WO2008015961A1 - Die assembly - Google Patents
Die assembly Download PDFInfo
- Publication number
- WO2008015961A1 WO2008015961A1 PCT/JP2007/064697 JP2007064697W WO2008015961A1 WO 2008015961 A1 WO2008015961 A1 WO 2008015961A1 JP 2007064697 W JP2007064697 W JP 2007064697W WO 2008015961 A1 WO2008015961 A1 WO 2008015961A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- conductive means
- heat generating
- conductive
- nesting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/72—Heating or cooling
- B29C45/73—Heating or cooling of the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
- B29C2033/023—Thermal insulation of moulds or mould parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/72—Heating or cooling
- B29C45/73—Heating or cooling of the mould
- B29C2045/7393—Heating or cooling of the mould alternately heating and cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/2673—Moulds with exchangeable mould parts, e.g. cassette moulds
Definitions
- the present invention relates to a mold assembly.
- thermoplastic resin As the molding material.
- studies are being made to satisfy thin cavities by reducing the molecular weight of thermoplastic resins or increasing the resin temperature.
- the molecular weight of the thermoplastic resin is lowered, the strength of the thermoplastic resin is insufficient, and thus there is a risk of damage during use of the molded product.
- the resin temperature is increased, the thermoplastic resin is decomposed by heat, which may cause discoloration or strength reduction.
- a molding method in which the injection rate of the injection molding machine is increased, that is, the injection speed is increased.
- a suitable thermoplastic resin can be used for molded products of a certain thickness and size.
- the injection speed of the molten thermoplastic resin into the cavity is very fast, and the injection pressure is high, so there are cases where stress remains in the molded product or warping occurs in the molded product.
- the injection rate is too high, there is a tendency that the molded product is burnt due to shearing.
- the injection molding machine itself is very expensive.
- the mold temperature is adjusted to the glass transition temperature T of the thermoplastic resin used.
- thermoplastic resin in the cavity by suppressing the cooling in the cavity of the thermoplastic resin by keeping it high to near, or in one molding cycle
- a method of intentionally changing the mold temperature specifically, the temperature of the surface constituting the mold cavity during the injection of molten thermoplastic resin into the cavity (referred to as the mold cavity surface for convenience).
- the temperature of the mold cavity surface is set to T after the injection is completed.
- a method of taking out the molded article after cooling to a temperature lower than g g can be mentioned.
- Other methods for intentionally changing the mold temperature include, for example, JP-A-4-265720, JP-A-8-90624, JP-A-8-132500, JP-T 2004-528677, JP-A-2004-42601, and the like. It is.
- a thin electrically conductive layer or electrical resistance layer is formed on the mold cavity surface, or a stamper is formed on the mold cavity surface.
- the electric conductive layer, the electric resistance layer, or the stamper (hereinafter collectively referred to as an electric conductive layer or the like) is caused to flow, and the electric conductive layer or the like is heated.
- an electric conductive layer or the like is controlled to control the temperature of the electrically conductive layer or the like, which is a portion in contact with the molten thermoplastic resin flowing in the cavity, and the fluidity of the molten thermoplastic resin. Since a current flows through the electrically conductive layer or the like, a thin electrically insulating layer is formed on the mold cavity surface under the electrically conductive layer or the like.
- Patent Document 1 Japanese Patent Laid-Open No. 4 265720
- Patent Document 2 JP-A-8-90624
- Patent Document 3 JP-A-8-132500
- Patent Document 4 Special Table 2004 528677
- Patent Document 5 JP 2004-42601 A
- a thin electrical resistance layer having a high electrical resistance value is used in order to raise the temperature by heating the resistance using a high voltage as a power source, Alternatively, it is necessary to form an electric resistance layer having a complicated pattern.
- the method of providing an electrical resistance layer having a low electrical resistance value since a low electrical voltage is used, there is a possibility that sufficient heat generation may not occur depending on the design of the electrical resistance layer used.
- the calculation result from the electric resistance values of the power source and the stamper used hardly raises the temperature.
- an object of the present invention is to control the temperature of the molten thermoplastic resin injected into the cavity easily, in a short time, accurately, reliably, and safely.
- An object of the present invention is to provide a mold assembly capable of controlling the cooling of a molten thermoplastic resin injected into a bite.
- a mold assembly according to a first aspect of the present invention comprises:
- a mold that includes a first mold part and a second mold part, and a cavity is formed by clamping the first mold part and the second mold part, (B) a nesting assembly having a nesting disposed in the first mold part, and
- a mold assembly comprising:
- the nested assembly is further
- the mold assembly according to the first aspect of the present invention may be configured such that a cavity for controlling the flow of current in the heat generating member is provided in the heat generating member.
- a cavity for controlling the flow of current in the heat generating member is provided in the heat generating member.
- a flow path for cooling the heat generating member by flowing a cooling medium is provided inside the heat generating member! /, S
- the cooling medium water having a high specific heat or high latent heat is suitable. In terms of temperature, water at normal temperature may be used in consideration of cost, or hot water in which the mold is temperature-controlled can be used. If the flow rate of the cooling medium is at least 0.5 liter / min or more, a sufficiently high cooling rate can be achieved. Further, the cooling rate can be further improved by increasing the cooling medium flow rate using a pressurizing pump or the like.
- the heating current is turned off and the cooling by heat transfer is started.
- the cooling medium for example, an electromagnetic valve is arranged in the pipe connected to the flow path
- the cooling medium can be flowed in the flow path by opening the electromagnetic vano rev.
- the heat of the heat generating member can be reliably and quickly removed, so cooling Compared to the case where no medium is used, the cooling rate can be increased by 5 times or more.
- the width and height of the cavity or the flow path are the thickness and strength of the portion of the heating member provided with the cavity or the like. It is preferable to determine as follows according to the relationship. That is, it is designed so that the minimum remaining thickness (t) on the side facing the cavity of the heat generating member (referred to as the cavity surface side) is! ⁇ 10mm, and the width (w) of the cavity is w ⁇ Designed to satisfy the 2 -t relationship, injection into the cavity
- the thickness is 0.1 mm to 20 mm, and w is preferably lmm or more.
- the pitch of the cavities, etc. is designed so that the shortest distance (w) between adjacent cavities, etc. is 1 mm or more. It is possible to secure S.
- Examples of projected shapes such as cavities include linear shapes, lattice shapes, spiral shapes, spiral shapes, partially concentric circle shapes, and zigzag shapes.
- examples of the cross-sectional shape of the cavity and the like include a rectangle, a circle, an ellipse, a trapezoid, and a polygon. From the viewpoint of maintaining the strength of the heat generating member, it is preferable to round the corners such as cavities, thereby avoiding stress concentration.
- a method for forming a cavity or the like a method of forming a cavity or the like formed by a groove or a through hole by performing NC machining or electric discharge machining on the heat generating member can be cited, or alternatively, a laser one molding method can be used.
- a method of stacking the molten metal on the heat generating member can be mentioned.
- arc welding, diffusion welding, silver brazing adhesion, high-temperature fusion, Bonding can be done by bolting.
- the cavity or the like will not communicate with the outside.
- the inside of the outer edge portion of the heat generating member may be joined or may not be joined. In the latter case, since the electrical resistance value of the part that is not particularly joined becomes high, the temperature increase rate can be further improved.
- a port may be provided so that at least two pipes for introducing and discharging the cooling medium can be connected when the flow path is manufactured.
- a manifold having a cross-sectional area larger than the total cross-sectional area of the flow paths is flowed in order to uniformly introduce the cooling medium into these flow paths. It is preferable to arrange at the entrance of the road.
- the pipe diameter on the discharge part side of the flow path should be reduced, or the cross-sectional area of the manifold placed at the outlet part of the flow path should be reduced.
- the heat generating member As a result, it is possible to cool the heat generating member more uniformly. Further, when the inner side of the outer edge of the heat generating member is not joined, the cooling medium flows through a small gap, so that the entire heat generating member can be further uniformly cooled.
- the outer edge of the heat generating member must be securely sealed with an O-ring seal or the like so that the cooling medium does not leak.
- the heat generating member and the first electrode are directly connected using an insulating bolt or a conductive bolt to generate heat.
- the member and the second electrode can be directly connected using an insulating bolt or a conductive bolt, or the heating member and the first electrode can be connected to the first electrode as described below.
- the heat generating member and the second electrode can also be indirectly connected using the second conductive means by using the conductive means.
- (B-2) has a first end and a second end, is disposed inside the insert, passes through the insulating layer, and the heat generating member and the first end are in contact with each other.
- (B-3) Has a first end and a second end, is disposed inside the nest, passes through the insulating layer, and the heat generating member and the first end are in contact with each other.
- a second conductive means for passing current is provided,
- the first electrode is in contact with the exposed second end of the first conductive means
- the second electrode is in contact with the exposed second end of the second conducting means
- the heat generating member may be configured to be electrically connected to the first electrode via the first conductive means and electrically connected to the second electrode via the second conductive means. it can.
- the mold assembly according to the first aspect of the present invention having such a configuration is referred to as “a mold assembly having a first configuration” for convenience.
- the nesting is further performed.
- the heat generating member is fixed on the insulating layer, the first conductive region, the conductive region extending portion, and the second conductive region, and constitutes part of the cavity, and the first conductive region, the conductive region extending portion, and the first conductive region Heated by Joule heat generated in the conduction area of 2 and by Jules heat generated by itself,
- the nested assembly is further
- (B-2) has a first end and a second end, is arranged inside the nest, the first conductive region and the first end are in contact, and the first conductive region A first conductive means for conducting current, and
- (B-3) has a first end and a second end, is placed inside the nest, and has a second conduction The region and the first end are in contact with each other, and has a second conductive means for passing a current through the second conductive region,
- the first electrode is in contact with the exposed second end of the first conductive means
- the second electrode is in contact with the exposed second end of the second conducting means
- the heat generating member may be configured to be electrically connected to the first electrode via the first conductive means and electrically connected to the second electrode via the second conductive means. It can. Note that the mold assembly according to the first aspect of the present invention having such a configuration is referred to as a “mold assembly having a second configuration” for convenience.
- the electric resistance value at 20 ° of the material constituting the heat generating member is R, the first conduction region, the second conduction region, and Configure the conductive region extension
- the electric resistance values of the first electrode, the second electrode, the first conductive means, the second conductive means, the first conductive region, the second conductive region, and the heating member are as follows: Satisfying the relationship is preferable from the viewpoint of achieving reliable heat generation of the heat generating member and preventing heat generation in the first electrode, the second electrode, the first conductive means, and the second conductive means.
- the electric resistance value can be obtained from ⁇ (volume resistance value of material / cross-sectional area of member) X length of member ⁇ .
- the electric resistance value R at 20 ° C of the material constituting the heat-generating member can be exemplified 2 X 10- 5 ⁇ 8 ⁇ 10- 2 ⁇ .
- the heat generating member has a tip portion screwed into the heat generating member and penetrates the insert.
- the second end of the first conductive means and the second end of the second conductive means are: Further, it is preferable that the structure is exposed on the side surface or the bottom surface of the nested body. Further, each of the first conductive means and the second conductive means is made of a block-shaped metal material (for example, copper). It is desirable to be made from.
- each of the first conductive means and the second conductive means is a tip.
- the portion corresponds to the first end
- the head corresponds to the second end
- the front end of the bolt is screwed with the heat generating member, and the head of the bolt is in contact with the electrode.
- the first mold portion is attached to the side of the insert.
- a side block that is attached to the side of the insert or the inside of the side block has a thermal conductivity of 1.3 (W / m'K) to 6. 3 (W / mK) and a thickness of 0.5 mm to 5 mm is formed to suppress rapid cooling of the molten thermoplastic resin injected into the cavity, or From the viewpoint of reducing the temperature uniformity of the heat generating member and the temperature increase / decrease loss, it is preferable from the viewpoint of improving insulation.
- the insert assembly further includes:
- the first conductive means is provided on the surface facing the nest, the first conductive means is in contact with the heat generating member, and the first conductive means faces the first side of the nest.
- the second conductive means is provided on the surface facing the nest, the second conductive means is in contact with the heat generating member, and is on the second side facing the first side of the nest.
- the first electrode is in contact with the first conductive means
- the second electrode is in contact with the second conductive means
- the heat generating member may be configured to be electrically connected to the first electrode via the first conductive means and electrically connected to the second electrode via the second conductive means. It can. Note that the mold assembly according to the first aspect of the present invention having such a configuration is referred to as a “mold assembly having a third configuration” for convenience.
- the nesting is further
- the heat generating member is fixed on the insulating layer, the first conductive region, the conductive region extending portion, and the second conductive region, and constitutes part of the cavity, and the first conductive region, the conductive region extending portion, and the first conductive region Heated by Joule heat generated in the conduction area of 2 and by Jules heat generated by itself,
- the nested assembly is further
- the first conductive means is provided on the surface facing the nesting, the first conductive means is in contact with the first conductive region, and faces the first side surface of the nesting.
- a first side block attached to the first mold part, and
- the second conductive means is provided on the surface facing the nest, the second conductive means is in contact with the second conductive region, and the second conductive means is opposed to the first side surface of the nest.
- a second side block attached to the first mold part, facing the side of the
- the first electrode is in contact with the first conductive means
- the second electrode is in contact with the second conductive means
- the heat generating member may be configured to be electrically connected to the first electrode via the first conductive means and electrically connected to the second electrode via the second conductive means. It can. Note that the mold assembly according to the first aspect of the present invention having such a configuration is referred to as a “fourth configuration mold assembly” for convenience.
- the insert further includes
- the heat generating member is fixed on the insulating layer, the first conductive region, the conductive region extending portion, and the second conductive region, and constitutes part of the cavity, and the first conductive region, the conductive region extending portion, and the first conductive region Heated by Joule heat generated in the conduction area of 2 and by Jules heat generated by itself,
- the nested assembly is further
- the first conductive means and the second conductive means are provided on the surface facing the nest, and the first conductive means is in contact with the first conductive region and is separated from the first conductive means.
- the first side block attached to the first mold part with the second conductive means provided in contact with the second conductive region and facing the first side surface of the nest And
- the first electrode is in contact with the first conductive means
- the second electrode is in contact with the second conductive means
- the heat generating member may be configured to be electrically connected to the first electrode via the first conductive means and electrically connected to the second electrode via the second conductive means. It can. Note that the mold assembly according to the first aspect of the present invention having such a configuration is referred to as a “fifth configuration mold assembly” for convenience.
- the fourth configuration! / Is the mold assembly of the fifth configuration! /, And the electric resistance value at 20 ° C. of the material constituting the heat generating member is R, the first conduction region , Second conduction region and conduction region
- each of the first electrode, the second electrode, the first conductive means, the second conductive means, the first conductive region, the conductive region extending portion, the second conductive region, and the heating member The resistance value satisfying the following relationship achieves reliable heat generation of the heat generating member, and in the first electrode, the second electrode, the first conductive means, and the second conductive means. It is preferable from the viewpoint of preventing heat generation.
- As the electric resistance value R at 20 ° C of the material constituting the heat-generating member can be exemplified 2 X 10- 5 ⁇ 8 ⁇ 10- 2 ⁇ .
- a thermal conductivity of 1 ⁇ 3 is provided inside each of the first side block and the second side block. (W / mK) to 6.3 (W / mK), and a ceramic material layer having a thickness of 0.5 mm to 5 mm is formed, the rapid cooling of the molten thermoplastic resin injected into the cavity It is preferable from the viewpoint of suppressing the temperature, or from the viewpoint of reducing the temperature uniformity and temperature increase / decrease loss of the heat generating member, and from the viewpoint of improving the insulation.
- the heat generating member has a tip portion screwed into the heat generating member and penetrates the insert.
- the heat generating member can be configured to be fixed to the nest by insulating bolts, or the heat generating member can include a first protrusion provided on the top of the first side block and a second side. The second protrusion provided on the top of the block is fixed to the nest by force S.
- the volume resistivity at 20 ° C of the material constituting the heat generating member (O. 017 ⁇ ⁇ ⁇ to 1.5 ⁇ ⁇ ⁇ , preferably (O.026 ⁇ ⁇ ⁇ to 0.8 ⁇ -m, more preferably 0 ⁇ 1, 1, ⁇ ⁇ ⁇ to 0 ⁇ 8 ⁇ ⁇ ⁇ is desirable, more specifically, the material having a volume resistivity of 0.017 / 2 ⁇ * m is copper (Cu), and the volume resistivity is The material having a rate of 0 ⁇ 026 ⁇ ⁇ m is aluminum (A1), and the thickness of the heat generating member is preferably 0.1 mm to 20 mm, preferably 0.3 mm to 5 mm.
- the mold assembly according to the first aspect of the present invention including the various preferable modes and configurations described above is arranged in the first mold part and / or the second mold part. It is desirable to further include a molten resin injection portion that is provided and communicates with the cavity.
- the molten resin injection portion may be any known gate structure, for example, a direct gate structure, a side gate structure, a jump gate structure, a pinpoint gate structure, a tunnel gate structure, a ring structure, Examples include a gate structure, a fan gate structure, a disk gate structure, a flash gate structure, a tab gate structure, and a film gate structure.
- the mold assembly according to the second to fourth aspects of the present invention includes:
- a mold that includes a first mold part and a second mold part, and a cavity is formed by clamping the first mold part and the second mold part,
- the insert is
- (b-2) A heating layer that is electrically connected to the first electrode and the second electrode and is formed on at least the top surface of the nesting body facing the cavity, and generates Joule heat.
- the nested assembly is further
- (B-1) A nesting mounting block disposed between the bottom surface of the nesting body and the first mold part and attached to the first mold part, It is characterized by being equipped with.
- the insert is
- the nested assembly is further
- the first conductive means is provided on the surface facing the nest, and the first conductive means is in contact with the first portion of the heat generating layer and faces the first side surface of the nest.
- a first side block attached to the first mold part, and
- the second conductive means is provided on the surface facing the nest, the second conductive means is in contact with the second portion of the heat generating layer and faces the first side of the nest.
- a second side block attached to the first mold part while facing the second side surface;
- the first electrode is in contact with the first conductive means
- the second electrode is in contact with the second conductive means.
- the heating layer is formed from the top surface of the nesting body facing the cavity to the side surface of the nesting body, from the top surface of the nesting body facing the cavity to the side surface of the nesting body, and further from the bottom surface. The form formed over the surface can be mentioned.
- the insert is
- the first conductive means and the second conductive means are provided on the surface facing the nest, and the first conductive means is in contact with the first portion of the heat generating layer, and the first conductive means The second conductive means spaced apart from the first portion is in contact with the second portion of the heat generating layer and faces the first side surface of the nest, and is attached to the first mold portion. 1 side block,
- the first electrode is in contact with the first conductive means
- the second electrode is in contact with the second conductive means.
- the heating layer is formed from the top surface of the nesting body facing the cavity to the side surface of the nesting body, from the top surface of the nesting body facing the cavity to the side surface of the nesting body, and further from the bottom surface. The form formed over the surface can be mentioned.
- a flow path for cooling the insert by flowing a cooling medium is provided inside the insert mounting block.
- Power S can be. It is desirable that the flow path be provided in an area close to the cavity inside the nested mounting block or in a surface area of the nested mounting block.
- the cooling medium water having a high specific heat or high latent heat is suitable. In terms of temperature, water at normal temperature may be used in consideration of cost, or hot water in which the mold is temperature-controlled can be used. If the flow rate of the cooling medium is at least 0.5 liter / min or more, a sufficiently high cooling rate can be achieved. Further, the cooling rate can be further increased by increasing the coolant flow rate using a pressurizing pump or the like.
- the heating current is turned off and cooling by heat transfer is started, but when the cooling medium is flowed, for example, an electromagnetic valve is placed in the pipe connected to the flow path to By opening the valve, the cooling medium can flow through the flow path.
- the cooling medium As the introduced cooling medium flows in the flow path, the heat of the nesting can be reliably and quickly taken away, so the cooling rate must be at least twice as fast as when no cooling medium is used. Is possible.
- the solenoid valve is closed, the air valve is opened, air blow is performed, and the flow path is purged. Then move on to the next molding cycle.
- the width and height of the flow path are preferably determined as follows according to the relationship between the thickness and strength of the portion of the nested mounting block provided with the flow path. That is, the design is such that the minimum remaining thickness (t) on the cavity-facing side of the nesting block (referred to as the cavity surface side) is !! ⁇ 1 Omm, and the flow path width (w) is w To satisfy the relationship of ⁇ 2 -t
- w is preferably lmm or more.
- the pitch of the flow path is designed so that the shortest distance (w) between the adjacent flow paths and the flow path is at least lmm, ensuring the strength of the nesting mounting block. can do.
- Examples of the projected shape of the flow path include a linear shape, a lattice shape, a spiral shape, a spiral shape, a partially concentric circle shape, and a zigzag shape.
- the cross-sectional shape of the flow path can be a rectangle, circle, ellipse, trapezoid, or polygon. From the point of view of maintaining the strength of the nested block, it is preferable to round the corners of the flow path, thereby avoiding stress concentration.
- a method of forming a flow path including a groove portion or a through hole by performing NC machining or electric discharge machining on the nesting mounting block can be cited.
- a laser can be formed. It is possible to cite a method of stacking molten metal on nested mounting blocks using modeling methods. For example, in order to produce a 35 mm thick nested mounting block with a flow path, a 2.5 mm plate and a 32.5 mm plate are used, and each plate has a desired size of flow path (for example, a groove).
- Nested blocks can be obtained by bonding together by bonding, high-temperature fusion, bolt fastening, and the like.
- a flow path (for example, a groove) of a desired size is formed on the surface of a single plate material by NC machining, and then a nest is attached to this surface to obtain an assembly of a nest and a nest mounting block. be able to. If an O-ring seal or the like is provided on the inner edge of the nesting attachment block, the flow path will not communicate with the outside. Yes.
- the inner side of the outer edge of the nesting mounting block may or may not be joined.
- a port may be provided so that at least two pipes for introducing and discharging the cooling medium can be connected when the flow path is manufactured.
- a manifold having a cross-sectional area larger than the total cross-sectional area of the flow paths is flowed in order to uniformly introduce the cooling medium into these flow paths. It is preferable to arrange at the entrance of the road.
- the pipe diameter on the discharge part side of the flow path should be reduced, or the cross-sectional area of the manifold placed at the outlet part of the flow path should be reduced.
- the first electrode is fixed to the insert mounting block using an insulating bolt or a conductive bolt, and the first electrode is fixed. It is also possible to connect directly to the heat generation layer, fix the second electrode to the nested mounting block using insulating bolts or conductive bolts, and connect the second electrode directly to the heat generation layer. As described below, the nested mounting block and the first electrode are indirectly connected by using the first conductive means, and the nested mounting block and the second electrode are used by the second conductive means. You can also connect indirectly.
- the force to use an insulating bolt the force to apply an insulating coating on the surface of the conductive bolt, and the conductive tape together with the insulating tape material provide insulation. It is preferable to do.
- the heat generating layer extends from the top surface of the nested body facing the cavity to the side surface of the nested body and the bottom surface of the nested body. Is formed on a part of
- the nested assembly is further (B-2) The first side block attached to the first mold part in a state facing the first side surface of the nest,
- the second end and the first end of the heat generating layer which has a first end and a second end, are disposed inside the nesting mounting block and formed on the bottom surface of the nesting body.
- a second conductive means that is in contact with each other and allows a current to flow through the heat generating layer
- the first electrode is in contact with the exposed second end of the first conductive means
- the second electrode is in contact with the exposed second end of the second conducting means
- the heat generating layer may be configured to be electrically connected to the first electrode via the first conductive means and to be electrically connected to the second electrode via the second conductive means. it can.
- each of the first conductive means and the second conductive means is made of a block-shaped metal material (for example, copper ) Is desirable.
- each of the first conductive means and the second conductive means is a block-shaped metal material (for example, copper ) Is desirable.
- the first side block facing the side surface of the nest Of the first side block and the second side block facing the nesting side or the second side block has a thermal conductivity of 1.3 (W / mK) to 6.3 (W / mK), and a ceramic material layer with a thickness of 0.5 mm to 5 mm is formed, the sharpness of the molten thermoplastic resin injected into the cavity It is preferable from the viewpoint of when cooling is suppressed, or when the temperature uniformity of the nesting and the rise / fall of the temperature are reduced, and further from the viewpoint of improving the insulation.
- the volume resistivity at 20 ° C of the material constituting the heat generating layer (O. 017 ⁇ ⁇ ⁇ to 1.5 ⁇ ⁇ ⁇ , preferably (O.026 ⁇ ⁇ ⁇ to 0.8 ⁇ ⁇ m, more preferably 0.1 ⁇ ⁇ ⁇ to is desirably 0 ⁇ 8 ⁇ ⁇ ⁇ . here, more specifically, the volume resistivity of the material of 0.
- 01 7 ⁇ ⁇ * m is a copper (Cu), volume resistivity 0 ⁇
- the material of 026 ⁇ .m is aluminum (A1)
- the thickness of the heating layer is 0.03 mm to 1.0 mm, preferably 0.03 mm to 0.5 mm, more preferably 0.1 mm to 0.3 mm is desirable.
- the mold assembly according to the second to fourth aspects of the present invention includes the first mold part and / or the second mold. It is desirable to further include a molten resin injection part disposed in the mold part and communicating with the cavity.
- the molten resin injection part can be any known gate structure, for example, a direct gate structure, a side gate structure, a jump gate structure, a pinpoint gate structure, a tunnel gate structure, Examples thereof include a ring gate structure, a fan gate structure, a disk gate structure, a flash gate structure, a tab gate structure, and a film gate structure.
- the nest is placed on the top of the first side block.
- the first protrusion provided and the second protrusion provided on the top of the second side block may be fixed.
- the mold assembly according to the first to fourth aspects of the present invention including the various preferred forms and configurations described above (hereinafter collectively referred to simply as the mold of the present invention)
- the mold is made from a metal material such as carbon steel, stainless steel, aluminum alloy, or copper alloy by a well-known method.
- examples of the material constituting the nested body include metal materials such as carbon steel, stainless steel, aluminum alloy, and copper alloy. It can be manufactured based on X-type polishing or wire electric discharge machining. Appropriate straight line A through-hole having a diameter may be provided inside the nested body, and a pipe for flowing cooling water may be disposed in the through-hole.
- examples of the material constituting the insert mounting block include metal materials such as carbon steel, stainless steel, aluminum alloy, and copper alloy. It can be manufactured based on IJ ⁇ polishing and wire electric discharge machining.
- a nesting attachment block may be provided.
- the interior of the nesting mounting block is similar to the mold assembly according to the second aspect of the present invention. May be provided with a flow path for cooling the nest by flowing a cooling medium.
- the material constituting the insulating layer has a thermal conductivity of 1 ⁇ 3 (W / mK) to 6 ⁇ 3 (W / mK),
- a ceramic material having a thickness of 0.5 mm to 5 mm can be exemplified.
- ceramic materials there can be broadly exemplified ceramics selected from zinco-based materials, partially-stabilized ginoleco-urea, alumina-based materials, and group force consisting of K 2 O-TiO force, and more specifically, ZrO, ZrO—CaO, ZrO Y ⁇ , ZrO MgO, ZrO SiO, ZrO CeO, KO—TiO, Al O, A 1 O—TiC, Ti N, 3A1 O—2SiO, MgO—SiO, 2MgO—SiO, MgO— Al O
- the method for forming the insulating layer may be appropriately selected depending on the material used. For example, a thermal spraying method (a method in which a powder composed of the above composition is sprayed onto the nesting body at a high temperature using a thermal spray gun. And arc spraying, plasma spraying, etc.).
- a material constituting the nesting body a wide range of materials is widely used: a zirconia-based material, a partially stabilized zirconia, an alumina-based material, K
- ceramics selected from the group consisting of O-TiO forces, more specifically ZrO, ZrO-CaO, ZrO—YO, ZrO—MgO, ZrO—SiO, ZrO—CeO, K 2 O—TiO Al O, Al O- TiC, Ti N, SAl ⁇ - 2SiO, MgO- SiO 2, 2MgO- Si_ ⁇ 2, MgO-Al O - SiO and titania force, et group consisting force, cited et selected ceramics That power S.
- a method of forming the nesting body for example, a plate-like nesting Examples thereof include a method of forming the main body by a firing method, a method of sintering a shaped net, and a method of finishing from a sintered block by cutting.
- the nested body is made of a sintered body.
- the nest body is sprayed at a high temperature by the spraying method (that is, using a spray gun) with the powder composed of the above composition on the nest mounting block. It can also be formed by arc spraying, plasma spraying, plasma powder single spraying, HVOF, etc.
- the material constituting the heat generating member can be any material as long as it is a conductive material such as stainless steel, steel, titanium, nickel, etc.
- the forces capable of S it is preferable to use titanium.
- the method for producing the heat generating member may be appropriately selected according to the material to be used. Examples thereof include processing into a plate shape, a plating method, and an electrodeposition method.
- the force that the heat generating member is fixed on the insulating layer or the like The concept of “fixing” includes a stamper configuration in which the heat generating member is detachably mounted on the insulating layer or the like, and the heat generating member is insulated.
- a form in which the insulating layer or the like is integrally formed on the layer or the like (for example, formed by a plating method or an electrodeposition method) is also included.
- the surface of the heat generating member may be smooth or may be provided with a pattern depending on the molded product to be molded.
- a design layer for applying a design to the surface of the molded product to be molded may be provided on the surface of the heat generating member, or the design layer may be placed and fixed.
- the state of heat generation depends on the heat generating member. Any value is not a problem.
- the thickness S of the plating layer can be exemplified by 0.03 mm to 0.5 mm.
- copper (Cu), a copper alloy for example, a copper-zinc alloy, a copper-cadmium alloy
- Copper-tin alloy Copper-tin alloy
- Cr chromium
- chromium alloy for example, nickel-chromium alloy
- nickel, nickel alloy nickel alloy (nickel-iron alloy, nickel-cobalt alloy, nickel-tin alloy, nickel-phosphorus alloy [Ni-P ), Nickel-iron-phosphorous alloy [NiFeP-based], nickel-cobalt-phosphorous alloy [Ni-Co-P-based]).
- the heat generation layer examples thereof include an electrolytic plating method, an electroless plating method, and a paste printing method.
- the surface of the heat generating layer may be smooth or may be provided with a pattern depending on the molded product to be molded.
- a design layer for applying a design to the surface of the molded product to be molded may be provided on the surface of the heat generating layer, or the design layer may be placed and fixed.
- a resin layer such as polyethylene and epoxy, a coating (preferably an insulating paint), an alumite treatment, a non-conductive coating layer made of tin alloy, etc.
- the side block may be made from the metal material exemplified as the material constituting the nesting body or the nesting mounting block, and the ceramic material layer may be formed from various materials exemplified as the material constituting the insulating layer or the nesting body. Good.
- the mold assembly of the second configuration or the fourth configuration to the fifth configuration as a material constituting the first conductive region, the conductive region extending portion, and the second conductive region, copper ( Cu), copper alloys (for example, copper-zinc alloys, copper-cadmium alloys, copper-tin alloys), chromium (Cr), chromium alloys (for example, nickel-one-chromium alloys), nickel-nore (Ni), nickel-nore alloys (two Nickel-iron alloy, nickel-cobalt alloy, nickel-tin alloy, nickel-phosphorus alloy [Ni-P series], nickel-iron iron-phosphorus alloy [NiFeP-series], nickel-cobalt-phosphorus alloy [Ni-Co-P-series]), Carbon can be mentioned.
- the method for forming the first conductive region, the conductive region extending portion, and the second conductive region include an electrolytic plating method, an electroless plating method, and a paste printing method.
- the first conductive means In the mold assembly of the first configuration or the third configuration in the mold assembly according to the first aspect of the present invention, the first conductive means, the heating member, In the mold assembly of the second configuration or the fourth configuration to the fifth configuration, the first conductive means, the first conductive means, 1st conduction area, conduction area extension The current flows to the existing part, the second conductive region, the second conductive means, and the second electrode.
- either direct current or alternating current may be used.
- Direct current is safer and safer as the frequency increases. For this reason, it is more preferable to use direct current than high frequency alternating current, which is more preferable to use high frequency alternating current than low frequency alternating current, and it is even more preferable to use high frequency direct current rather than direct current.
- the current to be passed can be exemplified by 1 ⁇ 10 2 ampere to 6 ⁇ 10 3 ampere, depending on the volume resistivity and size of the heat generating member.
- the voltage to be applied may be selected appropriately based on the current value to be applied and the electric resistance value of the heat generating member.
- the current supply may be started before the molten thermoplastic resin is injected into the cavity (for example, 1 second to 20 seconds before).
- the current supply to the heating member or the first conductive means is stopped at the same time as or after the injection of the molten thermoplastic resin into the cavity is completed (for example, after 0 to 30 seconds have elapsed from the completion of the injection). )And it is sufficient. If the set temperature is reached before or after the injection of the molten thermoplastic resin into the cavity, the current to the heat generating member or the first conductive means may be reached at that point in some cases. You can stop the supply.
- current is passed from the first electrode to the first conductive means, the heat generating layer, the second conductive means, and the second electrode.
- either direct current or alternating current may be used, and examples of the current to flow include 5 ⁇ 10 amperes to 2 ⁇ 10 3 amperes.
- an appropriate voltage may be selected as the applied voltage based on the current value to be applied and the electric resistance value of the heat generating layer.
- the current supply to the heat generating layer in the mold assembly of the present invention may be started before the molten thermoplastic resin is injected into the cavity (for example, 1 second to 20 seconds before). On the other hand Stop supplying current to the thermal layer at the same time as or after completion of injection of the molten thermoplastic resin into the cavity (for example, after 0 to 30 seconds have elapsed from the completion of injection! /). If the set temperature is reached before or after the injection of the molten thermoplastic resin into the cavity, the current supply to the heat generating layer may be stopped at that point in some cases. .
- the heat generating member is further heated by passing an electric current through the heat generating member, or alternatively, the first conductive region, the conductive region.
- the heat generating member is heated by the heat. 150 ° C ⁇ T ⁇ 280 ° C as an example, where T is the surface temperature of the heating element (the temperature of the surface facing the cavity)
- thermoplastic resin that is metered, plasticized and melted in an injection cylinder provided in an injection molding apparatus is injected from the injection cylinder, and a sprue and a molten resin injection part ( It is introduced (injected) into the cavity through the gate part) (injected) and held in pressure, but when the temperature of the molten thermoplastic resin in the injection cylinder is T, (T-230) ° C ⁇ T ⁇ T °
- T temperature of the molten thermoplastic resin in the injection cylinder
- T-230 ° C ⁇ T ⁇ T °
- the power to illustrate C is S.
- the force that causes the heat generating layer to generate heat by passing a current through the heat generating layer is T, 150 ° C ⁇ T ⁇ 280 ° C
- thermoplastic resin that is usually metered, plasticized and melted in an injection cylinder provided in an injection molding apparatus is injected from the injection cylinder, and a sprue and a molten resin injection part (gate) installed in a mold. Is introduced (emitted) into the cavity through the air and the pressure is maintained, but the temperature of the molten thermoplastic resin in the injection cylinder is ⁇
- thermoplastic resin suitable for molding a molded article using the mold assembly of the present invention include a crystalline thermoplastic resin and an amorphous thermoplastic resin, and specifically, polyethylene.
- Polyolefin resins such as resins and polypropylene resins; Polyamide resins such as polyamide 6, polyamide 66 and polyamide MXD6; Polyoxymethylene resins; Polyesters such as polyethylene terephthalate (PET) resins and polybutylene terephthalate (PBT) resins Resin; Polystyrene sulfide resin; Styrene resin such as polystyrene resin, ABS resin, AES resin, AS resin; Methacrylic resin; Polycarbonate resin; Modified PPE resin; Polysulfone resin; Polyethersulfone resin; Polyarylate resin; Resin; Polyamideimide resin; Polyimide resin; Polyetherketone resin; Polyetheretherketone resin; Polyester carbonate resin; Liquid crystal polymer, COP, COC
- thermoplastic resin made of a polymer alloy material can be used.
- the polymer alloy material is composed of a blend of at least two types of thermoplastic resins, or a block copolymer or a Daraff copolymer obtained by chemically combining at least two types of thermoplastic resins.
- Polymer alloy materials are widely used as highly functional materials that can have the unique performance of each single thermoplastic resin.
- thermoplastic resin that constitutes the polymer alloy material that is a blend of at least two types of thermoplastic resins, styrene resins such as polystyrene resin, ABS resin, AES resin and AS resin; polyolefin resins such as polyethylene resin and polypropylene resin; Metatalyl resin; Polycarbonate resin; Polyamide, Polyamide, 6, Polyamide, 66, Polyamide, MXD6, and other resins; Modified PPE resin; Polyester resin such as polybutylene terephthalate resin and polyethylene terephthalate resin; Polyoxymethylene resin; Polysulfone Resin; Polyimide resin; Polyphenylene sulfide resin; Polyarylate resin; Polyethersulfone resin; Polyetherketone resin; Polyetheretherketone resin; Polyester carbonate resin; Liquid crystal polymer; The last one can be mentioned.
- styrene resins such as polystyrene resin, ABS resin, AES resin and AS resin
- polyolefin resins
- polycarbonate resin As a polymer alloy material made by blending two types of thermoplastic resin, a polymer alloy material of polycarbonate resin and ABS resin can be exemplified. Such a combination of resins is expressed as polycarbonate resin / ABS resin. The same applies to the following.
- polycarbonate resin / PET resin polycarbonate resin / PBT resin, polycarbonate resin / polyamide resin, polycarbonate resin / PBT resin / PET resin, modified PPE resin as polymer alloy materials blended with at least two types of thermoplastic resin / HIPS resin, modified PPE resin / polyamide resin, modified PPE resin / PBT resin / PET resin, modified PPE resin / polyamide MXD6 resin, polyoxymethylene resin / polyurethane resin, PBT resin / PET resin Examples thereof include fat and polycarbonate resin / liquid crystal polymer.
- HIPS resin, ABS resin, AES resin, and AAS resin can be exemplified as a polymer alloy material made of a block copolymer or graft copolymer in which at least two kinds of thermoplastic resins are chemically bonded.
- thermoplastic resins described above It is possible to add stabilizers, ultraviolet absorbers, mold release agents, dyes and pigments to the various thermoplastic resins described above, and there is no need for glass beads, my strength, kaolin, calcium carbonate, etc.
- Machine fibers, inorganic fillers, or organic fillers can also be added.
- the inorganic fiber glass fiber, carbon fiber, wollastonite, aluminum borate whisker fiber, potassium titanate whisker fiber, basic magnesium sulfate whisker fiber, calcium silicate whisker fiber And calcium sulfate whisker fibers, and the content of inorganic fibers can be 5 to 80% by weight.
- an insulating layer having a defined thermal conductivity and thickness is formed on the top surface of the nested body, and the heat generating member and the first conduction region are formed. Since the conduction region extension and the second conduction region are designed to efficiently generate heat, it is possible to improve the temperature rise characteristics and temperature uniformity during energization. Therefore, the molten thermoplastic resin injected into the cavity cannot be cooled suddenly or unevenly, and it is difficult for appearance defects such as weld marks, flow marks, and glass fiber floats to occur in molded products.
- the fluidity of the molten thermoplastic resin in the cavity can be remarkably improved, so that fine irregularities can be reliably transferred to the surface of the molded product, and distortion occurs inside the molded product. hard. If the first conductive means and the second conductive means are defined, the heat generating member In addition, a large current can be reliably and safely passed through the first conduction region, the conduction region extension, and the second conduction region.
- the mold assembly by providing a cavity for controlling the flow of current in the heat generating member inside the heat generating member, that is, partially By reducing the thickness, the electric resistance value increases, and as a result, the current density increases, so that the temperature rises easily, and the heat generation state of the heat generating member can be controlled easily and accurately.
- Force S is possible.
- the temperature of the heat generating member is controlled by a temperature measuring means such as a thermocouple installed inside, and after the heat generating member reaches the set temperature, the molten thermoplastic resin is placed in the cavity. At the same time as the injection is completed, or after a predetermined time has elapsed, the cooling process is performed by flowing the cooling medium through the heat generating member.
- the molding cycle can be shortened, and productivity can be improved.
- the heat generating layer is formed on the surface of the nested body in which the thermal conductivity and the thickness are defined. It is possible to improve the temperature rise characteristics and temperature uniformity. Therefore, appearance defects such as weld marks, flow marks, and glass fiber floating occur in molded products in which the molten thermoplastic resin injected into the cavity cannot be cooled rapidly or unevenly. As a result, the fluidity of the molten thermoplastic resin in the cavity can be remarkably improved, so that fine irregularities can be reliably transferred to the surface of the molded product, and distortion is generated inside the molded product. Hard to live.
- the first conductive means and the second conductive means are defined, a large current can be reliably and safely passed through the heat generating layer. Since the heat generating layer is formed on the nested body having a heat insulating effect, the heat generating layer can be heated with a relatively small current.
- the temperature control of the nesting is usually performed while the temperature of the nesting is measured by a temperature measuring means such as a thermocouple installed therein.
- a temperature measuring means such as a thermocouple installed therein.
- the molten thermoplastic resin is injected into the cavity, and enters the cooling process at the same time as the injection is completed or after a predetermined time has elapsed.
- the cooling time of the injected thermoplastic resin can be shortened, that is, the molding cycle can be shortened, and the productivity can be improved.
- FIG. 1 (A) is a schematic perspective view of a nested assembly in the mold assembly of Example 1, and FIG. 1 (B) is an arrow A in FIG. 1 (A). — A schematic cross-sectional view along A.
- FIG. 2 (A), (B) and (C) in FIG. 2 are a schematic perspective view and a schematic of a side block, respectively, when the insert body and the like in the mold assembly of Example 1 are cut.
- FIG. 2 is a schematic perspective view and a schematic perspective view of a first electrode.
- Fig. 3 is a schematic perspective view of the nesting body and the like before assembly in the mold assembly of the first embodiment.
- FIG. 4 (A) and (B) in FIG. 4 are conceptual diagrams of the entire mold assembly and injection molding apparatus, respectively.
- FIG. 5 is a schematic cross-sectional view of a nesting assembly in the mold assembly of Example 2.
- FIG. 6 (A) is a schematic cross-sectional view of a nesting assembly in the mold assembly of Example 3
- FIG. 6 (B) is a diagram of the mold assembly in Example 3. It is a typical perspective view when a nesting body etc. are cut.
- FIGS. 7A to 7C schematically show patterns of a first conduction region, a conduction region extension portion, and a second conduction region in the mold assembly of Example 3.
- FIG. 7
- FIG. 8 is a schematic cross-sectional view of a nesting assembly in the mold assembly of Example 4.
- FIG. 9 (A) is a schematic cross-sectional view of a nested assembly in the mold assembly of Example 5, and FIG. 9 (B) is a schematic perspective view of a side block. is there.
- FIG. 10 is a schematic cross-sectional view of a nesting assembly in a mold assembly of Example 6.
- FIGS. 11A and 11B schematically show patterns of a first conduction region, a conduction region extending portion, and a second conduction region in the mold assembly of Example 6.
- FIG. 11
- FIG. 12 (A) and (B) of FIG. 12 are schematic views of the nested assembly in the mold assembly of Example 7. It is typical sectional drawing.
- FIGS. 13A and 13B are diagrams schematically showing patterns of the first conduction region, the conduction region extension, and the second conduction region in the mold assembly of Example 7. FIG. It is.
- FIG. 14 is a graph showing the results of measuring the temperature of the heat generating member when current was passed through the heat generating member in the nested assembly of Example 1.
- FIG. 15 (A) to (E) are schematic cross-sectional views of a heat generating member provided with a flow path for flowing a cooling medium.
- FIG. 16 (A) is a schematic cross-sectional view of the heat generating member along the direction perpendicular to the arrow A—A in FIG. 1 (A), and FIG. FIG. 6 is a schematic cross-sectional view when the heat generating member is cut along a virtual plane perpendicular to the thickness direction of the heat generating member.
- FIG. 17 (A) is a schematic perspective view of the insert assembly in the mold assembly of Example 10, and FIG. 17 (B) is an arrow A in FIG. 17 (A). — A schematic cross-sectional view along A.
- FIGS. 18A, 18B, and 18C are a schematic perspective view and a side block view of the side block when the insert body and the like in the mold assembly of Example 10 are cut, respectively.
- FIG. 2 is a schematic perspective view and a schematic perspective view of a first electrode.
- FIG. 19 is a schematic perspective view of a nesting body and the like before assembly in the mold assembly of Example 10.
- FIG. 20 (A) is a schematic cross-sectional view of the insert assembly in the mold assembly of Example 11, and FIG. 20 (B) is a schematic perspective view of the side block. is there.
- FIG. 21 is a schematic cross-sectional view of a nesting assembly in a modified example of the mold assembly of Example 11.
- FIG. 22 (A) and (B) are schematic cross-sectional views of a nesting assembly in a mold assembly of Example 12.
- FIG. 22 (A) and (B) are schematic cross-sectional views of a nesting assembly in a mold assembly of Example 12.
- FIG. 23 (A) to (D) schematically show the pattern of the heat generating layer in Example 12.
- FIG. 23 (A) to (D) schematically show the pattern of the heat generating layer in Example 12.
- FIG. 24 is a graph showing the results of measuring the temperature of the heat generating layer when a current was passed through the heat generating layer in the nested assembly of Example 10.
- FIG. 25 (A) in FIG. 25 is a schematic cross-sectional view of a nesting provided with a flow path for flowing a cooling medium, and (B) and (C) in FIG. It is a typical sectional view.
- FIG. 26 (A) in FIG. 26 is a schematic cross-sectional view similar to that of FIG. 17 (A) in FIG.
- FIG. 26 (B) is a schematic cross-sectional view of the nested mounting block cut along a virtual plane perpendicular to the thickness direction of the nested mounting block.
- FIG. 27 (A) to (C) are schematic cross-sectional views of modifications of the nesting mounting block provided with a flow path.
- FIGS. 28A to 28C are schematic sectional views of modified examples of the heat generating member.
- FIG. 29 (A) to (C) of FIG. 29 are schematic cross-sectional views of other modified examples of the heating member.
- FIG. 30 are schematic cross-sectional views of modified examples of the nesting and the nesting mounting block, respectively.
- FIG. 31 (A) and (B) of FIG. 31 are schematic cross-sectional views of another modified example of the nesting and the nesting mounting block, respectively.
- Example 1 relates to a mold assembly according to the first aspect of the present invention, and more specifically, to a mold assembly having the first configuration.
- a schematic perspective view of the insert assembly in the mold assembly of Example 1 is shown in ( ⁇ ) of FIG. 1, and a schematic cross-sectional view taken along arrows ⁇ — ⁇ of ( ⁇ ) of FIG. 1 is shown. Shown in 1 (B). Also, cut the nesting body along the arrow A—A in Fig. 1 (A).
- a schematic perspective view of the first electrode and the second electrode is shown in (A) of FIG. 2 and a schematic perspective view of the side block is shown in (B) of FIG. The figure is shown in Fig. 2 (C).
- a schematic perspective view of the nesting body before assembly is shown in FIG.
- FIGS. 4 (A) and 4 (B) 3 and conceptual diagrams of the entire mold assembly and the injection molding apparatus are shown in FIGS. 4 (A) and 4 (B).
- FIG. 1A some components are hatched to clearly indicate the components.
- Fig. 5, Fig. 6 (A), Fig. 8, Fig. 9 (A), and Fig. 10 described later are schematic cross-sectional views that are substantially the same as those taken along arrows A-A in Fig. 1 (A).
- FIG. 6B is a schematic perspective view when the nested body and the like are cut along arrows AA in FIG.
- the injection molding apparatus suitable for use in Example 1 or Examples 2 to 12 described later supplies molten thermoplastic resin. It includes an injection cylinder 10 having a screw 11 therein, a fixed platen 16A, a movable platen 16B, a tie bar 17, a hydraulic cylinder 18 for clamping, and a hydraulic piston 19.
- the movable platen 16B can be translated on the tie bar 17 by the operation of the hydraulic piston 19 in the clamping cylinder 18.
- the mold is composed of a second mold part (fixed mold part) 12, a first mold part (movable mold part) 13, It is composed of
- the fixed mold part 12 is attached to the fixed platen 16A
- the movable mold part 13 is attached to the movable platen 16B.
- the movable mold part 13 engages with the fixed mold part 12 and is clamped to form the cavity 15.
- the movable mold part 13 is disengaged from the fixed mold part 12 by moving the movable platen 16B in the direction of the arrow “B” in FIG.
- the mold part 12 is opened.
- the second mold part (fixed mold part) 12 is provided with a molten resin injection part (gate part) 14.
- the insert assembly 20 having the insert 30 is disposed in the first mold part (movable mold part) 13.
- the mold assembly includes a first electrode 60A and a second electrode 60B.
- the nesting 30 is composed of a nesting body 31 and an insulating layer 33 which are produced from a carbon steel S5 5C having a thickness of 35 mm by cutting 1 ”and polishing.
- the insulating layer 33 is, for example, a ceramic material having a thermal conductivity of 1.3 (W / m′K) to 6.3 (W / m′K) and a thickness of 0.5 mm to 5 mm.
- the nesting body 31 is made of Zirco-Year ceramics (Zr 0 2 — ⁇ 2 0 3 )] with a thickness of 1 ⁇ Omm and thermal conductivity of 3 (W / mK), and is applied to the top surface of the nested body 31 facing the cavity 15 by plasma spraying. It is formed based on the top surface of the nesting body 31.
- a lower insulating layer 32 made of the same material as the insulating layer 33 is also formed on the lower surface of the nested body 31.
- the nesting body 31 is provided with a gap (see FIG. 3) for attaching the first conductive means 50 ⁇ and the second conductive means 50 ⁇ .
- the insert assembly 20 further includes a heat generating member 41, a first conductive means 50 ⁇ , and a second conductive means 50 ⁇ .
- Heating member 41 has a thickness of 5. Omm, the volume resistivity at 20 ° C is 0 ⁇ 56 ⁇ ⁇ ⁇ ), the electric resistance value R of 1 ⁇ 96 X 10- 4 ⁇ SUS420J2 ( Hitachi Metals stock
- the first conductive means 50A for passing a current through the heat generating member 41 has a first end 51A and a second end 52A, and the inner beam of the insert 30 specifically, the insert body 31
- the heat generating member 41 and the first end 51A are in contact with each other through the insulating layer 33.
- the second conductive means 50B for causing a current to flow through the heat generating member 41 has a first end 51B and a second end 52B, and the inside of the insert 30 (more specifically, the insert body 31).
- the heating member 41 and the first end 51B are in contact with each other through the insulating layer 33.
- Each of the first conductive means 50A and the second conductive means 50B is made of a block-shaped metal material (specifically, copper) and has a substantially “L” -shaped cross section. Further, the second end 52 A of the first conductive means 50 A and the second end 52 B of the second conductive means 50 B are exposed on the side surface of the nesting body 31.
- the heat generating member 41 is screwed into the heat generating member 41 at its tip, and is an insulating bolt 35 that passes through the insert 30 [more specifically, Zirconia ceramics that is passed through the through hole 34 that passes through the insert 30 ( It is fixed to the nesting 30 by Bonoleto 35] made by ZrO-YO).
- the nesting assembly 20 further includes two side blocks 70A and 70B attached to the first mold part (movable mold part) 13 while facing the side surface of the nesting 30.
- Side blocks 70A and 70B are made of carbon steel.
- the side blocks 70A and 70B facing the side surfaces of the insert 30 have thermal conductivity of 1 ⁇ 3 (W / m'K) to 6 ⁇ 3 (W / m′K), and a ceramic material layer 71A, 71B having a thickness of 0.5 mm to 5 mm (specifically, a thickness of 0.8 mm) is formed based on a thermal spraying method.
- the ceramic material layers 71A and 71B are made of the same material as the insulating layer 33.
- the top portions 73A and 73B of the side blocks 70A and 70B are provided with protrusions 74A and 74B.
- the side surfaces 75A and 75B of the protrusions 74A and 74B face the cavity 15 and constitute a part of the cavity 15. To do.
- the top parts 73A and 73B of the side blocks 70A and 70B are the second molds.
- the side blocks 70A and 70B are provided with notches 72A and 72B for passing the first electrode 60A and the second electrode 60B.
- the first electrode 60A made of copper is in contact with the exposed second end 52A of the first conductive means 50A, and the second electrode 60B made of copper is exposed to the second conductive means 50B. In contact with the second end 52B. A part of the surface of the first electrode 60A and the second electrode 60B is covered with insulating films 61A and 61B. Furthermore, the portion of the first electrode 60A not in contact with the exposed second end 52A of the first conductive means 50A, and the exposed second end 52B of the second conductive means 50B The portion of the second electrode 60B that is not in contact is covered with an insulating paint (not shown). Further, the first electrode 60A and the second electrode 60B are provided with threaded mounting holes 62A, 62B for mounting the bolts 63A, 63B. Using 63B, the first electrode 60A and the second electrode 60B are securely fixed.
- the contact portion between the first electrode and the first conductive means, and the contact portion between the second electrode and the second conductive means may be flat, complementary shapes, or mutually. It may be a shape that engages with, for example, an uneven shape. The same applies to Examples 2 to 8 described later.
- the first conductive means 50 A and the second conductive means 50 B are inserted into the gap provided in the nesting body 31 from the side surface of the nesting body 31.
- the holding plate 36 is fixed to the side surface of the nesting body 31.
- the holding plate 36 is fixed to the side surface of the nesting body 31 through a through hole 37 provided in the holding plate 36, a mounting hole 38 provided in the side surface of the nesting body 31 and threaded, and a bolt (not shown). And fix with It can be done by the method.
- An insulating layer 33 ′ and a lower insulating layer 32 ′ are formed on the top surface and the lower surface of the holding plate 36 in the same manner as the insulating layer 33 and the lower insulating layer 32.
- the heat generating member 41 is fixed on the insulating layer 33 using the bolt 35.
- the first electrode 60A and the second electrode 60B are fixed to the notches 72A and 72B of the side blocks 7OA and 70B by an appropriate means and method, and the nesting body 31 is sandwiched between the side blocks 70A and 70B. State (see (B) of Fig. 1).
- the side blocks 70A and 70B are attached to the first mold part (movable mold part) 13 using bolts (not shown).
- a DC inverter power supply (16 KHz, DC pulse) having a maximum applied current of 6000 amperes and a maximum voltage of 8 volts was used as a power supply device.
- the size of the heat generating member 41 was 80 mm in width, 140 mm in length, and thickness (t) 5.0 mm.
- the direction of energization is generally along the width direction.
- FIG. 14 shows the temperature measurement result of the heat generating member 41 when a thermocouple, which is a temperature measuring means, is attached to the surface of the heat generating member 41 of the nested assembly 20 and a current is passed through the heat generating member 41. Since the mold temperature was set to 50 ° C., the temperature of the heat generating member 41 immediately before the current flow was 50 ° C. When a current of 5 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 1.2 volts was generated at both ends of the heat generating member 41. After 13 seconds from the start of current flow, the temperature of the heating member 41 reached 220 ° C. That is, the average heating rate was 13 ° C./second. On the other hand, the temperature of the heat generating member 41 reached 100 ° C. after 47 seconds had elapsed since the supply of current was stopped. That is, the average cooling rate was 2.6 ° C / sec.
- Comparative Example 1 As Comparative Example 1, an insulating layer was formed! /, Nana //, and a heat generating member was produced. Table 1 shows the material and thickness of the heat generating member. The width and length of the heat generating member in Comparative Example 1 are the same as those of the heat generating member of Example 1. Table 1 shows the temperature measurement results of the heating member when the heating member of Comparative Example 1 was used and a current was passed through the heating member under the same conditions as in Example 1. From Table 1, it can be seen that the heating member of Comparative Example 1 has a very low heating rate compared to the heating member of Example 1. In Comparative Example 1, the temperature of the force-generating member that continued to pass current for 120 seconds finally increased only to 95 ° C. [0088]
- Example 1 Injection molding was performed using the mold assembly of Example 1.
- a polycarbonate resin (HL7001, manufactured by Mitsubishi Engineering Plastics Co., Ltd., glass transition temperature: 143 ° C.) was used as the thermoplastic resin.
- the molding conditions were as shown in Table 2 below. Heating member g
- the heating member set temperature refers to the surface temperature of the heating member when not in contact with the molten thermoplastic resin.
- Heating member set temperature 240 ° C
- the obtained molded product (specifically, the light guide plate) has molding conditions of a low resin temperature and a slow injection speed even though the thickness is very thin at 0.3 mm.
- the cavity 15 could be easily and completely filled with molten thermoplastic resin.
- the transfer rate of the prism shape formed on the surface of the molded product was almost 100%.
- the distortion of the molded product was observed through the polarizing plate, it was found that the whole was black and the distortion was small.
- the cavity 15 could be filled with molten thermoplastic resin somehow.
- the distortion of the molded product was observed through a polarizing plate with a large warp, a rainbow color was observed in the entire molded product, and a very large birefringence was generated. was found to exist.
- the second end 52A of the first conductive means 50A is exposed to the side block 70A side, and the second end 52B of the second conductive means 50B is exposed. Force that is exposed to the side block 70B side Alternatively, the second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B are placed on the side block 70A side. The second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B may be separated to the side block 70B side. It may be exposed in the state. Also, the second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B may be exposed on the bottom surface of the nested body 31! /.
- the second embodiment is a modification of the first embodiment.
- each of the first conductive means 80A and the second conductive means 80B corresponds to the first end portions 81A and 81B.
- the head corresponds to the second end portion 82A, 82B and extends inside the insert 30 (specifically, through the insert 30 in the second embodiment).
- It consists of insulated conductive bolts (specifically made of carbon steel).
- the tip of the bolt is screwed with the heat generating member 41, and the head of the bolt is in contact with an electrode (not shown).
- the second end portion 82A of the first conductive means 80A and the second end portion 82B of the second conductive means 80B are exposed on the bottom surface of the nesting body 31. Except for the above points, the other components of the nesting assembly can be the same as the nesting assembly described in the first embodiment, and a detailed description thereof will be omitted.
- Example 3 also relates to a mold assembly according to the first aspect of the present invention, and more specifically, to a mold assembly having a second configuration.
- Schematic of the nesting assembly in the mold assembly of Example 3 A typical cross-sectional view is shown in FIG. 6 (A), and a schematic perspective view when the insert body is cut is shown in FIG. 6 (B). Further, the pattern of the first conduction region, the conduction region extension portion, and the second conduction region in the mold assembly of Example 3 is schematically shown in FIG.
- the insert 130 is composed of the insert main body 31 similar to that of the first embodiment and the insulating layer 33 similar to that of the first embodiment. Further, the nest 130 includes a first conductive region 139A, a second conductive region 139B, and a conductive region connecting the first conductive region 139A and the second conductive region 139B formed on the insulating layer 33. This point is different from the nesting 30 in the first embodiment.
- the first conduction region 139A, the second conduction region 139B, and the conduction region extension 139C are made of copper (Cu), and are formed on the insulating layer 33 based on an electrical plating method.
- the volume resistivity at 20 ° C. of the first conductive region 139A, the second conductive region 139B, and the conductive region extension 139C is 0 ⁇ 017 I ⁇ ′m.
- the first conductive region 139A, the electrical resistance I straight R in each of 20 ° C of the second conductive region 139B and conductive region extension 139C is, 0. 17 X 10- 5 ⁇ , 0. 18 X 10 - 5 ⁇ , is a 1. 9 X 10- 5 ⁇ .
- the first conductive region 139A, the second conductive region 139B, and the conductive region extending portion 139C are hatched.
- the first conductive region 139A and the second conductive region 139B are represented by regions surrounded by dotted lines.
- the nested assembly 120 in the third embodiment further includes a heat generating member 141 having the same configuration and structure as the heat generating member 41 of the first embodiment, the first conductive means 50A, and the second conductive means. It has 50B.
- the heat generating member 141 is fixed on the insulating layer 33, the first conductive region 139A, the conductive region extending portion 139C, and the second conductive region 139B. Part of the heat transfer of Joule heat generated in the first conductive region 139A, the conductive region extension 139C and the second conductive region 139B, and the heating member 14 1 is heated by the Joule heat generated in itself Is done.
- the first conductive means 5 OA has a first end portion 50A and a second end portion 52A, and is arranged inside the insert 130 (more specifically, inside the insert body 31). .
- the first conduction region 139A and the first end portion 50A are in contact with each other, so that a current can flow through the first conduction region 139A.
- the second conductive means 50B has a first end portion 50B and a second end portion 52B, and is disposed inside the insert 130 (more specifically, inside the insert body 31). .
- the second conduction region 139B and the first end 50B are in contact with each other, and a force S can be applied to cause a current to flow through the second conduction region 139B.
- the first electrode 60A is in contact with the exposed second end 52A of the first conductive means 50A
- the second electrode 60B is in contact with the second conductive It is in contact with the exposed second end 52B of the means 50B.
- the heat generating member 141 is fixed to the insert 30 with an insulating bolt 35 whose tip is screwed into the heat generating member 141 and penetrates the insert 30.
- the nesting assembly 120 is similar to the first embodiment in that two nesting assemblies 120 are attached to the first mold portion (movable mold portion) 13 while facing the side surface of the nesting 130. It has side blocks 70A and 70B. Since the configuration and structure of the side blocks 70A and 70B can be the same as the configuration and structure of the side blocks 70A and 70B described in the first embodiment, detailed description thereof is omitted.
- the configuration and structure of the first electrode 60A and the second electrode 60B are the same as the configuration and structure of the first electrode 60A and the second electrode 60B described in the first embodiment. Therefore, detailed description is omitted, and the assembly of the nested assembly 120 can be the same as the assembly of the nested assembly 20 described in the first embodiment, and thus detailed description thereof is omitted.
- thermocouple which is a temperature measuring means, is attached to the surface of the heat generating member 141 of such a nested assembly 120, and current flows through the first conduction region 139A, the conduction region extension 139C, and the second conduction region 139B.
- the temperature measurement result of the heat generating member 141 when flowing was substantially the same as in Example 1.
- FIGS. 7B and 7C show different patterns of the first conductive region 139A, the conductive region extension 139C, and the second conductive region 139B in the mold assembly of Example 3.
- the force patterns that schematically show examples are these “ladder” (see (A) in FIG. 7), “zigzag” (see (B) in FIG. 7), and “helical” (see FIG. 7). (See (C).) It can be made to be an arbitrary pattern.
- the second end 52A of the first conductive means 50A is exposed to the side block 70A side, and the second end 52B of the second conductive means 50B is exposed.
- the second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B are placed on the side block 70A side.
- the second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B may be separated to the side block 70B side. It may be exposed in the state.
- the second end 52A of the first conductive means 50A and the second end 52B of the second conductive means 50B may be exposed on the bottom surface of the nested body 31! /.
- Example 4 is a modification of Example 3.
- a schematic cross-sectional view of each of the first conductive means 80A and the second conductive means 80B is the same as in the second embodiment. It corresponds to the portions 81A and 81B, the head corresponds to the second end portions 82A and 82B, extends inside the insert 130, and has a conductive bolt force insulated from the insert body 31.
- the tip of the bolt constituting the first conductive means 80A (corresponding to the first end 81A) is in contact with the first conduction region 139A, and the head of this bolt (second The end 82A corresponds to a first electrode (not shown).
- the tip of the bolt constituting the second conductive means 80B (corresponding to the first end 81B) is in contact with the second conduction region 139B, and the head of the bolt (second end) (Corresponding to part 82B) is in contact with the second electrode (not shown).
- the second end portion 82A of the first conductive means 80A and the second end portion 82B of the second conductive means 80B are exposed on the bottom surface of the nesting body 31. Except for the above points, the other components of the nested assembly can be the same as the nested assembly described in the third embodiment, and thus detailed description thereof is omitted.
- Example 5 also relates to the mold assembly according to the first aspect of the present invention, and more specifically, to the mold assembly of the third configuration.
- a schematic cross-sectional view of the insert assembly in the mold assembly of Example 5 is shown in FIG. 9 (A), and a schematic perspective view of the side block is shown in FIG. 9 (B).
- Example 5 The basic configuration and structure of the mold assembly in Example 5 will be described in Example 1.
- the structure and structure of the mold assembly are the same.
- the insert 230 can be composed of the insert main body 31 similar to that of the first embodiment and the insulating layer 33 similar to that of the first embodiment.
- the nested assembly 220 is further provided with a heat generating member 41 similar to that of the first embodiment, which is fixed on the insulating layer 33 and forms part of the cavity 15 and generates Joule heat, as in the first embodiment. I have.
- the insert assembly 220 is provided with a first side block 270A and a second side block 270B.
- the first conductive means 250A is provided on the surface facing the insert 230.
- the first side block 270A is a first mold portion (movable mold). Part) It is attached with bolts not shown in Fig. 13.
- the second conductive means 250B is provided on the surface facing the insert 230.
- the second side block 270B is in a state where the second conductive means 250B is in contact with the heat generating member 41 and faces the second side face 30B facing the first side face 30A of the insert 230. It is attached to a mold part 1 (movable mold part) 13 by a bolt (not shown).
- the first electrode 60A is in contact with the end face 252A of the first conductive means 250A
- the second electrode 60B is in contact with the end face 252B of the second conductive means 250B.
- Each of the first conductive means 250A and the second conductive means 250B is made of a block-shaped metal material (specifically, copper) and has a substantially “L” -shaped cross section. Since the configuration and structure of the first electrode 60A and the second electrode 60B can be the same as the configuration and structure of the first electrode 60A and the second electrode 60B described in the first embodiment, a detailed description is provided. Is omitted.
- portions other than the portion that contacts the heat generating member 41 of the first conductive means 250A and the portion that contacts the first electrode 60A (end surface 252A) are covered with an insulating film (not shown).
- the portion other than the portion in contact with the heat generating member 41 of the second conductive means 250B and the portion in contact with the second electrode 60B (end surface 252B) is covered with an insulating film (not shown). Yes.
- each of the first side block 270A and the second side block 270B has a thermal conductivity of 1 ⁇ 3 (W / m'K) to 6.3 (W / m'K).
- the ceramic material layers 271A and 271B with a thickness of 0.5 mm to 5 mm (specifically 1.5 mm) are cut into the sintered body. It is formed based on machining.
- the constituent material of the ceramic material layers 271A and 271B may be the same as the constituent material of the insulating layer 33 in Example 1, and the constituent material of the side blocks 2 70A and 270B may be the same as that of the side block 70A in Example 1. , 70B.
- the heat generating member 41 includes a first protrusion 274A provided on the top of the first side block 270A and a second protrusion provided on the top of the second side block 270B. 274 Therefore, the nest is fixed to 230 °. Protrusions 274 mm, 274 mm IJ surfaces 275 mm, 275 B face the cavity 15 and constitute a part of the cavity 15. When the first mold part (movable mold part) 13 and the second mold part (fixed mold part) 12 are clamped, the top parts 273A and 273B of the side blocks 270A and 270B are the second molds. Contact part (fixed mold part) 12. The side blocks 270A and 270B are provided with notches 272A and 272B through which the first electrode 60A and the second electrode 60B pass.
- the first conductive means 250A and the second conductive means 250B are inserted into the notches 272A and 272B provided in the side blocks 270A and 270B.
- the heat generating member 41 includes the first protrusion 274A and the second side block provided on the top of the first side block 270A.
- the second protrusion 274B provided on the top of the 270B is fixed to the insert 230.
- the side blocks 270A and 270B are fixed to the first mold part using bolts (not shown). (Moving mold part) Attach to 13.
- the heat generating member 41 is screwed into the heat generating member 41 at the front end and penetrated through the insert 230 in the same manner as shown in FIG. Insulating bolt
- a method of fixing to the nest 230 can be adopted.
- Example 6 also relates to a mold assembly according to the first aspect of the present invention, and more specifically, to a mold assembly having a fourth configuration.
- a schematic cross-sectional view of the insert assembly in the mold assembly of Example 6 is shown in FIG. 11A to 11B show patterns of the first conduction region, the conduction region extension portion, and the second conduction region in the mold assembly of Example 6.
- FIG. 11A to 11B show patterns of the first conduction region, the conduction region extension portion, and the second conduction region in the mold assembly of Example 6.
- the basic configuration and structure of the mold assembly in the sixth embodiment are the same as the configuration and structure of the mold assembly described in the fifth embodiment. Furthermore, in Example 6, the nest 330 is composed of a nest body 31 similar to Example 1, an insulating layer 33 similar to Example 1, a first conductive region 339A similar to Example 3, and a second The conductive region 339B and the conductive region extending portion 339C.
- the insert assembly 320 further includes a heat generating member 141 having the same configuration and structure as the heat generating member 41 of the first embodiment, and the first side block 270A of the fifth embodiment.
- the first side block 370A and the second side block 370B have the same configuration and structure as the second side block 270B.
- the last two digits of the reference numerals of the constituent elements of the first side block 370A and the second side block 370B are the constituent elements of the first side block 270A and the second side block 270B described in the fifth embodiment.
- the same reference number as the last two digits indicates the same component.
- Example 6 the heat generating member 141 is fixed on the insulating layer 33, the first conduction region 339A, the conduction region extension 339C, and the second conduction region 339B.
- the first conductive means 350A is provided on the surface facing the insert 330.
- the first side block 370A is in contact with the first conduction region 339A and faces the first side surface 30A of the insert 330, and the first side block 370A is the first mold. Part (movable mold part) 13 is attached.
- the second side block 370B the second side block 270B in the fifth embodiment and Similarly, the second conductive means 350B is provided on the surface facing the insert 330. Then, the second side block 370 is in a state where the second conductive means 350B is in contact with the second conductive region 339B and faces the second side face 30B facing the first side face 30A of the insert 330. B is attached to a first mold part (movable mold part) 13.
- the configuration, structure, and formation method of the first conductive region 339A, the second conductive region 339B, and the conductive region extension 339C are the same as the first conductive region 139A, the second conductive region 139B, and the third embodiment.
- Conducting region extending portion 1 It can be the same as the structure, structure and forming method of 39C.
- the heat generating member 141 includes the first protrusion 374A provided on the top of the first side block 370A and the second protrusion provided on the top of the second side block 370B. This is fixed to the nest 330 by the projection 374B.
- the first conductive means 350A includes an insulating film (not shown) except for a portion in contact with the first conductive region 339A and a portion in contact with the first electrode 60A (end surface 352A).
- the second conductive means 350B is also made of an insulating film (not shown) except for the portion in contact with the second conductive region 339B and the portion in contact with the second electrode 60B (end surface 352B). It is covered.
- the configuration and structure of the first electrode 60A and the second electrode 60B are the same as the configuration and structure of the first electrode 60A and the second electrode 60B described in Example 1. Therefore, detailed description is omitted, and the assembly of the nested assembly 320 can be the same as the assembly of the nested assembly 220 described in the fifth embodiment, and thus detailed description thereof is omitted.
- thermocouple which is a temperature measuring means, is attached to the surface of the heat generating member 141 of such a nested assembly 320, and a current is supplied to the first conduction region 339A, the conduction region extension 339C, and the second conduction region 339B.
- the temperature measurement result of the heat generating member 141 when flowing was substantially the same as in Example 1.
- Example 7 also relates to a mold assembly according to the first aspect of the present invention, and more specifically, to a mold assembly of the fifth configuration.
- Schematic of the nesting assembly in the mold assembly of Example 7 Typical cross-sectional views are shown in Fig. 12 (A) and (B).
- (A) and (B) in FIG. 12 are schematic cross-sectional views (although the cutting sites are different) that are substantially the same as those taken along arrows A—A in FIG.
- patterns of the first conduction region, the conduction region extension portion, and the second conduction region in the mold assembly of Example 7 are shown in FIGS.
- the insert 430 includes the insert body 31 similar to Example 1, the insulating layer 33 similar to Example 1, the first conductive region 439A similar to Example 3, the second The conductive region 439B and the conductive region extending portion 439C.
- the insert assembly 420 further includes a heat generating member 141 having the same configuration and structure as the heat generating member 41 of the first embodiment, the first side block 470A and the second side block 470A. It has a side block 470B. Note that the last two digits of the reference numbers of the components of the first side block 470A and the second side block 470B are the same as the first side block 270A and the second side block 270B described in the fifth embodiment. The same number as the last two digits of a component reference number indicates the same component.
- the heat generating member 141 is similar to the heat generating member 141 in Example 6, with the insulating layer 33, the first conductive region 439A, the conductive region extending portion 439C, and the second conductive region. 439 B fixed on part of the cavity 15 and forming part of the cavity 15, the heat transfer of Joule heat generated in the first conduction region 439 A, the conduction region extension 439 C and the second conduction region 439 B, and the heating member 141 It is heated by the Joule heat generated in itself.
- the first side block 470A is different from the first side block 270A in the fifth embodiment, and the first conductive means 450A and the second conductive means 450B are provided on the surface facing the insert 430. ing.
- the first conductive means 450A is in contact with the first conductive region 439A
- the second conductive means 450B provided apart from the first conductive means 450A is in contact with the second conductive region 439B
- the first side block 470A is attached to the first mold part (movable mold part) 13 while facing the first side face 30A of the insert 430.
- the second side block 470B is slightly different from the second side block 270B in the fifth embodiment, and the first side block 470B faces the second side surface 30B facing the first side surface 30A of the insert 430. It is attached to a mold part (movable mold part) 13.
- the configuration, structure, and formation method of the first conductive region 439A, the second conductive region 439B, and the conductive region extension 439C are the same as those in the first conductive region 139A, the second conductive region 139B, and The structure, structure, and formation method of the conductive region extension 139C can be the same.
- the heat generating member 141 is provided with the first protrusion 474A provided on the top of the first side block 470A and the second protrusion provided on the top of the second side block 470B. This is fixed to the insert 430 by the projection 474B.
- the first conductive means 450A includes an insulating film (not shown) except for a portion in contact with the first conductive region 439A and a portion in contact with the first electrode 60A (end surface 452A).
- the second conductive means 450B is also made of an insulating film (not shown) except for the portion in contact with the second conductive region 439B and the portion in contact with the second electrode 60B (end surface 452B). It is covered.
- the configuration and structure of the first electrode 60A and the second electrode 60B are the same as the configuration and structure of the first electrode 60A and the second electrode 60B described in Example 1. Therefore, detailed description is omitted, and the assembly of the nested assembly 420 can be the same as the assembly of the nested assembly 220 described in the fifth embodiment, and thus detailed description thereof is omitted.
- thermocouple which is a temperature measuring means, is attached to the surface of the heat generating member 141 of such a nested assembly 420, and current flows through the first conduction region 439A, the conduction region extension 439C, and the second conduction region 439B.
- the temperature measurement result of the heat generating member 141 when flowing was substantially the same as in Example 1.
- Example 8 is a modification of Example 1.
- a flow path 42 for cooling the heat generating member 41 by flowing a cooling medium is provided inside the heat generating member 41.
- the cooling medium is specifically room temperature water.
- FIGS. 15A and 15B are schematic cross-sectional views of the heat generating member 41 that is substantially the same as taken along the arrows A—A in FIG. 1A, and FIG. Schematic section of the heating element 41 similar to that along the direction of the arrow A—A in FIG.
- FIG. 16B is a schematic cross-sectional view of the heat generating member 41 when cut along a virtual plane perpendicular to the thickness direction.
- the heat generating member 41 is formed by performing NC machining or electric discharge machining on each of the plate materials 41A and 41B made of two SUS420J2 stainless steel plates having a thickness of 2.5 mm to form groove portions 42A and 42B (FIG. 15 (A).
- an inlet side manifold 43, an outlet side Mayuno red 45, an inlet side port 44, and an outlet side port 46 are provided (see (A) in FIG. 16), and then two plates 41A and 41B are provided. With the convex part and convex part and the concave part and concave part on the opposite surface of the two, the two plates 41A and 41B are bonded together by silver brazing, and the force S can be obtained (see Fig. 15 (B)) ).
- the inlet side port 44 arranged at the inlet part of the flow path and the outlet side port 46 arranged at the outlet part of the flow path are connected to a pipe (not shown).
- a pipe not shown.
- an air valve is attached to the pipe connected to the inlet side port 44, and the air valve can be blown by opening the air valve so that the inside of the flow path 42 can be purged.
- the pipe connected to the outlet side port 46 is provided with a drain portion so that the cooling medium can be discharged when the passage 42 is purged.
- the projected shape of the flow path 42 is a linear shape, but is not limited to this, the lattice shape, the spiral shape, the spiral shape, and the parts are mutually connected.
- the shape of a concentric circle and a zigzag shape can be illustrated.
- the cross-sectional shape of the flow path is a rounded rectangle, it is not limited to this, and it is possible to list a circle, an ellipse, a trapezoid, and a polygon.
- the inlet side manifold 43 has a cross-sectional area larger than the total cross-sectional area of the flow paths 42, and the flow paths 4 2
- the outlet diameter of the outlet side manifold 45 is reduced and the sectional area of the outlet manifold 45 is reduced.
- the thickness of the heat generating member 41 (t) and the minimum remaining thickness of the heat generating member 41 on the cavity surface side (t) Flow path
- the width (w) of 42 and the shortest distance (w) between adjacent channels were as follows. Heat generation
- the member 41 has a width of 80 mm and a length of 140 mm. W and w are mean straight
- the number of grooves extending in parallel was set to 14.
- an electromagnetic valve (not shown) is arranged in the pipe connected to the flow path 42, and the electromagnetic valve is opened to cool the flow path 42.
- the medium can flow.
- the electromagnetic valve is closed, the air valve is opened, air is blown, the inside of the flow path 42 is purged, and the next molding cycle is started.
- the temperature of the heat generating member 41 immediately before the current flowed was 50 ° C.
- a current of 5 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 1.6 volts was generated at both ends of the heat generating member 41.
- the temperature of the central part of the heat generating member 41 reached 250 ° C. That is, the average temperature increase rate was 20 ° C./second, and the temperature increase rate could be improved as compared with the heat generating member 41 of Example 1 in which the flow path 42 was not provided.
- 23 ° C. water was allowed to flow through channel 42 at a rate of 2 liters / minute. As a result, the average cooling rate was 24 ° C / sec.
- an O-ring seal 47 is provided on the outer edge of the heat generating member 41, and the two plate members 41A and 41B are Fastened with bolts 48.
- the flow path 42 does not communicate with the outside.
- the inside of the outer edge portion of the heat generating member 41 may be joined or may not be joined. When not joined, the electrical resistance value of the part that is not joined is particularly high, so that the temperature raising rate can be further improved.
- the flow path 42 is provided by forming a through hole directly in one plate material.
- the height of the flow path 42 is changed depending on the position where the flow path 42 is provided.
- the flow path 42 functions as a cavity for controlling the flow of current in the heat generating member 41.
- the flow path or cavity described above can be applied to the heat generating members 41 and 141 described in the second to seventh embodiments.
- Example 9 the material constituting the heat generating member was examined. Specifically, the heat generating member was made of SUS420J2 having a thickness of 5. Omm (referred to as Example 9A), as in Example 1, and the thickness of the heat generating member on the surface of SUS420J2 having a thickness of 0. 1 mm copper plating layer (referred to as Example 9B) and 5 mm thick titanium (Ti) force manufactured (referred to as Example 9C). The temperature increase rate and temperature decrease rate in the center were measured. The size of the heat generating member was 150 mm x 100 mm, and a zigzag flow path (height 2. Omm, width 3. Omm), total extension about 1.5 mm) was formed inside. Room temperature water was used as a cooling medium.
- volume resistivity 1 is the value of volume resistivity at 20 ° C (unit: a ⁇ ⁇ ⁇ )
- volume resistivity 2 is the value of volume resistivity at 200 ° C (unit: ⁇ -m).
- the density unit is grams / cm 3 .
- the mold temperature was 50 ° C.
- Example 9A when a current of 5 ⁇ 10 ° ampere was passed through the heat generating member 41, a voltage of 0.945 volts was generated at both ends of the heat generating member 41.
- Example 9B when a current of 5 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 0.538 volts was generated across the heat generating member 41.
- Example 9C When a current of 6 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 0.78 volts was generated at both ends of the heat generating member 41. Temperature increase rate and temperature decrease rate at this time The degrees were as shown in Table 4. Furthermore, similarly, in Example 9C, when a current of 5 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 1.061 volts was generated at both ends of the heat generating member 41. When a current of 6 ⁇ 10 3 amperes was passed through the heat generating member 41, a voltage of 1.302 volts was generated at both ends of the heat generating member 41. Table 4 shows the rate of temperature increase and the rate of temperature decrease.
- the unit of current is ampere
- the rate of temperature rise is the average value obtained by dividing 150 ° C by the time it takes to reach 200 ° C at 50 ° C force, starting to flow current through the heat generating material.
- the temperature drop rate 1 is an average value (unit: ° C / second) obtained by dividing the temperature difference by the time required to drop to 50 ° C after the supply of current to the heat generating member is stopped.
- the temperature drop rate when water is flowing through the road, and the temperature drop rate 2 is the average value obtained by dividing the temperature difference by the time required to drop to 100 ° C after the supply of current to the heating element is stopped. (Unit: ° C / sec), which is the rate of temperature drop when water is not flowing through the channel.
- the heating member with the plating layer tended to have a slightly higher heating rate than the heating member without the plating layer, but this was not a problem.
- the reason why the rate of temperature increase is somewhat slow is that the electrical resistance value of the plating layer is slightly high, so that current flows preferentially to the heat generating member, and the temperature of the heating layer is determined by the heating layer. This is thought to be due to absorption.
- the heat generating member was made of titanium, it was found that both the heating rate and the temperature decreasing rate were superior to the heat generating member made of SUS 420J2.
- Example 10 relates to a mold assembly according to the second aspect of the present invention.
- a schematic perspective view of the insert assembly in the mold assembly of Example 10 is shown in FIG. 17A, and a schematic cross-sectional view along arrow A—A in FIG. (B).
- a schematic perspective view when the nesting body is cut along the arrow A—A in FIG. 17A is shown in FIG. 18A, and the first side block and the second side block are shown.
- a schematic perspective view of the block is shown in FIG. 18B, and a schematic perspective view of the first electrode and the second electrode is shown in FIG. 18C.
- FIG. 19 shows a schematic perspective view of the nesting body before assembly.
- FIG. 17A some components are hatched to clearly indicate the components.
- 20A, FIG. 21, and FIG. 25A, which will be described later are schematic cross-sectional views that are substantially the same as those taken along the arrow AA in FIG.
- a nested assembly 520 having a nested 530 is disposed in the first mold part (movable mold part) 13.
- the mold assembly includes a first electrode 560A and a second electrode 560B.
- the insert 530 is an insulating cell having a thermal conductivity of 1.3 (W / m.K) to 6.3 (W / m.K) and a thickness of 0.5 mm to 5 mm.
- Nested body 531 made of Lamix material [more specifically, Zirconia-ceramics (ZrO YO) with a thickness of 5.0 mm and thermal conductivity of 3 (W / m.K)] , And a heat generating layer 532.
- the heat generation layer 532 made of a nickel-phosphorus alloy [Ni—P system] having a volume resistivity at 20 ° C. of 0.1 to ⁇ ′ m and a thickness of 0.1 mm includes the first electrode 560A and It is electrically connected to the second electrode 560B and is formed on at least the top surface of the nested body 531 facing the cavity 15 to generate Joule heat.
- the heat generation layer 532 extends from the top surface of the nested body 531 facing the cavity 15 to the side surface of the nested body 531 and part of the bottom surface of the nested body 531 and is formed based on the electroless plating method. The portion formed on the top surface of the insert body 531 forms part of the cavity 15 and generates Joule heat.
- the nested thread and solid 520 further includes a nested mounting block 541, a first side block 570A, a second side block 570B, a first conductive means 550A, and a second conductive means 550B.
- Nested mounting block 541 is made from 30 mm thick carbon steel. It is disposed between the bottom surface of the lever main body 531 and the first mold part (movable mold part) 13 and attached to the first mold part (movable mold part) 13.
- a lower insulating layer 542 made of the same material as that of the nested body 531 is formed on the lower surface of the nested mounting block 541 based on a thermal spraying method. Further, the insert mounting block 541 is provided with a gap (see FIG. 19) for mounting the first conductive means 550A and the second conductive means 550B.
- the first side block 570A is attached to the first mold part (movable mold part) 13 so as to face the first side surface 530A of the insert 530, and the second side block 570B
- the insert 530 is attached to the first mold part (movable mold part) 13 so as to face the second side face 530B facing the first side face 530A.
- Side blocks 570A and 570B are made of carbon steel.
- the side blocks 570A and 570B facing the side surfaces 530A and 530B of the insert 530 have a thermal conductivity of 1 ⁇ 3 (W / mK) to 6 ⁇ 3 (W / mK) and a thickness of 0 Ceramic material layers 5571A and 571B having a thickness of 5 mm to 5 mm (specifically, a thickness of 0.6 mm) are formed based on a thermal spraying method.
- the ceramic material layers 571A and 571B are made of the same material as the nested body 531.
- Protrusions 574A and 574B are provided on the tops 573A and 573B of the side blocks 570A and 570B.
- the first conductive means 550A for causing a current to flow through the heat generating layer 532 has a first end 551A and a second end 552A, and is disposed inside the nesting mounting block 541, and the nesting body 531
- the first portion 532A and the first end portion 551A of the heat generating layer 532 formed on the bottom surface of each other are in contact with each other.
- the second conductive means 550B for flowing a current through the heat generating layer 532 has a first end 551B and a second end 552B, and is disposed inside the nesting mounting block 541.
- the second portion 532B of the heat generating layer 532 formed on the bottom surface is in contact with the first end portion 551B.
- Each of the first conductive means 550A and the second conductive means 550B is made of a block-shaped metal material (specifically, copper), and the cross-sectional shape is substantially “L”. It is letter-shaped. Further, the second end portion 552A of the first conductive means 550A and the second end portion 552B of the second conductive means 550B are exposed on the side surface of the nesting mounting block 541.
- the insert 530 includes a first protrusion 574A provided at the top of the first side block 570A, a second protrusion 574B provided at the top of the second side block 570B, and an insert mounting block. 541 is fixed to the first mold part (movable mold part) 13.
- the first electrode 560A made of copper is in contact with the exposed second end 552A of the first conductive means 550A, and the second electrode 560B made of copper is exposed to the second conductive means 550B. In contact with the second end 552B. Portions of the surfaces of the first electrode 560A and the second electrode 560B are covered with insulating films 561A and 561B. Furthermore, the portion of the first electrode 560A that is not in contact with the exposed second end 552A of the first conductive means 550A, and the exposed second end 552B of the second conductive means 550B ! /, NA! /, A portion of the second electrode 560B is covered with an insulating paint (not shown).
- first electrode 560A and the second electrode 560B are provided with threaded attachments 562A and 562B for attaching the Bonoleto 563A and 563B. Using 563B, the first electrode 560A and the second electrode 560B are securely fixed.
- the contact portion between the first electrode and the first conductive means, and the contact portion between the second electrode and the second conductive means may be flat, complementary shapes, or mutual. It may be a shape that engages with, for example, an uneven shape. The same applies to Example 11 to Example 13 described later.
- the first conductive means 550A and the second conductive means 550B are inserted into the gap provided in the nested mounting block 541 from the side surface of the nested mounting block 541. .
- the holding plate 543 is fixed to the side surface of the nested mounting block 541.
- the retaining plate 543 is fixed to the side surface of the insert mounting block 541 through the through hole 544 provided in the control plate 543, and the mounting hole 545 provided on the side surface of the insert mounting block 541 with a screw thread cut. If it is fixed with bolts (not shown), it can be done with any method.
- a lower insulating layer 542 ′ is provided on the lower surface of the holding plate 543, and the lower insulating layer 542 It is formed in the same way.
- the first electrode 560A and the second electrode 560B are fixed to the notches 572A and 572B of the side blocks 570A and 570B by an appropriate means and method, and the insert 530 and the insert mounting block 541 are interposed between the side blocks 570A and 570B. (See Fig. 17 (B)).
- the side blocks 570A and 570B are attached to the first mold part (movable mold part) 13 using bolts (not shown).
- FIG. 24 shows the temperature measurement results of the heat generating layer 532 when a thermocouple as a temperature measuring means is attached to the surface of the heat generating layer 532 of the nested assembly 520 and a current is passed through the heat generating layer 532.
- the direction of energization is generally along the width direction.
- the temperature of the insert 530 immediately before passing the current was 50 ° C.
- the temperature of the heat generation layer 532 reached 250 ° C. 4 seconds after the current started to flow. That is, the average heating rate was 50 ° C / sec. On the other hand, the temperature of the heating layer 532 reached 100 ° C. 30 seconds after the current supply was stopped. That is, the average cooling rate was 5 ° C / sec.
- a nested structure in which the heat generating layer and the nested body were changed was produced.
- Table 5 shows the specifications for nesting.
- the width and length of the nested body in Comparative Examples 2 to 6 are the same as the nested body of Example 10.
- Table 5 shows the temperature measurement results of the heat generating layer when current is passed through the heat generating layer under the same conditions as in Example 10 using the inserts of these comparative examples.
- the thickness of the heat generation layer made of Ni—P is 0.02 mm, which is less than 0.03 mm.
- the thickness of the nesting body is 0.4 mm, which is less than 0.5 mm.
- the thickness of the nesting body is 6 mm, which exceeds 5 mm.
- the thermal conductivity of the nested body is 60 (W / m.K), which exceeds 6.3 (W / m.K).
- a Fe—Cr film having a thickness of 0.003 mm was formed on the surface of the nesting mounting block without using the nesting body.
- Comparative Example 2 As a result of the test, in Comparative Example 2, the Ni-P plating layer, which is the heat generation layer, was melted and current control was not possible in Comparative Example 3, which had a heat insulating layer. Because it is thin, the heating rate is I'm getting late. In Comparative Example 4, the temperature rise characteristic was good, but the temperature of the heat generation layer became 150 ° C. 30 minutes after the current supply was stopped, and the temperature drop characteristic was not desirable. . In Comparative Example 5, the temperature rise characteristic is poor because the nesting body has no heat insulation effect. In Comparative Example 6, the Fe—Cr film serving as the heat generation layer was melted and current control became impossible. Also, from Table 5, it can be seen that Comparative Example 3 and Comparative Example 5 have a very low rate of temperature increase compared to the heat generation layer of Example 10. Table 5
- thermoplastic resin a polycarbonate resin (GS2020MR2, glass transition temperature T: 145 ° C. manufactured by Mitsubishi Engineering Plastics Co., Ltd.) added with 20% by weight of glass fiber was used. Also molded g
- the conditions are shown in Table 6 below. Energization of the heat generation layer 532 (current of 300 amps, generated voltage of 13 volts) was started 5 seconds before the start of injection into the molten thermoplastic resin cavity 15 and into the molten thermoplastic resin cavity 15 Stopped 0.5 seconds after completion of injection.
- the exothermic layer set temperature refers to the surface temperature of the exothermic layer in contact with the molten thermoplastic resin.
- Heating layer set temperature 250 ° C
- the obtained molded product (specifically, a nameplate panel for a television receiver)
- a nameplate panel for a television receiver Despite the fact that 20% by weight of glass fiber is contained in the plastic resin, it is possible to obtain a molded product having an appearance equivalent to that of the thermoplastic resin not containing glass fiber, and the surface roughness R is also 0. It is 5 m and has the same surface roughness as that of the mold cavity.
- Injection molding was performed under the same molding conditions using the nested assembly of Comparative Example 5 described above for comparison. Since the cavity could not be filled with the molten thermoplastic resin under the injection conditions of Example 10, the mold temperature was set to 130 ° C and the resin temperature was set to 350 ° C. could be filled with plastic resin. However, the glass fiber float was observed on the surface of the molded product, and silver was generated by the gas generated by the thermal decomposition of the resin. Furthermore, it was not a level that could be used as a nameplate panel with large warpage of the molded product.
- the second end 552A of the first conductive means 550A is exposed to the first side block 570A side, and the second end of the second conductive means 550B is exposed.
- Force for exposing part 5 52B to the side of second side block 570B Alternatively, the second end 552A of first conductive means 550A and the second end 552B of second conductive means 550B The first side block 570A may be exposed in a separated state, or the first conductive means 55 OA second end 552A and second conductive means 550B second end The part 552B may be exposed to the second side block 570B side in a separated state. Further, the second end 552A of the first conductive means 550A and the second end 552B of the second conductive means 550B may be exposed on the bottom surface of the nesting mounting block 541.
- Example 11 is a mold assembly according to the third aspect of the present invention.
- a schematic cross-sectional view of the insert assembly in the mold assembly of Example 11 is shown in FIG. 20 (A), and a schematic perspective view of the side block is shown in FIG. 20 (B).
- Example 11 The basic configuration and structure of the mold assembly in Example 11 will be described in Example 10.
- the structure and structure of the mold assembly are the same.
- the nesting 630 can be configured by the nesting body 631 similar to the tenth embodiment and the heat generation layer 632 similar to the tenth embodiment.
- the heat generating layer 632 is formed on the top surface and the side surface of the nested body 631, and is not formed on the bottom surface.
- the insert assembly 620 includes a first side block 670A and a second side block 670B. It should be noted that the last two-digit numerical force S of the reference numbers of the components of the first side block 670A and the second side block 670B, the first side block 570A and the second side block 570B described in Example 10 are used. The same reference numerals as the last two digits of a component indicate the same component.
- the first conductive means 650A is provided on the surface facing the insert 630. Then, the first conductive means 650A is in contact with the first portion 632A of the heat generating layer 632 formed on the side surface of the nested body 631, and faces the first side surface 630A of the nested 530.
- the side block 670A of 1 is attached to a first mold part (movable mold part) 13 with bolts (not shown).
- the second conductive means 650B is provided on the surface facing the insert 630.
- the second conductive means 650B is in contact with the second portion 632B of the heat generating layer 632 formed on the side surface of the nested body 631, and the second side surface is opposed to the first side surface 630A of the nested 630.
- the second side block 670B is attached to the first mold part (movable mold part) 13 with a bolt (not shown) while facing the 630B.
- the first electrode 560A is in contact with the end face 652A of the first conductive means 650A
- the second electrode 560B is in contact with the end face 652B of the second conductive means 650B.
- Each of the first conductive means 650A and the second conductive means 650B is made of a block-shaped metal material (specifically, copper) and has a substantially “L” -shaped cross section. Since the configurations and structures of the first electrode 560A and the second electrode 560B can be the same as the configurations and structures of the first electrode 560A and the second electrode 560B described in Example 10, the details are as follows. The explanation is omitted.
- portions other than the portion in contact with the heat generating layer 632 of the first conductive means 650A and the portion in contact with the first electrode 560A (end surface 652A) are covered with an insulating film (not shown).
- the portion other than the portion in contact with the heat generating layer 632 of the second conductive means 650B and the portion in contact with the second electrode 560B (end surface 652B) is covered with an insulating film (not shown).
- each of the first side block 670A and the second side block 670B has a thermal conductivity of 1 ⁇ 3 (W / m'K) to 6.3 (W / m'K).
- the ceramic material layers 671 A and 671B having a thickness of 0.5 mm to 5 mm (specifically 1. Omm) are formed based on the plasma spraying method.
- the constituent material of the ceramic material layers 671A and 671B may be the same as the constituent material of the nested body 531 in Example 10, for example, and the constituent materials of the first side block 670A and the second side block 670B are also implemented.
- the material may be the same as that of the side blocks 570A and 570B in Example 10.
- the nested mounting block 641 has the same configuration and structure as the nested mounting block 541 in Example 10, except that there is no gap for storing the first conductive means and the second conductive means. In some cases, the nested mounting block 641 is not necessary. Protrusions 3 ⁇ 4674A, 674B ⁇ J surface 675A, 675 ⁇ and 15% of cavity, and constitutes part of cavity 15.
- the top 673 ⁇ ⁇ ⁇ and 673 ⁇ of the side blocks 670 ⁇ and 670 ⁇ are the second die Contact part (fixed mold part) 12
- the side blocks 670 and 670 are provided with notches 672 and 672 through which the first electrode 560 and the second electrode 560 pass.
- the first conductive means 650 and second conductive means 650 are inserted into the notches 672 and 672 provided in the side blocks 670 and 670, respectively. Fix the first electrode 5 60mm and the second electrode 560mm by appropriate means and method, and nest between the side blocks 670mm and 670mm.
- the side block 670 ⁇ , 670 ⁇ is attached to the first mold part (movable mold part) 13 by using bolts (not shown).
- 630 is a first mold portion by a first protrusion 674 ⁇ provided on the top of the first side block 670 ⁇ and a second protrusion 674 ⁇ provided on the top of the second side block 670 ⁇ . (Moving mold part) It is fixed to 13.
- thermocouple as a temperature measuring means is attached to the surface of the heat generating layer 632 of such a nested assembly 620, and the temperature measurement result of the heat generating layer 632 when a current is passed through the heat generating layer 632 is shown in the example. It was almost the same as 10.
- the second conductive means 6 comes into contact with the first portion 632A ′ of the heat generating layer 632 formed on the bottom surface of 31.
- Example 12 relates to a mold assembly according to the fourth aspect of the present invention.
- FIGS. 22A and 22B show schematic cross-sectional views of the insert assembly in the mold assembly of Example 12.
- (A) and (B) in FIG. 22 are schematic cross-sectional views (although the cutting sites are different) that are substantially the same as those taken along arrows A—A in FIG. 17 (A).
- FIGS. 23A to 23D the force schematically showing the formation pattern of the heat generation layer and the heat generation layer are hatched.
- the nesting assembly 720 includes a nesting body 731 similar to that in the tenth embodiment, a heat generating layer 732, and a nesting mounting block 741 similar to that in the eleventh embodiment.
- the nested mounting block 741 is not necessary.
- the insert assembly 720 further includes a first side block 77OA and a second side block 770B. It should be noted that the last two digits of the reference number of the constituent elements of the first side block 770A and the second side block 770B are the same as those of the first side block 570A and the second side block 570B described in the tenth embodiment. The same two digits as the component reference number indicate the same component.
- the first side block 770A is slightly different from the first side block 670A in the eleventh embodiment, and the first conductive means 770A and the first conductive block 770A are arranged on the surface facing the insert 730. Two conducting means 770B are provided. Then, the first conductive means 770A is in contact with the first portion 732A of the heat generating layer 732 provided on the side surface of the nested body 731, and the second conductive means 770A is provided apart from the first conductive means 770A.
- Conductive means 770B is the bottom of the nested body 731
- the first side block 770A is in contact with the second portion 732B of the heat generating layer 732 provided on the surface and faces the first side surface 730A of the insert 730. It is attached to the mold part.
- the second side block 770B is slightly different from the second side block 670B in the embodiment 11, and the second side block 770B faces the second side surface 730B facing the first side surface 730A of the insert 730. It is attached to 1 mold part (movable mold part) 13.
- the basic configuration, structure, and formation method of the heat generation layer 732 can be the same as those of the heat generation layer 532 in Example 10.
- the insert 730 includes a first protrusion 774A provided on the top of the first side block 770A and a second protrusion provided on the top of the second side block 770B. Fixed to the first mold part (movable mold part) 130 by the part 774B and the insert mounting block 741
- the pattern of the heat generating layer 732 on the top surface of the nested 730 is shown by hatching in FIG. 23A, and the pattern of the heat generating layer 732 on the bottom surface of the nested 730 is hatched in FIG.
- the pattern of the heat generating layer 732 on the first side 730A of the nesting 730 is indicated by hatching in FIG. 23C, and the pattern of the heat generating layer 732 on the second side 730B of the nesting 730 is shown.
- the pattern is shown by hatching in (D) of FIG.
- the first conductive means 750A includes an insulating film in a portion other than the portion in contact with the first portion 732A of the heat generating layer 732 and the portion in contact with the first electrode 560A (end surface 752A). (Not shown). Further, the second conductive means 750B also has an insulating film (not shown) other than the portion of the heat generating layer 732 in contact with the second portion 732B and the portion in contact with the second electrode 560B (end surface 752B). )).
- the configuration and structure of the first electrode 560A and the second electrode 560B can be the same as the configuration and structure of the first electrode 560A and the second electrode 560B described in Example 10. Therefore, the detailed description is omitted, and the assembly of the nested assembly 720 can be the same as the assembly of the nested assembly 620 described in the eleventh embodiment, and the detailed description is omitted.
- thermocouple as a temperature measuring means is attached to the surface of the heat generating layer 732 of such a nested assembly 720, and the temperature measurement result of the heat generating layer 732 when current is passed through the heat generating layer 732 It was almost the same as 10.
- Example 13 is a modification of Example 10.
- a flow path 546 for cooling the nesting attachment block 541 by flowing a cooling medium is provided inside the nesting attachment block 541.
- the cooling medium is room temperature water.
- Fig. 25 (A) shows a schematic cross-sectional view of the nesting 530, which is substantially the same as that along the arrow A-A in Fig. 17 (A), and Fig. 25 (B) and (C) show nesting attachment.
- a schematic cross-sectional view of block 541 is shown, and in FIG. 26 (A), a schematic cross-sectional view of nested mounting block 541 similar to that along the direction perpendicular to arrow A—A in FIG. 17 (A) is shown.
- FIG. 26 (A) shows a schematic cross-sectional view of nested mounting block 541 similar to that along the direction perpendicular to arrow A—A in FIG. 17 (A) is shown.
- FIG. 26 (A) a schematic cross-sectional view of nested
- FIG. 26B shows a schematic cross-sectional view of the nesting mounting block 541 when cut along a virtual plane perpendicular to the thickness direction.
- the first insert mounting block 541 is formed with a gap for inserting the first conductive means 550A and the second conductive means 550B. The illustration of the gap is omitted.
- Nested mounting block 541 is made by applying NC machining or electrical discharge machining to each of the two SUS420J 2 stainless steel plate forces 541A and 541B with a thickness of 2.5 mm and a thickness of 32.5 mm.
- Grooves 546A and 546B are formed (see (B) in FIG. 25), and an inlet manifold 547A, an outlet manifold 547B, an inlet port 548A, and an outlet port 548B are provided (see ( A)), and then bonding the two plates 541A, 541B together by silver brazing with the projections and projections on the opposing surfaces of the two plates 541A and 541B and the recesses and recesses combined. (See (C) of FIG. 25).
- the inlet-side port 548A disposed at the inlet of the flow path and the outlet-side port 548B disposed at the outlet of the flow path are connected to a pipe (not shown). Note that an air valve is attached to the pipe connected to the inlet side port 548A, and the air blow is performed by opening the air valve so that the inside of the flow path 546 can be purged.
- the pipe connected to the outlet side port 548B is provided with a drain portion so that the cooling medium can be discharged when the flow path 546 is purged.
- the projected shape of 6 is a straight line shape, but examples thereof include a lattice shape, a spiral shape, a spiral shape, a concentric circle shape partially connected to each other, and a zigzag shape.
- the cross-sectional shape of the flow path is a rounded rectangle, the shape is not limited to this, and examples include a circle, an ellipse, a trapezoid, and a polygon.
- the inlet side manifold 547A has a cross-sectional area larger than the total cross-sectional area of the flow paths 546. The pipe diameter of the discharge part is reduced, and the cross-sectional area of the outlet manifold 547B is reduced.
- the minimum remaining wall thickness (t), the width (w) of the flow path 546, and the shortest distance (w) between the adjacent flow paths are as follows.
- the size of the nesting mounting block 541 is 50 mm wide and 100 mm long. W and w are average values.
- the number of grooves extending in parallel was set to 10.
- an electromagnetic valve (not shown) is disposed in the pipe connected to the flow path 546, and the electromagnetic valve is opened, so that the flow path 546 can be opened.
- the flow of cooling medium is possible.
- close the solenoid valve open the air valve, perform air blow, purge the inside of the flow path 546, and move to the next molding cycle! /.
- the temperature of the heat generating layer 532 immediately before the current flowed was 50 ° C.
- a current of 800 amperes was passed through the heat generating layer 532, a voltage of 3.3 volts was generated at both ends of the heat generating layer 532.
- the temperature at the center of the heat generating layer 532 reached 250 ° C. That is, the average heating rate was 50 ° C / sec.
- 23 ° C. water was allowed to flow through channel 546 at a rate of 2 liters / minute. As a result, the average cooling rate was 10 ° C / sec.
- Example 13 injection molding was performed under the same molding conditions as Example 10. As a result, the same result as in Example 10 was obtained.
- an O-ring seal 549A is provided on the inner edge of the nested mounting block 541, and two plates 5 41A, 541B is fastened with bolts 549B.
- the flow path 546 does not communicate with the outside.
- the inner side of the outer edge of the nesting attachment block 541 may be joined or may not be joined.
- a flow path 546 is provided by directly forming a through hole in one plate material. Further, in the modified example of the nested mounting block 541 shown in FIG. 27C, the height of the flow path 546 is changed depending on the position where the flow path 546 is provided! / .
- the present invention has been described based on the preferred embodiments, the present invention is not limited to these embodiments.
- the structure of the mold assembly, the structure of the insert assembly, the structure, the structure of the insert, the structure, the thermoplastic resin used, the injection molding conditions, etc. in the examples are examples and can be changed as appropriate.
- Example 1 to Example 4 force S shown in the example in which the ceramic material layer is formed on the side of the side block facing the side surface of the insert, alternatively, Example 5 to Example As shown in Example 7, a structure in which a ceramic material layer is formed inside the side block can be used. Further, in Examples 5 to 7, the force shown in the example in which the ceramic material layer is formed inside the side block. Alternatively, in the same manner as shown in Example 1 to Example 4, A ceramic material layer may be formed on the side block surface facing the side surface.
- Example 10 the example in which the ceramic material layer is formed on the side block surface facing the side surface of the insert is shown, but alternatively, the same as shown in Example 11 to Example 12
- a ceramic material layer may be formed inside the side block.
- Example 11 to Example 12 the force shown in the example in which the ceramic material layer is formed inside the side block.
- the heat generating member is indirectly connected to the heat generating layer and the first electrode using the first conductive means, and the heat generating member is connected to the second electrode and the second electrode.
- the conductive means is used for indirect connection.
- the first conductive means and the first electrode are manufactured as an integral member, and the second conductive means and the second electrode are connected to each other. It is also possible to make the structure as an integral member.
- the heat generating member and the first electrode are directly connected using an insulating bolt or a conductive bolt, and the heat generating member and the second electrode are connected with an insulating bolt or a conductive bolt.
- the first electrode and the second electrode can be connected directly to the nested mounting block using an insulating bolt or a conductive bolt, and the first electrode and the second electrode can be connected. Can be directly connected to the heat generating layer.
- the heat generating member 41 and the first electrode 60A are directly connected by the insulating bolt 35A.
- 41 and the second electrode 60B are directly connected by an insulating bolt 35A.
- the heat generating member 41 and the first electrode 60A are directly connected by an insulating bolt 35A, and the heat generating member 41 and the second electrode 60A are connected.
- the electrode 60B is directly connected by an insulating or conductive boron 35B.
- the heat generating member 41 and the first electrode 60A are directly connected by an insulating conductive bolt 35A.
- the second electrode 60B is directly connected to the second electrode 60B by an insulating or conductive bolt 35B, but a side block 70A is provided for fixing the heat generating member 41.
- the heat generating member 41 and the first electrode 60A are directly connected by the insulating bolt 35A, and the heat generating member 41 and the second electrode 60A are connected.
- 60B is indirectly connected by a conductive bolt 35C, and side blocks 70A and 70B are arranged for fixing the heat generating member 41.
- a flow path or a cavity may be provided for the heat generating member of these modified examples.
- the modification examples of the heat generating member described above are merely examples, and it goes without saying that various changes and modifications are possible.
- the heat generating layer 532 and the first electrode 560A are directly connected by an insulating bolt 580A.
- 532 and second electrode 56 The OB is directly connected with an insulating bolt 580A.
- the heat generating layer 532 and the first electrode 560A are directly connected by an insulating bolt 580A, and the heat generating layer 532 and the second electrode 560A are connected to each other.
- the electrode 560B is directly connected by an insulating or conductive bolt 580B.
- the heat generating layer 532 and the first electrode 560A are directly connected by an insulating conductive bolt 580A.
- the second electrode 560B is directly connected by an insulating bolt 58OA, but side blocks 57OA and 570B are arranged for fixing the insert 31. Needless to say, a flow path may be provided for the nested mounting blocks of these modified examples. Further, the above-described modification examples of the nesting attachment block are only examples, and it goes without saying that various changes and modifications are possible.
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Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/308,984 US20090291161A1 (en) | 2006-08-01 | 2007-07-26 | Mold Assembly |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006-209470 | 2006-08-01 | ||
| JP2006209470 | 2006-08-01 | ||
| JP2006209469 | 2006-08-01 | ||
| JP2006-209469 | 2006-08-01 |
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| WO2008015961A1 true WO2008015961A1 (en) | 2008-02-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/064697 Ceased WO2008015961A1 (en) | 2006-08-01 | 2007-07-26 | Die assembly |
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| Country | Link |
|---|---|
| US (1) | US20090291161A1 (ja) |
| KR (1) | KR20090064362A (ja) |
| WO (1) | WO2008015961A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115617095A (zh) * | 2022-12-19 | 2023-01-17 | 长沙观谱红外科技有限公司 | 一种温度控制方法 |
| CN119436813A (zh) * | 2024-10-21 | 2025-02-14 | 江苏艾瑞尔精密铝业有限公司 | 一种用于铝饰条成型模具的加热装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2948288B1 (en) * | 2013-01-24 | 2018-09-19 | Toyota Motor Europe | Method for moulding an object using a mould with increased thickness and heat conductive material |
| DE112016000080B4 (de) * | 2015-01-09 | 2019-05-29 | Mazda Motor Corporation | Spritzgussvorrichtung |
| JP6056879B2 (ja) * | 2015-01-09 | 2017-01-11 | マツダ株式会社 | 射出成形装置及び射出成形方法 |
| JP6056887B2 (ja) * | 2015-02-06 | 2017-01-11 | マツダ株式会社 | 射出成形装置及び射出成形方法 |
| JP6056886B2 (ja) * | 2015-02-06 | 2017-01-11 | マツダ株式会社 | 射出成形装置及び射出成形方法 |
| JP6645841B2 (ja) | 2016-01-20 | 2020-02-14 | 株式会社Ihi | 繊維強化複合部材の成形装置 |
| JP6838865B2 (ja) * | 2016-03-31 | 2021-03-03 | 宇部興産機械株式会社 | 射出成形装置および射出成形方法 |
| JP6943743B2 (ja) * | 2017-12-05 | 2021-10-06 | トヨタ自動車株式会社 | 電動機用ステータの製造方法 |
| US10987831B2 (en) * | 2019-05-24 | 2021-04-27 | The Boeing Company | Dies for forming a part and associated systems and methods |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03219936A (ja) * | 1990-01-26 | 1991-09-27 | Nissei Plastics Ind Co | プラスチックレンズの射出成形方法及び成形金型 |
| JPH0825426A (ja) * | 1994-07-14 | 1996-01-30 | Nissei Plastics Ind Co | 入子型金型装置 |
| JP2001353761A (ja) * | 2000-06-13 | 2001-12-25 | Canon Inc | 射出成形方法およびこれに用いる金型 |
| JP2003080574A (ja) * | 2001-09-12 | 2003-03-19 | Ishii Kikai Seisakusho:Kk | 射出成形用金型におけるウェルドラインの発生防止装置 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3444275A (en) * | 1966-08-19 | 1969-05-13 | Grace W R & Co | Method of molding utilizing dielectric heating |
| JPS61151289U (ja) * | 1985-03-12 | 1986-09-18 | ||
| JPH078505B2 (ja) * | 1986-07-30 | 1995-02-01 | 株式会社イノアックコ−ポレ−ション | プラスチツク発泡体の製造方法 |
| US5261806A (en) * | 1992-02-26 | 1993-11-16 | Pleasant Ronald E | Electrically heated mold insert |
| JP3982888B2 (ja) * | 1996-12-16 | 2007-09-26 | 日世株式会社 | 生分解性成形物の製造方法および製造装置 |
-
2007
- 2007-07-26 KR KR1020097001971A patent/KR20090064362A/ko not_active Withdrawn
- 2007-07-26 WO PCT/JP2007/064697 patent/WO2008015961A1/ja not_active Ceased
- 2007-07-26 US US12/308,984 patent/US20090291161A1/en not_active Abandoned
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03219936A (ja) * | 1990-01-26 | 1991-09-27 | Nissei Plastics Ind Co | プラスチックレンズの射出成形方法及び成形金型 |
| JPH0825426A (ja) * | 1994-07-14 | 1996-01-30 | Nissei Plastics Ind Co | 入子型金型装置 |
| JP2001353761A (ja) * | 2000-06-13 | 2001-12-25 | Canon Inc | 射出成形方法およびこれに用いる金型 |
| JP2003080574A (ja) * | 2001-09-12 | 2003-03-19 | Ishii Kikai Seisakusho:Kk | 射出成形用金型におけるウェルドラインの発生防止装置 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115617095A (zh) * | 2022-12-19 | 2023-01-17 | 长沙观谱红外科技有限公司 | 一种温度控制方法 |
| CN119436813A (zh) * | 2024-10-21 | 2025-02-14 | 江苏艾瑞尔精密铝业有限公司 | 一种用于铝饰条成型模具的加热装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090291161A1 (en) | 2009-11-26 |
| KR20090064362A (ko) | 2009-06-18 |
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