[go: up one dir, main page]

WO2007007295A2 - Dispositif d'emballage et de distribution d'une composition cosmétique - Google Patents

Dispositif d'emballage et de distribution d'une composition cosmétique Download PDF

Info

Publication number
WO2007007295A2
WO2007007295A2 PCT/IB2006/052399 IB2006052399W WO2007007295A2 WO 2007007295 A2 WO2007007295 A2 WO 2007007295A2 IB 2006052399 W IB2006052399 W IB 2006052399W WO 2007007295 A2 WO2007007295 A2 WO 2007007295A2
Authority
WO
WIPO (PCT)
Prior art keywords
oil
acid
composition
weight
compartment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2006/052399
Other languages
English (en)
Other versions
WO2007007295A3 (fr
Inventor
Xavier Blin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0552215A external-priority patent/FR2888476B1/fr
Application filed by LOreal SA filed Critical LOreal SA
Publication of WO2007007295A2 publication Critical patent/WO2007007295A2/fr
Publication of WO2007007295A3 publication Critical patent/WO2007007295A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/927—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of insects, e.g. shellac
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging

Definitions

  • the devices toward which the present invention is directed are more particularly intended for applying makeup and/or care products to the skin, the lips and/or the integuments.
  • These products are especially lipsticks, lip balms, lip pencils, liquid or solid foundations, especially cast as a stick or a dish, concealer products and skin coloring products, temporary tattoos, eye makeup products, for instance eye liners, in particular in the form of pencils, mascaras or eyeshadows.
  • the present invention relates to a device for packaging and distributing a cosmetic composition for caring for and/or making up keratin material(s), characterized in that it comprises:
  • a container delimiting at least one compartment containing a cosmetic composition comprising at least 50% by weight, relative to its total weight, of compounds approved for food use, the device being arranged such that, as long as the cosmetic composition remains in the compartment, the composition can be maintained therein protected from air, until the time of distribution for use on keratin materials.
  • a subject of the invention is a cosmetic process for caring for and/or making up keratin materials, comprising the application, on contact with a keratin material, of the composition packaged in a device according to the invention.
  • the compounds approved for food use may be "food grade compounds”.
  • the process of the invention may be a make up process.
  • the compositions packaged according to the invention contain a physiologically acceptable medium.
  • cosmetic composition denotes a composition as defined in Directive 93/35/EEC of the Council of 14 June 1993.
  • physiologically acceptable medium denotes a nontoxic medium that may be applied to at least one human keratin material.
  • keratin materials covers the skin, mucous membranes, for instance the lips, the nails and keratin fibers, such as the eyelashes and the hair.
  • the cosmetic compositions in accordance with the present invention are particularly advantageous for use on the skin and the lips.
  • the term "compounds approved for food use” means compounds chosen from ozokerite, rice wax, compounds referenced in the Codex alimentarius, and materials consisting exclusively of compounds referenced in the Codex alimentarius, for example such as pearls.
  • the Codex Alimentarius or Food Code
  • Food Code is the world reference acting as the authority for consumers, producers and processors of foodstuffs, national food control bodies and the international food products market. It combines the food standards, guidelines and other codes of use established in the field of food products by the Commission of the Codex Alimentarius, created in 1963 by the Food and Agriculture Organization (FAO) and the World Health Organization (WHO), in the context of the FAO/WHO joint program on food standards and under the aegis of the WHO.
  • FAO Food and Agriculture Organization
  • WHO World Health Organization
  • a compound referenced in the Codex alimentarius denotes a compound whose use as a food ingredient is considered in the Codex, and is or is not regulated therein according to specific terms.
  • the term “food” ingredient denotes any substance other than water, used in the manufacture or preparation of a food and present in the finished product even though occasionally in a modified form.
  • the term “food ingredient” especially includes food additives and food extracts.
  • the term "food additive” means any substance that is not normally consumed as a foodstuff per se and is not normally used as a characteristic ingredient of a food, whether or not it has nutrient value, and whose deliberate addition to the foodstuff for a technological or organoleptic purpose, at any step in the manufacture, transformation, preparation, processing, packaging, wrapping, transportation or storage of this foodstuff, leads or may lead (directly or indirectly) to its incorporation or to the incorporation of derivatives thereof into the foodstuff or can affect in any other way the characteristics of this foodstuff.
  • a product consisting exclusively of compounds referenced in the Codex alimentarius denotes a material whose composition consists exclusively of compounds referenced in the Codex alimentarius and which, consequently, comprises at least two compounds, or even more, referenced in the Codex alimentarius.
  • Materials of multilayer structure for instance pearls, are especially covered under this definition.
  • pearls generally consist of a mineral substrate such as mica or TiO 2 covered, for example, with a coat of iron oxide.
  • the Codex alimentarius under consideration according to the invention is that available at the date of filing of the present patent application.
  • the additives it is the Codex Food Additive and
  • extracts are especially defined in the Codex alimentarius volume 8 and more particularly in the Codex standards 19, 33 and 210.
  • the Codex under consideration is the version of the Codex standard 210 as amended in 2003.
  • the Codex under consideration is the version of the Codex standard 19-1981, as revised in February 1993.
  • the "compounds approved for food use” according to the present invention are “food grade compounds”.
  • a “food grade compound” may be a "compound approved for food use” that is sold as food grade compounds, i.e. a compound for which the supplier states it can be used in a food product.
  • a food grade compound is a compound specifically made to match the needs of the food industry.
  • a food grade compound can consist only of edible products.
  • a "food grade compound” can also refers to a compound, specifications of which are given in the US Code of Federal Regulation Title 21 Chap I Parts 73, 74, 82, 172, 184 and 854.
  • each chemical compound is defined as a "food grade compound" by a specification comprising i) a chemical name, ii) impurity levels the compound can contain, and/or iii) the concentration at which it can be used in a food.
  • the food grade compound will be used in the cosmetic composition with the specifications given in US Code of Federal Regulation Title 21 Chap I.
  • the part under consideration is 184.
  • the parts under consideration are 172, 73, 74 and 82.
  • compositions in accordance with the invention comprise at least 50% by weight, especially at least 55% by weight or even at least 60% by weight, in particular at least 65% by weight, and more particularly at least 70% by weight and especially at least 75% by weight, or even at least 80% by weight, especially at least 85% by weight, in particular at least 90% by weight, especially at least 95% by weight and more particularly consist of about 100% by weight of compound(s) approved for food use relative to their total weight.
  • compositions in accordance with the invention comprise at least 50% by weight, in particular at least 60% by weight, especially at least 70% by weight, especially at least 80% by weight, especially at least 90% by weight, and more particularly consist of about 100% by weight, relative to their total weight, of food grade compound(s).
  • the presence of the compounds under consideration according to the invention does not prove to be harmful to the expected associated qualities for a cosmetic composition, for example as regards wear or gloss in the case of lipsticks, or covering power in the more particular case of foundations.
  • a device for packaging and distributing a cosmetic composition in accordance with the invention comprises at least one container delimiting at least one compartment containing a cosmetic composition in accordance with the invention, and is arranged such that the composition can be maintained in the compartment protected from air until the time of distribution.
  • the devices according to the invention comprise takeup means that are known per se and do not require any particular description.
  • the compartment may be arranged such that its volume reduces in response to the distribution of the composition contained therein.
  • Such devices are especially illustrated by the implementation examples shown by figures 1, 3, 4 and 5.
  • the compartment may be delimited by at least one moveable wall.
  • the container 1 may comprise a piston mounted slideably inside the compartment.
  • the device may thus comprise takeup means arranged on the body of the container, and the container contains a follower piston slideably mounted inside the container.
  • This piston is mounted in a leaktight manner and can constitute a wall of the compartment.
  • the pressure reduction caused in the compartment by the distribution of all or some of the composition results in displacement of the slideably-mounted piston towards the takeup means.
  • the compartment may be delimited by at least one elastically deformable wall.
  • the elastically deformable wall may be a surface member of a bag arranged in the container, for example as in figure 1.
  • the surface member of the bag may thus define, with the other members of the inner surface of the container, a compartment containing the cosmetic composition according to the invention.
  • the surface member of the bag may constitute the base wall of the compartment.
  • the surface member of the bag may be made of an elastically deformable material and may be capable of moving in the container in response to a removal of composition to reduce the volume of the compartment containing the composition.
  • the surface member of the bag may be internally equipped with a lining made of an inelastically deformable material that is highly gas-impermeable, said lining being able to be deployed to accompany the deformation of the bag until the wall of said bag becomes taut.
  • the surface member of the bag may be fixed at one end at its periphery to the container and may be capable of being deformed to reduce the volume of the compartment until it substantially marries the shape of the inside of the container.
  • the pressure reduction thus created in the compartment by the removal of the composition causes the deformation of the surface member of the bag in the direction tending to reduce the volume of the compartment, until said pressure reduction has been canceled out.
  • the surface member of the bag may advantageously occupy, by virtue of its elasticity, in its stage of maximum dilation, virtually all of the volume initially occupied by the cosmetic composition, irrespective of the shape of the container.
  • the compartment may be configured in the form of a bag comprising at least one or consisting of one flexible wall.
  • the presence of at least one flexible wall allows retraction of the bag gradually as the amount of composition contained therein reduces.
  • the bag may have an elongated general shape and may be attached directly at an axial end to a distribution means as illustrated by figure 5.
  • the compartment especially featured by a bag may be arranged inside a container delimiting a closed volume adjacent to the compartment.
  • the container may be provided with at least one air intake orifice.
  • the container may have no air intake orifice.
  • the device may comprise a pressurized gas to allow the distribution of the composition under pressure.
  • the pressurized gas may be arranged inside the compartment.
  • the pressurized gas may be arranged outside the compartment, in the inner space of the container adjacent to the compartment.
  • Any propellent gas usually used in the field may be suitable for use in the present invention.
  • the takeup means that may be arranged with some of the abovementioned devices may comprise a pump without air intake, for distribution of the composition contained in the compartments thereof, thus preventing any entry of air liable to come into contact with the composition according to the invention in the device.
  • the pump may comprise a pushbutton for distribution of composition and may be equipped with means for connecting it to the container.
  • the pump may be equipped with a cap configured to lie against a circular rim of a neck of a rotationally symmetric container with a rigid wall.
  • the pump may also comprise a tube to take up the composition in the compartment. This tube may be engaged in the aperture of the neck and extend via its lower end into the inner space of the compartment containing the composition.
  • the pump may comprise a valve arranged in a manner known per se allowing the cosmetic composition according to the invention to be taken up, without entry of air, via the tube in the compartment.
  • the compartment does not undergo any deformation in response to distribution of the composition contained therein.
  • the makeup and/or care assembly according to the invention may be in the form of a spray device, such as that shown in figure 2.
  • the means for distributing the composition contained in the compartment can allow the composition to be sprayed, especially in the form of a mist of fine droplets.
  • the pumps usually used in the field for distribution by spraying may be used for the implementation of the present invention.
  • the packaging device is intended for a single use.
  • composition according to the invention is arranged at the surface of and/or inside a support that is itself arranged inside the container of the assembly in accordance with the invention.
  • the container may be arranged in the form especially of a sachet or a tray.
  • the container may be arranged in the form of a tray comprising a housing and a sealing unit to close the housing, especially in a leaktight manner.
  • the sealing unit may comprise a lid, which may be fixed to the receptacle of the tray by bonding or thermowelding, for example.
  • the lid may comprise, for example, a plastic and/or metal film.
  • the lid may be, for example, a polyethylene terephthalate (PET) or a polyolefin film, optionally covered with a metal, for example aluminum.
  • PET polyethylene terephthalate
  • At least one portion of the lid arranged at the periphery may not be adherent to the receptacle so as to allow handling of the lid, facilitating its removal.
  • the housing of the tray may be in any form adapted to all the uses of the support as defined above, usually performed in the field.
  • the tray may comprise a plurality of housings, each comprising a support, these supports possibly being impregnated with or comprising different formulations of compositions in accordance with the invention.
  • the user may, for example, select a support as a function of the cosmetic application to be made, or use several supports of different forms, combined with formulations of cosmetic compositions according to the invention, which may be identical or different, to simultaneously treat different areas of the face or body.
  • the tray may be made of any material usually used in the field, for example of plastic and/or metal.
  • the metal may be, for example, aluminum.
  • plastics that may be mentioned include thermoplastics, for example polyolefins, especially polyethylene or polypropylene.
  • the tray may be obtained by thermowelding.
  • the tray may advantageously consist of an at least partially transparent or translucent plastic.
  • FIG. 7 Another example illustrating this embodiment intended for a single use is shown in figure 7. This is an applicator comprising, firstly, a tube in the inner space of which is packaged the composition, and, secondly, an application member at one end of the tube.
  • the application member may be chosen from types such as a cotton tip, a foam tip, a felt tip, a flocked tip, a pad, a ceramic tip or a sinter tip.
  • the application member may also comprise a coarse brush, a comb or a fine brush.
  • the inner space may be closed off on one side opposite this application member by means of a splitable, removable, perforable or deformable end.
  • a liquid or powder stopper may be arranged in the inner space of the tube, to separate the liquid and the application member before use.
  • This stopper is arranged so as to be removed with the composition when said composition leaves the inner space of the tube during its distribution.
  • This packaging mode which is also referred to as being of swab or hollow- stemmed cotton bud type, which is suitable for implementation of the invention may be as described in patent application FR 02 12155.
  • some of the components of the makeup composition may be packaged in separate compartments, for example arranged in the form of a tube, so as to ensure their prolonged stability.
  • This embodiment is most particularly advantageous with regard to the compounds approved for food use that are generally more sensitive to oxidation by ambient air.
  • the swab may contain a first composition or a first part of composition in the cotton- wool or foam head and a second composition or a second part of composition in the compartment or hollow stem.
  • the compartments of such a packaging are not placed in communication with each other until the time of the use of the makeup and/or care composition(s) to allow extemporaneous mixing of its ingredients before application, for example by breaking a splitable portion.
  • Such an assembly is suitable for single use.
  • the cosmetic compositions packaged in the device according to the present invention may comprise a fatty phase especially comprising at least one compound chosen from oils and fatty substances that are solid at room temperature (20 - 25°C) and atmospheric pressure, for example such as waxes and pasty iatty substances, and mixtures thereof.
  • Oils and solid fatty substances are especially foodstuffs in accordance with the definition in section 1 of the Codex alimentarius and composed of fatty acid glycerides.
  • the oils and solid fatty substances are food grade compounds.
  • They may be of animal, plant, mineral, synthetic or marine origin. They may contain a small amount of other lipids, for instance phosphatides, unsaponifiable constituents and free fatty acids naturally present in these solid fatty substances and oils.
  • Oil means any fatty substance that is in liquid form at room temperature (20 - 25°C) and atmospheric pressure.
  • the liquid fatty phase may also contain, besides oils, other compounds dissolved in the oils, such as gelling and/or structuring agents.
  • the cosmetic composition according to the present invention may comprise at least one and in particular at least two oils.
  • oils that are suitable for the preparation of the cosmetic compositions according to the invention may be volatile or nonvolatile oils.
  • volatile oil means an oil
  • the volatile oil is a volatile cosmetic oil, which is liquid at room temperature, especially having a nonzero vapor pressure, at room temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40 000 Pa (10 ⁇ 3 to 300 mmHg), preferably ranging from 1.3 Pa to
  • nonvolatile oil means an oil having a vapor pressure of less than 0.13 Pa.
  • the volatile or nonvolatile oils may be hydrocarbon-based oils especially of animal, mineral or plant origin, synthetic oils, silicone oils or fluoro oils, or mixtures thereof.
  • hydrocarbon-based oil means an oil mainly containing hydrogen and carbon atoms and possibly oxygen, nitrogen, sulfur and/or phosphorus atoms.
  • oils that are more particularly considered according to the invention are hydrocarbon-based oils and more preferentially edible oils especially referenced in the Codex alimentarius and more specifically in standards 19 to 27, 33, 34, 123 to 128 and 210 thereof.
  • oils comprising at least one fatty acid chosen from caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, ricinoleic acid, linoleic acid, linolenic acid, arachidic acid, gadoleic acid, behenic acid, erucic acid, brassidic acid, cetoleic acid, lignoce
  • hydrocarbon-based plant oils are more particularly hydrocarbon-based plant oils and in particular those chosen from triglycerides consisting of fatty acid esters of glycerol, the fatty acids of which may have chain lengths ranging from C 4 to C 24 , these chains possibly being linear or branched, and saturated or unsaturated.
  • oils are especially heptanoic or octanoic triglycerides, groundnut oil, babassu oil, coconut oil, grapeseed oil, cottonseed oil, corn oil, corn germ oil, mustard seed oil, palm oil, rapeseed oil, sesame seed oil, soybean oil, sunflower oil, wheatgerm oil, canola oil, apricot oil, mango oil, castor oil, shea oil, avocado oil, olive oil, sweet almond oil, peach kernel oil, walnut oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppy seed oil, pumpkin oil, marrow oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, candlenut oil, passionflower oil, musk rose oil or shea butter oil, or alternatively caprylic/capric acid triglycerides, and mixtures thereof.
  • compositions according to the instant invention will contain at least some canola oil, in particular when they are intended to confer a gloss effect.
  • compositions according to the invention will contain reduced amounts of castor oil.
  • the castor oil is inclined to be partially oxidized by air with time and thus may generate unpleasant smell.
  • the compositions may preferably contain less than 5% by weight of castor oil, especially less than 2%, in particular less than 1% by weight relative to the total weight of the composition and more particularly are free of castor oil.
  • the cosmetic compositions in accordance with the invention may comprise at least one oil chosen from hydrocarbon- based plant oils and more particularly chosen from the following oils approved for food use: isopropyl myristate sold by Stearinerie Dubois, the caprylic/capric acid triglycerides sold by Stepan; hybrid rapeseed oil, liquid cottonseed oil, refined protected deodorized mango oil, the liquid fraction of protected shea butter and the refined canola seed oil sold by Karlshamns; Lipex Sheasoft and cottonseed oil sold by Karslshamns; the deodorized apricot kernel oil sold by Nestle; the sweet almond oil sold by Soetenaey; the peach kernel oil sold by Aarhus United; rapeseed oil, corn germ oil, olive oil, grapeseed oil, soybean oil and sunflower oil sold by Huileries de Lapalisse and walnut oil sold by Soetenaey.
  • isopropyl myristate sold by Stearinerie Dubois the caprylic/
  • the cosmetic composition in accordance with the present invention comprises at least one oil chosen from canola oil, caprylic/capric acid triglycerides, apricot oil, peach oil, walnut oil and olive oil.
  • the cosmetic compositions according to the invention comprise from 0.1% to 99% by weight, especially from 1% to 90% by weight, in particular from 5% to 70% by weight, in particular from 10% to 65% by weight and more particularly from 20% to 60% by weight, relative to the total weight of oil(s) approved for food use in the composition and more particularly referenced in the Codex alimentarius.
  • compositions in accordance with the present invention may obviously comprise at least one other liquid fatty substance, with the proviso that it is present in amounts in accordance with the requirements according to the invention.
  • Nonvolatile hydrocarbon-based oils that may especially be mentioned include: - synthetic ethers containing from 10 to 40 carbon atoms; - linear or branched hydrocarbons of mineral or synthetic origin such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam, and squalane, and mixtures thereof, and in particular hydrogenated polyisobutene, - synthetic esters, for instance oils of formula R 1 COOR 2 in which R 1 represents a linear or branched fatty acid residue containing from 1 to 40 carbon atoms and R 2 represents a hydrocarbon-based chain that is especially branched, containing from 1 to 40 carbon atoms provided that R 1 + R 2 > 10.
  • the esters may be chosen especially from iatty acid esters, for example:
  • isopropyl alcohol esters such as isopropyl myristate or isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl stearate or isostearate, isostearyl isostearate, octyl stearate, hydroxylated esters, for instance isostearyl lactate, octyl hydroxystearate, diisopropyl adipate, heptanoates, and especially isostearyl heptanoate, alcohol or polyalcohol octanoates, decanoates or ricinoleates, for instance propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, 2-ethylhexyl 4-diheptanoate and palmitate, alkylbenzoate, poly
  • 2-octyldodecanol isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol and 2-undecylpentadecanol;
  • the volatile hydrocarbon-based oils may be chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and especially branched C 8 -C 16 alkanes (also known as isoparaffins), for instance isododecane (also known as 2,2,4,4,6- pentamethylheptane), isodecane, isohexadecane and, for example, the oils sold under the trade names Isopars ® or Permethyls ® .
  • compositions according to the invention may also contain volatile or nonvolatile silicone oils.
  • the nonvolatile silicone oils that may be used in the composition according to the invention may be nonvolatile polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising alkyl or alkoxy groups that are pendent and/or at the end of a silicone chain, these groups each containing from 2 to 24 carbon atoms, phenyl silicones, for instance phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes and 2-phenylethyl trimethylsiloxysilicates, and dimethicones or phenyltrimethicones with a viscosity of less than or equal to 100 cSt, and mixtures thereof.
  • PDMS nonvolatile polydimethylsi
  • Volatile silicone oils that may more particularly be used include volatile linear or cyclic silicone oils, especially those with a viscosity ⁇ 8 centistokes (8 x 10 "6 mVs) and especially containing from 2 to 10 silicon atoms and in particular from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms.
  • volatile silicone oils that may be used in the invention, mention may be made especially of dimethicones with a viscosity of 5 and 6 cSt, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexa- siloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane and dodecamethylpentasiloxane, and mixtures thereof.
  • Volatile fluoro oils such as nonafluoromethoxybutane or perfluoro- methylcyclopentane, and mixtures thereof, may also be used.
  • the compositions according to the invention may also advantageously comprise at least one compound chosen from waxes and pasty iatty substances, and mixtures thereof.
  • the wax is solid at room temperature (25°C), has a reversible solid/liquid change of state, has a melting point of greater than 30°C, which may be up to 200°C and a hardness of greater than 0.5 MPa, and has an anisotropic crystal organization in the solid state.
  • compositions in accordance with the present invention comprise at least one wax chosen from waxes approved for food use.
  • a "wax approved for food use” covers ozokerite, rice wax, and the waxes referenced in the Codex alimentarius, more particularly including the waxes referenced in table 1 of the Codex alimentarius.
  • the compositions in accordance with the present invention advantageously comprise a wax chosen from beeswax, ozokerite, rice wax, carnauba wax, candelilla wax and microcrystalline waxes, and mixtures thereof.
  • the wax compounds are food grade compounds, as defined here-above, and more particularly are referenced in the US code of Federal Regulation Title 21 Chap I Part 184.
  • the wax used in the cosmetic compositions in accordance with the invention is chosen from the microcrystalline wax sold by Paramelt and more particularly ozokerite, beeswax, candelilla wax or carnauba wax sold by Strahl & Pitsch, and mixtures thereof. These waxes are preferably used under a form specified by the supplier as being convenient for food industry.
  • the wax(es) approved for food use is or are present in the cosmetic compositions in accordance with the present invention in a content ranging from 1% to 50% by weight, in particular from 3% to 40% by weight, in particular from 5% to 30% by weight and especially from 7% to 20% by weight relative to the total weight of the compositions.
  • compositions according to the invention may comprise one or more waxes chosen, for example, from synthetic waxes, for instance polyethylene wax (preferably with a molecular weight of between 400 and 600) or Fischer-Tropsch waxes, silicone waxes, for instance alkyl or alkoxy dimethicones containing from 16 to 45 carbon atoms, paraffin waxes, ceresins, for instance isoparaffins with a melting point of less than 40°C, such as EMW-0003, sold by the company Nippon Seirou, ⁇ -olefin oligomers, such as the polymers Performa V ® 825, 103 and 260, sold by the company New Phase Technologies; ethylene-propylene copolymers, such as Performalene ® EP 700, and mixtures thereof.
  • synthetic waxes for instance polyethylene wax (preferably with a molecular weight of between 400 and 600) or Fischer-Tropsch waxes, silicone waxes, for instance alkyl or alkoxy dimethicones
  • the cosmetic compositions in accordance with the present invention may also comprise at least one pasty compound.
  • pasty refers to a fatty compound with a reversible solid/liquid change of state and comprising, at a temperature of 25°C, a liquid fraction and a solid fraction.
  • the term pasty also means polyvinyl laurate.
  • Polyol esters are most particularly suitable as pasty compounds according to the invention.
  • polyol esters that may be used in the context of the present invention are commercially available or may be prepared in a conventional manner. They are generally of plant origin and may be obtained especially by mono- or polyesterification of a polyol with a C 2 -C 34 monocarboxylic acid, for instance a fatty acid or with a dicarboxylic acid such as a diacid dimer.
  • the ester obtained may especially be a polyester, a triester, a diester, a monoester or a mixture thereof.
  • the ester may be a mixture of two or more types of ester formed with different carboxylic acids.
  • esters with a relatively high molecular weight ranging from about 200 to 1300 g/mol, may be obtained.
  • a polyol dicarboxylate In the esterification reaction with a dicarboxylic acid, a polyol dicarboxylate may be obtained, which has a weight-average molecular weight, determined by gel permeation chromatography (GPC), ranging from 200 to 20 000 g/mol and preferably between 2000 and 4000 g/mol.
  • GPC gel permeation chromatography
  • polyol and “polyhydric alcohol” should be understood as meaning any organic molecule comprising at least two free hydroxyl groups.
  • the polyhydric alcohols that are advantageously suitable for the formulation of the cosmetic compositions according to the present invention are those especially containing from 2 to 20 carbon atoms, in particular from 3 to 10 carbon atoms and more particularly from 4 to 6 carbon atoms.
  • the polyol may be chosen, for example, from a diol dimer, glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, sorbitol, hydroxypropyl sorbitol and 1,2,6-hexanetriol; glycol ethers (especially containing from 3 to 16 carbon atoms) such as mono-, di- or tripropylene glycol (Ci-C 4 )alkyl ethers and mono-, di- or triethylene glycol (Ci-C 4 )alkyl ethers; and mixtures thereof.
  • a diol dimer glycerol
  • propylene glycol butylene glycol
  • pentylene glycol hexylene glycol
  • dipropylene glycol diethylene glycol
  • sorbitol hydroxypropyl sorbitol and 1,2,6-hexanetriol
  • diol dimer i.e. saturated diols produced by hydrogenation of the corresponding diacid dimers.
  • a diol dimer may be produced by hydrogenation of a diacid dimer, which is itself obtained by dimerization of an unsaturated fatty acid especially of C 8 to C 34 , such as those mentioned previously, especially of C 12 to C22 and in particular of C 16 to C 20 , preferably C 18 such as, for example, oleic acid and linoleic acid.
  • the polyols that are more particularly suitable are sugars chosen from monosaccharides, disaccharides and trisaccharides. Illustrations of these sugars that may especially be mentioned include monosaccharides such as xylose, arabinose, galactose, fructose, mannose and glucose, and mixtures thereof. Illustrations of disaccharide polyols that may more particularly be mentioned include maltose, lactose and sucrose and combinations thereof.
  • the monocarboxylic acid that may be used in the present invention may contain from 2 to 34 carbon atoms and especially from 10 to 32 carbon atoms.
  • - saturated linear acids such as butanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, nonadecanoic acid, eicosanoic acid, docosanoic acid and tetracosanoic acid,
  • branched fatty acids for instance isobutanoic acid, isopentanoic acid, pivalic acid, isohexanoic acid, isoheptanoic acid, isooctanoic acid, dimethyloctanoic acid, isononanoic acid, isodecanoic acid, isoundecanoic acid, isododecanoic acid, isotridecanoic acid, isotetradecanoic acid, isopentadecanoic acid, isohexadecanoic acid, isoheptadecanoic acid, isooctadecanoic acid, isononadecanoic acid, isoeicosanoic acid, 2-ethylhexanoic acid, 2-butyloctanoic acid, 2-hexyldecanoic acid, 2-octyldodecanoic acid, 2-decyltetradecanoic acid, 2-dodecyl
  • - hydroxy acids such as 2-hydroxybutanoic acid, 2-hydropentanoic acid, 2-hydroxyhexanoic acid, 2-hydroxyheptanoic acid, 2-hydroxyoctanoic acid,
  • 2-hydroxynonanoic acid 2-hydroxydecanoic acid, 2-hydroxyundecanoic acid, 2-hydroxydodecanoic acid, 2-hydroxytridecanoic acid, 2-hydroxytetradecanoic acid, 2- hydroxyhexadecanoic acid, 2-hydroxyheptadecanoic acid, 2-hydroxyoctadecanoic acid, 12-hydroxyoctadecanoic acid, 2-hydroxynonadecanoic acid, 2-hydroxyeicosanoic acid, 2- hydroxydocosanoic acid and 2-hydroxytetracosanoic acid,
  • - cyclic acids such as cyclohexanoic acid, hydrogenated rosin, rosin, abietic acid, hydrogenated abietic acid, benzoic acid, p-oxybenzoic acid, p-aminobenzoic acid, cinnamic acid, p-methoxycinnamic acid, salicylic acid, gallic acid, pyrrolidonecarboxylic acid and nicotinic acid, and - fatty acids of natural origin, such as the fatty acids of orange oil, of avocado oil, of macadamia oil, of olive oil, of hydrogenated soybean oil, of jojoba oil, of palm oil, of castor oil, of wheatgerm oil, of saffron oil, of cottonseed oil and of mink oil, and mixtures thereof.
  • the dicarboxylic acid that may be used according to the invention should contain at least two carboxylic groups per molecule.
  • n is an integer from 1 to 16 and preferably from 3 to 16.
  • dicarboxylic acids that are suitable for the invention, mention may be made especially of malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 1,9-nonamethylenedicar- boxylic acid, ljlO-decamethylenedicarboxylic acid, ljl l-undecamethylenedicarboxylic acid, lj ⁇ -dodecamethylenedicarboxylic acid, ljlS-tridecamethylenedicarboxylic acid, ljH-tetradecamethylenedicarboxylic acid, ljlS-pentadecamethylenedicarboxylic acid and 1,16-hexadecamethylenedicarboxylic acid, and mixtures thereof.
  • the dicarboxylic acid may also be a diacid dimer.
  • diacid dimer denotes a diacid obtained by polymerization reaction, especially by intermolecular dimerization of at least one unsaturated fatty acid especially of C 8 to C 34 , such as those mentioned previously, especially Of C 12 to C22 and in particular of C 16 to C 20 , preferably of C 18 such as, for example, oleic acid and linoleic acid.
  • Polyol polyesters in which the fatty acid ester units of the polyester comprise saturated or unsaturated chain lengths chosen such that the compound has the required behavior in terms of pasty compounds according to the invention, are also most particularly suitable as polyol esters.
  • the unsaturated fatty acid chains are typically branched chains and more particularly contain from 12 to about 22 and more particularly from about 18 to 22 carbon atoms.
  • the unsaturated fatty acid chains more particularly considered are monounsaturated and/or diunsaturated C 18 fatty acids.
  • These long chains may be combined with shorter saturated fatty acid chains. They are generally linear and contain from 2 to about 12, preferably from 6 to about 12 and more particularly from 8 to 12 carbon atoms.
  • the degree of esterification of these fatty acid esters is such that about 60% of the hydroxyl functions of the polyols and more particularly about 85% or even 95% of the hydroxyl functions of the polyols are esterified.
  • unsaturated long-chain fatty acid ester units mention may be made more particularly of lauroleates, myristoleates, palmitoleates, oleates, elaidates, eructates, linoleates, linolenates, arachidonates, eicosapentaenoates and docosahexaenoates.
  • monounsaturated and diunsaturated fatty acid chains are preferred.
  • long-chain unsaturated fatty acid ester units mention may be made more particularly of arachidate, behenate, linoserate and serotate esters.
  • short-chain saturated fatty acid ester units they may be more particularly acetate, caproate, caprylate, caprate and laurate.
  • solid polyol fatty acid polyesters that are most particularly suitable for the invention, mention may be made more particularly of raffinose octaesters in which the esterifying fatty acid parts are linoleate and behenate, maltose hectaesters in which the esterifying fatty acid parts are derived from sunflower seed oil fatty acid and from lignoserate, sucrose octaesters in which the esterifying fatty acid parts are behenate and oleate, and sucrose octaesters in which the esterifying fatty acid parts are laurates, linoleates and behenates.
  • Such solid fatty acid polyesters may be obtained according to methods already described for the preparation of the polyol polyesters. In this respect, reference may be made especially to documents US 5 306 516, US 5 306 515, US 5 305 514, US 4 797 300, US 3 963 699, US 4 518 772 and US 4 517 360.
  • the composition according to the invention comprises at least one ester of at least one carboxylic acid containing 1 to 7 carbon atoms and of a polyol containing at least 4 hydroxyl groups, the said ester having for example a molecular mass of less than 5 000 g/mol.
  • the ester preferably has a molecular mass of less than 2 000, more preferably less than 1 000, more preferably still less than 900 g/mol.
  • the molecular mass of the ester is preferably greater than 100 g/mol.
  • esters are particularly interesting for enhancing the wear of the compositions incorporating them.
  • the polyol according to the invention may be a monosaccharide, a polyhydroxyaldehyde (aldose) or polyhydroxyketone (ketose), which is cyclized or not.
  • the polyol is preferably a monosaccharide cyclized in hemiacetal form.
  • the polyol may also be a polyol derived from a monosaccharide, such as eythritol, xylitol or sorbitol.
  • aldoses mention may be made of D-ribose, D-xylose, L-arabinose, D- glucose (or alpha-D-glucopyranose when in cyclic hemiacetal form), D-mannose and D- galactose.
  • the polyol may be a monosaccharide or a polysaccharide containing from 1 to 10 monosaccharide units, preferably from 1 to 4, more preferably 1 ot 2 monosaccharide units.
  • the polyol is preferably selected from erythritol, xylitol, sorbitol, glucose and sucrose.
  • the polyol according to the invention is preferably a disaccharide.
  • disaccharides mention may be made of sucrose (alpha-D-glucopyranosyl-(l-3)-beta-D- fructofuranose), lactose (beta-D-galactopyranosyl-l(l-4)-beta-D-glucopyranose) and maltose (alpha-D-glucopyranosyl-(l -4)-beta-D-glucopyranose).
  • the polyol may be a polysaccharide composed of two or more identical monosaccharide units or at least two different monosaccharide units.
  • the ester according to the invention may be composed of a polyol substituted by at least two different monocarboxylic acids or by at least three different monocarboxylic acids.
  • the ester may be obtained by copolymerizing two esters according to the invention, in particular by copolymerizing i) a sucrose substituted by benzoyl groups and ii) a sucrose substituted by acetyl and/or isobutyryl groups.
  • the ester preferably contains no polar group, in particular no hydroxyl group.
  • the acid is added in an amount sufficient to react with all of the hydroxyl groups of the polyol.
  • the polar groups are, for example, ionic or non-ionic polar groups selected from -COOH; -OH; ethylene oxide; propylene oxide; -PO 4 ; -NHR; -NR 1 R 2 with R 1 and R 2 optionally forming a ring and each representing a linear or branched C 1 to C 20 alkyl or alkoxy radical.
  • the acid is preferably a monocarboxylic acid containing 1 to 7 carbon atoms, preferably 1 to 5 carbon atoms. It may be selected in particular from acetic, n-propanoic, isopropanoic, n-butanoic, isobutanoic, tert-butanoic, n-pentanoic and benzoic acids.
  • the ester may be obtained from at least two different monocarboxylic acids.
  • the acids is an unsubstituted linear or branched acid.
  • the acid is preferably selected from acetic acid, isobutyric acid and benzoic acid.
  • the ester has sucrose diacetate hexa(2- methylpropanoate) as a chemical name, and can bear the INCI name sucrose acetate isobutyrate.
  • fractionated hydrogenated triglycerides and especially those sold by SIO hydrogenated plant oils, hydrogenated palm oil, cocoa butter and, for example, the product sold by Karlshamns, solid cottonseed oil, for example the oil sold by SIO, and sucrose acetate isobutyrate, for example the product sold by Eastman Chemical.
  • lanolines and lanoline derivatives for instance acetylated lanolines, oxypropylenated lanolines or isopropyl lanolate, and mixtures thereof.
  • the amount in lanoline(s) will be also adjusted for avoiding any undesirable effect in particular in term of smell as soon as these compounds are inclined to oxidize with time.
  • silicone compounds such as high molecular weight polydimethylsiloxanes (PDMS) and in particular those with pendent chains of the alkyl or alkoxy type containing from 8 to 24 carbon atoms, and a melting point of 20-55°C, for instance stearyl dimethicones, especially those sold by the company
  • PDMS high molecular weight polydimethylsiloxanes
  • pendent chains of the alkyl or alkoxy type containing from 8 to 24 carbon atoms and a melting point of 20-55°C, for instance stearyl dimethicones, especially those sold by the company
  • the solid substances may be chosen for their efficacy in texturing a liquid fatty phase.
  • the compounds that are suitable in this respect have a melting point of greater than or equal to 50°C, in particular greater than or equal to 55°C or even ranging from 55 to
  • compositions according to the invention contain
  • hydrocarbon-based plant oil like for example canola oil, caprylic/capric acid triglycerides and/or one of their mixtures and
  • compositions according to the invention contain
  • hydrocarbon-based plant oil(s) in particular non hydrogenated vegetable oil(s) - about 20 to 70% by weight of ester(s) of at least one carboxylic acid containing 1 to 7 carbon atoms and of a polyol containing at least 4 hydroxyl groups, and
  • compositions may further contain at least one compound selected among waxes, dyestuffs and fillers as described here above, like for example rice starch and mixtures thereof.
  • the composition packaged according to the invention may comprise at least one aqueous medium, constituting an aqueous phase, which can form the continuous phase of the composition.
  • the aqueous phase may consist exclusively of water. It may also comprise a mixture of water and of water-miscible organic solvent
  • lower monoalcohols containing from 1 to 5 carbon atoms such as ethanol or isopropanol
  • glycols containing from 2 to 8 carbon atoms such as propylene glycol, ethylene glycol, 1,3-butylene glycol or dipropylene glycol, C 3 -C 4 ketones and C 2 -C 4 aldehydes.
  • the cosmetic composition that is suitable for use in the present invention may be in the form of a simple emulsion, a water-in-oil or oil- in-water emulsion, a multiple emulsion (water-oil-water or oil-water-oil) or an inverse emulsion, the use of which is well known to those skilled in the art.
  • the aqueous phase (water and optionally the water-miscible organic solvent) may be present in a content ranging from 0.1% to 50% by weight, especially ranging from 0.5% to 40% by weight, in particular from 1% to 25% by weight and in particular from 1% to 10% by weight relative to the total weight of the composition.
  • the composition according to the invention may be anhydrous.
  • anhydrous composition means a composition comprising less than 10% by weight of water relative to the total weight of the composition, especially less than 5%, in particular less than 2% and more particularly less than 1% by weight of water relative to the total weight of the composition.
  • an anhydrous composition according to the invention is free of water.
  • the cosmetic composition in accordance with the invention may advantageously incorporate one or more dyestuffs, especially such as pigments or pearls conventionally used in cosmetic compositions.
  • pigments should be understood as meaning white or colored, mineral or organic particles, which are insoluble in an aqueous solution and which are intended to color and/or opacify the corresponding cosmetic composition.
  • mineral pigments that may be used in the invention, mention may be made of zirconium oxide or cerium oxide and also zinc oxide or chromium oxide, ferric blue, manganese violet, ultramarine blue and chromium hydrate.
  • pearls should be understood as meaning iridescent or noniridescent colored particles of any form, produced especially by certain mo Husks in their shell or else synthesized, and which have a color effect by optical interference.
  • These dyestuffs may be present in a proportion of from 0.01% to 40% by weight, especially from 0.1% to 20% by weight and in particular from 0.5% to 15% by weight, or even from 1% to 10% by weight, relative to the total weight of the cosmetic composition.
  • compositions according to the invention comprise dyestuffs approved for food use especially referenced in the Codex alimentarius and more specifically the substances referenced in table 1 thereof.
  • the dyestuffs may be dyestuffs containing at least two materials, said dyestuff being referenced in the Codex alimentarius or consisting exclusively of materials referenced in the Codex alimentarius. More specifically, it is at least one dyestuff chosen from pearls consisting of materials referenced in the Codex alimentarius, lakes approved for food use, and also referenced in the Codex alimentarius, and coloring substances approved by the Codex alimentarius, and mixtures thereof.
  • dyestuffs that may be mentioned more particularly include mineral pigments such as titanium oxides and iron oxides, water-soluble or liposoluble coloring agents, for instance Sudan red, ⁇ -carotene, beetroot juice, the disodium salt of ponceau, the disodium salt of alizarine green, quinoline yellow, DC Red No. 7, DC Green No. 6, DC Yellow No. 11, DC Violet No. 2, DC Orange No.
  • mineral pigments such as titanium oxides and iron oxides
  • water-soluble or liposoluble coloring agents for instance Sudan red, ⁇ -carotene, beetroot juice, the disodium salt of ponceau, the disodium salt of alizarine green, quinoline yellow, DC Red No. 7, DC Green No. 6, DC Yellow No. 11, DC Violet No. 2, DC Orange No.
  • pearls based on mica coated with titanium and/or with iron oxide pearls based on mica coated with titanium and/or with iron oxide and surface-coated with at least one organic dye, for instance carbon black, and pearls based on mica coated with aluminum, silver and/or gold and, where appropriate, surface-coated with at least one organic dye.
  • organic dye for instance carbon black
  • the base material and the abovementioned surface coatings are materials approved for food use.
  • TiO 2 is authorized under the reference E171, iron oxide under the reference E172, carbon black under the reference E153, aluminum under the reference E 174, and gold under the reference E 175.
  • Such composite materials are especially sold by the company Merck under the name Candurin ® .
  • lakes mention may be made more particularly of carbon black, pigments of the type such as organic barium, strontium, calcium, aluminum or titanium lakes, including those submitted for certification by the Food and Drug Administration (FDA) (for example FD & C), lakes based on cochineal carmine, or the diketopyrrolopyrroles (DPP) described in documents EP-A-542 669, EP-A-787 730, EP-A-787 731 and WO-A-96/08537.
  • FDA Food and Drug Administration
  • DPP diketopyrrolopyrroles
  • pigments of "lake" type that are most particularly suitable for the invention, mention may be made especially of those sold by LCW Sensient under the names FD&C Yellow No. 5/E102, FD&C Yellow No. 6/E110, FD&C Blue No. 1/E132, FD&C Red No. 40/El 29, FD&C Blue No. 2 aluminum lake, FD&C Yellow No. 5 aluminum lake, FD&C Yellow No. 6 aluminum lake, FD&C Blue No. 1 aluminum lake, FD&C Red No. 40 aluminum lake and FD&C Green No. 3 aluminum lake. FD&C Blue No. 1 aluminum lake, FD&C Green No. 3 aluminum lake, FD&C Blue No. 1 aluminum lake, FD&C Green No. 3 aluminum lake, FD&C
  • Yellow No. 5 aluminum lake, FD&C Yellow No. 6 aluminum lake and FD&C Red No. 40 aluminum lake are most particularly advantageous.
  • these dyestuffs are especially advantageous for affording an effect other than a simple conventional shade effect, i.e. a unified and stabilized effect as produced by standard dyestuffs, for instance monochromatic pigments.
  • the term "stabilized" means free of a color variability effect according to the angle of observation.
  • the effect obtained with the pearls and/or lakes may be an effect chosen from metallic effects, and especially a mirror, soft- focus and/or rainbow effect.
  • the compositions may obviously comprise other organic or inorganic coloring substances.
  • organic pigments may thus be organic pigments. Mention may especially be made of those known under the following names: D&C Blue No. 4, D&C Brown No. 1, D&C Green No. 5, D&C Green No. 6, D&C Orange No. 4, D&C Orange No. 5, D&C Orange No. 10, D&C Orange No. 11, D&C Red No. 6, D&C Red No. 7, D&C Red No. 17, D&C Red No. 21, D&C Red No. 22, D&C Red No. 27, D&C Red No. 28, D&C Red No. 30, D&C Red No. 31, D&C Red No. 33, D&C Red No. 34, D&C Red No. 36, D&C Violet No. 2, D&C Yellow No. 7, D&C Yellow No. 8, D&C Yellow No. 10, D&C Yellow No. 11.
  • the organic dyestuff may comprise an organic lake supported on an organic support such as colophony or aluminum benzoate, for example.
  • organic lakes that may be mentioned in particular are those known under the following names: D&C Red No. 2 Aluminum lake, D&C Red No. 3 Aluminum lake, D&C Red No. 4 Aluminum lake, D&C Red No. 6 Aluminum lake, D&C Red No. 6 Barium lake, D&C Red No. 6 Barium/Strontium lake, D&C Red No. 6 Strontium lake, D&C Red No. 6 Potassium lake, D&C Red No. 7 Aluminum lake, D&C Red No. 7 Barium lake, D&C Red No. 7 Calcium lake, D&C Red No. 7 Calcium/Strontium lake, D&C Red No. 7 Zirconium lake, D&C Red No. 8 Sodium lake, D&C Red No.
  • D&C Red No. 30 lake Aluminum lake, D&C Red No. 31 Calcium lake, D&C Red No. 33 Aluminum lake, D&C Red No. 34 Calcium lake, D&C Red No. 36 lake, D&C Red No. 40 Aluminum lake, D&C Blue No. 1 Aluminum lake, D&C Green No. 3 Aluminum lake, D&C Orange No. 4 Aluminum lake, D&C Orange No. 5 Aluminum lake, D&C Orange No. 5 Zirconium lake, D&C Orange No. 10 Aluminum lake, D&C Orange No. 17 Barium lake, D&C Yellow No. 5 Aluminum lake, D&C Yellow No. 5 Zirconium lake, D&C Yellow No. 6 Aluminum lake, D&C Yellow No. 7 Zirconium lake, D&C Yellow No. 10 Aluminum lake.
  • compositions according to the invention may also contain diffracting agents, goniochromatic agents and/or reflective particles.
  • compositions according to the instant invention contain dyestuff considered as being food grade compound as defined here- above.
  • dyestuff can be chosen from dyestuff having the specifications given in the US Code of Federal Regulation Title 21 Chap I parts 73, 74 and 82.
  • the dyestuff will in particular be made of at least 50% by weight, more particularly at least 75% by weight, especially 90% by weight of the total weight, of "food grade compounds" as defined here-above.
  • these compositions may be free of non food grade dyestuff.
  • the cosmetic compositions also generally contain fillers of mineral or organic origin. Needless to say, compounds proposed above, especially as coloring agent, are capable of jointly fulfilling this function.
  • Nonpigmentary inorganic compounds approved by the Codex alimentarius and more particularly referenced in table 1 thereof are most particularly suitable for the invention.
  • talc precipitated calcium carbonate, magnesium carbonate, rice starch and magnesium hydrogen carbonate.
  • compositions according to the invention may also comprise any ingredient conventionally used as additives in cosmetics and dermatology.
  • additives are advantageously chosen from the food additives proposed in table 1 of the Codex alimentarius, for example antioxidants, thickeners, sequestrants, acidifying or basifying agents and preserving agents, and mixtures thereof.
  • compositions according to the invention may also contain flavorings and/or fragrances.
  • the amounts of these various ingredients are those conventionally used in the fields under consideration and range, for example, from 0.01% to 20% by weight relative to the total weight of the composition.
  • the cosmetic compositions according to the invention may also have a gloss of greater than or equal to 5, in particular greater than or equal to 10, especially greater than or equal to 15, more particularly greater than or equal to 20, especially greater than or equal to 25, greater than or equal to 30, or even about 50.
  • gloss denotes the gloss as may be measured by the following method, using a gonioreflectometer machine, for instance the GRM-2000 machine (from Micromodule), using an azimuth illumination angle of 30° relative to the normal of the sample, a specular reflection (R) detection angle of -30° and a diffuse reflection (D) detection angle of 0°.
  • Neoprene ® 3 mm thick which has an adhesive face, especially a foam known under the trade reference RE40 x 70 C/C 212B 1 skin, sold by the company Joint Technique
  • the foam support bearing the transparent adhesive plaster is then attached, by bonding by means of its adhesive face, to a metal plate 40x70 mm in size.
  • the assembly consisting of the support bonded to the metal plate forms a specimen.
  • the operator places the specimen on a hotplate set at a temperature of 38.5 °C, for example a hotplate of the type N81076 sold by the company Fisher Bioblock, and waits for the face of the support bearing the adhesive coating to reach a temperature of 33 ⁇ 1°C.
  • the operator manually applies a film about 15 ⁇ m thick of the cosmetic product to the Blenderm ® coating.
  • the cosmetic product which is, for example, a lipstick, was stored at 24 ⁇ 2°C.
  • the action performed by the operator to deposit the film of product consists of a to-and-fro motion, so as to obtain a uniform deposit.
  • the application of the product to the support is preferably performed so as to be as representative as possible of the real conditions of application of the product.
  • the same test product is applied in an identical manner to the five same specimens prepared previously.
  • the film of product is left to dry, the specimen being placed on the hotplate, such that the support remains at 33 ⁇ 1°C for 10 minutes.
  • the intensity of the specular reflection and that of the diffuse reflection of the film of product are measured at the incidences specified previously, for each of the five specimens.
  • the gloss Gloss t is calculated for each specimen via the ratio R/D for this specimen.
  • the weighting of the specular reflection measurement, generally used alone to characterize the gloss, by the diffuse reflection measurement (representative of the color/lightness of the sample) allows the visual perception of the gloss to be better appreciated.
  • the mean gloss value Gloss may finally be calculated:
  • compositions according to the invention may be suitable for forming a deposit with a wear of color index of greater than or equal to 30%, preferably greater than or equal to 40%, preferably greater than or equal to 45%, preferably greater than or equal to 50%, especially greater than or equal to 55%, in particular greater than or equal to 60%, or even greater than or equal to 65%, or greater than or equal to 70%.
  • the wear of color index of the deposit obtained with the composition according to the invention may be determined according to the measuring protocol described below.
  • a support (40 mm x 70 mm rectangle) consisting of an acrylic coating
  • the color L* o a* o b* o of the support, on the acrylic coating face, is measured using a Minolta CR 300 colorimeter.
  • the support thus prepared is preheated on a hotplate maintained at a temperature of 40°C in order for the surface of the support to be maintained at a temperature of 33°C ⁇ 1°C.
  • the hot support is removed from the plate and the composition is applied throughout the nonadhesive surface of the support (i.e. over the surface of the acrylic coating), spreading it out using a brush to obtain a deposit of about 15 ⁇ m of the composition.
  • the assembly is returned to the hotplate and left to dry for 10 minutes.
  • ⁇ E1 V(L * -L 0 * ) 2 ⁇ (a * - a o * ) 2 + (b * - b 0 T
  • the support is then bonded via its adhesive face (adhesive face of the foam layer) to an anvil 20 mm in diameter equipped with a screw pitch.
  • a specimen of the support/deposit assembly is then cut out using a punch 18 mm in diameter.
  • the anvil is then screwed onto a press (Statif Manuel Imada SV-2 from the company Someco) equipped with a tensile testing machine (Imada DPS-20 from the company Someco).
  • a strip 33 mm wide and 29.7 cm long is drawn on a sheet of white photocopying paper with a basis weight of 80 g/m 2 , a first line is marked 2 cm from the edge of the sheet, and a second line is then marked 5 cm from the edge of the sheet, the first and second lines thus delimiting a box on the strip; next, a first mark and a second mark located in the strip at reference points 8 cm and 16 cm, respectively, from the second line, are applied. 20 ⁇ l of water are placed on the first mark and 10 ⁇ l of refined sunflower oil (sold by the company Lesieur) are placed on the second mark.
  • the white paper is placed on the base of the press and the specimen placed on the box of the strip of paper is then pressed at a pressure of about 300 g/cm exerted for 30 seconds. Before pressing again, the specimen is removed and a measurement corresponding to the transfer after pressure is taken. The specimen is then placed again just after the second mark (i.e. next to the box), a pressure of about 300 g/cm 2 is again exerted, and the paper is displaced, in a rectilinear manner as soon as the contact is made, at a speed of 1 cm/s over the entire length of the strip such that the specimen passes through the water and oil deposits. After removing the specimen, some of the deposit has transferred onto the paper. The color L*', a*', b*' of the deposit remaining on the specimen is then measured.
  • the wear of color index of the composition is equal to the ratio:
  • the measurement is performed on 6 supports in succession and the transfer index corresponds to the mean of the 6 measurements obtained with the 6 supports.
  • the cosmetic compositions according to the invention may have a covering power of greater than or equal to 30, in particular greater than or equal to 50, especially greater than or equal to 60, more particularly greater than or equal to 80 and especially ranging from 90 to 100, or even of about 100.
  • This covering power may be measured via the following method.
  • the composition is blended beforehand so as to obtain a viscous paste.
  • the formulation is then spread to a thickness of 50 ⁇ m on an Erichsen type 24/5 contrast card, with a black background and a white background, and the trichromatic coordinates (X, Y and Z) are measured using a CH-2002 or CR-3700 colorimeter. Similar spreadings are made on two other contrast cards and three measurements are taken on each card. The mean corresponding to these nine measurements is then calculated.
  • the covering power is equal to 100 x Yb/Yw where Yb is the mean value of Y on the black background and Yw is the mean value of Y on the white background.
  • a covering power of 100 corresponds to a totally opaque formulation.
  • compositions according to the invention may be in the form of a colored or uncolored product or in the form of an antisun product. They may especially contain cosmetic active agents. They may then be used as a care or treatment base for the lips, for instance lip balms, for protecting the lips against the cold and/or sunlight and/or the wind.
  • cosmetic active agents that may be used in the invention, mention may be made of sunscreens, vitamins A, E, C and B3, provitamins, for instance D-panthenol, calmative active agents, for instance ⁇ -bisabolol, aloe vera or allantoin, plant extracts or essential oils, protective or restructuring agents, for instance ceramides, refreshing active agents, for instance menthol and derivatives thereof, emollients (cocoa butter), moisturizers (arginine PCA), anti-wrinkle active agents and essential fatty acids, and mixtures thereof.
  • sunscreens vitamins A, E, C and B3, provitamins, for instance D-panthenol
  • calmative active agents for instance ⁇ -bisabolol, aloe vera or allantoin
  • plant extracts or essential oils protective or restructuring agents
  • protective or restructuring agents for instance ceramides
  • refreshing active agents for instance menthol and derivatives thereof
  • emollients cocoa butter
  • moisturizers arg
  • composition of the invention may also be in the form of a lip makeup product, for instance a lipstick or a lip gloss, optionally having care or treating properties.
  • a lip makeup product for instance a lipstick or a lip gloss
  • the compositions according to the invention may be obtained according to the preparation processes conventionally used in cosmetics or dermatology.
  • compositions packaged according to the invention may be in very varied forms.
  • they may be in the form of a paste or a cream.
  • They may be an emulsion, especially an oil-in-water or water-in-oil emulsion, a solid or soft anhydrous gel, or may be in the form of loose or compacted powder, cast as a stick or a dish, and even in two-phase form.
  • they are in the form of an emulsion.
  • the makeup device according to the invention is chosen so as to be adapted to the galenical form of the composition.
  • FIG. 1 is a view in elevation, with partial longitudinal cross section, of a first example of implementation of the invention
  • FIG. 2 schematically shows, in perspective, a packaging device according to another implementation example of the invention
  • - figure 3 is a view in elevation, with partial longitudinal cross section, of another example of a packaging device according to the invention, - figure 4 shows in elevation another example of packaging device,
  • FIG. 5 is a schematic view in perspective of another example of a packaging device
  • FIG. 6 shows in perspective a single-use packaging device
  • FIG. 7 shows in elevation another example of a single-use packaging device.
  • Figure 1 shows a packaging and distribution device 1 that may be suitable for packaging a composition according to the invention.
  • This device comprises a container 2 equipped with a takeup means 3, for instance a pump without air intake.
  • the composition may be contained inside the container 2 in a flexible bag 4.
  • An air intake orifice 5 may be provided in the container 2.
  • Figure 2 shows another example of a packaging and distribution device that may be suitable for packaging a composition according to the invention.
  • This device 10 comprises a pressurized container 11 equipped with a takeup means 12, for instance a valve.
  • the composition may be contained in the container 11 by being mixed with the propellent gas or, as a variant, in a flexible bag, the propellent gas being outside the bag that is inside the container.
  • the valve 12 When the user presses the valve 12, the composition may be sprayed by means of the pressure of the propellent gas.
  • This gas may be compressed air when the composition is kept contained in a flexible bag inside the container 11.
  • Figure 3 shows another packaging and distribution device 20 that may be suitable for a composition according to the invention.
  • This device comprises a container 21 and a cylindrical body in which may slide a piston 22.
  • the composition is contained inside the container 21 above the piston.
  • the container is equipped with a pump 23 without air intake, for taking up the composition. When the volume of said composition reduces, the piston rises in the cylindrical container body.
  • Figure 4 shows another packaging and distribution device 30 that may be suitable for a composition according to the invention.
  • This device 30 comprises a container 31 containing the composition and a maneuvering unit 32 that rotates relative to the container 31 to move a piston therein.
  • the maneuvering unit 32 is in the form, for example, of a thumbwheel in the bottom part of the container 31 and may be securely fastened to a threaded stem that enmeshes with the piston.
  • the container 31 may be provided with a distribution orifice equipped with a flap valve 33 so as to prevent air intake.
  • the thumbwheel 32 may be equipped with a mechanism that prevents rotation in the direction opposite to that causing the distribution of the composition.
  • Figure 5 shows a packaging and distribution device 50 in accordance with one implementation variant of the invention.
  • This device 50 comprises a container 51 containing at least one flexible wall, for example in the form of a flexible tube.
  • the container 51 comprises a neck 52, which is, for example, threaded so as to allow a sealing cap, not shown, to be affixed, and which may be equipped with a distribution flap valve 53 preventing air intake after distribution of a dose of the composition.
  • This flap valve 53 is, for example, an elastomeric flap valve or a ball check valve.
  • the devices illustrated by the above set of figures are more particularly suitable for packaging fluid cosmetic compositions, for instance foundations and/or solutions intended to provide an additional effect to an already-applied makeup composition, for example in terms of gloss and/or staying power of the makeup.
  • FIG. 6 shows a single-use packaging and distribution device 60 in the form of a tray 63.
  • This tray contains the composition C, which impregnates, for example, a support 62 to be applied to the area to be treated.
  • This support is arranged in a housing 62 present in the tray.
  • the tray is sealed in a leaktight manner before the first use by means of a lid 61, which is, for example, thermowelded onto the tray, at least one portion 64 of which cannot adhere to the receptacle, so as to allow its handling.
  • This type of device is particularly suitable for packaging the compositions illustrated by examples 1 to 9 below.
  • Figure 7 shows another example of a packaging and application device 70 comprising a tube containing the composition C, this tube 73 having a splitable end 71 and an application member 72 at another end.
  • the composition is insulated from the air via a silicone stopper.
  • a tube is sold by the company Swab Plus.
  • the compounds can be independently one from the other be chosen from compounds approved for food use. According to one embodiment they can independently advantageously be food grade compounds as defined here-above.
  • the following compounds can be used in the examples:
  • sucrose acetate isobutyrate sold by Eastman under the trademark Eastman SAIB-100
  • deodorized apricot kernel oil sold by Nestle under the trademark
  • the waxes, the pasty compounds and the oils are melted at 100°C.
  • the ground pigmentary material containing the iron oxides and/or the aluminum lakes is incorporated therein and the mixture is then stirred for 45 minutes. At the end of the stirring period, the pearls and optionally the flavoring are added.
  • the mixture is poured into a tray such as that illustrated in figure 6, preheated to 42°C.
  • the tray is then placed in a refrigerator until the temperature of the mold reaches 2°C.
  • the mixture is then hermetically packaged using a lid that is thermowelded onto the edges of the tray.
  • Table 1 below presents seven lipstick formulations incorporating, as dyestuffs, lakes and pearls approved for food use. These dyestuffs are specifically made to match the needs of the food industry. They consist only of an edible silicate of natural origin in combination with the widely approved food colorants titanium dioxide and/or iron oxide. The composition of the white substance used in combination with the various mixtures of pearls and lakes is as follows: weight %
  • Cast foundation formulation weight %
  • Titanium dioxide 1.82
  • Red 27 lake 0.29 Red 7 1.51

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Insects & Arthropods (AREA)
  • Zoology (AREA)
  • Cosmetics (AREA)
  • Packages (AREA)

Abstract

L'invention porte sur un dispositif d'emballage et de distribution d'une composition cosmétique de matériaux de soin et/ou de maquillage consistant en un récipient délimitant au moins un compartiment contenant la composition cosmétique laquelle comprend au moins 50 % de son poids total d'un ou de composés à usage alimentaire. Le dispositif est tel qu'aussi longtemps que la composition cosmétique reste dans le compartiment, elle peut être maintenue à l'abri de l'air jusqu'à sa distribution sur une substance kératineuse.
PCT/IB2006/052399 2005-07-13 2006-07-13 Dispositif d'emballage et de distribution d'une composition cosmétique Ceased WO2007007295A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0552215A FR2888476B1 (fr) 2005-07-13 2005-07-13 Dispositif de conditionnement et de distribution d'une composition cosmetique
FR0552215 2005-07-13
US71217605P 2005-08-30 2005-08-30
US60/712,176 2005-08-30

Publications (2)

Publication Number Publication Date
WO2007007295A2 true WO2007007295A2 (fr) 2007-01-18
WO2007007295A3 WO2007007295A3 (fr) 2007-03-29

Family

ID=37467513

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2006/052399 Ceased WO2007007295A2 (fr) 2005-07-13 2006-07-13 Dispositif d'emballage et de distribution d'une composition cosmétique

Country Status (1)

Country Link
WO (1) WO2007007295A2 (fr)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3189231A (en) * 1963-01-16 1965-06-15 Fmc Corp Aerosol dispenser with sponge follower and method of making same
LU60732A1 (fr) * 1970-04-15 1972-03-02
DE3539999A1 (de) * 1985-11-12 1987-05-21 Schlerf Coronet Werke Spender fuer pastenfoermige oder fliessfaehige medien
FR2659631B1 (fr) * 1990-03-14 1992-07-31 Cebal Distributeur de produit pateux melange d'un deuxieme produit et son utilisation.
JPH09208445A (ja) * 1996-02-06 1997-08-12 Nakano Mari ニンニク化粧品
US5839616A (en) * 1997-08-14 1998-11-24 The Procter & Gamble Company Blow molded container having pivotal connector for an actuation lever
DE10246377B4 (de) * 2002-10-04 2007-01-11 Beiersdorf Ag Verfahren zur Herstellung von Pflastersystemen mit dotierten Trägermaterialien als Reservoir
CN1522581A (zh) * 2003-02-18 2004-08-25 戚海燕 一种食用又能美容护肤奶粉

Also Published As

Publication number Publication date
WO2007007295A3 (fr) 2007-03-29

Similar Documents

Publication Publication Date Title
WO2007007288A2 (fr) Ensemble de maquillage et/ou de soin cosmetique
ES2285999T3 (es) Composicion cosmetica que comprende un ester de acido graso hidroxilado.
CN1980628A (zh) 液体酯组合物以及含有其的化妆料
JP2006028181A (ja) シリコーンポリマーを含む２段コート式化粧用製品
US20060062752A1 (en) Oil-based cosmetic preparation
JP2005510496A (ja) エステルの脂肪族エステルおよび６５０ｇ／モルから１００００ｇ／モルの範囲のモル質量を有する油を含む、ケラチン物質のための化粧用ケアまたはメーキャップ組成物
US20090142286A1 (en) Cosmetic Makeup And/Or Care Process
WO2004100903A1 (fr) Preparation cosmetique a base d'huile
JP2008133280A (ja) 少なくとも一つの揮発性炭酸エステルを含む化粧品組成物
JP2005036005A (ja) ポリエステルを含む、ケラチン質のケアまたはメイクアップ用化粧品組成物とその使用
US20090028958A1 (en) Cosmetic Makeup and/or Care Process
JP5996155B2 (ja) 少なくとも一つの揮発性エステルを含む化粧品組成物
US20100015074A1 (en) Cosmetic Makeup and/or Care Process
US20090123403A1 (en) Cosmetic Composition With Color And/Or Optical Effects
WO2007007292A2 (fr) Produit cosmetique de maquillage et/ou de soin
WO2007007290A1 (fr) Maquillage et/ou procede de soins
WO2007007293A2 (fr) Compositions cosmetiques en batonnet
WO2007007295A2 (fr) Dispositif d'emballage et de distribution d'une composition cosmétique
CN116270312A (zh) 一种防晒棒和该防晒棒的制备方法
KR20230137931A (ko) 케라틴 물질의 케어 및/또는 메이크업을 위한 고체무수 조성물
JP5068948B2 (ja) アルコキシル化アルコールエステルおよび炭化水素系エステル油を含む化粧品組成物
WO2007007294A2 (fr) Film de produit cosmetique
FR2888476A1 (fr) Dispositif de conditionnement et de distribution d'une composition cosmetique
JP2006131636A (ja) オルガノゲルを形成できる無水の化粧料組成物
FR2888498A1 (fr) Composition cosmetique de type stick

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Country of ref document: DE

122 Ep: pct application non-entry in european phase

Ref document number: 06766074

Country of ref document: EP

Kind code of ref document: A2