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WO2007036157A1 - Appareil de mélange et de réaction - Google Patents

Appareil de mélange et de réaction Download PDF

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Publication number
WO2007036157A1
WO2007036157A1 PCT/CN2006/002565 CN2006002565W WO2007036157A1 WO 2007036157 A1 WO2007036157 A1 WO 2007036157A1 CN 2006002565 W CN2006002565 W CN 2006002565W WO 2007036157 A1 WO2007036157 A1 WO 2007036157A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixing
fluid
reaction apparatus
flow guiding
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2006/002565
Other languages
English (en)
Chinese (zh)
Inventor
Youqi Wang
Xianzhong Zhao
Sibiao Xu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Accelergy Shanghai R & D Center Co Ltd
Original Assignee
Accelergy Shanghai R & D Center Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Accelergy Shanghai R & D Center Co Ltd filed Critical Accelergy Shanghai R & D Center Co Ltd
Publication of WO2007036157A1 publication Critical patent/WO2007036157A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1812—Tubular reactors
    • B01J19/1843—Concentric tube
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/27—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
    • B01F27/272—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed axially between the surfaces of the rotor and the stator, e.g. the stator rotor system formed by conical or cylindrical surfaces
    • B01F27/2722—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed axially between the surfaces of the rotor and the stator, e.g. the stator rotor system formed by conical or cylindrical surfaces provided with ribs, ridges or grooves on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
    • B29B7/401—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft having a casing closely surrounding the rotor, e.g. with a plunger for feeding the material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
    • B29B7/405—Mixing heads
    • B29B7/407—Mixing heads with a casing closely surrounding the rotor, e.g. with conical rotor

Definitions

  • the present invention relates to a mixing and reaction apparatus, and more particularly to a mixing and reaction apparatus which can sufficiently mix a substance to be treated or sufficiently mix a substance to be treated to be sufficiently reacted.
  • Microreaction technology is a method and technique for applying the inherent advantages of microstructures to physical or (and) chemical processes, and devices or devices embodying such techniques are referred to as microreactors.
  • a microreactor is a miniaturized physical or (and) chemical reaction system with a unit reaction interface dimension on the order of microns. It is a micro-chemical technology that emerged in the 1990s.
  • the reaction interface of the microreactor is at least one dimension up to the order of microns, typically tens to hundreds of microns.
  • the effects of certain properties of matter will be very different from the macroscopic state.
  • the diffusion process is often the bottleneck of the chemical process and is difficult to control.
  • the diffusion process and its effects may be easier to control.
  • the diffusion coefficient of the protein is relatively small (the diffusion coefficient in water at normal temperature is about 8 * 10- 7 cm2 / s) , the diffusion may take up to ten days through a tube 1 cm in diameter, 10 microns by diffusion but The micropipe takes only one second. Therefore, in the microreactor system, the benefits of size reduction can be fully utilized to fabricate devices such as micromixers.
  • the area to volume ratio of the reactants also varies greatly, giving the microreactor the advantages that the macroreactor does not have:
  • the volume is small, and the reactant consumption is small.
  • the volume of the microreactor is much smaller than that of the conventional reactor system. Due to the small volume of the microreactor, a reaction process can be completed with only a small dose of the reaction. This feature has outstanding advantages for R&D reactors.
  • the reaction speed is fast. Since the space size of the microreactor is at least one dimension on the order of micrometers, the molecular diffusion distance is short, and the mass transfer is fast, so that the reactants can be quickly contacted, mixed and reacted quickly. Therefore, the reaction rate of the microreactor system is usually much higher than that of the conventional reactor.
  • the channel is generally laminar, and the fluid flow state is easy to control.
  • the reactor is small in volume, and the heat exchange between the reactants and the outside can be very rapid, and it is easy to confirm this.
  • the reaction temperature is controlled precisely to control the reaction rate.
  • rapid heat exchange is possible, some reactions that cannot be performed in a conventional reactor, such as rapid exothermic, flammable and explosive reactions, can be carried out in a microreactor.
  • the microreactor can realize "digital amplification", that is, one channel represents a reactor, and its amplification is only a superposition of numbers, avoiding the amplification effect of the conventional amplification process. Thanks to its "amplification and amplification" characteristics, the microreactor unit has both the stability required for continuous reaction and flexible production adjustment for on-demand production.
  • microreactors can improve the yield and selectivity of chemical reactions, ensure the safety of the reaction and reduce environmental problems; can greatly reduce the development cost, shorten the development cycle; realize the automation and efficiency of chemical experiments.
  • a microreactor is disclosed in U.S. Patent No. 6,938,687, which includes a stator provided with a cylindrical bore and a cylindrical rotor which is coaxially mounted in a cylindrical bore of the stator.
  • the opposite cylindrical faces of the rotor and the stator form a narrow annular cavity into which the fluid is injected.
  • the rotor rotates at a high speed, and the large shear force drives the relative movement of the fluid to mix the fluid.
  • the bottom of the rotor of the prior art microreactor is conical. During the rotation of the rotor, due to gravity, fluid that has not been sufficiently mixed often flows out from the bottom outlet of the annular chamber, affecting the mixing and reaction effects.
  • a common method is to install a valve at the bottom outlet.
  • the fluid in the dead zone 900 cannot be sufficiently mixed to become a waste liquid, resulting in waste of raw materials.
  • the conical rotor bottom has high precision and difficult machining.
  • microreactor is disclosed in U.S. Patent No. 6,742,774.
  • the structure of the microreactor is similar to the prior art microreactor described above, except that the fluid is fed into the annular chamber from the side wall of the microreactor near the bottom, and is output from the top side wall of the microreactor, and the bottom of the rotor is close to the outlet. flat.
  • the centrifugal force at the bottom of the flat rotor causes the fluid to slant toward the side wall of the microreactor in the tangential direction of the rotor, and since the outlet is disposed at the side wall, part of the fluid is drawn into the outlet.
  • a valve is also installed at the output port.
  • the rotor rotates at high speed, close the valve to prevent fluid leakage.
  • the fluid in the blind zone cannot be sufficiently mixed to become a waste liquid, which obviously also causes waste of raw materials.
  • Another object of the present invention is to provide a mixing and reaction apparatus which can sufficiently mix all the materials to be treated.
  • a third object of the present invention is to provide a mixing and reaction apparatus which can control the retention time of an object to be treated therein.
  • an aspect of the present invention provides a mixing and reaction apparatus comprising: a reaction portion and a driving portion, the reaction portion including a first member and a second member, wherein the first member is provided with a columnar hole for accommodating the second member
  • the portion of the second component received in the first component is cylindrical, forming an annular passage between the first and second components, and the second component is rotated relative to the first component, wherein: the second component is provided with rotation The bottom that moves the fluid radially outward.
  • the distance between the bottom of the second component and the first component reaches a micrometer.
  • the bottom of the second component is provided with a protrusion or a concave body.
  • the protrusion or the concave body is stripe-shaped.
  • the protrusion or the concave body has a dot shape.
  • the bottom shape includes but is not limited to the following shapes, for example, it may be substantially flat, or may be a hemispherical surface, or a semi-ellipsoidal surface, or a curved surface, etc.
  • the surface of the curvature may also be a cone or a frustum body.
  • the second component of the mixing and reaction device of the present invention is provided with a bottom portion which can move the fluid radially outward when rotated, and the distance between the bottom and the first member is on the order of micrometers, which can be effective
  • the fluid is raked to the vertical portion of the channel to prevent fluid from entering the mixing dead zone and to control the retention time of the fluid within the channel so that all fluids within the device are well mixed.
  • Figure 1 is a schematic view of the structure of the prior art.
  • Figure 2 is a schematic view showing the structure of the mixing and reaction apparatus of the present invention.
  • Figure 3 is a partial schematic view of the mixing and reaction apparatus of the present invention.
  • Figure 4 is a schematic view showing the structure of the second member of the mixing and reaction apparatus of the present invention.
  • Figure 5 is a schematic view of the bottom structure of the second component of the mixing and reaction apparatus of the present invention.
  • Figure 6 is a schematic illustration of another configuration of the bottom of the second component of the mixing and reaction apparatus of the present invention.
  • Figure 7 is a cross-sectional view showing a reaction portion of another embodiment of the present invention.
  • Figure 8 is a schematic cross-sectional view showing a reaction portion according to still another embodiment of the present invention. detailed description
  • the mixing and reaction apparatus of the present invention is used to sufficiently mix the materials to be treated or to sufficiently react the materials to be sufficiently reacted.
  • the material to be treated may be a fluid having one component, or may be a mixed fluid having a plurality of components, wherein the fluid may be a gas, a liquid, a colloid, a solid particle or a powder, etc., as long as the shape of the fluid can follow the fluid containing the fluid. It is only necessary to change the shape of the container, and at least one liquid is included in a group of the objects to be treated which enter the mixing and reaction apparatus of the present invention.
  • the mixing and reaction device of the invention can completely dissolve the soluble solid or liquid in the solvent to form a uniform solution, for example, adding a catalyst to the solution; and temporarily dispersing the insoluble solid particles or gas in the solvent to form a suspension.
  • a slightly soluble liquid in a solvent to form an emulsion, such as an adequate Mixing water and fuel to create new energy savings Fuel, solvent extraction or rejection of specific components from crude oil, etc.; Promote sufficient convection of the reactants, reduce local concentration differences, and complete the reaction, such as mixing the immiscible liquid and gas to complete reaction, etc.; Reduce the local temperature difference, so that the heat dissipation is uniform and the temperature of the solution is kept consistent; the biomaterial with higher viscosity can also be made
  • bio-derived feedstock is thoroughly mixed or reacted with other raw materials; it can also be used to develop graft polymers, ionic liquids, nanomaterials, and the like.
  • the mixing and reaction apparatus of the present invention includes a reaction portion and a driving portion 12.
  • the reaction portion includes a first member 15 and a second member 16, wherein the first member 15 is a stator that is stationary, and the second member 16 is a rotor that can rotate at a high speed.
  • the first element 15 and the second element 16 are cylindrical bodies, the first element 15 is provided with a cylindrical hole along its cylindrical axis direction, and the second element 16 is mounted in the cylindrical hole of the first element 15 and An element 15 is coaxial, thereby forming a narrow annular passage 17 between the first member 15 and the second member 16 that can accommodate fluid.
  • the channel 17 is at least one dimension up to the order of meters.
  • the thickness of the channel 17 is on the order of micrometers, which may be several tens of micrometers to several thousand micrometers.
  • the thickness of the channel 17 can be set to 50 to 80 micrometers. 120 ⁇ 130 microns, 200 microns, 350 microns, 1000 microns, 2000 microns, 3000 microns, etc.
  • the top of the passage 17 is provided with two inlets 30, 31 for inputting the object to be treated to the passage 17, and the bottom is provided with an outlet 18, and the inlets 30, 31 and the outlet 18 can be arranged in the passage according to actual needs. 17 other locations.
  • the inlets 30, 31 and the outlet 18 are each in communication with the passage 17, which may be any element such as a tube or valve that allows the object to be treated to enter or exit the passage 17.
  • the inlets 30, 31 and the outlet 18 may be the same element or arrangement, or may be different elements or arrangements.
  • the outlet 18 can be disposed on the central axis of the passage 17.
  • the second member 16 has a bottom 169.
  • the bottom 169 surface is a flat surface.
  • the distance between the bottom 169 and the bottom of the stator i.e., the horizontal portion of the channel 17
  • the thickness of the horizontal portion of the channel 17 can be set to 50 ⁇ 80 microns, 120 ⁇ 130 microns, 350 microns, 1000 microns, 2000 microns, 3000 microns, etc.
  • the centrifugal force provided by the second member 16 produces a radial component that causes the fluid in the horizontal portion of the passage 17 to flow centrifugally along the tangential direction of the bottom 169 of the second member 16, radially Flowing toward the side wall of the first element 15 to seal the fluid in the vertical portion of the passage 17,
  • the fluid in the passage 17 enters the horizontal portion or (and) the outlet 18 of the passage 17, thus preventing fluid from entering the mixing dead zone, allowing all of the fluid within the passage 17 to be thoroughly mixed or (and) reacted.
  • the bottom 169 surface may also be a curved surface having a curvature as long as the bottom 169 provides sufficient centrifugal force to move the fluid radially.
  • a first flow guiding portion 161 may be disposed on the bottom 169 of the second member 16 for accelerating the radial flow of the fluid.
  • the first flow guiding portion 161 may be integrally formed on the surface of the bottom portion 169 by mechanical processing, electroetching, photolithography or the like, or may be attached to the surface of the bottom portion 169 by plating, strong bonding or the like.
  • the first flow guiding portion 161 may be in any form, for example, it may be a projection provided on the surface of the bottom portion 169, or may be a concave body.
  • the degree of convexity and concavity of the first flow guiding portion 161 on the surface of the bottom portion 169 may be about 1% to 300% of the average thickness of the channel 17, for example, when the thickness of the channel is set to 100 ⁇ m, the first flow guiding portion 161
  • the distance between the most convex portion and the most concave portion in the axial direction of the bottom portion 169 of the second member 16 may be about 1 micrometer to 300 micrometers.
  • the degree of convexity and concavity of the first flow guiding portion 161 may be preferably set to about 5% to 100% of the thickness of the channel 17, and more preferably set to 10% to 30% of the thickness of the channel 17. about.
  • the degree of convexity and concavity of the first flow guiding portion 161 on the surface of the bottom portion 169 may be the same or different.
  • the density of the first flow guiding portion 161 on the surface of the bottom portion 169 may be set to be less than 50%.
  • the first flow guiding portion 161 may preferably occupy 1% to 40% of the surface area of the bottom portion 169.
  • the first flow guiding portion 161 may be of any shape. For example, it may be an array of a plurality of dots, which may be continuous stripes or intermittent stripes, or may be composed of dots and stripes.
  • the first flow guiding portions 161 may be randomly arranged on the surface of the bottom portion 169 or may be regularly arranged.
  • the direction of the strip-shaped first flow guiding portion 161 may be arbitrary as long as it is not parallel to the circumferential direction of the bottom portion 169.
  • the stripe-shaped first flow guiding portion 161 may extend from the center of the bottom portion 169 to the edge of the peripheral circumferential surface of the bottom portion 169, or may extend intermittently to the edge of the peripheral circumferential surface.
  • the plurality of stripes may be equally spaced or unequal, and there may be intersections between the plurality of stripes.
  • the first flow guiding portion 161 includes, but is not limited to, a plurality of consecutive equally spaced stripes as shown in Figs.
  • the cross-sectional shape of the first flow guiding portion 161 includes, but is not limited to, any polygonal shape such as a triangle, a trapezoid, a square, or the like, a semicircular shape, a semi-elliptical shape, or the like, or any combination of the above shapes.
  • the trend direction of the first flow guiding portion 161 may be arbitrary as long as the trend direction is overall Similarly, it is sufficient to generate a thrust in the direction of the flow.
  • the thrust creates a radial component that is parallel to the radius of the first element 15 and urges the fluid to flow in a radial direction.
  • the fluid in the horizontal portion of the passage 17 is caused to flow radially toward the side wall of the first member 15, thereby sealing the fluid in the vertical portion of the passage 17, preventing fluid within the passage 17 from entering the horizontal portion of the passage 17 or (and) the outlet 18.
  • the second component 16 facing the sidewall of the channel 17 may be provided with a second flow guiding portion 160, and the second guiding portion 160 may be integrally formed on the surface of the second component 16 by machining, electroetching, photolithography or the like. Further, it may be attached to the surface of the second member 16 by plating, strong bonding, or the like.
  • the second flow guiding portion 160 may be in any form, for example, may be a projection provided on the surface of the second member 16, or may be a concave body.
  • the degree of convexity and concavity of the second flow guiding portion 160 on the surface of the second element 16 may be about 1% to 300% of the average thickness of the channel 17, for example, when the thickness of the channel is set to 100 ⁇ m, the second flow guiding portion
  • the distance between the most convex portion and the most concave portion of 160 in the radial direction of the second member 16 may be about 1 micrometer to 300 micrometers.
  • the degree of convexity and concavity of the second flow guiding portion 160 may preferably be set to about 5% to 100% of the thickness of the channel 17, and more preferably, the thickness of the channel 17 is set to lO ⁇ SO ⁇ about.
  • the degree of convexity and concavity of the second flow guiding portion 160 on the surface of the second member 16 may be the same or different.
  • the density of the second flow guiding portion 160 on the surface of the second member 16 may be set to be less than 50%.
  • the second flow guiding portion 160 may preferably occupy 10 to 40 of the surface area of the second member 16.
  • the second flow guiding portion 160 may be of any shape. For example, it may be an array of a plurality of dots, which may be continuous stripes or intermittent stripes, or may be composed of dots and stripes.
  • the second flow guiding portions 160 may be randomly arranged on the surface of the second member 16, or may be regularly arranged.
  • the direction of the stripe-shaped second flow guiding portion 160 may be arbitrary as long as it is not perpendicular or parallel to the axial direction of the second member 16.
  • the stripe-shaped second flow guiding portion 160 may extend from the bottom of the second member 16 to the top or may extend intermittently to the top. Multiple stripes can be equal The distance may also be unequal spacing, and there may be intersections between the plurality of stripes.
  • the second flow guiding portion 160 includes, but is not limited to, a plurality of consecutive equally spaced stripes as shown in FIG.
  • the cross-sectional shape of the second flow guiding portion 160 includes, but is not limited to, any polygonal shape such as a triangle, a trapezoid, a square, or the like, a semicircular shape, a semi-elliptical shape, or the like, or any combination of the above shapes.
  • the triangular second flow guiding portion 160 shown in Fig. 4 is only one of them.
  • the second flow guiding portion 160 is a continuous stripe.
  • the direction of movement of the intersection is the trend direction of the stripe.
  • the direction of the second flow guiding portion 160 may be arbitrary as long as the direction of rotation is substantially opposite or the same as the direction of rotation of the second member 16.
  • a force in the direction of the flow is generated to the fluid.
  • the thrust creates an axial component that is parallel to the central axis of the first member 15 and urges the fluid to flow axially.
  • the object to be treated enters the annular passage 17 through the inlets 30 and 31.
  • the two components to be treated are quickly and thoroughly mixed under the action of the high shear force, high centrifugal force and axial force of the second member 16. If the two fluids can react chemically, they can be fully mixed and fully reacted.
  • the fluid flow in the passage 17 may be laminar, possibly turbulent.
  • the power provided by the high-speed rotation of the second element 16 drives the fluid to flow in layers, dividing the fluid into a plurality of thin layers.
  • the fluid layer can be quickly and otherly due to the different flow speeds between the thin layers.
  • the fluid layers are in close contact, resulting in rapid diffusion, allowing the two fluids to mix well.
  • the gap of the passage 17 is fixed, and whether the fluid of different viscosity occurs at different rotation speeds
  • the Coulter flow or Taylor vortex is determined by the Taylor coefficient.
  • the fluid flow in the channel 17 is laminar flow, then the fluid mixing effect is better, but due to the low speed, the input
  • the flow rate of the fluid to be mixed cannot be high. If the flow rate is high, the fluid quickly flows out through the passage 17 in the axial direction, and the mixing effect is not achieved.
  • the rotation speed of the rotor In order to mix with high efficiency and high flow rate, the rotation speed of the rotor must be increased. Increasing the rotational speed may result in a Taylor vortex. The mixing effect is deteriorated.
  • the mixing and reaction device of the present invention does not avoid the generation of Taylor vortex, the axial force provided by the second flow guiding portion 160 of the second member 16, Come Disturbing the Taylor vortex arranged in a direction perpendicular to the axis of the second element 16 breaks the closed fluid mass formed by the Taylor vortex, thereby causing the fluid in the vortex to communicate with the fluid outside the vortex, thereby increasing the mixing effect.
  • the second flow guiding portion 160 also disturbs the self-contained circulation in the vortex, causing the fluid in the circulation to agitate and mix.
  • the flow guiding portion 16 is provided on the second member 16, the mixing effect of the mixing and reaction device of the present invention can be prevented from being affected by the input flow rate and the number of revolutions.
  • the particles of the fluid mixed by the mixing and reaction device of the present invention are very small, and the radius can reach the nanometer level, which greatly improves the mixing efficiency and reaction efficiency of the fluid.
  • the second flow guiding portion 160 has a function of controlling the retention time of the fluid in the passage 17 in addition to the function of disturbing the Taylor vortex and increasing the mixing effect.
  • the trend direction of the second flow guiding portion 160 may be opposite to the rotation direction of the second member 16, and when the second member 16 rotates at a high speed, the second flow guiding portion 160 provides an upward axial force to prevent the fluid in the passage 17 from falling to The horizontal portion of channel 17 or (and) the outlet 18. In this way, all of the fluid can be confined within the vertical portion of the passage 17, ensuring that the fluid has sufficient time to mix and react within the passage 17, and to prevent fluid from entering the mixing dead zone, thereby ensuring that all of the passages are within the passage 17. The fluid can be thoroughly mixed or (and) reacted.
  • the fluid When the fluid is sufficiently mixed or/and reacted in the passage 17, it can be pressurized from the top of the passage 17 to reduce the fluid helium to the product outlet 18; or, the second member 16 can be reversely rotated, that is, the second diversion
  • the direction of the direction of the portion 160 is the same as the direction of rotation of the second member 16, and the second flow guiding portion 160 provides a downward axial force to cause fluid to drop to the product outlet 18.
  • the flow guiding portion 18 can also provide the above functions when it is necessary to invert the reaction portion in some cases.
  • the flow state of the fluid can be controlled to some extent by the axial force of the second flow guiding portion 160.
  • This includes, but is not limited to, controlling the retention time of the fluid in the reaction section, promoting the flow of fluid out of the reaction section, changing the rate at which the fluid flows out of the reaction section, increasing or decreasing the resistance of the fluid to be injected into the reaction section, and the like.
  • the mixing and reaction apparatus of the present invention may further include a connecting portion 13 and a bearing housing 11 mated with the second member 16, the second member 16 being coupled to the shaft of the driving portion 12 via the connecting portion 13, and the second member 16 passing through the bearing housing 11, An annular passage 17 is formed with the first element 15.
  • the mixing and reaction apparatus of the present invention may include means for connecting the driving portion 12 and the second member
  • the connecting portion 13 of the 16 is such that the driving portion 12 can drive the second member 16 to rotate.
  • the drive portion 12 can be an electric motor or any other component that can provide power to rotate the second member 16.
  • the maximum rotational speed of the second element 16 is mainly determined by the power and torque of the drive unit 12. Generally, the higher the power and torque of the driving portion 12, the larger the rotational speed of the second member 16. In the present embodiment, the maximum rotational speed of the second member 16 is 10,350 rpm. Depending on the characteristics of the fluid, choosing the appropriate speed or higher can achieve the desired or even better results of the mixing or (and) reaction.
  • the particle radius of the product can be reached. Rice or nanoscale.
  • the appropriate driving portion 12 is selected, and the mixing and reaction device of the present invention can achieve a higher rotational speed.
  • the operating temperature of the reaction unit can be set between -150 ° C and 300 ° C.
  • the operating temperature of the reaction unit is set at -150 ° C to 50 ° C and -50 ° C to 100. C, 20 ° C ⁇ 250. C, 150 ° C ⁇ 300 ° C and so on.
  • the mixing and reaction apparatus of the present invention may further comprise one or more first temperature control portions 14.
  • the first temperature control portion 14 may be provided at part or all of the periphery of the passage 17, and may be installed at other positions of the reaction portion.
  • the first temperature control portion 14 may include openings 32, 33 such as valves or tubes, through which the first temperature control portion 14 may be filled with a fluid to rapidly change the temperature of the reaction portion. Since heat may be generated in the mixing reaction, heat may also be absorbed, and the fluid circulates from the inlet 32 into the first temperature controller 14 of the reaction portion, and after sufficient heat exchange, flows out from the outlet 33, thereby circulating heat or bringing in heat.
  • the shearing friction may cause a large amount of heat to be generated in the fluid in the passage 17.
  • the cold fluid is circulated into the first temperature control portion 14 through the opening 32, and is sufficiently exchanged with the passage 17 to flow out from the outlet 33. If the chemical reaction in the passage 17 needs to absorb heat, and when the heat generated by the friction is insufficient to supply, the first temperature control portion 14 may be charged with a circulating fluid having a high temperature, and the high-temperature circulating fluid may heat the passage 17.
  • the circulating fluid of the set temperature can be rapidly exchanged with the fluid being mixed, and the fluid being mixed in the passage 17 can be quickly circulated with the circulating oil.
  • the temperatures are close.
  • the temperature of the fluid in the channel 17 is easily homogenized, which facilitates the consistency of the reaction.
  • the temperature in channel 17 is also guaranteed to be constant for specific temperature environments.
  • the mixing and reaction apparatus of the present invention may further comprise one or more second temperature controls.
  • the second temperature control portion is disposed on the bearing housing 11.
  • the second temperature control portion may include openings 34, 35 such as valves or tubes. Through the openings 34, 35, the second temperature control portion can charge the bearing housing 11 with fluid such as oil, water, etc., to rapidly change the temperature of the shaft 7 seat 11.
  • fluid such as oil, water, etc.
  • the temperature of the second temperature control portion is appropriately set to ensure that the temperature of the top of the second member 16 is the same as the temperature at the bottom of the second member 16 that projects into the passage 17.
  • the temperature of the second temperature control portion is appropriately set to ensure that the temperature of the top of the second member 16 is the same as the temperature at the bottom of the second member 16 that projects into the passage 17.
  • the mixing and reaction apparatus of the present invention may further comprise one or more third temperature controls.
  • the third temperature control unit is provided on the drive unit 12.
  • the second temperature control portion may include openings 36, 37 such as valves or tubes. Through the openings 36, 37, the second temperature control portion can charge the driving portion 12 with fluid to rapidly change the temperature of the driving portion 12.
  • the heat from the driving portion 12 is discharged from the opening 37 after entering the driving portion 12 from the opening 36. For example, when the drive unit 12 generates a large amount of heat at a high speed, the drive unit 12 can be cooled by water cooling.
  • the mixing and reaction apparatus of the present invention is mounted on a station (not shown) by means of a support device, and the angle of installation can be vertical, horizontal or any desired angle.
  • the supporting device may include a base 9 and a support base 10, wherein the base 9 is mounted on a console for fixing the driving portion 12 and the reaction portion to the base 9.
  • the cross-sectional area of the second member 16 may be elliptical or polygonal, such that when the second 'element 16 is rotated at a high speed, the width and width of any one of the fixed positions in the channel 17 follow the second element 16. The rotation is changed, and accordingly, the fluid in the passage 17 is thereby unevenly pressed, thereby achieving thorough mixing.
  • the cross-sectional area of the second member 16 may be other shapes, and the ellipse or polygon shown in Figs. 5 and 6 is only two of them.
  • the second member 16 may not be coaxial with the first member 15, and the shaft of the second member 16 may be parallel or intersect with the first member. Based on the similar principles described above, the fluid in the passage 17 is also subjected to uneven compression to achieve sufficient mixing.
  • the first element 15 and the second element 16 are interchangeable, i.e., the second element 16 is a stationary stator and the first element 15 is a rotor that can rotate at a high speed. .
  • the first element 15 and the second element 16 may be elements that rotate in opposite directions, or may be elements that rotate at different speeds.
  • the first and second members 15, 16 may also be elements of any shape that are close to each other, such as a sheet body that is close to each other, as long as a narrow passage 17 that can accommodate a fluid is formed therebetween.
  • the second flow guiding portion 160 may be selectively disposed on the first member 15 or (and) the second member 16.
  • the mixing and reaction apparatus of the present invention may be provided with only one inlet of the object to be treated; when a plurality of objects to be treated require mixing and reaction, a plurality of inlets for the object to be treated may be provided.
  • the mixing and reaction apparatus of the present invention may also be provided with a plurality of inlets to be treated in advance, and an appropriate number of inlets for the objects to be treated are selected according to the needs of the reaction.
  • the various components of the mixing and reaction apparatus of the present invention may be made of the same or different materials.
  • the components of the mixing and reaction device of the present invention may be made of a metal material such as cast iron, stainless steel, alloy, aluminum, etc., depending on factors of the property to be treated, product characteristics, reaction or (and) required conditions of the mixing process, cost, and the like. It is made of organic materials such as plastic, glass, and quartz glass, and can also be made of inorganic materials such as ceramics.
  • the first member 15 and the second member 16 are made of stainless steel, so that the mixing of the present invention and the reaction device can be applied to a highly corrosive object to be treated.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

L’appareil de mélange et de réaction selon la présente invention comprend une partie de réaction et une partie directive. La partie de réaction comprend un premier élément et un second élément, le premier élément ayant un trou cylindrique pour adapter le second élément et la partie du second élément adaptée dans le premier élément étant cylindrique. Il existe un canal étroit entre les premier et second éléments. Le second élément tourne par rapport au premier élément et est installé avec un inducteur situé au fond, l'inducteur pouvant réaliser un écoulement radial de fluide lorsque l'élément tourne. En raison de l'inducteur du second élément, le temps de séjour du fluide dans le canal peut être régulé et l'entrée du fluide dans la zone morte de mélange est empêchée, ainsi, la totalité du fluide dans le canal peut être entièrement mélangée grâce à l'appareil de mélange et de réaction de la présente invention.
PCT/CN2006/002565 2005-09-30 2006-09-29 Appareil de mélange et de réaction Ceased WO2007036157A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200510106114 2005-09-30
CN200510106114.5 2005-09-30

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WO2007036157A1 true WO2007036157A1 (fr) 2007-04-05

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5141328A (en) * 1990-05-23 1992-08-25 Dilley Jerry D High speed mixing apparatus
US5340891A (en) * 1991-02-05 1994-08-23 Nippon Paint Co., Ltd. Continuous polymerization method and apparatus
CN2621801Y (zh) * 2002-11-11 2004-06-30 虞培清 底部导流式高效节能搅拌装置
US6938687B2 (en) * 2002-10-03 2005-09-06 Holl Technologies Company Apparatus for transfer of heat energy between a body surface and heat transfer fluid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5141328A (en) * 1990-05-23 1992-08-25 Dilley Jerry D High speed mixing apparatus
US5340891A (en) * 1991-02-05 1994-08-23 Nippon Paint Co., Ltd. Continuous polymerization method and apparatus
US6938687B2 (en) * 2002-10-03 2005-09-06 Holl Technologies Company Apparatus for transfer of heat energy between a body surface and heat transfer fluid
CN2621801Y (zh) * 2002-11-11 2004-06-30 虞培清 底部导流式高效节能搅拌装置

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