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WO2007078900A3 - Two-part sizing composition for reinforcement fibers - Google Patents

Two-part sizing composition for reinforcement fibers Download PDF

Info

Publication number
WO2007078900A3
WO2007078900A3 PCT/US2006/048130 US2006048130W WO2007078900A3 WO 2007078900 A3 WO2007078900 A3 WO 2007078900A3 US 2006048130 W US2006048130 W US 2006048130W WO 2007078900 A3 WO2007078900 A3 WO 2007078900A3
Authority
WO
WIPO (PCT)
Prior art keywords
reinforcing fiber
size
composition
binder
size composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/048130
Other languages
French (fr)
Other versions
WO2007078900A2 (en
Inventor
Marc R Cossement
Jean-Marc P Henrion
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning Fiberglas Technology Inc
Owens Corning Intellectual Capital LLC
Original Assignee
Owens Corning Fiberglas Technology Inc
Owens Corning Fiberglas Technology II LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens Corning Fiberglas Technology Inc, Owens Corning Fiberglas Technology II LLC filed Critical Owens Corning Fiberglas Technology Inc
Priority to CN2006800498951A priority Critical patent/CN101351590B/en
Priority to CA 2635451 priority patent/CA2635451A1/en
Priority to JP2008548592A priority patent/JP2009522459A/en
Priority to EP20060845672 priority patent/EP1966432A2/en
Priority to BRPI0620728-6A priority patent/BRPI0620728A2/en
Publication of WO2007078900A2 publication Critical patent/WO2007078900A2/en
Publication of WO2007078900A3 publication Critical patent/WO2007078900A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/285—Acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/48—Coating with two or more coatings having different compositions
    • C03C25/50—Coatings containing organic materials only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)

Abstract

A two-part sizing formulation that imparts .improved strength of reinforced composites including a size composition and a binder composition is provided. The size composition may include one or more coupling agents and one or more film forming agents. The binder composition includes a high acid number copolymer formed from the polymerization of maleic anhydride or maleic acid and at least one other desired monomer and/or a high acid number polycarboxylic acid. In a preferred embodiment, the binder composition includes an ethylene-maleic acid copolymer formed by the hydrolysis of an ethylene maleic anhydride copolymer. The size composition may be applied to a reinforcing fiber material before the binder size material is applied. The two-part size composition may be applied to a reinforcing fiber material to form a reinforcing fiber product which may then be densified or compacted to form a densified reinforcing fiber product, such as a pellet.
PCT/US2006/048130 2005-12-30 2006-12-15 Two-part sizing composition for reinforcement fibers Ceased WO2007078900A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN2006800498951A CN101351590B (en) 2005-12-30 2006-12-15 Two-part sizing composition for reinforcement fibers
CA 2635451 CA2635451A1 (en) 2005-12-30 2006-12-15 Two-part sizing composition for reinforcement fibers
JP2008548592A JP2009522459A (en) 2005-12-30 2006-12-15 Two-part sizing composition for reinforcing fibers
EP20060845672 EP1966432A2 (en) 2005-12-30 2006-12-15 Two-part sizing composition for reinforcement fibers
BRPI0620728-6A BRPI0620728A2 (en) 2005-12-30 2006-12-15 two-part ironing composition for reinforcing fibers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/322,331 2005-12-30
US11/322,331 US20070154697A1 (en) 2005-12-30 2005-12-30 Two-part sizing composition for reinforcement fibers

Publications (2)

Publication Number Publication Date
WO2007078900A2 WO2007078900A2 (en) 2007-07-12
WO2007078900A3 true WO2007078900A3 (en) 2007-08-30

Family

ID=38180143

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/048130 Ceased WO2007078900A2 (en) 2005-12-30 2006-12-15 Two-part sizing composition for reinforcement fibers

Country Status (9)

Country Link
US (1) US20070154697A1 (en)
EP (1) EP1966432A2 (en)
JP (1) JP2009522459A (en)
KR (1) KR20080081164A (en)
CN (1) CN101351590B (en)
BR (1) BRPI0620728A2 (en)
CA (1) CA2635451A1 (en)
TW (1) TW200736182A (en)
WO (1) WO2007078900A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100055439A1 (en) * 2008-08-29 2010-03-04 Lee Jerry H C WUCS Fibers Having Improved Flowing And Dispersing Properties
FR2938847B1 (en) * 2008-11-21 2013-01-11 Arkema France POLYAMIDE COMPOSITIONS AND BIORESOURCE REINFORCEMENTS WITH IMPROVED MECHANICAL PROPERTIES
TWI529212B (en) * 2010-08-18 2016-04-11 Vertellus Specialties Inc Compositions, methods and articles produced by compounding polymides with olefin-maleic anhydride polymers
CA2848953A1 (en) * 2011-09-23 2013-03-28 Ocv Intellectual Capital, Llc Reinforcing fibers and their use for concrete reinforcement
EP2620419A1 (en) 2012-01-27 2013-07-31 3B Fibreglass Polyamide based sizing composition for glass fibres
US9758430B2 (en) 2012-03-20 2017-09-12 3B-Fibreglass Sprl Two part sizing composition for coating glass fibres and composite reinforced with such glass fibres
MY175183A (en) 2013-03-15 2020-06-12 Vertellus Holdings Llc Impact-modified polyamide compositions
WO2015119984A2 (en) * 2014-02-06 2015-08-13 Ocv Intellectual Capital, Llc Postponed differentiation of reinforced composites
BR112017000872B1 (en) 2014-07-14 2022-06-14 Vertellus Holdings Llc COMPATIBILIZED THERMOPLASTIC PELLETIZABLE POLYMER ALLOY COMPOSITION
FR3043883B1 (en) 2015-11-23 2018-08-17 Cnh Industrial France SECURING DEVICE FOR EQUIPPING A FRUIT HARVESTING UNIT
US11639316B2 (en) * 2018-09-26 2023-05-02 3M Innovative Properties Company Fiber tows with a heat-activated sizing
KR102613741B1 (en) * 2021-06-30 2023-12-14 주식회사 케이씨씨 Sizing composition and glass fiber using the same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001049627A1 (en) * 1999-12-29 2001-07-12 Owens Corning System for preparing glass fiber pellets having low discoloration
US20040209991A1 (en) * 2001-12-21 2004-10-21 Piret Willy H Hydrolization resistant sizing compositon
WO2005066237A2 (en) * 2003-12-19 2005-07-21 Ppg Industries Ohio, Inc. Sizing composition and glass fiber reinforced thermoplastic resin

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816235A (en) * 1972-08-18 1974-06-11 Owens Corning Fiberglass Corp Glass fiber size composition
DE2714897C3 (en) * 1977-04-02 1981-12-03 Basf Ag, 6700 Ludwigshafen Use of water-soluble alkaline earth salts of polymers of acrylic acid or methacrylic acid as sizing agents
US4318960A (en) * 1977-11-07 1982-03-09 Owens-Corning Fiberglas Corporation Glass fiber size composition comprising maleic anhydride graft copolymer
US4636437A (en) * 1984-11-05 1987-01-13 Owens-Corning Fiberglas Corporation Glass fiber size and impregnant compositions
US4785039A (en) * 1984-11-05 1988-11-15 Owens-Corning Fiberglass Corporation Glass fiber size and impregnant compositions
US5130197A (en) * 1985-03-25 1992-07-14 Ppg Industries, Inc. Glass fibers for reinforcing polymers
US5002827A (en) * 1987-10-26 1991-03-26 Nippon Glass Fiber Co., Ltd. Agglomerated glass flakes
US5236982A (en) * 1992-07-13 1993-08-17 Owens-Corning Fiberglas Technology, Inc. Size composition
US5272195A (en) * 1992-07-14 1993-12-21 Phillips Petroleum Company Glass-reinforced chemically coupled branched higher alpha-olefin compounds
US5300547A (en) * 1992-10-30 1994-04-05 Phillips Petroleum Company Reinforced polypropylene compounds with improved properties
US5639807A (en) * 1994-08-05 1997-06-17 Akzo Nobel Nv Process for manufacturing carbon fiber pellets, the high density, streamlined pellets resulting therefrom and process for producing reinforced thermoplastic resins employing the pellets
US5672641A (en) * 1995-01-23 1997-09-30 Ppg Industries, Inc. Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith
US5804313A (en) * 1996-07-15 1998-09-08 Ppg Industries, Inc. Polyamide and acrylic polymer coated glass fiber reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5824413A (en) * 1996-07-15 1998-10-20 Ppg Industries, Inc. Secondary coating for fiber strands, coated strand reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5945134A (en) * 1997-04-01 1999-08-31 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
US5868982A (en) * 1997-04-01 1999-02-09 Owens-Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
DE19857530C2 (en) * 1998-12-14 2001-11-15 Bayer Ag Sizing composition for glass fibers
US20010016259A1 (en) * 1999-02-16 2001-08-23 Les E. Campbell Sizing composition for glass fibers used to reinforce thermoplastic or thermosetting matrix polymers
JP4201423B2 (en) * 1999-02-25 2008-12-24 株式会社Ａｄｅｋａ Glass fiber sizing agent
US20010008921A1 (en) * 1999-05-20 2001-07-19 Westvaco Corporation Hydrocarbon/acrylic hybrid resins for use as sizing compositions
US6365090B1 (en) * 1999-07-16 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing polymer encapsulated glass fiber pellets
JP4511669B2 (en) * 2000-02-18 2010-07-28 旭化成ケミカルズ株式会社 Reinforced polyamide resin composition
US6844406B2 (en) * 2000-10-04 2005-01-18 Valspar Sourcing, Inc. High functionality number, low molecular weight polymers and methods of making same
US7267782B2 (en) * 2003-06-19 2007-09-11 Owens-Corning Fiberglas Technology Ii, Llc Two-part combination of compositions for forming substantially colorless thermoplastic reinforcements
US20070072989A1 (en) * 2004-03-19 2007-03-29 Piret Willy H Two-part sizing composition for reinforcement fibers
US20050214534A1 (en) * 2004-03-29 2005-09-29 Adamo Joseph R Extended curable compositions for use as binders
US20070286999A1 (en) * 2006-06-13 2007-12-13 Jacob Cornelis Dijt Sizing composition for glass fibers, sized fiber glass products, and composites

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001049627A1 (en) * 1999-12-29 2001-07-12 Owens Corning System for preparing glass fiber pellets having low discoloration
US20040209991A1 (en) * 2001-12-21 2004-10-21 Piret Willy H Hydrolization resistant sizing compositon
WO2005066237A2 (en) * 2003-12-19 2005-07-21 Ppg Industries Ohio, Inc. Sizing composition and glass fiber reinforced thermoplastic resin

Also Published As

Publication number Publication date
BRPI0620728A2 (en) 2011-11-22
JP2009522459A (en) 2009-06-11
US20070154697A1 (en) 2007-07-05
CA2635451A1 (en) 2007-07-12
TW200736182A (en) 2007-10-01
CN101351590A (en) 2009-01-21
KR20080081164A (en) 2008-09-08
EP1966432A2 (en) 2008-09-10
CN101351590B (en) 2011-12-14
WO2007078900A2 (en) 2007-07-12

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