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WO2008083600A8 - An integrated coal liquefaction process - Google Patents

An integrated coal liquefaction process

Info

Publication number
WO2008083600A8
WO2008083600A8 PCT/CN2007/071380 CN2007071380W WO2008083600A8 WO 2008083600 A8 WO2008083600 A8 WO 2008083600A8 CN 2007071380 W CN2007071380 W CN 2007071380W WO 2008083600 A8 WO2008083600 A8 WO 2008083600A8
Authority
WO
WIPO (PCT)
Prior art keywords
coal
carbon monoxide
carbonylation
liquefaction
liquefaction process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2007/071380
Other languages
French (fr)
Chinese (zh)
Other versions
WO2008083600A1 (en
Inventor
Rocco Fiato
Youqi Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Accelergy Corp
Original Assignee
Accelergy Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Accelergy Corp filed Critical Accelergy Corp
Publication of WO2008083600A1 publication Critical patent/WO2008083600A1/en
Publication of WO2008083600A8 publication Critical patent/WO2008083600A8/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

An integrated coal liquefaction process includes a coal gasification step (201), a Fischer-Tropsch synthesis step (203), a coal carbonylation step (207) and a coal direct liquefaction step (209), wherein the carbon monoxide consumption during water gas shift conversion reaction in the Fischer-Tropsch synthesis step (203) is less than 5%. The carbon monoxide in the synthesis gas produced from the coal gasification step (201) or t he carbon monoxide in the tail gas produced from the synthesis gas converting step (203) are used in the coal carbonylation step (207). The pretreated coal from the coal carbonylation step (207) is subjected to hydrogenation liquefaction in the coal direct liquefaction step (209). Applying recovered carbon monoxide to carbonylation reaction of feed coal can reduce the carbon dioxide emission of the liquefaction process, and simultaneously increase the utilization rate of carbon.
PCT/CN2007/071380 2006-12-30 2007-12-29 An integrated coal liquefaction process Ceased WO2008083600A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200610173377 2006-12-30
CN200610173377.2 2006-12-30

Publications (2)

Publication Number Publication Date
WO2008083600A1 WO2008083600A1 (en) 2008-07-17
WO2008083600A8 true WO2008083600A8 (en) 2008-09-18

Family

ID=39608356

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2007/071380 Ceased WO2008083600A1 (en) 2006-12-30 2007-12-29 An integrated coal liquefaction process

Country Status (2)

Country Link
CN (1) CN101270294A (en)
WO (1) WO2008083600A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2326417A1 (en) * 2008-09-10 2011-06-01 Basf Se Integrated method for producing carbonyl iron powder and hydrocarbons
AU2009301573B2 (en) * 2008-10-09 2013-09-26 Synfuels China Technology Co., Ltd. Method and equipment for multistage liquefying of carbonaceous solid fuel
US9074139B2 (en) * 2011-12-07 2015-07-07 IFP Energies Nouvelles Process for coal conversion comprising at least one step of liquefaction for the manufacture of aromatics
CN104232139B (en) * 2013-06-07 2016-12-07 中国海洋石油总公司 A kind of method being produced methane coproduction liquid fuel by carbonaceous material

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR820001970B1 (en) * 1979-05-12 1982-10-22 지. 엠 비네가르 Combination coal liquefaction-gasification process
US5151173A (en) * 1989-12-21 1992-09-29 Exxon Research And Engineering Company Conversion of coal with promoted carbon monoxide pretreatment
US5336395A (en) * 1989-12-21 1994-08-09 Exxon Research And Engineering Company Liquefaction of coal with aqueous carbon monoxide pretreatment
US5200063A (en) * 1990-06-21 1993-04-06 Exxon Research And Engineering Company Coal hydroconversion process comprising solvent enhanced pretreatment with carbon monoxide
JPH0532976A (en) * 1991-06-28 1993-02-09 Exxon Res & Eng Co Coal extraction hydroconversion process involving solvent-enhanced carbon monoxide pretreatment
WO2006070018A1 (en) * 2004-12-30 2006-07-06 Shell Internationale Research Maatschappij B.V. Improvements relating to coal to liquid processes

Also Published As

Publication number Publication date
WO2008083600A1 (en) 2008-07-17
CN101270294A (en) 2008-09-24

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