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WO2007001380A3 - High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making - Google Patents

High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making Download PDF

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Publication number
WO2007001380A3
WO2007001380A3 PCT/US2005/033755 US2005033755W WO2007001380A3 WO 2007001380 A3 WO2007001380 A3 WO 2007001380A3 US 2005033755 W US2005033755 W US 2005033755W WO 2007001380 A3 WO2007001380 A3 WO 2007001380A3
Authority
WO
WIPO (PCT)
Prior art keywords
glass
fuel cells
solid oxide
oxide fuel
metal part
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2005/033755
Other languages
French (fr)
Other versions
WO2007001380B1 (en
WO2007001380A2 (en
Inventor
K Scott Weil
Lawrence A Chick
Christopher A Coyle
John S Hardy
Guanguang Xia
Kerry D Meinhardt
Vincent L Sprenkle
Dean M Paxton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Memorial Institute Inc
Original Assignee
Battelle Memorial Institute Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/948,346 external-priority patent/US20060060633A1/en
Priority claimed from US10/948,359 external-priority patent/US20060063057A1/en
Application filed by Battelle Memorial Institute Inc filed Critical Battelle Memorial Institute Inc
Priority to JP2007533592A priority Critical patent/JP2008513346A/en
Priority to EP05858161A priority patent/EP1836138A2/en
Priority to CA002579781A priority patent/CA2579781A1/en
Publication of WO2007001380A2 publication Critical patent/WO2007001380A2/en
Anticipated expiration legal-status Critical
Publication of WO2007001380A3 publication Critical patent/WO2007001380A3/en
Publication of WO2007001380B1 publication Critical patent/WO2007001380B1/en
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/04—Joining glass to metal by means of an interlayer
    • C03C27/042—Joining glass to metal by means of an interlayer consisting of a combination of materials selected from glass, glass-ceramic or ceramic material with metals, metal oxides or metal salts
    • C03C27/044—Joining glass to metal by means of an interlayer consisting of a combination of materials selected from glass, glass-ceramic or ceramic material with metals, metal oxides or metal salts of glass, glass-ceramic or ceramic material only
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/183—Sealing members
    • H01M50/186—Sealing members characterised by the disposition of the sealing members
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/04—Joining glass to metal by means of an interlayer
    • C03C27/042—Joining glass to metal by means of an interlayer consisting of a combination of materials selected from glass, glass-ceramic or ceramic material with metals, metal oxides or metal salts
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
    • C—CHEMISTRY; METALLURGY
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
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    • H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/59—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/0282—Inorganic material
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    • H01M8/10—Fuel cells with solid electrolytes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00—Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/02—Ceramics
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    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6025—Tape casting, e.g. with a doctor blade
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    • C04B2237/706—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the metallic layers or articles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/70—Forming laminates or joined articles comprising layers of a specific, unusual thickness
    • C04B2237/708—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the interlayers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Fuel Cell (AREA)
  • Glass Compositions (AREA)
  • Ceramic Products (AREA)
  • Gasket Seals (AREA)

Abstract

A seal formed between two parts that will remain gas tight in high temperature operating environments which experience frequent thermal cycling, which is particularly useful as an insulating joint in solid oxide fuel cells. A first metal part is attached to a reinforcing material. A glass forming material in the positioned in between the first metal part and the second part, and a seal is formed between the first metal part and the second part by heating the glass to a temperature suitable to melt the glass forming materials. The glass encapsulates and bonds at least a portion of the reinforcing material, thereby adding tremendous strength to the overall seal. A ceramic material may be added to the glass forming materials, to assist in forming an insulating barrier between the first metal part and the second part and to regulating the viscosity of the glass during the heating step.
PCT/US2005/033755 2004-09-22 2005-09-19 High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making Ceased WO2007001380A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2007533592A JP2008513346A (en) 2004-09-22 2005-09-19 High strength insulating joints for solid oxide fuel cells and other high temperature applications and methods of making the same
EP05858161A EP1836138A2 (en) 2004-09-22 2005-09-19 High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making
CA002579781A CA2579781A1 (en) 2004-09-22 2005-09-19 High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/948,346 2004-09-22
US10/948,359 2004-09-22
US10/948,346 US20060060633A1 (en) 2004-09-22 2004-09-22 High strength insulating metal-to-ceramic joints for solid oxide fuel cells and other high temperature applications and method of making
US10/948,359 US20060063057A1 (en) 2004-09-22 2004-09-22 High strength insulating metal-to-metal joints for solid oxide fuel cells and other high temperature applications and method of making

Publications (3)

Publication Number Publication Date
WO2007001380A2 WO2007001380A2 (en) 2007-01-04
WO2007001380A3 true WO2007001380A3 (en) 2007-07-26
WO2007001380B1 WO2007001380B1 (en) 2007-08-23

Family

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PCT/US2005/033755 Ceased WO2007001380A2 (en) 2004-09-22 2005-09-19 High strength insulating joints for solid oxide fuel cells and other high temperature applications and method of making

Country Status (5)

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EP (1) EP1836138A2 (en)
JP (1) JP2008513346A (en)
KR (1) KR20070059159A (en)
CA (1) CA2579781A1 (en)
WO (1) WO2007001380A2 (en)

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US20080290138A1 (en) * 2007-05-22 2008-11-27 David Myron Lineman Method for bonding refractory ceramic and metal
US7691488B2 (en) 2007-06-11 2010-04-06 Battelle Memorial Institute Diffusion barriers in modified air brazes
KR101046233B1 (en) * 2009-10-12 2011-07-04 주식회사 루트제이드 Containers of energy storage
US9296644B2 (en) 2010-02-15 2016-03-29 Schott Ag High-temperature glass solder and its uses
DE102010035251B4 (en) * 2010-02-15 2013-09-26 Schott Ag High-temperature glass solder and its use
JP5686182B2 (en) * 2011-03-24 2015-03-18 株式会社村田製作所 Solid oxide fuel cell bonding material, solid oxide fuel cell, and solid oxide fuel cell module
WO2012133086A1 (en) * 2011-03-25 2012-10-04 株式会社村田製作所 Bonding member for solid oxide fuel cell, solid oxide fuel cell, and solid oxide fuel cell module
WO2012133087A1 (en) * 2011-03-30 2012-10-04 株式会社村田製作所 Bonding member for solid oxide fuel cell, solid oxide fuel cell, and solid oxide fuel cell module
JP5705636B2 (en) * 2011-04-26 2015-04-22 日本特殊陶業株式会社 Solid oxide fuel cell
JP5686190B2 (en) * 2011-07-21 2015-03-18 株式会社村田製作所 Joining material for solid oxide fuel cell, method for producing solid oxide fuel cell, method for producing solid oxide fuel cell module, solid oxide fuel cell and solid oxide fuel cell module
WO2014018536A1 (en) * 2012-07-23 2014-01-30 Mo-Sci Corporation Viscous sealing glass compositions for solid oxide fuels cells
US9208929B2 (en) * 2013-09-20 2015-12-08 Schott Corporation GTMS connector for oil and gas market
WO2016053750A1 (en) * 2014-10-01 2016-04-07 Saint-Gobain Ceramics & Plastics, Inc. Methods of forming a glass composition
EP3650415B1 (en) * 2018-11-07 2024-02-07 Schott Ag Joint connection comprising a crystallised glass, its use, crystallisable and at least partially crystallised glass and its use

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WO2003011794A1 (en) * 2001-07-24 2003-02-13 Forschungszentrum Jülich GmbH Method for producing a gas-tight connection between a metallic and a ceramic substrate
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Also Published As

Publication number Publication date
JP2008513346A (en) 2008-05-01
KR20070059159A (en) 2007-06-11
EP1836138A2 (en) 2007-09-26
WO2007001380B1 (en) 2007-08-23
CA2579781A1 (en) 2007-01-04
WO2007001380A2 (en) 2007-01-04

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