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WO2008078055A3 - Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations - Google Patents

Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations Download PDF

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Publication number
WO2008078055A3
WO2008078055A3 PCT/FR2007/052589 FR2007052589W WO2008078055A3 WO 2008078055 A3 WO2008078055 A3 WO 2008078055A3 FR 2007052589 W FR2007052589 W FR 2007052589W WO 2008078055 A3 WO2008078055 A3 WO 2008078055A3
Authority
WO
WIPO (PCT)
Prior art keywords
preparation
same
methacrylate units
copolymers based
units
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2007/052589
Other languages
English (en)
Other versions
WO2008078055A9 (fr
WO2008078055A2 (fr
Inventor
Laurence Couvreur
Stephanie Magnet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to US12/520,672 priority Critical patent/US8389643B2/en
Priority to EP07872000A priority patent/EP2113000A2/fr
Priority to JP2009542165A priority patent/JP2010513648A/ja
Publication of WO2008078055A2 publication Critical patent/WO2008078055A2/fr
Publication of WO2008078055A3 publication Critical patent/WO2008078055A3/fr
Anticipated expiration legal-status Critical
Publication of WO2008078055A9 publication Critical patent/WO2008078055A9/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention a trait à un procédé de préparation d'un copolymère comprenant un squelette à base d'unités méthacrylates comprenant une étape de polymérisation d'un ou plusieurs monomères méthacrylates précurseurs desdites unités en présence: d'un amorceur de polymérisation; d'au moins un agent de transfert du type «RAFT» susceptible de générer un radical primaire; et d'au moins un comonomère choisi notamment parmi les monomères styréniques, les monomères acrylates. L'invention concerne également les copolymères susceptibles d'être obtenus selon ce procédé, notamment les copolymères blocs et leurs utilisations comme additifs de matières plastiques.
PCT/FR2007/052589 2006-12-22 2007-12-20 Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations Ceased WO2008078055A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/520,672 US8389643B2 (en) 2006-12-22 2007-12-20 Copolymers based on methacrylate units, preparation method thereof and use of same
EP07872000A EP2113000A2 (fr) 2006-12-22 2007-12-20 Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations
JP2009542165A JP2010513648A (ja) 2006-12-22 2007-12-20 メタクリレート単位に基づくコポリマー、その調製方法及びその用途

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0655926 2006-12-22
FR0655926A FR2910475B1 (fr) 2006-12-22 2006-12-22 Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations
US93914107P 2007-05-21 2007-05-21
US60/939,141 2007-05-21

Publications (3)

Publication Number Publication Date
WO2008078055A2 WO2008078055A2 (fr) 2008-07-03
WO2008078055A3 true WO2008078055A3 (fr) 2008-11-06
WO2008078055A9 WO2008078055A9 (fr) 2009-09-17

Family

ID=38330477

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2007/052589 Ceased WO2008078055A2 (fr) 2006-12-22 2007-12-20 Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations

Country Status (6)

Country Link
US (1) US8389643B2 (fr)
EP (1) EP2113000A2 (fr)
JP (1) JP2010513648A (fr)
FR (1) FR2910475B1 (fr)
TW (1) TW200838882A (fr)
WO (1) WO2008078055A2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2931154B1 (fr) 2008-05-14 2011-04-08 Univ Paris Curie Copolymere amphiphile a blocs, procede pour sa preparation
KR101093676B1 (ko) * 2009-08-07 2011-12-15 세종대학교산학협력단 올레핀계 분절 공중합체의 제조 방법
GB201003970D0 (en) * 2010-03-10 2010-04-21 Univ Sheffield Polymer synthesis
WO2012061021A1 (fr) * 2010-11-04 2012-05-10 3M Innovative Properties Company Composition fluorée comprenant un groupe acide contenant du phosphore et un groupe alcoxysilane
US20150005442A1 (en) * 2012-02-03 2015-01-01 Dsm Ip Assets B.V. Polymer, process and composition
EP2634198B1 (fr) * 2012-03-02 2014-09-17 Suntech Co., Ltd. Copolymères contenant des groupes phosphorylcholines et leurs procédés de préparation et d'utilisation
CN102924503B (zh) * 2012-11-06 2016-03-09 上海交通大学 一种含有硅烷的raft链转移试剂及其制备与应用
CN104262542A (zh) * 2014-09-30 2015-01-07 山东瑞丰高分子材料股份有限公司 Acr 的制备方法
KR101735453B1 (ko) * 2014-12-16 2017-05-15 경북대학교 산학협력단 초임계 유체에서 흑연의 박리를 위한 고분자 분산제 및 이로부터 제조된 그래핀 분산액
CN104558325B (zh) * 2014-12-30 2017-10-20 华侨大学 一种可聚合的组合物及用此组合物制备聚乙烯基吡啶的方法
CN105085846B (zh) * 2015-09-06 2018-01-26 中国科学院长春应用化学研究所 一种嵌段共聚物及其制备方法
KR102387338B1 (ko) * 2016-03-14 2022-04-15 아이에스피 인베스트먼츠 엘엘씨 컨디셔닝, 색상 보호 및 스타일링 중합체를 포함하는 케라틴 기재용 개인 관리 조성물
CN108912288B (zh) 2018-05-17 2020-10-16 浙江大学 一种高熔融指数的热塑性弹性体及其制备方法
CN112442150B (zh) * 2019-08-30 2022-09-20 中国石油化工股份有限公司 一种高分子聚合物及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030060577A1 (en) * 2001-03-20 2003-03-27 Rensselaer Polytechnic Institute Transition metal superoxides
US20040106732A1 (en) * 2001-04-04 2004-06-03 Ryotaro Tsuji Thermoplastic resin composition and elastomer composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998001478A1 (fr) * 1996-07-10 1998-01-15 E.I. Du Pont De Nemours And Company Polymerisation presentant des caracteristiques vivantes
IL139666A0 (en) * 1997-07-21 2002-02-10 Commw Scient Ind Res Org Synthesis of dithioester chain transfer agents and use of bis (thioacyl) disulfides or dithioesters as chain transfer agents
JP2003012934A (ja) * 2001-06-26 2003-01-15 Kanegafuchi Chem Ind Co Ltd 熱可塑性樹脂用加工性改良剤及びそれを含む熱可塑性樹脂組成物
JP2003128712A (ja) * 2001-10-19 2003-05-08 Mitsubishi Rayon Co Ltd メタクリル樹脂及びその製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030060577A1 (en) * 2001-03-20 2003-03-27 Rensselaer Polytechnic Institute Transition metal superoxides
US20040106732A1 (en) * 2001-04-04 2004-06-03 Ryotaro Tsuji Thermoplastic resin composition and elastomer composition

Also Published As

Publication number Publication date
TW200838882A (en) 2008-10-01
WO2008078055A9 (fr) 2009-09-17
FR2910475A1 (fr) 2008-06-27
WO2008078055A2 (fr) 2008-07-03
JP2010513648A (ja) 2010-04-30
US20100069577A1 (en) 2010-03-18
FR2910475B1 (fr) 2009-02-20
EP2113000A2 (fr) 2009-11-04
US8389643B2 (en) 2013-03-05

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