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WO2008090282A3 - Catalyseur dηydrotraitement, son procede de preparation et son utilisation - Google Patents

Catalyseur dηydrotraitement, son procede de preparation et son utilisation Download PDF

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Publication number
WO2008090282A3
WO2008090282A3 PCT/FR2007/002073 FR2007002073W WO2008090282A3 WO 2008090282 A3 WO2008090282 A3 WO 2008090282A3 FR 2007002073 W FR2007002073 W FR 2007002073W WO 2008090282 A3 WO2008090282 A3 WO 2008090282A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
production
catalyst method
hydrotreatment catalyst
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2007/002073
Other languages
English (en)
Other versions
WO2008090282A2 (fr
Inventor
Claude Brun
Thierry Cholley
Carole Dupuy
Georges Fremy
Francis Humblot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
TotalEnergies Marketing Services SA
Original Assignee
Arkema France SA
Total France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA, Total France SA filed Critical Arkema France SA
Priority to CA2672953A priority Critical patent/CA2672953C/fr
Priority to US12/519,971 priority patent/US8318628B2/en
Priority to DK07871864.0T priority patent/DK2099565T3/en
Priority to EP07871864.0A priority patent/EP2099565B1/fr
Priority to KR1020097015459A priority patent/KR101466091B1/ko
Priority to JP2009542129A priority patent/JP5200219B2/ja
Priority to CN2007800471987A priority patent/CN101605603B/zh
Publication of WO2008090282A2 publication Critical patent/WO2008090282A2/fr
Publication of WO2008090282A3 publication Critical patent/WO2008090282A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0229—Sulfur-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0214
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un catalyseur d'hydroconversion d'hydrocarbures, comprenant un support à base d'au moins un oxyde réfractaire, au moins un métal du groupe VIII et au moins un métal du groupe VIB, caractérisé en ce qu'il comprend en outre au moins un composé organique comportant au moins deux fonctions thiol séparées par au moins un groupement oxygéné de formule (I) : HS-CxHyOz-SH (I) dans laquelle x est un nombre entier de 1 à 20, de préférence de 2 à 9, par exemple x est égal à 6, y est un nombre entier de 2 à 60, de préférence de 4 à 12, et z est un nombre entier de 1 à 10, de préférence de 1 à 6. Procédé de préparation et procédé d'activation dudit catalyseur, et utilisation du catalyseur activé pour l'hydrotraitement et/ ou l'hydrocraquage d'hydrocarbures.
PCT/FR2007/002073 2006-12-22 2007-12-14 Catalyseur dηydrotraitement, son procede de preparation et son utilisation Ceased WO2008090282A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA2672953A CA2672953C (fr) 2006-12-22 2007-12-14 Catalyseur d'hydrotraitement, son procede de preparation et son utilisation
US12/519,971 US8318628B2 (en) 2006-12-22 2007-12-14 Hydrotreatment catalyst, method for production and use thereof
DK07871864.0T DK2099565T3 (en) 2006-12-22 2007-12-14 Hydrogen treatment catalyst, process for their preparation and use thereof
EP07871864.0A EP2099565B1 (fr) 2006-12-22 2007-12-14 Catalyseur d'hydrotraitement, son procédé de préparation et son utilisation
KR1020097015459A KR101466091B1 (ko) 2006-12-22 2007-12-14 수소화처리 촉매, 그 제조 및 사용 방법
JP2009542129A JP5200219B2 (ja) 2006-12-22 2007-12-14 水素化処理触媒、その製造方法及びその使用
CN2007800471987A CN101605603B (zh) 2006-12-22 2007-12-14 加氢处理催化剂、其生产方法及用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0611267 2006-12-22
FR0611267A FR2910351B1 (fr) 2006-12-22 2006-12-22 Catalyseur d'hydrotraitement, son procede de preparation et son utilisation.

Publications (2)

Publication Number Publication Date
WO2008090282A2 WO2008090282A2 (fr) 2008-07-31
WO2008090282A3 true WO2008090282A3 (fr) 2008-10-02

Family

ID=38264729

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/002073 Ceased WO2008090282A2 (fr) 2006-12-22 2007-12-14 Catalyseur dηydrotraitement, son procede de preparation et son utilisation

Country Status (9)

Country Link
US (1) US8318628B2 (fr)
EP (1) EP2099565B1 (fr)
JP (1) JP5200219B2 (fr)
KR (1) KR101466091B1 (fr)
CN (1) CN101605603B (fr)
CA (1) CA2672953C (fr)
DK (1) DK2099565T3 (fr)
FR (1) FR2910351B1 (fr)
WO (1) WO2008090282A2 (fr)

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FR2949981B1 (fr) * 2009-09-11 2012-10-12 Eurecat Sa Procede de sulfuration de catalyseurs de traitement d'hydrocarbures
CN102933298B (zh) 2009-12-16 2016-08-03 Ifp新能源公司 可用于加氢处理的包含viii和vib族金属的催化剂以及使用乙酸和琥珀酸c1-c4二烷基酯的制备方法
FR2953740B1 (fr) * 2009-12-16 2012-01-13 Inst Francais Du Petrole Catalyseur utilisable en hydrotraitement comprenant des metaux des groupes viii et vib sauf le couple cobalt-molybdene, et preparation avec de l'acide acetique et du succinate de dialkyle c1-c4
FR2953739B1 (fr) * 2009-12-16 2012-01-13 Inst Francais Du Petrole Catalyseur utilisable en hydrotraitement comprenant du cobalt et du molybdene, son procede de preparation avec de l'acide acetique et du succinate de dialkyle c1-c4
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CN102029158B (zh) * 2010-10-13 2012-08-22 北京化工大学 一种硫化型加氢催化剂材料及其制备方法
KR101759351B1 (ko) * 2010-12-28 2017-07-21 에스케이이노베이션 주식회사 초임계 용매를 이용한 중질 탄화수소 유분의 수소화 분해 공정
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FR2977895B1 (fr) 2011-07-12 2015-04-10 Total Raffinage Marketing Compositions d'additifs ameliorant la stabilite et les performances moteur des gazoles non routiers
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US10053637B2 (en) 2015-12-15 2018-08-21 Uop Llc Transition metal tungsten oxy-hydroxide
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US20190233741A1 (en) 2017-02-12 2019-08-01 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
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CN107999148B (zh) * 2017-10-10 2020-11-06 浙江海洋大学 一种水溶液体系脱硫催化剂的复活方法
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FR3083130B1 (fr) * 2018-06-27 2022-11-04 Ifp Energies Now Catalyseur a base d'un lactate d'alkyle et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage
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US11426711B2 (en) 2019-05-22 2022-08-30 Uop Llc Method of making highly active metal oxide and metal sulfide materials

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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FR2910351B1 (fr) 2009-02-27
US8318628B2 (en) 2012-11-27
FR2910351A1 (fr) 2008-06-27
WO2008090282A2 (fr) 2008-07-31
DK2099565T3 (en) 2017-02-20
CA2672953C (fr) 2015-03-24
CN101605603B (zh) 2012-10-24
US20100044274A1 (en) 2010-02-25
KR101466091B1 (ko) 2014-11-27
JP5200219B2 (ja) 2013-06-05
CA2672953A1 (fr) 2009-07-31
EP2099565A2 (fr) 2009-09-16
KR20090100423A (ko) 2009-09-23
CN101605603A (zh) 2009-12-16
JP2010513008A (ja) 2010-04-30

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