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WO2007106888A2 - Desinfectant a base d'ozone - Google Patents

Desinfectant a base d'ozone Download PDF

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Publication number
WO2007106888A2
WO2007106888A2 PCT/US2007/064070 US2007064070W WO2007106888A2 WO 2007106888 A2 WO2007106888 A2 WO 2007106888A2 US 2007064070 W US2007064070 W US 2007064070W WO 2007106888 A2 WO2007106888 A2 WO 2007106888A2
Authority
WO
WIPO (PCT)
Prior art keywords
enclosure
ozone
item
sanitizing apparatus
opening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2007/064070
Other languages
English (en)
Other versions
WO2007106888A3 (fr
Inventor
Eugene I. Gordon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Germgard Lighting LLC
Original Assignee
Germgard Lighting LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Germgard Lighting LLC filed Critical Germgard Lighting LLC
Publication of WO2007106888A2 publication Critical patent/WO2007106888A2/fr
Publication of WO2007106888A3 publication Critical patent/WO2007106888A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/0005Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor for pharmaceuticals, biologicals or living parts
    • A61L2/0082Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor for pharmaceuticals, biologicals or living parts using chemical substances
    • A61L2/0094Gaseous substances
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/20Gaseous substances, e.g. vapours
    • A61L2/202Ozone

Definitions

  • This invention relates to an ozone based sanitizer, and more particularly to a sanitization device having a sealable enclosure that can be filled with ozone to sanitize the contents contained therein.
  • Ozone is known to kill pathogens quickly by processes that are not completely characterized for each pathogen. However, it is known that ozone can kill or deactivate all transient flora and pathogens, including all spores and possibly prions.
  • Kowalski describes in vitro experiments on rates of deactivation of bacterial cultures grown on the agar surface of petri dishes that have been ozonated.
  • Colony forming units (CFUs) on control petri dishes are compared to those on ozonated petri dishes to obtain survival fractions as a function of exposure times (e.g., 'death curve'), which is a standard in vitro time/kill-efficacy study technique.
  • 'death curve' a standard in vitro time/kill-efficacy study technique.
  • Kowalski observes that if the concentrations of ozone in air at atmospheric conditions can be low enough to meet OSHA limits (i.e., 0.1 parts per million in room air) it can be used to deactivate pathogens in room air.
  • Kowalski further speculates that ozone can be used to sterilize surfaces of medical equipment.
  • ozone results in exposure that is very close to 100% including hidden areas, folds, and crevices of the skin and other objects. Exposing one's hands to ozone can substantially expose the fingernail crevice, which has positive implications due to the localized concentration of pathogens and contaminants.
  • United States patent 6,254,625 to Rosenthal et al. describes a hand sanitation apparatus based on ozone and UVC.
  • the apparatus described is the size of a small refrigerator and produces ozone from air by UVC radiation from germicidal lamps.
  • Rosenthal describes no process for preventing ozone from entering room air, which is critical to the safety of using such a device. What is needed in the art is an easy, quick, and effective hand sanitation technique that is not associated with common skin irritation and problems and does not result in unacceptable levels of ozone in the surrounding environment
  • a sanitizing apparatus comprising an enclosure, and inlet connector and an exhaust-outlet.
  • the enclosure is substantially impermeable to ozone and has an inner volume and a sealable opening.
  • the sealable opening can be open to receive an item being inserted into the enclosure or closed to form an airtight volume in the enclosure.
  • the inlet connector is attached to the enclosure and can be used to introduce ozone into the enclosure to sanitize the item placed therein.
  • the exhaust-outlet is also attached to the enclosure and can be used to release the gas from the enclosure once the sanitization process is complete.
  • a method of sanitizing using ozone is provided.
  • an item is inserted into an enclosure having an inlet-connecter, an exhaust-outlet, and a sealable opening.
  • the opening is sealed after insertion of the item to form a substantially air tight barrier around the item.
  • the inlet-connector is connected to an ozone source and used to fill the enclosure with ozone to sanitize the item.
  • the ozone is allowed to convert into a resulting oxygen gas mixture, and released from the enclosure through the exhaust-outlet.
  • Figure 1 illustrates one embodiment of the invention including a pouch that encloses a user's hands;
  • Figure 2 illustrates one embodiment of the invention in which a pouch is used in combination with an ozone hood having a vacuum pump to prevent ozone from escaping the hood enclosure;
  • Figure 3 illustrates one embodiment of the invention comprising an ozone hood having a deformable opening
  • Figure 4 illustrate one embodiment of the invention that can be worn as a cuff around a users arm.
  • the present invention comprises an enclosure into which an item can be inserted and sterilized.
  • an item to be sanitized is inserted into a sealable opening in the enclosure.
  • the enclosure is then sealed to completely enclose the item or surround the item, such that a portion of the item projects out of the enclosure.
  • the enclosure is then filled with ozone which sanitizes the portion of the item inserted therein.
  • the ozone breaks down into oxygen.
  • the sanitizer 100 includes an enclosure 110 that receives an item to be sanitized.
  • Figure 1 illustrates the sanitizer 100 being used to sanitize a user's hand 190. While the invention is discussed below with respect to the sanitization of a user's hand, it would be appreciated by one of skill in the art that other bodily extremities or inanimate items can be sanitized using the sanitizer 100.
  • the enclosure 110 illustrated in Figure 1 includes a sealable opening 160.
  • the opening 160 is preferably sized to accommodate a variety of objects. However, it can optionally be shaped and/or sized to accommodate a specific application.
  • the opening 160 can be circular and sized slightly larger than the average human forearm.
  • the opening 160 can be easily sealed around the forearm while the hand 190 is inserted in the enclosure 110.
  • the enclosure 110 is designed to be quickly removed or pulled on by a user.
  • the sealable opening 160 can include a fitting to create an airtight seal, such as a snap or elastic fitting.
  • the enclosure 110 further includes and inlet-connector 120 that is used to fill the enclosure 110 with ozone.
  • the inlet-connector 120 can be connected to an ozone source 130 whereby ozone can be introduced into the interior of the enclosure 110.
  • the inlet- connector 120 preferably includes a valve 180, such as a Schrader valve, to prevent any gas contained within the sealed enclosure 110 from leaking into the surrounding environment. Furthermore, the valve 180 can ensure the ozone is not unintentionally discharged from the ozone source 130.
  • the enclosure 110 can accommodate various shapes and materials as required by the intended application or generic design.
  • the enclosure 110 can be made from a flexible material (e.g., polyethylene) that can expand as ozone is released through the inlet connector 120 from the ozone source 130 into the enclosure 110.
  • a flexible material e.g., polyethylene
  • an enclosure 110 made of a flexible material permits a user's hand 190 a degree of tactile sensation through the enclosure 110 as well as the ability to manipulate objects outside the enclosure 110.
  • a further increased level of dexterity can be provided by shaping the enclosure 110 as a mitten or a glove into which a user's hand 190 can be inserted.
  • a glove-shaped, flexible enclosure 110 permits a user to manipulate the inlet- connector 120 and the ozone source 130 while the user's hands are inserted in the enclosure 110.
  • the enclosure 110 can be filled with ozone from the ozone source 130.
  • a flexible enclosure 110 provides a visual indication of the pressure and ozone contained therein by the swelling of the enclosure 110.
  • the enclosure 110 can include a pressure gage to measure the pressure in the enclosure 110.
  • the ozone source 130 can be provided through various solutions.
  • Figure 1 illustrates a pressurized cartridge based ozone source 130 solution.
  • Cartridges can be filled with ozone at a central location and distributed throughout the environment in which the sanitizer 100 will be used.
  • a user can have easy access to an ozone source 130 as necessary.
  • the cartridge can be portable and carried by a user from site to site.
  • Ozone made from relatively pure oxygen can deactivate pathogens faster than ozone made from air because the greater partial pressure of ozone in the gas.
  • the partial pressure of oxygen in air is 21%, which limits the potential ozone concentration.
  • a high concentration results if oxygen alone is used to make the ozone. For example, a 10% concentration, 100,000 ppm is highly effective.
  • a relatively high concentration and high partial pressure of ozone both contribute to enhancing the deactivation rate of the ozone. This can greatly decrease the time required to achieve hand sanitization or sterility.
  • Ozone has a limited lifetime as it breaks down into oxygen molecules. Ozone's half- life depends in part on its temperature and surroundings. The following table illustrates the half-life of ozone as a function of temperature, when there are no other influences.
  • ozone can be produced on demand, or near the time of use.
  • a plastic, airtight cartridge can be filled with oxygen, preferably medical grade, at elevated pressure.
  • the oxygen filled cartridge would have a very long storage lifetime, and can be converted to ozone on or near the day of use.
  • the conversion from oxygen to ozone can be accomplished by disposing a coaxial pin within the cartridge that can be excited with an RF voltage, thereby initiating a corona or Tesla discharge internal to the cartridge. The discharge converts the O 2 (oxygen) to O 3 (ozone). If the walls of the cartridge are relatively transparent one can observe the color change to the light blue that is characteristic of ozone.
  • the ozone can then be transferred to the enclosure 110 using the valve 180 of the inlet-connector 120 controlling the pressure.
  • the cartridge can be used multiple times since not all the ozone is transferred.
  • new ozone can be created on subsequent days by reapplying the RF voltage.
  • an ozone source can be placed in each room in which it is needed.
  • the ozone source can include a small, closed, discharge and storage volume (DSV) with a pressure gauge.
  • the DSV preferably contains an electrode that supports an RF corona type discharge.
  • Medical grade oxygen from an oxygen cartridge or a small oxygen storage tank is connected to the DSV to let oxygen into the DSV at a prescribed pressure greater than atmospheric. No ozone is transferred into the DSV, and no pump is needed.
  • the electrical discharge takes place in relatively pure oxygen and some of the oxygen within the volume is converted to ozone.
  • the pressure decreases as a result of the conversion to ozone and the measured internal pressure of the DSV indicates conversion.
  • the lifetime of the ozone in the box can be several hours at room temperature.
  • the pressure within the DSV after all oxygen has been converted to ozone is preferably above atmospheric to ensure that the enclosure 110 inflates with an ozone/oxygen mixture.
  • the inlet-connector can be disconnected from the ozone source.
  • the ozone then begins to convert to oxygen (two ozone molecules become three oxygen molecules) and the pressure in the enclosure 110 increases. The increased pressure indicates that the process of killing pathogens is complete.
  • the resulting gas mixture in the enclosure 110 is eliminated by activating an exhaust-outlet 140.
  • the exhaust-outlet 140 preferably includes a filter of charcoal, or other catalyst which completely converts the ozone to oxygen.
  • the exhaust- outlet 140 includes a sintered plug heated to high temperature which increases the rate of conversion from ozone to oxygen. Effectively, a minimal amount of ozone is released in the air.
  • the user's hand 190 is then removed from the enclosure 110. It can be desirable to sanitize both hands 190 of a user at the same time.
  • the sanitizer 100 is readily adapted to this task.
  • An optional inter-connect 150 that allows the passage of gases can be used to connect two enclosures 110 together.
  • a user can place one hand 190 in each enclosure 110 and the ozone released from the ozone source 130 will fill both enclosures 110.
  • the enclosures 110 can be glove- shaped and made from a flexible material, the user can still independently manipulate the inlet-connector 120, ozone source 130, and exhaust-outlet 140.
  • Ozone can reduce the surviving fraction of hand pathogens can to less than 10 "4 with an exposure of no more than a few seconds.
  • ozone does not cause cancer or any other serious damage to the skin. Minor irritations resulting from ozone exposure, similar to those associated with hand washing and alcohol rubs, can be treated Vitamin E based skin emollients. However, ozone does not crack or dry the skin, or cause allergic reactions and rashes.
  • the rate of a chemical reaction between a single pathogen and surrounding ozone molecules is proportional to the concentration of ozone molecules. While ozone exposure is clearly effective at sanitizing, it requires contact exposure to oxidize pathogens. A small fraction of pathogens clump together and tend to screen one another from the ozone so that the deactivation rate is lower. However, unclumped pathogens are quickly deactivated.
  • One way to reduce clumping is to rub the hands together, or rub the item being sanitized.
  • the friction created by rubbing causes surface pathogens to slough off and expose previously shielded pathogens or to break up clumps.
  • a further way to address clumping is the use of vibrations, and in particular ultrasonic energy, such as that used for ultrasonic cleaning.
  • the introduction of vibrational energey to reduce clumping increases the level of deactivation and reduces the necessary ozone exposure time.
  • the enclosure 110 can include a vibrational coupler 170 which allows introduction of vibrational (e.g., ultrasonic) energy at high intensity into the enclosure 110 containing the hands.
  • vibrational sources such as ultrasonic transducers can be included on the ozone source.
  • the enclosure 110 can be placed against the ozone source for both ozone filling and providing ultrasonic energy.
  • piezoelectric transducers at 40 KHz, about 1 cm in diameter, are commonly used in commercial ultrasonic cleaners. Such transducers would produce acoustic energy that is inaudible and at an intensity that is not damaging to the human ear.
  • the 40 KHz, ultrasonic radiation can be introduced into the pouch through a low loss, vibration coupler 170 in the enclosure 110 wall. Ultrasonic energy can thus be directed directly into the hand, for example by virtue placing a finger against the coupler
  • Human tissue being comprised of mostly water, readily transmits the acoustic energy and vibrates the skin surface thereby dec lumping pathogens on the skin as the ozone in the enclosure 110 sanitizes.
  • FIG. 1 illustrates an embodiment of the invention that includes a gas exhaust system.
  • the user's hand 290 is inserted through a sealable opening 260 into an enclosure 210, such as a glove or pouch having an inlet-connector 220.
  • the enclosure 210 is then inserted into a second enclosure 280 through an opening 265.
  • the second enclosure 210 can be integrated with the ozone source 230 and vibrational energy source 270.
  • An exhaust apparatus 235 such as a small vacuum pump or fan, can be included in the second enclosure 280.
  • the exhaust apparatus moves air into the opening 265 and out an exhaust outlet 240.
  • any ozone that escapes the enclosure 210 is moved away from the user and vented through exhaust outlet 240, which is preferably located opposite the user.
  • the exhaust outlet 240 can include a filter 245 that increases the conversion of ozone to oxygen. Filters for the exhaust sintered from a variety of materials, for example stainless steel or activated carbon particles, provide good catalysts for converting ozone to oxygen. This conversion can be further enhanced by heating the filter, for example to a temperature greater than 250 degrees C.
  • the second enclosure 280 can also include a heat source 250 along the interior of the enclosure to further convert any ozone that leaks from the first enclosure 210 to oxygen.
  • the heat source can 250 include incandescent light bulbs or other heating elements known in the art.
  • the exhaust apparatus of the sanitizing device 200 makes the system substantially ozone leak-proof.
  • the enclosure 210 preferably remains within the second enclosure 280 during the treatment period for protection against a leak and for the ultrasonic input provided by the vibrational coupler 270 for declumping. This configuration allows for higher concentrations of ozone to be provided by the ozone source 230 because the danger of a potential leak is virtually eliminated
  • the enclosure 310 can include a deformable elastic opening 360 that provides a nominal seal to gas flow.
  • the enclosure 310 can be a rigid or flexible structure.
  • the user inserts a hand
  • the opening 360 can be shaped to provide an opening smaller than a user's forearm or wrist. Thus, the user must stretch the opening to insert the hand 390 and the opening will be flush and tight around the user's extremity thereby preventing leaks.
  • the opening 360 ring can then be inflated to form an air tight seal with the user's extremity.
  • the ring can be deflated so that the user's hand can be removed from the enclosure 310 through the opening 360 without rubbing against the side of the opening 360. Thus the risk of cross contamination is reduced.
  • any opening 360 of sufficiently large diameter or perimeter which can be closed around the forearm or wrist during sanitization and withdrawn after the process is completed can decrease the risk of cross contamination.
  • the sealable opening is preferably made of a material that is not damages by ozone, such as Teflon.
  • the sanitizing device 300 can provide this benefit by including two openings 360.
  • Each opening 360 can include its own elastic opening that seals the interface of the opening 360 and the user's wrist of forearm.
  • the enclosure 310 can also include vibrational transducers (e.g., ultrasonic transducers 370.
  • vibrational transducers e.g., ultrasonic transducers 370.
  • the ultrasonic transducers 370 can be used to initiate the sanitization process.
  • the capacity for ozone to deactivate pathogens can be increased through the introduction of water vapor.
  • Ozone in a high humidity ambient is known to be highly effective at deactivating pathogens.
  • the dominant contributor is the production of hydroxyl ions, which are more effective at oxidizing pathogens than ozone.
  • hydroxyl ions are generally short lived so do not pose a health or safety risk to the user.
  • Water vapor can be introduced by evaporation or injection into the enclosure through the inlet-connector 340 similar to the introduction of ozone. Alternatively it can be applied in the ozone storage volume.
  • Figure 4 illustrates a further use of the sanitizing device 400 that provides easy access and fast application.
  • the device 400 can include an enclosure 410 made of a flexible material, such as lightweight polyethylene, that can be worn like a cuff on the forearm of the user's arm.
  • the enclosure 410 has elastic fitting 450 that provides an airtight seal around the forearm. When the enclosure is pulled forward and the opening 460 sealed, by way of a zipper or reusable adhesive, it forms a closed volume around the hand 490 of the user.
  • Ozone can be introduced into the enclosure 410 through inlet-connector 420.
  • the hand is sanitized and the ozone converts into oxygen.
  • the enclosure 410 will expand as the ozone is converted to oxygen.
  • the ozone can be released from the enclosure 410 through the exhaust-outlet 440.
  • the sealable opening 460 is opened and the enclosure 410 cuff is pulled back.
  • the procedure utilized by the device 400 greatly reduces the risk of recontamination.
  • the enclosure and opening can be adapted to receive various bodily extremities such as a user's foot.
  • the sanitizing device can be used to treat athlete's foot or nail fungi using a foot pouch or enclosure similar to the glove for the hands.
  • a body pouch can also be designed to wrap around portions of the body to treat large area wounds or burns.
  • the sanitizing device can be used to sanitize inanimate objects. For example, it is crucial to sanitize surgical devices before they can be reused. Ozone sanitization can be used to locally and quickly sterilize these surgical/medical instruments.
  • the sanitization device is used as described above. However, the opening of the enclosure is sealed to surround the item.

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

La présente invention concerne un appareil désinfectant qui possède une enceinte, et un raccord d'entrée et une sortie d'évacuation. L'enceinte de l'appareil est sensiblement imperméable à l'ozone et possède un volume intérieur et une ouverture qui peut être fermée de façon hermétique. Des articles inanimés ou extrémités corporelles d'utilisateur peuvent être insérés dans l'ouverture qui peut être fermée de façon hermétique pour former une barrière étanche à l'air autour de ou avec l'article inséré. De l'ozone peut être introduit dans le volume intérieur à travers le raccord d'entrée. Des pathogènes sur la surface de l'article sont désactivés par l'exposition à l'ozone. Des pathogènes groupés peuvent être décomposés à l'aide d'énergie vibratoire ou frottement. Une fois désinfecté, le mélange gazeux à base d'oxygène contenu dans l'enceinte peut être libéré à travers la sortie d'évacuation. Des catalyseurs, tels que des filtres de carbone et de la chaleur, peuvent être utilisés pour garantir que tout l'ozone s'est décomposé en oxygène. L'appareil désinfectant est sûr, rapide, et efficace.
PCT/US2007/064070 2006-03-15 2007-03-15 Desinfectant a base d'ozone Ceased WO2007106888A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US78298806P 2006-03-15 2006-03-15
US60/782,988 2006-03-15

Publications (2)

Publication Number Publication Date
WO2007106888A2 true WO2007106888A2 (fr) 2007-09-20
WO2007106888A3 WO2007106888A3 (fr) 2007-12-13

Family

ID=38510288

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/064070 Ceased WO2007106888A2 (fr) 2006-03-15 2007-03-15 Desinfectant a base d'ozone

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Country Link
WO (1) WO2007106888A2 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8278628B2 (en) * 2007-04-03 2012-10-02 Timothy Hamilton Apparatus and process for sterilization and preservation of objects
WO2016112922A1 (fr) * 2015-01-16 2016-07-21 Scan Unic Aps Appareil, procédé et produit logiciel pour désinfection de main par application d'eau ozonée
EP3167959A4 (fr) * 2015-07-07 2018-05-23 Airtech Japan, Ltd. Enceinte de sécurité et procédé de décontamination d'enceinte de sécurité
CN110548159A (zh) * 2019-10-12 2019-12-10 宁波慈溪小家电创新设计研究院有限公司 一种投入式消毒机
EP3858389A1 (fr) * 2020-01-27 2021-08-04 Smart Cleaner AS Appareil de désinfection des mains et procédé de fonctionnement
IT202000019804A1 (it) 2020-08-07 2022-02-07 Tecnoscan Int S R L Dispositivo di sanificazione mediante ozono, preferibilmente dispositivo per la sanificazione delle mani, e metodo di sanificazione associato
IT202200014800A1 (it) * 2022-07-14 2024-01-14 Michele Marzella Dispositivo per la sanificazione degli arti superiori

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6764659B2 (en) * 1996-06-26 2004-07-20 Ozontech Ltd. Ozone applications for disinfection, purification and deodorization
JP3903564B2 (ja) * 1998-01-16 2007-04-11 松下電器産業株式会社 手乾燥装置
US6343425B1 (en) * 1999-05-06 2002-02-05 Intecon Systems, Inc. Measurement and cleaning of elastomeric articles having particulate adhered thereto
US6872366B2 (en) * 2001-08-17 2005-03-29 Marhoc, Inc. Method and apparatus for using ozone as disinfectant

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8278628B2 (en) * 2007-04-03 2012-10-02 Timothy Hamilton Apparatus and process for sterilization and preservation of objects
WO2016112922A1 (fr) * 2015-01-16 2016-07-21 Scan Unic Aps Appareil, procédé et produit logiciel pour désinfection de main par application d'eau ozonée
US11058782B2 (en) 2015-01-16 2021-07-13 Scan Unic Aps Apparatus, method, system and software product for hand sanitisation
EP3167959A4 (fr) * 2015-07-07 2018-05-23 Airtech Japan, Ltd. Enceinte de sécurité et procédé de décontamination d'enceinte de sécurité
CN110548159A (zh) * 2019-10-12 2019-12-10 宁波慈溪小家电创新设计研究院有限公司 一种投入式消毒机
EP3858389A1 (fr) * 2020-01-27 2021-08-04 Smart Cleaner AS Appareil de désinfection des mains et procédé de fonctionnement
IT202000019804A1 (it) 2020-08-07 2022-02-07 Tecnoscan Int S R L Dispositivo di sanificazione mediante ozono, preferibilmente dispositivo per la sanificazione delle mani, e metodo di sanificazione associato
IT202200014800A1 (it) * 2022-07-14 2024-01-14 Michele Marzella Dispositivo per la sanificazione degli arti superiori

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