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WO2008060303A1 - Nettoyant moussant pour surfaces dures - Google Patents

Nettoyant moussant pour surfaces dures Download PDF

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Publication number
WO2008060303A1
WO2008060303A1 PCT/US2006/061047 US2006061047W WO2008060303A1 WO 2008060303 A1 WO2008060303 A1 WO 2008060303A1 US 2006061047 W US2006061047 W US 2006061047W WO 2008060303 A1 WO2008060303 A1 WO 2008060303A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
foamable composition
horizontal line
foamable
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/061047
Other languages
English (en)
Inventor
Patrick Diet
Isabelle Leonard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to MX2009005155A priority Critical patent/MX2009005155A/es
Priority to CA2669329A priority patent/CA2669329C/fr
Priority to PL06839936T priority patent/PL2097501T3/pl
Priority to DK06839936.9T priority patent/DK2097501T3/da
Priority to PCT/US2006/061047 priority patent/WO2008060303A1/fr
Priority to AU2006350750A priority patent/AU2006350750B2/en
Priority to PT06839936T priority patent/PT2097501E/pt
Priority to EP06839936A priority patent/EP2097501B1/fr
Priority to NZ576960A priority patent/NZ576960A/en
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Priority to ES06839936T priority patent/ES2388617T3/es
Priority to CN2006800563931A priority patent/CN101563442B/zh
Publication of WO2008060303A1 publication Critical patent/WO2008060303A1/fr
Priority to EC2009009329A priority patent/ECSP099329A/es
Priority to CR10800A priority patent/CR10800A/es
Anticipated expiration legal-status Critical
Priority to NO20092326A priority patent/NO20092326L/no
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • Hard surface cleaners are usually mostly water that include cleaning materials, fragrance, and color. Hard Surface cleaners are usually sprayed onto a surface and then wiped to clean the surface. Because hard surface cleaners are mostly water, they will drip when applied to vertical surfaces because of gravity.
  • a foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate in an amount of about 0.01 to about 1% by weight of the composition; b) at least one glycol ether in an amount of about 0.1 to about 1.5% by weight of the composition; c) at least one alcohol in an amount of about 2 to about 6 % by weight of the composition; and d) water.
  • a foamable composition comprising: a) at least one anionic surfactant chosen from a salt of an alkyl sulfate and a salt of an alkyl ether sulfate; b) at least one glycol ether; and c) at least one alcohol; and d) water, wherein the composition has a run down time of greater than about 15 seconds, wherein the run down time is measured by providing a vertical glass surface, which is perpendicular to the earth's surface, with a first horizontal line that is 10 cm above a second horizontal line and both are parallel to the earth's surface, applying the composition to the vertical glass surface at the first horizontal line from a distance of 20 cm perpendicular to the surface, and measuring the time for the composition to run down from the first horizontal line to the second horizontal line.
  • ranges are used as a shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range.
  • AU references to amounts in this specification are by active weight of the material in the total composition.
  • the active weight of a material is the actual amount of the material not including other materials, such as water, in the form in which it is supplied.
  • the counter ion for the salt of a surfactant can be a metal ion, an ammonium ion, or an amine.
  • Metal cations that can be used include, but are not limited to, alkali metal ions and alkaline earth ions.
  • the metal cation ion can be lithium, sodium, potassium, magnesium, or calcium.
  • the amine is triethanolamine.
  • the foaming composition includes at least one anionic surfactant chosen from a salt of an alkyl sulfate surfactant and a salt of an alkyl ether sulfate surfactant.
  • the surfactant is present in the composition in an amount of about 0.1 to about 1 % by weight.
  • the surfactant comprises a triethanolamine alkyl sulfate.
  • the alkyl is a ClO to C14 alkyl.
  • the surfactant comprises a triethanolamine lauryl sulfate.
  • the Methanol amine alkyl sulfate is present in an amounfof about 0.1 to about 0.3% by weight, and in another embodiment in an amount of about 0.18 to about 0.22% by weight.
  • the surfactant comprises the salt of an alkyl ether sulfate.
  • the alkyl is a ClO to C14.
  • the surfactant is a sodium lauiyl ether sulfate.
  • the sodium lauryl ether sulfate is present in an amount of about 0.05 to about 0.2% by weight, and in another embodiment at 0.06 to about 0.08% by weight.
  • the foaming composition can include an amine oxide surfactant.
  • Amine oxide semi-polar nonionic surfactants can comprise compounds and mixtures of compounds having the formula:
  • R 1 (C 2 H 4 O) n N ⁇ O R 3
  • R ⁇ is an alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl, or 3-alkoxy-2-hydroxypropyl radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms
  • R2 and R3 are each methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, or 3-hydroxypropyl
  • n is from 0 to 10.
  • Particularly preferred are amine oxides of the formula:
  • R 3 wherein R ⁇ is a C42-I6 a&yl and R2 and R3 are methyl or ethyl.
  • ethylene oxide condensates, amides, and amine oxides are described in U.S. Pat. No. 4,316,824.
  • the amine oxides comprise alkyl amine oxides and/ or cocoamidopropyl amine oxide.
  • the ratio of anionic surfactant to amine oxide surfactant is about 3:1 to about 4:1.
  • the composition additionally includes at least one glycol ether. In one embodiment, the amount of glycol ether is about 0.1 to about 1.5% by weight.
  • glycol ethers include, but are not limited to, propylene glycol n-butyl ether, propylene glycol n-propyl ether, ethylene glycol n-hexal ether, ethylene glycol n-butyl ether, dipropylene glycol methyl ether, and combinations thereof.
  • the composition includes propylene glycol n-butyl ether in an amount up to about 1.5% by weight, and in another embodiment at about 1.25% by weight.
  • the foaming composition includes at least one alcohol. Any alcohol can be used in the composition.
  • the alcohol comprises a Ci-C 6 alkyl alcohol.
  • the alcohol is chosen from methanol, ethanol, n-propanol, isopropanol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, 1- 2- or 3- pentanol, neopentyl alcohol, and/ or hexanol.
  • the alcohol is present in the composition in an amount of about 2 to about 6% by weight, about 3 to about 5% by weight, about 3 to about 4.5% by weight, or in another embodiment, the amount is about 4% by weight.
  • the at least one alcohol comprises ethanol.
  • ethanol is present in the composition in an amount of about 2 to about 6% by weight, about 3 to about 5% by weight, about 3 to about 4.5% by weight, or in another embodiment, the amount is about 4% by weight.
  • the alcohol comprises ethanol and isopropanol.
  • isopropanol is present in an amount of 0 to about 1.5% by weight, and in another embodiment the isopropanol is present at about 1 % by weight.
  • the composition can optionally include at least one dispersant.
  • the dispersant can be present in any amount that provides a dispersant effect. In one embodiment, the dispersant is present in an amount of about 0.01 to about 1 % by weight. In one embodiment, the dispersant is a maleic acid/ olefin copolymer. In one embodiment, a dispersant of this type is a maleic acid/d ⁇ sobutylene copolymer available from Rohm and Haas under the trade name ACUSOLTM 460NK.
  • the composition can additionally include any fragrance or perfume. In one embodiment, the perfume is present in an amount of about 0.03 to about 0.08% by weight. The composition can additionally include any dye or coloring agent.
  • composition can contain any pH agent, a biocide/ antibacterial agent, or any other material for a desired effect.
  • ammonium hydroxide and/ or vinegar can be included, and in one embodiment they can be included up to about 0.2% by weight.
  • citric acid can be used to adjust the pH of the composition.
  • Water can be included in the composition in any amount to make the sum of the amount of materials in the composition total 100 weight percent.
  • the composition when applied as a foam to a vertical glass surface will have a run down time of greater than about 15 seconds. In other embodiments, the run down time is greater than about 18 seconds, greater than about 20 seconds, greater than about 23 seconds, or about 15 to about 30 seconds. Run down time is measured by applying the foamed composition to a vertical glass surface, which is perpendicular to the earth's surface, at a first horizontal line marked on the surface from a distance of 20 cm perpendicular to the surface using a foaming dispenser. A second horizontal line is marked 10 cm below the first horizontal line on the glass surface. Run down time is the time that it takes the composition to run down from the first line to the second line. Both the first and second horizontal lines are parallel to the earth's surface.
  • the foam is generated by a foaming dispenser that mixes air with the composition when it is dispensed.
  • the composition does not contain any propellants that would eject the composition from the container or cause the composition to foam.
  • Any foaming dispenser can be used with the composition.
  • the dispenser is available from MeadWestvaco Calmar GmbH under the product name TS 800 Top Gun Trigger Sprayer.
  • the composition can be used as a cleaner on all surfaces.
  • the surface is a horizontal surface, which is parallel to the earth's surface.
  • the surface is a non-horizontal surfaces, such as those that are angled at greater than 0 to 90° to the earth's surface.
  • the composition can be used as a cleaner on a vertical surface, which is perpendicular to the earth's surface.
  • the composition is a glass cleaner.
  • the composition can be used in a method for removing soil from a surface comprising applying the composition to the surface and removing the composition.
  • Removing includes, but is not limited to, wiping, squeegeeing, rinsing, and mopping.
  • the surface can be, horizontal, non-horizontal, or vertical.
  • composition according to the invention was prepared by mixing the ingredients.
  • the composition was added to a container with a foaming dispenser.
  • composition was compared against AJAXTM Triple Action Glass Cleaner, which is commercially available in Europe in a conventional glass cleaner spray bottle, in the run down test described above.
  • a positioning device was used to position each container so that they sprayed at the same point on the vertical glass surface.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition moussante comprenant : a) au moins un tensioactif anionique choisi parmi un sel d'un sulfate d'alkyle et un sel d'un éther sulfate d'alkyle en une quantité d'environ 0,01 à environ 1 % en poids de la composition ; b) au moins un éther de glycol en une quantité d'environ 0,1 à environ 1,5 % en poids de la composition ; c) au moins un alcool en une quantité d'environ 2 à environ 6 % en poids de la composition ; et d) de l'eau. L'invention concerne également une composition moussante comprenant : a) au moins un tensioactif anionique choisi parmi un sel d'un sulfate d'alkyle et un sel d'un éther sulfate d'alkyle ; b) au moins un éther de glycol ; c) au moins un alcool ; et d) de l'eau, ladite composition ayant un temps d'écoulement supérieur à environ 15 secondes sur une surface en verre verticale sur une distance de 10 cm.
PCT/US2006/061047 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures Ceased WO2008060303A1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
NZ576960A NZ576960A (en) 2006-11-17 2006-11-17 Foaming hard surface cleaner
PL06839936T PL2097501T3 (pl) 2006-11-17 2006-11-17 Pieniący środek do czyszczenia stałych powierzchni
DK06839936.9T DK2097501T3 (da) 2006-11-17 2006-11-17 Skummende rengøringsmiddel til hårde overflader
PCT/US2006/061047 WO2008060303A1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures
AU2006350750A AU2006350750B2 (en) 2006-11-17 2006-11-17 Foaming hard surface cleaner
PT06839936T PT2097501E (pt) 2006-11-17 2006-11-17 Espuma de limpeza para superfícies duras
EP06839936A EP2097501B1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures
MX2009005155A MX2009005155A (es) 2006-11-17 2006-11-17 Limpiador espumante para superficies duras.
ES06839936T ES2388617T3 (es) 2006-11-17 2006-11-17 Limpiador espumoso de superficies duras
CA2669329A CA2669329C (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures
CN2006800563931A CN101563442B (zh) 2006-11-17 2006-11-17 发泡硬表面清洁剂
EC2009009329A ECSP099329A (es) 2006-11-17 2009-05-14 Limpiador espumante para superficies duras
CR10800A CR10800A (es) 2006-11-17 2009-05-15 Limpiador espumante para superficies duras
NO20092326A NO20092326L (no) 2006-11-17 2009-06-16 Skummende rengjoringsmiddel for harde overflater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2006/061047 WO2008060303A1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures

Publications (1)

Publication Number Publication Date
WO2008060303A1 true WO2008060303A1 (fr) 2008-05-22

Family

ID=38255536

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/061047 Ceased WO2008060303A1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures

Country Status (14)

Country Link
EP (1) EP2097501B1 (fr)
CN (1) CN101563442B (fr)
AU (1) AU2006350750B2 (fr)
CA (1) CA2669329C (fr)
CR (1) CR10800A (fr)
DK (1) DK2097501T3 (fr)
EC (1) ECSP099329A (fr)
ES (1) ES2388617T3 (fr)
MX (1) MX2009005155A (fr)
NO (1) NO20092326L (fr)
NZ (1) NZ576960A (fr)
PL (1) PL2097501T3 (fr)
PT (1) PT2097501E (fr)
WO (1) WO2008060303A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX338888B (es) * 2011-03-08 2016-05-04 Sca Hygiene Prod Ab Composicion limpiadora antimicrobiana baja en alcohol.
WO2019115297A1 (fr) * 2017-12-12 2019-06-20 Unilever N.V. Composition de nettoyage moussante
CN111718804A (zh) * 2020-07-24 2020-09-29 上海绿瑞生物科技有限公司 一种泡沫型清洗剂组合物及其应用
AU2022226326B2 (en) * 2021-02-24 2023-11-09 Valvoline Licensing And Intellectual Property Llc Foaming evaporator coil cleaner

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463735A (en) * 1967-10-18 1969-08-26 Drackett Co Glass cleaning composition
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
EP0527625A2 (fr) * 1991-08-09 1993-02-17 S.C. Johnson & Son, Inc. Composition de nettoyage pour verre
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
US6420326B1 (en) * 1997-08-13 2002-07-16 The Procter & Gamble Company Glass cleaner compositions having good surface lubricity and alkaline buffer
US20050026796A1 (en) * 2003-07-30 2005-02-03 Colgate-Palmolive Company Foam glass cleaning composition
WO2005118765A1 (fr) * 2004-05-24 2005-12-15 Ecolab Inc. Composition de mousse nettoyante, procede de moussage d'une composition de nettoyage, et distributeur de mousse

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005044513A1 (de) * 2005-09-16 2007-03-22 Henkel Kgaa Reinigungsmittel für harte Oberflächen

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463735A (en) * 1967-10-18 1969-08-26 Drackett Co Glass cleaning composition
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
EP0527625A2 (fr) * 1991-08-09 1993-02-17 S.C. Johnson & Son, Inc. Composition de nettoyage pour verre
US6420326B1 (en) * 1997-08-13 2002-07-16 The Procter & Gamble Company Glass cleaner compositions having good surface lubricity and alkaline buffer
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
US20050026796A1 (en) * 2003-07-30 2005-02-03 Colgate-Palmolive Company Foam glass cleaning composition
WO2005118765A1 (fr) * 2004-05-24 2005-12-15 Ecolab Inc. Composition de mousse nettoyante, procede de moussage d'une composition de nettoyage, et distributeur de mousse

Also Published As

Publication number Publication date
NO20092326L (no) 2009-08-04
EP2097501B1 (fr) 2012-06-06
PL2097501T3 (pl) 2012-10-31
PT2097501E (pt) 2012-09-10
DK2097501T3 (da) 2012-09-17
CA2669329A1 (fr) 2008-05-22
CR10800A (es) 2009-09-03
AU2006350750B2 (en) 2011-05-12
CN101563442B (zh) 2013-06-19
EP2097501A1 (fr) 2009-09-09
ECSP099329A (es) 2009-06-30
CN101563442A (zh) 2009-10-21
AU2006350750A1 (en) 2008-05-22
CA2669329C (fr) 2013-10-01
MX2009005155A (es) 2009-05-25
ES2388617T3 (es) 2012-10-17
NZ576960A (en) 2011-11-25

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