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WO2008058720A1 - Préparations cosmétiques contenant des alcools de guerbet - Google Patents

Préparations cosmétiques contenant des alcools de guerbet Download PDF

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Publication number
WO2008058720A1
WO2008058720A1 PCT/EP2007/009835 EP2007009835W WO2008058720A1 WO 2008058720 A1 WO2008058720 A1 WO 2008058720A1 EP 2007009835 W EP2007009835 W EP 2007009835W WO 2008058720 A1 WO2008058720 A1 WO 2008058720A1
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WO
WIPO (PCT)
Prior art keywords
preparation
acid
inci
cosmetic
ethylhexyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/009835
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German (de)
English (en)
Inventor
Andreas Bleckmann
Celina Storbeck
Lesmona Scherf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
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Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Publication of WO2008058720A1 publication Critical patent/WO2008058720A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/045Hydroxy compounds, e.g. alcohols; Salts thereof, e.g. alcoholates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00Drugs for dermatological disorders
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the present invention relates to cosmetic preparations with Guerbet alcohols and cationic emulsifiers, preferably combinations of Guerbet alcohols and Dimethyldioctadecylammoniumchlorid.
  • Cleansing of the skin serves to remove dirt, sweat and remnants of dead skin particles, which form an ideal breeding ground for pathogens and parasites of all kinds.
  • Skin care products are usually used to moisten and restore the skin. Often, agents that regenerate the skin and, for example, prevent and reduce their premature aging (e.g., wrinkles, wrinkles) are added to them.
  • Emulsions are generally understood to mean heterogeneous systems which consist of two liquids which are immiscible or only to a limited extent miscible with one another, which are usually referred to as phases and in which one of the two liquids is dispersed in the form of very fine droplets in the other liquid. Viewed externally and with the naked eye, emulsions appear homogeneous.
  • the two liquids are water and oil and oil droplets are finely distributed in water, then it is an oil-in-water emulsion (O / W emulsion, eg milk).
  • O / W emulsion oil-in-water emulsion
  • the basic character of an O / W emulsion is characterized by the water.
  • a water-in-oil emulsion W / O emulsion, eg butter
  • emulsifiers are added to the emulsions.
  • Emulsifiers are usually molecules with a polar, hydrophilic structural element and a nonpolar, lipophilic structural element.
  • HLB value a dimensionless number between 0 and 20
  • Numbers below 9 indicate oil-soluble, hydrophobic emulsifiers, numbers above 1 1 water-soluble, hydrophilic.
  • Emulsifiers can be present in different forms, for example as anionic emulsifiers (for example: potassium cetyl phosphate), as nonionic emulsifiers (for example: polyoxyethylene (4) cetyl ether) or as cationic emulsifiers (for example dimethyldioctadecylammonium chloride).
  • anionic emulsifiers for example: potassium cetyl phosphate
  • nonionic emulsifiers for example: polyoxyethylene (4) cetyl ether
  • cationic emulsifiers for example dimethyldioctadecylammonium chloride
  • Cationic emulsifiers in particular dimethyldioctadecylammonium chloride (INCI: Distearyldimonium Chloride, CAS 0764-2), when used in cosmetic preparations, lead to aqueous formulas which rapidly enter the skin and produce a dull skin sensation. Because of these properties, the preparations are difficult to distribute on the skin.
  • Another object of the present invention was to develop a cosmetic preparation based on an emulsion formed with the emulsifier dimethyldioctadecylammonium chloride, which has a higher viscosity at the same proportion of oil and water phase.
  • a further object of the present invention was to develop a cosmetic preparation based on an emulsion formed with the emulsifier dimethyldioctadecylammonium chloride, in which anionic cosmetic ingredients or anionic active ingredients, in particular anionic polymeric thickeners, can be stably incorporated without causing, for example, lumps or Precipitation comes.
  • Cosmetic emulsions regularly contain greater amounts of glycerin than skin moisturizers.
  • a disadvantage of such preparations is the fact that the glycerol in the formulas regularly leads to the preparation feeling sticky on the skin.
  • Another object of the present invention was therefore to develop a cosmetic emulsion with the emulsifier dimethyldioctadecylammonium chloride and glycerol, which is significantly less sticky than comparable preparations of the prior art.
  • a cosmetic preparation comprising a combination of a) Guerbet alcohols and b) one or more cationic emulsifiers.
  • a cosmetic preparation comprising a combination of a) Guerbet alcohols and b) dimethyldioctadecylammonium chloride.
  • Guerbet alcohols are compounds according to the invention which have the following structure:
  • the dimethyldioctadecylammonium chloride according to the invention has the following structure:
  • WO 01/00161 describes preparations with dimethyldioctadecylammonium chloride. The combination of both substances and their effects are not yet described.
  • the invention further relates to the use of Guerbet alcohols for improving the spreadability of cosmetic preparations containing cationic emulsifiers, in particular dimethyldioctadecylammonium chloride.
  • the preparation according to the invention is present in the form of a G7W emulsion.
  • the preparation according to the invention contains Guerbet alcohols in a concentration of 0.5 to 20% by weight, based on the total weight of the preparation.
  • the preparation according to the invention contains Guerbet alcohols in a concentration of 2 to 10% by weight, based on the total weight of the preparation.
  • Guerbet alcohol is 2-octyldodecanol which has the following structure:
  • Embodiments which are advantageous according to the invention are characterized in that the preparation according to the invention contains cationic emulsifiers in a concentration of 0.3 to 6% by weight, based on the total weight of the preparation.
  • Preferred embodiments according to the invention are characterized in that the preparation according to the invention contains cationic emulsifiers in a concentration of 0.5 to 3% by weight, based on the total weight of the preparation.
  • Embodiments which are advantageous according to the invention are characterized in that the preparation according to the invention contains dimethyldioctadecylammonium chloride in a concentration of 0.3 to 6% by weight, based on the total weight of the preparation.
  • the preparation according to the invention contains dimethyldioctadecylammonium chloride in a concentration of 0.5 to 3% by weight, based on the total weight of the preparation.
  • the weight ratio of Guerbet alcohols to dimethyldioctadecylammonium chloride is advantageously from 1: 1 to 20: 1, preferably from 2: 1 to 10: 1.
  • UV filter substances which are liquid at room temperature for the purposes of the present invention are homomenthyl salicylate (INCI: homosalates), 2-ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene), terephthalidene dic- imheresulfonic acid; 2-ethylhexyl 2-hydroxybenzoate (2-ethylhexyl salicylate, octyl salicylate, INCI: octyl salicylate) and esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxy cinnamate (2-ethylhexyl-4-methoxycinnamate, INCI: octyl methoxycinnamate) and 4-methoxycinnamic acid isopentyl ester
  • Ethylhexyl triazone Ethylhexyl triazone); 2,4,6-tribiphenyl-4-yl-1,3,5-triazine; merocyanines; Titiandioxid; Zinc oxide in a concentration of 0.01 to 40% by weight and particularly preferably in a concentration of 1 - 20% by weight based on the total weight of the preparation.
  • Ingredients One or more compounds selected from the group of folic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, polydocanol, natural and / or synthetic isoflavonoids, genistein, flavonoids, carotenoids, creatine, creatinine, taurine, ascorbic acid and derivatives , Oxygen, tocopherol + ester, urea; long and short chain hyaluronic acid (i.e., hyaluronic acid having an average molecular weight of 1 million to 3 million daltons, as well as 5,000 daltons - 1 million daltons); dihydroxyacetone; 8-hexadecene-1, 16-dicarboxylic acid and / or licochalcone A contains.
  • hyaluronic acid i.e., hyaluronic acid having an average molecular weight of 1 million to 3 million daltons, as well as 5,000 dalton
  • Such active ingredients may be contained individually or in combination in the preparation in each case in a single concentration of 0.01 to 10% by weight, based on the total weight of the preparation in this.
  • Embodiments of the present invention that are advantageous according to the invention are characterized in that the preparation contains one or more compounds selected from the group consisting of parabens, phenoxyethanol, ethylhexylglycerol, 2-methylpropane-1,3-diol, butylene glycol, propylene glycol.
  • Such active ingredients may be contained individually or in combination in the preparation in each case in a single concentration of 0.01 to 10% by weight, based on the total weight of the preparation in this.
  • the preparation according to the invention contains glycerol in a concentration of greater than or equal to 15% by weight, based on the total weight of the preparation.
  • the preparation according to the invention contains glycerol in a concentration of greater than or equal to 10% by weight, based on the total weight of the preparation.
  • the preparation according to the invention contains anionic polymeric thickeners, in particular anionic polymeric thickeners which contain acrylic acid and / or acrylic acid salts as monomer building blocks.
  • polyacrylic acid and / or polyacrylic acid copolymers are preferred.
  • Concentration of 0 to 5% by weight, based on the total weight of the preparation contains.
  • the preparations according to the invention may also advantageously contain repellents for protection against mosquitoes, ticks and spiders and the like.
  • repellents for protection against mosquitoes, ticks and spiders and the like.
  • Advantageous z. N, N-diethyl-3-methylbenzamide (trade name: meta-delphphene, "DEET"), dimethyl phthalate (trade name: palatinol M, DMP), 1-piperidinecarboxylic acid 2- (2-hydroxyethyl) -1-methylpropyl ester and especially 3- (Nn-butyl-N-acetyl-amino) -propionic acid ethyl ester (available under the trade name Insect Repellent® 3535 from Merck).
  • the repellents can be used both individually and in combination.
  • Moisturizers are substances or mixtures of substances which give cosmetic preparations the property of reducing the moisture release of the horny layer (also called transepidermal water loss (TEWL) after application or spreading on the skin surface) and / or hydrating the horny layer positively influence.
  • TEWL transepidermal water loss
  • humectants for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccharide gum-1, glycine soya, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and urea.
  • polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gellable polysaccharides.
  • the cosmetic preparations according to the invention may also advantageously, although not necessarily, contain fillers which are e.g. B. further improve the sensory and cosmetic properties of the formulations and, for example, cause or enhance a velvety or silky feel on the skin.
  • Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as, for example, tapioca starch, distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), pigments which have neither mainly UV filter nor coloring action (such as, for example, US Pat. B. boron nitride etc.) and / or Aerosils ® (CAS no. 7631-86-9) and / or talc.
  • the aqueous phase of the preparations according to the invention may advantageously comprise customary cosmetic auxiliaries, for example alcohols, in particular those of low C number, preferably ethanol and / or isopropanol, diols or polyols of low C number and their ethers, preferably propylene glycol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analogous products, polymers, foam stabilizers, electrolytes, self-tanning agents (especially DHA) and thickeners, which can be advantageously selected from the group consisting of silicon dioxide, aluminum silicates, Polysac- charide or its derivatives, eg. Hyaluronic acid, xanthan gum, hydroxypropylmethylcellulose.
  • customary cosmetic auxiliaries for example alcohols, in particular those of low C number, preferably ethanol and
  • the preparation according to the invention advantageously contains film formers.
  • Film formers for the purposes of the present invention are substances of different composition, which are characterized by the following property: If a film former is dissolved in water or other suitable solvents and the solution is then applied to the skin, it forms a film after the solvent has evaporated which essentially serves to fix the light filters on the skin and thus to increase the water resistance of the product.
  • copolymers of polyvinylpyrrolidone for example, the PVP hexadecene copolymer and the PVP eicosene copolymer, which are among the
  • polystyrene sulfonate sold under the tradename Flexan 130 at National Starch and Chemical Corp. and / or polyisobutene, available from Rewo under the tradename Rewopal PIB1000.
  • suitable polymers are e.g. Polyacrylamides (Seppigel 305), polyvinyl alcohols, PVP, PVP / VA copolymers, polyglycols, acrylate / octylacralymide copolymer (Dermacryl 79).
  • hydrogenated castor oil Dimerdilinoleat (CAS 646054-62-8, INCI Hydrogenated Castor OiI Dimer Dilinoleate), which can be purchased from Kokyu Alcohol Kogyo under the name Risocast DA-H or PPG-3 Benzylethermyristat ( CAS 403517-45-3), which can be obtained under the trade name Crodamol STS from Croda Chemicals.
  • the oil phase of the preparation according to the invention is advantageously selected from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, namely the Triglycehnester of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, especially 12 to 18 C atoms.
  • the fatty acid triglycerides can be selected, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, such as.
  • Cocoglyceride olive oil, sunflower oil, jojoba oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grapeseed oil, thistle oil, evening primrose oil, macadamia nut oil and the like.
  • Also advantageous according to the invention are z.
  • natural waxes of animal and vegetable origin such as beeswax and other insect waxes and berry wax, shea butter and / or lanolin (wool wax).
  • further advantageous polar oil components can furthermore be selected from the group of esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or or unbranched alcohols having a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols having a chain length of 3 to 30 carbon atoms.
  • ester oils can then advantageously be selected from the group consisting of phenethyl benzoate, 2-phenylethyl benzoate, isopropyl lauroyl sarcosinate, phenyl trimethicone, cyclomethicone, dibutyl adipate, octyl palmitate, octyl cocoate, octyl isostearate, octyldodeceyl myristate, octyldodecanol, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n Butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-
  • oil phase can be advantageously selected from the group of dialkyl ethers and
  • Dialkyl advantageous are z.
  • oil component (s) is selected from the group consisting of isoeicosane, neopentyl glycol diheptanoate, propylene glycol dicaprylate / dicaprate, gaprylic / capric / diglyceryl succinate,
  • Advantageous oil components are also z.
  • Butyloctyl salicylate for example that available under the trade name Hallbrite BHB from the company CP Hall
  • tridecyl salicylate which is available under the trade name Cosmacol ESI from the company Sasol
  • C12-C15 Alkyl salicylate available under the trade name Dermol NS from Alzo
  • hexadecyl benzoate and butyl octyl benzoate and mixtures thereof Hallstar AB
  • diethylhexyl naphthalate Hallbrite TQ or Corapan TQ from Symrise
  • the oil phase may also advantageously contain non-polar oils, for example those selected from the group of branched and unbranched hydrocarbons and hydroxides, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes, C13-16 isoparaffin and isohexadecane.
  • non-polar oils for example those selected from the group of branched and unbranched hydrocarbons and hydroxides, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes, C13-16 isoparaffin and isohexadecane.
  • non-polar oils for example those selected from the group of branched and unbranched hydrocarbons and hydroxides, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefin
  • the preparations according to the invention may furthermore advantageously comprise one or more substances from the following group of siloxane elastomers, for example in order to increase the water resistance and / or the sun protection factor of the products:
  • siloxane elastomers which contain the units R 2 SiO and RSiOi , 5 and / or R 3 SiO 0 , 5 and / or SiO 2 , wherein the individual radicals R are each independently hydrogen, C 24 -alkyl (such as, for example, methyl , Ethyl, propyl) or aryl (such as phenyl or ToIyI),
  • Alkenyl (such as vinyl) and the weight ratio of units R 2 SiO to RSiOi i5 is selected from the range of 1: 1 to 30: 1;
  • Siloxane elastomers which are insoluble and swellable in silicone oil obtainable by the addition reaction of an organopolysiloxane (1) containing silicon-bonded hydrogen with an organopolysiloxane (2) containing unsaturated aliphatic groups, the proportions used being such in that the amount of hydrogen of the organopolysiloxane (1) or of the unsaturated aliphatic groups of the organopolysiloxane (2) is in the range from 1 to 20 mol%, if the organopolysiloxane is not cyclic and is in the range from 1 to 50 mol% % is when the organopolysiloxane is cyclic.
  • the siloxane elastomer (s) are in the form of spherical powders or in the form of gels.
  • siloxane elastomers are those with the INCI name dimethicone / vinyl dimethicone crosspolymer, for example available from DOW CORNING under the trade designations DOW CORNING 9506 Powder.
  • siloxane elastomer is used in combination with oils of hydrocarbons of animal and / or vegetable origin, synthetic oils, synthetic esters, synthetic ethers or mixtures thereof.
  • compositions are also obtained when antioxidants are used as additives or active ingredients.
  • the preparations advantageously contain one or more antioxidants.
  • antioxidants all suitable or common for cosmetic applications antioxidants can be used.
  • water-soluble antioxidants can be used, such as vitamins, eg. As ascorbic acid and its derivatives.
  • antioxidants are vitamin E and its derivatives as well as vitamin A and its derivatives.
  • the amount of the antioxidants (one or more compounds) in the preparations is preferably 0.001 to 30 wt .-%, particularly preferably 0.05 to 20 wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.
  • vitamin E and / or its derivatives are the antioxidant (s), it is advantageous to choose their respective concentrations from the range from 0.001 to 10% by weight, based on the total weight of the formulation.
  • vitamin A or vitamin A derivatives, or carotenes or derivatives thereof are the antioxidant (s), it is advantageous if their respective concentrations are in the range from 0.001 to 10% by weight, based on the total weight of the formulation choose.
  • the cosmetic preparations according to the present invention contain cosmetic active ingredients, where preferred active ingredients are antioxidants which can protect the skin against oxidative stress.
  • Inventive formulations which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially ⁇ -glycosyl rutin), coenzyme Q10, vitamin E and / or derivatives and the like, are particularly advantageous for protection against aesthetically unattractive skin Changes, such as Skin aging (such as dryness, roughness, dryness wrinkles, itching, decreased refatting (eg, after washing), visible vascular dilation (telangiectasia, cuperosis), slackness and wrinkle and wrinkle formation, localized hypersensitivity). , Hypo and false pigmentation (eg, age spots), increased susceptibility to mechanical stress (eg, cracking), and the like) and tired skin. Furthermore, they are advantageously suitable against the appearance of dry or rough skin.
  • compositions for the care of the skin they can serve the cosmetic sunscreen, as well as make-up product in decorative cosmetics.
  • cosmetic compositions according to the present invention for example, be used as a skin protection cream, day or night cream, etc. It may be possible and advantageous to use the compositions of the invention as a basis for pharmaceutical formulations.
  • UV-A or UV-B filter substances usually incorporated UV-A or UV-B filter substances.
  • cosmetic preparations which are in the form of a sunscreen.
  • the use of the preparation according to the invention for protection against aging of the skin in particular for protection against UV-related aging of the skin
  • a sunscreen agent for protection against UV-related aging of the skin
  • the preparation according to the invention advantageously has a pH of 5 to 8. This can be adjusted by the conventional acids, bases and buffer systems.
  • the cosmetic preparations according to the invention are applied to the skin and / or the hair in a sufficient amount in the manner customary for cosmetics. Comparative tests
  • the senor is "different” (more slippery, smoother, less waxy) if the lipid is present in the formula:

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

Préparations cationiques à teneur en alcools de Guerbet, qui contiennent une combinaison constituée (a) d'alcools de Guerbet et (b) d'un ou plusieurs émulsifiants cationiques.
PCT/EP2007/009835 2006-11-17 2007-11-14 Préparations cosmétiques contenant des alcools de guerbet Ceased WO2008058720A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006055016.1 2006-11-17
DE102006055016A DE102006055016A1 (de) 2006-11-17 2006-11-17 Kosmetische Zubereitungen mit Guerbetalkoholen

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Publication Number Publication Date
WO2008058720A1 true WO2008058720A1 (fr) 2008-05-22

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PCT/EP2007/009835 Ceased WO2008058720A1 (fr) 2006-11-17 2007-11-14 Préparations cosmétiques contenant des alcools de guerbet

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WO (1) WO2008058720A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8524258B2 (en) * 2008-12-22 2013-09-03 Johnson & Johnson Consumer Companies, Inc. Structured lotions
DE102013209904A1 (de) * 2013-05-28 2014-12-04 Beiersdorf Ag Stabile kosmetische Zubereitung
DE102013209927A1 (de) * 2013-05-28 2014-12-04 Beiersdorf Ag Stabile kosmetische Zubereitung

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB882742A (en) * 1959-02-19 1961-11-22 Chesebrough Ponds Anhydrous germicidal compositions
US4808388A (en) * 1986-08-20 1989-02-28 Merz + Co. Gmbh & Co. Foamable creams
EP0830857A2 (fr) * 1996-08-30 1998-03-25 Henkel Kommanditgesellschaft auf Aktien Compositions cosmétiques
DE19928112A1 (de) * 1999-06-19 2000-12-21 Cognis Deutschland Gmbh Guerbetalkohole
DE19960099A1 (de) * 1999-12-14 2001-06-21 Cognis Deutschland Gmbh Guerbetalkohole

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB882742A (en) * 1959-02-19 1961-11-22 Chesebrough Ponds Anhydrous germicidal compositions
US4808388A (en) * 1986-08-20 1989-02-28 Merz + Co. Gmbh & Co. Foamable creams
EP0830857A2 (fr) * 1996-08-30 1998-03-25 Henkel Kommanditgesellschaft auf Aktien Compositions cosmétiques
DE19928112A1 (de) * 1999-06-19 2000-12-21 Cognis Deutschland Gmbh Guerbetalkohole
DE19960099A1 (de) * 1999-12-14 2001-06-21 Cognis Deutschland Gmbh Guerbetalkohole

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