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WO2008060972A3 - Procédés d'hydrogénation utilisant une composition catalytique de surface fonctionnelle - Google Patents

Procédés d'hydrogénation utilisant une composition catalytique de surface fonctionnelle Download PDF

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Publication number
WO2008060972A3
WO2008060972A3 PCT/US2007/084200 US2007084200W WO2008060972A3 WO 2008060972 A3 WO2008060972 A3 WO 2008060972A3 US 2007084200 W US2007084200 W US 2007084200W WO 2008060972 A3 WO2008060972 A3 WO 2008060972A3
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WIPO (PCT)
Prior art keywords
equal
less
substrate
catalyst composition
functional surface
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Ceased
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PCT/US2007/084200
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English (en)
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WO2008060972A2 (fr
Inventor
Robert L Bedard
Jeffery C Bricker
Ally S Chan
Dean E Rende
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Honeywell UOP LLC
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UOP LLC
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Publication of WO2008060972A2 publication Critical patent/WO2008060972A2/fr
Publication of WO2008060972A3 publication Critical patent/WO2008060972A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
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    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
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    • B01J37/28—Phosphorising
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    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
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    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
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    • B01J35/394—Metal dispersion value, e.g. percentage or fraction
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    • B01J35/396—Distribution of the active metal ingredient
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
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    • B01J35/613—10-100 m2/g
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne des procédés d'hydrogénation dans lesquels est utilisée une composition catalytique, qui comprend de préférence un substrat de verre; un ou plusieurs composants tensioactifs fonctionnels étant intégrés sur et/ou dans la surface du substrat. Un substrat sensiblement non microporeux/non mésoporeux qui comprend des macropores présente (i) une surface totale comprise entre 0,1 m2/g et 50 m2/g; et (ii) un point isoélectrique prédéterminé (IEP) obtenu dans une plage de pH supérieure à 0, de préférence supérieure ou égale à 4,5; ou idéalement supérieure ou égale à 6,0; mais inférieure ou égale à 14. Au moins une zone catalytiquement active peut être contiguë ou non contiguë et présente une épaisseur inférieure ou égale à environ 30 nm, de préférence inférieure ou égale à 20 nm et idéalement inférieure ou égale à 10 nm. De préférence, le substrat est une composition de verre présentant un SARCNa inférieur ou égal à environ 0,5.
PCT/US2007/084200 2006-11-11 2007-11-09 Procédés d'hydrogénation utilisant une composition catalytique de surface fonctionnelle Ceased WO2008060972A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86540806P 2006-11-11 2006-11-11
US60/865,408 2006-11-11

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WO2008060972A2 WO2008060972A2 (fr) 2008-05-22
WO2008060972A3 true WO2008060972A3 (fr) 2008-07-17

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Publication number Priority date Publication date Assignee Title
EP2328679A1 (fr) 2008-08-20 2011-06-08 DSM IP Assets B.V. Nouveau catalyseur d'hydrogénation sélective comprenant du palladium sur du verre de silice poreux et son utilisation
CN117138838A (zh) 2015-07-22 2023-12-01 巴斯夫公司 用于乙酸乙烯酯单体产生制备的高几何表面积催化剂

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (fr) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Préparation de catalyseur
EP1044935A1 (fr) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne Fibre de verre poreuse, résistante à poids léger ayant des propriétés physiques, chimiques ou biologiques
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
JP2003284954A (ja) * 2002-03-28 2003-10-07 Nippon Shokubai Co Ltd 金超微粒子担持体、その製造方法、及び該担持体からなる触媒

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0258942A2 (fr) * 1986-08-29 1988-03-09 Shell Internationale Researchmaatschappij B.V. Préparation de catalyseur
US20020035033A1 (en) * 1997-09-30 2002-03-21 Herbert Muller Process for preparing a shell-type catalyst
EP1044935A1 (fr) * 1999-04-13 2000-10-18 Ecole Polytechnique Federale De Lausanne Fibre de verre poreuse, résistante à poids léger ayant des propriétés physiques, chimiques ou biologiques
JP2003284954A (ja) * 2002-03-28 2003-10-07 Nippon Shokubai Co Ltd 金超微粒子担持体、その製造方法、及び該担持体からなる触媒

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
HOELLER VOLKER ET AL: "Three-phase nitrobenzene hydrogenation over supported glass fiber catalysts:reaction kinetics study", CHEMICAL ENGINEERING AND TECHNOLOGY, WEINHEIM, DE, vol. 23, no. 3, March 2000 (2000-03-01), pages 251 - 255, XP009097523, ISSN: 0930-7516 *
KIWI-MINSKER L ET AL: "Glass fiber catalysts for total oxidation of CO and hydrocarbons in waste gases", CATALYSIS TODAY, ELSEVIER, vol. 54, 1999, pages 39 - 46, XP002362223, ISSN: 0920-5861 *
KIWI-MINSKER L ET AL: "Supported glass fibers catalysts for novel multi-phase reactor design", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 54, November 1999 (1999-11-01), pages 4785 - 4790, XP002299322, ISSN: 0009-2509 *
SIMONOVA L G ET AL: "Catalysts Based on Fiberglass Supports: I. Physicochemical Properties of Silica Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 5, September 2001 (2001-09-01), pages 693 - 702, XP009097809, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: II. Physicochemical Properties of Alumina Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, November 2001 (2001-11-01), pages 828 - 836, XP009097808, ISSN: 1608-3210 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: III. Properties of Supported Metals Pt and Pd) According to Electron-Microscopic and XPS Datana Borosilicate Fiberglass Supports", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 42, no. 6, 2001, pages 837 - 846, XP009097609 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: IV. Platinum Catalysts Based on Fiberglass Support in Oxidation of Hydrocarbons (Propane and n-Butane) and Sulfur Dioxide", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 1, 2002, pages 61 - 66, XP009097611 *
SIMONOVA1 L G ET AL: "Catalysts Based on Fiberglass Supports: V. Absorption and Catalytic Properties of Palladium Catalysts Based on a Leached Silica-Fibergless Support in the Selective Hydrogenation of an Ethylen-Acetylene Mixture", KINETICS AND CATALYSIS, KLUWER ACADEMIC PUBLISHERS, BO, vol. 43, no. 4, 2002, pages 542 - 549, XP009097610 *
YU MATATOV-MEYTAL ET AL: "Cloth catalysts for water denitrification: I. Pd on glass fibers", APPLIED CATALYSIS B: ENVIRONMENTAL, ELSEVIER, vol. 27, 2000, pages 127 - 135, XP009097566, ISSN: 0926-3373 *

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