WO2008075505A1 - Heat-resistant bound double woven fabric and garment and heat-resistant glove comprising the same - Google Patents

Abstract

A heat-resistant bound double woven fabric which comprises: two ground weave layers (10 and 20) constituting upper and lower layers and each formed from warps and wefts; and binding yarns (1a and 1b) which connect the two upper and lower ground weave layers (10 and 20). At least one of the two upper and lower ground weave layers (10 and 20) is constituted of heat-resistant fiber yarns, and the binding yarns (1a and 1b) are constituted of fancy twisted yarns having loops. Also provided is a garment part or all of which comprises the heat-resistant bound double woven fabric and in which the ground weave layer constituted of the heat-resistant fiber yarns is disposed on the outer side. Furthermore provided is a glove which has the heat-resistant bound double woven fabric united to the grasp side and in which the ground weave layer constituted of the heat-resistant fiber yarns is disposed on the outer side. The heat-resistant bound double woven fabric is high in heat-insulating properties, heat resistance, flameproofness, flame retardancy, and protective properties. The garment and heat-resistant glove employ this fabric.

Description

 Specification

 Heat-resistant binding Double woven fabric and clothing and heat-resistant gloves

 Technical field

 [0001] The present invention relates to a heat-resistant, double-woven fabric with high heat insulation, heat resistance, flame resistance, and flame retardancy, and clothing and heat-resistant gloves using the same.

 Background art

 [0002] Two upper and lower ground texture layers composed of warps and wefts, and a bonded double woven fabric in which the two upper and lower ground texture layers are connected by a binding yarn, are known as materials for napped fabrics, usually called moquette fabrics. It is. In other words, after weaving using a moquette weaving machine, cutting the binding yarn into two cut pile fabrics, arranging the nappings and using them as car seats, vehicle seat sheets, sofa seats, etc. Patent literature;! ~ 3).

 [0003] On the other hand, heat-resistant clothing and gloves are required from the viewpoint of safety in welding work such as arc welding, pre-furnace work such as a blast furnace, and work involving high-temperature objects such as cooking. In addition, fire-resistant clothing is required to have heat resistance. Conventionally, heat-resistant gloves and fire fighting clothing are made using heat-resistant fibers such as aramid fiber, polybenzimidazole fiber, polybenzoxazole fiber, polybenzazole fiber, polyamideimide fiber, melamine fiber and polyimide fiber. This has been proposed (for example, Non-Patent Document 1, Patent Document 1). Non-Patent Document 1 describes that fire-fighting clothing uses 95% meta-aramid fibers for flameproofing and workability, and 5% para-aramid fibers for dimensional stability and prevention of shrinkage. Yes. Patent Document 4 describes that a glove is knitted using a single amide fiber yarn, and a synthetic resin is heat-sealed to the palm portion.

 Patent Document 1: Japanese Patent Laid-Open No. 2005-154952

 Patent Document 2: Japanese Patent Laid-Open No. 10-130992

 Patent Document 3: Japanese Patent Laid-Open No. 9 250052

 Patent Document 4: Utility Model Registration No. 3048633

 Non-Patent Document 1: “Encyclopedia of Textiles”, Maruzen, March 25, 2002, p. 619

Disclosure of the invention [0004] Conventionally, gloves made of animal skin have been used as heat-resistant gloves, but there are problems with workability in which fingers are difficult to move, and there is no function to absorb sweat and cannot be washed. It was a bad material. In addition, the conventional gloves using a single heat-resistant fiber yarn fabric have a problem of heat insulation. For example, when an arc hits the glove by arc welding, there is a problem that the skin burns. If the thickness of the fabric is increased, this problem can be solved. In this case, there is a problem that the work of the finger causes a problem in workability and the cost increases. Furthermore, fire fighting clothing using heat-resistant fibers is formed with an aluminum foil (including coating) as the outermost layer, a cloth made of the heat-resistant fibers alone is formed inside, and a non-woven fabric is used for heat insulation inside. As a result, the overall weight was increased, resulting in problems in work and injuries to the human body. In recent years, clothing with heat resistance and protective properties has been demanded.

 [0005] In order to solve the above-mentioned conventional problems, the present invention has a heat insulating, heat resistant, flame retardant, flame retardant, high protective property! /, Heat resistant bonded double woven fabric and clothing using the same. And provide heat-resistant gloves.

 [0006] The heat-resistant double woven fabric of the present invention is a double woven fabric in which two upper and lower ground texture layers composed of warps and wefts are connected to each other by the binding yarn. Then, at least one of the two upper and lower ground texture layers is composed of a heat-resistant fiber yarn, and the binding yarn is a design twist yarn including a loop.

 [0007] The garment of the present invention is a garment partially or entirely including the heat-resistant double-woven fabric, wherein a ground tissue layer composed of the heat-resistant fiber yarn is disposed on the surface side. And

 [0008] The glove of the present invention is a glove in which the heat-resistant double-woven fabric is integrated with a gripping surface, and a ground tissue layer composed of the heat-resistant fiber yarn is arranged on the surface side. And Brief Description of Drawings

 FIG. 1A is a side view of a design twisted yarn of one embodiment used in the present invention, and FIG. 1B is a cross-sectional view thereof.

 [FIG. 2] FIGS. 2A-B are cross-sectional structure diagrams of a bonded double woven fabric used in one example of the present invention.

 [FIG. 3] FIGS. 3A-C are cross-sectional structure diagrams of the bonded double woven fabrics of Examples 1 to 4 of the present invention.

 FIG. 4 is a front view of a heat-resistant glove obtained in an example of the present invention.

 FIG. 5 is a back view of the same.

BEST MODE FOR CARRYING OUT THE INVENTION [0010] The present invention is a bonded double woven fabric including heat resistant fibers and design twisted yarn, heat resistant yarn is arranged in at least one ground fabric, and design twist yarn is used as the binding yarn, and a large amount of air is discharged. By including it, a heat-resistant fabric having high heat insulation, heat resistance, flame resistance, flame retardancy, and protection, and clothing and heat-resistant gloves using the same can be obtained. In other words, since there are many loops in the design twisted yarn, the bonded double woven fabric using these loops as the binding yarn can force a large amount of air between the ground structures. Since air has high heat insulation, the bonded double woven fabric also has high heat insulation! /. In addition, since there are many heat-resistant fibers on one side, this part exhibits heat resistance, flame resistance, flame resistance, and protection. In addition, the heat-resistant bonded double woven fabric of the present invention and clothing and heat-resistant gloves using the same are breathable, have good workability, and can be washed.

 [0011] The bound double woven fabric of the present invention refers to a woven fabric having a double woven structure in which the bound yarn is not cut.

[0012] In the conventional moquette fabric, the surface of the binding yarn becomes a cut pile and is arranged on the surface of the sheet, and the opposite surface of the ground structure is the back surface of the sheet. On the other hand, the bonded double woven fabric of the present invention has a heat-insulating layer without cutting the bonded yarn, and the heat-resistant yarn is arranged on the warp and weft on the side without the bonded yarn, that is, the conventional moquette. It is used by arranging the back side of the sheet as a fabric on the front side (atmosphere side).

[0013] In the present invention, the heat-resistant fiber may be any inorganic fiber or organic fiber as long as it has a melting point or decomposition point of about 350 ° C or higher, preferably 400 ° C or higher. Preferably, aramid fibers (melting point or decomposition point of para-aramid: 480 to 570 ° C, meta-type: 400 to 430 ° C), polybenzimidazole fibers (glass transition temperature: 400 ° C or higher), poly (p —Polybenzoxazole fibers (melting point or decomposition temperature: 650 ° C) such as fluorene benzobisoxal) (PBO), polybenzoxy such as poly (p-phenylene benzobisthiazole) (PBZT) Azole fiber (melting point or decomposition temperature: 650 ° C), polyamideimide fiber (melting point or decomposition temperature: 350 ° C or higher), melamine fiber (melting point or decomposition temperature: 400 ° C or higher), polyimide fiber (melting point or decomposition point) Temperature: 350 ° C or higher), polyarylate fiber (melting point or decomposition temperature: 400 ° C or higher) and carbon fiber (melting point or decomposition temperature: 2000-3500 ° C). These fibers are easy to process into knitted or woven fabrics. The fineness is preferably about 1 to 50 in cotton. It can be used with a single yarn, or multiple yarns can be aligned or twisted Can be used.

 [0014] The design twisted yarn includes, for example, a core yarn, a loop yarn, and a presser yarn. More preferably, the design twisted yarn has a structure in which a presser yarn is actually twisted at a twist number of 200 to 600 times / m from above the core yarn and the loop yarn.

 [0015] The loop yarn is preferably at least one selected from cotton, rayon, hemp, wool, acrylic fiber, and the heat-resistant fiber. The core yarn and presser yarn are at least one fiber yarn selected from aramid, polybenzimidazole, polybenzoxazonole, polybenzthiazonole, polyamideimide, melamine, polyimide, polyarylate, polyester, nylon and polyolefin. Preferably there is. More preferable core yarn and presser yarn are polyester filament yarn or the heat-resistant fiber.

 [0016] The loop yarn with respect to the core yarn is 1.0; in the range of 10 to 10 times, preferably 1.2 to 6 times over. Can be formed. When the loop yarn is overfeeded to the core yarn, the loop yarn becomes longer relative to the core yarn by the amount of overfeed, and a loop is formed.

The fineness of the design twisted yarn is preferably about 118 to 11811 dtex (cotton count: 0.5 to 50). A single yarn can be used, or a plurality of yarns can be aligned or twisted. The loop yarn of the above-mentioned twisted design yarn may contain a low melting point heat-bonding fiber! /. Low-melting point heat-bonding When the fiber is included, the design twisted yarn becomes more integrated and the fraying prevention becomes higher and the waist becomes higher.

 [0018] The thickness of the heat-resistant bonded double woven fabric of the present invention is preferably 0.5 mm or more and 5 mm or less, more preferably 1 mm or more and 3 mm or less. The thickness of the woven fabric can be controlled to a desired thickness by adjusting the binding length of the binding yarn.

 [0019] The weight per unit area (weight per unit area) of the heat-resistant bonded double woven fabric is 100 to 3000 g / m

Range mosquito preferably two, further scope of 300~2000g / cm ^2, in particular 400 to; is 1500 g / cm ² in the range preferred. When the thickness and the weight per unit area are within the above ranges, in addition to heat insulation, combustion resistance is also improved.

[0020] The heat-resistant double-woven fabric of the present invention has heat insulation and heat resistance due to a ground texture layer composed of heat-resistant fiber yarns and a binding yarn composed of design twisted yarns having a large number of loops. Synergistic To be high. Further, the heat resistance fiber yarn disposed on the outer side provides good protection. For example, uniforms such as airplane crews, firefighters, police officers, self-defense personnel, outer clothing such as jumpers, coats, vests, arm strength bars, aprons, protective hoods, fire clothes, protective clothes, work clothes, fire cloths It is useful for interior materials such as airplanes, automobiles and trains. It is also useful as a heat-resistant glove used for welding work such as arc welding, pre-furnace work such as a blast furnace, heat cooking, fire extinguishing work, and handling high-temperature materials such as engine repair.

 [0021] This will be described below with reference to the drawings. FIG. 1A is a side view of a design twisted yarn 1 of one embodiment used in the present invention, and FIG. 1B is a sectional view thereof. This design twisted yarn 1 is composed of a core yarn 2, a loop yarn 3, and a presser yarn 4 from above, and the loop yarn 3 is an example of a natural fiber such as cotton or wool. The loop yarn 3 may contain a low melting point fiber. The low melting point fiber is included in the natural fiber by synthetic yarn, blended fiber, blended fiber or the like. The mixing ratio of the low melting point fiber to the natural fiber is preferably in the range of 10 to 30% by weight.

 FIG. 2A-B is a structural diagram of a heat-resistant, bonded double woven fabric used in one embodiment of the present invention.

 As shown in FIG. 2A, the upper texture 10 is formed by warps 11 and 12 and wefts 13 made of heat-resistant fiber yarns. The underlying texture 20 is formed of warps 21 and 22 and wefts 23 made of heat-resistant fiber yarns. As the upper and lower ground structures, plain weaves, oblique weaves, satin weaves, or these changed weaves, satin or other woven fabrics, crest weaves, etc. can be used.

 [0023] As shown in FIG. 2B, the upper and lower ground structures 10 and 20 are connected by a binding yarn 30 made of design twisted yarns la and lb. The binding thread 30 is entangled or inserted into the upper and lower wefts 13, 23 by dobby, jacquard or the like. In this way, a heat-resistant bonded double woven fabric is formed. Since there are many loops in design twisted yarns, a bonded double woven fabric using these loops as a binding yarn can contain a lot of air between the ground structures, and can exhibit a heat insulation effect. In addition, the design twisted yarn has many loops, which makes it bulky. When the upper and lower ground textures are pressed by hand, the fabric twists in the diagonal direction, and feels like a normal thick fabric.

[0024] In the above description, the upper and lower ground structures 10, 20 are formed of heat resistant fiber yarns, but only one of the ground structures may be formed of heat resistant yarns. When only one ground structure is formed with heat-resistant yarn, the other ground structure may be formed with a design twisted yarn, or natural fibers, synthetic fibers used in ordinary fabrics, and spinning of these blends. Yarn, filament yarn or spun yarn It can also be formed from twisted yarn of irament yarn.

[0025] The heat-resistant fiber yarns 11, 12, 13 are arranged on the surface, and the design twisted yarns la, lb are arranged inside the woven fabric. A large number of loops 3 (Fig. 1A, Fig. 1B) protrude from the design twisted yarns la and lb. Since heat resistant fiber yarns 11, 12, and 13 are present on the surface, they exhibit heat resistance, flame resistance, and flame retardancy. Some loops 3 also protrude on the heat-resistant fiber yarns 11, 12, 13 side surface S, and does not affect heat resistance. Rather, when exposed to a flame or touching a high-temperature object, the loop 3 on the surface of the heat resistant fiber yarn 11, 12, 13 side burns, so that the operator can feel danger.

 Example

 [0026] The present invention will be described more specifically with reference to the following examples. The present invention is not limited to the following examples.

[0027] (Example 1)

 (1) Manufacture of design twisted yarn

 Polyester multifilament, wooly processed yarn (manufactured by Toray Industries, Inc.), total fineness of 167 dtex (150 denier), and 96 filaments were used as the core yarn and presser yarn.

[0028] Cotton yarn as loop yarn 196. 9dtex (Cotton number: 30) 4 single yarns and low melting point heat-bonding fiber yarn (low melting point nylon, melting point 110-113 ° Product name "ELDER" manufactured by Toray Industries, Inc. ") L Two lOd tex were used.

 [0029] Loop yarn is fed to the core yarn at an overfeed rate of 1.5 to 2.0 times and entangled. At the same time as entanglement, the presser yarn is twisted at 200 to 600 turns / m. A real twist was applied. The obtained design twisted yarn was as shown in Fig. 1A-B. The average protruding length of the loop was 3 mm, and an average of 20 to 30 loops per inch protruded at an angle of 360 °. The fineness of this design twisted yarn was 1007.6 dtex.

 [0030] (2) Preparation of heat-resistant fiber yarn

 Commercially available Teijin's trade name "Conex" (meta-aramide fiber) spun yarn, fineness: 295 · 3dtex (cotton count: No. 20) was used as a double yarn.

 [0031] (3) Weaving Double weaving

Using a moquette weaving machine, the heat-resistant fiber yarn is 40 warp densities (upper and lower structures) for each / 2. It was driven at 54cm, weft density (up and down structure) of 30 each / 2. 54cm, and the upper and lower ground structures were woven into a plain structure as shown in Fig. 2A. The resulting fabric was heat set at 110 ° C for 40 minutes

Yes

[0032] The designed twisted yarn was used as a binding yarn for connecting the upper and lower ground structures, and was arranged as the binding yarns la and lb shown in Fig. 3A. The resulting bonded double woven fabric 31 had a thickness of about 3 mm and a basis weight of 1 kg / m ² . This fabric could not be cut with a manual cutter knife and could not be pierced, so it was confirmed that it was protective.

 [0033] (4) Gloves knitting and heat resistance test

 In order to evaluate the heat resistance of the bonded double woven fabric obtained above, a knit was knitted using a circular knitting machine, and the obtained knit was sewn into gloves. The knit was knitted using 60% by weight of the heat-resistant fiber yarn and 40% by weight of the design twisted yarn. The knitted structure is a double-sided knitted fabric, heat-resistant fiber yarns are arranged on the front side, design twisted yarns are arranged on the back side, loops are the forces S that are mainly present on the back side, and some are also exposed on the front side Was. As shown in FIGS. 4 to 5, the double woven fabric was integrated by sewing to the palm part (gripping part) 41 of the glove 40 and the tip parts 42 to 46 of each finger.

 [0034] Even if a nickel burner flame of about 800 ° C was applied to the palm of the obtained glove for 2 minutes, it did not burn and the surface was burnt, but the heat was felt inside. In addition, even when working on a 400 ° C heated object, no heat was felt and there was no scorch. This confirmed the flame retardancy and heat resistance.

 [0035] Also, when used for arc welding work, it does not feel heat, the sparks of welding (about 1200 ° C) are strong, but it is thin enough to be hot, and has air permeability that does not impair the work operation. It was very good. It could be washed after work and used repeatedly.

 [0036] In addition, when used in a cooking operation in which a pizza pie is baked in a combustion furnace, it also has high heat insulation, heat resistance, flame resistance, flame resistance, breathability, good workability, and washing The ability to do so, hygiene † life was also good.

 [0037] Table 1 shows the measured thermal conductivity of the bonded double woven fabric and other substances. The thermal conductivity was measured with the KES-F7 (Thermo Lab) device of the Osaka Prefectural Industrial Technology Research Institute.

[0038] [Table 1] Material Thermal conductivity (w / mK)

 Cotton 0.2 2 4 3

 Water 0.5 8 2

 Iron 8 3. 5

 Copper 4 0 3. 0

 Air 0.0 2 1

 As shown in Table 1, the bonded double woven fabric of Example 1 of the present invention had a low thermal conductivity.

Yes

 [0039] Next, the cut strength was measured using the bonded double woven fabric of Example 1 of the present invention. The cutting strength is in accordance with the “constant-speed extensometer method test” specified in JIS—1096 burst strength B method. A knife (OLFA SDS-7) is attached to the end of the push rod, and the knife speed is 2 cm / min. The strength with which the knife cuts through the sample was measured. As a comparative example, commercially available heat-resistant gloves were measured with good cutability! /, !! The results are shown in Table 2.

 [0040] [Table 2]

表 2に示すように本発明の実施例 1で得られた接結 2重織物の切創強さは、市販の 耐熱用皮手袋よりはるかに高かった。

As shown in Table 2, the cut strength of the bonded double woven fabric obtained in Example 1 of the present invention was much higher than that of commercially available heat-resistant leather gloves.

[0041] (Example 2)

As a design yarn yarn, two single yarns of cotton yarn 196.9 dtex (cotton count: 30), low-melting heat-bonded fiber yarn (low-melting nylon, melting point 110-113 °, trade name “Toray”) Ruda 1 ") l Weaved in the same manner as in Example 1 except that only one lOdtex was used. The resulting bonded double woven fabric had a thickness of about 2 mm and a basis weight of 600 g / m ² . The texture was softer than the fabric of Example 1. This fabric was also protected as in Example 1.

[0042] In the same manner as in Example 1, this bonded double woven fabric was integrated with the palm and fingers of the glove by sewing and was resistant to damage. As a result of examining the thermal properties, as in Example 1, the heat insulating property, heat resistance, flameproof property, flame retardancy, air permeability, workability were good, washing was possible, and hygiene was good.

 [0043] (Example 3)

Weaving was performed in the same manner as in Example 1, except that the same design twisted yarn as in Example 2 was used, and that the woven structure was placed every other weft yarn of the upper base structure as shown in Fig. 3B. . The resulting bonded double woven fabric 32 had a thickness of about 1.5 mm and a basis weight of 550 g / m ² . The texture was softer than the fabric of Example 1. This fabric was also observed to have the same protective properties as in Example 1.

 [0044] When this double-woven fabric was integrated into the palm and fingers of a glove by sewing as in Example 1, the heat resistance was examined. As in Example 1, heat insulation, heat resistance, and flame resistance were obtained. Good fire resistance, breathability, workability, washability, and good hygiene.

 [0045] (Example 4)

Weaving in the same manner as in Example 2 except that the same design twisted yarn as in Example 2 was used, and the woven structure was arranged such that the binding yarns la and lb were placed on the wefts of the upper base structure as W as shown in Fig. 3C. did. The resulting bonded double woven fabric 33 had a thickness of about 1.5 mm and a basis weight of 500 g / m ² . The texture was more flexible than the fabric of Example 3. This fabric was also protected as in Example 1.

 [0046] When this double-woven fabric was integrated into the palm and fingers of the glove by sewing as in Example 1, the heat resistance was examined. As in Example 1, heat insulation, heat resistance, and flameproofing were obtained. Good fire resistance, breathability, workability, washability, and good hygiene.

 [0047] Further, the resulting bonded double woven fabric 33 was used to sew on a gentleman's jacket. This jacket has the same weight and thickness as thick woolen clothes, and is suitable for uniforms such as airplane crews, fire crews, police officers, and self-defense personnel who require good heat resistance and protection. It turns out that.

 [0048] (Comparative Example 1)

Using the glove fabric of Example 1, 2 mm thick cowhide leather was sewn together at the same palm and finger positions in Example 1. When the heat resistance was examined, it burned with a heated object at 400 ° C and smoked, and the heat resistance was low. Also, there is stuffiness, and the feeling of wearing is bad, so you can not wash There was also a problem with hygiene. Furthermore, it was easily cut with the same cutter as in Example 1, and no protective property was observed.

Industrial applicability

 Examples of the use of the heat-resistant bonded double fabric of the present invention include uniforms such as airplane crews, fire fighters, police officers, self-defense personnel, outer clothing such as jumpers, coats and vests, arm strength bars, aprons, protective hoods, Useful for interior materials such as fire clothes, protective clothing, work clothes, fire cloth, airplanes, automobiles, and trains. It is also useful as a heat-resistant glove used for welding work such as arc welding, pre-furnace work such as a blast furnace, calorie heat cooking, fire extinguishing work, and working on high-temperature objects such as engine repairs.

Claims

The scope of the claims  [1] A double woven fabric in which two upper and lower ground texture layers composed of warp and weft and the two upper and lower ground texture layers are connected by a binding yarn,  Of the two upper and lower ground texture layers, at least one layer is composed of heat-resistant fiber yarns, and the binding yarns are design twisted yarns including loops. Yes  [2] The heat-resistant fiber yarn constituting the ground structure is composed of aramid fiber, polybensimidazole fiber, polybensoxazole fiber, polybenthiazole fiber, polyamideimide fiber, melamine fiber, polyimide fiber and polyarylate fiber. 2. The heat-resistant bonded double woven fabric according to claim 1, wherein the double-woven fabric is at least one yarn selected.  [3] The heat-resistant bonded double woven fabric according to claim 1, wherein the design twisted yarn is composed of a core yarn, a loop yarn, and a presser yarn.  [4] The heat-resistant bonded double woven fabric according to claim 1 or 3, wherein the design twisted yarn has a structure in which a presser yarn is actually twisted at a twist number of 200 to 600 times / m from above a core yarn and a loop yarn. . [5] The loop yarn is at least one fiber selected from cotton, rayon, hemp, wool, acrylic, aramid, polybensimidazole, polybensoxazole, polybenthiazole, polyamideimide, melamine, polyimide and polyarylate. The claim 3, which is a thread 4. Heat-resistant bonded double woven fabric according to 4. [6] The heat-resistant double bonded fabric according to any one of claims 3 to 5, wherein the loop yarn is 1.01 to 10 times longer than the core yarn. [7] The core yarn and the holding yarn are at least one fiber selected from aramid, polybensimidazole, polybenzoxazole, polybenthiazole, polyamideimide, melamine, polyimide, polyarylate, polyesteranol, nylon, and polyolefin. The heat-resistant bonded double woven fabric according to claim 3 or 4, which is a yarn. [8] The heat-resistant double bonded fabric according to claim 1, 3 or 4, wherein the loop yarn of the design twisted yarn includes a low-melting-point heat-bonding fiber. [9] The heat-resistant double-woven fabric according to any one of claims 1 to 8, wherein the fineness of the design twisted yarn is in a range of 118 to 118118 dtex (cotton count: 0 · 5 to 50). [10] The heat-resistant stitching double fabric basis weight, according to claim 1 in the range of 100 to 3000 g / m ² The heat-resistant bonded double woven fabric according to any one of? [11] The heat-resistant double-woven fabric according to any one of [10] to [10], wherein the heat-resistant double-woven fabric has a thickness of 0.5 to 5 mm. [12] The heat-resistant bonded fabric according to any one of claims 1 to 11, wherein the clothing comprises part or all of the double woven fabric, wherein the ground tissue layer composed of the heat-resistant fiber yarn is on the surface side. Clothing characterized by being placed in.  [13] A heat-resistant binding according to any one of claims 1 to 11, wherein the double woven fabric is integrated with a gripping surface, and the ground tissue layer composed of the heat-resistant fiber yarn is disposed on the surface side. Heat-resistant gloves characterized by being placed in.