[go: up one dir, main page]

WO2008089609A1 - Electro-phoretic paingting method and integrated equipment for strip of sheet - Google Patents

Electro-phoretic paingting method and integrated equipment for strip of sheet Download PDF

Info

Publication number
WO2008089609A1
WO2008089609A1 PCT/CN2007/001597 CN2007001597W WO2008089609A1 WO 2008089609 A1 WO2008089609 A1 WO 2008089609A1 CN 2007001597 W CN2007001597 W CN 2007001597W WO 2008089609 A1 WO2008089609 A1 WO 2008089609A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrophoresis
coil material
electrophoretic coating
workpiece
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2007/001597
Other languages
French (fr)
Chinese (zh)
Inventor
Zailiang Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN KELIER CHEMICAL INDUSTRY Ltd
Original Assignee
WUHAN KELIER CHEMICAL INDUSTRY Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN KELIER CHEMICAL INDUSTRY Ltd filed Critical WUHAN KELIER CHEMICAL INDUSTRY Ltd
Publication of WO2008089609A1 publication Critical patent/WO2008089609A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/12Electrophoretic coating characterised by the process characterised by the article coated
    • C25D13/16Wires; Strips; Foils
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D13/00Electrophoretic coating characterised by the process
    • C25D13/22Servicing or operating apparatus or multistep processes

Definitions

  • the invention relates to a method and a device for electrophoretic coating of materials, in particular to a coil material (such as a steel plate, an aluminum plate and the like, and a non-metal coil material but specially processed to become an electric conductor). Coil coating technology and complete equipment.
  • a coil material such as a steel plate, an aluminum plate and the like, and a non-metal coil material but specially processed to become an electric conductor.
  • electrophoretic coating technology mainly processes electrophoresis of workpieces with simple and easy-to-paint workpieces, but due to the influence of baking of electrophoretic coatings, materials for coiled sheets (such as steel plates, aluminum plates, copper plates and other metal conductor coils)
  • materials for coiled sheets such as steel plates, aluminum plates, copper plates and other metal conductor coils
  • the anti-corrosion treatment of materials and non-metal coil materials but various types of coils which have been specially treated to become electrical conductors cannot be treated by conventional electrophoresis techniques, and other treatment methods in the prior art cannot solve such materials well. Electrophoresis and its surface anti-corrosion problems.
  • the object of the present invention is to provide an electrophoretic coating of a coil material (such as a metal coil material such as a steel plate or an aluminum plate and a non-metal coil material but specially processed into a conductive material) in view of the defects of the prior art.
  • a coil material such as a metal coil material such as a steel plate or an aluminum plate and a non-metal coil material but specially processed into a conductive material
  • Another object of the present invention is to provide an apparatus for electrophoretic coating of a coil material.
  • the object of the present invention is achieved by the following technical solutions: it adopts a cathodic electrophoresis process or an anodic electrophoresis process, and specifically includes the following steps:
  • the coil material is connected to the conductive device as a cathode or anode system, the conductive device is connected to the negative electrode or the positive electrode of the electrophoresis power source; and the anode or cathode of the electrophoresis device is connected to the positive or negative electrode of the power source.
  • the coil material described therein is a coil material which is specially treated to become a conductor of metal or non-metal.
  • the coil material described therein is an iron plate, a steel plate, a copper plate, a zinc plate or an aluminum plate.
  • the coil material described therein is a fiberboard or a plastic board.
  • the electrophoretic coating used in the electrophoresis process comprises polybutadiene resin, phenolic resin, epoxy resin, acrylic acid or polyurethane.
  • the electrophoretic coatings used in the electrophoresis process include colorless and transparent, 3 ⁇ 4 light colorless or various color coatings, as well as flashing colors, pearlescent colors, and electrophoretic coatings with dyes or pigments.
  • the electrophoretic coating described therein is added with a filler and an auxiliary agent for enhancing the performance of the electrophoretic coating.
  • the electrophoretic coating used in the electrophoresis process comprises a thermosetting or photosensitive electrophoretic coating.
  • the material of the anode plate used in the cathodic electrophoresis process or the material of the cathode plate used in the anodic electrophoresis process is stainless steel, iron, aluminum, copper or non-metal material metallized conductive conductive member, the shape of which is Plate system, tubular system or bare plate.
  • the electrophoretic coating apparatus of the present invention comprises a unwinder and a winder, and an electrophoresis device is disposed between the unwinder and the winder.
  • the electrophoresis tank device comprises an electrophoresis main tank and an electrophoresis storage tank, and a front end of the electrophoresis main tank is provided with a conductive device, and the conductive device is connected with the coil material.
  • the electrophoresis tank device can adopt two forms: the first one is that the electrophoresis main tank is placed inside the electrophoresis storage tank, and is a large trough sleeve shape, and the electrophoresis main tank has parallel or longitudinal slots, which can Through the coil material, the upper and lower sides of the parallel slot or the left and right sides of the longitudinal slot have an anode or cathode system, and the parallel slot or the longitudinal slot is provided with a deflector on both sides, and the function of the drain plate will flow out from the slot The electrophoretic paint is hooked down to the next electrophoresis Storage tank.
  • the power pump installed on the electrophoresis storage tank is connected to the electrophoresis main tank through a conveying pipe, and an overflow pipe is arranged on the electrophoresis main tank, and the overflow pipe is connected with the electrophoresis storage tank.
  • the excess electrophoretic paint in the main electrophoresis tank overflows into the electrophoresis reservoir through the overflow tube. This forms a closed loop system.
  • the second type is that the electrophoresis main tank and the electrophoresis storage tank are separated and independent, adopting a double-slot or multi-slot structure, and the electrophoresis main tank has parallel or longitudinal slots, which can pass through the coil material, parallel to the upper surface of the slot
  • a collecting slot is provided under the electrophoresis main slot in the direction in which the coil material passes, and the small slot is collected.
  • the volume can be large or small, and the electrophoretic paint that can flow out of the slot can be collected and transported to the electrophoresis storage tank.
  • the collection trough is equipped with a pipeline connected to the electrophoresis storage tank.
  • the power pump installed on the electrophoresis storage tank is connected to the electrophoresis main tank through the transport tube, and the electrophoresis main tank is provided with an overflow tube, and the overflow tube is connected with the electrophoresis storage tank.
  • the excess electrophoretic paint in the main electrophoresis tank overflows into the electrophoresis reservoir through the overflow tube. This forms a closed loop system.
  • a flattening machine, a positioning machine, a pretreatment machine, a water washing machine and a baking machine are arranged between the unwinder and the winder.
  • the invention can open a plurality of parallel slots or longitudinal slots in the electrophoresis main groove, and install a plurality of parallel or longitudinal plate systems, so that a plurality of coil materials can be simultaneously electrophoresed.
  • the invention completely solves the coil material (such as steel plate, aluminum plate, copper plate and other metal conductor coil material and non-metal coil material but special treatment into various types of coils of electrical conductor) and non-metal special treatment
  • the electrophoresis treatment of the coiled sheet of the conductor makes the surface of the above material anticorrosive by electrophoretic coating.
  • Figure 1 is a process flow and equipment layout diagram of the present invention
  • FIG. 3 is a structural diagram of an electrophoresis device of the present invention
  • FIG. 4 is a view showing another embodiment of an electrophoresis apparatus according to the present invention.
  • FIG. 5 is still another embodiment of the electrophoresis device device of the present invention.
  • FIG. 6 is a view showing still another embodiment of the electrophoresis device device of the present invention.
  • the electrophoretic coating complete equipment of the present invention comprises a unwinder 1 and a winder 2, and an electrophoresis device is arranged between the unwinder 1 and the winder 2.
  • the electrophoresis tank device can take two forms:
  • the first type is that the electrophoresis main tank 3 is placed inside the electrophoresis storage tank 4, which is in the shape of a large trough sleeve, and the electrophoresis main tank 3 has a horizontal slot 5, which can pass through the coil material.
  • An anode or cathode system 6 is disposed above and below the parallel slot 5, and a parallel plate 5 is provided on both sides of the parallel slot 5, and the draining plate 7 functions to uniformly drain the electrophoretic paint flowing out of the slot 5 to the lower electrophoresis storage.
  • Slot 4 is that the electrophoresis main tank 3 is placed inside the electrophoresis storage tank 4, which is in the shape of a large trough sleeve, and the electrophoresis main tank 3 has a horizontal slot 5, which can pass through the coil material.
  • An anode or cathode system 6 is disposed above and below the parallel slot 5, and a parallel plate 5 is provided on both sides of the parallel slot 5, and the draining plate 7 functions
  • the power circulation pump 8 mounted on the electrophoresis storage tank 4 is connected to the electrophoresis main tank 3 through a transport pipe 9, and the electrophoresis main tank 3 is provided with an overflow pipe 10, and the overflow pipe 10 is connected to the electrophoresis storage tank 4.
  • the electrophoretic main tank 3 excess electrophoretic paint is then overflowed through the overflow tube 10 to the electrophoresis storage tank 4.
  • the present invention can also adopt a longitudinal slot, and the anode or cathode system 6 is also disposed longitudinally when a longitudinal slot is used.
  • the second type is that the electrophoresis main tank 3 and the electrophoresis storage tank 4 are separated and independent, and adopts a double-slot or multi-slot structure, and the horizontal slot 5 on the electrophoresis main tank 3 can pass through the coil.
  • the material has an anode or cathode system 6 above and below the horizontal slot 5, and a drainage plate 7 is arranged on both sides of the horizontal slot.
  • a collecting slot 11 is provided under the electrophoresis main slot in the direction in which the coil material passes, and the small slot 11 is collected.
  • the volume can be large or small, and the electrophoretic paint that can flow out of the slot can be collected and transported to the electrophoresis storage tank.
  • the collecting trough is provided with a pipe 12, and the pipe 12 is connected to the electrophoresis storage tank 4.
  • the power circulation pump 8 installed on the electrophoresis storage tank 4 is connected to the electrophoresis main tank 3 through the conveying pipe 9, and the electrophoresis main tank 3 is provided with an overflow pipe 10,
  • the overflow pipe 10 is connected to the electrophoresis storage tank 4.
  • the electrophoretic main tank 3 excess electrophoretic paint is then overflowed through the overflow tube 10 to the electrophoresis storage tank 4. This forms a closed loop system.
  • the utility model can also adopt a longitudinal slot, and the anode or cathode system 6 is also longitudinally disposed when a longitudinal slot is used.
  • a flattening machine 14, a positioning machine 15, a front processing machine 16, a water washing machine 17, and a baking machine 18 are provided between the unwinding machine 1 and the winder 2.
  • a conductive device 13 is mounted in front of the slot of the electrophoresis main tank 3.
  • Example 1 In the case of planar transverse cathodic electrophoresis -
  • the coil material workpiece 19 is an electrophoretic member, which is a cathode system, and is connected to a negative electrode (-) of the electrophoresis source through a conductive device 13.
  • the anode system is connected to the positive (+) power supply.
  • the anode is a fixed connection, and the cathode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece.
  • the coil material workpiece 19 is passed through the electrophoretic paint solution of the electrophoresis main tank 4 in parallel, and the workpiece of the coil material is passed through two parallel slots of the electrophoresis main tank to start moving the power supply to make the coil
  • the workpiece moves in parallel; when the workpiece of the coil material passes through the leveling machine, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process.
  • the workpiece of the coil material passes through the positioning machine 15, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning.
  • different treatment methods can be adopted according to different coil materials. At the same time, different treatment methods can be adopted according to the degree of surface contamination of different materials.
  • the pre-treatment method can be degreasing and degreasing treatment: If the coil material has no other performance requirements, it can be degreased and degreased only to make the surface clean, and the workpiece can be transported in the next process.
  • the pre-treatment method can be electroplating treatment: If the coil material has other performance requirements, the surface can be plated differently according to requirements, and the surface can be plated with different metal layers, and then the workpiece can be transported in the next process. Such as galvanized coil plates.
  • the pretreatment method can be phosphating: If the coil material has other performance requirements, the surface can be phosphatized according to requirements, and the surface can be obtained with different phosphating layers, and then transported to the next process. Workpiece. Such as coiled iron sheet and so on.
  • the pretreatment method can be oxidation treatment: If the coil material has other performance requirements, the surface can be oxidized differently according to the requirements, and the surface can be obtained with different oxide layers, and then the workpiece can be transported in the next process. Such as rolled aluminum sheet and so on.
  • the surface of the workpiece is cleaned with tap water or purified water, the liquid and impurities brought out by the previous process are cleaned, the surface of the workpiece is cleaned, and then the workpiece is conveyed in the next process.
  • the power circulation pump 8 is started, the electrophoretic paint of the electrophoresis storage tank 4 is twitched, and the workpiece is completely immersed in the electrophoretic paint.
  • the main channel of the electrophoresis has an overflow port on the anode system, and the excess electrophoretic paint can be discharged from the overflow port.
  • the pipeline flows out and flows into the electrophoresis storage tank to prevent the full circulation of the power circulation pump due to excessive delivery.
  • This overflow line is open to the side or other Position, but can not affect the electrophoresis process, as long as it does not cause full tank phenomenon and can continuously supply electrophoretic coating, so that the electrophoresis workpiece can be fully immersed in the electrophoretic paint.
  • the electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface float paint.
  • the workpiece of the coil material is baked in parallel into the baking machine 18, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the coil material is cooled and dried, it can be packaged in rolls.
  • the apparatus of the present invention can simultaneously electrophoreize single-roll and multi-rolled coil materials.
  • the thickness of the electrophoretic paint film can be guaranteed by controlling the voltage and time and other conditions.
  • Example 2 In the case of a planar lateral anodic electrophoresis process:
  • the workpiece of the coil material is an electrophoresis member, which is an anode system and is connected to the positive electrode (+) of the electrophoresis source.
  • the cathode system is connected to the negative (-) power supply.
  • the cathode is a fixed connection, and the anode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece.
  • the workpiece of the coil material is passed through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two parallel slots of the electrophoresis tank. Start moving the power supply and let the coil workpiece move in parallel.
  • the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process.
  • the workpiece of the coil material passes through the positioning machine, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning.
  • different treatment methods can be adopted according to different coil materials.
  • different treatment methods can be adopted according to the degree of surface contamination of different materials.
  • the pretreatment method is the same as that of the first embodiment.
  • the main channel of the electrophoresis has an overflow port on the upper part of the anode system, and the excess electrophoretic paint can flow out from the overflow port and flow into the electrophoresis storage tank to prevent the large amount of the power pump from being delivered. phenomenon.
  • the overflow pipe is open to the side or other position, but it does not affect the electrophoresis process. As long as the full tank is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint.
  • the electrophoresis power source is turned on for electrophoresis. After leaving the electrophoresis tank, the workpiece of the coil material is washed with ultrafiltration water or pure water to rinse off the surface of the workpiece. The coil material is baked in parallel into the baking machine 18, and the electrophoretic paint film is leveled and solidified. After the coil material workpiece leaves the oven, it is forced to cool with cold air. 19 materials for coiling materials. After cooling and drying, they can be packaged in rolls.
  • Embodiment 3 When the vertical cathodic electrophoresis process is erected: the workpiece of the coil material is an electrophoresis member, For the cathode system, connect the negative electrode (-) of the electrophoresis source. The anode system is connected to the positive pole of the power supply ( + ). The anode is a fixed connection, and the cathode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece. As shown in FIG. 2, the workpiece of the coil material is vertically erected through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two vertical longitudinal slots of the electrophoresis tank.
  • the power circulation pump 8 is started, the electrophoresis paint of the electrophoresis storage tank is twitched, and the workpiece is completely immersed in the electrophoretic paint.
  • the main channel of the electrophoresis has an overflow port on the cathode system, and the excess electrophoretic paint can be discharged from the overflow pipe.
  • the road flows out and flows into the electrophoresis storage tank to prevent the tank from being over-sized due to excessive power transmission.
  • the overflow pipe is open to the side or other position, but it cannot affect the electrophoresis process. As long as the full-slot phenomenon is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint.
  • the electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface varnish.
  • the workpiece of the coil material is longitudinally baked into the baking machine 18 to be baked, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the sheet material is cooled, it can be packaged in rolls.
  • the workpiece of the coil material is an electrophoresis member, which is an anode system, and is connected to the positive electrode (+) of the electrophoresis source.
  • the cathode system is connected to the negative (-) power supply.
  • the cathode is a fixed connection, and the anode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece.
  • FIG. 4 The workpiece of the coil material is erected longitudinally through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two vertical longitudinal slots of the electrophoresis tank. Start moving the power supply and let the coiled workpiece move vertically.
  • the workpiece of the coil material passes through the leveling machine, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process.
  • the workpiece of the coil material passes through the positioning machine, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning.
  • different treatment methods can be adopted according to different coil materials. Meanwhile also Different treatment methods can be adopted according to the degree of surface contamination of different materials.
  • the pretreatment method is the same as that of the first embodiment.
  • the power circulation pump is started, the electrophoresis paint of the electrophoresis storage tank is twitched, and the workpiece is completely immersed in the electrophoretic paint.
  • the main channel of the electrophoresis has an overflow port on the cathode system, and the excess electrophoretic paint can be drained from the overflow port. It flows out and flows into the electrophoresis storage tank to prevent the tank from being over-sized due to excessive power transmission.
  • the overflow pipe is open to the side or other position, but it does not affect the electrophoresis process. As long as the full tank is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint.
  • the electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface varnish.
  • the workpiece of the coil material is longitudinally baked into the baking machine 18 to be baked, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the sheet material is cooled, it can be packaged in rolls.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

A electro-phoretic painting method and integrated equipment for strip of sheet are disclosed. The method involves cathodic or anodic electrophoresis process, and the strip of sheet is horizontally or vertically passed through the bath solution of the electrophoresis cell. The present invention can throughly solve the problem on treating strips of metal sheets (such as steel sheet, Al sheet and Cu sheet etc. ) and the other conductive strips which are obtained by specifically processing the non-conductive strips, and it can achieve an anticorrosion effect by painting the surfaces of those materials in an electro-phoretic process.

Description

卷板材料的电泳涂装技术方法及成套设备 技术领域  Electrophoretic coating technology method and complete equipment for coil material

本发明涉及一种材料的电泳涂装技术方法及设备,具体地说是一 种卷板材料(如钢板, 铝板等金属卷板材料以及非金属卷板材料但经 过特殊处理成为导电体的各类卷材) 的电泳涂装技术方法及成套设 备。  The invention relates to a method and a device for electrophoretic coating of materials, in particular to a coil material (such as a steel plate, an aluminum plate and the like, and a non-metal coil material but specially processed to become an electric conductor). Coil coating technology and complete equipment.

背景技术 Background technique

电泳涂装技术自二十世纪六十年代发展及得到工业化应用以来, 其优良的高耐腐蚀性, 水性环保, 高泳透率, 高库仑效率, 不溶解被 涂物, 槽液稳定, 自动化程度高, 连续性生产等优势, 在汽车行业, 摩托车行业,家用电器, 仪表仪器, 军工建材, 装饰发饰, 眼镜锁具, 五金轻工, 日用品等行业获得广泛应用, 巳逐步取代了常规的表面涂 装技术, 并成为当今世界最重要的涂装技术方式一种。  Since the development of the electrophoretic coating technology in the 1960s and its industrial application, its excellent high corrosion resistance, water-based environmental protection, high throughput, high coulombic efficiency, insoluble coating, stable bath, automation High, continuous production and other advantages, in the automotive industry, motorcycle industry, household appliances, instrumentation, military building materials, decorative hair accessories, glasses locks, hardware and light industry, daily necessities and other industries have been widely used, 巳 gradually replaced the conventional surface Painting technology, and become one of the most important painting techniques in the world today.

目前的电泳涂装技术主要电泳处理一般工件结构简单较易涂装 的工件, 但由于受到电泳涂料的需烘烤的影响, 针对卷板材料(如钢 板,铝板,铜板及其它金属导电体卷板材料以及非金属卷板材料但经 过特殊处理成为导电体的各类卷材)的防腐处理则无法用常规电泳技 术的处理,现有技术中的其它处理方法都不能较好的解决此类材料的 电泳及其表面的防腐问题。  At present, electrophoretic coating technology mainly processes electrophoresis of workpieces with simple and easy-to-paint workpieces, but due to the influence of baking of electrophoretic coatings, materials for coiled sheets (such as steel plates, aluminum plates, copper plates and other metal conductor coils) The anti-corrosion treatment of materials and non-metal coil materials but various types of coils which have been specially treated to become electrical conductors cannot be treated by conventional electrophoresis techniques, and other treatment methods in the prior art cannot solve such materials well. Electrophoresis and its surface anti-corrosion problems.

发明内容 Summary of the invention

本发明目的就是针对现有技术的缺陷,提供一种卷板材料(如钢 板,铝板等金属卷板材料以及非金属卷板材料但经过特殊处理成为导 电体的各类卷材)的电泳涂装技术及成套设备, 它彻底解决了卷板材 料的电泳涂装技术难题, 使上述材料满足防腐要求。  The object of the present invention is to provide an electrophoretic coating of a coil material (such as a metal coil material such as a steel plate or an aluminum plate and a non-metal coil material but specially processed into a conductive material) in view of the defects of the prior art. Technology and complete sets of equipment, it completely solves the technical problems of electrophoretic coating of coiled materials, so that the above materials meet the anti-corrosion requirements.

本发明的另一目的就是提供一种卷板材料电泳涂装成套设备。 本发明的目的通过以下技术方案来实现:它采用阴极电泳工艺或 阳极电泳工艺, 具体包括以下步骤:  Another object of the present invention is to provide an apparatus for electrophoretic coating of a coil material. The object of the present invention is achieved by the following technical solutions: it adopts a cathodic electrophoresis process or an anodic electrophoresis process, and specifically includes the following steps:

( 1 ) 将卷板材料与导电装置连接作为阴极或阳极系统, 导电装 置接电泳电源的负极或正极;电泳装置阳极或阴极接电源正极或负极  (1) The coil material is connected to the conductive device as a cathode or anode system, the conductive device is connected to the negative electrode or the positive electrode of the electrophoresis power source; and the anode or cathode of the electrophoresis device is connected to the positive or negative electrode of the power source.

认本 作为阳极或阴极系统; Recognize As an anode or cathode system;

( 2 )将卷板材料工件平行或纵向通过电泳槽的电泳漆溶液中; (2) passing the workpiece of the coil material in parallel or longitudinally through the electrophoretic paint solution of the electrophoresis tank;

(3 ) 开通电泳电源进行电泳; (3) turning on the electrophoresis power source for electrophoresis;

(4)卷板材料工件离开电泳槽后, 用水冲洗工件表面, 冲洗掉表 面浮漆;  (4) After the workpiece of the coil material leaves the electrophoresis tank, rinse the surface of the workpiece with water and rinse off the surface floating paint;

(5 )将卷板材料工件平行或纵向进入烘箱烘烤, 使电泳漆膜流平 及固化;  (5) The workpiece of the coil material is baked in parallel or longitudinally into the oven to make the electrophoretic paint film level and solidify;

(6)卷板材料工件离开烘箱后, 用冷气强制冷却、 干燥后, 收成 卷包装。  (6) After the workpiece of the coil material leaves the oven, it is forced to cool and dry with cold air, and then the package is packaged.

其中所述的卷板材料为金属或非金属经特殊处理变为导电体的 卷板材料。  The coil material described therein is a coil material which is specially treated to become a conductor of metal or non-metal.

其中所述的卷板材料为铁板、 钢板、 铜板、 锌板或铝板。  The coil material described therein is an iron plate, a steel plate, a copper plate, a zinc plate or an aluminum plate.

其中所述的卷板材料为纤维板或塑料板。  The coil material described therein is a fiberboard or a plastic board.

其中电泳过程中使用的电泳涂料包含聚丁二烯树脂、 酚醛树脂、 环氧树脂, 丙烯酸或聚胺脂。  The electrophoretic coating used in the electrophoresis process comprises polybutadiene resin, phenolic resin, epoxy resin, acrylic acid or polyurethane.

其中电泳过程中使用的电泳涂料包含无色透明、 ¾光无色或各类 彩色涂料, 以及闪光色、 珠光色和添加有染料或颜料的电泳涂料。  The electrophoretic coatings used in the electrophoresis process include colorless and transparent, 3⁄4 light colorless or various color coatings, as well as flashing colors, pearlescent colors, and electrophoretic coatings with dyes or pigments.

其中所述的电泳涂料中添加有填料及增强电泳涂料性能的助剂。 其中电泳过程中使用的电泳涂料包含热固性或光敏性电泳涂料。 其中在阴极电泳工艺中所用阳极板的材料或在阳极电泳工艺中 所用的阴极板的材料为不锈钢, 铁件、铝件、铜件或非金属材料金属 化处理可导电的导体件, 其形状为板式系统、 管式系统或裸露极板。  The electrophoretic coating described therein is added with a filler and an auxiliary agent for enhancing the performance of the electrophoretic coating. The electrophoretic coating used in the electrophoresis process comprises a thermosetting or photosensitive electrophoretic coating. The material of the anode plate used in the cathodic electrophoresis process or the material of the cathode plate used in the anodic electrophoresis process is stainless steel, iron, aluminum, copper or non-metal material metallized conductive conductive member, the shape of which is Plate system, tubular system or bare plate.

本发明的电泳涂装成套设备包括放卷机和收卷机,放卷机和收卷 机之间设有电泳设备装置。所述电泳槽设备装置包含电泳主槽和电泳 储槽, 电泳主槽前端装有导电装置,导电装置与卷板材料连接。  The electrophoretic coating apparatus of the present invention comprises a unwinder and a winder, and an electrophoresis device is disposed between the unwinder and the winder. The electrophoresis tank device comprises an electrophoresis main tank and an electrophoresis storage tank, and a front end of the electrophoresis main tank is provided with a conductive device, and the conductive device is connected with the coil material.

所述电泳槽设备装置可以采用两种形式:第一种是所述电泳主槽 放在电泳储槽的里面,是大槽套小槽形状, 电泳主槽上有平行或纵向 的槽孔,可以通过卷板材料,平行槽孔的上面和下面或者纵向槽孔的 左面和右面有阳极或阴极系统,平行槽孔或者纵向槽孔两边装有引流 板,引流板的作用起到将从槽孔流出的电泳漆均勾弓 I流到下面的电泳 储槽。电泳储槽上装有的动力泵通过输送管连接到电泳主槽, 电泳主 槽上装有溢流管,溢流管与电泳储槽连接。 电泳主槽多余的电泳漆再 通过溢流管溢流到电泳储槽。 这样形成一个闭路循环系统。 The electrophoresis tank device can adopt two forms: the first one is that the electrophoresis main tank is placed inside the electrophoresis storage tank, and is a large trough sleeve shape, and the electrophoresis main tank has parallel or longitudinal slots, which can Through the coil material, the upper and lower sides of the parallel slot or the left and right sides of the longitudinal slot have an anode or cathode system, and the parallel slot or the longitudinal slot is provided with a deflector on both sides, and the function of the drain plate will flow out from the slot The electrophoretic paint is hooked down to the next electrophoresis Storage tank. The power pump installed on the electrophoresis storage tank is connected to the electrophoresis main tank through a conveying pipe, and an overflow pipe is arranged on the electrophoresis main tank, and the overflow pipe is connected with the electrophoresis storage tank. The excess electrophoretic paint in the main electrophoresis tank overflows into the electrophoresis reservoir through the overflow tube. This forms a closed loop system.

第二种是所述电泳主槽与电泳储槽是分开独立的结构,采用双槽 或多槽结构, 电泳主槽上有平行或纵向的槽孔, 可以通过卷板材料, 平行槽孔的上面和下面或者纵向槽孔的左面和右面有阳极或阴极系 统,平行槽孔或者纵向槽孔两边装有引流板,在卷板材料通过的方向 电泳主槽下面设有收集小槽,收集小槽的容积可大可小, 能达到满足 从槽孔中流出的电泳漆能收集并输送到电泳储槽即可。收集小槽上装 有管道,管道与电泳储槽连接, 电泳储槽上装有的动力泵通过输送管 连接到电泳主槽, 电泳主槽上装有溢流管, 溢流管与电泳储槽连接。 电泳主槽多余的电泳漆再通过溢流管溢流到电泳储槽。这样形成一个 闭路循环系统。  The second type is that the electrophoresis main tank and the electrophoresis storage tank are separated and independent, adopting a double-slot or multi-slot structure, and the electrophoresis main tank has parallel or longitudinal slots, which can pass through the coil material, parallel to the upper surface of the slot There are anode or cathode systems on the left and right sides of the lower or longitudinal slots, and a drainage plate is arranged on both sides of the parallel slot or the longitudinal slot. A collecting slot is provided under the electrophoresis main slot in the direction in which the coil material passes, and the small slot is collected. The volume can be large or small, and the electrophoretic paint that can flow out of the slot can be collected and transported to the electrophoresis storage tank. The collection trough is equipped with a pipeline connected to the electrophoresis storage tank. The power pump installed on the electrophoresis storage tank is connected to the electrophoresis main tank through the transport tube, and the electrophoresis main tank is provided with an overflow tube, and the overflow tube is connected with the electrophoresis storage tank. The excess electrophoretic paint in the main electrophoresis tank overflows into the electrophoresis reservoir through the overflow tube. This forms a closed loop system.

所述放卷机和收卷机之间设有压平机、定位机、前处理机、水洗 机和烘烤机。  A flattening machine, a positioning machine, a pretreatment machine, a water washing machine and a baking machine are arranged between the unwinder and the winder.

本发明可以在电泳主槽上开多个平行槽孔或者纵向槽孔,装多个 平行或纵向的极板系统, 这样可以同时电泳多个卷板材料。  The invention can open a plurality of parallel slots or longitudinal slots in the electrophoresis main groove, and install a plurality of parallel or longitudinal plate systems, so that a plurality of coil materials can be simultaneously electrophoresed.

本发明彻底解决了卷板材料(如钢板, 铝板, 铜板及其它金属导 电体卷板材料以及非金属卷板材料但经过特殊处理成为导电体的各 类卷材) 以及非金属经特殊处理变为导电体的卷板材的电泳处理难 题, 使上述材料表面通过电泳涂装防腐成为现实。  The invention completely solves the coil material (such as steel plate, aluminum plate, copper plate and other metal conductor coil material and non-metal coil material but special treatment into various types of coils of electrical conductor) and non-metal special treatment The electrophoresis treatment of the coiled sheet of the conductor makes the surface of the above material anticorrosive by electrophoretic coating.

附图说明 DRAWINGS

图 1为本发明的工艺流程和设备布置图  Figure 1 is a process flow and equipment layout diagram of the present invention

图 2为本发明的另一实施方式工艺流程和设备布置图  2 is a process flow and equipment layout diagram of another embodiment of the present invention

图 3为本发明电泳设备装置结构图  Figure 3 is a structural diagram of an electrophoresis device of the present invention

图 4为本发明电泳设备装置的另一实施方式图  4 is a view showing another embodiment of an electrophoresis apparatus according to the present invention;

图 5为本发明电泳设备装置的又一实施方式图  FIG. 5 is still another embodiment of the electrophoresis device device of the present invention;

图 6为本发明电泳设备装置的又一实施方式图  6 is a view showing still another embodiment of the electrophoresis device device of the present invention;

具体实施方式 detailed description

以下结合实施例对本发明作进一步描述 - 本发明电泳涂装成套设备包括放卷机 1和收卷机 2, 放卷机 1和 收卷机 2之间设有电泳设备装置。所述电泳槽设备装置可以采用两种 形式: The present invention will be further described below in conjunction with the embodiments - The electrophoretic coating complete equipment of the present invention comprises a unwinder 1 and a winder 2, and an electrophoresis device is arranged between the unwinder 1 and the winder 2. The electrophoresis tank device can take two forms:

如图 3所示, 第一种是所述电泳主槽 3放在电泳储槽 4的里面, 是大槽套小槽形状, 电泳主槽 3上有水平的槽孔 5, 可以通过卷板材 料, 平行槽孔 5的上面和下面有阳极或阴极系统 6, 平行槽孔 5两边 装有引流板 7, 引流板 7的作用起到将从槽孔 5流出的电泳漆均匀引 流到下面的电泳储槽 4。 电泳储槽 4上装有的动力循环泵 8通过输送 管 9连接到电泳主槽 3, 电泳主槽 3上装有溢流管 10, 溢流管 10与 电泳储槽 4连接。 电泳主槽 3多余的电泳漆再通过溢流管 10溢流到 电泳储槽 4。 这样形成一个闭路循环系统。 如图 4所示, 本实用新型 也可以采用纵向的槽孔,当采用纵向的槽孔时阳极或阴极系统 6也纵 向设置。  As shown in FIG. 3, the first type is that the electrophoresis main tank 3 is placed inside the electrophoresis storage tank 4, which is in the shape of a large trough sleeve, and the electrophoresis main tank 3 has a horizontal slot 5, which can pass through the coil material. An anode or cathode system 6 is disposed above and below the parallel slot 5, and a parallel plate 5 is provided on both sides of the parallel slot 5, and the draining plate 7 functions to uniformly drain the electrophoretic paint flowing out of the slot 5 to the lower electrophoresis storage. Slot 4. The power circulation pump 8 mounted on the electrophoresis storage tank 4 is connected to the electrophoresis main tank 3 through a transport pipe 9, and the electrophoresis main tank 3 is provided with an overflow pipe 10, and the overflow pipe 10 is connected to the electrophoresis storage tank 4. The electrophoretic main tank 3 excess electrophoretic paint is then overflowed through the overflow tube 10 to the electrophoresis storage tank 4. This forms a closed loop system. As shown in Fig. 4, the present invention can also adopt a longitudinal slot, and the anode or cathode system 6 is also disposed longitudinally when a longitudinal slot is used.

如图 5所示,第二种是所述电泳主槽 3与电泳储槽 4是分开独立 的结构,采用双槽或多槽结构, 电泳主槽 3上有水平的槽孔 5可以通 过卷板材料, 水平槽孔 5的上面和下面有阳极或阴极系统 6, 水平槽 孔两边装有引流板 7, 在卷板材料通过的方向电泳主槽下面设有收集 小槽 11, 收集小槽 11的容积可大可小, 能达到满足从槽孔中流出的 电泳漆能收集并输送到电泳储槽即可。 收集小槽上装有管道 12, 管 道 12与电泳储槽 4连接, 电泳储槽 4上装有的动力循环泵 8通过输 送管 9连接到电泳主槽 3, 电泳主槽 3上装有溢流管 10, 溢流管 10 与电泳储槽 4连接。 电泳主槽 3多余的电泳漆再通过溢流管 10溢流 到电泳储槽 4。 这样形成一个闭路循环系统。 如图 6所示, 本实用新 型也可以采用纵向的槽孔,当采用纵向的槽孔时阳极或阴极系统 6也 纵向设置。  As shown in FIG. 5, the second type is that the electrophoresis main tank 3 and the electrophoresis storage tank 4 are separated and independent, and adopts a double-slot or multi-slot structure, and the horizontal slot 5 on the electrophoresis main tank 3 can pass through the coil. The material has an anode or cathode system 6 above and below the horizontal slot 5, and a drainage plate 7 is arranged on both sides of the horizontal slot. A collecting slot 11 is provided under the electrophoresis main slot in the direction in which the coil material passes, and the small slot 11 is collected. The volume can be large or small, and the electrophoretic paint that can flow out of the slot can be collected and transported to the electrophoresis storage tank. The collecting trough is provided with a pipe 12, and the pipe 12 is connected to the electrophoresis storage tank 4. The power circulation pump 8 installed on the electrophoresis storage tank 4 is connected to the electrophoresis main tank 3 through the conveying pipe 9, and the electrophoresis main tank 3 is provided with an overflow pipe 10, The overflow pipe 10 is connected to the electrophoresis storage tank 4. The electrophoretic main tank 3 excess electrophoretic paint is then overflowed through the overflow tube 10 to the electrophoresis storage tank 4. This forms a closed loop system. As shown in Fig. 6, the utility model can also adopt a longitudinal slot, and the anode or cathode system 6 is also longitudinally disposed when a longitudinal slot is used.

所述放卷机 1和收卷机 2之间设有压平机 14、 定位机 15、 前处 理机 16、水洗机 17和烘烤机 18。 电泳主槽 3的槽孔前装有导电装置 13。  A flattening machine 14, a positioning machine 15, a front processing machine 16, a water washing machine 17, and a baking machine 18 are provided between the unwinding machine 1 and the winder 2. A conductive device 13 is mounted in front of the slot of the electrophoresis main tank 3.

本发明方法可以通过以下实施方式实现:  The method of the invention can be implemented by the following embodiments:

实施例 1 : 平面横向阴极电泳工艺时- 卷板材料工件 19为被电泳件,为阴极系统,通过导电装置 13接 电泳源的负极 (-)。 阳极系统接电源正极(+)。 阳极是固定式连接, 阴极使用有弹性金属材料压接或者夹接, 但不能影响工件的连续走 动。 如图 1所示: 将卷板材料工件 19平行通过电泳主槽 4的电泳漆 溶液中,将卷板材料工件穿过电泳主槽的两个平行的槽孔,开动移动 输送电源, 让卷板工件平行移动; 卷板材料工件通过整平机时,通过 整平使工件平整均匀, 向下道工序输送工件。卷板材料工件通过定位 机 15时, 通过定位使工件上下, 左右保持一致, 定位后向下道工序 输送工件。卷板材料工件 19通过前处理机 16时,可根据不同的卷板 材质采取不同的处理方式。同时也可根据材质不同的表面污染程度采 取不同的处理方式。 Example 1: In the case of planar transverse cathodic electrophoresis - The coil material workpiece 19 is an electrophoretic member, which is a cathode system, and is connected to a negative electrode (-) of the electrophoresis source through a conductive device 13. The anode system is connected to the positive (+) power supply. The anode is a fixed connection, and the cathode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece. As shown in Figure 1: The coil material workpiece 19 is passed through the electrophoretic paint solution of the electrophoresis main tank 4 in parallel, and the workpiece of the coil material is passed through two parallel slots of the electrophoresis main tank to start moving the power supply to make the coil The workpiece moves in parallel; when the workpiece of the coil material passes through the leveling machine, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process. When the workpiece of the coil material passes through the positioning machine 15, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning. When the coil material workpiece 19 passes through the pretreatment machine 16, different treatment methods can be adopted according to different coil materials. At the same time, different treatment methods can be adopted according to the degree of surface contamination of different materials.

A. 前处理方式可以为脱脂除油处理: 若卷板材料无其他性能要 求, 就可以仅对表面作脱脂除油处理, 让表面洁净即可, 向下道工序 输送工件。  A. The pre-treatment method can be degreasing and degreasing treatment: If the coil material has no other performance requirements, it can be degreased and degreased only to make the surface clean, and the workpiece can be transported in the next process.

B. 前处理方式可以为电镀处理: 若卷板材料有其他性能要求, 就可以根据要求对表面作不同的电镀处理,使其表面得到不同的电镀 金属层, 然后向下道工序输送工件。 如镀锌卷板材等。  B. The pre-treatment method can be electroplating treatment: If the coil material has other performance requirements, the surface can be plated differently according to requirements, and the surface can be plated with different metal layers, and then the workpiece can be transported in the next process. Such as galvanized coil plates.

C. 前处理方式可以为磷化处理: 若卷板材料有其他性能要求, 就可以根据要求对表面作不同的磷化处理,使其表面得到不同的磷化 膜层, 然后向下道工序输送工件。 如卷铁板材等。  C. The pretreatment method can be phosphating: If the coil material has other performance requirements, the surface can be phosphatized according to requirements, and the surface can be obtained with different phosphating layers, and then transported to the next process. Workpiece. Such as coiled iron sheet and so on.

D. 前处理方式可以为氧化处理 : 若卷板材料有其他性能要求, 就可以根据要求对表面作不同的氧化处理,使其表面得到不同的氧化 膜层, 然后向下道工序输送工件。 如卷铝板材等。  D. The pretreatment method can be oxidation treatment: If the coil material has other performance requirements, the surface can be oxidized differently according to the requirements, and the surface can be obtained with different oxide layers, and then the workpiece can be transported in the next process. Such as rolled aluminum sheet and so on.

卷板材料工件通过清洗机时,通过对工件表面用自来水或纯净水 的清洗, 清洗掉前道工序带出的液体及杂质物, 使工件表面洁净, 然 后向下道工序输送工件。  When the workpiece of the coil material passes through the washing machine, the surface of the workpiece is cleaned with tap water or purified water, the liquid and impurities brought out by the previous process are cleaned, the surface of the workpiece is cleaned, and then the workpiece is conveyed in the next process.

开动动力循环泵 8, 抽动电泳储槽 4的电泳漆, 让工件全部浸没 于电泳漆中, 同时电泳主槽上在阳极系统的上面开有溢流口管路, 多 余电泳漆可以从此溢流口管路流出,流入到电泳储槽, 以防止因动力 循环泵的输送量过大,造成满槽现象。此溢流口管路开于侧面或其他 位置,但不能影响电泳过程,只要不造成满槽现象同时又能连续供应 电泳涂料,让电泳工件全部浸入电泳漆中即可。开通电泳电源进行电 泳。工件离开电泳槽后, 用超滤水或纯水冲洗工件其表面, 冲洗掉表 面浮漆。 将卷板材料工件平行进入烘烤机 18烘烤, 电泳漆膜流平及 固化。将卷板材料工件工件离开烘箱后, 用冷气强制冷却。卷板材料 工件冷却干燥后, 即可以成卷包装。 The power circulation pump 8 is started, the electrophoretic paint of the electrophoresis storage tank 4 is twitched, and the workpiece is completely immersed in the electrophoretic paint. At the same time, the main channel of the electrophoresis has an overflow port on the anode system, and the excess electrophoretic paint can be discharged from the overflow port. The pipeline flows out and flows into the electrophoresis storage tank to prevent the full circulation of the power circulation pump due to excessive delivery. This overflow line is open to the side or other Position, but can not affect the electrophoresis process, as long as it does not cause full tank phenomenon and can continuously supply electrophoretic coating, so that the electrophoresis workpiece can be fully immersed in the electrophoretic paint. The electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface float paint. The workpiece of the coil material is baked in parallel into the baking machine 18, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the coil material is cooled and dried, it can be packaged in rolls.

本发明设备可以同时电泳单卷及多卷的卷板材料。电泳漆膜的厚 度可通过控制电压及时间及其他条件保证。  The apparatus of the present invention can simultaneously electrophoreize single-roll and multi-rolled coil materials. The thickness of the electrophoretic paint film can be guaranteed by controlling the voltage and time and other conditions.

实施例 2: 平面横向阳极电泳工艺时:  Example 2: In the case of a planar lateral anodic electrophoresis process:

卷板材料工件为被电泳件, 为阳极系统, 接电泳源的正极(+)。 阴极系统接电源负极(-)。 阴极是固定式连接, 阳极使用有弹性金属 材料压接或者夹接,但不能影响工件的连续走动。将卷板材料工件平 行通过电泳槽的电泳漆溶液中,将卷板材料工件穿过电泳槽的两个平 行的槽孔。开动移动输送电源, 让卷板工件平行移动。卷板材料工件 通过整平机时, 通过整平使工件平整均匀, 向下道工序输送工件。卷 板材料工件通过定位机时, 通过定位使工件上下, 左右保持一致, 定 位后向下道工序输送工件。卷板材料工件通过前处理机时,可根据不 同的卷板材质采取不同的处理方式。同时也可根据材质不同的表面污 染程度采取不同的处理方式。 前处理方式与实施例 1相同。  The workpiece of the coil material is an electrophoresis member, which is an anode system and is connected to the positive electrode (+) of the electrophoresis source. The cathode system is connected to the negative (-) power supply. The cathode is a fixed connection, and the anode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece. The workpiece of the coil material is passed through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two parallel slots of the electrophoresis tank. Start moving the power supply and let the coil workpiece move in parallel. Rolling material workpiece When the leveling machine is passed, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process. When the workpiece of the coil material passes through the positioning machine, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning. When the workpiece of the coil material passes through the pretreatment machine, different treatment methods can be adopted according to different coil materials. At the same time, different treatment methods can be adopted according to the degree of surface contamination of different materials. The pretreatment method is the same as that of the first embodiment.

开动动力循环泵,抽动电泳储槽的电泳漆, 让工件全部浸没于电 泳漆中。同时电泳主槽上在阳极系统的上面开有溢流口管路, 多余电 泳漆可以从此溢流口管路流出,流入到电泳储槽, 以防止因动力泵的 输送量过大, 造成满槽现象。此溢流口管路开于侧面或其他位置, 但 不能影响电泳过程, 只要不造成满槽现象同时又能连续供应电泳涂 料, 让电泳工件全部浸入电泳漆中即可。开通电泳电源进行电泳。卷 板材料工件离开电泳槽后,用超滤水或纯水冲洗工件其表面,冲洗掉 表面浮漆。 将卷板材料平行进入烘烤机 18烘烤, 电泳漆膜流平及固 化。 卷板材料工件离开烘箱后, 用冷气强制冷却。 卷板材料工 19件 冷却干燥后, 即可以成卷包装。  Start the power circulation pump and twitch the electrophoretic paint of the electrophoresis storage tank so that the workpiece is completely immersed in the electrophoretic paint. At the same time, the main channel of the electrophoresis has an overflow port on the upper part of the anode system, and the excess electrophoretic paint can flow out from the overflow port and flow into the electrophoresis storage tank to prevent the large amount of the power pump from being delivered. phenomenon. The overflow pipe is open to the side or other position, but it does not affect the electrophoresis process. As long as the full tank is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint. The electrophoresis power source is turned on for electrophoresis. After leaving the electrophoresis tank, the workpiece of the coil material is washed with ultrafiltration water or pure water to rinse off the surface of the workpiece. The coil material is baked in parallel into the baking machine 18, and the electrophoretic paint film is leveled and solidified. After the coil material workpiece leaves the oven, it is forced to cool with cold air. 19 materials for coiling materials. After cooling and drying, they can be packaged in rolls.

实施例 3 :竖立纵向阴极电泳工艺时:卷板材料工件为被电泳件, 为阴极系统, 接电泳源的负极( -)。 阳极系统接电源正极( + )。 阳极 是固定式连接, 阴极使用有弹性金属材料压接或者夹接,但不能影响 工件的连续走动。如图 2所示:将卷板材料工件竖立纵向通过电泳槽 的电泳漆溶液中, 将卷板材料工件穿过电泳槽的两个竖立纵向的槽 孔。幵动移动输送电源, 让卷板工件竖立纵向移动。卷板材料工件通 过整平机时, 通过整平使工件平整均匀, 向下道工序输送工件。卷板 材料工件通过定位机时, 通过定位使工件上下, 左右保持一致, 定位 后向下道工序输送工件。卷板材料工件通过前处理机时, 可根据不同 的卷板材质采取不同的处理方式。同时也可根据材质不同的表面污染 程度釆取不同的处理方式。 前处理方式与实施例 1相同。 Embodiment 3: When the vertical cathodic electrophoresis process is erected: the workpiece of the coil material is an electrophoresis member, For the cathode system, connect the negative electrode (-) of the electrophoresis source. The anode system is connected to the positive pole of the power supply ( + ). The anode is a fixed connection, and the cathode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece. As shown in FIG. 2, the workpiece of the coil material is vertically erected through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two vertical longitudinal slots of the electrophoresis tank. Move the conveyor power supply to move the coiled workpiece upright. When the workpiece of the coil material passes through the leveling machine, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process. When the workpiece of the coil material passes through the positioning machine, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning. When the workpiece of the coil material passes through the pretreatment machine, different treatment methods can be adopted according to different coil materials. At the same time, different treatment methods can be adopted according to the degree of surface contamination of different materials. The pretreatment method is the same as that of the first embodiment.

开动动力循环泵 8, 抽动电泳储槽的电泳漆, 让工件全部浸没于 电泳漆中, 同时电泳主槽上在阴极系统的上面开有溢流口管路, 多余 电泳漆可以从此溢流口管路流出,流入到电泳储槽, 以防止因动力泵 的输送量过大, 造成满槽现象。 此溢流口管路开于侧面或其他位置, 但不能影响电泳过程,只要不造成满槽现象同时又能连续供应电泳涂 料, 让电泳工件全部浸入电泳漆中即可。开通电泳电源进行电泳。工 件离开电泳槽后,用超滤水或纯水冲洗工件其表面,冲洗掉表面浮漆。 将卷板材料工件纵向进入烘烤机 18烘烤, 电泳漆膜流平及固化。 将 卷板材料工件工件离开烘箱后,用冷气强制冷却。卷板材料工件冷却 干燥后, 即可以成卷包装。  The power circulation pump 8 is started, the electrophoresis paint of the electrophoresis storage tank is twitched, and the workpiece is completely immersed in the electrophoretic paint. At the same time, the main channel of the electrophoresis has an overflow port on the cathode system, and the excess electrophoretic paint can be discharged from the overflow pipe. The road flows out and flows into the electrophoresis storage tank to prevent the tank from being over-sized due to excessive power transmission. The overflow pipe is open to the side or other position, but it cannot affect the electrophoresis process. As long as the full-slot phenomenon is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint. The electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface varnish. The workpiece of the coil material is longitudinally baked into the baking machine 18 to be baked, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the sheet material is cooled, it can be packaged in rolls.

实施例 4: 竖立纵向阳极电泳工艺时:  Example 4: When erecting the longitudinal anodic electrophoresis process:

将卷板材料工件为被电泳件,为阳极系统,接电泳源的正极(+)。 阴极系统接电源负极(-)。 阴极是固定式连接, 阳极使用有弹性金属 材料压接或者夹接, 但不能影响工件的连续走动。如图 4所示: 将卷 板材料工件竖立纵向通过电泳槽的电泳漆溶液中,将卷板材料工件穿 过电泳槽的两个竖立纵向的槽孔。开动移动输送电源,让卷板工件竖 立纵向移动。卷板材料工件通过整平机时,通过整平使工件平整均匀, 向下道工序输送工件。卷板材料工件通过定位机时,通过定位使工件 上下, 左右保持一致, 定位后向下道工序输送工件。卷板材料工件通 过前处理机时,可根据不同的卷板材质采取不同的处理方式。同时也 可根据材质不同的表面污染程度采取不同的处理方式。前处理方式与 实施例 1相同。 The workpiece of the coil material is an electrophoresis member, which is an anode system, and is connected to the positive electrode (+) of the electrophoresis source. The cathode system is connected to the negative (-) power supply. The cathode is a fixed connection, and the anode is crimped or clamped with a resilient metal material, but does not affect the continuous movement of the workpiece. As shown in FIG. 4: The workpiece of the coil material is erected longitudinally through the electrophoretic paint solution of the electrophoresis tank, and the workpiece of the coil material is passed through two vertical longitudinal slots of the electrophoresis tank. Start moving the power supply and let the coiled workpiece move vertically. When the workpiece of the coil material passes through the leveling machine, the workpiece is leveled evenly by leveling, and the workpiece is conveyed in the next process. When the workpiece of the coil material passes through the positioning machine, the workpiece is moved up and down by positioning, and the workpiece is conveyed in the next process after positioning. When the workpiece of the coil material passes through the pretreatment machine, different treatment methods can be adopted according to different coil materials. Meanwhile also Different treatment methods can be adopted according to the degree of surface contamination of different materials. The pretreatment method is the same as that of the first embodiment.

开动动力循环泵,抽动电泳储槽的电泳漆,让工件全部浸没于电 泳漆中, 同时电泳主槽上在阴极系统的上面开有溢流口管路,多余电 泳漆可以从此溢流口管路流出,流入到电泳储槽, 以防止因动力泵的 输送量过大, 造成满槽现象。此溢流口管路开于侧面或其他位置, 但 不能影响电泳过程, 只要不造成满槽现象同时又能连续供应电泳涂 料, 让电泳工件全部浸入电泳漆中即可。开通电泳电源进行电泳。工 件离开电泳槽后,用超滤水或纯水冲洗工件其表面,冲洗掉表面浮漆。 将卷板材料工件纵向进入烘烤机 18烘烤, 电泳漆膜流平及固化。 将 卷板材料工件工件离开烘箱后,用冷气强制冷却。卷板材料工件冷却 干燥后, 即可以成卷包装。  The power circulation pump is started, the electrophoresis paint of the electrophoresis storage tank is twitched, and the workpiece is completely immersed in the electrophoretic paint. At the same time, the main channel of the electrophoresis has an overflow port on the cathode system, and the excess electrophoretic paint can be drained from the overflow port. It flows out and flows into the electrophoresis storage tank to prevent the tank from being over-sized due to excessive power transmission. The overflow pipe is open to the side or other position, but it does not affect the electrophoresis process. As long as the full tank is not caused and the electrophoretic coating can be continuously supplied, the electrophoresis workpiece can be completely immersed in the electrophoretic paint. The electrophoresis power source is turned on for electrophoresis. After the workpiece leaves the electrophoresis tank, rinse the surface of the workpiece with ultra-filtered water or pure water to rinse off the surface varnish. The workpiece of the coil material is longitudinally baked into the baking machine 18 to be baked, and the electrophoretic paint film is leveled and solidified. After the workpiece of the coil material is removed from the oven, it is forced to cool with cold air. After the sheet material is cooled, it can be packaged in rolls.

上述实施例用来解释说明此发明, 而不是对本发明进行限制, 在 本发明的精神和权利要求的保护范围内,对本发明作出任何修改和改 变, 都落入本发明而保护范围。  The above-mentioned embodiments are intended to be illustrative of the invention, and are not intended to limit the scope of the invention, and any modifications and changes may be made without departing from the scope of the invention.

Claims

权 利 要 求 书 Claim 1、 一种卷板材料的电泳涂装技术方法, 它采用阴极电泳工艺或 阳极电泳工艺, 具体包括以下步骤:  1. A method for electrophoretic coating of a coil material, which adopts a cathodic electrophoresis process or an anodic electrophoresis process, and specifically comprises the following steps: ( 1 )将卷板材料与导电装置连接作为阴极或阳极系统, 导电装置 接电泳电源的负极或正极; 电泳装置阳极或阴极接电源正极或负极 作为阳极或阴极系统;  (1) connecting the coil material and the conductive device as a cathode or anode system, the conductive device is connected to the negative electrode or the positive electrode of the electrophoresis power source; the anode or the cathode of the electrophoresis device is connected to the positive electrode or the negative electrode of the power source as an anode or a cathode system; ( 2 ) 将卷板材料工件平行或纵向通过电泳槽的电泳漆溶液中; (2) passing the workpiece of the coil material in parallel or longitudinally through the electrophoretic paint solution of the electrophoresis tank; (3) 开通电泳电源进行电泳; (3) Turn on the electrophoresis power supply for electrophoresis; (4) 卷板材料工件离开电泳槽后, 用水冲洗工件表面, 冲洗掉表 面浮漆;  (4) After the workpiece of the coil material leaves the electrophoresis tank, rinse the surface of the workpiece with water and rinse off the surface floating paint; (5) 将卷板材料工件平行或纵向进入烘箱烘烤, 使电泳漆膜流平 及固化;  (5) The workpiece of the coil material is baked in parallel or longitudinally into the oven to make the electrophoretic paint film level and solidify; (6) 卷板材料工件离开烘箱后, 用冷气强制冷却、 干燥后, 收成 卷包装。  (6) After the workpiece of the coiled material leaves the oven, it is forced to cool with cold air, dried, and then packed into a roll. 2、 根椐权利要求 1所述的卷板材料的电泳涂装技术方法, 其中 所述的卷板材料为金属或非金属经处理变为导电体的卷板材料。  2. The method of electrophoretic coating of a coil material according to claim 1, wherein the coil material is a coil material which is treated to become a conductor by metal or nonmetal. 3、 根椐权利要求 1或 2所述的卷板材料的电泳涂装技术方法, 其中所述的卷板材料为铁板、 钢板、 铜板、 锌板或铝板。  3. The electrophoretic coating technique of the coil material according to claim 1 or 2, wherein the coil material is iron plate, steel plate, copper plate, zinc plate or aluminum plate. 4、 根椐权利要求 1或 2所述的卷板材料的电泳涂装技术方法, 其中所述的卷板材料为纤维板或塑料板。  4. The method of electrophoretic coating of a coil material according to claim 1 or 2, wherein the coil material is a fiberboard or a plastic sheet. 5、 根椐权利要求 1所述的卷板材料的电泳涂装技术方法, 其中 电泳过程中使用的电泳涂料包含聚丁二烯树脂、酚醛树脂、环氧树脂, 丙烯酸或聚胺脂。  5. The electrophoretic coating method of the coil material according to claim 1, wherein the electrophoretic coating used in the electrophoresis process comprises a polybutadiene resin, a phenol resin, an epoxy resin, an acrylic acid or a polyurethane. 6、 根椐权利要求 1或 5所述的卷板材料的电泳涂装技术方法, 其中电泳过程中使用的电泳涂料包含无色透明、哑光无色或各类彩色 涂料, 以及闪光色、 珠光色和添加有染料或颜料的电泳涂料。  6. The electrophoretic coating method of the coil material according to claim 1 or 5, wherein the electrophoretic coating used in the electrophoresis process comprises colorless transparent, matte colorless or various color paints, and glitter color and pearl light. Color and electrophoretic coatings with dyes or pigments added. 7、 根椐权利要求 1或 5所述的卷板材料的电泳涂装技术方法, 其中所述的电泳涂料中添加有填料及增强电泳涂料性能的助剂。  7. The electrophoretic coating method according to claim 1 or 5, wherein the electrophoretic coating is provided with a filler and an auxiliary agent for enhancing the performance of the electrophoretic coating. 8、 根椐权利要求 1或 5所述的卷板材料的电泳涂装技术方法, 其中电泳过程中使用的电泳涂料包含热固性或光敏性电泳涂料。 8. The electrophoretic coating technique of the coil material according to claim 1 or 5, The electrophoretic coating used in the electrophoresis process comprises a thermosetting or photosensitive electrophoretic coating. 9、 根椐权利要求 1所述的卷板材料的电泳涂装技术方法, 其中 在阴极电泳工艺中所用阳极板的材料或在阳极电泳工艺中所用的阴 极板的材料为不锈钢、铁件、铝件、铜件或非金属材料金属化处理可 导电的导体件, 其形状为板式系统、 管式系统或裸露极板。  9. The electrophoretic coating method according to claim 1, wherein the material of the anode plate used in the cathodic electrophoresis process or the material of the cathode plate used in the anodic electrophoresis process is stainless steel, iron, aluminum. Pieces, copper or non-metallic materials metallize the electrically conductive conductor members in the form of plate systems, tubular systems or bare plates. 10、一种卷板材料的电泳涂装成套设备,它包括放卷机和收卷机, 其特征是: 放卷机和收卷机之间设有电泳设备装置。  10. An electrophoretic coating apparatus for a coil material, comprising a unwinder and a winder, wherein: an electrophoresis device is disposed between the unwinder and the winder. 11、 根据权利要求 10所述的卷板材料的电泳涂装成套设备, 其 特征是:所述电泳设备装置包含电泳主槽和电泳储槽, 电泳主槽前端 装有导电装置,导电装置与卷板材料连接。  11. The electrophoretic coating device of the coil material according to claim 10, wherein the electrophoresis device comprises an electrophoresis main tank and an electrophoresis storage tank, and the electrophoresis main tank front end is provided with a conductive device, the conductive device and the coil. Board material connection. 12、根据权利要求 10或 11所述的卷板材料的电泳涂装成套设备, 其特征是: 所述电泳主槽放在电泳储槽的里面, 是大槽套小槽形状, 电泳主槽上有平行或纵向的槽孔,可以通过卷板材料,平行槽孔的上 面和下面或者纵向槽孔的左面和右面有阳极或阴极系统,平行槽孔或 者纵向槽孔两边装有引流板,电泳储槽上装有的动力泵通过输送管连 接到电泳主槽, 电泳主槽上装有溢流管, 溢流管与电泳储槽连接。  The apparatus for electrophoretic coating of a coil material according to claim 10 or 11, wherein: the electrophoresis main tank is placed inside the electrophoresis storage tank, and is in the shape of a large trough sleeve, and is electrophoresed on the main tank. There are parallel or longitudinal slots, which can pass through the coil material, the upper and lower sides of the parallel slot or the left and right sides of the longitudinal slot have an anode or cathode system, and the parallel slot or the longitudinal slot is provided with a drainage plate on both sides, and the electrophoresis storage The power pump installed in the tank is connected to the electrophoresis main tank through a conveying pipe, and an overflow pipe is arranged on the electrophoresis main tank, and the overflow pipe is connected with the electrophoresis storage tank. 13、根据权利要求 10或 11所述的卷板材料的电泳涂装成套设备, 其特征是:所述电泳主槽与电泳储槽是分幵独立的结构,采用双槽或 多槽结构, 电泳主槽上有平行或纵向的槽孔, 可以通过卷板材料,平 行槽孔的上面和下面或者纵向槽孔的左面和右面有阳极或阴极系统, 平行槽孔或者纵向槽孔两边装有引流板,在卷板材料通过的方向电泳 主槽下面设有收集小槽,收集小槽上装有管道,管道与电泳储槽连接, 电泳储槽上装有的动力泵通过输送管连接到电泳主槽,电泳主槽上装 有溢流管, 溢流管与电泳储槽连接。  The electrophoretic coating equipment for a coil material according to claim 10 or 11, wherein the electrophoresis main tank and the electrophoresis storage tank are separate structures, and the double-slot or multi-slot structure is used for electrophoresis. The main groove has parallel or longitudinal slots, which can pass through the coil material, the upper and lower sides of the parallel slot or the left and right sides of the longitudinal slot have an anode or cathode system, and the parallel slot or the longitudinal slot is provided with a deflector A collecting small groove is arranged under the main electrophoresis groove in the direction of the coil material passing through, and a collecting pipe is arranged on the small groove, and the pipe is connected with the electrophoresis storage tank, and the power pump installed on the electrophoresis storage tank is connected to the electrophoresis main tank through the conveying pipe, and electrophoresis The main tank is provided with an overflow pipe, and the overflow pipe is connected with the electrophoresis storage tank. 14、根据权利要求 10或 11所述的卷板材料的电泳涂装成套设备, 其特征是:所述放卷机和收卷机之间设有压平机、定位机、前处理机、 水洗机和烘烤机。  The electrophoretic coating equipment for a coil material according to claim 10 or 11, wherein the unwinder and the winder are provided with a flattening machine, a positioning machine, a pretreatment machine, and a water washing machine. Machine and baking machine.
PCT/CN2007/001597 2007-01-18 2007-05-16 Electro-phoretic paingting method and integrated equipment for strip of sheet Ceased WO2008089609A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200710051306.X 2007-01-18
CNB200710051306XA CN100503900C (en) 2007-01-18 2007-01-18 Electrophoretic coating technology method and complete set of equipment for coil materials

Publications (1)

Publication Number Publication Date
WO2008089609A1 true WO2008089609A1 (en) 2008-07-31

Family

ID=38888954

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2007/001597 Ceased WO2008089609A1 (en) 2007-01-18 2007-05-16 Electro-phoretic paingting method and integrated equipment for strip of sheet

Country Status (2)

Country Link
CN (1) CN100503900C (en)
WO (1) WO2008089609A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111983000A (en) * 2020-08-29 2020-11-24 恒硕(唐山)科技有限公司 Liquid cooling type electrophoresis tank
CN114574921A (en) * 2022-03-15 2022-06-03 阳江市鼎华晟新材料科技有限公司 Fingerprint-resistant plate rolling automatic production line

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105316746A (en) * 2014-06-27 2016-02-10 天津市鑫泰旺金属制品有限公司 Metal wire material electrophoresis device
CN104532325B (en) * 2014-12-31 2017-08-29 天津市天玉名涂料科技有限公司 A kind of electrophoretic coating device of the floating paint of automatic cleaning electrophoresis
CN105603494A (en) * 2016-01-27 2016-05-25 南通彩都新能源科技有限公司 Electrophoretic deposition system and method for preparing silicon-based anode material of lithium ion battery
CN109822064B (en) * 2019-04-09 2021-01-29 中冶赛迪工程技术股份有限公司 Method for growing inorganic coating on the surface of copper plate of continuous casting mold

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1385860A (en) * 1972-07-27 1975-03-05 Canada Wire & Cable Co Ltd Electrocoating process and apparatus
US4083763A (en) * 1968-07-08 1978-04-11 Nippon Steel Corporation Method for manufacturing colored metal sheets
JP2003213493A (en) * 2002-01-22 2003-07-30 Goto Denshi Kk Cationic electrodeposition coating system for electric wire
EP1741806A1 (en) * 2005-07-08 2007-01-10 Höllmüller Maschinenbau GmbH Apparatus and process for electroplating treatment of foils from roller to roller

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4083763A (en) * 1968-07-08 1978-04-11 Nippon Steel Corporation Method for manufacturing colored metal sheets
GB1385860A (en) * 1972-07-27 1975-03-05 Canada Wire & Cable Co Ltd Electrocoating process and apparatus
JP2003213493A (en) * 2002-01-22 2003-07-30 Goto Denshi Kk Cationic electrodeposition coating system for electric wire
EP1741806A1 (en) * 2005-07-08 2007-01-10 Höllmüller Maschinenbau GmbH Apparatus and process for electroplating treatment of foils from roller to roller

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111983000A (en) * 2020-08-29 2020-11-24 恒硕(唐山)科技有限公司 Liquid cooling type electrophoresis tank
CN111983000B (en) * 2020-08-29 2022-08-16 恒硕(唐山)科技有限公司 Liquid cooling type electrophoresis tank
CN114574921A (en) * 2022-03-15 2022-06-03 阳江市鼎华晟新材料科技有限公司 Fingerprint-resistant plate rolling automatic production line

Also Published As

Publication number Publication date
CN100503900C (en) 2009-06-24
CN101037788A (en) 2007-09-19

Similar Documents

Publication Publication Date Title
WO2008089608A1 (en) Method for electrophoretically coating a wire and apparatus for implementing the method
WO2008089609A1 (en) Electro-phoretic paingting method and integrated equipment for strip of sheet
CN100564606C (en) Apparatus for continuous electrodepositing of metallic film and method thereof
CN103924225A (en) High tin bronze plating solution for chemical plating of surface of tempered bead wire, and its chemical dip plating method
CN109518131A (en) A kind of ultrathin copper foil with carrier, ultrathin copper foil production method and device
US3718547A (en) Continuous electrolytic treatment for cleaning and conditioning aluminum surfaces
CN104480499A (en) Nickel electroplating method adopting ionic liquid
CN103409783B (en) A kind of method of aluminium alloy BSL102 sulphuric acid anodizing
CN107630241B (en) Can continuous production anti-finger print steel plate processing method
US7678242B2 (en) System and method for manufacturing flexible copper clad laminate film
CN103361663A (en) Ultrasonic descaling method of steel wires
CN114381781A (en) Surface coating process for radiator for transformer
CN106283157A (en) Method and system for workpiece surface treatment
CN108707950B (en) An all-round electrophoretic coating device for automobile shell production
CN108166032A (en) A kind of high-speed plating mist nickel electroplating technology
CN210117413U (en) Silane pretreatment device for electrophoretic coating
CN217230989U (en) Electroplating oiling unit for fingerprint-resistant rolled plate
US4128459A (en) Continuous electroplating of alloy onto metallic strip
CN104846410A (en) Method for electroplating nickel on brass and red copper alloy
CN206872971U (en) A kind of intelligent multi-function the electrophoresis paint of aluminium profile system
CN102534443B (en) Production process for improving strength of aluminum profile
CN106702468B (en) A method for efficient and continuous preparation of metal thin films with an equipotential vertical fully immersed cathode
DE10318933A1 (en) Electro dip painting process and continuous system for its implementation
CN209722336U (en) A kind of aluminium alloy extrusions electrophoretic paint recirculation system
CN114438571A (en) Nodular cast iron pipe fitting coating structure and preparation method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07721170

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 07721170

Country of ref document: EP

Kind code of ref document: A1