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WO2006130150A3 - Nanotubes de carbone a simple paroi fonctionnalises - Google Patents

Nanotubes de carbone a simple paroi fonctionnalises Download PDF

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Publication number
WO2006130150A3
WO2006130150A3 PCT/US2005/022413 US2005022413W WO2006130150A3 WO 2006130150 A3 WO2006130150 A3 WO 2006130150A3 US 2005022413 W US2005022413 W US 2005022413W WO 2006130150 A3 WO2006130150 A3 WO 2006130150A3
Authority
WO
WIPO (PCT)
Prior art keywords
walled carbon
nanotubes
functionalized
single walled
carbon nanotubes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2005/022413
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English (en)
Other versions
WO2006130150A2 (fr
WO2006130150A9 (fr
Inventor
Robert Hoch
Alan Fischer
Howard Tennent
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hyperion Catalysis International Inc
Original Assignee
Hyperion Catalysis International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyperion Catalysis International Inc filed Critical Hyperion Catalysis International Inc
Priority to JP2007519302A priority Critical patent/JP2008513318A/ja
Priority to AU2005332329A priority patent/AU2005332329A1/en
Priority to CA002571575A priority patent/CA2571575A1/fr
Priority to EP05857879A priority patent/EP1776125A4/fr
Publication of WO2006130150A2 publication Critical patent/WO2006130150A2/fr
Anticipated expiration legal-status Critical
Publication of WO2006130150A3 publication Critical patent/WO2006130150A3/fr
Publication of WO2006130150A9 publication Critical patent/WO2006130150A9/fr
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/003—Catalysts comprising hydrides, coordination complexes or organic compounds containing enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B1/008—Nanostructures not provided for in groups B82B1/001 - B82B1/007
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0061—Methods for manipulating nanostructures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0095—Manufacture or treatments or nanostructures not provided for in groups B82B3/0009 - B82B3/009
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/14—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Composite Materials (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Peptides Or Proteins (AREA)

Abstract

La présente invention se rapporte à des nanotubes de graphite, qui contiennent des fullerènes tubulaires (communément appelés 'buckytubes' en anglais) et des fibrilles, et qui sont fonctionnalisés par substitution chimique ou par adsorption de fractions fonctionnelles. Plus précisément, l'invention a trait à des nanotubes de carbone à simple paroi présentant un diamètre inférieur à 5 nanomètres, qui sont uniformément ou non uniformément substitués par des fractions chimiques ou sur lesquels sont adsorbés certains composés cycliques, ainsi qu'à des structures complexes constituées de tels nanotubes fonctionnalisés liés les uns aux autres. L'invention concerne aussi des procédés permettant d'introduire des groupes fonctionnels sur la surface de tels nanotubes. L'invention a également pour objet des procédés d'utilisation desdits nanotubes de carbone à simple paroi fonctionnalisés.
PCT/US2005/022413 2004-06-23 2005-06-23 Nanotubes de carbone a simple paroi fonctionnalises Ceased WO2006130150A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2007519302A JP2008513318A (ja) 2004-06-23 2005-06-23 官能基化単層カーボンナノチューブ
AU2005332329A AU2005332329A1 (en) 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes
CA002571575A CA2571575A1 (fr) 2004-06-23 2005-06-23 Nanotubes de carbone a simple paroi fonctionnalises
EP05857879A EP1776125A4 (fr) 2004-06-23 2005-06-23 Nanotubes de carbone a simple paroi fonctionnalises

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87543504A 2004-06-23 2004-06-23
US10/875,435 2004-06-23

Publications (3)

Publication Number Publication Date
WO2006130150A2 WO2006130150A2 (fr) 2006-12-07
WO2006130150A3 true WO2006130150A3 (fr) 2009-04-16
WO2006130150A9 WO2006130150A9 (fr) 2009-06-11

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/022413 Ceased WO2006130150A2 (fr) 2004-06-23 2005-06-23 Nanotubes de carbone a simple paroi fonctionnalises

Country Status (7)

Country Link
EP (1) EP1776125A4 (fr)
JP (1) JP2008513318A (fr)
KR (1) KR20070030282A (fr)
CN (1) CN101432227A (fr)
AU (1) AU2005332329A1 (fr)
CA (1) CA2571575A1 (fr)
WO (1) WO2006130150A2 (fr)

Cited By (14)

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US9090472B2 (en) 2012-04-16 2015-07-28 Seerstone Llc Methods for producing solid carbon by reducing carbon dioxide
US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
US9556031B2 (en) 2009-04-17 2017-01-31 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
US9598286B2 (en) 2012-07-13 2017-03-21 Seerstone Llc Methods and systems for forming ammonia and solid carbon products
US9604848B2 (en) 2012-07-12 2017-03-28 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US9731970B2 (en) 2012-04-16 2017-08-15 Seerstone Llc Methods and systems for thermal energy recovery from production of solid carbon materials by reducing carbon oxides
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
US9783421B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
US9796591B2 (en) 2012-04-16 2017-10-24 Seerstone Llc Methods for reducing carbon oxides with non ferrous catalysts and forming solid carbon products
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
US9993791B2 (en) 2012-11-29 2018-06-12 Seerstone Llc Reactors and methods for producing solid carbon materials
US10106416B2 (en) 2012-04-16 2018-10-23 Seerstone Llc Methods for treating an offgas containing carbon oxides
US10322832B2 (en) 2013-03-15 2019-06-18 Seerstone, Llc Systems for producing solid carbon by reducing carbon oxides
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same

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US7947247B2 (en) 2005-03-29 2011-05-24 Hyperion Catalysis International, Inc. Method for preparing single walled carbon nanotubes from a metal layer
US8529862B2 (en) 2005-03-29 2013-09-10 Hyperion Catalysis International, Inc. Method for preparing single walled carbon nanotubes from a metal layer
WO2008060654A2 (fr) 2006-03-29 2008-05-22 Hyperion Catalysis International, Inc. Procédé de préparation de nanotubes de carbone uniformes à paroi unique
EP2169070B1 (fr) * 2007-06-21 2015-06-10 National University Corporation Nagoya University Procédé d'introduction d'une substance étrangère dans une cellule ayant une paroi cellulaire
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US8841454B2 (en) 2009-07-17 2014-09-23 Exxonmobil Research And Engineering Company Functionalized carbon nanostructures which are soluble in hydrocarbons and method for preparation
US8435931B2 (en) 2009-07-17 2013-05-07 Exxonmobil Research And Engineering Company Reduced friction lubricating oils containing functionalized carbon nanomaterials
EP2532622B1 (fr) * 2010-02-04 2016-12-07 Japan Science And Technology Agency Procédé de fonctionnalisation de nanotubes de carbone
CN102335434A (zh) * 2010-07-23 2012-02-01 复旦大学 特异性单克隆抗体靶向性碳纳米管药物载体及其制备方法
KR101281733B1 (ko) * 2010-11-18 2013-07-04 한국과학기술원 폴리(아릴렌 에테르)계 고분자가 부착된 탄소 나노튜브의 제조방법
JP5429893B2 (ja) * 2011-11-02 2014-02-26 独立行政法人物質・材料研究機構 レドックスたんぱく質を非共有結合で結合させ機能化した生体反応性カーボンナノチューブの製法
US10115844B2 (en) 2013-03-15 2018-10-30 Seerstone Llc Electrodes comprising nanostructured carbon
US9783416B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Methods of producing hydrogen and solid carbon
EP3129135A4 (fr) 2013-03-15 2017-10-25 Seerstone LLC Réacteurs, systèmes et procédés de formation de produits solides
KR102095282B1 (ko) * 2015-12-31 2020-04-01 기초과학연구원 광 발광성 탄소 집합체 및 이의 제조방법
CN106058034B (zh) * 2016-07-12 2023-04-28 北京服装学院 一种（1,3-二硫-2-羰基）稠合的萘二酰亚胺/碳纳米管复合热电材料制备方法
US11752459B2 (en) 2016-07-28 2023-09-12 Seerstone Llc Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
CN106809817B (zh) * 2017-01-16 2019-01-11 东华大学 一种多孔碳纳米管的制备方法
CN106841344B (zh) * 2017-04-07 2018-12-11 西北师范大学 一种孔状单壁碳纳米管及其修饰电极的制备和应用
US10865502B2 (en) 2018-05-14 2020-12-15 Global Graphene Group, Inc. Continuous graphene fibers from functionalized graphene sheets
US12246967B2 (en) 2018-05-15 2025-03-11 Global Graphene Group, Inc. Process for producing integral graphene films from functionalized graphene sheets
US10927478B2 (en) 2018-05-21 2021-02-23 Global Graphene Group, Inc. Fabric of continuous graphene fiber yarns from functionalized graphene sheets
US10934637B2 (en) 2018-05-21 2021-03-02 Global Graphene Group, Inc. Process for producing fabric of continuous graphene fiber yarns from functionalized graphene sheets
CN108636363B (zh) * 2018-05-25 2019-12-27 湖南大学 谷氨酸修饰的碳纳米管复合材料及其制备方法和应用
CN110564016B (zh) * 2019-08-27 2022-06-14 山东大展纳米材料有限公司 一种高补强橡胶胶乳湿法混炼复合材料及其制备工艺
CN111019934A (zh) * 2019-12-31 2020-04-17 广东工业大学 一种酶固定化复合材料及制备方法
CN111135344A (zh) * 2020-02-27 2020-05-12 福州大学 复合白蛋白的碳纳米管/胶原基软骨修复用支架及其制备方法
TWI813493B (zh) * 2021-07-20 2023-08-21 友達光電股份有限公司 顯示裝置
CN114518453B (zh) * 2022-01-26 2023-05-16 东北农业大学 一种多壁碳纳米管复合物及其制备方法和应用
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CN115228437B (zh) * 2022-08-18 2023-10-31 四川轻化工大学 一种使活性炭表面呈正电性的表面修饰方法
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CN119390056B (zh) * 2024-10-28 2025-09-30 吉林大学 Zn单原子修饰硬碳材料及其制备方法和应用
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EP1776125A2 (fr) 2007-04-25
JP2008513318A (ja) 2008-05-01
WO2006130150A2 (fr) 2006-12-07
EP1776125A4 (fr) 2012-01-25
AU2005332329A1 (en) 2006-12-07
KR20070030282A (ko) 2007-03-15
WO2006130150A9 (fr) 2009-06-11
CN101432227A (zh) 2009-05-13
CA2571575A1 (fr) 2006-12-07

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