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WO2006087333A1 - Machine de procede ou de travail dans laquelle le liquide de fonctionnement est un liquide ionique - Google Patents

Machine de procede ou de travail dans laquelle le liquide de fonctionnement est un liquide ionique Download PDF

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Publication number
WO2006087333A1
WO2006087333A1 PCT/EP2006/050941 EP2006050941W WO2006087333A1 WO 2006087333 A1 WO2006087333 A1 WO 2006087333A1 EP 2006050941 W EP2006050941 W EP 2006050941W WO 2006087333 A1 WO2006087333 A1 WO 2006087333A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
alkyl groups
aryl
fluid
ionic liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2006/050941
Other languages
German (de)
English (en)
Inventor
Claus Hilgers
Marc Uerdingen
Markus Wagner
Peter Wasserscheid
Eberhard Schlücker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvent Innovation GmbH
Original Assignee
Solvent Innovation GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvent Innovation GmbH filed Critical Solvent Innovation GmbH
Priority to EP06708277A priority Critical patent/EP1848789A1/fr
Priority to JP2007555599A priority patent/JP2008530441A/ja
Publication of WO2006087333A1 publication Critical patent/WO2006087333A1/fr
Priority to US11/839,228 priority patent/US20080038123A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/56Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
    • C10M105/70Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen as ring hetero atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/72Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/74Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/78Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing boron
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/023Amines, e.g. polyalkylene polyamines; Quaternary amines used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/2203Heterocyclic nitrogen compounds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • C10M2215/224Imidazoles
    • C10M2215/2245Imidazoles used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/0603Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/077Ionic Liquids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/44Super vacuum or supercritical use

Definitions

  • the invention relates to a process or working machine with a liquid as operating fluid.
  • liquids preferably oils, as a lubricating fluid, sealing fluid, barrier fluid, pressure transmission fluid , d. H. used in general as a working fluid.
  • Hydraulic diaphragm pumps In this case, oil or another liquid is used as hydraulic fluid for the membrane drive and as coupling fluid between the membranes;
  • Hydraulic diaphragm pumps are a typical example of the disadvantages described. Due to their hermetic properties and simultaneously high pressure rigidity and conveying accuracy, such hydraulic diaphragm pumps are preferably used for critical conveying tasks, such as conveying toxic, environmentally relevant or hygienic liquids, for conveying at high pressures and for precisely dosing any liquids. In this case, however, a multiple limiting factor is the hydraulic fluid which is used as pressure transfer fluid from the piston to the diaphragm. Usually this mineral oil or synthetic oil, for example, polyglycol with a variety of additives, or special oil is used. Due to the physiological dubiousness of this lubricant, glycerine is also used in food or biotechnology.
  • glycerol requires the use of inhibitors of biological decomposition. Nevertheless, the decomposition can not be prevented.
  • the thermal limit is here only 95 0 C.
  • the viscosity is hereby set in a complex manner by mixing with water.
  • piston machines are another typical example of the occurrence of the disadvantages described.
  • a possible technical solution for special applications would be to operate them for the purpose of gas or liquid conveyance with a liquid flask or a liquid feed piston, given a sufficient difference in density and immiscibility.
  • this has so far failed at the limits of the known operating fluids, and that is because in the application of aqueous liquids, the known disadvantages, such as evaporation, corrosion, toxicity, gas solubility, etc. arise.
  • organic liquids since the disadvantages of evaporation, toxicity, volatility, etc. occur.
  • the use of liquid metals has the disadvantages of toxicity, high cost, high density, difficult sealing, etc.
  • DE 10 2004 024 967 A1 discloses the use of ionic liquids as working fluid (ie the liquid to be conveyed) for absorption heat pumps, absorption refrigerating machines and heat transformers. Gas conveying machines, hydraulic diaphragm pumps, liquid ring vacuum Recirculating and piston machines that use ionic liquids as operating fluids are not disclosed in DE 10 2004 024 967 A1.
  • the present invention is therefore based on the object, a process or working machine of the generic type, which has a fluid as Railflüs- sity designed such that the disadvantages are avoided, without losing the benefits of reaching previously used operating fluids.
  • this invention relates to a device, in particular a pump, comprising an ionic liquid as the operating medium, in particular as a separating liquid and / or hydraulic fluid.
  • a first preferred embodiment of the present invention is a gas-conveying machine which is characterized in that it has an ionic liquid as the lubricating fluid.
  • a second preferred embodiment of the present invention is a hydraulic diaphragm pump which is characterized in that it has an ionic liquid as the hydraulic fluid.
  • a third preferred embodiment of the present invention is a liquid ring vacuum pump which is characterized in that it can be used as ring liquid. having an ionic liquid. This extends the working range of the pump to the fine vacuum range.
  • a fourth preferred embodiment of the present invention is a piston type machine characterized in that it is configured with a piston oscillating in a cylinder in the form of a liquid piston or an upstream liquid feed piston made of an ionic liquid. Due to the oscillating movement of the liquid piston, a gas, a low-density immiscible liquid or a high-density liquid can be promoted.
  • the invention further relates to methods of operating the above device using ionic liquids as the operating medium.
  • the invention is based on the essential idea of designing a process machine in such a way that the operating medium provided in it, that is, the operating fluid, is an ionic fluid. This results in amazing advantages, which are set out in detail below.
  • ionic liquids consist of ions, ie anions and cations, and are thus salts.
  • common salts for example sodium chloride, they have a lower melting point and can be liquid even at room temperature.
  • all salts which are liquid in pure form below 100 ° C. are considered to be ionic liquids.
  • Ionic liquids can be referred to as liquid salts. They have an extremely low vapor pressure (10 "13 bars), have only small gas solubility, are non-flammable, are often physiologically harmless, are often thermally stable up to 250 0 C and lubricity. The list of advantages that ionic liquids , is long, so ionic liquids make one umweit- and resource-saving replacement for the previously described fluids.
  • ionic liquids In the case of ionic liquids, a suitable gradual adjustment of the polarity and thus a tuning of their properties, in particular their solubility properties, is possible by suitable choice of cation and anion.
  • the spectrum ranges from water-miscible ionic liquids, to water-immiscible liquids, to those that form two phases even with organic solvents.
  • the clever use of these extraordinary properties of ionic liquids is the key to the successful use of these fluids in the sense of the invention.
  • Ionic liquids are therefore able to avoid the disadvantages described so far. Due to their extremely low vapor pressure of 10 "13 bar (liquid salt), they can achieve extremely low pressures in the vacuum technology and at the same time avoid contamination of the process gas in both vacuum pumps and compressors.
  • ionic liquids in process machines, it is now also possible to operate the aforementioned piston machines with a liquid piston, which consists of an ionic liquid, while avoiding the disadvantages described.
  • the use of ionic liquids also has the advantage that a reaction with the conveyed is excluded because they are highly inert.
  • liquid ring vacuum pumps due to the use according to the invention of ionic liquids as ring liquid, the use of these pumps is also made possible in the fine vacuum range.
  • liquid ring vacuum pumps can be used instead of the previously used screw compressors, reciprocating compressors, rotating vane compressors, etc. be able to fully exploit their great advantages in terms of robustness, reliability and process reliability.
  • a paddle wheel is eccentrically arranged in a cylindrical housing in a liquid ring vacuum pump.
  • the operating fluid in the housing forms due to the rotation of the impeller a co-rotating, concentric liquid ring. This completes together with the rotor blades, the gas volumes in the chambers. Due to the eccentricity of the rotor, the blades in the upper area completely submerge in the liquid ring, so that the chamber volume is filled with operating fluid.
  • the liquid ring lifts off the impeller hub and forms a crescent-shaped space.
  • the gaseous fluid to be delivered is sucked into the working space by the control disk openings arranged on the end faces of the impeller.
  • the suction slot ends, and the chamber is sealed by the control discs, the impeller blades, and the fluid. Then the liquid ring migrates back to the hub and compresses the gas like a piston. As soon as the pressure slot openings are reached, the compressed gas is expelled.
  • the operating fluid has to fulfill in liquid ring vacuum pumps above all three functions, namely, first, the function of a moving piston with the Working cycles sucking, compressing and pushing out, secondly the sealing function for sealing the pump chambers against each other and thirdly the absorption of the heat of compression.
  • a portion of the operating fluid is constantly discharged through the pressure slot, wherein the same amount of fresh liquid is supplied via a fluid channel in the shaft hub of the pump. Due to this permanent recooling, a constant temperature of the operating fluid is achieved.
  • the vapor pressure of the working fluid limits the lowest suction level to be achieved in the intake manifold of the pump. If the suction pressure drops to a value equal to or close to the vapor pressure of the liquid, it cavitates and thus a complete power loss of the pump.
  • oils that have a lower vapor pressure.
  • oils lead to contamination of the pumped medium and pose an environmental risk.
  • chemicals for example, concentrated sulfuric acid for chlorine gas compression.
  • the invention provides a remedy by extending the range of application of the liquid ring vacuum pumps in the fine vacuum range due to the inventively provided use of ionic liquids. Since such ionic fluids have no appreciable vapor pressure, no cavitation occurs, so that there is no limitation of the suction pressure down. Furthermore, ionic fluids have very good lubricating properties and thus enable a shaft seal adapted to the fine vacuum. In contrast to the use of oil, there is no contamination of the delivery fluid.
  • Liquid ring vacuum pumps Due to the inventively provided use of ionic liquids in process machines, in particular in liquid ring vacuum pumps, therefore their range of application is expanded into the fine vacuum range. Liquid ring vacuum pumps are thus entering a field of application previously covered by rotary and gate valves, Roots pumps or steam jet pumps.
  • these have the disadvantage that the necessary oil lubrication of the impeller in the housing leads to a contamination of the pumped medium and that the removal of the heat of compression can be realized only expensive apparatus.
  • inventively used as operating liquid ionic liquids are compounds which are composed of cations and anions, wherein the cation used
  • imidazole-Kem may be substituted with at least one group selected from d-C ⁇ -alkyl, CrC ⁇ -alkoxy, CrC ⁇ -aminoalkyl, C 5 - C 2 -aryl or C 5 -C 2 Aryl-C 1 -C 6 -alkyl groups,
  • pyridin-Kem may be substituted with at least one group selected from -C 6 alkyl, -C 6 alkoxy, C 6 aminoalkyl, C 5 - - Pyrazolium cations of the general formula
  • pyrazole core may be substituted with at least one group selected from -C 6 alkyl, -C 6 alkoxy, C 6 aminoalkyl, C 5 -
  • triazole nucleus may be substituted with at least one group selected from -C 6 alkyl, -C 6 alkoxy, C 6 aminoalkyl, C 5 - C 2 -aryl or C 5 -C 2- aryl-C 1 -C 6 -alkyl groups,
  • R 1 , R 2 , R 3 are independently selected from the group consisting of - hydrogen;
  • Heteroaryl, heteroarylCrC ⁇ -alkyl groups having 3 to 8 carbon atoms in the heteroaryl radical and at least one heteroatom selected from N, O and S which may be substituted by at least one group selected from C 1 -C 6 -alkyl groups and / or halogen atoms;
  • aryl-CrC ⁇ -alkyl groups having 5 to 12 carbon atoms in the aryl radical, which may be optionally substituted with at least one d-C ⁇ -alkyl groups and / or a halogen atom;
  • Heteroaryl-CrC ⁇ -alkyl groups having 3 to 8 carbon atoms in the aryl radical and at least one heteroatom selected from N, O and S, which may be substituted by at least one d-C ⁇ -alkyl groups and / or halogen atoms;
  • Aryl-CrC ⁇ -alkyl groups having 5 to 12 carbon atoms in the aryl radical, which may be optionally substituted by at least one d-C ⁇ -alkyl group and / or a halogen atom,
  • the anion of the ionic liquid used is an anion of the group [PF 6 ] -, [BF 4 ] -, [CF 3 CO 2 ] -, [CF 3 SO 3 ] -, [(CF 3 SO 2 J 2 N] -, [(CF 3 SO 2) (CF 3 COO) N] -, [R 4 - SO 3] "[R 4 -O-SO 3]” [R 4 COO] ", Cr, Br” , I " , [NO 3 ] " , [N (CN) 2 ] “ , [HSO 4 ] ' or [R 4 R 5 PO 4 ] " and the radicals R 4 and R 5 are independently selected from the group consisting of - hydrogen;
  • heteroaryl, heteroaryl-Ci-C 6 alkyl groups having 3 to 8 carbon atoms in the heteroaryl radical and at least one heteroatom selected from N, O and S, which is substituted with at least one group selected from d-C ⁇ -alkyl groups and / or halogen atoms could be;
  • aryl-CrC ⁇ -alkyl groups having 5 to 12 carbon atoms in the aryl radical, which may be substituted by at least one d-C ⁇ -alkyl group and / or a halogen atom.
  • Butyltrimethylphosphoniumdimethylphosphat miscible, stable, chemically inert with water to 200 0 C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Reciprocating Pumps (AREA)

Abstract

L'invention concerne une machine de procédé ou de travail dans laquelle un liquide est utilisé comme liquide de fonctionnement, l'invention étant caractérisée en ce que ce liquide de fonctionnement est un liquide ionique. L'invention concerne en outre l'utilisation de liquides de fonctionnement dans des machines de procédé ou de travail, un liquide ionique étant utilisé comme liquide de fonctionnement, en particulier comme liquide de lubrification, d'arrêt, d'étanchéité, de transmission de pression, etc.
PCT/EP2006/050941 2005-02-16 2006-02-15 Machine de procede ou de travail dans laquelle le liquide de fonctionnement est un liquide ionique Ceased WO2006087333A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP06708277A EP1848789A1 (fr) 2005-02-16 2006-02-15 Machine de procede ou de travail dans laquelle le liquide de fonctionnement est un liquide ionique
JP2007555599A JP2008530441A (ja) 2005-02-16 2006-02-15 作動液としてイオン液体を備えている加工機械および/または作業機械
US11/839,228 US20080038123A1 (en) 2005-02-16 2007-08-15 Processing and/or operating machine comprising an ionic liquid as the operating liquid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005007100.7 2005-02-16
DE102005007100A DE102005007100A1 (de) 2005-02-16 2005-02-16 Prozess- bzw. Arbeitsmaschine mit ionischer Flüssigkeit als Betriebsflüssigkeit

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/839,228 Continuation-In-Part US20080038123A1 (en) 2005-02-16 2007-08-15 Processing and/or operating machine comprising an ionic liquid as the operating liquid

Publications (1)

Publication Number Publication Date
WO2006087333A1 true WO2006087333A1 (fr) 2006-08-24

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Family Applications (1)

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PCT/EP2006/050941 Ceased WO2006087333A1 (fr) 2005-02-16 2006-02-15 Machine de procede ou de travail dans laquelle le liquide de fonctionnement est un liquide ionique

Country Status (5)

Country Link
US (1) US20080038123A1 (fr)
EP (1) EP1848789A1 (fr)
JP (1) JP2008530441A (fr)
DE (1) DE102005007100A1 (fr)
WO (1) WO2006087333A1 (fr)

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WO2008083961A1 (fr) * 2007-01-12 2008-07-17 Friedrich-Alexander-Universität Erlangen-Nürnberg Procédé de contrôle par impulsion à haute pression d'éléments mécaniques
WO2011012687A2 (fr) 2009-07-31 2011-02-03 Basf Se Composés phosphine-borane contenant des groupes imidazole et procédé de production de composés phosphorés contenant des groupes imidazole
WO2011026822A2 (fr) 2009-09-03 2011-03-10 Basf Se Liquides ioniques dotés d'une viscosité améliorée
WO2012016835A2 (fr) 2010-07-26 2012-02-09 Basf Se Liquides ioniques présentant une certaine teneur en polymères ioniques
WO2013060579A1 (fr) 2011-10-25 2013-05-02 Basf Se Utilisation en tant que fluide de travail de compositions liquides contenant des sels d'imidazolium
US8703670B2 (en) 2010-07-26 2014-04-22 Basf Se Ionic liquids having a content of ionic polymers
US8936719B2 (en) 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
US10214697B2 (en) 2013-03-15 2019-02-26 Ultraclean Fuel Pty Limited Process for removing sulphur compounds from hydrocarbons

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JP5465485B2 (ja) * 2009-08-11 2014-04-09 日本化学工業株式会社 潤滑油用添加剤、潤滑油組成物及びグリース組成物
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JP2012172030A (ja) * 2011-02-21 2012-09-10 Hitachi High-Technologies Corp 真空装置及びそれに用いる潤滑油
CN102732365B (zh) * 2012-07-10 2013-05-22 广州市联诺化工科技有限公司 一种功能化离子液体辅助增效的水性环保切削液及其制备方法
US20150045266A1 (en) * 2012-12-14 2015-02-12 Exxonmobil Research And Engineering Company Ionic liquid as lubricating oil base stocks, cobase stocks and multifunctional functional fluids
US20140171348A1 (en) * 2012-12-14 2014-06-19 Exxonmobil Research And Engineering Company Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids
US20140271257A1 (en) * 2013-03-14 2014-09-18 Oscomp Systems Inc. Natural gas compressing and refueling system and method
DE102013211084A1 (de) * 2013-06-14 2014-12-18 Siemens Aktiengesellschaft Verfahren zum Betrieb einer Wärmepumpe und Wärmepumpe
US9957460B2 (en) * 2014-02-20 2018-05-01 Ut-Battelle, Llc Ionic liquids containing symmetric quaternary phosphonium cations and phosphorus-containing anions, and their use as lubricant additives
FR3028523B1 (fr) * 2014-11-19 2018-01-19 Nyco Procede pour ameliorer la resistance a la cokefaction d'une composition lubrifiante
DK4136202T3 (da) * 2020-04-16 2024-08-26 Totalenergies Onetech En fosfonium-baseret ionisk væske og dens anvendelse som et smøreadditiv
CN112375602B (zh) * 2020-11-20 2022-07-15 常熟理工学院 一种离子液体基纳米流体切削液及其制备方法
CN114958454B (zh) * 2022-05-26 2023-10-10 金宏气体股份有限公司 离子液体组合物及其制备方法
CN118994020A (zh) * 2024-08-16 2024-11-22 中国科学院兰州化学物理研究所 氢压机用离子液体的合成及筛选方法

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US8936719B2 (en) 2006-03-22 2015-01-20 Ultraclean Fuel Pty Ltd. Process for removing sulphur from liquid hydrocarbons
WO2008083961A1 (fr) * 2007-01-12 2008-07-17 Friedrich-Alexander-Universität Erlangen-Nürnberg Procédé de contrôle par impulsion à haute pression d'éléments mécaniques
WO2011012687A2 (fr) 2009-07-31 2011-02-03 Basf Se Composés phosphine-borane contenant des groupes imidazole et procédé de production de composés phosphorés contenant des groupes imidazole
WO2011026822A2 (fr) 2009-09-03 2011-03-10 Basf Se Liquides ioniques dotés d'une viscosité améliorée
WO2012016835A2 (fr) 2010-07-26 2012-02-09 Basf Se Liquides ioniques présentant une certaine teneur en polymères ioniques
US8703670B2 (en) 2010-07-26 2014-04-22 Basf Se Ionic liquids having a content of ionic polymers
WO2013060579A1 (fr) 2011-10-25 2013-05-02 Basf Se Utilisation en tant que fluide de travail de compositions liquides contenant des sels d'imidazolium
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons
US10214697B2 (en) 2013-03-15 2019-02-26 Ultraclean Fuel Pty Limited Process for removing sulphur compounds from hydrocarbons

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JP2008530441A (ja) 2008-08-07

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