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WO2008007002A3 - Catalyseur membranaire pour la synthèse d'acide acrylique à partir de glycérol - Google Patents

Catalyseur membranaire pour la synthèse d'acide acrylique à partir de glycérol Download PDF

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Publication number
WO2008007002A3
WO2008007002A3 PCT/FR2007/051596 FR2007051596W WO2008007002A3 WO 2008007002 A3 WO2008007002 A3 WO 2008007002A3 FR 2007051596 W FR2007051596 W FR 2007051596W WO 2008007002 A3 WO2008007002 A3 WO 2008007002A3
Authority
WO
WIPO (PCT)
Prior art keywords
glycerol
acrylic acid
membrane
membrane catalyst
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2007/051596
Other languages
English (en)
Other versions
WO2008007002A2 (fr
Inventor
Jean-Luc Dubois
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Publication of WO2008007002A2 publication Critical patent/WO2008007002A2/fr
Publication of WO2008007002A3 publication Critical patent/WO2008007002A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B01J37/0223—Coating of particles by rotation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La présente invention a pour objet un catalyseur membranaire pour la synthèse d'acide acrylique à partir de glycérol, la préparation du catalyseur membranaire et son utilisation pour la préparation d'acide acrylique à partir de glycérol. Ledit catalyseur membranaire comprend une première couche A 10 constituée d'une phase capable de convertir sélectivement l'acroléine en acide acrylique, et une seconde couche B formée sur ladite première couche A, constituée d'une phase acide ayant une acidité de Hammett H0 inférieure à +2, capable d'effectuer sélectivement la réaction de déshydratation du glycérol en acroléine.
PCT/FR2007/051596 2006-07-13 2007-07-05 Catalyseur membranaire pour la synthèse d'acide acrylique à partir de glycérol Ceased WO2008007002A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0652960A FR2903620B1 (fr) 2006-07-13 2006-07-13 Catalyseur membranaire pour la synthese d'acide acrylique a partir de glycerol
FR0652960 2006-07-13

Publications (2)

Publication Number Publication Date
WO2008007002A2 WO2008007002A2 (fr) 2008-01-17
WO2008007002A3 true WO2008007002A3 (fr) 2008-02-28

Family

ID=37836684

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/051596 Ceased WO2008007002A2 (fr) 2006-07-13 2007-07-05 Catalyseur membranaire pour la synthèse d'acide acrylique à partir de glycérol

Country Status (2)

Country Link
FR (1) FR2903620B1 (fr)
WO (1) WO2008007002A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109304164B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸催化剂

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2008066079A1 (ja) * 2006-12-01 2010-03-04 株式会社日本触媒 アクリル酸の製造方法
FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
AU2014221198B2 (en) 2013-09-16 2015-05-07 Armstrong World Industries, Inc. Methods for preparing methacrylic acid from biobased starting materials
CN105195166A (zh) * 2015-10-23 2015-12-30 中国海洋石油总公司 一种丙烯氧化制丙烯醛催化剂的制备方法
CN105195167A (zh) * 2015-10-23 2015-12-30 中国海洋石油总公司 一种丙烯醛氧化制丙烯酸催化剂的制备方法
CN109305909B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸的方法
CN109304163B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油生产丙烯酸的催化剂

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6410800B1 (en) * 1999-09-30 2002-06-25 Korea Research Institute Of Chemical Technology Process for preparing acrolein
DE10360058A1 (de) * 2003-12-19 2004-07-08 Basf Ag Verfahren zur Herstellung von katalytisch aktiven Multielementoxidmassen, die wenigstens eines der Elemente Nb und W sowie die Elemente Mo, V und Cu enthalten
EP1468721A1 (fr) * 2003-04-17 2004-10-20 ICT Co., Ltd. Catalyseur pour la purification de gaz d'échappements et procédé associé
WO2005073160A1 (fr) * 2004-01-30 2005-08-11 Nippon Shokubai Co., Ltd. Methode de production d’acide acrylique
WO2006092272A2 (fr) * 2005-02-28 2006-09-08 Stockhausen Gmbh Acide acrylique et structures polymeres absorbant l'eau a base de matieres premieres renouvelables et procede de fabrication
WO2006114506A1 (fr) * 2005-04-25 2006-11-02 Arkema France Procede de preparation d’acide acrylique a partir de glycerol

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6410800B1 (en) * 1999-09-30 2002-06-25 Korea Research Institute Of Chemical Technology Process for preparing acrolein
EP1468721A1 (fr) * 2003-04-17 2004-10-20 ICT Co., Ltd. Catalyseur pour la purification de gaz d'échappements et procédé associé
DE10360058A1 (de) * 2003-12-19 2004-07-08 Basf Ag Verfahren zur Herstellung von katalytisch aktiven Multielementoxidmassen, die wenigstens eines der Elemente Nb und W sowie die Elemente Mo, V und Cu enthalten
WO2005073160A1 (fr) * 2004-01-30 2005-08-11 Nippon Shokubai Co., Ltd. Methode de production d’acide acrylique
EP1710227A1 (fr) * 2004-01-30 2006-10-11 Nippon Shokubai Co.,Ltd. Methode de production d'acide acrylique
WO2006092272A2 (fr) * 2005-02-28 2006-09-08 Stockhausen Gmbh Acide acrylique et structures polymeres absorbant l'eau a base de matieres premieres renouvelables et procede de fabrication
WO2006114506A1 (fr) * 2005-04-25 2006-11-02 Arkema France Procede de preparation d’acide acrylique a partir de glycerol

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109304164B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸催化剂

Also Published As

Publication number Publication date
FR2903620B1 (fr) 2009-02-20
FR2903620A1 (fr) 2008-01-18
WO2008007002A2 (fr) 2008-01-17

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