WO2007099941A1 - Melting furnace and process for producing molten metal therewith - Google Patents
Melting furnace and process for producing molten metal therewith Download PDFInfo
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- WO2007099941A1 WO2007099941A1 PCT/JP2007/053619 JP2007053619W WO2007099941A1 WO 2007099941 A1 WO2007099941 A1 WO 2007099941A1 JP 2007053619 W JP2007053619 W JP 2007053619W WO 2007099941 A1 WO2007099941 A1 WO 2007099941A1
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- Prior art keywords
- main body
- slag
- change
- melting furnace
- molten metal
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/10—Details, accessories or equipment, e.g. dust-collectors, specially adapted for hearth-type furnaces
- F27B3/28—Arrangement of controlling, monitoring, alarm or the like devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/10—Details, accessories or equipment, e.g. dust-collectors, specially adapted for hearth-type furnaces
- F27B3/19—Arrangements of devices for discharging
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D19/00—Arrangements of controlling devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
- F27D21/0028—Devices for monitoring the level of the melt
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/14—Charging or discharging liquid or molten material
Definitions
- the present invention relates to a melting furnace for continuously producing a molten metal such as molten iron by melting a solid reduced metal such as solid reduced iron, and a molten metal production method using the same. It is related with the grasp and control technology of the slag level inside.
- the melting furnace also uses molten iron and slag by means of repeatedly opening the tap holes and taking out the molten iron and slag and then closing the tap holes with mud at regular intervals. Can be taken out.
- Patent Document 2 a smelting reduction furnace in which an iron raw material, a charcoal material, and a slagging agent are charged as raw fuel into a melting furnace body, oxygen is blown, and the iron raw material is melted and reduced to directly produce molten iron
- a hot metal reservoir and a slag reservoir communicating with the melting furnace main body through siphon ports, respectively, and the outlet is located at the tip of the hot metal reservoir.
- the one provided with a tap is disclosed.
- Patent Document 2 describes that the hot metal and slag in the melting furnace body are discharged out of the furnace from the hot metal reservoir and the slag reservoir through the outlet and outlet through the siphon port, respectively. ⁇ The
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-176170
- Patent Document 2 JP-A-11 310814
- an object of the present invention is to easily and surely grasp the slag level in a furnace for melting a solid reduced metal such as solid reduced iron to produce a molten metal such as molten iron.
- a melting furnace that can be controlled simultaneously and a method for producing a molten metal using the same.
- a batch type discharge port is provided at a position higher than the discharge port for discharging the slag in the main body of the melting furnace body. At least one of the amount of change in the pressure in the main body and the amount of change in the temperature of the exhaust gas exhausted by opening and closing the push-type exhaust pipe is detected.
- the slag level in the furnace can be easily and reliably grasped and controlled based on the amount of gasification or the temperature change of the exhaust gas.
- FIG. 1 is a front sectional view showing a melting furnace according to an embodiment of the present invention.
- FIG. 2 is a plan view showing a melting furnace according to an embodiment of the present invention.
- FIG. 3 (a) is a sectional view showing a continuous discharge port, and (b) is a cross-sectional view showing a continuous molten iron discharge port.
- FIG. 4 is a flow diagram illustrating a method of controlling the slag level by detecting the amount of pressure change in the main body.
- FIG. 5 is a flowchart for explaining a slag level control method based on detection of an ID fan damper opening change amount, which is a modification of the embodiment of the present invention.
- FIG. 1 is a front sectional view showing a melting furnace according to an embodiment of the present invention
- FIG. 2 is a plan view thereof
- FIG. 3 (a) is a sectional view showing a continuous discharge port
- FIG. 3 (b) is continuous molten iron. It is sectional drawing which shows a discharge port.
- the melting furnace includes a main body la for melting solid reduced iron therein to obtain a molten metal containing molten iron M and slag S, and an outer side of a lower portion of the main body la.
- a melting furnace main body 1 having a molten metal reservoir portion lb provided in.
- the main body (hereinafter also referred to simply as "furnace", for example, “inside the furnace” means “inside the main body of the melting furnace body”.)
- the la ceiling has solid reduced iron R, carbonaceous material, Raw material input 2 for supplying raw fuel made of ironmaking agent or the like into the main body la and charcoal material in slag and carbon in Z or molten iron as a heat source for melting solid reduced iron R
- an oxygen blowing lance 3 for secondary combustion of the gas generated in the furnace and exhaust gas after secondary combustion from the main body la
- An exhaust gas duct 4 is provided.
- the molten metal reservoir lb has an internal space communicating with the inside of the main body la through the siphon 5, and the molten metal reservoir lb has a continuous exhaust for continuously discharging slag S.
- the continuous discharge port 7 and the continuous molten iron discharge port 8 have a groove shape extending in the vertical direction in FIG. 2, and the continuous discharge port 7 and the continuous molten iron discharge port 8 form the inside of the molten metal reservoir lb.
- the space is open upward and horizontally.
- the continuous waste pipe 7 is provided upstream of the continuous molten iron outlet 8 (that is, the side closer to the main body la). (See Fig. 2), its height position (ie, the lowest point position of the continuous discharge port 7) HA is the height position of the continuous molten iron discharge port 8 (ie, the lowest point of the continuous molten iron discharge port 8) (Point position) It should be higher than HB (see Fig. 3).
- a notch type exhaust rod 9 configured to be openable and closable separately from the continuous exhaust rod 7 is provided on the side wall of the main body la.
- the height position of the Notch type exhaust rod 9 (that is, the position of the lowest point of the portion of the Notch type exhaust rod 9 that penetrates the side wall of the main body la) HC is from the height position HA of the continuous exhaust port 7 It ’s too expensive. For example, if a slide gate system is used as the open / close mechanism of the batch type outlet 9,
- the melting furnace body 1 is for detecting the amount of change in the pressure in the main body la (hereinafter, also simply referred to as "furnace pressure") when the notch type exhaust rod 9 is opened and closed.
- a pressure gauge 11 is provided, and the exhaust gas duct 4 is provided with a thermometer 12 for detecting the amount of change in exhaust gas temperature when the batch type exhaust port 9 is opened and closed.
- the pressure gauge 11 for detecting the amount of change in pressure may be provided in the exhaust gas treatment facility (including the exhaust gas duct) for treating the exhaust gas from the melting furnace body 1 in addition to the melting furnace body 1. .
- the siphon 5 may be configured by a gap between the bottom of the melting furnace body 1 and the partition wall 10 suspended from the ceiling of the melting furnace body 1.
- the siphon 5 may be provided in the molten metal reservoir lb.
- the partition wall 10 can be moved up and down, and the upper end height position HD of the siphon 5 can be adjusted by adjusting the immersion depth of the partition wall 10 in the molten metal (slag + molten iron). Is preferred.
- a raw material made of solid reduced iron R or the like is dissolved and separated into slag and molten iron, and a slag layer S is formed on the molten iron layer M! .
- the raw material charged from the raw material inlet 2 is submerged in the slag layer S and dissolved by the combustion heat of the gas generated in the carbonaceous material furnace by the oxygen blown by the oxygen blowing lance 3 or oxygen-enriched air. Is done.
- the melted raw material is separated into slag and molten iron and moves into the slag layer S and the molten iron layer M, respectively, and both the molten iron level ML and the slag level SL in the main body la rise.
- the upper end height position HD of the siphon 5 is set so that the exhaust gas in the main body la does not blow out of the furnace or the outside air does not leak into the main body la. It is necessary to keep the partition wall 10 lower than the bell SL, that is, to immerse the partition wall 10 in at least the molten metal. However, when the upper end height position HD of the siphon 5 is made lower than the molten iron level ML, that is, when the partition wall 10 is immersed into the molten iron layer M, the slag S in the main body la can pass through the siphon 5.
- the upper end height position of the siphon 5 must be in the range of the slag layer S, that is, the partition wall 10 should be kept immersed in the slag layer S. .
- the reduction rate of solid reduced iron obtained in the reduction furnace particularly in the process of manufacturing molten iron by connecting the rotary hearth furnace (reduction furnace) and melting furnace described in Patent Document 1 above.
- the components such as the carbon content and the carbon content vary, the discharge rate of the reduction furnace fluctuates, the amount of raw fuel input to the main body la of the melting furnace body 1 fluctuates, the variation of these components, the fluctuation of the input amount, etc. If an unsteady reaction occurs in the main body la due to the occurrence of a slag, the balance between the generation rate of slag and molten iron in the main body 1a and the discharge rate from the molten metal reservoir lb is lost. Thus, the slag level SL in the main body la may vary greatly.
- the slag level SL in the main body la is higher than the batch type exhaust port 9, the slag exists at the front side of the notch type exhaust port 9 inside the furnace, so that the melting furnace has a positive pressure. If the furnace is being operated in the furnace, the slag will also flow out of the furnace first, and the gas power ⁇ , will not be blown out suddenly. The amount of intrusion is small V, and the degree of pressure drop in the main body la is small even when there is a slippage.
- the slag level SL is set to the batch type discharge port.
- the degree of pressure change in the main body 1a! / ⁇ (change amount) Force S is small, and in this case, the slag level SL should be above the batch type outlet 9 I understand.
- the amount of change in the pressure in the main body la can be measured using a pressure gauge 11 installed in the melting furnace main body 1 (or in the exhaust gas treatment facility).
- the slag level SL is set to the batch type exhaust port. It exists below port 9 and the degree of change in exhaust gas temperature! / ⁇ (change) is small! In this case, it can be seen that the slag level SL exists above the batch type outlet 9.
- the amount of change in the temperature of the exhaust gas can be measured using a thermometer 12 installed in the exhaust gas duct 4.
- the batch type exhaust port 9 is opened and closed periodically (for example, at intervals of 5 min), and the degree of change (change amount) in the pressure in the main body la and the temperature of Z or exhaust gas is changed.
- the degree of change (change amount) in the pressure in the main body la and the temperature of Z or exhaust gas is changed.
- the batch type discharge rod 9 is opened for a predetermined time (for example, 5 seconds) (see S2).
- a predetermined time for example, 5 seconds
- the pressure change amount ⁇ P in the main body la is compared with a predetermined set value ⁇ Ps (see S3).
- the slag level SL is higher than the batch type exhaust 9 Since the batch type outlet 9 is kept open for a predetermined time (for example, 5 seconds), a certain amount of slag is discharged from the batch type outlet 9 and the slag level is determined. (See S2). Then, ⁇ ⁇ and A Ps are compared again, and this loop (S2 ⁇ S3 ⁇ S) until ⁇ ⁇ A Ps (that is, until the slag level SL becomes lower than the batch-type discharge rod 9). Repeat 4 ⁇ S2).
- the set value A Ps may be determined as follows, for example. That is, in the past operation, ⁇ P when the batch type outlet 9 was opened and the slurry from the batch type outlet 9 If there is no slag outflow from the batch outlet 9, set the upper limit of ⁇ P to ⁇ Ps!
- partition wall 10 configured to be able to move up and down.
- the partition wall 10 is lowered, the immersion depth in the slag layer S is increased, and the opening area of the siphon 5 is reduced.
- the discharge rate of slag from within la can be reduced.
- the partition wall 10 is immersed in the molten iron layer M to prevent the slag in the main body la from flowing out of the siphon 5.
- the opening area can be manipulated only by the raising / lowering operation of the partition wall 10, but the slurry level cannot be controlled. If the partition wall 10 is immersed in the slag for a long period of time, it will be eroded and the immersion depth will change, resulting in poor accuracy. ! It is desirable that the partition wall 10 is moved up and down only when the slag level is continuously high or low.
- the present invention can naturally be applied to the case where the molten iron and the slag taken out from the main body of the melting furnace body are intermittently taken out by a tap hole similar to the blast furnace. That is, in the said embodiment, although the discharge port for discharging
- the change amount ⁇ T of the exhaust gas temperature is compared with a predetermined set value ⁇ Ts in step S3. Then, on condition that ⁇ AT ⁇ ATs, that is, when the exhaust gas temperature changes greatly due to the opening of the notch type exhaust 9, the batch type exhaust 9 is closed (see S6) Don't maintain SL and raise it.
- the partition wall 10 can be raised and lowered.
- the slag can be moved by the elevating partition wall 10 as described in the section of [Method of maintaining the slag level using the elevating partition wall]. If it is necessary to maintain the level, it can be fixed.
- one siphon 5 and one molten metal reservoir lb are installed one by one, and both the continuous discharge port and the continuous molten iron discharge port are provided in this one molten metal reservoir.
- two siphons may be provided, one with a slag reservoir, the other with a molten iron reservoir, and the former with a continuous drain and the latter with a molten iron outlet. .
- the oxygen blowing lance 3 is exemplified as the heat source supply means for dissolving the raw material, but an electrode may be used.
- solid reduced iron is exemplified as the solid reduced metal
- molten iron is exemplified as the molten metal, but as the metal element contained in the solid reduced metal and the molten metal, in addition to Fe, Mn, Ni, It may contain non-ferrous metals such as Cr, Mo and Ti.
- the amount of change in the temperature of the exhaust gas may be detected based on a method for detecting the amount of change in the pressure in the main body la. In this way, the slag level can be determined more accurately. Can be gripped.
- the melting furnace according to the present invention is a melting furnace that melts a solid reduced metal to produce a molten metal, and melts the solid reduced metal therein to contain a molten metal and slag.
- a melting furnace main body having a mouth, a pressure gauge for detecting a change in pressure in the main body when the batch type discharge port is opened and closed, and the main body when the batch type discharge port is opened and closed It is characterized by comprising at least one of thermometers for detecting the amount of change in the temperature of exhaust gas discharged from the component force.
- the discharge port is constituted by a continuous discharge port for continuously discharging the slag from the main body part through a siphon
- the furnace main body may be configured to further include a continuous molten metal discharge port for continuously discharging the molten metal via the main body part force siphon.
- the discharge port is configured by a tap hole for intermittently discharging the slag and the molten metal from the main body.
- the siphon may be configured by a gap between a bottom portion of the main body portion and a partition wall that is suspended from the ceiling portion of the main body portion so as to be lifted and lowered.
- a first molten metal production method is a method of producing a molten metal using the melting furnace, in which the batch type waste gas is periodically opened and closed. Detecting a change in pressure in the main body or a change in temperature of the exhaust gas, and grasping and controlling a slag level in the main body based on the detected change. .
- a second molten metal production method is a method of producing a molten metal using the melting furnace, in which the batch type waste gas is periodically opened and closed. Detect the amount of change in pressure in the main body or the amount of change in temperature of the exhaust gas. When the amount of change is less than a preset value, the batch type discharge port is opened for a predetermined time to discharge slag from the main body and lower the slag level in the main body. When the amount of change is equal to or greater than the set value, the slag level in the main body is controlled by closing the batch-type evacuation valve for a predetermined time and maintaining and increasing the slag level in the main body. It is characterized by this.
- the third molten metal production method is a method of producing a molten metal using a melting furnace having a siphon as described above, and periodically opening and closing the batch type discharge port. At this time, the amount of change in pressure in the main body or the amount of change in temperature of the exhaust gas is detected, and when the detected amount of change falls below a predetermined set value, the batch type exhaust port is opened. The main body force slag is discharged for a predetermined time to discharge the slag level in the main body, and when the detected change is equal to or greater than the set value, the batch type outlet is closed for a predetermined time.
- the slag level in the main body is controlled by maintaining or increasing the slag level in the main body, and when the slag level in the main body is excessively increased or decreased, the slag level in the main body is increased into the molten metal in the main body.
- the immersion depth of Kitsukamatsu cutting walls it is characterized in that to control the slag level in the body portion.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Furnace Charging Or Discharging (AREA)
- Gasification And Melting Of Waste (AREA)
Abstract
Description
明 細 書 Specification
溶解炉およびそれを用いた溶融金属製造方法 Melting furnace and molten metal manufacturing method using the same
技術分野 Technical field
[0001] 本発明は、固体還元鉄などの固体還元金属を溶解して溶鉄などの溶融金属を連 続的に製造する溶解炉およびそれを用いた溶融金属製造方法に関し、詳しくは、溶 解炉内のスラグレベルの把握および制御技術に関する。 TECHNICAL FIELD [0001] The present invention relates to a melting furnace for continuously producing a molten metal such as molten iron by melting a solid reduced metal such as solid reduced iron, and a molten metal production method using the same. It is related with the grasp and control technology of the slag level inside.
背景技術 Background art
[0002] 本出願人は、回転炉床炉と溶解炉を連結した溶鉄製造プロセスにおいて、酸ィ匕鉄 と炭素質還元剤を含む成形体を回転炉床炉で加熱還元して金属化率 60%以上の 固体還元鉄とした後、この固体還元鉄を溶解炉へ送り、燃料として供給される炭材を 酸素で燃焼させて該溶解炉内における二次燃焼率を 40%以下に制御しつつ、前記 固体還元鉄を溶解させて鉄溶湯を得る溶鉄の製造方法を開発した (特許文献 1参照 [0002] In a molten iron production process in which a rotary hearth furnace and a melting furnace are connected, the applicant of the present application heat-reduced a compact containing iron oxide and a carbonaceous reducing agent in the rotary hearth furnace to obtain a metallization rate of 60. After reducing the solid reduced iron to not less than 50%, this solid reduced iron is sent to the melting furnace, and the carbon material supplied as fuel is burned with oxygen to control the secondary combustion rate in the melting furnace to 40% or less. , Developed a method for producing molten iron by melting the solid reduced iron to obtain a molten iron (see Patent Document 1)
) o ) o
[0003] し力しながら、本出願人は、溶解炉内で固体還元鉄を溶解することにより生成した 溶鉄とスラグを溶解炉力も取り出す手段については、溶解炉の側壁にタップホールを 設けることのみを開示するにとどまっており、具体的な取り出し手段を開示していなか つた o [0003] However, as for the means for taking out the molten iron and slag generated by melting the solid reduced iron in the melting furnace, the applicant only provides a tap hole on the side wall of the melting furnace. No disclosure of specific means of retrieval o
[0004] もちろん、従来の高炉と同様、一定時間ごとに、タップホールを開口して溶鉄とスラ グを取り出した後にタップホールをマッドで閉塞することを繰り返す手段により、溶解 炉カも溶鉄とスラグを取り出すことが可能である。 [0004] Of course, as with conventional blast furnaces, the melting furnace also uses molten iron and slag by means of repeatedly opening the tap holes and taking out the molten iron and slag and then closing the tap holes with mud at regular intervals. Can be taken out.
[0005] 一方、特許文献 2では、溶解炉本体に鉄原料、炭材および造滓剤を原燃料として 装入し、酸素を吹き込んで、鉄原料を溶融還元し溶鉄を直接製造する溶融還元炉に おいて、溶解炉本体の下部の外側の左右に、溶解炉本体とそれぞれサイフォン口で 連通する溶銑溜まりおよびスラグ溜まりが設けられ、溶銑溜まりの先に出銑口が、スラ グ溜まりの先に出滓口が設けられたものが開示されている。そして、特許文献 2には、 溶解炉本体内の溶銑およびスラグは、それぞれサイフォン口を経て溶銑溜まりおよび スラグ溜まりから出銑口および出滓口を通って炉外に排出されることが記載されて ヽ る。 [0005] On the other hand, in Patent Document 2, a smelting reduction furnace in which an iron raw material, a charcoal material, and a slagging agent are charged as raw fuel into a melting furnace body, oxygen is blown, and the iron raw material is melted and reduced to directly produce molten iron In addition, on the left and right outside of the lower part of the melting furnace body, there are provided a hot metal reservoir and a slag reservoir communicating with the melting furnace main body through siphon ports, respectively, and the outlet is located at the tip of the hot metal reservoir. The one provided with a tap is disclosed. Patent Document 2 describes that the hot metal and slag in the melting furnace body are discharged out of the furnace from the hot metal reservoir and the slag reservoir through the outlet and outlet through the siphon port, respectively.ヽ The
[0006] 上記特許文献 2に記載の溶融還元炉によれば、溶鉄およびスラグを連続的に炉外 に取り出すことが可能になる。 [0006] According to the smelting reduction furnace described in Patent Document 2, molten iron and slag can be continuously taken out of the furnace.
[0007] し力しながら、上記高炉と同様の間欠的な取出し方法あるいは上記特許文献 2に記 載の連続的な取出し方法の 、ずれの取出し方法を採用するとしても、原燃料の成分 のノ ラツキや原燃料の投入量の変動等に加え、炉内においては非定常的な反応が 起こること力ゝら、溶鉄およびスラグの発生量や状況が変動し溶湯レベルゃスラダレべ ルが変動する。 [0007] Even though the intermittent removal method similar to that of the blast furnace or the continuous extraction method described in Patent Document 2 is employed, the deviation of the raw fuel component is not detected. In addition to fluctuations in the amount of injection and raw fuel input, the amount of molten iron and slag generated and the situation fluctuate due to the fact that an unsteady reaction takes place in the furnace.
[0008] ところが、溶解炉内は高温でかつ溶融ダストが多量に発生するため常時監視するこ とは実際上不可能であり、スラグレベルを把握することはもちろん、ましてゃスラグレ ベルを確実に一定レベルに維持するように制御することは非常に困難な状態にあつ た。 [0008] However, since the melting furnace is high temperature and a large amount of molten dust is generated, it is practically impossible to constantly monitor the slag level. It was very difficult to control to maintain the level.
[0009] このため、スラグレベルが異常に上昇した場合でも、その検知および制御が非常に 困難なため、炉蓋シール部などから高温のスラグが炉外に噴出したり、炉蓋シール部 の水冷構造ゃ炉頂に接続する水冷ダクトなどに高温のスラグが接触して冷却水が漏 れ、水蒸気爆発を引き起こしたりする危険性が存在していた。 [0009] For this reason, even when the slag level rises abnormally, it is very difficult to detect and control the slag level, so high-temperature slag is ejected from the furnace seal part or the like, or water cooling of the furnace cover seal part is performed. There was a danger that high-temperature slag would come into contact with the water-cooled duct connected to the top of the furnace and the coolant would leak, causing a steam explosion.
特許文献 1:特開 2004 - 176170号公報 Patent Document 1: Japanese Patent Application Laid-Open No. 2004-176170
特許文献 2 :特開平 11 310814号公報 Patent Document 2: JP-A-11 310814
発明の開示 Disclosure of the invention
[0010] そこで、本発明の目的は、固体還元鉄などの固体還元金属を溶解して溶鉄などの 溶融金属を製造する溶解炉にぉ 、て、炉内のスラグレベルを容易かつ確実に把握し うるとともに制御しうる溶解炉およびそれを用いた溶融金属の製造方法を提供するこ とである。 [0010] Therefore, an object of the present invention is to easily and surely grasp the slag level in a furnace for melting a solid reduced metal such as solid reduced iron to produce a molten metal such as molten iron. A melting furnace that can be controlled simultaneously and a method for producing a molten metal using the same.
[0011] 前記目的を達成するため、本発明に係る溶解炉では、溶解炉本体の本体部におけ るスラグを排出するための排出口より高い位置にバッチ式排滓口が設けられ、このバ ツチ式排滓ロを開閉した際における本体部内の圧力の変化量または本体部力 排 出される排ガスの温度の変化量の少なくとも一方が検知されるようになっている。 In order to achieve the above object, in the melting furnace according to the present invention, a batch type discharge port is provided at a position higher than the discharge port for discharging the slag in the main body of the melting furnace body. At least one of the amount of change in the pressure in the main body and the amount of change in the temperature of the exhaust gas exhausted by opening and closing the push-type exhaust pipe is detected.
[0012] この構成によれば、ノ ツチ式排滓ロを開閉した際に検知した本体部内の圧力の変 化量または排ガスの温度の変化量に基づいて炉内のスラグレベルを容易かつ確実 に把握することができるとともに制御することができる。この結果、溶解炉力ものスラグ の噴出や水蒸気爆発などの重大事故を確実に防止しつつ、固体還元金属を溶解し て溶融金属を製造することが実現できる。 [0012] According to this configuration, the change in the pressure in the main body detected when the notch type exhaust valve is opened and closed. The slag level in the furnace can be easily and reliably grasped and controlled based on the amount of gasification or the temperature change of the exhaust gas. As a result, it is possible to manufacture molten metal by melting solid reduced metal while reliably preventing serious accidents such as slag jetting and steam explosions with melting furnace power.
図面の簡単な説明 Brief Description of Drawings
[0013] [図 1]図 1は、本発明の実施形態に係る溶解炉を示す正断面図である。 FIG. 1 is a front sectional view showing a melting furnace according to an embodiment of the present invention.
[図 2]図 2は、本発明の実施形態に係る溶解炉を示す平面図である。 FIG. 2 is a plan view showing a melting furnace according to an embodiment of the present invention.
[図 3] (a)は連続式排滓口、(b)は連続式溶鉄排出口をそれぞれ示す断面図である。 [FIG. 3] (a) is a sectional view showing a continuous discharge port, and (b) is a cross-sectional view showing a continuous molten iron discharge port.
[図 4]図 4は、本体部内の圧力の変化量を検知してスラグレベルを制御する方法を説 明するフロー図である。 [FIG. 4] FIG. 4 is a flow diagram illustrating a method of controlling the slag level by detecting the amount of pressure change in the main body.
[図 5]図 5は、本発明の実施形態の変形例である、 IDファンのダンバ開度変化量検知 によるスラグレベル制御方法を説明するフロー図である。 FIG. 5 is a flowchart for explaining a slag level control method based on detection of an ID fan damper opening change amount, which is a modification of the embodiment of the present invention.
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
[0014] 以下、本発明の実施形態を示す図面を参照しつつ、本発明をより詳細に説明する 。なお、固体還元金属として固体還元鉄を用い、溶融金属として溶鉄を製造する場 合を代表例に選び、溶解炉力 の溶鉄とスラグの取出しは連続的に行う場合につい て説明を行う。まず、溶解炉の構成について説明する。 Hereinafter, the present invention will be described in more detail with reference to the drawings illustrating embodiments of the present invention. The case where solid reduced iron is used as the solid reduced metal and molten iron is produced as the molten metal is selected as a representative example, and the case where the molten iron and slag are continuously taken out will be explained. First, the structure of the melting furnace will be described.
[0015] 〔溶解炉の構成〕 [Configuration of melting furnace]
図 1は本発明の実施形態に係る溶解炉を示す正断面図、図 2は同平面図、図 3 (a) は連続式排滓口を示す断面図、図 3 (b)は連続式溶鉄排出口を示す断面図である。 1 is a front sectional view showing a melting furnace according to an embodiment of the present invention, FIG. 2 is a plan view thereof, FIG. 3 (a) is a sectional view showing a continuous discharge port, and FIG. 3 (b) is continuous molten iron. It is sectional drawing which shows a discharge port.
[0016] 図 1に示すように、前記溶解炉は、内部で固体還元鉄を溶解させて溶鉄 Mおよびス ラグ Sを含む溶湯を得るための本体部 laと、この本体部 laの下部の外側に設けられ た溶湯溜まり部 lbとを有する溶解炉本体 1を備えている。 [0016] As shown in Fig. 1, the melting furnace includes a main body la for melting solid reduced iron therein to obtain a molten metal containing molten iron M and slag S, and an outer side of a lower portion of the main body la. A melting furnace main body 1 having a molten metal reservoir portion lb provided in.
[0017] 前記本体部(以下、単に「炉」ともいい、例えば「炉内」は「溶解炉本体の本体部内」 を意味する。 ) laの天井部には、固体還元鉄 R、炭材、造滓剤等からなる原燃料を本 体部 la内に投入するための原料投入口 2と、固体還元鉄 Rを溶解する熱源としてス ラグ中の炭材および Zまたは溶鉄中の炭素を燃焼するとともに炉内発生ガスを二次 燃焼させるための酸素吹き込みランス 3と、二次燃焼後の排ガスを本体部 laから排 出する排ガスダクト 4が設けられて 、る。 [0017] The main body (hereinafter also referred to simply as "furnace", for example, "inside the furnace" means "inside the main body of the melting furnace body".) The la ceiling has solid reduced iron R, carbonaceous material, Raw material input 2 for supplying raw fuel made of ironmaking agent or the like into the main body la and charcoal material in slag and carbon in Z or molten iron as a heat source for melting solid reduced iron R At the same time, an oxygen blowing lance 3 for secondary combustion of the gas generated in the furnace and exhaust gas after secondary combustion from the main body la An exhaust gas duct 4 is provided.
[0018] 前記溶湯溜まり部 lbは、本体部 laの内部とサイフォン 5で連通する内部空間を有 しており、この溶湯溜まり部 lbには、スラグ Sを連続的に排出するための連続式排滓 口(本発明の排出口に相当) 7と、溶鉄 Mを連続的に排出するための連続式溶鉄排 出口(連続式溶融金属排出口) 8が設けられて 、る。連続式排滓口 7および連続式溶 鉄排出口 8は図 2において上下方向に延びる溝状をなしており、この連続式排滓口 7 および連続式溶鉄排出口 8によって溶湯溜まり部 lbの内部空間が上方および水平 方向に開放されている。なお、回収された溶鉄 M中にスラグ Sができるだけ混入しな いように、連続式排滓ロ 7を連続式溶鉄排出口 8より上流側(すなわち、本体部 laに 近 ヽ側)に設けるとともに(図 2参照)、その高さ位置 (すなわち、連続式排滓口 7の最 下点の位置) HAを連続式溶鉄排出口 8の高さ位置 (すなわち、連続式溶鉄排出口 8 の最下点の位置) HBより高くしておくとよい(図 3参照)。 [0018] The molten metal reservoir lb has an internal space communicating with the inside of the main body la through the siphon 5, and the molten metal reservoir lb has a continuous exhaust for continuously discharging slag S. There are provided an outlet (corresponding to the outlet of the present invention) 7 and a continuous molten iron outlet (continuous molten metal outlet) 8 for continuously discharging molten iron M. The continuous discharge port 7 and the continuous molten iron discharge port 8 have a groove shape extending in the vertical direction in FIG. 2, and the continuous discharge port 7 and the continuous molten iron discharge port 8 form the inside of the molten metal reservoir lb. The space is open upward and horizontally. In addition, in order to prevent the slag S from entering the recovered molten iron M as much as possible, the continuous waste pipe 7 is provided upstream of the continuous molten iron outlet 8 (that is, the side closer to the main body la). (See Fig. 2), its height position (ie, the lowest point position of the continuous discharge port 7) HA is the height position of the continuous molten iron discharge port 8 (ie, the lowest point of the continuous molten iron discharge port 8) (Point position) It should be higher than HB (see Fig. 3).
[0019] さらに、本体部 laの側壁には上記連続式排滓ロ 7とは別に開閉可能に構成された ノツチ式排滓ロ 9が設けられている。ノツチ式排滓ロ 9の高さ位置 (すなわち、ノツチ 式排滓ロ 9における本体部 laの側壁を貫通する部分の最下点の位置) HCが連続 式排滓口 7の高さ位置 HAよりも高くなつて 、る。バッチ式排滓口 9の開閉機構として は、例えばスライドゲート方式を採用すればょ 、。 [0019] Further, a notch type exhaust rod 9 configured to be openable and closable separately from the continuous exhaust rod 7 is provided on the side wall of the main body la. The height position of the Notch type exhaust rod 9 (that is, the position of the lowest point of the portion of the Notch type exhaust rod 9 that penetrates the side wall of the main body la) HC is from the height position HA of the continuous exhaust port 7 It ’s too expensive. For example, if a slide gate system is used as the open / close mechanism of the batch type outlet 9,
[0020] さらに、溶解炉本体 1には、ノ ツチ式排滓ロ 9を開閉した際における本体部 la内の 圧力(以下、単に「炉内圧」ともいう。)の変化量を検知するための圧力計 11が設けら れ、排ガスダクト 4にはバッチ式排滓口 9を開閉した際における排ガスの温度の変化 量を検知するための温度計 12が設けられている。なお、上記圧力の変化量を検知 するための圧力計 11は、溶解炉本体 1の他、溶解炉本体 1からの排ガスを処理する 排ガス処理設備 (排ガスダクトを含む)内に設けてもよ ヽ。 [0020] Further, the melting furnace body 1 is for detecting the amount of change in the pressure in the main body la (hereinafter, also simply referred to as "furnace pressure") when the notch type exhaust rod 9 is opened and closed. A pressure gauge 11 is provided, and the exhaust gas duct 4 is provided with a thermometer 12 for detecting the amount of change in exhaust gas temperature when the batch type exhaust port 9 is opened and closed. The pressure gauge 11 for detecting the amount of change in pressure may be provided in the exhaust gas treatment facility (including the exhaust gas duct) for treating the exhaust gas from the melting furnace body 1 in addition to the melting furnace body 1. .
[0021] サイフォン 5は、図 1に示すように、例えば溶解炉本体 1の底部と、溶解炉本体 1の 天井部から垂下された仕切り壁 10との間の隙間で構成するとよい。また、サイフォン 5 は溶湯溜まり部 lb内に設けてもよい。そして、この仕切り壁 10は昇降可能としておき 、溶湯 (スラグ +溶鉄)中への仕切り壁 10の浸漬深さを調整することで、サイフォン 5 の上端高さ位置 HDを調整できるようにしておくのが好ましい。 [0022] 溶解炉本体 1の本体部 la内には、固体還元鉄 R等からなる原料が溶解されてスラ グと溶鉄に分離され、溶鉄層 M上にスラグ層 Sが形成されて!ヽる。 As shown in FIG. 1, for example, the siphon 5 may be configured by a gap between the bottom of the melting furnace body 1 and the partition wall 10 suspended from the ceiling of the melting furnace body 1. The siphon 5 may be provided in the molten metal reservoir lb. The partition wall 10 can be moved up and down, and the upper end height position HD of the siphon 5 can be adjusted by adjusting the immersion depth of the partition wall 10 in the molten metal (slag + molten iron). Is preferred. [0022] In the main body la of the melting furnace body 1, a raw material made of solid reduced iron R or the like is dissolved and separated into slag and molten iron, and a slag layer S is formed on the molten iron layer M! .
[0023] 原料投入口 2から投入された原料は、スラグ層 S中に潜り込み、酸素吹き込みランス 3により吹き込まれた酸素あるいは酸素富化空気による炭材ゃ炉内発生ガス等の燃 焼熱で溶解される。溶解された原料は、スラグと溶鉄に分離され、上記スラグ層 Sおよ び溶鉄層 M中にそれぞれ移行し、本体部 la内の溶鉄レベル MLおよびスラグレベル SLがともに上昇する。この結果、本体部 la内外に液圧差が生じスラグおよび溶鉄の 増加分がサイフォン 5を通過して溶湯溜まり部 lbに移動し、連続式排滓口 7および連 続式溶鉄排出口 8からそれぞれ連続的に排出される。 [0023] The raw material charged from the raw material inlet 2 is submerged in the slag layer S and dissolved by the combustion heat of the gas generated in the carbonaceous material furnace by the oxygen blown by the oxygen blowing lance 3 or oxygen-enriched air. Is done. The melted raw material is separated into slag and molten iron and moves into the slag layer S and the molten iron layer M, respectively, and both the molten iron level ML and the slag level SL in the main body la rise. As a result, a hydraulic pressure difference occurs between the inside and outside of the main body la, and the increased amount of slag and molten iron passes through the siphon 5 and moves to the molten metal reservoir lb, and continuously from the continuous discharge port 7 and the continuous molten iron discharge port 8 respectively. Are exhausted.
[0024] なお、サイフォン 5の上端高さ位置 HDは、本体部 la内の排ガスが炉外に噴出した り、あるいは外気が本体部 la内に漏れこんだりしないように、本体部 la内のスラダレ ベル SLより低くしておぐすなわち仕切り壁 10を少なくとも溶湯中に浸漬しておく必 要がある。し力しながら、サイフォン 5の上端高さ位置 HDを溶鉄レベル MLより低くす ると、すなわち仕切り壁 10を溶鉄層 M中まで浸漬すると、本体部 la内のスラグ Sがサ ィフォン 5を通過できなくなり、スラグ Sが本体部 la内から排出できなくなるので、サイ フォン 5の上端高さ位置はスラグ層 Sの範囲、すなわち仕切り壁 10はスラグ層 S中に 浸漬した状態に留めておく必要がある。 [0024] It should be noted that the upper end height position HD of the siphon 5 is set so that the exhaust gas in the main body la does not blow out of the furnace or the outside air does not leak into the main body la. It is necessary to keep the partition wall 10 lower than the bell SL, that is, to immerse the partition wall 10 in at least the molten metal. However, when the upper end height position HD of the siphon 5 is made lower than the molten iron level ML, that is, when the partition wall 10 is immersed into the molten iron layer M, the slag S in the main body la can pass through the siphon 5. Since the slag S cannot be discharged from the inside of the main body la, the upper end height position of the siphon 5 must be in the range of the slag layer S, that is, the partition wall 10 should be kept immersed in the slag layer S. .
[0025] 溶解炉本体 1の本体部 la内でのスラグおよび溶鉄の生成速度と溶湯溜まり部 lbか らのこれらの排出速度がバランスして!/、る場合は、上記のようにしてスラグレベル SL が一定に維持され、連続的な溶鉄の製造ができることとなる。 [0025] If the generation rate of slag and molten iron in the main body la of the melting furnace main body 1 and the discharge rate from the molten metal reservoir lb are balanced! SL is kept constant, and continuous molten iron can be produced.
[0026] ところが、特に上記特許文献 1に記載の回転炉床炉 (還元炉)と溶解炉とを連結し て溶鉄を製造するプロセスのように、還元炉で得られた固体還元鉄の還元率や炭素 含有量など成分がばらついたり、還元炉カ の排出速度が変動して溶解炉本体 1の 本体部 laへの原燃料の投入量が変動したり、これら成分のバラツキや投入量の変動 等に起因して本体部 la内で非定常的な反応が起こったりしゃすい場合は、本体部 1 a内でのスラグおよび溶鉄の生成速度と溶湯溜まり部 lbからのこれらの排出速度の バランスが崩れて、本体部 la内のスラグレベル SLが大きく変動する場合がある。しか しながら、本体部 la内では、酸素吹き込み中には高温かつ溶融ダストが多量に発生 するため、スラグレベル SLを常時監視することは実際上不可能である。また、スラグ レベル SLを計測するために酸素等の吹き込みを中断して、サブランスを炉内に装入 する手段を用いることも考えられるが、設備コストが上昇するうえ、操業中断により生 産性が低下する問題があり、事実上採用できない。 [0026] However, the reduction rate of solid reduced iron obtained in the reduction furnace, particularly in the process of manufacturing molten iron by connecting the rotary hearth furnace (reduction furnace) and melting furnace described in Patent Document 1 above. The components such as the carbon content and the carbon content vary, the discharge rate of the reduction furnace fluctuates, the amount of raw fuel input to the main body la of the melting furnace body 1 fluctuates, the variation of these components, the fluctuation of the input amount, etc. If an unsteady reaction occurs in the main body la due to the occurrence of a slag, the balance between the generation rate of slag and molten iron in the main body 1a and the discharge rate from the molten metal reservoir lb is lost. Thus, the slag level SL in the main body la may vary greatly. However, a large amount of high-temperature and molten dust is generated in the main body la during oxygen blowing. Therefore, it is practically impossible to constantly monitor the slag level SL. In order to measure the slag level SL, it may be possible to use a means of interrupting the injection of oxygen or the like and charging the sub lance into the furnace, but this increases the equipment cost and increases the productivity due to the interruption of operation. There is a problem of decline, and practically it cannot be adopted.
[0027] そこで、以下、上記構成力もなる溶解炉を用いて、まず、操業を停止することなぐ 本体部 la内のスラグレベル SLを把握する方法について説明する。 [0027] In view of this, a method for grasping the slag level SL in the main body la without using the melting furnace having the above-described constituent power without stopping the operation will be described below.
[0028] 〔スラグレベルの把握方法〕 [0028] [Method of grasping slag level]
ノツチ式排滓ロ 9を定期的に開閉し、その際における本体部 la内の圧力の変化量 および Zまたは排ガスの温度の変化量を検知することにより本体部 la内のスラダレ ベル SLを把握することができる。 Open and close the notch type exhaust rod 9 periodically, and detect the amount of pressure change in the main body la and the change in temperature of Z or exhaust gas at that time, and grasp the ladder level SL in the main body la be able to.
[0029] まず、本体部 la内の圧力の変化量の検知によりスラグレベル SLを把握する方法に ついて詳述する。 [0029] First, a method for grasping the slag level SL by detecting the amount of change in pressure in the main body la will be described in detail.
[0030] すなわち、バッチ式排滓口 9を閉止状態から一定時間 (例えば 5s)開放状態にする と、本体部 la内のスラグレベル SLがノツチ式排滓ロ 9より下方にあるときは、溶解炉 が正圧で操業されている場合は炉内からガスが急速に噴き出し、一方溶解炉が負圧 で操業されている場合は炉外から大気が急速に侵入して、いずれの場合も本体部 1 a内の圧力が大きく変化する (正圧操業では圧力が低下、負圧操業では圧力は増加 •上昇する)。 [0030] That is, when the batch type discharge port 9 is opened from the closed state for a certain time (for example, 5 seconds), if the slag level SL in the main body la is below the notch type discharge port 9, When the furnace is operated at a positive pressure, gas is rapidly ejected from the inside of the furnace, while when the melting furnace is operated at a negative pressure, the atmosphere rapidly enters from the outside of the furnace. 1 The pressure in a changes greatly (pressure decreases in positive pressure operation, and pressure increases / increases in negative pressure operation).
[0031] 他方、本体部 la内のスラグレベル SLがバッチ式排滓ロ 9より上方にあるときは、ノ ツチ式排滓口 9の炉内側前面にスラグが存在するため、溶解炉が正圧で操業されて いる場合は炉内力もまずスラグが流出し、ガス力 ^、きなり噴き出すことがなぐ一方溶 解炉が負圧で操業されている場合は炉内側前面のスラグに邪魔されて大気の侵入 量が少なぐ V、ずれの場合も本体部 la内の圧力の低下の度合 、は小さ 、。 [0031] On the other hand, when the slag level SL in the main body la is higher than the batch type exhaust port 9, the slag exists at the front side of the notch type exhaust port 9 inside the furnace, so that the melting furnace has a positive pressure. If the furnace is being operated in the furnace, the slag will also flow out of the furnace first, and the gas power ^, will not be blown out suddenly. The amount of intrusion is small V, and the degree of pressure drop in the main body la is small even when there is a slippage.
[0032] したがって、バッチ式排滓口 9を一定時間開放状態にすることで、その際における 本体部 la内の圧力の変化の度合い(変化量)が大きい場合にはスラグレベル SLが バッチ式排滓口 9より下方に存在し、本体部 1 a内の圧力の変化の度合!/ヽ(変化量) 力 S小さ 、場合にはスラグレベル SLがバッチ式排滓口 9より上方に存在することがわか る。 [0033] なお、本体部 la内の圧力の変化量は溶解炉本体 1 (または排出ガス処理設備内) に設置した圧力計 11を用いて測定することができる。 [0032] Therefore, by leaving the batch type discharge port 9 open for a certain period of time, if the degree of change (change amount) in the main body la at that time is large, the slag level SL is set to the batch type discharge port. The degree of pressure change in the main body 1a! / ヽ (change amount) Force S is small, and in this case, the slag level SL should be above the batch type outlet 9 I understand. [0033] It should be noted that the amount of change in the pressure in the main body la can be measured using a pressure gauge 11 installed in the melting furnace main body 1 (or in the exhaust gas treatment facility).
[0034] つぎに、排ガスの温度の変化量によりスラグレベル SLを把握する方法について詳 述する。 [0034] Next, a method for grasping the slag level SL from the amount of change in the temperature of the exhaust gas will be described in detail.
[0035] すなわち、バッチ式排滓口 9を閉止状態から一定時間 (例えば 5s)開放状態にする と、本体部 la内のスラグレベル SLがノツチ式排滓ロ 9より下方にあるときは、溶解炉 が正圧で操業されている場合は炉内力ゝら高温ガスが急速に噴き出し、一方溶解炉が 負圧で操業されて 、る場合は炉外力 冷た 、大気が急速に侵入して、 V、ずれの場 合も排ガスの温度が大きく低下する。 [0035] That is, when the batch type discharge port 9 is opened from the closed state for a certain time (for example, 5 seconds), if the slag level SL in the main body la is below the notch type discharge port 9, When the furnace is operated at a positive pressure, high-temperature gas is rapidly ejected from the power inside the furnace, while when the melting furnace is operated at a negative pressure, the external power is cooled, the atmosphere rapidly enters, V, Even in the case of deviation, the temperature of the exhaust gas greatly decreases.
[0036] 他方、本体部 la内のスラグレベル SLがバッチ式排滓ロ 9より上方にあるときは、バ ツチ式排滓口 9の炉内側前面にスラグが存在するため、溶解炉が正圧で操業されて いる場合は炉内力もまずスラグが流出し、高温ガス力 ^、きなり噴き出すことがなぐ一 方溶解炉が負圧で操業されている場合は炉内側前面のスラグに邪魔されて冷たい 大気の侵入量が少なく、 、ずれの場合も排ガスの温度の低下の度合 、は小さ 、。 [0036] On the other hand, when the slag level SL in the main body la is above the batch-type exhaust port 9, the slag exists on the front surface inside the furnace of the batch-type exhaust port 9, so the melting furnace is at a positive pressure. If the furnace is operated at low pressure, the slag will also flow out first, causing high-temperature gas power ^, while it will not blow out suddenly. The amount of intrusion into the atmosphere is small, and the degree of decrease in exhaust gas temperature is small even in the case of deviation.
[0037] したがって、バッチ式排滓口 9を一定時間開放状態にすることで、その際における 排ガスの温度の変化の度合 ヽ(変化量)が大き 、場合にはスラグレベル SLがバッチ 式排滓口 9より下方に存在し、排ガスの温度の変化の度合!/ヽ (変化量)が小さ!、場合 にはスラグレベル SLがバッチ式排滓口 9より上方に存在することがわかる。 [0037] Therefore, by leaving the batch type exhaust port 9 open for a certain period of time, the degree of change in the temperature of the exhaust gas at that time (the amount of change) is large. In this case, the slag level SL is set to the batch type exhaust port. It exists below port 9 and the degree of change in exhaust gas temperature! / ヽ (change) is small! In this case, it can be seen that the slag level SL exists above the batch type outlet 9.
[0038] なお、排ガスの温度の変化量は排ガスダクト 4に設置した温度計 12を用いて測定 することができる。 [0038] The amount of change in the temperature of the exhaust gas can be measured using a thermometer 12 installed in the exhaust gas duct 4.
[0039] そして、このようなバッチ式排滓口 9の開閉操作を定期的(例えば 5min間隔)に行 い、本体部 la内の圧力および Zまたは排ガスの温度の変化の度合い(変化量)を検 知することにより、スラグレベル SLがバッチ式排滓ロ 9の高さ位置を超えた力否かを 常に把握しておくことが可能となり、スラグレベル SLの異常上昇を迅速かつ的確に検 知でき、重大事故を未然に防止できる。 [0039] Then, the batch type exhaust port 9 is opened and closed periodically (for example, at intervals of 5 min), and the degree of change (change amount) in the pressure in the main body la and the temperature of Z or exhaust gas is changed. By detecting it, it is possible to always know whether or not the slag level SL has exceeded the height position of the batch type slag 9 and quickly and accurately detect abnormal increases in the slag level SL. And can prevent serious accidents.
[0040] 〔バッチ式排滓口開閉時における本体部内の圧力の変化量の検知によるスラダレ ベルの制御方法〕 [0040] [Sladder level control method by detecting the amount of pressure change in the main body when the batch type exhaust port is opened and closed]
上記のようにしてスラグレベル SLを把握することで、重大事故を未然に回避できる ものであるが、スラグレベル SLを把握するだけに留まらず、より積極的にスラグレベル を一定レベルに維持するように制御する方法につ!、て詳述する。 By grasping the slag level SL as described above, serious accidents can be avoided in advance. However, we will not only grasp the slag level SL, but also explain in detail how to control the slag level to maintain it at a constant level.
[0041] 以下、溶解炉が負圧で操業されている場合について本体部 la内の圧力の変化量 の検知を用いる方法を代表例に挙げ、図 4にしたがって説明する。 [0041] Hereinafter, a method using detection of the amount of change in the pressure in the main body la when the melting furnace is operated at a negative pressure will be described as a representative example and described with reference to FIG.
[0042] 図 4に示すように、スラグレベル SLの制御を開始するため、炉内圧自動制御を解除 [0042] As shown in Fig. 4, in order to start control of slag level SL, automatic control of furnace pressure is released.
(OFF)するとともに、排ガスを吸引する IDファンのダンバ開度を固定する(S1参照) 。これにより、ノツチ式排滓ロ 9の開閉による本体部 la内の圧力の変化量を感度良く 検知できることとなる。 (OFF) and fix the damper opening of the ID fan that sucks exhaust gas (see S1). As a result, the amount of change in the pressure in the main body la due to the opening and closing of the notch type exhaust rod 9 can be detected with high sensitivity.
[0043] そして、バッチ式排滓ロ 9を所定時間(例えば 5s)開放する(S2参照)。この際にお ける本体部 la内の圧力の変化量 Δ Pと予め定めた設定値 Δ Psとを比較する(S3参 照)。 [0043] Then, the batch type discharge rod 9 is opened for a predetermined time (for example, 5 seconds) (see S2). At this time, the pressure change amount ΔP in the main body la is compared with a predetermined set value ΔPs (see S3).
[0044] そして、 Δ Ρく A Psの場合 (すなわち、バッチ式排滓ロ 9の開放前後で本体部 la 内の圧力がほぼ同じ場合)は、スラグレベル SLがバッチ式排滓ロ 9より高くなつてい ると判定される(S4参照)ので、バッチ式排滓口 9を引き続き所定時間 (例えば 5s)開 放したままにし、このバッチ式排滓ロ 9から一定量スラグを排出し、スラグレベルを低 下させる(S2参照)。そして、再度 Δ Ρと A Psとを比較し、 Δ Ρ≥ A Psとなるまで (すな わち、スラグレベル SLがバッチ式排滓ロ 9より低くなるまで)このループ(S2→S3→S 4→S2)を繰り返す。 [0044] And, in the case of Δ Ρ APS (that is, when the pressure in the main body la is almost the same before and after the batch type exhaust 9 is opened), the slag level SL is higher than the batch type exhaust 9 Since the batch type outlet 9 is kept open for a predetermined time (for example, 5 seconds), a certain amount of slag is discharged from the batch type outlet 9 and the slag level is determined. (See S2). Then, Δ Ρ and A Ps are compared again, and this loop (S2 → S3 → S) until Δ Ρ≥ A Ps (that is, until the slag level SL becomes lower than the batch-type discharge rod 9). Repeat 4 → S2).
[0045] 一方、 Δ Ρ≥Δ Ρ3の場合 (すなわち、バッチ式排滓ロ 9の開放により本体部 la内の 圧力が大きく変化する場合)は、スラグレベル SLがバッチ式排滓ロ 9より低くなつてい ると判定される(S5参照)ので、バッチ式排滓ロ 9を閉止し (S6参照)、炉内圧自動制 御に復帰 (ON)させるとともに、 IDファンのダンバ開度を自動制御に戻す (S7参照) 。これにより溶解炉は通常操業に戻り、スラグレベル SLが維持ないし上昇する。そし て、所定時間(例えば 5min)経過後(S8参照)、再度 S1に戻って同様の制御フロー が繰り返され、スラグレベル SLがバッチ式排滓口 9より低 、位置に維持されることとな る。 [0045] On the other hand, in the case of Δ Ρ≥Δ Ρ3 (that is, when the pressure in the main body la largely changes due to the opening of the batch type exhaust 9), the slag level SL is lower than the batch type exhaust 9 Since it is determined that the operation is successful (refer to S5), the batch type exhaust 9 is closed (refer to S6), and the internal pressure control is returned to ON (ON) and the damper opening of the ID fan is automatically controlled. Return (see S7). As a result, the melting furnace returns to normal operation and the slag level SL is maintained or raised. Then, after a predetermined time (for example, 5 min) has elapsed (see S8), the process returns to S1 again and the same control flow is repeated, and the slag level SL is maintained at a position lower than the batch type exhaust port 9. The
[0046] なお、設定値 A Psは、例えば以下のようにして定めればよい。すなわち、過去の操 業にお 、て、バッチ式排滓口 9を開放したときの Δ Pと、バッチ式排滓口 9からのスラ グの流出の有無と^^計し、バッチ式排滓口 9からのスラグの流出が発生しな ヽ Δ P の上限値を Δ Psとすればよ!、。 Note that the set value A Ps may be determined as follows, for example. That is, in the past operation, ΔP when the batch type outlet 9 was opened and the slurry from the batch type outlet 9 If there is no slag outflow from the batch outlet 9, set the upper limit of Δ P to Δ Ps!
[0047] 〔昇降式の仕切り壁を用いたスラグレベルの維持方法〕 [Method of maintaining slag level using elevating partition wall]
通常は、上述したような方法にてスラグレベル SLを維持できる力 スラグレベル SL が過度に上昇ないし下降した場合には、より迅速にスラグレベルを適正な位置に戻 す必要がある。 Normally, the force that can maintain the slag level SL as described above If the slag level SL rises or falls excessively, it is necessary to return the slag level to the proper position more quickly.
[0048] このような場合には、昇降可能に構成された仕切り壁 10を利用するのがよい。 [0048] In such a case, it is preferable to use the partition wall 10 configured to be able to move up and down.
[0049] すなわち、スラグレベル SLが過度に上昇したときは、仕切り壁 10を上昇させて、ス ラグ層 S中への浸漬深さを浅くし、サイフォン 5の開口面積を大きくすることにより、本 体部 la内からのスラグの排出速度を大きくすることができる。 That is, when the slag level SL rises excessively, the partition wall 10 is raised, the immersion depth in the slag layer S is decreased, and the opening area of the siphon 5 is increased. The discharge rate of slag from the body la can be increased.
[0050] 他方、スラグレベル SLが過度に下降したときは、仕切り壁 10を下降させて、スラグ 層 S中への浸漬深さを深くし、サイフォン 5の開口面積を小さくすることにより、本体部 la内からのスラグの排出速度を小さくすることができる。あるいは仕切り壁 10を溶鉄 層 M中まで浸漬して、本体部 la内のスラグをサイフォン 5から流出させないようにする ことちでさる。 [0050] On the other hand, when the slag level SL is excessively lowered, the partition wall 10 is lowered, the immersion depth in the slag layer S is increased, and the opening area of the siphon 5 is reduced. The discharge rate of slag from within la can be reduced. Alternatively, the partition wall 10 is immersed in the molten iron layer M to prevent the slag in the main body la from flowing out of the siphon 5.
[0051] 上記仕切り壁 10の昇降操作のみでは、開口面積を操作することはできるがスラダレ ベルは制御できな 、。仕切り壁 10は長期間スラグ中に浸漬して 、ると侵食されてそ の浸漬深さが変化してしまい精度に劣るため、通常は上述したようにバッチ式排滓ロ 9の開閉操作を行!、、継続してスラグレベルが高 、もしくは低 、場合のみ上記仕切り 壁 10の昇降操作を行うようにするのが望ま 、。 [0051] The opening area can be manipulated only by the raising / lowering operation of the partition wall 10, but the slurry level cannot be controlled. If the partition wall 10 is immersed in the slag for a long period of time, it will be eroded and the immersion depth will change, resulting in poor accuracy. ! It is desirable that the partition wall 10 is moved up and down only when the slag level is continuously high or low.
[0052] 〔変形例〕 [Modification]
上記実施形態では、溶解炉本体 1の本体部 laからの溶鉄とスラグの取出しを、サイ フォン 5と連続式排滓口 7と連続式溶鉄排出口 8との組合せにて連続的に行う場合の 適用例を示したが、本発明は、溶解炉本体の本体部力ゝらの溶鉄とスラグの取出しを、 高炉と同様のタップホールにて間欠的に行う場合にも当然に適用できる。すなわち、 上記実施形態では、本体部 laからスラグを排出するための排出口を連続式排滓口 7 で構成しているが、前記排出口をタップホールで構成してもよい。この場合には、バッ チ式排滓口をタップホールより高 、位置に設ければょ 、。 [0053] また、上記実施形態では、本体部 la内の圧力の変化量を検知するための圧力計 1 1と排ガスの温度の変化量を検知するための温度計 12の両方を設置する例を示した 力 本体部 la内の圧力の変化量あるいは排ガスの温度の変化量の一方のみを用い てスラグレベルの維持を図る場合は、必ずしも両方設置する必要はなぐ一方のみ設 置すればよい。 In the above embodiment, when the molten iron and slag are continuously taken out from the main body la of the melting furnace main body 1 by the combination of the siphon 5, the continuous discharge port 7, and the continuous molten iron discharge port 8, Although an application example has been shown, the present invention can naturally be applied to the case where the molten iron and the slag taken out from the main body of the melting furnace body are intermittently taken out by a tap hole similar to the blast furnace. That is, in the said embodiment, although the discharge port for discharging | emitting slag from the main-body part la is comprised by the continuous type discharge port 7, you may comprise the said discharge port by a tap hole. In this case, the batch type outlet should be located higher than the tap hole. [0053] In the above embodiment, an example in which both the pressure gauge 11 for detecting the amount of change in pressure in the main body la and the thermometer 12 for detecting the amount of change in exhaust gas temperature are installed. The indicated force When maintaining the slag level using only one of the amount of change in pressure in the main body la or the amount of change in exhaust gas temperature, it is not necessary to install both.
[0054] 例えば、温度計 12のみを設置する場合には、図 4に示すフローチャートにおいて、 S3のステップで排ガスの温度の変化量 Δ Tと予め定めた設定値 Δ Tsとを比較する。 そして、 ΔΤ≥ ATsであることを条件に、すなわち、ノ ツチ式排滓ロ 9の開放により排 ガス温度が大きく変化する場合に、バッチ式排滓口 9を閉止して (S6参照)スラダレ ベル SLを維持な 、し上昇させるようにすればょ 、。 For example, when only the thermometer 12 is installed, in the flowchart shown in FIG. 4, the change amount ΔT of the exhaust gas temperature is compared with a predetermined set value ΔTs in step S3. Then, on condition that Δ AT≥ATs, that is, when the exhaust gas temperature changes greatly due to the opening of the notch type exhaust 9, the batch type exhaust 9 is closed (see S6) Don't maintain SL and raise it.
[0055] また、上記実施形態では、仕切り壁 10は昇降可能としたが、〔昇降式の仕切り壁を 用いたスラグレベルの維持方法〕の欄で説明したような昇降式の仕切り壁 10でスラグ レベルの維持を図る必要のな 、場合は、固定式としてもよ 、。 [0055] In the above embodiment, the partition wall 10 can be raised and lowered. However, the slag can be moved by the elevating partition wall 10 as described in the section of [Method of maintaining the slag level using the elevating partition wall]. If it is necessary to maintain the level, it can be fixed.
[0056] また、上記実施形態では、サイフォン 5および溶湯溜まり部 lbは 1つずつ設置し、こ の 1つの溶湯溜まり部に連続式排滓口と連続式溶鉄排出口の両方を設けた例を示し たが、サイフォンを 2つ設け、一方にはスラグ溜まり部、他方には溶鉄溜まり部を連通 し、前者に連続式排滓ロを、後者に連続式溶鉄排出口を設けるようにしてもよい。 [0056] In the above embodiment, one siphon 5 and one molten metal reservoir lb are installed one by one, and both the continuous discharge port and the continuous molten iron discharge port are provided in this one molten metal reservoir. As shown, two siphons may be provided, one with a slag reservoir, the other with a molten iron reservoir, and the former with a continuous drain and the latter with a molten iron outlet. .
[0057] また、上記実施形態では、原料を溶解するための熱源供給手段として、酸素吹き込 みランス 3を例示したが、電極を用いてもよい。 In the above embodiment, the oxygen blowing lance 3 is exemplified as the heat source supply means for dissolving the raw material, but an electrode may be used.
[0058] また、上記実施形態では、固体還元金属として固体還元鉄を、溶融金属として溶鉄 を例示したが、固体還元金属および溶融金属に含まれる金属元素としては、 Feの他 、 Mn、 Ni、 Cr、 Mo、 Ti等の非鉄金属を含有するものでもよい。 [0058] In the above embodiment, solid reduced iron is exemplified as the solid reduced metal, and molten iron is exemplified as the molten metal, but as the metal element contained in the solid reduced metal and the molten metal, in addition to Fe, Mn, Ni, It may contain non-ferrous metals such as Cr, Mo and Ti.
[0059] また、上記実施形態では、炉内圧自動制御を解除し IDファンのダンバ開度を固定 して本体部 1 a内の圧力の変化量を検知する方法を例示したが、図 5に示すように、 炉内圧自動制御および IDファンのダンバ開度の自動制御を解除することなぐ本体 部 la内の圧力の変化量に代えてダンバ開度の変化量を検知するようにしてもよい。 [0059] In the above embodiment has illustrated a method of securing the Danba opening of release and ID fans furnace pressure automatic control for detecting the amount of change in the pressure within the main body 1 a, shown in FIG. 5 As described above, the change amount of the damper opening may be detected instead of the change amount of the pressure in the main body la without releasing the automatic control of the furnace pressure and the automatic control of the damper opening of the ID fan.
[0060] あるいは、本体部 la内の圧力の変化量を検知する方法にカ卩えて、排ガスの温度の 変化量を検知するようにしてもよい。このようにすれば、より正確にスラグレベルを把 握することができる。 [0060] Alternatively, the amount of change in the temperature of the exhaust gas may be detected based on a method for detecting the amount of change in the pressure in the main body la. In this way, the slag level can be determined more accurately. Can be gripped.
[0061] 〔まとめ〕 [0061] [Summary]
上述したように、本発明に係る溶融炉は、固体還元金属を溶解して溶融金属を製 造する溶解炉であって、内部で前記固体還元金属を溶解させて溶融金属およびスラ グを含む溶湯を得るための本体部、この本体部力 前記スラグを排出するための排 出口、および、前記本体部の側壁における前記排出口より高い位置に設けられ、開 閉可能に構成されたバッチ式排滓口を有する溶解炉本体と、前記バッチ式排滓口を 開閉した際における前記本体部内の圧力の変化量を検知するための圧力計、およ びバッチ式排滓口を開閉した際における前記本体部力も排出される排ガスの温度の 変化量を検知するための温度計のうちの少なくとも一方とを備えることを特徴とするも のである。 As described above, the melting furnace according to the present invention is a melting furnace that melts a solid reduced metal to produce a molten metal, and melts the solid reduced metal therein to contain a molten metal and slag. A main body part for obtaining the slag, a discharge outlet for discharging the slag, and a batch-type discharger provided at a position higher than the discharge port on the side wall of the main body part and configured to be openable and closable A melting furnace main body having a mouth, a pressure gauge for detecting a change in pressure in the main body when the batch type discharge port is opened and closed, and the main body when the batch type discharge port is opened and closed It is characterized by comprising at least one of thermometers for detecting the amount of change in the temperature of exhaust gas discharged from the component force.
[0062] また、前記溶解炉にぉ 、て、前記排出口は、前記本体部からサイフォンを介して前 記スラグを連続的に排出するための連続式排滓口で構成されており、前記溶解炉本 体は、前記本体部力 サイフォンを介して前記溶融金属を連続的に排出するための 連続式溶融金属排出口をさらに有するものである構成とすることができる。 [0062] Further, after the melting furnace, the discharge port is constituted by a continuous discharge port for continuously discharging the slag from the main body part through a siphon, The furnace main body may be configured to further include a continuous molten metal discharge port for continuously discharging the molten metal via the main body part force siphon.
[0063] または、前記溶解炉にぉ 、て、前記排出口は、前記本体部から前記スラグおよび 前記溶融金属を間欠的に排出するためのタップホールで構成されている構成とする ことちでさる。 [0063] Alternatively, after the melting furnace, the discharge port is configured by a tap hole for intermittently discharging the slag and the molten metal from the main body. .
[0064] さらには、前記サイフォンは、前記本体部の底部と、前記本体部の天井部から昇降 可能に垂下された仕切り壁との間の隙間で構成されている構成とすることもできる。 [0064] Further, the siphon may be configured by a gap between a bottom portion of the main body portion and a partition wall that is suspended from the ceiling portion of the main body portion so as to be lifted and lowered.
[0065] 一方、本発明に係る第 1の溶融金属製造方法は、前記溶解炉を用いて溶融金属を 製造する方法であって、前記バッチ式排滓ロを定期的に開閉し、その際における前 記本体部内の圧力の変化量または前記排ガスの温度の変化量を検知して、その検 知した変化量に基づいて前記本体部内のスラグレベルを把握し制御することを特徴 とするちのである。 [0065] On the other hand, a first molten metal production method according to the present invention is a method of producing a molten metal using the melting furnace, in which the batch type waste gas is periodically opened and closed. Detecting a change in pressure in the main body or a change in temperature of the exhaust gas, and grasping and controlling a slag level in the main body based on the detected change. .
[0066] また、本発明に係る第 2の溶融金属製造方法は、前記溶解炉を用いて溶融金属を 製造する方法であって、前記バッチ式排滓ロを定期的に開閉し、その際における前 記本体部内の圧力の変化量または前記排ガスの温度の変化量を検知し、その検知 した変化量が予め定めた設定値を下回ったときは、前記バッチ式排滓口を所定時間 開放して前記本体部からスラグを排出して当該本体部内のスラグレベルを低下させ る一方、検知した変化量が前記設定値以上のときは、前記バッチ式排滓ロを所定時 間閉止して前記本体部内のスラグレベルを維持な 、し上昇させることにより、前記本 体部内のスラグレベルを制御することを特徴とするものである。 [0066] Further, a second molten metal production method according to the present invention is a method of producing a molten metal using the melting furnace, in which the batch type waste gas is periodically opened and closed. Detect the amount of change in pressure in the main body or the amount of change in temperature of the exhaust gas. When the amount of change is less than a preset value, the batch type discharge port is opened for a predetermined time to discharge slag from the main body and lower the slag level in the main body. When the amount of change is equal to or greater than the set value, the slag level in the main body is controlled by closing the batch-type evacuation valve for a predetermined time and maintaining and increasing the slag level in the main body. It is characterized by this.
また、本発明に係る第 3の溶融金属製造方法は、前述したようにサイフォンを構成し た溶解炉を用いて溶融金属を製造する方法であって、前記バッチ式排滓口を定期 的に開閉し、その際における前記本体部内の圧力の変化量または前記排ガスの温 度の変化量を検知し、その検知した変化量が予め定めた設定値を下回ったときは、 前記バッチ式排滓口を所定時間開放して前記本体部力 スラグを排出して当該本体 部内のスラグレベルを低下させる一方、検知した変化量が前記設定値以上のときは 、前記バッチ式排滓口を所定時間閉止して前記本体部内のスラグレベルを維持な 、 し上昇させることにより、前記本体部内のスラグレベルを制御し、前記本体部内のスラ グレベルが過度に上昇または下降したときには、前記本体部内の溶湯中への前記仕 切り壁の浸漬深さを調節することにより、前記本体部内のスラグレベルを制御すること を特徴とするものである。 The third molten metal production method according to the present invention is a method of producing a molten metal using a melting furnace having a siphon as described above, and periodically opening and closing the batch type discharge port. At this time, the amount of change in pressure in the main body or the amount of change in temperature of the exhaust gas is detected, and when the detected amount of change falls below a predetermined set value, the batch type exhaust port is opened. The main body force slag is discharged for a predetermined time to discharge the slag level in the main body, and when the detected change is equal to or greater than the set value, the batch type outlet is closed for a predetermined time. The slag level in the main body is controlled by maintaining or increasing the slag level in the main body, and when the slag level in the main body is excessively increased or decreased, the slag level in the main body is increased into the molten metal in the main body. By adjusting the immersion depth of Kitsukamatsu cutting walls, it is characterized in that to control the slag level in the body portion.
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006054523A JP4110174B2 (en) | 2006-03-01 | 2006-03-01 | Melting furnace and molten metal manufacturing method using the same |
| JP2006-054523 | 2006-03-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2007099941A1 true WO2007099941A1 (en) | 2007-09-07 |
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ID=38459045
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2007/053619 Ceased WO2007099941A1 (en) | 2006-03-01 | 2007-02-27 | Melting furnace and process for producing molten metal therewith |
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| Country | Link |
|---|---|
| JP (1) | JP4110174B2 (en) |
| WO (1) | WO2007099941A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2822523C1 (en) * | 2023-07-28 | 2024-07-08 | Общество с ограниченной ответственностью "Инновационная Компания Интехпром" | Furnace for selective processing of solid household and industrial waste |
| WO2024196276A1 (en) * | 2023-03-20 | 2024-09-26 | Общество с ограниченной ответственностью "Инновационная Компания Интехпром" | Furnace for the selective treatment of solid domestic and industrial waste |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102017218649A1 (en) * | 2017-10-19 | 2019-04-25 | Sms Group Gmbh | Intermediate container for slag separation |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56127718A (en) * | 1980-03-11 | 1981-10-06 | Kawasaki Steel Corp | Slopping prediction method in converter |
| JPH10176945A (en) * | 1996-12-18 | 1998-06-30 | Nkk Corp | Measurement method of slag temperature or slag level position in melting furnace |
| JP2002115822A (en) * | 2000-10-05 | 2002-04-19 | Nkk Corp | Equipment and method for waste disposal |
| JP2003105415A (en) * | 2001-10-01 | 2003-04-09 | Kobe Steel Ltd | Method and device for producing molten metal |
| JP2004176170A (en) * | 2002-01-24 | 2004-06-24 | Kobe Steel Ltd | Method for producing molten iron |
-
2006
- 2006-03-01 JP JP2006054523A patent/JP4110174B2/en not_active Expired - Fee Related
-
2007
- 2007-02-27 WO PCT/JP2007/053619 patent/WO2007099941A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56127718A (en) * | 1980-03-11 | 1981-10-06 | Kawasaki Steel Corp | Slopping prediction method in converter |
| JPH10176945A (en) * | 1996-12-18 | 1998-06-30 | Nkk Corp | Measurement method of slag temperature or slag level position in melting furnace |
| JP2002115822A (en) * | 2000-10-05 | 2002-04-19 | Nkk Corp | Equipment and method for waste disposal |
| JP2003105415A (en) * | 2001-10-01 | 2003-04-09 | Kobe Steel Ltd | Method and device for producing molten metal |
| JP2004176170A (en) * | 2002-01-24 | 2004-06-24 | Kobe Steel Ltd | Method for producing molten iron |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024196276A1 (en) * | 2023-03-20 | 2024-09-26 | Общество с ограниченной ответственностью "Инновационная Компания Интехпром" | Furnace for the selective treatment of solid domestic and industrial waste |
| RU2822523C1 (en) * | 2023-07-28 | 2024-07-08 | Общество с ограниченной ответственностью "Инновационная Компания Интехпром" | Furnace for selective processing of solid household and industrial waste |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4110174B2 (en) | 2008-07-02 |
| JP2007232273A (en) | 2007-09-13 |
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