WO2006012800A1 - An apparatus for preparing oil from waste plastics in continuous and industrial production - Google Patents
An apparatus for preparing oil from waste plastics in continuous and industrial production Download PDFInfo
- Publication number
- WO2006012800A1 WO2006012800A1 PCT/CN2005/001195 CN2005001195W WO2006012800A1 WO 2006012800 A1 WO2006012800 A1 WO 2006012800A1 CN 2005001195 W CN2005001195 W CN 2005001195W WO 2006012800 A1 WO2006012800 A1 WO 2006012800A1
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- WO
- WIPO (PCT)
- Prior art keywords
- oil
- disposed
- dust removal
- outlet
- water
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/18—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/005—Coking (in order to produce liquid products mainly)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Definitions
- Waste plastic oiling device capable of continuous industrial mass production
- the present invention relates to a waste plastic oiling apparatus which can continuously produce industrially produced gasoline fractions, diesel fractions or high quality fuel oils and civil liquefied gases by catalytic or non-catalytic cracking using waste plastics or waste lubricating oils or heavy oils.
- the second high-temperature slagging equipment How to design a safe slagging equipment to discharge the suspended silt impurities generated during the melting and the coke generated by the reaction in the cracking reaction process, and also form the continuous production. Necessary conditions.
- the third reaction heating problem how to design a non-open flame heating reaction heating furnace, which can meet the requirements of improving flame temperature and radiation intensity, provide sufficient reaction heat, and must obey the flammable and explosive pressure vessel to prohibit open flame. Heating design specification requirements.
- the sixth design has equipment to ensure safe production measures. This mainly refers to how to ensure the high temperature continuous feeding and slagging in the process of flammable and explosive high temperature reaction, such as feeding back gas protection, slagging fire prevention and Extinguish, container overpressure protection, eliminate tempering, etc., hardware equipment and measures.
- Japan Fuji Recycling Company and POKODA Group Corporation Energy Materials Recycling Department are researching and developing waste plastic oiling technology.
- the first feature is that waste plastics are subject to careful sorting, washing and drying, extrusion molding, etc., and the processing steps are very complicated. It is huge; another feature is that melting and cracking are carried out separately, but the problem of solidification of molten plastic in the pump body and in the pipeline is not solved.
- Other companies are also vigorously conducting research and development, but they have not been able to form industrial-scale production facilities.
- an object of the present invention is to provide a waste plastic oiling apparatus which can be continuously industrially produced.
- a waste plastic oiling device capable of continuous industrial production comprising: a reaction kettle, a feeding device connected to the reaction vessel, and a heating device for reacting the reaction vessel a defocusing device disposed at the bottom of the reaction vessel, followed by a fractionation-strip-condensation cooling device, an oil-gas separation-gas absorption device, an oil extraction and refining device, and an oil-gas separation-gas after the reactor a liquefied gas recovery device drawn from the absorption device; characterized in that: it further comprises a three-waste treatment device having a flue gas dedusting and dust removal device and an oil-water separation device, wherein the flue gas de-blackening and dust removal device is connected to the flue gas of the reaction vessel heating device An oil-water separation device connected to the oil extraction and refining device; the feeding device includes a two-stage feeding device surrounded by a heating device, and the heating device of the reaction vessel is a non-open flame radiation
- the high temperature interlocking defocusing device comprises a first stage coke discharge tank and a second stage coke discharge tank connected to a first row of focus slide valves on the bottom defocused tube of the reaction kettle, connected to the first and second stage coke discharges a second sliding valve between the tanks and a third sliding valve connected under the secondary discharging tank, the three sliding valves interlocking the coke, the first-stage coke cans is provided with two rows of focal robots and one Focusing manipulator.
- the high-temperature interlocking defocusing device comprises three parallel-discharging and co-operating coke-discharging tanks, wherein one front decanting tank is disposed on the same axis as the defocused tube of the reaction kettle, and the other two of the coke-discharging tanks
- the central axis of the front decanting tank is disposed at an angle on the left and right sides, and the left and right rows of coke tanks are respectively inclined downwardly to the first-degree focal angle, and the three coke-discharging tanks respectively pass through a row of focal-slip valves
- a discharge tube of the reaction kettle is connected, and the three slide valves interlock with each other, and a discharge robot is disposed on each of the discharge tanks.
- the high-temperature interlocking defocusing device comprises two ashing reactors respectively connected to the bottom of the reactor and used for conversion, and a vaporization fractionation tower is respectively arranged on the top seal head of the two ashing reactors, and the fractionation
- the tower is filled with a filler, and the top of the branching tower is provided with a cooling water coil, and the bottoms of the two ashing reactors are respectively connected to a row of slag containers through a row of slag, and the two rows of slag containers are respectively arranged with cooling Water jacket.
- the two-stage feeding device comprises a hot-pressing and compacting roll device and a high-temperature sealing and feeding device, the hot-pressing and compacting roll device comprising a bucket elevator, and a flue gas jacketed furnace connected to the bucket elevator, a crawler type chain machine and a hot press hardening roll set in a jacketed furnace, a conveyor belt disposed under the hot pressurizing and thickening roll set, a cooling water spray head disposed above the conveyor belt, and a conveyor belt outlet a gantry file, a cooling pool disposed under the trowel and a squeegee chain machine disposed therein for conveying material to the high temperature sealing feeder.
- the hot-pressing and compacting roll device comprising a bucket elevator, and a flue gas jacketed furnace connected to the bucket elevator, a crawler type chain machine and a hot press hardening roll set in a jacketed furnace, a conveyor belt disposed under the hot pressurizing and thickening roll set, a cooling water spray head
- the high-temperature sealing feeding device comprises a hoist driven by a variable frequency speed regulating motor, a feeding inclined pipe connected between the hoist and a hopper with a mixer, and a sealed plastic melting feeding extrusion connecting the hopper
- the feeding extruder comprises a pusher screw driven by a variable frequency speed regulating motor and a screw barrel surrounding the pusher screw, and a heating flue gas jacket is arranged at an exit of the feeding extruder
- a feeding cylinder is vertically connected at the outlet of the feeding extruder, and a topping robot is disposed at the top of the feeding cylinder, and the bottom of the feeding cylinder is connected to the reaction vessel through a thermal expansion joint and a feeding valve.
- the two-stage feeding device is a two-stage feeding extruder, and the two-stage feeding extruder comprises a screw barrel, and one end of the two barrels is respectively mounted with a speed regulating motor, and the output of the two speed regulating motors a screw is respectively connected to the end, and the two screws are respectively provided with spiral blades, and electric heating devices are respectively arranged around the two screw barrels; a feeding hopper with a stirring and discharging machine is arranged at the inlet of the first feeding extruder.
- a catalyst hopper is disposed on an upper side of the hopper, an inlet of the secondary feeding extruder is located below the outlet of the primary feeding extruder, and an inlet of the secondary feeding extruder is provided with a double roller A hopper, an outlet of the secondary feeding extruder is connected to a feeding cylinder on a side of the top of the reactor.
- the non-open flame radiant heating device comprises a ring jacketed furnace disposed around the reaction vessel and a combustion furnace disposed at a lower portion of the reactor, a ring flame guide or six flame tubes communicating with the ring jacket furnace And a burning furnace, a flame-retardant plate is disposed on the burning furnace, and a flame-retardant hole is disposed on the flame-retardant plate, and a burner is disposed on each side of the burning furnace, the burning The fire exit of the device is inclined in the direction of the furnace wall, so that the flame that is ejected forms a swirling flame in the furnace.
- the flue gas dehumidification and dust removal device is a dust removal tower, a partition is arranged in the middle of the dust removal tower, the dust removal tower is divided into upper and lower sections, the upper part is sprayed with dust, and the lower part is water sealed and dusted, the dust removal tower a circulating water pump is disposed outside, and a recirculating water nozzle connected to the outlet of the circulating water pump is disposed in the dust removing tower, and a liquid flow pipe is disposed at a lowest point of the partition, and the flue gas inlet and outlet are respectively disposed on the dust removing tower In the lower stage, the outlet pipe at the top of the dust removal tower is connected to the water in the lower part of the dust removal tower, and the bottom of the dust removal tower is connected to the circulation water pump inlet through a filter.
- the oil-water separation device includes a grease trap and a water-oil separator, the grease trap is connected to a bottom outlet of the oil extraction and refining device, and the oil-water separator is connected to a water outlet of the grease trap through a water pump.
- the water outlet of the oil water separator is connected to the circulating water pump, and the oil drain of the grease trap and the oil water separator is connected Reactor.
- the utility model also comprises a plastic crusher arranged between the hot press compacting roll device and the high temperature sealing feeding device, before the reaction kettle is arranged, and the hot waste oil and the heavy oil are transported to the reaction kettle. Tubular furnace.
- the present invention has the following advantages due to the above technical solution: 1.
- the present invention adopts a two-stage feeding device, and a heating device is arranged around the two-stage feeding device, so that the waste plastic conveyed through the two-stage feeding device is Semi-melting or close to melting state, therefore, it can effectively prevent the unsafe phenomenon that the occasional high-temperature oil and gas in the reactor is backflowed back to the screw barrel and the hopper; at the same time, two sets of stirring blades connected in series are arranged in the reaction kettle.
- the reaction kettle is set to a negative pressure, which further prevents the back-flushing phenomenon occurring in the reaction kettle, and in particular, various types of interlocking slagging devices are arranged in the system, which effectively ensures the continuous large-scale operation of the present invention.
- Industrial production. 2 The invention provides a hot press compacting roll device in the two-stage feeding device, and a flue gas jacketed furnace, a chain machine, a roll set, a conveyor belt, a gantry file, and a cooling pool are arranged in the hot press compacting roll device.
- the chain machine in the pool so that it can be heated in the process of conveying the waste plastic in the chain machine, and is rolled by the hot-pressed and dense-rolled roll group to form a tightly pressed plastic belt, and the plastic belt can be
- the cooling water nozzle is used to cool down, and is cut into smaller plastic pieces by the gantry boring tool, and then sent to the next process through the chain machine in the cooling pool.
- the crusher can also cut the plastic into more. The fine particles effectively solve the problem of pre-treatment of waste plastics with a certain proportion of silt dust. 3.
- the invention provides a high-temperature sealing feeding device in the two-stage feeding device, and a flue gas jacket is arranged at the outlet end of the high-temperature sealing feeding device feeding extruder, and the waste plastic is plasticized or melted into the reaction by the flue gas heating.
- the kettle is arranged to reduce the blockage formed by the block material;
- the bucking manipulator is arranged on the upper part of the feeding cylinder, and the feeding block is blocked or not smooth by manual or automatic processing by the robot;
- an electronic monitor is arranged in the unloading inclined pipe, and is monitored with the regulator of the hoisting machine.
- the invention provides a two-stage feeding extruder in the two-stage feeding device, and the outlet of the first-stage extruder is arranged above the inlet of the second-stage extruder, so that the structure is simple and the operation and control are convenient. 5.
- the present invention is provided with a tubular heating furnace for preheating waste oil and heavy oil before the reaction vessel, so that the invention can be used for both waste plastic oiling and waste lubricating oil or heavy oil. It is a high-quality fuel or gasoline-diesel fraction that can be used in both catalytic cracking and non-catalytic cracking processes.
- the invention adopts a ring-shaped jacketed furnace which is arranged around the reaction vessel and a combustion furnace which is arranged in the lower part of the reaction vessel, and which has a large flow cross section, small resistance, and can ensure the negative pressure of the furnace, or six flame guides.
- the tube is connected to the annular jacketed furnace and the burning furnace.
- the invention has various interlocking and decoking devices, so that the flow dynamic operation of the reaction kettle can be effectively ensured, and the opening or closing of each sliding valve or the slag discharging valve is realized during the operation of the reaction kettle. Interlocking and decoking, especially in the coke cans, a twisting manipulator is installed, which can discharge various jams in time to ensure the smooth operation of the coke. 8.
- the invention also provides an ashing reaction kettle for conversion in the interlocking decoking device, further pulverizing the fluid state slag entering the ashing reaction kettle, making the waste plastic oil more thoroughly, and discharging the ash.
- the slag is a solid carbon black and can be used as a fuel.
- the present invention is provided with a flue gas dedusting and dust removing device including a dust removing tower and an oil-water separating device including a grease trap and a water-oil separator, so that the waste flue gas generated by the burning furnace can be sprayed and water-sealed and dust-removed. It is discharged into the environment to reduce environmental pollution. At the same time, the waste oil can be separated.
- the water After the water is purified, it can be used for the dust removal tower.
- the oil is returned to the reactor for further cracking, thus effectively solving the "three wastes" faced by the oilification equipment. solving issues.
- the present invention when the present invention is provided with an exhaust gas coke boiler, it is also possible to use the coke produced by the apparatus of the present invention and excess gas as fuel to produce steam or the like.
- Figure 1 is a schematic view of the system apparatus of the present invention
- FIG. 2 is a schematic view showing the structure of a waste plastic hot press compacting roll device of the present invention
- FIG. 3 is a schematic view showing the structure of the high temperature sealing feeding device of the present invention
- Figure 4 is a schematic view showing the structure of the flow dynamic reaction kettle and the non-open flame radiation heating furnace of the present invention.
- Figure 5 is a schematic view showing another structure of the flow dynamic reaction kettle and the non-open flame radiation heating furnace of the present invention.
- Figure 6 is a schematic view showing the structure of the high temperature interlocking defocusing device of the present invention.
- FIG 7 is another schematic structural view of the high temperature interlocking defocusing device of the present invention.
- Figure 8 is a schematic view showing the structure of the branching-striping-condensing cooling device of the present invention
- Figure 9 is a schematic view showing the structure of the oil-gas separation-gas absorption device of the present invention.
- Figure 10 is a schematic view showing the structure of the liquefied gas recovery device of the present invention.
- Figure 11 is a schematic view showing the structure of the oil extracting and refining device of the present invention
- Figure 12 is a schematic view showing the structure of the "three wastes" processing apparatus of the present invention.
- Figure 13 is another embodiment of the high temperature defocused device of the present invention.
- the waste plastics cracking device capable of continuously large-scale industrial production of the present invention comprises: a hot press compacting roll device 1, a high temperature sealed charging device 2, a flow dynamic reaction kettle device 3, and a non-open flame radiation heating device 4
- the high-temperature interlocking defocusing device 5 the fractionation-striping-condensation cooling device 6, the oil-gas separation-gas absorption device 7, the liquefied gas recovery device 8, the oil extraction and refining device 9, and the "three wastes" treatment device 10, and the like. The details are described separately below.
- the newly added hot-pressed compacting roll device 1 of the present invention includes a front set
- the bucket elevator 101 is connected to the bucket elevator 101 as a flue gas jacketed furnace 102.
- the jacketed furnace 102 is a sandwich oven composed of an inner and outer two-layer structure that provides heat from flue gas waste heat.
- the inner layer of the jacketed furnace 102 is provided with a motor-driven crawler type chain machine 103.
- the crawler belt on the chain machine 103 feeds the waste plastic fed from the bucket elevator 101 back into the hot press compacting roll set 104, and the jacketed furnace.
- the outer layer of the outer layer is provided with a flue gas jacketed furnace, and the waste plastic from the hot chain machine 103 is heated by the hot flue gas introduced from the flue gas inlet 105 to a softening temperature.
- the control thermocouple 106 disposed on the upper portion of the roll set 104 and the regulating valve 107 on the flue gas inlet 105 automatically control the plastic softening rolling temperature.
- the conveyor belt 108 disposed under the roll set 104 feeds the softened plastic strip rolled by the roll set 104 into a gantry cutter 109 mounted at the rear thereof, and is cut into small pieces, and a cooling water spray head is disposed above the conveyor belt 108.
- the softened plastic strip rolled out by the roll set 104 is cooled and hardened to facilitate cutting and preventing adhesion.
- the small piece of plastic cut from the file 109 falls into the cooling pool 111 at the lower part of the file 109.
- the cutting frequency of the file 109 can be adjusted according to the required size of the cutting block.
- the scraping type chain machine 112 disposed in the pool 111 can be cooled.
- the rear plastic piece is sent to the subsequent equipment on the shore of the pool 111, and the rotational speed of the chain machine 103 and the gap of the roll set 104 can be set to be adjustable and controllable.
- the high-temperature sealing and feeding device 2 of the present invention comprises a hoist 201 disposed at the front portion, which is driven by the variable frequency speed regulating motor 202, and can be controlled by the speed regulating motor 202 and the regulator 203.
- the blanking pipe 204 is connected to the hoist 201 and the hopper 205 with the mixer.
- the electronic monitor 206 is disposed in the middle of the blanking pipe 204 to monitor the smoothness of the blanking, and continuously feeds the monitored information into the regulator 203. Thereby, the feed amount of the hoisting machine 201 and the pushing speed of the unloading inclined pipe 204 are adjusted.
- a high temperature sealed plastic melt extruder 207 is disposed below the hopper 205.
- the feed extruder 207 includes a pusher screw 209 that is driven by the variable speed motor 208 and a barrel 210 that surrounds the pusher screw 209.
- the use of the variable frequency speed regulating motor 208 makes the pushing speed of the pushing material easier to control, and makes the feeding extruder 207 operate safely and reliably, which provides a guarantee for the automation of the feeding, and can prevent the occurrence of an accident or terminate the accident in time.
- the feeding extruder 207 is also characterized in that a flue gas jacket 211 is provided at the outlet thereof, and the waste plastic is plasticized or melted into the reaction vessel 301 by the flue gas heating.
- the charging cylinder 212 is vertically installed on the top sealing head of the reaction vessel 301, and is connected with a feeding extruder 207 and a reaction kettle 301.
- a charging robot 213 is disposed at the top of the charging cylinder 212, and a cutter 214 is disposed at the end of the robot 213 to prevent In case of plastic congestion at the bottom of the feeding cylinder, the dredging process is used.
- the thermal expansion joint 218 is disposed at a lower portion of the charging cylinder 212 to absorb the stress generated by the thermal expansion and contraction. This stress is due to the high temperature of the reaction vessel 301 during operation, and the reactor 301 is thermally expanded to extend upward by 10 to 30 mm, and the feeding extruder is fed.
- a monitoring alarm thermal element 215 is disposed in the middle of the feeding extruder 207.
- the alarm thermal element 215 immediately sends a signal to the regulator 216, the regulator 216 is adjusted and sent to the frequency converter motor 208 of the feeding extruder 207, automatically adjusting the pushing speed of the variable frequency motor 208, accelerating the pushing material to block the return air; Then, the feed valve 217 will be quickly closed, and the feed extruder 207 and the lifter 201 will be stopped by the signal.
- the monitoring the thermal element 215 sends a signal to the variable frequency motor 208, starts the feeding extruder 207 and the elevator 201, and then opens the feeding valve 217 to resume normal operation.
- the flow dynamic reactor device 3 of the present invention comprises a flow dynamic reaction vessel 301.
- the reactor 301 is provided with upper and lower two-stage stirring blades 302 and 303, a rectangular stirring blade 302 and a curved shape.
- the agitating paddles 303 are arranged in a crossover arrangement (the two are schematically drawn in one plane), and the vertical bearings between the upper and lower agitating paddles 302 and 303 are provided with vertical bearings, which are adjustable in centrality. Tie rod support. All the blades of the paddles 302, 303 are provided with a knife edge on both sides to break the coke block or the sintered plastic block in the liquid.
- An electric heating jacket furnace 404 is disposed around the reaction vessel 301 to provide heat required for the reaction; a vaporization-fractionator 306 is disposed on the top of the reactor head, and a cooling water coil 307 is disposed at the top of the reactor to provide internal reflux to generate the entire tower. Rectification.
- the tower is filled with a high efficiency Pall ring.
- the light component gasoline split or naphtha fraction
- the diesel portion is extracted from the side line of the middle of the tower, and the heavy heavy oil and heavy wax are fractionated and returned to the reaction vessel 301.
- the removal of light components ensures that the flash point of diesel or high quality fuel is acceptable, and the removal of heavy components and heavy wax ensures that the carbon residue and freezing point are acceptable.
- a defocused tube 304 with an anti-coking jacket is arranged, which can prevent the high temperature flue gas from burning the defocused tube, avoiding the coking of the heavy oil in the tube wall, and ensuring the smooth discharge path.
- the catalyst slurry feeding device 305 is disposed on the top of the reaction kettle 301.
- the lower isolation tank is equipped with a high temperature resistant glass plate level gauge to control the catalyst paddle addition speed.
- a foaming section 306 is arranged on the top of the reactor 301, and a grid support plate and a Pall ring are arranged in the foaming gasification section 306.
- the top of the vaporization section 306 is provided with a cooling water coil 307 for generating internal reflux and a light oil return pipe 308 for providing external reflux.
- the charging cylinder 212 disposed at the top of the reaction vessel 301 is installed at a 90° angle to the feed feeding extruder 207.
- the non-open flame radiation type heating device 4 of the present invention is disposed under the reaction vessel 301 and integrated with the reaction vessel 301.
- the utility model comprises a furnace skirt 401.
- a circular flame guiding sleeve 402 (as shown in FIG. 4) or six to eight flame guiding tubes 403 (shown in FIG. 5) are arranged around the skirt 401, and a ring around the reaction kettle 301 is arranged.
- the jacket furnace 404 and the combustion furnace 405 at the lower portion of the reactor 301 are in communication via a ring flame guide 402 or a flame tube 403.
- the heating device of the present invention is different from the conventional reaction combustion furnaces in that the flow section of the flame trap 402 or the flame guiding tube 403 is larger than twice the cross section of the jacketed furnace 404 around the reaction vessel 301. This reduces the flow resistance of the flue gas from the wide flow volume of the furnace and shortens the section, ensures the vacuum of the furnace and good combustion state, and prevents the furnace from generating positive pressure, which provides a guarantee for improving the furnace temperature.
- This design solves the problem that the flow path of the flame tube is small in the previous design, causing large resistance, low vacuum of the furnace, and even positive pressure combustion often occurs, the flame exits the furnace door, is unsafe, and limits the temperature increase of the furnace, so that the reaction is provided. Insufficient heat and other issues.
- a waveform thermal expansion joint 406 is disposed at the upper and lower ends of the flame shield 402 or the flame tube 403 (as shown in FIG. 4 and FIG. 5). Show), to absorb the thermal expansion stress, to ensure the normal operation of the furnace.
- This structure solves the problem that the expansion ring is seriously leaked in the previous design, the furnace vacuum is lowered, and the combustion is poor, which not only solves the problem of absorbing thermal expansion stress but also ensures the furnace sealing problem.
- a radiation obstruction plate 407 made of a high-radiation-resistant high-temperature (1000 ⁇ or higher) material is disposed on the combustion furnace 405, and a flame-retardant hole is disposed on the flame-retardant plate 407, and a flame-retardant hole is distributed on the flame-retardant plate 407.
- the plate 407 prevents the flame from directly contacting the reaction vessel 301, forming a non-open flame radiant heating mode.
- the design of the present invention is combined with the aforementioned large flame-conducting cross-section channel structure, which can not only allow a high furnace temperature, fully ensure the heat supply of the reactor, but also ensure the safe operation of the production, and fundamentally solve the flammability.
- the burner 408 used in the combustion furnace 405 is a mixed oil and gas type, and has the functions of automatic ignition, flame monitoring, flameout protection, etc., which are disposed on the lower part of the furnace and above the ash, and two burners are respectively disposed in the combustion furnace 405.
- the fire inlet is inclined in the direction of the furnace wall, so that the flame that is ejected forms a flame in the furnace, so that the heat of the flame trap 407 is more uniform.
- a flue gas outlet 409 is disposed at an upper portion of the reactor annular jacket furnace 404, and the derived flue gas can be removed from the jacketed furnace 102 of the hot press densification roll device 1 and the flue gas jacket 211 of the high temperature seal feeding device 2, and the like.
- the flue gas is finally sent to the "three wastes" treatment unit 10 for flue gas de-blackening treatment, and finally the water vapor, nitrogen and carbon dioxide are discharged from the chimney.
- the high temperature interlocking defocusing device 5 of the present invention is disposed on one side of the reaction vessel 301, and is composed of a primary coke discharge tank 501 and a secondary coke discharge tank 502.
- the first stage coke canister 501 and the reaction kettle 301 are connected by a jacketed discharge tube 304.
- a first discharge spool valve 503 is disposed on the exhaust pipe 304.
- a second spool valve 504 is disposed between the secondary coke cans 501, 502, and a third spool valve 505 is disposed below the secondary coke canister 502.
- the three valves 503, 504, and 505 operate in an interlocked state, that is, in the normal state, the spool valve 503 is normally open, and the spool valves 504 and 505 are normally closed.
- the interlocking coke removal procedure is as follows: In the first step, when a certain amount of coke paddle is deposited in the first-stage coke oven 501, the slide valve 503 is closed, and the connection with the reaction kettle 301 is cut off to ensure the safety of slag discharge.
- the valve is in the closed state; the second step, the slide valve 504 is opened, the coke residue in 501 is discharged into the secondary coke discharge tank 502, and in the third step, the slide valve 504 is closed, and the slide valve 505 is opened, the opening degree is 10 ⁇ 30 %, let it gradually drain the slag, fall into the slant bottom defocusing pool 506, and carry the condensed and cooled coke block in the water to the ground by a chain scraper (not shown).
- the above three steps of slagging are continuously repeated, and the coke generated in the reaction is continuously discharged to ensure continuous operation of the device.
- Three robots 507, 508, 509 are respectively disposed at the top and the side of the first-stage coke can 501, and the top ends of the robots 507, 509 are respectively provided with a sparse drill pipe having a trigeminal drill bit, and the robot 509 is directly connected to the exhaust pipe 304 and At the bottom of the reaction vessel 301, the robot 507 passes straight through the valve front of the spool 505. The bottom of the robot 508 is a disk to monitor the accumulation of the bottom of the primary coke 501.
- the robots 507, 508, and 509 can be controlled automatically or manually.
- the high-temperature interlocking defocusing device 5 of the present invention can also adopt a multi-head structure, which is different from the above-mentioned single-head interlocking defocusing device in that three sets of parallel decanting tanks 510 are provided. , 511, 512, available Run in conversion, flexible operation, increase the flow of defocused.
- the front decanting tank 510 is disposed on the same center line as the reaction vessel 301, and is connected to the defocused tube 305 through the defocused sliding 513.
- the horizontal dipstick 514 is disposed on the same axis of the decanter 510 and the defocused tube 305.
- the left and right side decanting tanks 511, 512 are disposed at a position horizontally at an angle of about 30° to the left and right of the central axis of the coke-discharging tank 510, and have the same structure as the coke-discharging tank 510, but the left and right sides of the coke-discharging tanks 511 and 512 are designed.
- the flow axis has a certain degree of flow coke, that is, the central axis of the defocusing tubes 514, 515 of the coke drums 511, 512 is inclined at an angle of 5 to 15 ° with the horizontal angle, which is favorable for the downward flow of the coke pad and prevents the coke from being discharged.
- the bottoms of the tubes 514, 515 are deposited.
- the fractionation-strip-condensation cooling device 6 of the present invention comprises a fractionation tower 601 with a flue gas jacket 602 as a heat source in the lower portion, and a grid support plate 603 is arranged in the lower portion of the fractionation tower 601, and supports A high efficiency Pall ring packing 604 is placed in the tower.
- the bottom of the tower is provided with a heavy diesel fuel collecting tank 605 and its extraction line side line 606, a light diesel oil collecting tank 607 and its extraction line side line 608, a kerosene fuel collecting tank 609 and its extraction side line 610.
- a gasoline return port 611 From the top of the tower to the bottom of the tower, there are a gasoline return port 611, a kerosene return port 612, a light diesel oil return port 613, a heavy diesel oil return port 614 and a heavy oil return port 615.
- the kerosene stripper 616, the light diesel stripper 617, and the heavy diesel stripper 618 are mounted on the same axis from top to bottom, and they are disposed on the side of the fractionation column 601.
- the condensing cooling water tank 619 is disposed on the lower side of the stripping towers 616, 617, and 618 so that each oil flow can automatically flow through the respective condensing cooling coils 620 to the next process by means of the difference.
- the cooling tower 621 is installed at the top of the water tank 619, and the circulating water pump 622 is installed on the bottom side of the water tank 619, and the hot water is pumped into the cooling tower 621, which is sprayed and cooled, and recycled.
- the oil-gas separation-gas absorption device 7 of the present invention comprises an oil-gas separation column 701, a primary gas absorption tower 702, a secondary gas absorption tower 703, and a water-sealing tank 704, etc., a secondary absorption tower.
- the 703 is filled with high efficiency Pall ring packing 705. 1.
- the secondary absorption tower removes the harmful components mixed in the reaction cracking gas, such as hydrogen chloride, hydrogen sulfide, etc., and sends it to the liquefied gas recovery unit 8.
- the liquefied gas (LPG) recovery unit 8 of the present invention includes a low pressure gas stabilizing tank 801, and a clean cracking gas introduction tank 801 sent from the unit 7 is sent to the primary compressor 802 after the pressure is stabilized. , compressed to 0.3 ⁇ 0.4Mpa, sent to the first-stage compression condensate tank 803, which is equipped with a condensing cooling coil 804, which condenses part of the heavier liquefied gas component into light gasoline recovery, and after de-heavy components
- the cracked gas is sent to the secondary compressor 805 to be compressed to 0.5 to 0.8 MPa, and then sent to the condensing cooler 806.
- the liquefied gas component is condensed into a liquid, that is, LPG, and then sent to the high pressure liquid gas separation tank 807, where In the 807 tank, LPG is separated from the dry gas (methyl hydrazine, ethane, ethylene component) which cannot be compressed and liquefied.
- LPG flows from the bottom of the tank into the high-pressure liquefied gas storage tank 808, and then through the bottled pump 809, and several bottled packing lines 810 The bottle is for sale for civilian use.
- Dry gas is sent from the top of the 807 tank to the high-pressure dry gas stabilization tank 811, and the water seal flame arrester 812 is sent to the furnace as a fuel for own use. If there is excess flare, it can be sent to the boiler 12 (if set) for fuel.
- a self-operated pressure self-control valve 813 is mounted on the torch vent line of the flame arrester 812, which controls the full system pressure.
- the oil extracting and refining device 9 of the present invention comprises a gasoline-light diesel oil extraction system. They are composed of A-extraction tanks 901, 902, B-extraction tanks 903, 904, and additive blending tanks 905, 906, and the like.
- the gas oil and crude gasoline produced from the cracking reactor and the branching tower cannot fully meet the quality requirements of the national standard and need to be refined.
- the gas oil is first sent to the A-extraction tank 801, the A agent is added, and the A-extraction purification process is carried out, the non-ideal components are removed, and then sent to the B-extraction tank 803, and the B-extractant is added to further remove the non-ideal components and then fed.
- the mixing tank 805 is added to the qualified product delivery device for sale according to the performance requirement and the necessary additives; the crude gasoline extraction and refining process is also the same.
- the "three wastes" processing device 10 of the present invention includes a flue gas de-blackening and dust removing device and a water-oil separating device.
- the flue gas de-blacking and dust removing device includes a dust removing tower 1001, and a circulating water pump 1004 is disposed outside the dust removing tower 1001.
- a set of recirculating water nozzles 1005 connected to the outlet of the circulating water pump 1004 is disposed in the dust removing tower 1001.
- a separator 1006 is arranged in the middle of the dust removal tower 1001, and the dust removal tower 1001 is divided into upper and lower sections, the upper section is sprayed with dust, and the lower section is water sealed and dusted.
- a liquid flow tube 1007 is disposed at the lowest point of the partition 1006, and the dust removal tower is disposed.
- the bottom of the 1001 is connected to a filter, and the outlet of the filter is connected to the inlet of the circulating water pump 1004.
- the flue gas inlet of the dust removing tower 1001 is connected to the flue gas outlet 409 of the non-open flame radiant heating device 4 through a pipeline, and the flue pipe at the top of the dust removing tower 1001 is connected to the stagnant water in the lower section of the dust removing tower 1001, so that the flue gas is in the stagnant water. After the water seal is further removed from the water, it is discharged from the flue gas outlet disposed in the lower stage of the dust removal tower 1001.
- the oil-water separation device includes a grease trap 1009 and a water separator.
- the grease trap 1009 is connected to the bottom of the oil extraction and refining device.
- the oil-water separator 1008 is disposed behind the grease trap 1009, and a pump 1010 is disposed therebetween.
- the water pump 1010 pumps the water separated from the grease trap 1009 to the oil-water separator 1008.
- the purified water treated by the oil-water separator 1008 is returned to the dust-removing tower 1001 by the circulating water pump 1004 for use in the dust-removing tower 1001, the grease trap 1009 and the oil-water tank.
- the oil separated by the separator 1008 is returned to the reaction vessel 301 to continue cracking.
- the hot press compacting roller device 1 and the high temperature sealing feeding device 2 may be changed, for example, the hot press compacting roll device 1 and the high temperature sealing and feeding device 2 are set to two stages.
- Feed extruders 220, 230, primary feed extruder 220 are located in front of secondary feed extruder 230.
- the two-stage feeding extruders 220 and 230 respectively include a screw barrel 221 and 231, and a speed regulating motor 222 and 232 are respectively installed at the ends of the two screw barrels 221 and 231, and the output ends of the two speed regulating motors 222 and 232 are respectively connected with a screw. 223, 233, the two screws 223, 233 are respectively provided with spiral blades (not shown).
- the screw 223 of the primary feeding extruder 220 may be a single screw or a relatively rotating twin screw.
- the two barrels 221 and 231 are respectively provided with self-controlled electric heating metal bath blocks or other electric heating devices for heating the barrels 221 and 231, and the lower parts of the two barrels 221 and 231 are provided with a firm bracket.
- the inlet of the first-stage feeding extruder 220 is provided with a hopper 224 with a stirring and discharging machine.
- the upper side of the charging hopper 224 is provided with a quantitatively-addable catalyst hopper 225, and the inlet of the secondary feeding extruder 230 is located at the first-stage feeding and extruding.
- the inlet of the secondary feeding extruder 230 is provided with a hopper 235 with a double roller 234, and the outlet of the secondary feeding extruder 230 is connected to the charging cylinder 212 on the top side of the reaction vessel 301.
- the waste plastic After being pulverized, the waste plastic is lifted into the hopper 224 of the primary feeding extruder 220, and proportionally The catalyst in the catalyst hopper 225 is fed into the hopper 224, mixed with the waste plastic into the primary feeding extruder 220, pushed vigorously forward by the screw 223, and heated by the electric heating device outside the screw 221 to the softening temperature.
- the outlet of the barrel 221 causes the waste plastic in a semi-molten state to fall into the hopper 235 through the double rollers 234 of the secondary feeding extruder 230, and is then extruded into the secondary feeding extruder 230, which is a waste plastic in a visco state.
- the outlet of the secondary feeding extruder 230 is extruded, and is introduced into the reaction vessel 301 through the charging cylinder 212 to carry out a cracking reaction.
- the electric heating device outside the two-stage feeding extruder 220, 230 barrels 221, 231 only heats up at the initial stage of startup, and after normal operation, the strong pushing force of the screws 223, 233 causes the extruded plastic to be extruded. It generates enough heat to soften automatically. At this time, the electric heating stops heating under the control of the control system.
- the waste plastic extruded from the secondary feeding extruder 230 is in a semi-melting or near-melting state, and can effectively prevent the unsafe phenomenon that the occasional temperature and oil in the reactor 301 is countercurrently returned to the screw barrel 231 and the hopper 235. .
- the reaction kettle 301 is operated by micro-negative pressure, which can effectively avoid the occurrence of high-temperature oil and gas back-flux.
- the structure of the high temperature interlocking defocusing device 5 can be various.
- the slag discharging pipes 304 disposed at the bottom of the reaction kettle 301 are two, and the outlets of the two oil discharging slag pipes 304 are respectively connected to one.
- the ashing reactors 521 and 522 are provided with heating means around the ashing reactors 521 and 522.
- the pyrolysis oil and coke discharged from the bottom of the reactor 301 into the two ashing reactors 521 and 522 are further cracked to form oil vapor and Ash residue.
- the oil vapor generated in the two ashing reactors 521, 522 rises to the vaporization fractionation columns 523, 524 disposed on one side of the top seal head, the tower is filled with a high efficiency Pall ring packing, and the top of the tower is provided with a cooling water coil 525. 526, used to generate internal reflux.
- the light sputum oil gasoline fraction
- the middle part of the oil is extracted from the middle (diesel part)
- the heavy oil and heavy wax are returned to the reactor for cracking.
- the final residue formed by secondary cracking in the two ashing reactors 521, 522 is ash, discharged into the slag discharge containers 529, 530 through the bottom slag discharge valves 527, 528, and cooled by the surrounding cooling water jackets 531, 532. Thereafter, the system is discharged from the ash discharge valves 533, 534 and carried away by the trolley.
- the two ashing reactors 521, 522 are used in turn, one operation, and the other can discharge coke.
- the number of each of the decanting tanks (or ashing reactors) and the defocusing valves of the high-temperature interlocking defocusing device 5 can be changed, for example, the number of the coke-removing tanks is 2 to 4, The number of focal lengths is 2 to 8.
- the "three wastes" treatment device 10 can also adopt various flue gas and oil-water separation devices in the prior art, even if the de-blackening and dust removal device and the oil-water separation device of the present invention are used, the dust removal tower 1001, the grease trap 1009 and the oil-water separator In addition to 1008, it is also possible to add a replacement to other structures and devices.
- the waste plastic is removed from mud sand, masonry, cotton cloth, wood, iron filings, etc., as shown in FIG. 1 and FIG. 2, it is firstly crushed and sent to the bucket elevator 101 installed at the foremost part, and then The crawler type chain machine 103 and the roll set 104 surrounded by the flue gas waste jacketed furnace 102 are hot-rolled into plastic strips, and the waste plastics are densified by a packing density of less than 0.1 t/m 3 through the cooling head 110 and the boring tool 109. Become a small piece of plastic of 0.5 ⁇ 1.2t/m 3 . It is also possible to feed the crusher 11 (shown in Fig.
- the apparatus of the present invention simultaneously processes waste oil or heavy oil, the tubular heating furnace 12 for preheating the waste oil and the heavy oil is placed before the reaction vessel 301, so that the waste plastic and the waste oil can be separately entered separately.
- the reaction vessel 301 can also be mixed into the reaction vessel 301 while being mixed in any ratio, and cracked into various light fuel oils or gasoline diesel oil.
- the oil and gas mixture generated by the reaction kettle 301 is introduced into the fractionation column 601 (shown in Figs. 1, 8) from the top, and the gasoline and gas are discharged from the top of the column 601, and the kerosene is extracted from the side line of the tower, light and heavy.
- Diesel, light and heavy diesel oil is liquid phase inflow into kerosene, light and heavy diesel stripper 616, 617, 618 stripping, kerosene and light diesel oil combined and heavy diesel oil flow through condensing cooling water tank 619 to cool.
- the gasoline vapor and gas at the top of the fractionation column 601 are cooled by the condensing cooling water tank 619, and then flowed into the oil-gas separation column 701 (as shown in Figs. 1 and 9), and the gasoline is refluxed into the fractionation column 601 to control the temperature at the top of the column to control the quality of the gasoline.
- the separated crude gasoline is fed into the extraction refining device 9; the gas is introduced into the liquefied gas recovery device 8 (shown in Figs.
- the accumulated water at the bottom of the dust removal tower 1001 is filtered and sent to the circulating water pump 1004 for further use, and the carbon black in the filter can be used as a fuel.
- the water After the oil and water separation from the bottom outlet of the oil extraction and refining device 9 into the grease trap 1009, the water enters the oil water separator 1008, and the water from the oil water separator 1008 is sent to the circulating water pump 1004 for further use, and is separated from the grease trap 1009 and the oil water.
- the oil separated by the vessel 1008 is returned to the reactor 301 to continue cracking.
- the present invention may select all or part of the apparatus of the system of the present invention as needed, and may add some means to the system of the present invention, such as providing an exhaust gas coke breeze 13 with coke and excess gas produced by the apparatus of the present invention. Fuel, steam production, etc.
- the invention utilizes waste plastic or waste lubricating oil or heavy oil, etc., and can continuously industrialize large-scale production of gasoline fraction, diesel oil or high quality fuel oil and civil liquefied gas.
- the "three wastes" treatment device is arranged in the equipment, so that the exhaust gas, the waste oil and the waste water of the invention are treated, the exhaust gas discharged to the environment is minimized, the waste water is recycled, and the separated oil is returned to the reactor for cracking. .
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Abstract
Description
可连续工业化大规模生产的废塑料油化裝置 技术领域 Waste plastic oiling device capable of continuous industrial mass production
本发明涉及一种利用废塑料或废润滑油或重质油等通过催化或非催化裂解生 产汽油馏分、 柴油馏分或高质燃油及民用液化气的可连续工业化生产的废塑料油化 装置。 The present invention relates to a waste plastic oiling apparatus which can continuously produce industrially produced gasoline fractions, diesel fractions or high quality fuel oils and civil liquefied gases by catalytic or non-catalytic cracking using waste plastics or waste lubricating oils or heavy oils.
背景技术 Background technique
国内外有关废塑料油化技术的研究与开发已有二十多年的历史, 其分为催化与 非催化裂解两大类。 但是要形成大规模连续化工业生产时, 都遇到了同样困难的工 艺及设备问题。 直到目前, 国内外仍较少有连续化、 长周期运行的大规模工业生产 装置投产。 遇到的主要工艺设备问题有六种: 第一高温加料设备: 如何设计出一套 完备的加料设备能在裂解高温下, 易燃易爆的气氛中, 将夹带着一定比例泥沙尘土 和水份的废塑料加入反应釜中, 是连续化生产遇到的首要设备问题。 第二高温排渣 设备: 如何设计出一套安全的排渣设备能在裂解反应过程中, 将熔化时产生的悬浮 的泥砂杂质和反应产生的焦渣及时排出反应釜, 也是形成连续化生产的必要条件。 第三反应供热问题, 如何设计出一套非明火加热的反应加热炉, 它既能满足提高火 焰温度和辐射强度的要求, 提供足够的反应热, 又必须服从易燃易爆压力容器禁止 明火加热的设计规范要求。 第四设计出一套有效的裂解油的精制处理设备, 对产物 进行脱色、 除臭、 安定, 使之全部质量指标达到国标要求。 第五工艺过程中不可避 免地会产生废气、 废水、 废渣, 如何设计出一套有效的二次污染处理设备, 将它们 处理消灭在装置内部, 也是装置能否生存的重要工艺及设备问题。 第六设计有保证 安全生产措施的设备, 这主要是指在易燃易爆的高温反应过程中, 如何保证高温连 续加料和排渣的绝对安全可靠, 如加料返气保护、 排渣失火预防及扑灭、 容器超压 保护、 杜绝回火等, 硬件设备及措施。 At home and abroad, the research and development of waste plastics oil technology has been more than 20 years old, and it is divided into two major categories: catalytic and non-catalytic cracking. However, in the case of large-scale continuous industrial production, the same difficult process and equipment problems were encountered. Until now, there have been few large-scale industrial production facilities with continuous and long-term operation at home and abroad. There are six main process equipment problems encountered: The first high-temperature feeding equipment: How to design a complete feeding equipment that can clamp a certain proportion of silt dust and water in a flammable and explosive atmosphere under cracking high temperature. The addition of waste plastics to the reactor is a primary equipment problem encountered in continuous production. The second high-temperature slagging equipment: How to design a safe slagging equipment to discharge the suspended silt impurities generated during the melting and the coke generated by the reaction in the cracking reaction process, and also form the continuous production. Necessary conditions. The third reaction heating problem, how to design a non-open flame heating reaction heating furnace, which can meet the requirements of improving flame temperature and radiation intensity, provide sufficient reaction heat, and must obey the flammable and explosive pressure vessel to prohibit open flame. Heating design specification requirements. The fourth design of an effective refining treatment equipment for pyrolysis oil, decolorization, deodorization and stability of the product, so that all the quality indicators meet the national standard requirements. In the fifth process, waste gas, waste water and waste residue are inevitably generated. How to design an effective secondary pollution treatment equipment and destroy them in the interior of the device is also an important process and equipment problem for the survival of the device. The sixth design has equipment to ensure safe production measures. This mainly refers to how to ensure the high temperature continuous feeding and slagging in the process of flammable and explosive high temperature reaction, such as feeding back gas protection, slagging fire prevention and Extinguish, container overpressure protection, eliminate tempering, etc., hardware equipment and measures.
目前, 日本富士回收公司和 POKODA集团公司能源物资再生部等正在研究开 发废塑料油化技术, 其特点一是废塑料要经过仔细分选、 水洗烘干、 挤塑成形等, 而处理工序十分复杂庞大; 另一特点是熔化与裂解分别进行, 但熔化塑料在泵体内 和管线中输送时的凝固等问题, 并没有得到解决。 还有一些公司也正在大力开展研 究开发, 但均未能形成工业规模的生产装置。 At present, Japan Fuji Recycling Company and POKODA Group Corporation Energy Materials Recycling Department are researching and developing waste plastic oiling technology. The first feature is that waste plastics are subject to careful sorting, washing and drying, extrusion molding, etc., and the processing steps are very complicated. It is huge; another feature is that melting and cracking are carried out separately, but the problem of solidification of molten plastic in the pump body and in the pipeline is not solved. Other companies are also vigorously conducting research and development, but they have not been able to form industrial-scale production facilities.
美国曾有肯塔基大学米迪,塔格希艾 (Mehdi Taghiei ) 教授为首的研究开发 小组, 从事过不少研究, 取得了实验研究成果, 肯定了废塑料经裂解可制得高质燃 油的理论和实验的可行性。 但是他们是用加氢催化的方法, 工艺十分复杂。 In the United States, there was a research and development team led by Professor Mehdi Taghiei of the University of Kentucky. He has done a lot of research and obtained experimental research results. He affirmed the theory that high-quality fuel can be produced by cracking waste plastics. The feasibility of the experiment. But they use hydrogenation catalysis, the process is very complicated.
英国 BP公司及欧共体 5家石油公司,曾于 1993年在苏格兰扑兰奇矛斯炼油厂 建了一套处理能力为 100kg/h的小型试验装置, 这是一套流化床砂子炉的高温裂解 装置。它是将洗净粉碎的废塑料细小碎片喷射到 400〜900°C高温的砂子流化床反应 釜内, 裂解为以乙烯、 丙烯为主的烃类混合物。 乙烯、 丙烯经精密分熘及处理后将 可作为聚乙烯、 聚丙烯单体。 但时至今日, 并无大规模工业装置投产。 British BP and five European oil companies, in 1993 in the Scotland Ranchimouth refinery A small test unit with a processing capacity of 100 kg/h was built. This is a high temperature cracking unit for a fluidized bed sand furnace. It sprays the finely divided pieces of washed and pulverized waste plastic into a sand fluidized bed reactor at a high temperature of 400 to 900 ° C, and is cracked into a hydrocarbon mixture mainly composed of ethylene and propylene. Ethylene and propylene can be used as polyethylene and polypropylene monomers after precise separation and treatment. However, to date, no large-scale industrial installations have been put into production.
国内情况, 土炼油釜式裂解小反应炉很多, 多数无法实现连续化操作, 不能实 现髙温连续加料, 更无法高温排渣, 而是一釜一釜地进行; 其油产品色深、臭味大、 性质不稳定, 质量达不到国家标准; 二次污染较为严重, 废水废渣废气随地排放; 生产安全, 人身安全缺乏得力措施, 没有保障。 Domestically, there are many small reactors for soil refining tank type cracking. Most of them cannot realize continuous operation, and it is impossible to achieve continuous feeding of enthalpy temperature, and it is not possible to discharge slag at high temperature, but it is carried out in one pot and one pot; the color and odor of oil products are Large, unstable nature, the quality does not meet national standards; secondary pollution is more serious, waste water waste slag emissions are discharged anywhere; production safety, lack of effective measures for personal safety, no guarantee.
发明公开 Invention disclosure
针对上述各种问题, 本发明的目的是提供一种可连续工业化生产的废塑料油化 装置。 In view of the above various problems, an object of the present invention is to provide a waste plastic oiling apparatus which can be continuously industrially produced.
为实现上述目的, 本发明采取以下技术方案: 一种可连续工业化生产的废塑料 油化装置, 它包括: 反应釜, 连接所述反应釜的进料装置, 供所述反应釜反应的加 热装置, 设置在所述反应釜底部的排焦装置, 依次连接在所述反应釜之后的分馏- 汽提-冷凝冷却装置, 油气分离-气体吸收装置, 油品萃取精制装置, 以及由油气分 离 -气体吸收装置引出的液化气回收装置;其特征在于: 它还包括具有烟气脱黑除尘 装置和油水分离装置的三废处理装置, 所述烟气脱黑除尘装置连接所述反应釜加热 装置的烟气出口, 所述油水分离装置连接所述油品萃取精制装置; 所述进料装置包 括包围有加热装置的两级加料装置, 所述反应釜的加热装置为非明火辐射式加热装 置, 所述排焦装置由 2〜4台排焦罐和 2~8个互锁的排焦滑阀组成。 In order to achieve the above object, the present invention adopts the following technical solutions: A waste plastic oiling device capable of continuous industrial production, comprising: a reaction kettle, a feeding device connected to the reaction vessel, and a heating device for reacting the reaction vessel a defocusing device disposed at the bottom of the reaction vessel, followed by a fractionation-strip-condensation cooling device, an oil-gas separation-gas absorption device, an oil extraction and refining device, and an oil-gas separation-gas after the reactor a liquefied gas recovery device drawn from the absorption device; characterized in that: it further comprises a three-waste treatment device having a flue gas dedusting and dust removal device and an oil-water separation device, wherein the flue gas de-blackening and dust removal device is connected to the flue gas of the reaction vessel heating device An oil-water separation device connected to the oil extraction and refining device; the feeding device includes a two-stage feeding device surrounded by a heating device, and the heating device of the reaction vessel is a non-open flame radiation heating device, the row The coke device consists of 2 to 4 coke drums and 2 to 8 interlocking coke slide valves.
所述高温互锁排焦装置包括与所述反应釜底部排焦管上的第一排焦滑阀连接 的一级排焦罐和二级排焦罐, 连接在所述一、 二级排焦罐之间的第二滑阀和连接在 二级排焦罐下面的第三滑阀, 所述三个滑阀互锁排焦, 所述一级排焦罐上设置有两 排焦机械手和一探焦机械手。 The high temperature interlocking defocusing device comprises a first stage coke discharge tank and a second stage coke discharge tank connected to a first row of focus slide valves on the bottom defocused tube of the reaction kettle, connected to the first and second stage coke discharges a second sliding valve between the tanks and a third sliding valve connected under the secondary discharging tank, the three sliding valves interlocking the coke, the first-stage coke cans is provided with two rows of focal robots and one Focusing manipulator.
所述高温互锁排焦装置包括三台并联且转换运行的排焦罐, 其中一正面排焦罐 设置在与所述反应釜的排焦管同一轴线上, 另两所述排焦罐与所述正面排焦罐的中 心轴线呈一角度设置在左、右两侧,且所述左右两排焦罐分别向下倾斜一流焦斜度, 所述三台排焦罐分别通过一排焦滑阀连接所述反应釜的排焦管, 且所述三个滑阀互 锁排焦, 所述每一排焦罐上设置有一排焦机械手。 The high-temperature interlocking defocusing device comprises three parallel-discharging and co-operating coke-discharging tanks, wherein one front decanting tank is disposed on the same axis as the defocused tube of the reaction kettle, and the other two of the coke-discharging tanks The central axis of the front decanting tank is disposed at an angle on the left and right sides, and the left and right rows of coke tanks are respectively inclined downwardly to the first-degree focal angle, and the three coke-discharging tanks respectively pass through a row of focal-slip valves A discharge tube of the reaction kettle is connected, and the three slide valves interlock with each other, and a discharge robot is disposed on each of the discharge tanks.
所述高温互锁排焦装置包括两台分别连接在所述反应釜底部且转换使用的灰 化反应釜, 所述两灰化反应釜的顶封头上分别设置一汽化分馏塔, 所述分馏塔内装 填有填料, 所述分镏塔顶设置有冷却水盘管, 所述两灰化反应釜底部分别通过一排 渣阔连接一排渣容器, 所述两排渣容器分别周围设置有冷却水套。 所述两级加料装置包括热压增密轧辊装置和高温密封加料装置, 所述热压增密 轧辊装置包括斗式提升机, 与斗式提升机连接的烟气夹套炉, 设置在所述夹套炉内 的履带式链条机及热压增密轧辊组, 设置在所述热压增密轧辊组下面的输送带, 设 置在所述输送带上方的冷却水喷头和设置所述输送带出口的龙门铡刀, 设置在所述 铡刀下方的冷却水池及设置在其内的向所述高温密封加料装置输送物料的刮板式 链条机。 The high-temperature interlocking defocusing device comprises two ashing reactors respectively connected to the bottom of the reactor and used for conversion, and a vaporization fractionation tower is respectively arranged on the top seal head of the two ashing reactors, and the fractionation The tower is filled with a filler, and the top of the branching tower is provided with a cooling water coil, and the bottoms of the two ashing reactors are respectively connected to a row of slag containers through a row of slag, and the two rows of slag containers are respectively arranged with cooling Water jacket. The two-stage feeding device comprises a hot-pressing and compacting roll device and a high-temperature sealing and feeding device, the hot-pressing and compacting roll device comprising a bucket elevator, and a flue gas jacketed furnace connected to the bucket elevator, a crawler type chain machine and a hot press hardening roll set in a jacketed furnace, a conveyor belt disposed under the hot pressurizing and thickening roll set, a cooling water spray head disposed above the conveyor belt, and a conveyor belt outlet a gantry file, a cooling pool disposed under the trowel and a squeegee chain machine disposed therein for conveying material to the high temperature sealing feeder.
所述高温密封加料装置包括由变频调速电机带动的提升机, 连接在所述提升机 和带搅拌机的加料斗之间的下料斜管, 连接所述加料斗的密封塑熔式加料挤出机, 所述加料挤出机包括由变频调速电机带动的推料螺杆和环绕在所述推料螺杆周围 的螺筒, 在所述加料挤出机的出口处设置有加热用烟气夹套, 在所述加料挤出机的 出口处垂向连接一加料筒, 所述加料筒的顶部设置有一捅料机械手, 所述加料筒的 底部通过热膨胀节和加料阀门连接所述反应釜。 The high-temperature sealing feeding device comprises a hoist driven by a variable frequency speed regulating motor, a feeding inclined pipe connected between the hoist and a hopper with a mixer, and a sealed plastic melting feeding extrusion connecting the hopper The feeding extruder comprises a pusher screw driven by a variable frequency speed regulating motor and a screw barrel surrounding the pusher screw, and a heating flue gas jacket is arranged at an exit of the feeding extruder A feeding cylinder is vertically connected at the outlet of the feeding extruder, and a topping robot is disposed at the top of the feeding cylinder, and the bottom of the feeding cylinder is connected to the reaction vessel through a thermal expansion joint and a feeding valve.
所述两级加料装置为两级加料挤出机, 所述两级加料挤出机分别包括一螺筒, 所述两螺筒的一端分别安装一调速电机, 所述两调速电机的输出端分别连接一螺 杆, 所述两螺杆上分别设置有螺旋叶片, 所述两螺筒周围分别设置有电加热装置; 所述一级加料挤出机的进口设置一带搅拌拨料机的加料斗, 所述加料斗上方一侧设 置一催化剂料斗, 所述二级加料挤出机的进口位于所述一级加料挤出机出口下方, 所述二级加料挤出机的进口设置一带双滚轮的加料斗, 所述二级加料挤出机的出口 连接所述反应釜顶封头一侧的加料筒。 The two-stage feeding device is a two-stage feeding extruder, and the two-stage feeding extruder comprises a screw barrel, and one end of the two barrels is respectively mounted with a speed regulating motor, and the output of the two speed regulating motors a screw is respectively connected to the end, and the two screws are respectively provided with spiral blades, and electric heating devices are respectively arranged around the two screw barrels; a feeding hopper with a stirring and discharging machine is arranged at the inlet of the first feeding extruder. a catalyst hopper is disposed on an upper side of the hopper, an inlet of the secondary feeding extruder is located below the outlet of the primary feeding extruder, and an inlet of the secondary feeding extruder is provided with a double roller A hopper, an outlet of the secondary feeding extruder is connected to a feeding cylinder on a side of the top of the reactor.
所述非明火辐射式加热装置包括设置在所述反应釜周围的环形夹套炉和设置 在所述反应釜下部的燃烧炉, 一环形导焰套或六条导焰管连通所述环形夹套炉和燃 烧炉, 在所述燃烧炉上设置了一层阻焰板, 且所述阻焰板上分布有一种阻焰小孔, 在所述燃烧炉的两侧分别设置一燃烧器, 所述燃烧器的出火口沿炉壁方向倾斜, 使 喷出的火焰在炉膛内形成旋焰。 The non-open flame radiant heating device comprises a ring jacketed furnace disposed around the reaction vessel and a combustion furnace disposed at a lower portion of the reactor, a ring flame guide or six flame tubes communicating with the ring jacket furnace And a burning furnace, a flame-retardant plate is disposed on the burning furnace, and a flame-retardant hole is disposed on the flame-retardant plate, and a burner is disposed on each side of the burning furnace, the burning The fire exit of the device is inclined in the direction of the furnace wall, so that the flame that is ejected forms a swirling flame in the furnace.
所述烟气脱黑除尘装置为一除尘塔, 所述除尘塔中段设置有一隔板, 将所述除 尘塔分成上下两段, 上段为喷啉除尘, 下段为水封除尘吸收, 所述除尘塔外设置有 循环水泵, 所述除尘塔内设置连接所述循环水泵出口的回流水喷头, 所述隔板最低 点设置有液流管, 所述烟气进、 出口分别设置在所述除尘塔上、 下段, 所述除尘塔 顶部的出烟管连接至所述除尘塔下段的积水内, 所述除尘塔底部通过一过滤器连接 所述循环水泵进口。 The flue gas dehumidification and dust removal device is a dust removal tower, a partition is arranged in the middle of the dust removal tower, the dust removal tower is divided into upper and lower sections, the upper part is sprayed with dust, and the lower part is water sealed and dusted, the dust removal tower a circulating water pump is disposed outside, and a recirculating water nozzle connected to the outlet of the circulating water pump is disposed in the dust removing tower, and a liquid flow pipe is disposed at a lowest point of the partition, and the flue gas inlet and outlet are respectively disposed on the dust removing tower In the lower stage, the outlet pipe at the top of the dust removal tower is connected to the water in the lower part of the dust removal tower, and the bottom of the dust removal tower is connected to the circulation water pump inlet through a filter.
所述油水分离装置包括隔油池和油水分离器, 所述隔油池连接所述油品萃取精 制装置底部出口, 所述油水分离器通过一抽水泵连接所述隔油池的出水口, 所述油 水分离器的出水口连接所述循环水泵, 所述隔油池和油水分离器的出油口连接所述 反应釜。 The oil-water separation device includes a grease trap and a water-oil separator, the grease trap is connected to a bottom outlet of the oil extraction and refining device, and the oil-water separator is connected to a water outlet of the grease trap through a water pump. The water outlet of the oil water separator is connected to the circulating water pump, and the oil drain of the grease trap and the oil water separator is connected Reactor.
它还包括一设置在所述热压增密轧辊装置与高温密封加料装置之间的塑料破 碎机, 一设置在所述反应釜之前、 且向所述反应釜输送热废油和重质油的管式加热 炉。 The utility model also comprises a plastic crusher arranged between the hot press compacting roll device and the high temperature sealing feeding device, before the reaction kettle is arranged, and the hot waste oil and the heavy oil are transported to the reaction kettle. Tubular furnace.
本发明由于采取以上技术方案, 其具有以下优点: 1、 本发明由于采用两级加 料装置, 且在两级进料装置的周围设置加热装置, 因此使通过两级加料装置输送出 的废塑料呈半融化或接近融化状态, 因此可以有效地防止反应釜内偶尔产生的高温 油气逆流返冲回螺筒和料斗的不安全现象发生; 同时在反应釜内设置了串连连接的 两组搅拌桨, 且使反应釜呈为负压设置, 进一步防止了反应釜中发生的返冲现象发 生, 特别是在系统中设置了各种类型的互锁排渣装置, 有效的保证了本发明连续化 大规模工业生产。 2、 本发明在两级加料装置中设置了热压增密轧辊装置, 并在热 压增密轧辊装置中设置了烟气夹套炉、 链条机、 轧辊组、 输送带、 龙门铡刀、 冷却 水池和在水池中的链条机, 因此可以在链条机传送废塑料的过程中对其加热, 并经 热压增密轧辊组的碾压, 形成一条被压轧紧密的塑料带, 同时塑料带又可以在输送 带出口通过冷却水喷头降温, 并被龙门铡刀切成较规格的塑料小块, 然后通过冷却 水池中的链条机送到下道工序, 特别是设置了破碎机还可以将塑料切成更细小的颗 粒, 有效地解决了带有一定比例泥沙尘土的废塑料的前期处理的问题。 3、 本发明 在两级加料装置中设置了高温密封加料装置, 并在高温密封加料装置加料挤出机出 口端设置了烟气夹套, 通过烟气加热使废塑料被塑化或熔化进入反应釜, 减少块状 物料形成的堵塞; 在加料筒上部设置捅料机械手, 通过机械手人工或自动处理加料 堵塞或不畅; 在下料斜管中设置电子监测仪, 与提升机的调节器配合监视并调节下 料流动状态;在加料挤出机螺筒内设置返气热敏报警元件,随时发讯关闭加料滑阀, 防止返气发生; 在加料筒下部设置热膨胀节, 以吸收热胀冷缩所产生的应力, 减轻 对反应釜热负荷的影响, 以上各项措施使高温密封加料更安全更可靠更可连续化地 运行。 4、 本发明在两级加料装置中设置了两级加料挤压机, 并将第一级挤出机的 出口设置在第二级挤出机的进口上方, 使结构简单, 操作控制方便。 5、 本发明由 于在反应釜之前设置了一预热废油和重质油的管式加热炉, 因此, 本发明既可用于 废塑料油化、 又可用于废润滑油或重质油的轻质油化, 生产高质燃油或汽油柴油馏 分, 而且既可用于催化裂解过程, 又可用于非催化裂解过程。 6、 本发明由于采用 了设置了围绕反应釜的环形夹套炉和设置在反应釜下部的燃烧炉, 且通过流动截面 大、阻力小、能保证炉膛负压的环形导焰套或六条导焰管连通环形夹套炉和燃烧炉, 同时通过在燃烧炉内设置阻焰板, 在阻焰板上设置均勾分布的阻焰小孔, 因此实现 了对反应釜进行非明火辐射式的均匀加热方式, 不但提高了加热效率, 而且减少了 反应釜底部的结焦。 7、 本发明由于设置了各种互锁排焦装置, 因此, 可以有效地 保证反应釜的流动态操作,在反应釜的运行过程中,通过各个滑阀或排渣阀的开启、 关闭, 实现互锁排焦, 特别是在各排焦罐上设置了绞焦机械手, 可以及时排出各种 堵塞情况, 保证排焦的顺利进行。 8、 本发明还在互锁排焦装置中设置了转换使用 的灰化反应釜, 使进入灰化反应釜的流态油渣进一步裂解反应, 使废塑料油化更加 彻底, 而且使排出的灰渣为固体状碳黑, 可以用作燃料。 9、 本发明由于设置了一 包括除尘塔的烟气脱黑除尘装置和包括隔油池和油水分离器的油水分离装置, 因此 可以将燃烧炉产生的废烟气进行喷淋和水封除尘后再排入环境中, 降低了环境污 染, 同时可以将废油水分离, 将水净化后继续供除尘塔使用, 将油返回反应釜继续 裂解, 从而有效地解决了这个油化设备面临的 "三废"处理问题。 特别是当本发明 增加设置了废气焦渣锅炉, 还可以用本发明装置产出的焦渣和多余的瓦斯为燃料, 生产蒸汽等。 The present invention has the following advantages due to the above technical solution: 1. The present invention adopts a two-stage feeding device, and a heating device is arranged around the two-stage feeding device, so that the waste plastic conveyed through the two-stage feeding device is Semi-melting or close to melting state, therefore, it can effectively prevent the unsafe phenomenon that the occasional high-temperature oil and gas in the reactor is backflowed back to the screw barrel and the hopper; at the same time, two sets of stirring blades connected in series are arranged in the reaction kettle. Moreover, the reaction kettle is set to a negative pressure, which further prevents the back-flushing phenomenon occurring in the reaction kettle, and in particular, various types of interlocking slagging devices are arranged in the system, which effectively ensures the continuous large-scale operation of the present invention. Industrial production. 2. The invention provides a hot press compacting roll device in the two-stage feeding device, and a flue gas jacketed furnace, a chain machine, a roll set, a conveyor belt, a gantry file, and a cooling pool are arranged in the hot press compacting roll device. And the chain machine in the pool, so that it can be heated in the process of conveying the waste plastic in the chain machine, and is rolled by the hot-pressed and dense-rolled roll group to form a tightly pressed plastic belt, and the plastic belt can be At the conveyor belt outlet, the cooling water nozzle is used to cool down, and is cut into smaller plastic pieces by the gantry boring tool, and then sent to the next process through the chain machine in the cooling pool. In particular, the crusher can also cut the plastic into more. The fine particles effectively solve the problem of pre-treatment of waste plastics with a certain proportion of silt dust. 3. The invention provides a high-temperature sealing feeding device in the two-stage feeding device, and a flue gas jacket is arranged at the outlet end of the high-temperature sealing feeding device feeding extruder, and the waste plastic is plasticized or melted into the reaction by the flue gas heating. The kettle is arranged to reduce the blockage formed by the block material; the bucking manipulator is arranged on the upper part of the feeding cylinder, and the feeding block is blocked or not smooth by manual or automatic processing by the robot; an electronic monitor is arranged in the unloading inclined pipe, and is monitored with the regulator of the hoisting machine. Adjust the flow state of the blanking; set the returning heat alarm element in the screw of the feeding extruder, and send the closing of the feeding slide valve at any time to prevent the return air from occurring; set the thermal expansion joint in the lower part of the feeding cylinder to absorb the thermal expansion and contraction The resulting stress reduces the impact on the heat load of the reactor. The above measures make the high temperature seal feeding safer, more reliable and more continuous. 4. The invention provides a two-stage feeding extruder in the two-stage feeding device, and the outlet of the first-stage extruder is arranged above the inlet of the second-stage extruder, so that the structure is simple and the operation and control are convenient. 5. The present invention is provided with a tubular heating furnace for preheating waste oil and heavy oil before the reaction vessel, so that the invention can be used for both waste plastic oiling and waste lubricating oil or heavy oil. It is a high-quality fuel or gasoline-diesel fraction that can be used in both catalytic cracking and non-catalytic cracking processes. 6. The invention adopts a ring-shaped jacketed furnace which is arranged around the reaction vessel and a combustion furnace which is arranged in the lower part of the reaction vessel, and which has a large flow cross section, small resistance, and can ensure the negative pressure of the furnace, or six flame guides. The tube is connected to the annular jacketed furnace and the burning furnace. At the same time, by providing a flame-retardant plate in the burning furnace, a flame-retardant hole is distributed on the flame-retardant plate, thereby achieving uniform heating of the reactor by non-explosive radiation. Way, not only improves heating efficiency, but also reduces Coking at the bottom of the reactor. 7. The invention has various interlocking and decoking devices, so that the flow dynamic operation of the reaction kettle can be effectively ensured, and the opening or closing of each sliding valve or the slag discharging valve is realized during the operation of the reaction kettle. Interlocking and decoking, especially in the coke cans, a twisting manipulator is installed, which can discharge various jams in time to ensure the smooth operation of the coke. 8. The invention also provides an ashing reaction kettle for conversion in the interlocking decoking device, further pulverizing the fluid state slag entering the ashing reaction kettle, making the waste plastic oil more thoroughly, and discharging the ash. The slag is a solid carbon black and can be used as a fuel. 9. The present invention is provided with a flue gas dedusting and dust removing device including a dust removing tower and an oil-water separating device including a grease trap and a water-oil separator, so that the waste flue gas generated by the burning furnace can be sprayed and water-sealed and dust-removed. It is discharged into the environment to reduce environmental pollution. At the same time, the waste oil can be separated. After the water is purified, it can be used for the dust removal tower. The oil is returned to the reactor for further cracking, thus effectively solving the "three wastes" faced by the oilification equipment. solving issues. In particular, when the present invention is provided with an exhaust gas coke boiler, it is also possible to use the coke produced by the apparatus of the present invention and excess gas as fuel to produce steam or the like.
附图说明 DRAWINGS
图 1是本发明系统装置示意图 Figure 1 is a schematic view of the system apparatus of the present invention
图 2是本发明废塑料热压增密轧辊装置结构示意图 2 is a schematic view showing the structure of a waste plastic hot press compacting roll device of the present invention;
图 3是本发明高温密封加料装置结构示意图 Figure 3 is a schematic view showing the structure of the high temperature sealing feeding device of the present invention
图 4是本发明流动态反应釜及非明火辐射加热炉结构示意图 Figure 4 is a schematic view showing the structure of the flow dynamic reaction kettle and the non-open flame radiation heating furnace of the present invention.
图 5是本发明流动态反应釜及非明火辐射加热炉的另一种结构示意图 图 6是本发明高温互锁排焦装置结构示意图 Figure 5 is a schematic view showing another structure of the flow dynamic reaction kettle and the non-open flame radiation heating furnace of the present invention. Figure 6 is a schematic view showing the structure of the high temperature interlocking defocusing device of the present invention.
图 7是本发明高温互锁排焦装置的另一种结构示意图 7 is another schematic structural view of the high temperature interlocking defocusing device of the present invention.
图 8是本发明分熘 -汽提 -冷凝冷却装置结构示意图 Figure 8 is a schematic view showing the structure of the branching-striping-condensing cooling device of the present invention
图 9是本发明油气分离 -气体吸收装置结构示意图 Figure 9 is a schematic view showing the structure of the oil-gas separation-gas absorption device of the present invention
图 10是本发明液化气回收装置结构示意图 Figure 10 is a schematic view showing the structure of the liquefied gas recovery device of the present invention
图 11是本发明油品萃取精制装置结构示意图 Figure 11 is a schematic view showing the structure of the oil extracting and refining device of the present invention
图 12是本发明 "三废"处理装置结构示意图 Figure 12 is a schematic view showing the structure of the "three wastes" processing apparatus of the present invention
图 13是本发明高温排焦装置的另一实施例 Figure 13 is another embodiment of the high temperature defocused device of the present invention
实施发明的最佳方式 The best way to implement the invention
如图 1所示, 本发明可连续化大规模工业生产的废塑料裂解装置包括: 热压增 密轧辊装置 1 , 高温密封加料装置 2, 流动态反应釜装置 3, 非明火辐射式加热装置 4, 高温互锁排焦装置 5, 分馏-汽提-冷凝冷却装置 6、 油气分离-气体吸收装置 7、 液化气回收装置 8、 油品萃取精制装置 9及 "三废"处理装置 10等。 下面分别加以 详细描述。 As shown in FIG. 1, the waste plastics cracking device capable of continuously large-scale industrial production of the present invention comprises: a hot press compacting roll device 1, a high temperature sealed charging device 2, a flow dynamic reaction kettle device 3, and a non-open flame radiation heating device 4 The high-temperature interlocking defocusing device 5, the fractionation-striping-condensation cooling device 6, the oil-gas separation-gas absorption device 7, the liquefied gas recovery device 8, the oil extraction and refining device 9, and the "three wastes" treatment device 10, and the like. The details are described separately below.
如图 1、 图 2所示, 本发明新增设置的热压增密轧辊装置 1包括设置在最前面 的斗式提升机 101, 与斗式提升机 101连接的是烟气夹套炉 102, 夹套炉 102是由 烟气废热提供热量的内外两层结构组成的夹层烘炉。 夹套炉 102内层设有电机带动 的履带式链条机 103, 链条机 103上的履带将从斗式提升机 101送入的废塑料向后 送入热压增密轧辊组 104, 夹套炉 102外层设置了烟气夹套炉膛, 利用从烟气入口 105引入的灼热烟气烘热链条机 103上的废塑料至软化温度。 设置在轧辊组 104上 部的控制热偶 106和烟气入口 105上的调节阀 107可自动控制塑料软化轧制温度。 设置在轧辊组 104下面的输送带 108将被轧辊组 104轧制好的软化塑料条带送入安 装在其后部的龙门铡刀 109切成小块, 在输送带 108 的上方设置有一冷却水喷头 110, 使由轧辊组 104轧出的软化塑料条冷却变硬, 便于切铡, 防止粘连。 从铡刀 109切落的塑料小块落入铡刀 109下部的冷却水池 111中, 铡刀 109下切频率可根 据所要求的切块大小来调节, 设置在水池 111 中的刮板式链条机 112, 可将冷却后 的塑料小块送到水池 111岸上的后续设备中, 链条机 103的转速和轧辊组 104的间 隙均可设置为可调节可控制。 As shown in FIG. 1 and FIG. 2, the newly added hot-pressed compacting roll device 1 of the present invention includes a front set The bucket elevator 101 is connected to the bucket elevator 101 as a flue gas jacketed furnace 102. The jacketed furnace 102 is a sandwich oven composed of an inner and outer two-layer structure that provides heat from flue gas waste heat. The inner layer of the jacketed furnace 102 is provided with a motor-driven crawler type chain machine 103. The crawler belt on the chain machine 103 feeds the waste plastic fed from the bucket elevator 101 back into the hot press compacting roll set 104, and the jacketed furnace. The outer layer of the outer layer is provided with a flue gas jacketed furnace, and the waste plastic from the hot chain machine 103 is heated by the hot flue gas introduced from the flue gas inlet 105 to a softening temperature. The control thermocouple 106 disposed on the upper portion of the roll set 104 and the regulating valve 107 on the flue gas inlet 105 automatically control the plastic softening rolling temperature. The conveyor belt 108 disposed under the roll set 104 feeds the softened plastic strip rolled by the roll set 104 into a gantry cutter 109 mounted at the rear thereof, and is cut into small pieces, and a cooling water spray head is disposed above the conveyor belt 108. 110, the softened plastic strip rolled out by the roll set 104 is cooled and hardened to facilitate cutting and preventing adhesion. The small piece of plastic cut from the file 109 falls into the cooling pool 111 at the lower part of the file 109. The cutting frequency of the file 109 can be adjusted according to the required size of the cutting block. The scraping type chain machine 112 disposed in the pool 111 can be cooled. The rear plastic piece is sent to the subsequent equipment on the shore of the pool 111, and the rotational speed of the chain machine 103 and the gap of the roll set 104 can be set to be adjustable and controllable.
如图 1、图 3所示,本发明的高温密封加料装置 2包括设置在前部的提升机 201, 它由变频调速电机 202带动, 利用调速电机 202和调节器 203, 可控制供料量的大 小。 下料斜管 204连接着提升机 201与带搅拌机的加料斗 205, 电子监测仪 206设 置在下料斜管 204中段, 监视着下料流畅情况, 并将所监测到的信息不断送入调节 器 203, 从而调节提升机 201供料量和下料斜管 204的推料速度。 高温密封塑熔式 加料挤出机 207设置在加料斗 205之下, 加料挤出机 207包括由变频调速电机 208 带动的推料螺杆 209和环绕在推料螺杆 209周围的螺筒 210。 变频调速电机 208的 使用, 使推料转速更容易控制, 使加料挤出机 207更安全可靠地运行, 为加料的自 动化提供了保证, 并可及时地防止事故的发生或终止事故的发生。 加料挤出机 207 的特点还体现在其出口处设置了烟气夹套 211, 通过烟气加热使废塑料被塑化或熔 化进入反应釜 301。 加料筒 212被垂直安装在反应釜 301顶封头上, 连接着加料挤 出机 207与反应釜 301 , 加料筒 212的顶部设置有一捅料机械手 213, 机械手 213 末端设置有绞刀 214, 以防万一发生加料筒底部塑料挤塞时疏通处理之用。 热膨胀 节 218设置在加料筒 212的下部, 以吸收热胀冷缩所产生的应力, 这一应力是由于 运行时, 高温使反应釜 301热膨胀而往上伸长 10〜30mm, 而加料挤出机 207基础 固定在常温下的钢架上, 产生巨大的应力, 具有破坏性, 热膨胀节 218的设置很好 地解决了这一问题。 加料挤出机 207中部设置有监视报警热敏元件 215, 当万一发 生裂解高温油气返窜回加料挤出机到中部时, 报警热敏元件 215就会立即发出信号 给调节器 216, 调节器 216经过调节变送再发讯给加料挤出机 207的调速电机 208 的变频器, 自动调节变频电机 208的推料转速, 加速推料堵住返气; 如果还不能制 止, 则将迅速关闭加料阀 217, 同时发讯号停止加料挤出机 207和提升机 201。 当 油气返窜消除, 监视热敏元件 215将发讯号给变频电机 208, 启动加料挤出机 207 和提升机 201, 随后开启加料阀 217, 恢复正常运行。 As shown in FIG. 1 and FIG. 3, the high-temperature sealing and feeding device 2 of the present invention comprises a hoist 201 disposed at the front portion, which is driven by the variable frequency speed regulating motor 202, and can be controlled by the speed regulating motor 202 and the regulator 203. The size of the quantity. The blanking pipe 204 is connected to the hoist 201 and the hopper 205 with the mixer. The electronic monitor 206 is disposed in the middle of the blanking pipe 204 to monitor the smoothness of the blanking, and continuously feeds the monitored information into the regulator 203. Thereby, the feed amount of the hoisting machine 201 and the pushing speed of the unloading inclined pipe 204 are adjusted. A high temperature sealed plastic melt extruder 207 is disposed below the hopper 205. The feed extruder 207 includes a pusher screw 209 that is driven by the variable speed motor 208 and a barrel 210 that surrounds the pusher screw 209. The use of the variable frequency speed regulating motor 208 makes the pushing speed of the pushing material easier to control, and makes the feeding extruder 207 operate safely and reliably, which provides a guarantee for the automation of the feeding, and can prevent the occurrence of an accident or terminate the accident in time. The feeding extruder 207 is also characterized in that a flue gas jacket 211 is provided at the outlet thereof, and the waste plastic is plasticized or melted into the reaction vessel 301 by the flue gas heating. The charging cylinder 212 is vertically installed on the top sealing head of the reaction vessel 301, and is connected with a feeding extruder 207 and a reaction kettle 301. A charging robot 213 is disposed at the top of the charging cylinder 212, and a cutter 214 is disposed at the end of the robot 213 to prevent In case of plastic congestion at the bottom of the feeding cylinder, the dredging process is used. The thermal expansion joint 218 is disposed at a lower portion of the charging cylinder 212 to absorb the stress generated by the thermal expansion and contraction. This stress is due to the high temperature of the reaction vessel 301 during operation, and the reactor 301 is thermally expanded to extend upward by 10 to 30 mm, and the feeding extruder is fed. The 207 foundation is fixed on a steel frame at normal temperature, which generates great stress and is destructive. The setting of the thermal expansion joint 218 solves this problem well. A monitoring alarm thermal element 215 is disposed in the middle of the feeding extruder 207. When the pyrolysis high temperature oil and gas is returned to the feeding extruder to the middle, the alarm thermal element 215 immediately sends a signal to the regulator 216, the regulator 216 is adjusted and sent to the frequency converter motor 208 of the feeding extruder 207, automatically adjusting the pushing speed of the variable frequency motor 208, accelerating the pushing material to block the return air; Then, the feed valve 217 will be quickly closed, and the feed extruder 207 and the lifter 201 will be stopped by the signal. When the oil and gas return is eliminated, the monitoring the thermal element 215 sends a signal to the variable frequency motor 208, starts the feeding extruder 207 and the elevator 201, and then opens the feeding valve 217 to resume normal operation.
如图 1、 图 4所示, 本发明的流动态反应釜装置 3包括流动态反应釜 301, 反 应釜 301内设置有上、 下两层搅拌桨 302、 303, 矩形的搅拌桨 302和弧形的搅拌桨 303呈十字立交设置(图中示意性地将二者画在一个平面内), 上、 下搅拌桨 302和 303之间的大轴上设置有竖向轴承, 由可调中心度的拉杆支持。搅拌桨 302、 303带 的所有桨叶两侧均设置有刀口, 以破碎液体中的焦渣块或熔结的塑料块。 这就解决 了以往设计中焦渣块和塑料熔结块碰坏搅拌叶, 堵塞排焦管或使搅拌电机瞬间超负 荷而跳闸, 或造成反应釜强烈振动等问题。反应釜 301周围设置电加热夹套炉 404, 提供反应所需热量; 反应釜顶封头一侧设置汽化一分馏塔 306, 塔顶设置冷却水盘 管 307, 以提供内回流, 使全塔产生精馏作用。 塔内装填有高效鲍尔环。 塔顶部分 镏出轻组分 (汽油熘分或石脑馏分), 塔中部侧线抽出柴油部分, 很重的重油和重 蜡则被分馏返回反应釜 301。 轻组分的除去保证了柴油或高质燃油的闪点合格, 重 组分和重蜡的除去, 则保证残炭和凝点合格。 反应釜 301底部侧面设置了带防结焦 夹套的排焦管 304, 它可以防止高温烟气灼烤排焦管, 避免管内重油在管壁结焦, 保证排焦路径畅通。 催化剂油浆加料装置 305设置在反应釜 301顶部, 它由上下两 段隔离罐和顶部加料漏斗三部分组成, 下段隔离罐装有耐高温的玻璃板液位计, 以 控制催化剂桨加入速度。 反应釜 301顶部设置一破沫汽化段 306, 破沫气化段 306 内装有格栅支板及鲍尔环。 汽化段 306顶部设置有一产生内回流的冷却水盘管 307 和提供外回流的轻油回流管 308, 反应釜 301顶部设置的加料筒 212, 与进料加料 挤出机 207成 90° 垂直安装。 As shown in Fig. 1 and Fig. 4, the flow dynamic reactor device 3 of the present invention comprises a flow dynamic reaction vessel 301. The reactor 301 is provided with upper and lower two-stage stirring blades 302 and 303, a rectangular stirring blade 302 and a curved shape. The agitating paddles 303 are arranged in a crossover arrangement (the two are schematically drawn in one plane), and the vertical bearings between the upper and lower agitating paddles 302 and 303 are provided with vertical bearings, which are adjustable in centrality. Tie rod support. All the blades of the paddles 302, 303 are provided with a knife edge on both sides to break the coke block or the sintered plastic block in the liquid. This solves the problems in the previous design that the coke breeze block and the plastic frit block hit the stirring blade, block the exhaust pipe or cause the stirring motor to instantaneously overload and trip, or cause the reactor to vibrate strongly. An electric heating jacket furnace 404 is disposed around the reaction vessel 301 to provide heat required for the reaction; a vaporization-fractionator 306 is disposed on the top of the reactor head, and a cooling water coil 307 is disposed at the top of the reactor to provide internal reflux to generate the entire tower. Rectification. The tower is filled with a high efficiency Pall ring. At the top of the tower, the light component (gasoline split or naphtha fraction) is taken out, the diesel portion is extracted from the side line of the middle of the tower, and the heavy heavy oil and heavy wax are fractionated and returned to the reaction vessel 301. The removal of light components ensures that the flash point of diesel or high quality fuel is acceptable, and the removal of heavy components and heavy wax ensures that the carbon residue and freezing point are acceptable. On the bottom side of the reaction kettle 301, a defocused tube 304 with an anti-coking jacket is arranged, which can prevent the high temperature flue gas from burning the defocused tube, avoiding the coking of the heavy oil in the tube wall, and ensuring the smooth discharge path. The catalyst slurry feeding device 305 is disposed on the top of the reaction kettle 301. It consists of three upper and lower isolation tanks and a top feeding funnel. The lower isolation tank is equipped with a high temperature resistant glass plate level gauge to control the catalyst paddle addition speed. A foaming section 306 is arranged on the top of the reactor 301, and a grid support plate and a Pall ring are arranged in the foaming gasification section 306. The top of the vaporization section 306 is provided with a cooling water coil 307 for generating internal reflux and a light oil return pipe 308 for providing external reflux. The charging cylinder 212 disposed at the top of the reaction vessel 301 is installed at a 90° angle to the feed feeding extruder 207.
如图 4、 图 5所示, 本发明的非明火辐射式加热装置 4设置在反应釜 301下面, 并与反应釜 301连成一整体。 它包括一炉子裙座 401, 在裙座 401周围设置一环形 导焰套 402 (如图 4所示) 或六〜八条导焰管 403 (如图 5所示), 反应釜 301周围 设置的环形夹套炉 404和反应釜 301下部的燃烧炉 405通过环形导焰套 402或导焰 管 403相连通。 本发明加热装置与以往各种反应燃烧炉不同点体现在: 导焰套 402 或导焰管 403的流动截面大于反应釜 301周围夹套炉 404截面的 2倍以上。 这就减 少了烟气由炉膛宽大的流动体积突然缩小截面的流动阻力, 保证炉膛的真空度和良 好的燃烧状态, 防止炉膛产生正压, 为提高炉膛温度提供了保证。 这一设计解决了 以往设计中导焰管流动截面小,造成阻力大,炉膛真空度低, 甚至常发生正压燃烧, 火焰冒出炉门, 不安全, 且限制了炉膛温度的提高, 使反应供热不足等问题。 在导 焰套 402或导焰管 403的上、 下相接处设置有波形热膨胀节 406 (如图 4、 图 5所 示), 用以吸收热膨胀应力, 保证炉体正常运行。 这一结构解决了以往设计中膨胀 圈严重漏风, 使炉膛真空度降低, 燃烧不良的问题, 既解决了吸收热膨胀应力, 又 保证了炉膛密封问题。 在燃烧炉 405上设置了一层由高辐射强度的耐高温(1000Ό 以上) 材质制成的辐射阻焰板 407, 且阻焰板 407上设置有一组分布均勾的阻焰小 孔, 阻焰板 407可以防止火焰直接接触反应釜 301, 形成非明火的辐射加热方式。 本发明这一设计与前述大的导焰截面通道结构相结合, 既可以允许很高的炉膛温 度, 充分保证反应釜供热需要, 又可以保证生产的安全运行, 而且从根本上解决了 易燃易爆的反应釜不能明火加热的容器设计规范要求的问题。燃烧炉 405使用的燃 烧器 408为油气混烧型, 具有自动点火、 火焰监测、 熄火保护等功能, 它设置在炉 膛下段而在灰膛之上, 两台燃烧器分别设置在燃烧炉 405的两侧, 且使入火口沿炉 壁方向倾斜, 使喷出的火焰在炉膛内形成旋焰, 使阻焰板 407的受热更加均匀。 在 反应釜环形夹套炉 404的上部设置有烟气出口 409, 导出的烟气可以去热压增密轧 辊装置 1的夹套炉 102和高温密封加料装置 2的烟气夹套 211, 以及其它需要烟气 加热的设备, 烟气最终被送入 "三废"处理装置 10进行烟气脱黑处理, 最后从烟 囱排出的将是水蒸汽、 氮气和二氧化碳。 As shown in Figs. 4 and 5, the non-open flame radiation type heating device 4 of the present invention is disposed under the reaction vessel 301 and integrated with the reaction vessel 301. The utility model comprises a furnace skirt 401. A circular flame guiding sleeve 402 (as shown in FIG. 4) or six to eight flame guiding tubes 403 (shown in FIG. 5) are arranged around the skirt 401, and a ring around the reaction kettle 301 is arranged. The jacket furnace 404 and the combustion furnace 405 at the lower portion of the reactor 301 are in communication via a ring flame guide 402 or a flame tube 403. The heating device of the present invention is different from the conventional reaction combustion furnaces in that the flow section of the flame trap 402 or the flame guiding tube 403 is larger than twice the cross section of the jacketed furnace 404 around the reaction vessel 301. This reduces the flow resistance of the flue gas from the wide flow volume of the furnace and shortens the section, ensures the vacuum of the furnace and good combustion state, and prevents the furnace from generating positive pressure, which provides a guarantee for improving the furnace temperature. This design solves the problem that the flow path of the flame tube is small in the previous design, causing large resistance, low vacuum of the furnace, and even positive pressure combustion often occurs, the flame exits the furnace door, is unsafe, and limits the temperature increase of the furnace, so that the reaction is provided. Insufficient heat and other issues. A waveform thermal expansion joint 406 is disposed at the upper and lower ends of the flame shield 402 or the flame tube 403 (as shown in FIG. 4 and FIG. 5). Show), to absorb the thermal expansion stress, to ensure the normal operation of the furnace. This structure solves the problem that the expansion ring is seriously leaked in the previous design, the furnace vacuum is lowered, and the combustion is poor, which not only solves the problem of absorbing thermal expansion stress but also ensures the furnace sealing problem. A radiation obstruction plate 407 made of a high-radiation-resistant high-temperature (1000 Ό or higher) material is disposed on the combustion furnace 405, and a flame-retardant hole is disposed on the flame-retardant plate 407, and a flame-retardant hole is distributed on the flame-retardant plate 407. The plate 407 prevents the flame from directly contacting the reaction vessel 301, forming a non-open flame radiant heating mode. The design of the present invention is combined with the aforementioned large flame-conducting cross-section channel structure, which can not only allow a high furnace temperature, fully ensure the heat supply of the reactor, but also ensure the safe operation of the production, and fundamentally solve the flammability. Explosive reactors are not subject to the requirements of the design specifications for containers that are heated by open flame. The burner 408 used in the combustion furnace 405 is a mixed oil and gas type, and has the functions of automatic ignition, flame monitoring, flameout protection, etc., which are disposed on the lower part of the furnace and above the ash, and two burners are respectively disposed in the combustion furnace 405. On the side, the fire inlet is inclined in the direction of the furnace wall, so that the flame that is ejected forms a flame in the furnace, so that the heat of the flame trap 407 is more uniform. A flue gas outlet 409 is disposed at an upper portion of the reactor annular jacket furnace 404, and the derived flue gas can be removed from the jacketed furnace 102 of the hot press densification roll device 1 and the flue gas jacket 211 of the high temperature seal feeding device 2, and the like. For equipment that requires flue gas heating, the flue gas is finally sent to the "three wastes" treatment unit 10 for flue gas de-blackening treatment, and finally the water vapor, nitrogen and carbon dioxide are discharged from the chimney.
如图 1、 图 6所示, 本发明的高温互锁排焦装置 5设置在反应釜 301的一侧, 它由一级排焦罐 501和二级排焦罐 502组成。 一级排焦罐 501与反应釜 301之间由 带夹套的排焦管 304相连接。 排焦管 304上设置有第一道排焦滑阀 503。 一、 二级 排焦罐 501、 502之间设置了第二道滑阀 504, 二级排焦罐 502下面设置了第三道滑 阀 505。 三道阀 503、 504、 505成互锁状态运行, 即正常状态下, 滑阀 503为常开, 滑阀 504和 505为常闭状态。 互锁排焦程序如下: 第一步当一级排焦罐 501中沉积 了一定量的焦桨时, 关闭滑阀 503, 切断与反应釜 301的连接, 确保排渣安全, 此 时三道滑阀均处于关闭状态; 第二步, 打开滑阀 504, 令 501中的焦渣排入二级排 焦罐 502,第三步,关闭滑阀 504,打开滑阀 505, 开度为 10〜30%,令其逐渐排渣, 落入斜底排焦水池 506, 并由链条刮板机 (图中未示出) 将水中冷凝冷却后的焦渣 块捞到地面上。 如此不断重复上述排渣三步骤, 不断地排出反应中生成的焦渣, 保 证装置连续运行。 三只机械手 507、 508、 509分别设置在一级排焦罐 501的顶部和 侧面, 机械手 507、 509的顶端头分别设置一具有三叉钻头的疏焦钻杆, 机械手 509 直通到排焦管 304和反应釜 301底部,机械手 507直通滑阀 505的阀前。机械手 508 底部为一园盘, 以监测一级焦罐 501底部积焦情况。 机械手 507、 508、 509可以自 动控制, 也可以手动控制。 As shown in Figs. 1 and 6, the high temperature interlocking defocusing device 5 of the present invention is disposed on one side of the reaction vessel 301, and is composed of a primary coke discharge tank 501 and a secondary coke discharge tank 502. The first stage coke canister 501 and the reaction kettle 301 are connected by a jacketed discharge tube 304. A first discharge spool valve 503 is disposed on the exhaust pipe 304. First, a second spool valve 504 is disposed between the secondary coke cans 501, 502, and a third spool valve 505 is disposed below the secondary coke canister 502. The three valves 503, 504, and 505 operate in an interlocked state, that is, in the normal state, the spool valve 503 is normally open, and the spool valves 504 and 505 are normally closed. The interlocking coke removal procedure is as follows: In the first step, when a certain amount of coke paddle is deposited in the first-stage coke oven 501, the slide valve 503 is closed, and the connection with the reaction kettle 301 is cut off to ensure the safety of slag discharge. The valve is in the closed state; the second step, the slide valve 504 is opened, the coke residue in 501 is discharged into the secondary coke discharge tank 502, and in the third step, the slide valve 504 is closed, and the slide valve 505 is opened, the opening degree is 10~30 %, let it gradually drain the slag, fall into the slant bottom defocusing pool 506, and carry the condensed and cooled coke block in the water to the ground by a chain scraper (not shown). The above three steps of slagging are continuously repeated, and the coke generated in the reaction is continuously discharged to ensure continuous operation of the device. Three robots 507, 508, 509 are respectively disposed at the top and the side of the first-stage coke can 501, and the top ends of the robots 507, 509 are respectively provided with a sparse drill pipe having a trigeminal drill bit, and the robot 509 is directly connected to the exhaust pipe 304 and At the bottom of the reaction vessel 301, the robot 507 passes straight through the valve front of the spool 505. The bottom of the robot 508 is a disk to monitor the accumulation of the bottom of the primary coke 501. The robots 507, 508, and 509 can be controlled automatically or manually.
如图 1、 图 7所示, 本发明的高温互锁排焦装置 5还可以采用多头结构, 其与 上述单头互锁排焦装置不同之处是设置了三台套并联的排焦罐 510、 511、 512, 可 以转换运行, 灵活操作, 加大排焦流量。 正面排焦罐 510设置在与反应釜 301同一 中心线上,通过排焦滑阔 513与排焦管 305相连,水平绞焦杆 514设置在排焦罐 510 和排焦管 305同一轴线上。 左右两侧排焦罐 511、 512设置在排焦罐 510中心轴线 水平夹角左、 右 30° 左右的位置上, 其结构与排焦罐 510相同, 但左右两侧排焦罐 511、 512设计成具有一定流焦斜度, 即排焦罐 511、 512的排焦管 514、 515的中心 轴线与水平夹角呈 5〜15 ° 向下斜装, 有利于焦桨下流, 防止焦碳在排焦管 514、 515管底沉积。 As shown in FIG. 1 and FIG. 7, the high-temperature interlocking defocusing device 5 of the present invention can also adopt a multi-head structure, which is different from the above-mentioned single-head interlocking defocusing device in that three sets of parallel decanting tanks 510 are provided. , 511, 512, available Run in conversion, flexible operation, increase the flow of defocused. The front decanting tank 510 is disposed on the same center line as the reaction vessel 301, and is connected to the defocused tube 305 through the defocused sliding 513. The horizontal dipstick 514 is disposed on the same axis of the decanter 510 and the defocused tube 305. The left and right side decanting tanks 511, 512 are disposed at a position horizontally at an angle of about 30° to the left and right of the central axis of the coke-discharging tank 510, and have the same structure as the coke-discharging tank 510, but the left and right sides of the coke-discharging tanks 511 and 512 are designed. The flow axis has a certain degree of flow coke, that is, the central axis of the defocusing tubes 514, 515 of the coke drums 511, 512 is inclined at an angle of 5 to 15 ° with the horizontal angle, which is favorable for the downward flow of the coke pad and prevents the coke from being discharged. The bottoms of the tubes 514, 515 are deposited.
如图 1、 图 8所示, 本发明的分馏-汽提-冷凝冷却装置 6包括下部带有烟气夹 套 602作为热源的分馏塔 601, 分馏塔 601 内下部设置格栅支板 603, 支持着装满 塔内的高效鲍尔环填料 604。 塔内自下而上设置有重柴油集油箱 605及其抽出线侧 线 606、轻柴油集油箱 607及其抽出线侧线 608、煤油集油箱 609及其抽出侧线 610。 塔外自塔顶至塔底设置有汽油回流口 611, 煤油回流口 612, 轻柴油回流口 613, 重 柴油回流口 614及重油回流口 615。煤油汽提塔 616、轻柴油汽提塔 617、 重柴油汽 提塔 618自上而下重叠安装在同一轴线上, 它们设置在分馏塔 601—侧。 冷凝冷却 水箱 619设置在汽提塔 616、 617、 618的下侧, 以便各油流能依靠位差自动流经各 自的冷凝冷却盘管 620流向下一工序。 凉水塔 621安装在水箱 619顶部, 循环水泵 622安装在水箱 619底部一侧, 将热水泵入凉水塔 621, 下喷冷却, 循环使用。 As shown in FIG. 1 and FIG. 8, the fractionation-strip-condensation cooling device 6 of the present invention comprises a fractionation tower 601 with a flue gas jacket 602 as a heat source in the lower portion, and a grid support plate 603 is arranged in the lower portion of the fractionation tower 601, and supports A high efficiency Pall ring packing 604 is placed in the tower. The bottom of the tower is provided with a heavy diesel fuel collecting tank 605 and its extraction line side line 606, a light diesel oil collecting tank 607 and its extraction line side line 608, a kerosene fuel collecting tank 609 and its extraction side line 610. From the top of the tower to the bottom of the tower, there are a gasoline return port 611, a kerosene return port 612, a light diesel oil return port 613, a heavy diesel oil return port 614 and a heavy oil return port 615. The kerosene stripper 616, the light diesel stripper 617, and the heavy diesel stripper 618 are mounted on the same axis from top to bottom, and they are disposed on the side of the fractionation column 601. The condensing cooling water tank 619 is disposed on the lower side of the stripping towers 616, 617, and 618 so that each oil flow can automatically flow through the respective condensing cooling coils 620 to the next process by means of the difference. The cooling tower 621 is installed at the top of the water tank 619, and the circulating water pump 622 is installed on the bottom side of the water tank 619, and the hot water is pumped into the cooling tower 621, which is sprayed and cooled, and recycled.
如图 1、 图 9所示, 本发明的油气分离-气体吸收装置 7包括油气分离塔 701, 一级气体吸收塔 702, 二级气体吸收塔 703, 以及水封罐 704等, 二级吸收塔 703 内装填着高效鲍尔环填料 705。 一、 二级吸收塔将混合在反应裂化气体中的有害成 分, 如氯化氢、 硫化氢等除掉, 送入液化气回收装置 8。 As shown in FIG. 1 and FIG. 9, the oil-gas separation-gas absorption device 7 of the present invention comprises an oil-gas separation column 701, a primary gas absorption tower 702, a secondary gas absorption tower 703, and a water-sealing tank 704, etc., a secondary absorption tower. The 703 is filled with high efficiency Pall ring packing 705. 1. The secondary absorption tower removes the harmful components mixed in the reaction cracking gas, such as hydrogen chloride, hydrogen sulfide, etc., and sends it to the liquefied gas recovery unit 8.
如图 1、 图 10所示, 本发明的液化气(LPG) 回收装置 8包括低压气体稳定罐 801 , 从装置 7送过来的干净裂化气引入罐 801, 稳定压力后送入一级压缩机 802, 被压缩至 0.3〜0.4Mpa,送入一级压缩分凝液罐 803,其罐内装有冷凝冷却盘管 804, 将部分较重的液化气组分冷凝成为轻汽油回收, 而脱重组分后的裂化气再送入二级 压缩机 805压缩至 0.5〜0.8Mpa,再送入冷凝冷却器 806,此时液化气组分将被冷凝 为液体, 即 LPG, 再送入高压液气分离罐 807, 在此 807罐中, LPG与无法压缩液 化的干气 (甲垸、 乙烷、 乙烯组分) 分离, LPG从罐底流入高压液化气储罐 808, 再经瓶装泵 809, 若干瓶装分装线 810装瓶出售民用。 干气从 807罐顶部逸出送入 高压干气稳定罐 811 , 及水封阻火罐 812后送去炉子作为自用燃料, 若有多余放火 炬排空或送锅炉 12 (如设置的话)作燃料。在阻火罐 812的火炬放空线上安装有自 力式压力自控阀 813, 它控制着全装置系统压力。 As shown in Figs. 1 and 10, the liquefied gas (LPG) recovery unit 8 of the present invention includes a low pressure gas stabilizing tank 801, and a clean cracking gas introduction tank 801 sent from the unit 7 is sent to the primary compressor 802 after the pressure is stabilized. , compressed to 0.3~0.4Mpa, sent to the first-stage compression condensate tank 803, which is equipped with a condensing cooling coil 804, which condenses part of the heavier liquefied gas component into light gasoline recovery, and after de-heavy components The cracked gas is sent to the secondary compressor 805 to be compressed to 0.5 to 0.8 MPa, and then sent to the condensing cooler 806. At this time, the liquefied gas component is condensed into a liquid, that is, LPG, and then sent to the high pressure liquid gas separation tank 807, where In the 807 tank, LPG is separated from the dry gas (methyl hydrazine, ethane, ethylene component) which cannot be compressed and liquefied. LPG flows from the bottom of the tank into the high-pressure liquefied gas storage tank 808, and then through the bottled pump 809, and several bottled packing lines 810 The bottle is for sale for civilian use. Dry gas is sent from the top of the 807 tank to the high-pressure dry gas stabilization tank 811, and the water seal flame arrester 812 is sent to the furnace as a fuel for own use. If there is excess flare, it can be sent to the boiler 12 (if set) for fuel. A self-operated pressure self-control valve 813 is mounted on the torch vent line of the flame arrester 812, which controls the full system pressure.
如图 1、 图 11所示, 本发明的油品萃取精制装置 9包括汽油 -轻柴油萃取系统。 它们由 A-萃取罐 901、 902, B-萃取罐 903、 904, 及添加剂调合罐 905、 906等所组 成。从裂解反应釜和分镏塔生产出的粗柴油、粗汽油尚不能完全满足国标质量要求, 需经过精制。 粗柴油首先送入 A-萃取罐 801, 加入 A剂, 进行 A-萃取精制过程, 除去非理想组分后送入 B-萃取罐 803,加入 B-萃取剂,进一步除去非理想成分后再 送入调合罐 805, 根据性能要求加必要的添加剂调合成合格产品送出装置出售; 粗 汽油萃取精制过程亦相同。 As shown in Figs. 1 and 11, the oil extracting and refining device 9 of the present invention comprises a gasoline-light diesel oil extraction system. They are composed of A-extraction tanks 901, 902, B-extraction tanks 903, 904, and additive blending tanks 905, 906, and the like. The gas oil and crude gasoline produced from the cracking reactor and the branching tower cannot fully meet the quality requirements of the national standard and need to be refined. The gas oil is first sent to the A-extraction tank 801, the A agent is added, and the A-extraction purification process is carried out, the non-ideal components are removed, and then sent to the B-extraction tank 803, and the B-extractant is added to further remove the non-ideal components and then fed. The mixing tank 805 is added to the qualified product delivery device for sale according to the performance requirement and the necessary additives; the crude gasoline extraction and refining process is also the same.
如图 1、 图 12所示, 本发明的 "三废"处理装置 10包括烟气脱黑除尘装置和 油水分离装置, 烟气脱黑除尘装置包括除尘塔 1001, 除尘塔 1001外设置一循环水 泵 1004, 除尘塔 1001内设置一组连接循环水泵 1004出口的回流水喷头 1005。 除 尘塔 1001中段设置一隔板 1006, 将除尘塔 1001分隔成上、 下两段, 上段为喷啉除 尘, 下段为水封除尘, 在隔板 1006的最低点设置一液流管 1007, 除尘塔 1001底部 连通一过滤器, 过滤器的出口连接循环水泵 1004的进口。 除尘塔 1001的烟气进口 通过管路连接非明火辐射式加热装置 4的烟气出口 409,除尘塔 1001顶部的出烟管 连接至除尘塔 1001下段的积水中, 使烟气在积水中进一步水封除尘后, 从设置在 除尘塔 1001下段的烟气出口排出。 油水分离装置包括隔油池 1009和油水分离器 1008。 隔油池 1009连接油品萃取精制装置 9底部出口, 油水分离器 1008设置在隔 油池 1009之后, 二者之间设置有一抽水泵 1010。 抽水泵 1010将隔油池 1009分离 出的水, 泵给油水分离器 1008, 油水分离器 1008处理后的净水通过循环水泵 1004 返回来供给除尘塔 1001喷淋除尘使用, 隔油池 1009和油水分离器 1008分离出的 油返回反应釜 301继续裂解。 As shown in FIG. 1 and FIG. 12, the "three wastes" processing device 10 of the present invention includes a flue gas de-blackening and dust removing device and a water-oil separating device. The flue gas de-blacking and dust removing device includes a dust removing tower 1001, and a circulating water pump 1004 is disposed outside the dust removing tower 1001. A set of recirculating water nozzles 1005 connected to the outlet of the circulating water pump 1004 is disposed in the dust removing tower 1001. A separator 1006 is arranged in the middle of the dust removal tower 1001, and the dust removal tower 1001 is divided into upper and lower sections, the upper section is sprayed with dust, and the lower section is water sealed and dusted. A liquid flow tube 1007 is disposed at the lowest point of the partition 1006, and the dust removal tower is disposed. The bottom of the 1001 is connected to a filter, and the outlet of the filter is connected to the inlet of the circulating water pump 1004. The flue gas inlet of the dust removing tower 1001 is connected to the flue gas outlet 409 of the non-open flame radiant heating device 4 through a pipeline, and the flue pipe at the top of the dust removing tower 1001 is connected to the stagnant water in the lower section of the dust removing tower 1001, so that the flue gas is in the stagnant water. After the water seal is further removed from the water, it is discharged from the flue gas outlet disposed in the lower stage of the dust removal tower 1001. The oil-water separation device includes a grease trap 1009 and a water separator. The grease trap 1009 is connected to the bottom of the oil extraction and refining device. The oil-water separator 1008 is disposed behind the grease trap 1009, and a pump 1010 is disposed therebetween. The water pump 1010 pumps the water separated from the grease trap 1009 to the oil-water separator 1008. The purified water treated by the oil-water separator 1008 is returned to the dust-removing tower 1001 by the circulating water pump 1004 for use in the dust-removing tower 1001, the grease trap 1009 and the oil-water tank. The oil separated by the separator 1008 is returned to the reaction vessel 301 to continue cracking.
如图 13所示, 上述实施例中, 热压增密乳辊装置 1、 高温密封加料装置 2可以 有所变化, 比如将热压增密轧辊装置 1和高温密封加料装置 2, 设置成两级加料挤 出机 220、 230, 一级加料挤出机 220位于二级加料挤出机 230前面。 两级加料挤出 机 220、 230分别包括一螺筒 221、 231 , 在两螺筒 221、 231—端分别安装一调速电 机 222、 232, 两调速电机 222、 232输出端分别连接一螺杆 223、 233, 两螺杆 223、 233上分别设置有螺旋叶片(图中未示出)。另外一级加料挤出机 220的螺杆 223可 以是一单螺杆, 也可以是相对旋转的双螺杆。 两螺筒 221、 231 周围分别设置有自 控的电加热金属浴块或其它电加热装置为螺筒 221、 231加热, 两螺筒 221、 231下 部设置牢固的支架。一级加料挤出机 220的进口设置一带搅拌拨料机的加料斗 224, 加料斗 224上方一侧设置一可定量加催化剂料斗 225, 二级加料挤出机 230的进口 位于一级加料挤出机 220出口下方,二级加料挤出机 230的进口设置一带双滚轮 234 的加料斗 235,二级加料挤出机 230的出口连接反应釜 301顶封头一侧的加料筒 212。 As shown in FIG. 13, in the above embodiment, the hot press compacting roller device 1 and the high temperature sealing feeding device 2 may be changed, for example, the hot press compacting roll device 1 and the high temperature sealing and feeding device 2 are set to two stages. Feed extruders 220, 230, primary feed extruder 220 are located in front of secondary feed extruder 230. The two-stage feeding extruders 220 and 230 respectively include a screw barrel 221 and 231, and a speed regulating motor 222 and 232 are respectively installed at the ends of the two screw barrels 221 and 231, and the output ends of the two speed regulating motors 222 and 232 are respectively connected with a screw. 223, 233, the two screws 223, 233 are respectively provided with spiral blades (not shown). Further, the screw 223 of the primary feeding extruder 220 may be a single screw or a relatively rotating twin screw. The two barrels 221 and 231 are respectively provided with self-controlled electric heating metal bath blocks or other electric heating devices for heating the barrels 221 and 231, and the lower parts of the two barrels 221 and 231 are provided with a firm bracket. The inlet of the first-stage feeding extruder 220 is provided with a hopper 224 with a stirring and discharging machine. The upper side of the charging hopper 224 is provided with a quantitatively-addable catalyst hopper 225, and the inlet of the secondary feeding extruder 230 is located at the first-stage feeding and extruding. Below the outlet of the machine 220, the inlet of the secondary feeding extruder 230 is provided with a hopper 235 with a double roller 234, and the outlet of the secondary feeding extruder 230 is connected to the charging cylinder 212 on the top side of the reaction vessel 301.
废塑料经粉碎后被提升至一级加料挤出机 220的加料斗 224内, 同时按比例将 催化剂料斗 225中的催化剂加到加料斗 224内, 随废塑料一起混合进入一级加料挤 出机 220中, 通过螺杆 223强力推向前进, 并被螺筒 221外的电热装置加热至软化 温度推出螺筒 221出口, 使呈半熔化状态的废塑料通过二级加料挤出机 230的双滚 轮 234落入加料斗 235, 进而被挤入二级加料挤出机 230, 呈粘胶状态的废塑料被 挤出二级加料挤出机 230出口, 通过加料筒 212进入反应釜 301内进行裂解反应。 After being pulverized, the waste plastic is lifted into the hopper 224 of the primary feeding extruder 220, and proportionally The catalyst in the catalyst hopper 225 is fed into the hopper 224, mixed with the waste plastic into the primary feeding extruder 220, pushed vigorously forward by the screw 223, and heated by the electric heating device outside the screw 221 to the softening temperature. The outlet of the barrel 221 causes the waste plastic in a semi-molten state to fall into the hopper 235 through the double rollers 234 of the secondary feeding extruder 230, and is then extruded into the secondary feeding extruder 230, which is a waste plastic in a visco state. The outlet of the secondary feeding extruder 230 is extruded, and is introduced into the reaction vessel 301 through the charging cylinder 212 to carry out a cracking reaction.
两级加料挤出机 220、 230螺筒 221、 231外的电加热装置, 只是在启动初期起 加热作用, 当正常运转后, 螺杆 223、 233 强大的推压力, 会使被挤塑的废塑料产 生足够的热量而自动软化, 此时电加热便会在控制系统的控制下停止加热。 从二级 加料挤出机 230挤出的废塑料呈半融化或接近融化状态, 可有效地防止反应釜 301 内偶尔产生的髙温油气逆流返冲回螺筒 231和料斗 235的不安全现象发生。 同时反 应釜 301采用微负压操作, 也可有效地避免高温油气返冲现象发生。 The electric heating device outside the two-stage feeding extruder 220, 230 barrels 221, 231 only heats up at the initial stage of startup, and after normal operation, the strong pushing force of the screws 223, 233 causes the extruded plastic to be extruded. It generates enough heat to soften automatically. At this time, the electric heating stops heating under the control of the control system. The waste plastic extruded from the secondary feeding extruder 230 is in a semi-melting or near-melting state, and can effectively prevent the unsafe phenomenon that the occasional temperature and oil in the reactor 301 is countercurrently returned to the screw barrel 231 and the hopper 235. . At the same time, the reaction kettle 301 is operated by micro-negative pressure, which can effectively avoid the occurrence of high-temperature oil and gas back-flux.
上述各实施例中, 高温互锁排焦装置 5的结构可以是各种各样的, 比如设置在 反应釜 301底部的排渣管 304为两根, 两油排渣管 304的出口分别连接一灰化反应 釜 521、 522, 灰化反应釜 521、 522周围设置有加热装置, 从反应釜 301底部排入 两灰化反应釜 521、 522 的裂解油和焦渣在此进一步裂解生成油汽和灰渣。 在两灰 化反应釜 521、 522产生的油汽上升到设置在顶封头一侧的汽化分馏塔 523、 524中, 其塔内装填有高效鲍尔环填料, 塔顶设置冷却水盘管 525、 526, 用以产生内回流。 塔顶馏出轻熘分油 (汽油馏分), 中部抽出中间熘分油 (柴油部分), 重油和重蜡返 回反应釜裂解。 在两灰化反应釜 521、 522 中二次裂解生成的最终残渣为灰渣, 通 过底部排渣阀 527、 528排入排渣容器 529、 530中, 被其周围的冷却水套 531、 532 冷却后, 由灰渣排出阀 533、 534排出系统, 由小车运走。使用中两灰化反应釜 521、 522是轮流使用的, 一个操作, 另一个可以排焦渣。 In the above embodiments, the structure of the high temperature interlocking defocusing device 5 can be various. For example, the slag discharging pipes 304 disposed at the bottom of the reaction kettle 301 are two, and the outlets of the two oil discharging slag pipes 304 are respectively connected to one. The ashing reactors 521 and 522 are provided with heating means around the ashing reactors 521 and 522. The pyrolysis oil and coke discharged from the bottom of the reactor 301 into the two ashing reactors 521 and 522 are further cracked to form oil vapor and Ash residue. The oil vapor generated in the two ashing reactors 521, 522 rises to the vaporization fractionation columns 523, 524 disposed on one side of the top seal head, the tower is filled with a high efficiency Pall ring packing, and the top of the tower is provided with a cooling water coil 525. 526, used to generate internal reflux. At the top of the column, the light sputum oil (gasoline fraction) is distilled off, the middle part of the oil is extracted from the middle (diesel part), and the heavy oil and heavy wax are returned to the reactor for cracking. The final residue formed by secondary cracking in the two ashing reactors 521, 522 is ash, discharged into the slag discharge containers 529, 530 through the bottom slag discharge valves 527, 528, and cooled by the surrounding cooling water jackets 531, 532. Thereafter, the system is discharged from the ash discharge valves 533, 534 and carried away by the trolley. In use, the two ashing reactors 521, 522 are used in turn, one operation, and the other can discharge coke.
上述各实施例中, 高温互锁排焦装置 5的各排焦罐(或灰化反应釜)和排焦阀 的数量都是可以变化的, 比如排焦罐的数量为 2〜4个, 排焦阔的数量为 2〜8个。 "三废"处理装置 10还可以采用现有技术中的各种烟气、 油水分离装置, 即使是 采用本发明的脱黑除尘装置和油水分离装置, 除尘塔 1001、 隔油池 1009和油水分 离器 1008之外, 也可以增加替换成采用其它结构和装置。 In the above embodiments, the number of each of the decanting tanks (or ashing reactors) and the defocusing valves of the high-temperature interlocking defocusing device 5 can be changed, for example, the number of the coke-removing tanks is 2 to 4, The number of focal lengths is 2 to 8. The "three wastes" treatment device 10 can also adopt various flue gas and oil-water separation devices in the prior art, even if the de-blackening and dust removal device and the oil-water separation device of the present invention are used, the dust removal tower 1001, the grease trap 1009 and the oil-water separator In addition to 1008, it is also possible to add a replacement to other structures and devices.
本发明使用时, 废塑料经除去泥砂、 砖石、 棉布、 木头、 铁屑等后, 如图 1、 图 2所示, 先经初步破碎送入设置在最前部的斗式提升机 101, 再经由烟气废热夹 套炉 102包围的履带式链条机 103及轧辊组 104热压轧辊成塑料条, 并经冷却喷头 110和铡刀 109,使废塑料由堆积密度不足 0.1t/m3被增密成为 0.5〜1.2t/m3的塑料小 块。 还可以再送入破碎机 11 (如图 1所示), 破碎机 11设置在热压增密轧辊装置 1 之后但在高温密封加料装置 2之前。 塑料切块被破碎为 I X lcm2以下的碎块, 再送 入高温密封加料装置 2。 高温密封进料装置 2将增密破碎后的废塑料密封地在反应 过程中连续安全地加入反应釜 301, 进行催化裂解反应, 生成轻质燃油和汽油、 柴 油镏分等。 当本发明装置同时处理废油或重质油时, 用来预热废油和重质油的管式 加热炉 12被设置在反应釜 301之前, 进而使废塑料和废油既可单独分别进入反应 釜 301, 也可按任意比例混合同时迸入反应釜 301, 裂解为各种轻质燃油或汽油柴 油镏分。 由反应釜 301生成的油气混合物呈汽相从顶部出来被引入分馏塔 601 (如 图 1、 图 8所示) 分馏, 分熘塔 601塔顶出汽油与瓦斯, 塔侧线抽出煤油、 轻、 重 柴油, 轻重柴油呈液相流入煤油、 轻、 重柴油汽提塔 616、 617、 618汽提后, 煤油 与轻柴油合一和重柴油流经冷凝冷却水箱 619冷却。 分馏塔 601塔顶汽油蒸汽和瓦 斯气经冷凝冷却水箱 619冷却后, 流入油气分离塔 701 (如图 1、 图 9所示), 汽油 回流入分馏塔 601, 控制塔顶温度从而控制汽油质量。 分出的粗汽油进萃取精制装 置 9; 瓦斯气经气体吸收塔 702、 703等吸收净化后引入液化气回收装置 8 (如图 1、 图 10所示), 经液化气回收装置 8处理后分出民用液化气和干气, 这部分干气可作 为自用燃料气。 汽油与轻柴油在经油品萃取精制装置 901、 902、 903、 904萃取精 制后 (如图 1、 图 11所示), 再经添加剂调合罐 905、 906适当调合成为成品油, 油 品成品由此出装置。 如图 1、 图 12所示, 从非明火辐射式加热装置 4的烟道出口 409进入除尘塔 1001的烟气, 经过喷淋除尘和水封除尘后, 可将烟气中的黑尘微粒 及有害成份除净, 使排出的烟气对环境的污染降至最低。 除尘塔 1001底部的积水 经过滤后送入循环水泵 1004继续使用, 过滤器内的碳黑可以作为燃料使用。 从油 品萃取精制装置 9底部出口进入隔油池 1009的油水分离后, 水进入油水分离器 1008, 从油水分离器 1008出来的水送入循环水泵 1004继续使用, 从隔油池 1009 和油水分离器 1008分离出来的油返回反应釜 301继续裂解。 When the invention is used, after the waste plastic is removed from mud sand, masonry, cotton cloth, wood, iron filings, etc., as shown in FIG. 1 and FIG. 2, it is firstly crushed and sent to the bucket elevator 101 installed at the foremost part, and then The crawler type chain machine 103 and the roll set 104 surrounded by the flue gas waste jacketed furnace 102 are hot-rolled into plastic strips, and the waste plastics are densified by a packing density of less than 0.1 t/m 3 through the cooling head 110 and the boring tool 109. Become a small piece of plastic of 0.5~1.2t/m 3 . It is also possible to feed the crusher 11 (shown in Fig. 1), which is disposed after the hot press compacting roll device 1 but before the high temperature seals the feeding device 2. The plastic dicing is broken into pieces below IX lcm 2 and then sent Into the high temperature sealing feeding device 2. The high-temperature sealed feeding device 2 continuously and safely adds the denatured and crushed waste plastic to the reaction vessel 301 during the reaction, and performs catalytic cracking reaction to generate light fuel oil, gasoline, diesel, and the like. When the apparatus of the present invention simultaneously processes waste oil or heavy oil, the tubular heating furnace 12 for preheating the waste oil and the heavy oil is placed before the reaction vessel 301, so that the waste plastic and the waste oil can be separately entered separately. The reaction vessel 301 can also be mixed into the reaction vessel 301 while being mixed in any ratio, and cracked into various light fuel oils or gasoline diesel oil. The oil and gas mixture generated by the reaction kettle 301 is introduced into the fractionation column 601 (shown in Figs. 1, 8) from the top, and the gasoline and gas are discharged from the top of the column 601, and the kerosene is extracted from the side line of the tower, light and heavy. Diesel, light and heavy diesel oil is liquid phase inflow into kerosene, light and heavy diesel stripper 616, 617, 618 stripping, kerosene and light diesel oil combined and heavy diesel oil flow through condensing cooling water tank 619 to cool. The gasoline vapor and gas at the top of the fractionation column 601 are cooled by the condensing cooling water tank 619, and then flowed into the oil-gas separation column 701 (as shown in Figs. 1 and 9), and the gasoline is refluxed into the fractionation column 601 to control the temperature at the top of the column to control the quality of the gasoline. The separated crude gasoline is fed into the extraction refining device 9; the gas is introduced into the liquefied gas recovery device 8 (shown in Figs. 1 and 10) after being absorbed and purified by the gas absorption towers 702 and 703, and is processed by the liquefied gas recovery device 8 For people to use liquefied gas and dry gas, this part of dry gas can be used as a fuel gas for own use. After the gasoline and light diesel oil are extracted and refined by oil extraction and refining devices 901, 902, 903, and 904 (as shown in Fig. 1 and Fig. 11), they are appropriately blended into refined oil by the additive blending tanks 905 and 906. The finished product is thus discharged from the device. As shown in FIG. 1 and FIG. 12, the flue gas entering the dust removal tower 1001 from the flue outlet 409 of the non-open flame radiant heating device 4, after the dust removal by the spray dusting and the water seal, the black dust particles in the flue gas and The removal of harmful components minimizes the environmental pollution of the discharged fumes. The accumulated water at the bottom of the dust removal tower 1001 is filtered and sent to the circulating water pump 1004 for further use, and the carbon black in the filter can be used as a fuel. After the oil and water separation from the bottom outlet of the oil extraction and refining device 9 into the grease trap 1009, the water enters the oil water separator 1008, and the water from the oil water separator 1008 is sent to the circulating water pump 1004 for further use, and is separated from the grease trap 1009 and the oil water. The oil separated by the vessel 1008 is returned to the reactor 301 to continue cracking.
本发明可以根据需要全部或部分选用本发明系统中的各个装置, 并可以为本发 明系统增加一些装置, 比如设置一废气焦渣锅炉 13, 用本发明装置产出的焦渣和多 余的瓦斯为燃料, 生产蒸汽等。 The present invention may select all or part of the apparatus of the system of the present invention as needed, and may add some means to the system of the present invention, such as providing an exhaust gas coke breeze 13 with coke and excess gas produced by the apparatus of the present invention. Fuel, steam production, etc.
工业应用 Industrial application
本发明利用废塑料或废润滑油或重质油等, 可连续工业化大规模生产汽油馏 分、 柴油熘分或高质燃油及民用液化气。 同时在设备中配置了 "三废"处理装置, 使本发明的烟气、 废油、 废水经处理后, 排放的废气对环境污染达到最小, 废水循 环使用, 分离出的油重新回到反应釜裂解。 The invention utilizes waste plastic or waste lubricating oil or heavy oil, etc., and can continuously industrialize large-scale production of gasoline fraction, diesel oil or high quality fuel oil and civil liquefied gas. At the same time, the "three wastes" treatment device is arranged in the equipment, so that the exhaust gas, the waste oil and the waste water of the invention are treated, the exhaust gas discharged to the environment is minimized, the waste water is recycled, and the separated oil is returned to the reactor for cracking. .
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100580183A CN1250677C (en) | 2004-08-06 | 2004-08-06 | Waste plastic oiling device for continuous industrial production at large scale |
| CN200410058018.3 | 2004-08-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2006012800A1 true WO2006012800A1 (en) | 2006-02-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2005/001195 Ceased WO2006012800A1 (en) | 2004-08-06 | 2005-08-04 | An apparatus for preparing oil from waste plastics in continuous and industrial production |
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| CN (1) | CN1250677C (en) |
| WO (1) | WO2006012800A1 (en) |
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| CN111377589A (en) * | 2018-12-31 | 2020-07-07 | 潍坊奥华环保新材料科技有限公司 | A process for automatic gas injection feeding for producing rock wool electric melting furnace |
| CN110180307A (en) * | 2019-06-24 | 2019-08-30 | 中国船舶重工集团公司第七0三研究所 | A kind of static oil-gas separator applied to gas turbine |
| CN110180307B (en) * | 2019-06-24 | 2024-05-28 | 中国船舶重工集团公司第七0三研究所 | Static oil-gas separator applied to gas turbine |
| CN111500305B (en) * | 2020-04-28 | 2024-02-20 | 徐宗胜 | Waste plastic processing equipment |
| CN111500305A (en) * | 2020-04-28 | 2020-08-07 | 徐宗胜 | Waste plastic treatment equipment |
| CN116514186A (en) * | 2022-01-24 | 2023-08-01 | 江苏龙腾城矿环境技术有限公司 | A sludge recovery system for waste water containing mineral oil |
| CN115155100A (en) * | 2022-06-02 | 2022-10-11 | 贵阳晨光生物科技有限公司 | An automated supercritical extraction method |
| CN117603723A (en) * | 2023-10-11 | 2024-02-27 | 河南国立百特环保科技有限公司 | Two-step catalytic cracking distillation wax removal process flow |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1587350A (en) | 2005-03-02 |
| CN1250677C (en) | 2006-04-12 |
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