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WO2006034717A1 - Procede pour la preparation d'une membrane asymetrique comprenant un substrat mesoporeux ou macroporeux et une couche microporeuse/mesoporeuse deposee dessus et membrane asymetrique - Google Patents

Procede pour la preparation d'une membrane asymetrique comprenant un substrat mesoporeux ou macroporeux et une couche microporeuse/mesoporeuse deposee dessus et membrane asymetrique Download PDF

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Publication number
WO2006034717A1
WO2006034717A1 PCT/DK2005/000620 DK2005000620W WO2006034717A1 WO 2006034717 A1 WO2006034717 A1 WO 2006034717A1 DK 2005000620 W DK2005000620 W DK 2005000620W WO 2006034717 A1 WO2006034717 A1 WO 2006034717A1
Authority
WO
WIPO (PCT)
Prior art keywords
meso
porous
nanoparticles
micro
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DK2005/000620
Other languages
English (en)
Inventor
Tue Johannessen
Majid Mosleh
Johnny Johansen
Hans Livbjerg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danmarks Tekniske Universitet
Original Assignee
Danmarks Tekniske Universitet
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danmarks Tekniske Universitet filed Critical Danmarks Tekniske Universitet
Publication of WO2006034717A1 publication Critical patent/WO2006034717A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0004—Organic membrane manufacture by agglomeration of particles
    • B01D67/00041—Organic membrane manufacture by agglomeration of particles by sintering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0004—Organic membrane manufacture by agglomeration of particles
    • B01D67/00043—Organic membrane manufacture by agglomeration of particles by agglomeration of nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/025—Aluminium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C01B13/20—Methods for preparing oxides or hydroxides in general by oxidation of elements in the gaseous state; by oxidation or hydrolysis of compounds in the gaseous state
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/30—Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds
    • C01F7/302—Hydrolysis or oxidation of gaseous aluminium compounds in the gaseous phase
    • C01F7/304—Hydrolysis or oxidation of gaseous aluminium compounds in the gaseous phase of organic aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4582—Porous coatings, e.g. coating containing porous fillers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/04—Coating on selected surface areas, e.g. using masks
    • C23C16/045—Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/453—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating passing the reaction gases through burners or torches, e.g. atmospheric pressure CVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/022—Asymmetric membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/10—Catalysts being present on the surface of the membrane or in the pores
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • C04B2111/00801—Membranes; Diaphragms

Definitions

  • Ceramic membranes offer a higher thermal, chemical, and mechanical stability than polymeric membranes presently dominating in industrial practice.
  • Ceramic membranes with pore sizes in the nanometer range are obtained by slip- casting with a pore diameter of approximately 2 nm as the lower limit.
  • Figure 12 An "empirical" figure showing the normally observed correlation between precursor loading in a particle synthesis unit and the resulting morphology. Small concentrations result in very small, compact particles whereas an increase in concentration results in an increase in particle size and at even higher concentration aggregates of primary particles are formed (because there is insufficient residence time to sinter/coalesce the aggregate into a compact spherical particle).
  • Figure 15 The three figures (left column) illustrate the build-up of a layer in the pore mouths of and on the surface of a substrate during a dynamic deposition experiment in which the particle size gradually decreases with time.
  • the fairly coarse nanoparticles close the pore mouth of the substrate. Somewhat finer nanoparticles are deposited between the coarser nanoparticles in the pore mouth, and very fine nanoparticles are deposited on top and between the somewhat finer particles whereby an outer layer of nanoparticles are build on the surface of the substrate.
  • the deposition rate mass per time
  • a continuous reduction of the particle size can be obtained by continuously lowering the temperature in the saturator.
  • the diagram (right hand side) illustrates the continuous reduction in particle diameter.
  • the mixture of feed gases is fed to the burner through the swirl mixer to ensure high degree of mixing of fuel, oxidant and precursor.
  • the combustion of fuel takes place just above the flame arrestor, which is a thick (0.5-1 cm) metal plate with small cylindrical holes.
  • the flame arrestor distributes the flow of the feed gases and prevents flashback of the flame front.
  • the precursor is added to the flame as a vapour in a gas (e.g. nitrogen) stream from saturator unit that consists of a metal box with one or more metal trays on which thin layers of the precursor powder are in contact with the nitrogen stream.
  • the precursor has a certain sublimation pressure, which combined with the control of the heating element of the unit determines the concentration of the precursor in the carrier gas.
  • the aerosol phase of nanoparticles is prepared by the heating in a hot plasma of a gas mixture or aerosol containing desired precursor metals either present as evaporated molecules or as small droplets of precursors dissolved in a solvent (e.g. metal nitrates in aqueous solution or metal alkoxides in organic solvent).
  • a solvent e.g. metal nitrates in aqueous solution or metal alkoxides in organic solvent.
  • F is called the permeance and has the same unit as a diffusion coefficient and is defined as follows:
  • the permeability of H 2 , He and N 2 for the top layer hardly changes with the trans-membrane pressure difference also showing that the transport of gases through the top layer is controlled by the Knudsen diffusion mechanism.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Nanotechnology (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Structural Engineering (AREA)
  • Plasma & Fusion (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

La présente invention concerne un procédé pour la préparation d'une membrane inorganique asymétrique comprenant un substrat mésoporeux ou macroporeux et une couche microporeuse/mésoporeuse déposée dessus. La présente invention concerne également des membranes asymétriques présentant un diamètre des pores de l'ordre du nanomètre à un chiffre.
PCT/DK2005/000620 2004-09-29 2005-09-29 Procede pour la preparation d'une membrane asymetrique comprenant un substrat mesoporeux ou macroporeux et une couche microporeuse/mesoporeuse deposee dessus et membrane asymetrique Ceased WO2006034717A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US61372704P 2004-09-29 2004-09-29
DKPA200401483 2004-09-29
DKPA200401483 2004-09-29
US60/613,727 2004-09-29

Publications (1)

Publication Number Publication Date
WO2006034717A1 true WO2006034717A1 (fr) 2006-04-06

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Family Applications (1)

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PCT/DK2005/000620 Ceased WO2006034717A1 (fr) 2004-09-29 2005-09-29 Procede pour la preparation d'une membrane asymetrique comprenant un substrat mesoporeux ou macroporeux et une couche microporeuse/mesoporeuse deposee dessus et membrane asymetrique

Country Status (1)

Country Link
WO (1) WO2006034717A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008106028A1 (fr) * 2007-02-27 2008-09-04 Corning Incorporated Membranes inorganiques, et procédé de fabrication
WO2010002455A1 (fr) * 2008-07-03 2010-01-07 Millipore Corporation Membranes asymétriques poreuses
WO2010002462A1 (fr) * 2008-07-03 2010-01-07 Millipore Corporation Membranes asymétriques poreuses
US7669719B2 (en) 2006-07-05 2010-03-02 General Electric Company Membrane structure and method of making
US20100166815A1 (en) * 2007-07-23 2010-07-01 Sophie Mailley Method for Preparation of a Nanocomposite Material by Vapour Phase Chemical Deposition
WO2017075328A1 (fr) * 2015-10-30 2017-05-04 Corning Incorporated Filtres céramiques poreux et leurs procédés de fabrication
WO2018170460A1 (fr) * 2017-03-16 2018-09-20 University Of Maryland Membranes et procédés d'utilisation associés
CN113368538A (zh) * 2021-04-23 2021-09-10 厦门大学 沉积氧化铝纳米涂层的柔性铜网及其制备方法和应用
US11117124B2 (en) 2017-10-31 2021-09-14 Corning Incorporated Honeycomb body and particulate filter comprising a honeycomb body
US11161782B2 (en) 2017-11-30 2021-11-02 Corning Incorporated Method of increasing IOX processability on glass articles with multiple thicknesses
CN116099384A (zh) * 2023-02-16 2023-05-12 浙江理工大学 一种尖晶石纳米颗粒改性的陶瓷膜制备方法
US12290786B2 (en) 2018-12-14 2025-05-06 Entegris, Inc. Composite nanoporous metal membrane

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5447708A (en) * 1993-01-21 1995-09-05 Physical Sciences, Inc. Apparatus for producing nanoscale ceramic powders
US20040137209A1 (en) * 2002-12-12 2004-07-15 Robert Zeller Porous sintered composite materials

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5447708A (en) * 1993-01-21 1995-09-05 Physical Sciences, Inc. Apparatus for producing nanoscale ceramic powders
US20040137209A1 (en) * 2002-12-12 2004-07-15 Robert Zeller Porous sintered composite materials

Non-Patent Citations (7)

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Title
DANSK KEMI, vol. 84, no. 9, 2003, pages 28 - 31, ISSN: 0011-6335 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 22 April 2004 (2004-04-22), JOHANNESSEN, TUE ET AL: "Constructive aerosol technology - synthesis and use of nanostructured materials in aerosol form", XP002331262, retrieved from STN Database accession no. 140:290806 *
JENSEN J R ET AL: "A study of Cu/ZnO/Al2O3 methanol catalysts prepared by flame combustion synthesis", JOURNAL OF CATALYSIS, ACADEMIC PRESS, DULUTH, MN, US, vol. 218, no. 1, 15 August 2003 (2003-08-15), pages 67 - 77, XP004432695, ISSN: 0021-9517 *
MAJID MOSLEH., ET AL.: "Flame assisted synthesis of catalytic ceramic membranes", EIGHTH INTERNATIONAL CONFERENCE ON INORGANIC MEMBRANES, 19 July 2004 (2004-07-19), CINCINNATI, OHIO, USA, XP002331257, Retrieved from the Internet <URL:http://www.che.utoledo.edu/icim8/viewpaper.cfm?ID=731> [retrieved on 20050607] *
MOSLEH M. ET AL: "Product engineering by high-temperature flame synthesis", INTERNET ARTICLE, XP002331260, Retrieved from the Internet <URL:http://216.239.59.104/search?q=cache:qWEWE_6D_4gJ:www.dechema.de/granada/TOPIC%2520-%2520013/P-13-032.pdf+johannessen+mosleh+membrane+product+engineering+high+temperature+flame&hl=nl> [retrieved on 20050607] *
SUNE K. ANDERSEN, ET AL.: "The formation of porous membranes by filtration of aerosol nanoparticles", JOURNAL OF NANOPARTICLE RESEARCH, vol. 4, 2002, NETHERLANDS, pages 405 - 416, XP002331258 *
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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7669719B2 (en) 2006-07-05 2010-03-02 General Electric Company Membrane structure and method of making
US7919025B2 (en) 2006-07-05 2011-04-05 General Electric Company Membrane structure and method of making
WO2008106028A1 (fr) * 2007-02-27 2008-09-04 Corning Incorporated Membranes inorganiques, et procédé de fabrication
US8393478B2 (en) 2007-02-27 2013-03-12 Corning Incorporated Inorganic membranes and method of making
US20100166815A1 (en) * 2007-07-23 2010-07-01 Sophie Mailley Method for Preparation of a Nanocomposite Material by Vapour Phase Chemical Deposition
WO2010002455A1 (fr) * 2008-07-03 2010-01-07 Millipore Corporation Membranes asymétriques poreuses
WO2010002462A1 (fr) * 2008-07-03 2010-01-07 Millipore Corporation Membranes asymétriques poreuses
JP2018533471A (ja) * 2015-10-30 2018-11-15 コーニング インコーポレイテッド 多孔質セラミックフィルタ及びその製造方法
US11389769B2 (en) 2015-10-30 2022-07-19 Corning Incorported Porous ceramic filters and methods for making the same
WO2017075328A1 (fr) * 2015-10-30 2017-05-04 Corning Incorporated Filtres céramiques poreux et leurs procédés de fabrication
US11752469B2 (en) 2015-10-30 2023-09-12 Corning Incorporated Porous ceramic filters and methods for making the same
CN108290102A (zh) * 2015-10-30 2018-07-17 康宁股份有限公司 多孔陶瓷过滤器及其制造方法
WO2018170460A1 (fr) * 2017-03-16 2018-09-20 University Of Maryland Membranes et procédés d'utilisation associés
US10940444B2 (en) 2017-03-16 2021-03-09 University Of Maryland, College Park Membranes and methods of use thereof
US11458464B2 (en) 2017-10-31 2022-10-04 Corning Incorporated Honeycomb body and particulate filter comprising a honeycomb
US11117124B2 (en) 2017-10-31 2021-09-14 Corning Incorporated Honeycomb body and particulate filter comprising a honeycomb body
US11161782B2 (en) 2017-11-30 2021-11-02 Corning Incorporated Method of increasing IOX processability on glass articles with multiple thicknesses
US12290786B2 (en) 2018-12-14 2025-05-06 Entegris, Inc. Composite nanoporous metal membrane
CN113368538B (zh) * 2021-04-23 2022-06-21 厦门大学 沉积氧化铝纳米涂层的柔性铜网及其制备方法和应用
CN113368538A (zh) * 2021-04-23 2021-09-10 厦门大学 沉积氧化铝纳米涂层的柔性铜网及其制备方法和应用
CN116099384A (zh) * 2023-02-16 2023-05-12 浙江理工大学 一种尖晶石纳米颗粒改性的陶瓷膜制备方法

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