minute while spraying water to obtain a mixture having a water content of 7%. This is formed on the back surface layer mat to form the surface layer mat, and the two layer mat is hot-pressed at 210 ° C for 3 minutes, and is 3 mm thick and 1.5 g / cm 3 density inorganic plate Got
[0127] (実施例 5) [Example 5]
ガラス繊維 7重量%と、シラス発泡体 70重量%と、炭酸カルシウム 16重量%と、粉 体フエノール 7重量%とを、水を噴霧しながらミキサーで 2分間攪拌して、含水率 10 %の混合物を得た。これを均一にフォーミングして裏面層マットを成形した。 7% by weight of glass fiber, 70% by weight of shirasu foam, 16% by weight of calcium carbonate, and 7% by weight of powdered phenol are stirred with a mixer for 2 minutes while spraying water, and a mixture with a moisture content of 10% Got. This was uniformly formed to form a back surface layer mat.
[0128] 別途、長さ 850 m以下に粉砕したロックウールを 30重量%と、大きさ 500 m以 下のシラス発泡体 50重量%と、水酸化アルミニウム 10重量%と、粉体フエノール 10 重量%とを、水を噴霧して加えながら 1分間撹拌混合し、含水率 10%の混合物を得 た。これを上記裏面層マット上にフォーミングして表面層マットを成形し、 2層のマット を 210°Cで 4分の熱圧プレスを行い、 9mm厚さで密度 0. 3g/cm3の無機質板を得 た。 [0128] Separately, 30% by weight of rock wool pulverized to a length of 850 m or less, 50% by weight of shirasu foam having a size of 500 m or less, 10% by weight of aluminum hydroxide, and 10% by weight of powdered phenol Were mixed with stirring for 1 minute while spraying water to obtain a mixture having a water content of 10%. This is formed on the back surface layer mat to form a surface layer mat, and the two layer mats are hot-pressed at 210 ° C for 4 minutes to form an inorganic plate with a thickness of 9 g and a density of 0.3 g / cm3. Obtained.
[0129] 図 5に示すように、以上の実施例;!〜 5で得られた無機質板に、化粧シートとしてコ ート紙、突き板、 DAP含浸紙を貼着したところ、無機質板との密着性も良好であった 。そして表面性がとてもよい化粧板を得ることができた。また、無機質板に対する一般 塗装及び鏡面塗装も良好であった。 [0129] As shown in Fig. 5, when coated paper, veneer and DAP impregnated paper as a decorative sheet were pasted on the inorganic board obtained in the above examples;! Adhesion was also good. A decorative board with a very good surface property was obtained. In addition, for inorganic plates Coating and mirror coating were also good.
[0130] (実施例 6) [0130] (Example 6)
無機繊維として繊維長 6mm、繊維径 l O ^ mのガラス繊維 7重量%と、無機質粉状 体として炭酸カルシウム 63重量%と、補助剤としてポリエステル繊維 2重量%とをミキ サ一に入れて 1分間撹拌 ·解繊を行い、そこへ軽量骨材として大きさ lmm以下のシ ラス発泡体 20重量%と、結合剤として粉体フエノール 8重量%と、水とを加えて 30秒 攪拌し、含水率 7%の混合物を得た。これを均一にフォーミングして裏面層マットを成 形した。 Mix 7% by weight of glass fiber with a fiber length of 6mm and fiber diameter lO ^ m as inorganic fiber, 63% by weight of calcium carbonate as inorganic powder, and 2% by weight of polyester fiber as an auxiliary agent in a mixer 1 Stir for minutes and defiltrate, add 20% by weight of glass foam with a size of lmm or less as a lightweight aggregate, 8% by weight of powdered phenol as a binder, and water and stir for 30 seconds to contain water A mixture with a rate of 7% was obtained. This was uniformly formed to form a back layer mat.
[0131] 別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 50重量% と、軽量骨材として大きさ 500 111のシラス発泡体 30重量%と、無機質粉状体として 水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とに水を加 えて混合し、含水率 7%の混合物を得、これを上記裏面層マット上にフォーミングして 表面層マットを成形し、 2層のマットを 220°Cで 120秒の熱圧プレスを行った。冷却後 、アクリル樹脂 30g/m2 (固形成分)を塗布した坪量 50g/m2のガラス不織布(シート 状物)を貼着し、 3mm厚さで密度 1. 2g/cm3の無機質板を得た。 [0131] Separately, 50% by weight of rock wool pulverized to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam of size 500 111 as lightweight aggregate, and water as inorganic powder Water is added to and mixed with 10% by weight of aluminum oxide and 10% by weight of powdered phenol as a binder to obtain a mixture with a moisture content of 7%, which is formed on the back layer mat to form a surface layer mat. Then, the two-layer mat was hot-pressed at 220 ° C. for 120 seconds. After cooling, a glass nonwoven fabric (sheet-like material) with a basis weight of 50 g / m 2 coated with acrylic resin 30 g / m 2 (solid component) is pasted, and an inorganic plate with a thickness of 3 mm and a density of 1.2 g / cm 3 is attached. Obtained.
[0132] (比較例 1) [0132] (Comparative Example 1)
繊維長 6mm、繊維径 10 μ mのガラス繊維 7重量%と、大きさ lmm以下のシラス発 泡体 70重量%と、炭酸カルシウム 16重量%と、粉体フエノール 7重量%とに水を噴 霧しながらミキサーで 2分間撹拌し、含水率 10%の混合物を得た。これを均一にフォ 一ミングして裏面層マットを成形した。 Water is sprayed on 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10 μm, 70% by weight of Shirasu foam with a size of lmm or less, 16% by weight of calcium carbonate, and 7% by weight of powdered phenol. While stirring with a mixer for 2 minutes, a mixture having a water content of 10% was obtained. This was uniformly formed to form a back surface layer mat.
[0133] 別途、長さ 850 m以下に粉砕したロックウールを 10重量%と、大きさ 500 m以 下のシラス発泡体 80重量%と、粉体フエノール 10重量%とを、水を噴霧して加えな がら 1分間撹拌混合し、含水率 7%の混合物を得た。これを上記裏面層マット上にフ ォーミングして表面層マットを成形し、 2層のマットを 210°Cで 3分の熱圧プレスを行い 、 6mm厚さで密度 0. 8g/cm3の無機質板を得た。図 5に示すように、この比較例 1 は表面硬度が低ぐ平滑性も悪かった。 [0133] Separately, 10% by weight of rock wool pulverized to a length of 850 m or less, 80% by weight of shirasu foam having a size of 500 m or less, and 10% by weight of powder phenol are sprayed with water. In addition, the mixture was stirred and mixed for 1 minute to obtain a mixture having a water content of 7%. This is formed on the back surface layer mat to form a surface layer mat, and the two layer mats are hot-pressed at 210 ° C for 3 minutes, and are 6 mm thick and 0.8 g / cm 3 in density. I got a plate. As shown in FIG. 5, Comparative Example 1 had low surface hardness and poor smoothness.
[0134] (比較例 2) [0134] (Comparative Example 2)
無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、軽量骨材と して大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸カルシゥ ム 16重量%と、結合剤として粉体フエノール 7重量%と、水とを噴霧しながらミキサー で 2分間撹絆し、含水率 10%の混合物を得た。これを均一にフォーミングして裏面層 マットを成形した。 7% by weight glass fiber with a fiber length of 6mm and fiber diameter of 10m as inorganic fiber, lightweight aggregate Then, 70% by weight of shirasu foam with a size of lmm or less, 16% by weight of calcium carbonate as an inorganic powder, 7% by weight of powdered phenol as a binder, and water for 2 minutes with a mixer. Bonded to obtain a mixture with a moisture content of 10%. This was uniformly formed to form a back surface layer mat.
[0135] 別途、微細な無機繊維として長さ 1500 H m以下に粉砕したロックウールを 50重量 %と、軽量骨材として大きさ δΟΟ ^ ιη以下のシラス発泡体 30重量%と、無機質粉状 体として水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とを 、水を噴霧して加えながら 1分間攪拌混合し、含水率 7%の混合物を得た。これを上 記裏面層マット上にフォーミングして表面層マットを成形し、 2層のマットを 210°Cで 3 分の熱圧プレスを行い、 6mm厚さで密度 0. 8g/cm3の無機質板を得た。図 5に示 すように、この比較例 2は、表面に繊維ダマ (繊維の塊)が発生し、平滑性が失われて いた。 [0135] Separately, 50% by weight of rock wool crushed to a length of 1500 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam with a size of δΟΟ ^ ιη or less as a lightweight aggregate, and an inorganic powder As a binder, 10% by weight of aluminum hydroxide and 10% by weight of powdered phenol as a binder were mixed with stirring for 1 minute while spraying water to obtain a mixture having a water content of 7%. This is formed on the back surface layer mat to form a surface layer mat, and the two layer mats are hot-pressed for 3 minutes at 210 ° C, and are 6 mm thick and 0.8 g / cm 3 in density. I got a plate. As shown in FIG. 5, in Comparative Example 2, fiber lumps (fiber clumps) were generated on the surface, and smoothness was lost.
[0136] (比較例 3) [0136] (Comparative Example 3)
無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、軽量骨材と して大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸カルシゥ ム 16重量%と、結合剤として粉体フエノール 7重量%と、水とを噴霧しながらミキサー で 2分間撹拌し、含水率 10%の混合物を得た。これを均一にフォーミングして裏面層 マットを成形した。 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10m as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and 16% by weight of calcium carbonate as inorganic powder. The mixture was stirred for 2 minutes with a mixer while spraying 7% by weight of powder phenol as a binder and water to obtain a mixture having a water content of 10%. This was uniformly formed to form a back surface layer mat.
[0137] 別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 50重量% と、軽量骨材として大きさ lmm以下のシラス発泡体 30重量%と、無機質粉状体とし て水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とを、水を 噴霧して加えながら 1分間攪拌混合し、含水率 7%の混合物を得た。これを上記裏面 層マット上にフォーミングして表面層マットを成形し、 2層のマットを 210°Cで 3分の熱 圧プレスを行い、 6mm厚さで密度 0. 8g/cm3の無機質板を得た。図 5に示す如ぐ この比較例 3は、表面に凹凸が発生し、平滑性が失われていた。 [0137] Separately, 50% by weight of rock wool pulverized to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam with a size of lmm or less as a lightweight aggregate, and an inorganic powder 10% by weight of aluminum hydroxide and 10% by weight of powdered phenol as a binder were mixed with stirring for 1 minute while spraying water to obtain a mixture having a water content of 7%. This is formed on the back surface layer mat to form a surface layer mat, and the two layer mats are hot-pressed at 210 ° C for 3 minutes, and are 6 mm thick and an inorganic plate with a density of 0.8 g / cm 3 . Got. As shown in FIG. 5, this Comparative Example 3 had irregularities on the surface and lost smoothness.
[0138] (比較例 4) [0138] (Comparative Example 4)
無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、軽量骨材と して大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸カルシゥ ム 16重量%と、結合剤として粉体フエノール 7重量%と、水とを噴霧しながらミキサー で 2分間撹拝し、含水率 30%の混合物を得た。これを均一にフォーミングして裏面層 マットを成形した。 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10m as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and calcium carbonate as inorganic powder. The mixture was stirred for 2 minutes with a mixer while spraying 16% by weight of the powder, 7% by weight of powder phenol as a binder, and water to obtain a mixture having a water content of 30%. This was uniformly formed to form a back surface layer mat.
[0139] 別途、微細な無機繊維として長さ 850 H m以下に粉砕したロックウールを 50重量% と、軽量骨材として大きさ 500 ^ 111以下のシラス発泡体 30重量%と、無機質粉状体と して水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とを、水 を噴霧して加えながら 1分間攪拌混合し、含水率 30%の混合物を得た。これを上記 裏面層マット上にフォーミングして表面層マットを成形した。 2層のマットを熱圧締を行 おうとしたが、水の蒸発が激しぐマット材料が爆裂を起こして製板ができな力、つた。 [0139] Separately, 50% by weight of rock wool crushed to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of Shirasu foam having a size of 500 ^ 111 or less as a lightweight aggregate, and an inorganic powder As a binder, 10% by weight of aluminum hydroxide and 10% by weight of powdered phenol as a binder were mixed with stirring for 1 minute while spraying water to obtain a mixture having a water content of 30%. This was formed on the back surface layer mat to form a surface layer mat. An attempt was made to hot-press two layers of mats, but the mat material, which was apt to evaporate water, explode and was unable to produce a sheet.
[0140] (実施例 7) [0140] (Example 7)
微細な無機繊維として長さ 850 H m以下に粉砕されたロックウール 50重量%と、軽 量骨材として大きさ(粒径) 500 μ m以下のシラス発泡体 30重量%と、無機質粉状体 として水酸化アルミニウム 10重量%と、結合剤として粉体フエノール樹脂 10重量%と に水を加えてミキサーで混合し、含水率 7%の第 1混合物を得た。そして、この第 1混 合物をフォーミングして裏層マットを成形した。 50% by weight of rock wool crushed to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam with a size (particle size) of 500 μm or less as a light aggregate, and inorganic powder As a binder, water was added to 10% by weight of aluminum hydroxide and 10% by weight of powdered phenolic resin as a binder, and mixed with a mixer to obtain a first mixture having a water content of 7%. Then, the first mixture was formed to form a back layer mat.
[0141] 次に、別途、無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、 軽量骨材として大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭 酸カルシウム 15重量%と、結合剤として粉体フエノール樹脂 8重量%とに水を加えて 含水率 10%になるようにミキサーで攪拌混合して、第 2混合物を得た。得られた第 2 混合物を上記裏層マット上にフォーミングして芯層マットを成形した。 [0141] Next, separately, 7% by weight of glass fiber having a fiber length of 6 mm and a fiber diameter of 10 m as inorganic fibers, 70% by weight of shirasu foam having a size of 1 mm or less as a lightweight aggregate, and charcoal as an inorganic powder. Water was added to 15% by weight of calcium acid and 8% by weight of powdered phenol resin as a binder, and the mixture was stirred and mixed with a mixer to obtain a water content of 10% to obtain a second mixture. The obtained second mixture was formed on the backing mat to form a core layer mat.
[0142] さらに、上記と同様に混合して得られた第 1混合物を上記芯層マット上にフォーミン グして表層マットを成形した。 [0142] Furthermore, the first mixture obtained by mixing in the same manner as described above was formed on the core layer mat to form a surface layer mat.
[0143] そして、この 3層マットを 210°C5分間の熱圧プレスを行い、 9mm厚さ、密度 0. 8g /cm3の無機質板を得た。 [0143] Then, the three-layer mat performs hot press of 210 ° C5 minutes to obtain 9mm thickness, the inorganic board of density 0. 8 g / cm 3.
[0144] (実施例 8) [Example 8]
微細な無機繊維として長さ 850 H m以下に粉砕されたロックウール 50重量%と、軽 量骨材として大きさ 500 m以下のシラス発泡体 30重量%と、無機質粉状体として 水酸化アルミニウム 10重量%と、結合剤として粉体フエノール樹脂 10重量%とに水 を加えてミキサーで混合し、含水率 7%の第 1混合物を得た。この第 1混合物をフォー ミングして裏層マットを成形した。 50% by weight of rock wool pulverized to a length of 850 Hm or less as fine inorganic fibers, 30% by weight of shirasu foam having a size of 500 m or less as light aggregate, and aluminum hydroxide as inorganic powder 10 Water and 10% by weight of powdered phenolic resin as binder. Was added and mixed with a mixer to obtain a first mixture having a water content of 7%. The first mixture was formed to form a back layer mat.
[0145] 次に、別途、無機繊維として繊維長 6mm、繊維径 10 mのガラス繊維 7重量%と、 軽量骨材として大きさ lmm以下のシラス発泡体 30重量%と、無機質粉状体として炭 酸カルシウム 16重量%と、結合剤として粉体フエノール樹脂 7重量%と、機能性を付 与する材料として珪藻土 40重量%とに水を加えて含水率 10%になるようにミキサー で撹拌混合して、第 2混合物を得た。こうして得られた第 2混合物を上記裏層マット上 にフォーミングして芯層マットを成形した。 [0145] Next, 7% by weight of glass fiber having a fiber length of 6 mm and a fiber diameter of 10 m as inorganic fibers, 30% by weight of shirasu foam having a size of 1 mm or less as a lightweight aggregate, and charcoal as an inorganic powder. Add water to 16% by weight of calcium oxide, 7% by weight of powdered phenolic resin as a binder, and 40% by weight of diatomaceous earth as a material to add functionality, and stir and mix with a mixer to a moisture content of 10%. To obtain a second mixture. The second mixture thus obtained was formed on the back layer mat to form a core layer mat.
[0146] さらに、上記と同様に混合して得られた第 1混合物を上記芯層マット上でフォーミン グして表層マットを成形した。 [0146] Further, the first mixture obtained by mixing in the same manner as described above was formed on the core layer mat to form a surface layer mat.
[0147] そして、この 3層マットを 210°C5分間の熱圧プレスを行い、 9mm厚さ、密度 0. 8g /cm3の無機質板を得た。 [0147] Then, the three-layer mat performs hot press of 210 ° C5 minutes to obtain 9mm thickness, the inorganic board of density 0. 8 g / cm 3.
[0148] このようにして得られた実施例 7, 8の無機質板に、化粧シートとしてコート紙、突き 板、 DAP含浸紙を貼着したところ、その無機質板との密着性も良好であった。そして 、表面性がとても良い化粧板を得ることができた。 [0148] When coated paper, veneer and DAP-impregnated paper were pasted as decorative sheets to the inorganic boards of Examples 7 and 8 obtained in this manner, the adhesion to the inorganic boards was also good. . And, a decorative board having a very good surface property could be obtained.
[0149] また、吸放湿性能を JIS A 1470— 1に準じ測定したところ、実施例 7では 18g/m2 であったが、実施例 8では 72g/m2の吸放湿量を計測することができた。 [0149] The moisture absorption / release performance was measured in accordance with JIS A 1470-1, and it was 18 g / m 2 in Example 7, but 72 g / m 2 was measured in Example 8. I was able to.
[0150] (比較例 5) [0150] (Comparative Example 5)
微細な無機繊維として長さ 850 m以下に粉砕したロックウール 10重量%と、軽量 骨材として大きさ 500 m以下のシラス発泡体 80重量%と、結合剤として粉体フエノ ール 10重量%とに水を噴霧しながら加えて 1分間撹拌混合し、含水率 7%の第 1混 合物を得た。この第 1混合物をフォーミングして裏層マットを成形した。 10% by weight of rock wool ground to a length of 850 m or less as fine inorganic fibers, 80% by weight of shirasu foam with a size of 500 m or less as lightweight aggregate, and 10% by weight of powdered phenol as a binder Water was sprayed onto the mixture and stirred and mixed for 1 minute to obtain a first mixture having a water content of 7%. This first mixture was formed to form a back layer mat.
[0151] 次に、無機繊維として繊維長 6mm、繊維径 10 μ mのガラス繊維 7重量%と、軽量 骨材として大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸力 ルシゥム 16重量%と、結合剤として粉体フエノール 7重量%とに水を噴霧しながらミキ サ一で 2分間攪拌し、含水率 10%の第 2混合物を得た。これを上記裏層マット上に 均一にフォーミングして芯層マットを成形した。 [0151] Next, 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10μm as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and carbonic acid as inorganic powder The mixture was stirred for 2 minutes with a mixer while spraying water on 16% by weight of Lucium and 7% by weight of powdered phenol as a binder to obtain a second mixture having a water content of 10%. This was uniformly formed on the back layer mat to form a core layer mat.
[0152] さらに、上記と同様に得られた第 1混合物を上記芯層マット上にフォーミングして表 層マットを成形した。 [0152] Further, the first mixture obtained in the same manner as described above was formed on the core layer mat and displayed. A layer mat was formed.
[0153] そして、 3層になったマットを 210°C3分の熱圧プレスを行い、 9mm厚さで密度 0. 8 g/cm3の無機質板を得た。図 6に示すように、この比較例 5は表面硬度が低ぐ平滑 性も悪力、つた。 [0153] Then, the three-layer mat was hot-pressed at 210 ° C for 3 minutes to obtain an inorganic plate having a thickness of 9 mm and a density of 0.8 g / cm 3 . As shown in FIG. 6, this comparative example 5 had a low surface hardness and a poor smoothness.
[0154] (比較例 6) [0154] (Comparative Example 6)
微細な無機繊維として長さ 1500 m以下に粉砕したロックウール 50重量%と、軽 量骨材として大きさ 500 m以下のシラス発泡体 30重量%と、無機質粉状体として 水酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とに水を噴 霧しながら加えて 1分間撹拌混合し、含水率 7%の第 1混合物を得た。この第 1混合 物をフォーミングして裏層マットを成形した。 50% by weight of rock wool crushed to a length of 1500 m or less as fine inorganic fibers, 30% by weight of shirasu foam with a size of 500 m or less as light aggregate, and 10% by weight of aluminum hydroxide as an inorganic powder Then, water was added to 10% by weight of powder phenol as a binder while spraying water, and the mixture was stirred and mixed for 1 minute to obtain a first mixture having a moisture content of 7%. The first mixture was formed to form a back layer mat.
[0155] 次に、無機繊維として繊維長 6mm、繊維径 10 μ mのガラス繊維 7重量%と、軽量 骨材として大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸力 ルシゥム 16重量%と、結合剤として粉体フエノール 7重量%とに水を噴霧しながら加 えてミキサーで 2分間攪拌し、含水率 10%の第 2混合物を得た。これを上記裏層マツ ト上に均一にフォーミングして芯層マットを成形した。 [0155] Next, 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10μm as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and carbonic acid as inorganic powder Water was sprayed onto 16% by weight of Lucium and 7% by weight of powdered phenol as a binder, and the mixture was stirred for 2 minutes with a mixer to obtain a second mixture having a water content of 10%. This was uniformly formed on the above-mentioned back layer mat to form a core layer mat.
[0156] さらに、上記と同様に得られた第 1混合物を上記芯層マット上にフォーミングして表 層マットを成形した。 [0156] Further, the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface mat.
[0157] そして、 3層になったマットを 210°C3分の熱圧プレスを行い、 9mm厚さで密度 0. 8 g/cm3の無機質板を得た。図 6に示すように、この比較例 6は、表面に繊維ダマ(繊 維の塊)が発生し、平滑性が失われていた。 [0157] The three-layer mat was hot-pressed at 210 ° C for 3 minutes to obtain an inorganic plate having a thickness of 9 mm and a density of 0.8 g / cm 3 . As shown in FIG. 6, in Comparative Example 6, fiber lumps (fiber clumps) were generated on the surface, and smoothness was lost.
[0158] (比較例 7) [0158] (Comparative Example 7)
微細な無機繊維として長さ 850 m以下に粉砕したロックウール 50重量%と、軽量 骨材として大きさ 1000 m以下のシラス発泡体 30重量%と、無機質粉状体として水 酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とに水を噴霧し ながら加えて 1分間撹拌混合し、含水率 7%の第 1混合物を得た。この第 1混合物を フォーミングして裏層マットを成形した。 50% by weight of rock wool pulverized to a length of 850 m or less as fine inorganic fibers, 30% by weight of shirasu foam with a size of 1000 m or less as lightweight aggregate, and 10% by weight of aluminum hydroxide as an inorganic powder Then, 10% by weight of powdered phenol as a binder was added while spraying water and mixed with stirring for 1 minute to obtain a first mixture having a moisture content of 7%. This first mixture was formed to form a back layer mat.
[0159] 次に、無機繊維として繊維長 6mm、繊維径 10 μ mのガラス繊維 7重量%と、軽量 骨材として大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸力 ルシゥム 16重量%と、結合剤として粉体フエノール 7重量%とに水を噴霧しながら加 えてミキサーで 2分間撹絆し、含水率 10%の第 2混合物を得た。これを上記裏層マツ トに均一にフォーミングして芯層マットを成形した。 [0159] Next, 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10μm as inorganic fiber, 70% by weight of shirasu foam with a size of lmm or less as a lightweight aggregate, and carbonic acid as an inorganic powder 16% by weight of Lucium and 7% by weight of powdered phenol as a binder were added while spraying water and stirred for 2 minutes with a mixer to obtain a second mixture having a water content of 10%. A core layer mat was formed by uniformly forming this on the back layer mat.
[0160] さらに、上記と同様に得られた第 1混合物を上記芯層マット上にフォーミングして表 層マットを成形した。 [0160] Further, the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface layer mat.
[0161] そして、 3層になったマットを 210°C3分の熱圧プレスを行い、 9mm厚さで密度 0. 8 g/cm3の無機質板を得た。図 6に示す如ぐこの比較例 7は、表面に凹凸が発生し、 平滑性が失われていた。 [0161] The three-layer mat was hot-pressed at 210 ° C for 3 minutes to obtain an inorganic plate having a thickness of 9 mm and a density of 0.8 g / cm 3 . In Comparative Example 7 as shown in FIG. 6, the surface was uneven and the smoothness was lost.
[0162] (比較例 8) [0162] (Comparative Example 8)
微細な無機繊維として長さ 850 m以下に粉砕したロックウール 50重量%と、軽量 骨材として大きさ 500 m以下のシラス発泡体 30重量%と、無機質粉状体として水 酸化アルミニウム 10重量%と、結合剤として粉体フエノール 10重量%とに水を噴霧し ながら加えて 1分間撹拌混合し、含水率 30%の第 1混合物を得た。この第 1混合物を フォーミングして裏層マットを成形した。 50% by weight of rock wool crushed to a length of 850 m or less as fine inorganic fibers, 30% by weight of shirasu foam with a size of 500 m or less as lightweight aggregate, and 10% by weight of aluminum hydroxide as an inorganic powder Then, 10% by weight of powdered phenol as a binder was added while spraying water and mixed with stirring for 1 minute to obtain a first mixture having a water content of 30%. This first mixture was formed to form a back layer mat.
[0163] 次に、無機繊維として繊維長 6mm、繊維径 10 μ mのガラス繊維 7重量%と、軽量 骨材として大きさ lmm以下のシラス発泡体 70重量%と、無機質粉状体として炭酸力 ルシゥム 16重量%と、結合剤として粉体フエノール 7重量%とに水を噴霧しながら加 えてミキサーで 2分間撹絆し、含水率 30%の第 2混合物を得た。これを上記裏層マツ ト上に均一にフォーミングして芯層マットを成形した。 [0163] Next, 7% by weight of glass fiber with a fiber length of 6mm and a fiber diameter of 10μm as inorganic fiber, 70% by weight of shirasu foam with a size of 1mm or less as lightweight aggregate, and carbonic acid as inorganic powder 16% by weight of Lucium and 7% by weight of powdered phenol as a binder were added while spraying water and stirred for 2 minutes with a mixer to obtain a second mixture having a water content of 30%. This was uniformly formed on the above-mentioned back layer mat to form a core layer mat.
[0164] さらに、上記と同様に得られた第 1混合物を上記芯層マット上にフォーミングして表 層マットを成形した。 [0164] Further, the first mixture obtained in the same manner as described above was formed on the core layer mat to form a surface layer mat.
[0165] そして、 3層になったマットの熱圧締を行おうとした力 水の蒸発が激しぐマット材 料が爆裂を起こして製板ができな力、つた。 [0165] And the power to try to hot-clamp the three-layered mat. The mat material, whose water evaporation is intense, explodes and has the power to make a sheet.
産業上の利用可能性 Industrial applicability
[0166] 本発明は、表面平滑性、不燃性、取扱性、加工性及び施工性に優れた高強度の 無機質板が得られることから、極めて有用で産業上の利用可能性が高い。 [0166] The present invention provides a high-strength inorganic plate excellent in surface smoothness, nonflammability, handleability, workability, and workability, and thus is extremely useful and highly industrially applicable.
Claims
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006208538A JP5137353B2 (en) | 2006-07-31 | 2006-07-31 | Inorganic board and method for producing the same |
| JP2006-208538 | 2006-07-31 | ||
| JP2006-250837 | 2006-09-15 | ||
| JP2006250837A JP5137364B2 (en) | 2006-09-15 | 2006-09-15 | Inorganic board and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008016011A1 true WO2008016011A1 (en) | 2008-02-07 |
Family
ID=38997187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/064904 Ceased WO2008016011A1 (en) | 2006-07-31 | 2007-07-30 | Inorganic plate and method for producing the same |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2008016011A1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6143548A (en) * | 1984-08-08 | 1986-03-03 | 大建工業株式会社 | Manufacture of mineral fiber board |
| JPS6155297A (en) * | 1984-08-21 | 1986-03-19 | 大建工業株式会社 | mineral fiberboard |
| JPH0550417A (en) * | 1991-08-20 | 1993-03-02 | Daiken Trade & Ind Co Ltd | Manufacture of inorganic building board |
| JPH0592407A (en) * | 1992-01-20 | 1993-04-16 | Kikusui Kagaku Kogyo Kk | Manufacture of laminated body |
| JPH0890532A (en) * | 1994-09-22 | 1996-04-09 | Junichi Haneda | Manufacture of building meterial |
-
2007
- 2007-07-30 WO PCT/JP2007/064904 patent/WO2008016011A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6143548A (en) * | 1984-08-08 | 1986-03-03 | 大建工業株式会社 | Manufacture of mineral fiber board |
| JPS6155297A (en) * | 1984-08-21 | 1986-03-19 | 大建工業株式会社 | mineral fiberboard |
| JPH0550417A (en) * | 1991-08-20 | 1993-03-02 | Daiken Trade & Ind Co Ltd | Manufacture of inorganic building board |
| JPH0592407A (en) * | 1992-01-20 | 1993-04-16 | Kikusui Kagaku Kogyo Kk | Manufacture of laminated body |
| JPH0890532A (en) * | 1994-09-22 | 1996-04-09 | Junichi Haneda | Manufacture of building meterial |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO1999016984A1 (en) | Composite refractory building material, method of manufacturing the same, gypsum board, and resin composition | |
| AU2020100332A4 (en) | Wood-based composite panel faced with eucalyptus veneer and preparation method thereof | |
| JP2007530307A (en) | Lightweight lignocellulose composite plank materials with enhanced strength and methods for their production | |
| CA2502953A1 (en) | Wood cement board and method for the manufacturing thereof | |
| JP5392469B2 (en) | Composite board | |
| JP2010018961A (en) | Sound-absorbing and sound-insulating composite material | |
| JP2019064840A (en) | Inorganic board, and method of producing the same | |
| JP3530699B2 (en) | Method for producing inorganic plate-like body | |
| JP2004091230A (en) | Woody cement plate and its manufacturing process | |
| WO2000049246A1 (en) | Composite building material and production method thereof and comosite floor material | |
| WO2008016011A1 (en) | Inorganic plate and method for producing the same | |
| JP4119086B2 (en) | Manufacturing method of wood cement board | |
| JP5137364B2 (en) | Inorganic board and method for producing the same | |
| JP5137353B2 (en) | Inorganic board and method for producing the same | |
| JPH08297492A (en) | Damping sound insulating material | |
| JP2001032515A (en) | Floor material | |
| JP2006063573A (en) | Architectural plate | |
| JPH11315594A (en) | Fire-resistive complex building material and fire-resistive composite floor material | |
| JP2910899B2 (en) | Manufacturing method of plate | |
| JPH11303369A (en) | Fire resisting composite building material and fire resisting composite flooring | |
| JP2001140454A (en) | Floor structure of building and its floor substrate material | |
| JPH11315593A (en) | Fire-resistive complex building material and fire-resistive composite floor material | |
| JP3865897B2 (en) | Fireproof ground plate | |
| JP4150528B2 (en) | Manufacturing method of inorganic board | |
| UA126718C2 (en) | Mineral wool board with fillers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07791589 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| NENP | Non-entry into the national phase |
Ref country code: RU |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 07791589 Country of ref document: EP Kind code of ref document: A1 |