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WO2007086970A3 - Déshydrogénation par métal de base d'amine-boranes - Google Patents

Déshydrogénation par métal de base d'amine-boranes Download PDF

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Publication number
WO2007086970A3
WO2007086970A3 PCT/US2006/042556 US2006042556W WO2007086970A3 WO 2007086970 A3 WO2007086970 A3 WO 2007086970A3 US 2006042556 W US2006042556 W US 2006042556W WO 2007086970 A3 WO2007086970 A3 WO 2007086970A3
Authority
WO
WIPO (PCT)
Prior art keywords
amine
boranes
base metal
metal dehydrogenation
dehydrogenating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/042556
Other languages
English (en)
Other versions
WO2007086970A2 (fr
Inventor
Johanna Marie Blacquiere
Ralph Thomas Baker
Richard Jeffrey Keaton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Los Alamos National Security LLC
Original Assignee
Los Alamos National Security LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Los Alamos National Security LLC filed Critical Los Alamos National Security LLC
Publication of WO2007086970A2 publication Critical patent/WO2007086970A2/fr
Anticipated expiration legal-status Critical
Publication of WO2007086970A3 publication Critical patent/WO2007086970A3/fr
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/022—Boron compounds without C-boron linkages
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0637—Direct internal reforming at the anode of the fuel cell
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/222—Fuel cells in which the fuel is based on compounds containing nitrogen, e.g. hydrazine, ammonia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La présente invention concerne la déshydrogénation d'un amine-borane de formule R1H2N-BH2R2 au moyen d'un catalyseur à métal de base. Le procédé conduit à la production d'hydrogène et d'au moins un oligomère [R1HN-BHR2]m et un oligomère [R1N-BR2]n. Le procédé peut être employé pour produire H2 dans des sources d'alimentation portatives comprenant, entre autres des piles à combustible.
PCT/US2006/042556 2005-11-04 2006-10-30 Déshydrogénation par métal de base d'amine-boranes Ceased WO2007086970A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US73386605P 2005-11-04 2005-11-04
US60/733,866 2005-11-04

Publications (2)

Publication Number Publication Date
WO2007086970A2 WO2007086970A2 (fr) 2007-08-02
WO2007086970A3 true WO2007086970A3 (fr) 2009-04-16

Family

ID=38309680

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/042556 Ceased WO2007086970A2 (fr) 2005-11-04 2006-10-30 Déshydrogénation par métal de base d'amine-boranes

Country Status (1)

Country Link
WO (1) WO2007086970A2 (fr)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005203188A (ja) * 2004-01-14 2005-07-28 Nippon Oil Corp 燃料電池用水素の発生方法および燃料電池システム
US7285142B1 (en) * 2006-04-28 2007-10-23 University Of Central Florida Research Foundation, Inc. Catalytic dehydrogenation of amine borane complexes

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005203188A (ja) * 2004-01-14 2005-07-28 Nippon Oil Corp 燃料電池用水素の発生方法および燃料電池システム
US7285142B1 (en) * 2006-04-28 2007-10-23 University Of Central Florida Research Foundation, Inc. Catalytic dehydrogenation of amine borane complexes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JASKA ET AL. ET AL.: "Transition Metal-Catalyzed Formation of Boron-Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines.", JACS, vol. 125, no. 31, 2003, pages 9424 - 34 *
TEMPLE ET AL.: "Catalytic Dehydrocoupling of amine-Borane Addcuts to form Aminoboranes and Borazines", PHOSPHORUS, SULFUR AND SILICON, vol. 179, 2004, pages 733 - 736 *

Also Published As

Publication number Publication date
WO2007086970A2 (fr) 2007-08-02

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