[go: up one dir, main page]

WO2006099964A1 - Soluble speckle granule - Google Patents

Soluble speckle granule Download PDF

Info

Publication number
WO2006099964A1
WO2006099964A1 PCT/EP2006/002302 EP2006002302W WO2006099964A1 WO 2006099964 A1 WO2006099964 A1 WO 2006099964A1 EP 2006002302 W EP2006002302 W EP 2006002302W WO 2006099964 A1 WO2006099964 A1 WO 2006099964A1
Authority
WO
WIPO (PCT)
Prior art keywords
granule
speckle
mica
speckle granule
clay
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2006/002302
Other languages
French (fr)
Inventor
Paulo Cesar Puelle Andrade
Mario Jovelino Del Nunzio
Adrey Marcel Marchi Sanches
Andrea De Freitas Silva
Andrew Thomas Steel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hindustan Unilever Ltd
Unilever NV
Original Assignee
Hindustan Lever Ltd
Hindustan Unilever Ltd
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hindustan Lever Ltd, Hindustan Unilever Ltd, Unilever NV filed Critical Hindustan Lever Ltd
Priority to GB0717486A priority Critical patent/GB2441444B/en
Priority to CN200680009170XA priority patent/CN101146904B/en
Priority to BRPI0609708A priority patent/BRPI0609708B8/en
Publication of WO2006099964A1 publication Critical patent/WO2006099964A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0063—Photo- activating compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites

Definitions

  • the present invention relates to a soluble speckle granule for use in granular detergent compositions .
  • Particulate detergent compositions may contain coloured speckles. This may be achieved by adding coloured dyes. However, such dyes may cause stains on fabrics being washed. Speckles may alternatively contain pigments such as copper phthalocyanine . Although chosen for their poor fabric substantivity, pigments may nevertheless stain some fabrics and may be environmentally unsound.
  • WO 00 61718 suggests that the problems associated with use of dyes, particularly aqueous dyes, can be overcome by use of a coating of particles that reflect light.
  • Mica or titanium dioxide coated granules are described.
  • the exemplified base granules may be sodium citrate dihydrate, sodium carbonate or sodium sulphate.
  • the coated granule may be formed by dusting a particulate material with the light reflecting component and then optionally applying binding material to the dusted particle. It is stated that the alternative process of mixing the light reflecting material with the base ingredients is less preferred because then only a part of the light reflecting material will be at the surface of the particle.
  • WO 00 27980 discloses a cleaning composition speckle particle which comprises a solid material which is coloured with a colorant, the particle having a sparkle index of at least 5%, and a transparency index of at least 5%.
  • the speckle particle preferably comprises a crystalline hydrated inorganic salt, a crystalline organic acid salt, a crystalline organic salt, a crystalline surfactant, a saccharide, or mixtures thereof. It is particularly preferred that the particle comprises trisodium citrate dihydrate, most preferably coloured with a dye.
  • Other ingredients commonly employed in detergent compositions that are crystalline materials, such as crystalline silicate, including crystalline layered silicate may also be useful, according to this disclosure.
  • a soluble speckle granule comprising at least one clay mineral carrier material coated in mica particles.
  • the granule comprises from 0.5 to 1.5 wt% mica.
  • the speckle granule preferably has an average particle size of from 0.8 mm to 3.0 mm. More preferably, it has an average particle size of from 1.0 mm to 2.0 mm.
  • a soluble builder salt admixed with the clay in the granule.
  • the preferred material is sodium tripolyphosphate (STP) and it is preferably mixed with the clay mineral in a ratio clay: STP from 1:2 to 5:1, most preferably about 1:1.
  • STP sodium tripolyphosphate
  • the clay mineral carrier is preferably one or more clays selected from bi-layer clays (e.g. china clay and halloysite) which may be dioctahedral clays (such as kaolin) or trioctahedral clays (such as antigorite and amesite) ; tri -layer clays such as smectite and hormite, bentonite, beidelite, nontronite, hectorite, attapulgite, pimelite, mica, muscovite and vermiculite as well as pyrophyllite/ talc, willemseite and minnesotaite clays.
  • a preferred class of clays is the bentonites.
  • the clay should be capable of providing a benefit in the wash.
  • the clay is chosen from the class of clays that will give a fabric softening benefit.
  • the particle size of the clay preferably lies in the range 1 to 2 mm. However, it is an aid to dispersion if lower swelling clay swelling is used, especially if the amount of STP is reduced or absent; a swelling of 20 ml or less is preferred in this case .
  • Finely divided mica pigment material may be used as the Mica Particles.
  • the mica is coated. More preferably, it is coated with a very thin layer of titanium dioxide. Most preferably, it is coated with a mixture of titanium dioxide and iron oxide to give a gold lustre.
  • Suitable titanium coated pigments are available from Merck as Timiron MP 115 and as Iriodin ® 300 with the additional iron oxide coating. Suitable pigments have a particle size of from 10 to 60 microns.
  • Anhydrous Sodium Tripolyphosphate is preferred.
  • a standard grade of the usual particle size for detergent formulations is suitable.
  • the speckle granule may have a water-soluble polymeric coating.
  • the coating may be polyvinyl alcohol or microcrystalline cellulose.
  • microcrystalline cellulose is preferred for granules with low levels of STP or no STP and polyvinyl alcohol is preferred when STP is used at the optimum amount. This selection gives the required combination of fast dispersion and good coating adhesion.
  • the polymeric coating seeps into the pores of the clay carrier and anchors itself onto the surface of the speckle .
  • the dry ingredients are preblended for about one minute. This includes the mica pigment, the bentonite clay, and the soluble STP builder salt.
  • a double cone mixer with multiple spay heads has been found to be ideal for the process.
  • the optional coating material or water is sprayed at pressure onto the particles for about 25 minutes in a dilute solution and the mixture is then further mixed for a few minutes to obtain the speckle granules.
  • the speckle granule may be combined in any amount with any of the granular ingredients normally found in granular laundry detergent cleaning compositions .
  • it is used at a level of 1 to 4 % by weight, preferably 1.5 to 3 % by weight in the detergent powder composition. This is particularly useful if the clay is a softening type of clay, so that it provides a benefit to the fabric.
  • Bentonite in particulate form with particle sizes ranging from 1.0 to 2.0 mm was obtained from Bentonit Uniao as Pelben 10 (Examples 5 and 7) or Pelben 35.
  • Pelben 10 has a swelling of 10 ml whereas Pelben 35 has a swelling of 35 ml plus.
  • Coating A was microcrystalline cellulose and Coating B was polyvinyl alcohol. Their compositions are detailed in table 2.
  • the process is controlled so that the speckle granules produced have substantially the same particle size as the original Bentonite granules.
  • the dispersal times for granules without STP are too long to be of practical use in some wash processes, especially after they have been coated so that the mica did not rub off the surface during subsequent manual handling. Since it is often necessary to use such a coating to avoid the coating rubbing off and thereby rendering the granule indistinct and unsuitable for use as a speckle, it is clearly advantageous to use STP in the speckle granule.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Use of a soluble speckle granule in a particulate laundry detergent composition, characterised in that the granule comprises a clay mineral carrier material and a mica pigment. Preferably the granule further comprises sodium tripolyphosphate and it may be provided with a water-soluble polymer coating.

Description

SOLUBLE SPECKLE GRANULE
The present invention relates to a soluble speckle granule for use in granular detergent compositions .
Particulate detergent compositions may contain coloured speckles. This may be achieved by adding coloured dyes. However, such dyes may cause stains on fabrics being washed. Speckles may alternatively contain pigments such as copper phthalocyanine . Although chosen for their poor fabric substantivity, pigments may nevertheless stain some fabrics and may be environmentally unsound.
WO 00 61718 (Procter & Gamble) suggests that the problems associated with use of dyes, particularly aqueous dyes, can be overcome by use of a coating of particles that reflect light. Mica or titanium dioxide coated granules are described. The exemplified base granules may be sodium citrate dihydrate, sodium carbonate or sodium sulphate. The coated granule may be formed by dusting a particulate material with the light reflecting component and then optionally applying binding material to the dusted particle. It is stated that the alternative process of mixing the light reflecting material with the base ingredients is less preferred because then only a part of the light reflecting material will be at the surface of the particle.
WO 00 27980 (Procter & Gamble) discloses a cleaning composition speckle particle which comprises a solid material which is coloured with a colorant, the particle having a sparkle index of at least 5%, and a transparency index of at least 5%. The speckle particle preferably comprises a crystalline hydrated inorganic salt, a crystalline organic acid salt, a crystalline organic salt, a crystalline surfactant, a saccharide, or mixtures thereof. It is particularly preferred that the particle comprises trisodium citrate dihydrate, most preferably coloured with a dye. Other ingredients commonly employed in detergent compositions that are crystalline materials, such as crystalline silicate, including crystalline layered silicate may also be useful, according to this disclosure.
According to the present invention there is provided a soluble speckle granule comprising at least one clay mineral carrier material coated in mica particles. This provides an attractive, different and robust speckle for use in detergent compositions. Preferably, the granule comprises from 0.5 to 1.5 wt% mica.
The speckle granule preferably has an average particle size of from 0.8 mm to 3.0 mm. More preferably, it has an average particle size of from 1.0 mm to 2.0 mm.
To improve the speed of dispersion of the granule in wash liquor it is advantageous to include a soluble builder salt admixed with the clay in the granule. The preferred material is sodium tripolyphosphate (STP) and it is preferably mixed with the clay mineral in a ratio clay: STP from 1:2 to 5:1, most preferably about 1:1. The Clay Mineral
The clay mineral carrier is preferably one or more clays selected from bi-layer clays (e.g. china clay and halloysite) which may be dioctahedral clays (such as kaolin) or trioctahedral clays (such as antigorite and amesite) ; tri -layer clays such as smectite and hormite, bentonite, beidelite, nontronite, hectorite, attapulgite, pimelite, mica, muscovite and vermiculite as well as pyrophyllite/ talc, willemseite and minnesotaite clays. A preferred class of clays is the bentonites. It is highly desirable that the clay should be capable of providing a benefit in the wash. Preferably, the clay is chosen from the class of clays that will give a fabric softening benefit. The particle size of the clay preferably lies in the range 1 to 2 mm. However, it is an aid to dispersion if lower swelling clay swelling is used, especially if the amount of STP is reduced or absent; a swelling of 20 ml or less is preferred in this case .
The Mica Particles
Finely divided mica pigment material may be used as the Mica Particles. Preferably, the mica is coated. More preferably, it is coated with a very thin layer of titanium dioxide. Most preferably, it is coated with a mixture of titanium dioxide and iron oxide to give a gold lustre. Suitable titanium coated pigments are available from Merck as Timiron MP 115 and as Iriodin® 300 with the additional iron oxide coating. Suitable pigments have a particle size of from 10 to 60 microns. The Sodium Tripolyphosphate
Anhydrous Sodium Tripolyphosphate is preferred. A standard grade of the usual particle size for detergent formulations is suitable.
The Polymeric Coating
Optionally the speckle granule may have a water-soluble polymeric coating. This may help to prevent the mica pigment from leaving the clay, thereby reducing the speckle effect, during storage and handling. The coating may be polyvinyl alcohol or microcrystalline cellulose. We have found that microcrystalline cellulose is preferred for granules with low levels of STP or no STP and polyvinyl alcohol is preferred when STP is used at the optimum amount. This selection gives the required combination of fast dispersion and good coating adhesion.
Without wishing to be bound by any particular theory, it is believed that the polymeric coating seeps into the pores of the clay carrier and anchors itself onto the surface of the speckle .
The Speckle Manufacturing Process
Although many processes could be used to make the speckle we have found that one process is particularly advantageous to get a high yield of dry and well coated particles of the required particle size, durability and dispersibility when the appropriate composition is used. In this process, the dry ingredients are preblended for about one minute. This includes the mica pigment, the bentonite clay, and the soluble STP builder salt. A double cone mixer with multiple spay heads has been found to be ideal for the process. After pre-blending of the dry ingredients the optional coating material (or water) is sprayed at pressure onto the particles for about 25 minutes in a dilute solution and the mixture is then further mixed for a few minutes to obtain the speckle granules.
Detergent Ingredients
The speckle granule may be combined in any amount with any of the granular ingredients normally found in granular laundry detergent cleaning compositions . Advantageously it is used at a level of 1 to 4 % by weight, preferably 1.5 to 3 % by weight in the detergent powder composition. This is particularly useful if the clay is a softening type of clay, so that it provides a benefit to the fabric.
The invention will now be further described with reference to the following non-limiting examples.
EXAMPLES
The ingredients in the amounts detailed in Table 1 were added to a double cone mixer and manufactured into speckle granules using the process outlined below.
TABLE 1
Figure imgf000007_0001
Bentonite in particulate form with particle sizes ranging from 1.0 to 2.0 mm was obtained from Bentonit Uniao as Pelben 10 (Examples 5 and 7) or Pelben 35. Pelben 10 has a swelling of 10 ml whereas Pelben 35 has a swelling of 35 ml plus.
2
Mica with particle size 10 to 60 microns was obtained from
Merck as Iriodin 300 and Timiron Starluster MP-115. The Bentonite, mica and, when used, STP were gently blended in the mixer for 1 minute. Then, the coating solution was sprayed into the mixer and mixing continued for 25 minutes. Two different types of coating solution were used: Coating A was microcrystalline cellulose and Coating B was polyvinyl alcohol. Their compositions are detailed in table 2.
TABLE 2
The process is controlled so that the speckle granules produced have substantially the same particle size as the original Bentonite granules. However, as seen from table 1 the dispersal times for granules without STP are too long to be of practical use in some wash processes, especially after they have been coated so that the mica did not rub off the surface during subsequent manual handling. Since it is often necessary to use such a coating to avoid the coating rubbing off and thereby rendering the granule indistinct and unsuitable for use as a speckle, it is clearly advantageous to use STP in the speckle granule.

Claims

1. Use of a soluble speckle granule in a particulate laundry detergent composition, characterised in that the granule comprises a clay mineral carrier material and mica.
2. Use of a speckle granule as claimed in claim 1 wherein the granule further comprises sodium tripolyphosphate .
3. Use as claimed in claim 1 or claim 2, wherein the granule has a water-soluble polymer coating.
4. Use as claimed in claim 3, wherein the polymer is a polymeric alcohol .
5. Use as claimed in claim 3, wherein the polymer is cellulose .
6. Use of a speckle granule as claimed in any preceding claim, wherein the granule has an average particle size of from 0.8 mm to 3.0 mm.
7. Use of a speckle granule as claimed in claim 5, which has an average particle size of from 1.0 mm to 2.0 mm.
8. Use of a speckle granule as claimed in any preceding claim, which comprises from 0.5 to 1.5 wt% mica.
9. Use of a speckle granule as claimed in any preceding claim, wherein the clay mineral comprises a softening clay.
10. Use of a speckle granule as claimed in claim 9, wherein the clay mineral comprises bentonite clay.
11. Use of a speckle granule as claimed in any preceding claim, wherein the mica is coated, preferably with titanium dioxide.
12. Use of a speckle granule as claimed in claim 11 in which the mica is coated with titanium dioxide and iron oxide .
13. Use of a speckle granule as claimed in any preceding claim wherein the detergent composition comprises from 1 to 4 wt% of the speckle granule.
14. Use of a speckle granule as claimed in claim 13, wherein the detergent composition comprises from 1.5 to 3 wt% of the speckle granule.
PCT/EP2006/002302 2005-03-22 2006-03-13 Soluble speckle granule Ceased WO2006099964A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB0717486A GB2441444B (en) 2005-03-22 2006-03-13 Detergent composition comprising soluble speckle granule
CN200680009170XA CN101146904B (en) 2005-03-22 2006-03-13 Soluble speckle granule
BRPI0609708A BRPI0609708B8 (en) 2005-03-22 2006-03-13 use of a soluble splash granule in a particulate laundry detergent composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0505778.1 2005-03-22
GBGB0505778.1A GB0505778D0 (en) 2005-03-22 2005-03-22 Soluble speckle granule

Publications (1)

Publication Number Publication Date
WO2006099964A1 true WO2006099964A1 (en) 2006-09-28

Family

ID=34531601

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/002302 Ceased WO2006099964A1 (en) 2005-03-22 2006-03-13 Soluble speckle granule

Country Status (5)

Country Link
CN (1) CN101146904B (en)
BR (1) BRPI0609708B8 (en)
GB (2) GB0505778D0 (en)
WO (1) WO2006099964A1 (en)
ZA (1) ZA200707937B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011028249A1 (en) 2009-08-25 2011-03-10 Milliken & Company Colored speckles
WO2011149871A1 (en) 2010-05-28 2011-12-01 Milliken & Company Colored speckles having delayed release properties
US8470760B2 (en) 2010-05-28 2013-06-25 Milliken 7 Company Colored speckles for use in granular detergents

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000061718A1 (en) * 1999-04-13 2000-10-19 The Procter & Gamble Company Light reflecting particles
WO2001077274A1 (en) * 2000-04-05 2001-10-18 The Procter & Gamble Company Speckled detergent composition
US20030087790A1 (en) * 2001-08-20 2003-05-08 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Photobleach speckle and laundry detergent compositions containing it

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1071452A (en) * 1991-10-17 1993-04-28 王学波 Detergent mixture and its production and use
US6770609B1 (en) * 1999-04-13 2004-08-03 Procter & Gamble Company Light reflecting particles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000061718A1 (en) * 1999-04-13 2000-10-19 The Procter & Gamble Company Light reflecting particles
WO2001077274A1 (en) * 2000-04-05 2001-10-18 The Procter & Gamble Company Speckled detergent composition
US20030087790A1 (en) * 2001-08-20 2003-05-08 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Photobleach speckle and laundry detergent compositions containing it

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011028249A1 (en) 2009-08-25 2011-03-10 Milliken & Company Colored speckles
US8318652B2 (en) 2009-08-25 2012-11-27 Milliken & Company Colored speckles comprising a porous carrier and a releasing agent layer
WO2011149871A1 (en) 2010-05-28 2011-12-01 Milliken & Company Colored speckles having delayed release properties
US8470760B2 (en) 2010-05-28 2013-06-25 Milliken 7 Company Colored speckles for use in granular detergents
US8476216B2 (en) 2010-05-28 2013-07-02 Milliken & Company Colored speckles having delayed release properties
US8921301B2 (en) 2010-05-28 2014-12-30 Milliken & Company Colored speckles for use in granular detergents
US11649417B2 (en) 2010-05-28 2023-05-16 Milliken & Company Colored speckles for use in granular detergents

Also Published As

Publication number Publication date
BRPI0609708B8 (en) 2016-11-16
BRPI0609708A2 (en) 2011-10-18
GB0505778D0 (en) 2005-04-27
ZA200707937B (en) 2009-06-24
BRPI0609708B1 (en) 2016-10-18
GB2441444B (en) 2010-03-10
CN101146904A (en) 2008-03-19
GB2441444A8 (en) 2008-03-06
CN101146904B (en) 2011-02-09
GB0717486D0 (en) 2007-10-17
GB2441444A (en) 2008-03-05

Similar Documents

Publication Publication Date Title
EP1070115B1 (en) Coloured granular composition for use in particulate detergent compositions
CA2253337C (en) Thickened abrasive-free cleaning composition containing a low concentration of calcium ions
CN101743299B (en) A solid detergent composition
FI72136B (en) PARTICELFORMIG TEXTILUPPMJUKANDE TVAETTMEDELKOMPOSITION FOERFARANDE FOER ATT TVAETTA OCH UPPMJUKA BYKE MED EN VATTENLOESNING AV EN SAODAN TVAETTMEDELKOMPOSITION
JP2007530773A (en) Detergent composition with concealed coloring ingredients
US8318652B2 (en) Colored speckles comprising a porous carrier and a releasing agent layer
JPH0445560B2 (en)
GB2142929A (en) Retarding setting or crutcher slurry for manufacturing base beads for detergent compositions
TWI449785B (en) Detergent builder granules
WO2006099964A1 (en) Soluble speckle granule
JPS60262897A (en) Granular nonionic detergent composition containing builder
SE462045B (en) SOFTY, PARTICULAR DETERGENT COMPOSITION AND SOFTY, PARTICULAR COMPOSITION FOR INHIBITION IN DETERGENT COMPOSITIONS
ES367854A1 (en) Laundry products
US5480578A (en) Detergent additive for detergents containing a fabric softener
US20070028392A1 (en) Particulate textile treatment composition comprising silicone, clay and anionic surfactant
GB2361242A (en) Floating detergent tablet
US3829385A (en) Detergent compositions containing n-chloro-imides
CN1200142A (en) Detergent composition comprising clay flocculating polymer with particle size less than 250 microns
JPH02286800A (en) Detergent granule
DK159553B (en) PARTICULATED EMERGENCY, SYNTHETIC, WHITE COLORED CLEANING PRODUCT AND PROCEDURE FOR ITS MANUFACTURING
JPS58145799A (en) Thixotropic gel type composition for dish washer
US20070028393A1 (en) Composition for use in the laundering or treatment of fabrics, and a process for making the composition
CA2376221A1 (en) Detergent composition containing zeolite map
JP3367801B2 (en) Method for producing high bulk density granular detergent and high bulk density granular detergent particles
JPS63248900A (en) Aqueous thixotropy liquid composition

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 0717486.5

Country of ref document: GB

WWE Wipo information: entry into national phase

Ref document number: 1405/MUMNP/2007

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 200680009170.X

Country of ref document: CN

NENP Non-entry into the national phase

Ref country code: DE

NENP Non-entry into the national phase

Ref country code: RU

WWW Wipo information: withdrawn in national office

Ref document number: RU

122 Ep: pct application non-entry in european phase

Ref document number: 06723396

Country of ref document: EP

Kind code of ref document: A1

WWW Wipo information: withdrawn in national office

Ref document number: 6723396

Country of ref document: EP

ENP Entry into the national phase

Ref document number: PI0609708

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20070921