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WO2008009922A2 - Compositions de fluide caloporteur - Google Patents

Compositions de fluide caloporteur Download PDF

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Publication number
WO2008009922A2
WO2008009922A2 PCT/GB2007/002699 GB2007002699W WO2008009922A2 WO 2008009922 A2 WO2008009922 A2 WO 2008009922A2 GB 2007002699 W GB2007002699 W GB 2007002699W WO 2008009922 A2 WO2008009922 A2 WO 2008009922A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
composition according
heat transfer
gwp
systems
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2007/002699
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English (en)
Other versions
WO2008009922A3 (fr
Inventor
Robert Elliott Low
Stuart Corr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Fluor Holdings Ltd
Original Assignee
Ineos Fluor Holdings Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Fluor Holdings Ltd filed Critical Ineos Fluor Holdings Ltd
Publication of WO2008009922A2 publication Critical patent/WO2008009922A2/fr
Publication of WO2008009922A3 publication Critical patent/WO2008009922A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/127—Mixtures of organic and inorganic blowing agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/06—CO2, N2 or noble gases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/126—Unsaturated fluorinated hydrocarbons

Definitions

  • R- 134a 1,1,1,2-tetrafluoroethane
  • R- 134a has a global warming potential (GWP) of 1300.
  • R-1225ye is a non-flammable refrigerant, and has a relatively low Greenhouse Warming Potential. Its boiling point, critical temperature, and other properties make it a potential alternative to higher GWP refrigerants such as R- 134a.
  • a principal object of the present invention is therefore to provide a heat transfer composition which is usable in its own right or suitable as a replacement for existing refrigeration usages which should have a reduced Greenhouse Warming Potential, yet have a capacity and energy efficiency (which may be conveniently expressed as the "Coefficient of Performance") ideally within 20% of the values, for example R- 134a, and preferably with 10% of these values. It is known in the art that differences of this order between fluids are usually resolvable by redesign of equipment and system operational features without entailing significant cost differences.
  • the composition should also ideally have reduced toxicity and flammability.
  • R-134a 1,1,2,2-tetrafluoroethane (R-134); dimethyl ether; heptafluoropropane (R-227ea); propane (R-290); propene (R-1270); isobutane (R-600a); n-butane (R-600); 3,3,3-trifluoropropene (R-1243zf); 1,3,3,3- tetrafluoropropene (R-1234ze, cis- or trans-isomers), 1,1- difluorocyclopr ⁇ pane; 1,1,2-trifluorocyclopropane; 1,1,2,2- tetrafluorocyclopropane; pentafluorocyclopropane, or ammonia, or mixtures thereof.
  • the R-1225ye component comprises at least 50% Z isomer, preferably at least 80% Z isomer, preferably at least 90%, 95% or 98% Z isomer.
  • compositions according to the invention typically have improved capacity compared to either R-1225ye or R-1234yf alone.
  • incorporation of a relatively small proportion of further refrigerant(s) in one facet, the incorporation of a relatively small proportion of further refrigerant(s)
  • the composition comprises the at least one further refrigerant in an amount of from about 1 to about 10% by weight of the composition.
  • the composition further comprises a lubricant.
  • the heat transfer device is selected from group consisting of automotive air conditioning systems, residential air conditioning systems, commercial air conditioning systems, residential refrigerator systems, residential freezer systems, commercial refrigerator systems, commercial freezer systems, chiller air conditioning systems, chiller refrigeration systems, heat pump systems.
  • the heat transfer device contains a centrifugal-type compressor.
  • the mechanical power generation device is adapted to use a Rankine Cycle or modification thereof to generate work from heat.
  • the GWP value may also be used to set a preferred composition range.
  • the Peng Robinson equation uses a binary interaction constant to describe the vapour liquid equilibrium of binary pairs. This constant was set to zero where no data were available for mixture pairs; otherwise its value was chosen to give a good representation of the known equilibrium data at temperatures close to O 0 C.
  • Binary data for pairs among the fluids R-32/R-125/R-134a were obtained from measurements published in M. Nagel, K. Bier, Int. J. Refrig. 18 (1995) 534-543.
  • Binary data for R-1225ye with R-1234yf were taken from US Patent Application US2005/0233932A1.
  • Binary data for R-32 with CO 2 were taken from Rivollet et al. Fluid Phase Equilib 218 (2004), pp. 95- 101.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Composition de fluide caloporteur comprenant : (i) du R-1225 ; (ii) du R-1234 ; et (iii) au moins un fluide frigorigène supplémentaire sélectionné parmi le dioxyde de carbone (R-744) ; le fluorométhane (R-41) ; le difluorométhane (R-32) ; le fluoroéthane (R-161) ; le 1,1-difluoroéthane (R-152a) ; le 1,1,1-trifluoroéthane (R-143a) ; le 1,1,1,2-tétrafluoroéthane (R-134a) ; le 1,1,2,2-tétrafluoroéthane (R-134) ; le diméthyléther ; l'heptafluoropropane (R-227ea) ; le propane (R-290) ; le propène (R-1270) ; l'isobutane (R-600a) ; le n-butane (R-600) ; le 3,3,3-trifluoropropène (R-1243zf) ; le 1,3,3,3-tétrafluoropropène (R-1234ze, isomères cis ou trans) ; le 1,1-difluorocyclopropane ; le 1,1,2-trifluorocyclopropane ; le 1,1,2,2-tétrafluorocyclopropane ; le pentafluorocyclopropane ou l'ammoniac ou des mélanges de ceux-ci.
PCT/GB2007/002699 2006-07-17 2007-07-17 Compositions de fluide caloporteur Ceased WO2008009922A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0614080.0 2006-07-17
GBGB0614080.0A GB0614080D0 (en) 2006-07-17 2006-07-17 Heat transfer compositions

Publications (2)

Publication Number Publication Date
WO2008009922A2 true WO2008009922A2 (fr) 2008-01-24
WO2008009922A3 WO2008009922A3 (fr) 2008-06-05

Family

ID=36955712

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2007/002699 Ceased WO2008009922A2 (fr) 2006-07-17 2007-07-17 Compositions de fluide caloporteur

Country Status (2)

Country Link
GB (2) GB0614080D0 (fr)
WO (1) WO2008009922A2 (fr)

Cited By (31)

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FR2932492A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
FR2932493A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
FR2932494A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
WO2010059685A1 (fr) 2008-11-19 2010-05-27 E. I. Du Pont De Nemours And Company Compositions comprenant du 2,3,3,3-tétrafluoropropène et des hydrocarbures, et leurs utilisations
WO2011007966A3 (fr) * 2009-07-13 2011-04-21 주식회사 와이엠환경연구소 Composition réfrigérante
WO2011037314A3 (fr) * 2009-09-25 2011-05-19 주식회사 와이엠환경연구소 Composition frigorigène
EP2487216A1 (fr) 2011-02-10 2012-08-15 Arkema France Compositions binaires de 2,3,3,3-tétrafluoropropène et d'ammoniac
WO2012168607A1 (fr) 2011-06-07 2012-12-13 Arkema France Compositions binaires de 1,3,3,3-tetrafluoropropene et d'ammoniac
WO2013110868A1 (fr) 2012-01-25 2013-08-01 Arkema France Compositions de transfert de chaleur presentant une miscibilite amelioree avec l'huile de lubrification
US8808569B2 (en) 2009-09-11 2014-08-19 Arkema France Use of ternary compositions
US8940180B2 (en) 2012-11-21 2015-01-27 Honeywell International Inc. Low GWP heat transfer compositions
US9011711B2 (en) 2009-09-11 2015-04-21 Arkema France Heat transfer fluid replacing R-410A
US9175203B2 (en) 2009-09-11 2015-11-03 Arkema France Ternary compositions for low-capacity refrigeration
US9267064B2 (en) 2009-09-11 2016-02-23 Arkema France Ternary compositions for high-capacity refrigeration
US9353302B2 (en) 2010-08-13 2016-05-31 Carrier Corporation Fluorinated hydrocarbon composition
EP2652065B1 (fr) 2010-12-14 2016-07-27 The Chemours Company FC, LLC Utilisation de réfrigérants comprenant e-1,3,3,3-tétrafluoropropène et au moins un tétrafluoroéthane pour le refroidissement
US9599381B2 (en) 2008-10-08 2017-03-21 Arkema France Heat transfer fluid
US9683157B2 (en) 2009-09-11 2017-06-20 Arkema France Heat transfer method
EP2246649B1 (fr) 2008-02-29 2017-07-19 Daikin Industries, Ltd. Appareil de réfrigération
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US10035938B2 (en) 2009-09-11 2018-07-31 Arkema France Heat transfer fluid replacing R-134a
EP2888333B1 (fr) 2012-08-23 2018-10-03 The Chemours Company FC, LLC Mélanges réfrigérants comprenant des tétrafluoropropènes et du difluorométhane, et utilisation de ces derniers
EP2888334B1 (fr) 2012-08-23 2018-10-10 The Chemours Company FC, LLC Mélanges de réfrigérants comprenant des tétrafluoropropènes et du difluorométhane et leurs utilisations
CN110746936A (zh) * 2019-10-11 2020-02-04 金华永和氟化工有限公司 一种环保混合制冷剂
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US11186424B2 (en) 2013-07-16 2021-11-30 The Procter & Gamble Company Antiperspirant spray devices and compositions
KR20210151992A (ko) * 2008-05-07 2021-12-14 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물
CN113845882A (zh) * 2021-10-21 2021-12-28 珠海格力电器股份有限公司 三元环保混合制冷剂、其制备方法及制冷系统
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US9579265B2 (en) 2014-03-13 2017-02-28 The Procter & Gamble Company Aerosol antiperspirant compositions, products and methods
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EP2246649B1 (fr) 2008-02-29 2017-07-19 Daikin Industries, Ltd. Appareil de réfrigération
EP2246649B2 (fr) † 2008-02-29 2023-10-25 Daikin Industries, Ltd. Appareil de réfrigération
KR102884920B1 (ko) 2008-05-07 2025-11-12 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물
KR20210151992A (ko) * 2008-05-07 2021-12-14 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물
KR102479255B1 (ko) 2008-05-07 2022-12-20 더 케무어스 컴퍼니 에프씨, 엘엘씨 1,1,1,2,3-펜타플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물
WO2010000994A3 (fr) * 2008-06-11 2010-03-04 Arkema France Compositions a base d'hydrofluoroolefines
US8252198B2 (en) 2008-06-11 2012-08-28 Arkema France Hydrofluoroolefin compositions
FR2932492A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
WO2010000995A3 (fr) * 2008-06-11 2010-03-04 Arkema France Compositions a base d'hydrofluoroolefines
EP2615150A3 (fr) * 2008-06-11 2017-03-08 Arkema France Compositions à base d'hydrofluorooléfines
FR2932493A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
WO2010000994A2 (fr) 2008-06-11 2010-01-07 Arkema France Compositions a base d'hydrofluoroolefines
US8070977B2 (en) 2008-06-11 2011-12-06 Arkema France Hydrofluoroolefin compositions
US8075798B2 (en) 2008-06-11 2011-12-13 Arkema France Hydrofluoroolefin compositions
WO2010000993A2 (fr) 2008-06-11 2010-01-07 Arkema France Compositions a base d'hydrofluoroolefines
US8246850B2 (en) 2008-06-11 2012-08-21 Arkema France Hydrofluoroolefin compositions
WO2010000993A3 (fr) * 2008-06-11 2010-03-04 Arkema France Compositions a base d'hydrofluoroolefines
WO2010000995A2 (fr) 2008-06-11 2010-01-07 Arkema France Compositions a base d'hydrofluoroolefines
FR2932494A1 (fr) * 2008-06-11 2009-12-18 Arkema France Compositions a base d'hydrofluoroolefines
TWI649413B (zh) * 2008-06-11 2019-02-01 艾克瑪公司 建基於氫氟烯烴類之組成物
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