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WO2008060992A3 - Selective hydrogenation processes using functional surface catalyst composition - Google Patents

Selective hydrogenation processes using functional surface catalyst composition Download PDF

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Publication number
WO2008060992A3
WO2008060992A3 PCT/US2007/084231 US2007084231W WO2008060992A3 WO 2008060992 A3 WO2008060992 A3 WO 2008060992A3 US 2007084231 W US2007084231 W US 2007084231W WO 2008060992 A3 WO2008060992 A3 WO 2008060992A3
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WO
WIPO (PCT)
Prior art keywords
equal
less
substrate
catalyst composition
selective hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2007/084231
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French (fr)
Other versions
WO2008060992A2 (en
Inventor
Robert L Bedard
Jeffery C Bricker
Ally S Chan
Dean E Rende
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Honeywell UOP LLC
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UOP LLC
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Publication date
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Publication of WO2008060992A2 publication Critical patent/WO2008060992A2/en
Publication of WO2008060992A3 publication Critical patent/WO2008060992A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
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    • C07C7/167—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation for removal of compounds containing a triple carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
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Abstract

Selective hydrogenation processes using a catalyst composition which, preferably comprises a glass substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface. A substantially nonmicroporous/nonmesoporous substrate having macropores has (i) a total surface area between about 0.1 m2/g and 50 m2/g; and (ii) a predetermined isoelectric point (IEP) obtained in a pH range greater than 0, preferably greater than or equal to 4.5, or more preferably greater than or equal to 6.0, but less than or equal to 14. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness less than or equal to about 30 nm, preferably less than or equal to 20 nm and more preferably less than or equal to 10 nm. Preferably, the substrate is a glass composition having a SARCNa less than or equal to about 0.5.
PCT/US2007/084231 2006-11-11 2007-11-09 Selective hydrogenation processes using functional surface catalyst composition Ceased WO2008060992A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86540506P 2006-11-11 2006-11-11
US60/865,405 2006-11-11

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WO2008060992A2 WO2008060992A2 (en) 2008-05-22
WO2008060992A3 true WO2008060992A3 (en) 2008-07-10

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
US10525448B2 (en) 2015-07-22 2020-01-07 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production

Families Citing this family (2)

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Publication number Priority date Publication date Assignee Title
EP2328679A1 (en) * 2008-08-20 2011-06-08 DSM IP Assets B.V. Novel selective hydrogenation catalyst comprising palladium on porous silica glass and the use thereof
TWI586693B (en) 2013-07-23 2017-06-11 財團法人工業技術研究院 Method for selectively hydrogenating copolymer

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EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
EP0258942A2 (en) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
EP1044935A1 (en) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne A low weight resistant porous glass fiber having physical, chemical or biological properties

Non-Patent Citations (8)

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US10864500B2 (en) 2015-07-22 2020-12-15 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production
US12064749B2 (en) 2015-07-22 2024-08-20 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production

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