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WO2007067090A1 - Anilines a substitution alcoxy ou melanges, qui servent de composants, d'additifs (adjuvants) et/ou d'agents synergiques avec ou sans oxygenats ou de melanges de ceux-ci et ameliorent efficacement la resistance a la detonation de combustibles (carburants), et compositions combustibles a base desdites anilines - Google Patents

Anilines a substitution alcoxy ou melanges, qui servent de composants, d'additifs (adjuvants) et/ou d'agents synergiques avec ou sans oxygenats ou de melanges de ceux-ci et ameliorent efficacement la resistance a la detonation de combustibles (carburants), et compositions combustibles a base desdites anilines Download PDF

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Publication number
WO2007067090A1
WO2007067090A1 PCT/RU2006/000427 RU2006000427W WO2007067090A1 WO 2007067090 A1 WO2007067090 A1 WO 2007067090A1 RU 2006000427 W RU2006000427 W RU 2006000427W WO 2007067090 A1 WO2007067090 A1 WO 2007067090A1
Authority
WO
WIPO (PCT)
Prior art keywords
fuels
additives
para
ortho
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2006/000427
Other languages
English (en)
Russian (ru)
Inventor
Yuri Alexandrovich Ivanov
Alexander Yurievich Frolov
Valeriy Vladimirovich Osinin
Vladimir Mikhaylovich Perevezentzev
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Obschestvo S Ogranichennoy Otvetstvennstyu 'inoxim'
IFO LLC
Original Assignee
Obschestvo S Ogranichennoy Otvetstvennstyu 'inoxim'
IFO LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Obschestvo S Ogranichennoy Otvetstvennstyu 'inoxim', IFO LLC filed Critical Obschestvo S Ogranichennoy Otvetstvennstyu 'inoxim'
Publication of WO2007067090A1 publication Critical patent/WO2007067090A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom

Definitions

  • the present invention relates to substances that increase the antiknock resistance of hydrocarbon fuels (fuels) and can be used in the field of oil refining, gas processing to create high-octane fuels.
  • This problem can be solved by creating new chemical processes of reforming gasoline of direct race, catalytic cracking and catalytic reforming or by adding special antiknock additives and high-octane components to hydrocarbon fuels (fuels) [1,4]. In this case, a synergistic effect may occur [1-7].
  • additives are organic compounds of manganese, iron, copper, chromium, cobalt, nickel, rare earth elements, lead [1,4,5,17], etc.
  • Ashless antiknock additives although less effective than ash ones, are more widely used and used, especially in combination with other components [1-15,17].
  • additives are: low molecular weight aromatic amines [N-methylaniline (MMA), xylidine, toluidine].
  • the additive Extralin TU 6.02.571-90 is known, containing in percentage weight ratios dimethylaniline up to 4.5%, aniline up to 6% and N-methylaniline up to 100% [14].
  • Another known additive of a similar type is the ADA additive TU 38-401-58-61-93, which additionally contains an antioxidant additive like ionol [14]
  • Homologues of benzene are also known as antiknock agents: xylene, ethylbenzene, toluene [14, 16, 17], which increase the octane number of fuels very slightly.
  • hydrocarbon fuels consist of a mixture of various hydrocarbons, which, with a certain combination of components, can acquire the desired properties in the process of their use (application), namely, as hydrocarbon fuels (fuel) in internal combustion engines, where their optimal operation requires simultaneous achievement of the maximum pressure of the vapor-air mixture at the moment the piston passes the top dead center and decomposition (ignition) of this mixture from the electric spark of the spark plug. If these conditions are not met, detonation occurs, which adversely affects engine operation, fuel consumption and exhaust gas composition [1-7].
  • Aromatic amines can, in combination with hydrocarbon fuels (fuels), consisting of a mixture of various hydrocarbons, form intermolecular bonds with the molecules of the substances in the composition of the fuels through the formation of complexes, with charge transfer, ⁇ - complexes, ⁇ - complexes, as well as free stable radicals and other active intermediate products with resonant energy exchange or new formations [18-32], which determines the possibility of a synergistic effect.
  • fuels fuels
  • fuels consisting of a mixture of various hydrocarbons
  • the system can be excited by various and numerous factors at the same time or selectively from just one single factor, for example, from an electric discharge, which is very important when certain processes occur under these conditions.
  • anisidines methoxyanilines, aminoanisoles
  • phenetidines ethoxyanilines, aminophenetols
  • dyes eg triarylmethane
  • prototypes can be selected as osigenates: ethyl or methyl tert-butyl ether, and aniline, xylidine, toluidine, which are primary amines.
  • alkoxy substituted anilines was determined by the increase in the octane number determined by the motor method (ORM) and the research method (ORI) in the reference fuel mixture of isooctane and normal heptane (70:30 vol%, respectively).
  • Example 1 Para-ethoxyaniline, taken 1.3% of the mass, in relation to the reference fuel mixture gave an increase in HF by 5.5 units. (OFM) and 7 units. (OCHI).
  • Example 2 Ortho-ethoxyaniline, taken 1.3% of the mass, in relation to the reference fuel mixture gave an increase in NF by 4 units. (OFM) and 6 units. (OCHI)
  • Example Z Meta-ethoxyaniline, taken 1.3% of the mass, in relation to the reference fuel mixture gave an increase in HF by 3.8 units. (OFM) and 5.6 units. (OCHI).
  • Example 4 Para-methoxyaniline, taken 1% of the mass, in relation to the reference fuel mixture gave an increase in HF by 2.5 units. (OFM) and 5 units.
  • Example b Meta-methoxyaniline, taken 1.3% of the mass relative to the reference fuel mixture gave an increase in HF by 2 units. (OFM) and 4.2 units.
  • Example 7 A mixture of para-ethoxyaniline and ortho-ethoxyaniline in a ratio of 1: 1, taken 1.3% of the mass, in relation to the reference fuel mixture gave an increase in HF by 5.5 units. (OFM) and 7.5 units. (OCHI).
  • Example 8 A mixture of para-ethoxyaniline and MTBE in a ratio of 1: 1, taken 3% of the mass, in relation to the reference fuel mixture gave an increase in HF by 7 units. (OFM) and 9.5 units. (OCHI).
  • Example 9 A mixture of para-methoxyaniline and methyl tert.-butyl ether (MBE) in a ratio of 1: 1, respectively, taken 3% with respect to the reference fuel mixture gave an increase in HF by 6 units.
  • MBE methyl tert.-butyl ether
  • Example 9 Papa-ethoxyaniline, taken 1.3% of the mass, in relation to gasoline direct race 58 units. HFM, gave an increase in HF by 14 units. (OFM) and 17.5 units. (OCHI).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

La présente invention se rapporte à des anilines à substitution alcoxy en tant que telles ou à des mélanges de ces dernières, qui servent de composants, d'additifs (adjuvants) et/ou d'agents synergiques avec ou sans oxygénats ou de mélanges de ceux-ci et améliorent efficacement la résistance à la détonation de combustibles (carburants), ainsi qu'à des compositions combustibles à base desdites anilines. L'invention a également trait à des compositions (combinaisons, formulations) combustibles, qui sont caractérisées en ce qu'elles utilisent (emploient), en tant que composants, additifs (adjuvants) et/ou agents synergiques permettant d'augmenter le taux d'octane de combustibles hydrocarbonés, des anilines à substitution alcoxy présentes en une quantité égale à 0-100 % poids et 0,1-25 % poids par rapport aux combustibles (carburants) hydrocarbonés. L'invention concerne aussi des compositions (combinaisons, formulations) combustibles, qui sont caractérisées en ce qu'elles utilisent (emploient), en tant que composants, additifs (adjuvants) et/ou agents synergiques permettant d'augmenter le taux d'octane de combustibles (carburants) hydrocarbonés, des anilines à substitution alcoxy contenant des oxygénats, présentes en une quantité égale à 0,1-90 % poids, les oxygénats représentant jusqu'à 100 %, respectivement, et en une quantité égale à 0,1-40 % par rapport aux combustibles (carburants) hydrocarbonés.
PCT/RU2006/000427 2005-12-07 2006-08-14 Anilines a substitution alcoxy ou melanges, qui servent de composants, d'additifs (adjuvants) et/ou d'agents synergiques avec ou sans oxygenats ou de melanges de ceux-ci et ameliorent efficacement la resistance a la detonation de combustibles (carburants), et compositions combustibles a base desdites anilines Ceased WO2007067090A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2005138061/04A RU2305128C9 (ru) 2005-12-07 2005-12-07 Антидетонационная добавка к бензину на основе алкоксизамещенных анилинов и топливные композиции, ее содержащие
RU2005138061 2005-12-07

Publications (1)

Publication Number Publication Date
WO2007067090A1 true WO2007067090A1 (fr) 2007-06-14

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PCT/RU2006/000427 Ceased WO2007067090A1 (fr) 2005-12-07 2006-08-14 Anilines a substitution alcoxy ou melanges, qui servent de composants, d'additifs (adjuvants) et/ou d'agents synergiques avec ou sans oxygenats ou de melanges de ceux-ci et ameliorent efficacement la resistance a la detonation de combustibles (carburants), et compositions combustibles a base desdites anilines

Country Status (2)

Country Link
RU (1) RU2305128C9 (fr)
WO (1) WO2007067090A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008076759A1 (fr) * 2006-12-14 2008-06-26 Shell Oil Company Composition de carburant et utilisation correspondante
EP2014643A4 (fr) * 2006-04-12 2009-09-09 Obshestvo S Ogranichennoy Otve Dérivés de para-méthoxyanilines augmentant le pouvoir antidétonant de carburants hydrocarbonés et compositions sur leur base
US20100258071A1 (en) * 2009-04-09 2010-10-14 Paggi Raymond Edward Fuel composition and its use
RU2554076C1 (ru) * 2014-09-17 2015-06-27 Владимир Алексеевич Лазарев Добавка к бензину и композиция, ее содержащая

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0923604A2 (pt) * 2008-12-30 2019-09-24 Shell Int Research composição de combustível, e, método para melhorar o número de octanagem de uma gasolina, e para reduzir depósitos na válvula de entrada em um motor de combustão interna.
RU2576327C1 (ru) * 2015-03-31 2016-02-27 Евгений Владимирович Ройтман Антидетонационная добавка и топливо с указанной добавкой
RU2592269C1 (ru) * 2015-05-13 2016-07-20 Общество с ограниченной ответственностью "ИФОТОП" Многофункциональная эфирная присадка к углеводородсодержащему топливу и топливная композиция

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2050841A5 (en) * 1969-06-26 1971-04-02 Elf Antiknock additives for high-octane fuels
US4973336A (en) * 1988-06-10 1990-11-27 Gheysens Jean Louis G Fuel additives
RU2184767C1 (ru) * 2001-06-28 2002-07-10 Аветисян Владимир Евгеньевич Добавка к бензину и автомобильное топливо, ее содержащее

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2050841A5 (en) * 1969-06-26 1971-04-02 Elf Antiknock additives for high-octane fuels
US4973336A (en) * 1988-06-10 1990-11-27 Gheysens Jean Louis G Fuel additives
RU2184767C1 (ru) * 2001-06-28 2002-07-10 Аветисян Владимир Евгеньевич Добавка к бензину и автомобильное топливо, ее содержащее

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BROWN J.E. ET AL.: "Mechanism of Aromatic Amine Antiknock Action", INDUSTRIAL & ENGINEERING CHEMISTRY, October 1955 (1955-10-01), pages 2141 - 2146, XP003014351 *
DANILOV A.M.: "Primeninie prisadok v toplivakh dlya avtomobiley", SPRAVOCHNIK, 2000, MOSCOW, pages 39 - 47 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2014643A4 (fr) * 2006-04-12 2009-09-09 Obshestvo S Ogranichennoy Otve Dérivés de para-méthoxyanilines augmentant le pouvoir antidétonant de carburants hydrocarbonés et compositions sur leur base
WO2008076759A1 (fr) * 2006-12-14 2008-06-26 Shell Oil Company Composition de carburant et utilisation correspondante
JP2010513605A (ja) * 2006-12-14 2010-04-30 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 燃料組成物及びその使用
US7976591B2 (en) 2006-12-14 2011-07-12 Shell Oil Company Fuel composition and its use
US20100258071A1 (en) * 2009-04-09 2010-10-14 Paggi Raymond Edward Fuel composition and its use
AU2010234545B2 (en) * 2009-04-09 2012-10-04 Shell Internationale Research Maatschappij B.V. Fuel composition and its use
US8715376B2 (en) 2009-04-09 2014-05-06 Shell Oil Company Fuel composition and its use
RU2554076C1 (ru) * 2014-09-17 2015-06-27 Владимир Алексеевич Лазарев Добавка к бензину и композиция, ее содержащая

Also Published As

Publication number Publication date
RU2305128C9 (ru) 2007-12-27
RU2005138061A (ru) 2007-06-27
RU2305128C1 (ru) 2007-08-27

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