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WO2006004840A3 - Processus de conversion selective d'alkanes en acides carboxyliques insatures - Google Patents

Processus de conversion selective d'alkanes en acides carboxyliques insatures Download PDF

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Publication number
WO2006004840A3
WO2006004840A3 PCT/US2005/023121 US2005023121W WO2006004840A3 WO 2006004840 A3 WO2006004840 A3 WO 2006004840A3 US 2005023121 W US2005023121 W US 2005023121W WO 2006004840 A3 WO2006004840 A3 WO 2006004840A3
Authority
WO
WIPO (PCT)
Prior art keywords
unsaturated carboxylic
selective conversion
alkanes
carboxylic acids
metal oxide
Prior art date
Application number
PCT/US2005/023121
Other languages
English (en)
Other versions
WO2006004840A2 (fr
Inventor
Paulette N Hazin
Original Assignee
Saudi Basic Ind Corp
Paulette N Hazin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp, Paulette N Hazin filed Critical Saudi Basic Ind Corp
Priority to EP05787797.9A priority Critical patent/EP1771405B1/fr
Priority to JP2007520366A priority patent/JP4758990B2/ja
Priority to ES05787797.9T priority patent/ES2439697T3/es
Publication of WO2006004840A2 publication Critical patent/WO2006004840A2/fr
Publication of WO2006004840A3 publication Critical patent/WO2006004840A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un processus de conversion sélective d'un alkane en acides carboxyliques insaturés dans un processus en une étape avec une composition de catalyseur métal oxyde mélangé représenté par la formule générale suivante : MOVaNbbTecSbdMeOX. Dans cette formule M est optionnel et peut-être un ou plusieurs des éléments suivants sélectionnés parmi argent, silicium, soufre, zirconium, titane, aluminium, cuivre, lithium, sodium, potassium,rubidium, césium, gallium, phosphore, fer, rhénium, cobalt, chrome, manganèse, arsenic, indium, thallium, bismuth, germanium, étain, cérium ou lanthanum. Ce catalyseur peut être préparé par coprécipitation de composés métalliques qui sont calcinés de façon à former un catalyseur métal oxyde mélangé.
PCT/US2005/023121 2004-06-30 2005-06-30 Processus de conversion selective d'alkanes en acides carboxyliques insatures WO2006004840A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP05787797.9A EP1771405B1 (fr) 2004-06-30 2005-06-30 Processus de conversion selective d'alkanes en acides carboxyliques insatures
JP2007520366A JP4758990B2 (ja) 2004-06-30 2005-06-30 アルカンの不飽和カルボン酸への選択的転化法
ES05787797.9T ES2439697T3 (es) 2004-06-30 2005-06-30 Procedimiento para la conversión selectiva de alcanos en ácidos carboxílicos insaturados

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/881,815 2004-06-30
US10/881,815 US7009075B2 (en) 2004-06-30 2004-06-30 Process for the selective conversion of alkanes to unsaturated carboxylic acids

Publications (2)

Publication Number Publication Date
WO2006004840A2 WO2006004840A2 (fr) 2006-01-12
WO2006004840A3 true WO2006004840A3 (fr) 2006-03-16

Family

ID=35514906

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/023121 WO2006004840A2 (fr) 2004-06-30 2005-06-30 Processus de conversion selective d'alkanes en acides carboxyliques insatures

Country Status (6)

Country Link
US (1) US7009075B2 (fr)
EP (1) EP1771405B1 (fr)
JP (1) JP4758990B2 (fr)
CN (1) CN100558692C (fr)
ES (1) ES2439697T3 (fr)
WO (1) WO2006004840A2 (fr)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
FR2897350B1 (fr) * 2006-02-14 2008-05-16 Centre Nat Rech Scient Preparation d'un compose comprenant l'association de deux phases cristallines
US7807601B2 (en) * 2006-12-27 2010-10-05 Exxonmobil Research And Engineering Company Mixed metal oxide catalysts and processes for their preparation and use
US20090042723A1 (en) * 2007-02-06 2009-02-12 Kun Wang Process for preparing mixed metal oxide catalysts
US7754910B2 (en) * 2007-02-16 2010-07-13 Ineos Usa Llc Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US7531681B2 (en) * 2007-02-16 2009-05-12 Ineos Usa Llc Process for the ammoxidation of propane and isobutane
MY160792A (en) * 2007-02-16 2017-03-15 Ineos Usa Llc Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
JP2009051816A (ja) 2007-08-23 2009-03-12 Rohm & Haas Co 不飽和カルボン酸およびニトリルの製造方法
WO2010087262A1 (fr) * 2009-01-30 2010-08-05 旭化成ケミカルズ株式会社 Procédé de fabrication de catalyseur à support de silice, et procédé de fabrication d'un acide carboxylique insaturé et d'un nitrile insaturé
DE102011109816B4 (de) 2011-08-09 2017-04-06 Clariant Produkte (Deutschland) Gmbh Katalysatormaterial für die Oxidation von Kohlenwasserstoffen
EP2900374A1 (fr) 2012-09-28 2015-08-05 Rohm and Haas Company Préparation de catalyseurs d'oxydation de propane
SG11201502415UA (en) 2012-09-28 2015-04-29 Rohm & Haas Preparation of propane oxidation catalysts
CN105143157B (zh) * 2013-04-24 2018-11-13 沙特基础工业公司 从天然资源产生产物
CN105749944A (zh) * 2016-03-23 2016-07-13 重庆紫光海力催化剂有限公司 一种由2-甲基丙烯醛气相催化氧化法制备α－甲基丙烯酸的催化剂
DE102017000862A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit reduziertem Gehalt an Niob und Tellur und höherer Aktivität für die oxidative Dehydrierung von Ethan
DE102017000861A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVTeNb-Katalysators aus preisgünstigen Metalloxiden
DE102017000848A1 (de) * 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung molybdänhaltiger Mischoxidmaterialien
DE102017000865A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit erhöhter spezifischer Oberfläche und höherer Aktivität für die oxidative Dehyxdrierung von Ethan zu Ethylen
US11909046B2 (en) 2017-03-07 2024-02-20 The Research Foundation For The State University Of New York Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions
US10329217B2 (en) 2017-04-11 2019-06-25 Uchicago Argonne, Llc Multimetallic catalysts for selective hydrogenation of dienes and acetylenes, and purification of olefin feedstocks
US10828621B2 (en) 2017-08-28 2020-11-10 Uchicago Argonne, Llc Supported multimetallic catalysts for oxidative dehydrogenation of alkanes
DE102017121709A1 (de) 2017-09-19 2019-03-21 Clariant International Ltd Synthese eines MoVNbTe-Schalenkatalysators für die oxidative Dehydrierung von Ethan zu Ehtylen
AR115798A1 (es) 2018-07-19 2021-02-24 Nova Chem Int Sa Catalizadores para la deshidrogenación oxidativa de alcanos
CA3050795A1 (fr) 2018-08-03 2020-02-03 Nova Chemicals Corporation Catalyseurs de deshydrogenation oxydatifs
CA3050720A1 (fr) 2018-08-03 2020-02-03 Nova Chemicals Corporation Compositions de catalyseurs de deshydrogenation oxydatifs
CN113070079B (zh) * 2021-04-13 2022-01-11 宁波昊祥新材料科技有限公司 Mo-V-Te-Sb-Nb-O催化剂的制备方法及系统
CN113083284B (zh) * 2021-04-13 2022-03-08 宁波昊祥新材料科技有限公司 Mo-V-Te-Sb-Nb-O催化剂、其制备方法与应用
CN115999548B (zh) * 2021-10-21 2025-03-18 中石化南京化工研究院有限公司 一种硝基苯加氢制苯胺的催化剂及其制备方法与应用
CN115463672A (zh) * 2022-08-02 2022-12-13 宁波昊祥新材料科技有限公司 一种丙烷为原料制取丙烯酸的催化剂获得方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6166241A (en) * 1996-11-15 2000-12-26 Mitsubishi Chemical Corporation Process for the simultaneous preparation of acrylonitrile and arcylic acid

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW218008B (fr) * 1991-05-09 1993-12-21 Mitsubishi Chemicals Co Ltd
US5281745A (en) * 1991-08-08 1994-01-25 Mitsubishi Kasei Corporation Process for producing nitriles
DE69402567T2 (de) * 1993-01-28 1997-11-27 Mitsubishi Chem Corp Methode zur Herstellung einer ungesättigten Carbonsäure
JP3769866B2 (ja) * 1996-04-18 2006-04-26 三菱化学株式会社 気相接触酸化用触媒の製造方法
JPH1045664A (ja) 1996-07-30 1998-02-17 Mitsubishi Chem Corp α，β−不飽和カルボン酸の製造方法
JPH1057813A (ja) 1996-08-22 1998-03-03 Mitsubishi Chem Corp 複合金属酸化物触媒の製造方法、及び該触媒を用いるアクリル酸の製造方法
FR2754817B1 (fr) * 1996-10-21 2000-03-17 Toagosei Co Ltd Procede de production d'acide acrylique a partir de propane et d'oxygene gazeux
DE19835247B4 (de) * 1997-08-05 2022-04-28 Asahi Kasei Kabushiki Kaisha Ammonoxidationskatalysator und Verfahren zur Herstellung von Acrylnitril oder Methacrylnitril aus Propan oder Isobutan durch Ammonoxidation
JP2001058827A (ja) * 1999-06-17 2001-03-06 Mitsubishi Chemicals Corp 複合酸化物の製造方法
WO2002006199A2 (fr) * 2000-07-18 2002-01-24 Basf Aktiengesellschaft Procede de production d'acide acrylique par oxydation en phase gazeuse de propane, catalysee de maniere heterogene
EP1346766B1 (fr) * 2000-12-22 2009-02-11 Nippon Kayaku Kabushiki Kaisha Procede de production d'un compose insature contenant de l'oxygene
DE10117357A1 (de) * 2001-04-06 2002-10-10 Basf Ag Verfahren zur Herstellung von Acrylsäure oder Methacrylsäure durch Gasphasenoxidation von Propan oder Isobutan
EP1270068B1 (fr) * 2001-06-18 2006-04-19 Rohm And Haas Company Préparation de catalyseurs à base d'oxydes de Mo-V-M-X synthétisés de façon hydrothermale pour l'oxydation sélective d'hydrocarbures
EP1407819A3 (fr) * 2002-10-01 2004-06-23 Rohm And Haas Company Catalyseurs à base d'un oxyde de Mo-V-M-Nb-X préparés par une méthode hydrothermale pour l'oxydation sélective d'hydrocarbures
US20050137422A1 (en) * 2003-12-19 2005-06-23 Saudi Basic Industries Corporation Process for producing an unsaturated carboxylic acid from an alkane

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6166241A (en) * 1996-11-15 2000-12-26 Mitsubishi Chemical Corporation Process for the simultaneous preparation of acrylonitrile and arcylic acid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1771405A4 *

Also Published As

Publication number Publication date
US7009075B2 (en) 2006-03-07
ES2439697T3 (es) 2014-01-24
EP1771405A4 (fr) 2008-05-28
JP4758990B2 (ja) 2011-08-31
EP1771405A2 (fr) 2007-04-11
EP1771405B1 (fr) 2013-10-30
JP2008505178A (ja) 2008-02-21
CN1976889A (zh) 2007-06-06
CN100558692C (zh) 2009-11-11
WO2006004840A2 (fr) 2006-01-12
US20060004228A1 (en) 2006-01-05

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