WO2005113076A1

WO2005113076A1 - Golf club head

Info

Publication number: WO2005113076A1
Application number: PCT/US2004/013544
Authority: WO
Inventors: Steven M. Ehlers; John B. Kosmatka; Anthony V. Nigro; Matthew J. Erickson
Original assignee: Callaway Golf Co
Current assignee: Topgolf Callaway Brands Corp
Priority date: 2004-04-29
Filing date: 2004-04-29
Publication date: 2005-12-01
Anticipated expiration: 2006-10-29
Also published as: JP2007534438A

Abstract

A golf club head (20) having a matrix layer (40) composed of an interconnected reinforcement structure (50) and a polymer material (52) is disclosed herein. The matrix layer (40) provides the golf club head (20) with a greater coefficient of restitution during impact with a golf ball. The matrix layer (40) is preferably disposed within a recess in the front wall (30) of the body (22) of the golf club head (20). The interconnected reinforcement structure (50) is preferably composed of interconnected hexagonal cells.

Description

Title GOLF CLUB HEAD

Technical Field The present invention relates to a golf club head. More specifically, the present invention relates to a golf club head with a polymer face.

Background Art Technical innovation in the material, construction and performance of golf clubs has resulted in a variety of new products. The advent of metals as a structural material has largely replaced natural wood for wood-type golf club heads, and is but one example of this technical innovation resulting in a major change in the golf industry. In conjunction with such major changes are smaller scale refinements to likewise achieve dramatic results in golf club performance. For example, the metals comprising the structural elements of a golf club head have distinct requirements according to location in the golf club head. A sole or bottom section of the golf club head should be capable of withstanding high frictional forces for contacting the ground. A crown or top section should be lightweight to maintain a low center of gravity. A front or face of the golf club head should exhibit high strength and durability to withstand repeated impact with a golf ball. While various metals and composites are known for use in the face, several problems arise from the use of traditional face structure and materials. In addition, material interaction of the golf club head and the golf ball during impact is an important factor for performance of

the golf club. The golf ball is typically composed of a core-shell arrangement with a thin polymer shell, or cover material such as ionomers, surrounding a rubber-like core. These polymeric materials exhibit compression and shear, stiffness and strength properties dependent upon strain (load), input frequency (time dependency of small linear strain), strain rate (time rate of loading including large nonlinear strains), and temperature. The compression and shear stiffness properties of polymeric materials are measured and classified in terms of a storage moduli (E', G') and a loss moduli (E", (?"), respectively. The storage moduli (E G') represent the amount of compression and shear energy, respectively, stored during a complete loading cycle. For quasi-static loading, it is equivalent to the well known Young's modulus (E' =

E) and shear modulus (G' = G = E/(2(l+ v)), where (v) is the material Poisson ratio.

For most polymers, the storage modulus increases significantly with strain, input frequency, and strain rate. For example, typical storage moduli for golf balls at low speed impacts, in the temperature range (50-100°F), are E'baii ⁼ 450-6,000 lb/in² and G _MI = 150-2,000 lb/in². During high-speed impacts, in the temperature range (50- 100°F), the typical storage moduli are E ' _aιι = 9,000-50,000 lb/in² and G '_baιι = 3,000- 16,500 lb/in². The low speed impact represents a putting stroke or a soft pitch shot, while the high-speed impact represents a golf swing with an iron-type or a wood- type golf club head. The loss moduli (E G") represent the amount of compression and shear energy, respectively, dissipated during a cycle. For most polymers, the loss moduli

also increase significantly with strain, input frequency, and strain rate, but the rate of

increase can be very different than the aforementioned storage moduli. Finally, the

magnitude of the loss moduli at a given strain, strain rate, frequency, or temperature

typically vary from 0.005-2.0 times that of the storage moduli.

A loss (or damping) factor (η^, TJQ) or loss angle (<%, o for compression and

shear are commonly defined as the ratio of the corresponding moduli; η_E = TanJ_£ = — , η_G = TanJ_G = — .

These loss factors are an important measure of the damping capability (energy loss

mechanisms) of the material. For most ball-type materials, (η_E = ηo.) and

magnitudes fall in the range of 0.005 (low energy loss) to 2.0 (high-energy losses),

where magnitudes clearly depend upon polymer composition, strain, input frequency, strain rate, and temperature. As a comparison, the loss factors (energy

loss mechanisms) in a metallic face of a golf club head are on the order of 10-100

times smaller than that of a golf ball. For most elastomeric polymer materials

operating below the glass transition region, the Poisson ratio is fairly constant with

(v= 0.4-0.5), while for stiff polymers acting at or above the glass transition region ( v

= 0.3-0.33).

Thus, during impact of the golf ball with the golf club head, a significant

portion of impact energy is lost as a result of the large deformations (0.05 to 0.50

inches) and deformation rates of the high damped golf ball materials, as opposed to the small deformations of the low damped metallic club face (0.025 to 0.050 inches) materials. A larger portion of this impact energy is lost in the golf ball because the magnitude of the deformation, the deformation rate, and energy loss mechanisms are greater for the golf ball than the face of the golf club head. Application of hard polymers to the face of the golf club head represents a traditional structure of natural wood golf club heads, where a hard insert material centrally located in the face of the golf club and requiring an exacting fit between two or more distinct elements. The hard insert must be manufactured to a close tolerance to fit within a recess in the face of the golf club, and high surface hardness is less efficient in transferring energy to the golf ball during impact with the golf club. A homogeneous face structure is simpler to manufacture but is limited to the inherent material properties of the single material comprising the face structure. The present invention achieves a more efficient energy transfer during impact while maintaining a simple construction. The use of a polymer coating or layer on the face of a metal driver has been shown to increase durability and the coefficient of restitution ("COR") of the driver through the compliance of the polymer layer. However, when a golf ball impacts the face at angles that are not normal to face, such as the case with lofted drivers, shear deformation of the polymer coating introduces energy losses that reduce or eliminate the COR benefit provided by the polymer coating. Summary of the Invention

The present invention provides a solution to the shear deformation of a polymer layer during non-normal angle impact of a golf ball with a polymer coated or polymer layer face. The present invention is a golf club head with a matrix layer disposed on the face. The matrix layer is preferably composed of a reinforcement structure and a polymer material. The reinforcement structure reduces or prevents the shear deformation of the polymer material during impact of a face of a golf club head with a golf ball. The reinforcement structure also reduces or prevents the shear deformation of the polymer material without affecting the normal compliance behavior of the polymer material during impact of a face of a golf club head with a golf ball thereby resulting in a golf club head with a greater COR and better durability. One aspect of the present invention is a wood-type golf club head with a matrix layer disposed on the front wall of a body of the wood-type golf club head. The matrix layer preferably comprises a reinforcement structure and a polymer material. Another aspect of the present invention is an iron-type golf club head with a matrix layer disposed on the front wall of a body of the iron-type golf club head. The matrix layer preferably comprises a reinforcement structure and a polymer material. Yet another aspect of the present invention is a putter-type golf club head with a matrix layer disposed on the front wall of a body of the putter-type golf club head. The matrix layer preferably comprises a reinforcement structure and a polymer material.

Brief Description of the Drawings

FIG 1 is a front view of a wood-type golf club head with a matrix layer. FIG 1 A is a front view of a wood-type golf club head with an alternative matrix layer. FIG IB is a front view of a wood-type golf club head with an alternative matrix layer. FIG. 2 is a front view of a wood-type golf club head illustrating height and width measurements. FIG. 3 is a top view of the wood-type golf club head of FIG. 1. FIG. 4 is a cross-sectional view of the wood-type golf club head of FIG. 1 taken along line 4-4 of FIG. 3. FIG. 4A is a cross-sectional view of an alternative embodiment of a wood- type golf club head. FIG. 5 is an enlarged isolated view of a matrix layer and a front wall. FIG. 5 A is an enlarged isolated view of the alternative embodiment of FIG. 4A.

FIG. 6 is an enlarged isolated view of a prior art polymer layer disposed on a

front wall of a loft driver to illustrate the shear deformation during impact with a

golf ball. FIG. 7 is a heel-side view of the wood-type golf club head of FIG. 1.

FIG. 8 is a toe-side view of the wood-type golf club head of FIG. 1.

FIG. 9 is a bottom plan view of the wood-type golf club head of FIG. 1.

FIG. 10 is a bottom perspective view of the wood-type golf club head of FIG. 1. FIG. 11 illustrates an alternative embodiment of a matrix layer.

FIG. 12 illustrates an alternative embodiment of a matrix layer.

FIG. 13 is cross-sectional view of an alternative embodiment of a wood-type

golf club head with a matrix layer.

FIG. 14 is a front view of a putter-type golf club head with a matrix layer. FIG. 15 is a toe-side view of the putter-type golf club head of FIG. 14.

FIG. 16 is a rear perspective view of the putter-type golf club head of FIG.

14.

FIG. 17 is a top plan view of the putter-type golf club head of FIG. 14. FIG. 18 is a front view of an alternative putter-type golf club head with a

matrix layer.

FIG. 19 is a rear perspective view of the putter-type golf club head of FIG. FIG. 20 is a cross-sectional view of the putter-type golf club head of FIG. 18 along line 20-20. FIG. 21 is a top plan view of the putter-type golf club head of FIG. 18. FIG. 22 is a top perspective view of an alternative putter-type golf club head with a matrix layer. FIG. 23 is a front plan view of the putter-type golf club head of FIG. 22. FIG. 24 is a top plan view of the putter-type golf club head of FIG. 22. FIG. 25 is a bottom plan view of the putter-type golf club head of FIG. 22. FIG. 26 is a front plan view of an iron-type golf club head with a matrix layer. FIG. 27 is a cross-section view of an alternative iron-type golf club head with a matrix layer.

Best Mode(s) For Carrying Out The Invention

As shown in FIGS. 1-10, the golf club head of the present invention is generally designated 20. The golf club head 20 of FIGS. 1-10 is a driver, however, the golf club head of the present invention may alternatively be a fairway wood, an iron or a putter. The golf club head 20 has a body 22 that is preferably composed of a metal material such as titanium, titanium alloy, or the like, and is most preferably composed of a cast titamum alloy material. The body 22 is preferably cast from molten metal in a method such as the well-known lost-wax casting method. The metal for casting is preferably titanium or a titamum alloy such as 6-4 titanium alloy, alpha-beta titanium alloy or beta titanium alloy for forging, and 6-4 titanium for casting. Alternatively, the body 22 is composed of 17-4 steel alloy. Additional methods for manufacturing the body 22 include forming the body 22 from a flat sheet of metal, super-plastic forming the body 22 from a flat sheet of metal, machining the body 22 from a solid block of metal, electrochemical milling the body from a forged pre-form, casting the body using centrifugal casting, casting the body using levitation casting, and like manufacturing methods. The golf club head 20, when designed as a driver, preferably has a volume from 200 cubic centimeters to 600 cubic centimeters, more preferably from 300 cubic centimeters to 450 cubic centimeters, and most preferably from 350 cubic centimeters to 420 cubic centimeters. A golf club head 20 for a driver with a body 22 composed of a cast titanium alloy most preferably has a volume of 380 cubic centimeters. The volume of the golf club head 20 will also vary between fairway woods (preferably ranging from 3-woods to eleven woods) with smaller volumes than drivers. The golf club head 20, when designed as a driver, preferably has a mass no more than 215 grams, and most preferably a mass of 180 to 215 grams. When the golf club head 20 is designed as a fairway wood, the golf club head preferably has a mass of 135 grams to 180 grams, and preferably from 140 grams to 165 grams. The body 22 has a crown 24, a sole 26, a ribbon 28, and a front wall 30. The body 22 optionally has a recess 32 in the front wall 30. The recess 32 preferably has a depth, "Dr", as shown in FIG. 4, that ranges from 0.040 inch to 0.250 inch, more preferably from 0.080 inch to 0.120 inch, and is most preferably 0.100 inch. The body 22 preferably has a hollow interior 47. The golf club head 20 has a heel end 36, a toe end 38 an aft end 37. A shaft, not shown, is placed within a hosel 49 at the heel end 36. hi a preferred embodiment, the hosel 49 is internal to the body 22, and the shaft extends to the sole 26. The golf club head 20 has a matrix layer 40 that is disposed on the front wall 30 of the body 22. In a preferred embodiment, the matrix layer 40 is an insert that is disposed in the recess 32 of the front wall 30. In an alternative embodiment shown in FIG. 13, the matrix layer 40 is disposed on the exterior surface of the front wall 30. The matrix layer 40 is preferably composed of a reinforcement structure 50 and a polymer material 52. As shown in FIG. 2, the matrix layer 50 has a width Wm that preferably ranges from 2.0 inches to 4.0 inches. In a preferred embodiment, the matrix layer 40 has an uniform thickness that ranges from 0.040 inch to 0.250 inch, more preferably a thickness of 0.080 inch to 0.120 inch, and is most preferably 0.100 inch. The polymer material 52 for the matrix layer 50 is preferably a thermoplastic polyurethane material. Polymer materials that may be utilized in the matrix layer 50 include: polymers from Bayer Corporation sold under the TEXIN brand such as

TEXIN 4215, TEXIN 4210, TEXTN 270, TEXTN 4210 T2, TEXTN 270 T2, TEXIN 4215 T2 and TEXTN 4215 T3, which are thermoplastic polyurethanes and thermoplastic polyurethane and polycarbonate blends; polymers from BASF corporation such as TERLURAN EGP-7, TERLURAN HI-10, TERLURAN GP-22, which are ABS polymers, ULTRAMTD A3HG5, LURANS 778 TI and LURAN S 778 T/TE T2, which are ABS and polyamide blends, and TRIAX 1120, which is an ABS and polyamide blend; polymers from Du Pont Chemicals such as HYTREL 7246 thermoplastic polyester elastomer and HYLENE 58D polymer and SURLYN ionomers; polymers from GE Polymers such as NORYL PPX/PPX7115 polyphenylene ether and polystryene blend, LEXAN EXL 1330 T2, LEXAN EXL 1330 T3, LEXAN ML 6143/C1000, LEXAN 1330/ML6143, LEXAN ML6143H and LEXAN 1330, which are amorphous thermoplastic polymers, CYCOLOY CIOOOHF TI, CYCOLOY CIOOOHF T2, CYCOLOY CIOOOHF T3, CYCOLOY CIOOOHF T4 AND CYCOLOY CIOOOHF T5, which are ABS and polycarbonate blends; polymers from Atofϊna corporation sold under the brands ATOFINA 3429, ATOFINA 3467 and ATOFINA 7823 MZ; polymers from BP Chemical sold under the brand

BAREX 210, which is an E acrylonitrile-methyl acrylate copolymer; polymers from Chevron corporation sold under the brands BK-12, KR03 and BK10/NAS90 blend; polymers from Exxon Mobil chemical sold under the brands PP1024E4, PP1043N,

PP7033N, PP7032E2T1, PP7032KN and PP7032E2T2; polymers from Huntsman

Chemical sold under the brand IROGRAN 113557; polymers from RTP corporation sold under the brands 1299-A 80D w/glass, 1299-B 80D without glass, RTP 4085 and Nylon 6 with nano; and polymers from Uniroyal sold under the brand AN2501750 blend TI, AN2501750 blend T2 and LF750D. The polymer material 52 is preferably injection molded or compression molded around the reinforcement structure 50. However, those skilled in the pertinent art will recognize that other integration methods may be utilized in combining the reinforcement structure 50 and the polymer material 52 without departing from the scope and spirit of the present invention. The matrix layer 40 is applied to the front wall 30 of the golf club head 20. One application method is to use an adhesive to adhere an interior surface of the matrix layer 40 to the exterior surface of the front wall 30 within the recess 32. Another method is to use compressive forces to apply the matrix layer 40 within the recess 32. Yet another method is to use bolts to secure the matrix layer 40 within the recess 32. Yet a further method is to form the matrix layer 40 within the recess 32. However, those skilled in the pertinent art will recognize other methods to place the matrix layer 40 on the front wall 30 of the golf club head 20 without departing from the scope and spirit of the present invention. The reinforcement structure 50 is preferably composed of aluminum, aramid fiber, fiberglass, carbon or a rigid polyurethane material, and such reinforcement structures are available from Hexcel Corporation of Pleasanton, California under the brand HEXCEL COMPOSITES. The reinforcement structure 50 is preferably a plurality of interconnected cells 51, with each cell 51 preferably having a cell size ranging from 0.010 inch to 0.375 inch, more preferably from 0.0625 inch to 0.125 inch. Each cell 51 is preferably formed of integrated walls 53. As shown in FIG. 5, the reinforcement structure 50 preferably has a depth that extends along the entire depth, "Dm", of the matrix layer 40. In an alternative embodiment, the reinforcement structure 50 has a depth that partially extends along the depth of the matrix layer 40, ranging from 25% to 75% of the depth of the matrix layer 40. As shown in FIG. 5, each of the walls 53 of the reinforcement structure 50 preferably has a thickness, "Tr", ranging from 0.0005 inch to 0.01 inch, more preferably from 0.001 inch to 0.005 inch, and most preferably 0.002 inch. hi an alternative embodiment shown in FIGS. 4 A and 5 A, an outer layer 41 covers the matrix layer 40. The outer layer 41 provides additional protection to the matrix layer 40 during impact with a golf ball. The outer layer may be composed of any of the previously disclosed polymer materials. Further, the outer layer 41

preferably has a thickness ranging from 0.005 inch to 0.100 inch. In a most

preferred embodiment, the outer layer 41 is composed of the same material as the

polymer material 52 of the matrix layer 40. As shown in FIGS. 1 A and IB, alternative embodiments of the matrix layer

40 have a reinforcement structure 50 that is only present in a portion of the matrix

layer 40. hi FIG. 1 A, the reinforcement structure is only disposed in the center of the

face of the golf club head 20 in accordance with high impact probability locations.

In FIG. IB, the reinforcement structure is absent from the center of the face 45 of the

golfclub head 20.

FIGS. 11 and 12 illustrate various grid formations of the reinforcement

structure 50. FIG. 11 has a rectangular grid formation and FIG. 12 has a triangular

grid formation. A preferred embodiment has a hexagonal grid formation, as shown in FIG. 1. Those skilled in the pertinent art will recognize that other grid formations

may be used for the reinforcement structure 50 of the matrix layer 40 without

departing from the scope and spirit of the present invention.

As shown in FIG. 6, a lofted driver with a polymer layer 52a on the front

wall 30a will experience a shear stress, τ₀, from the normal stress, σ₀, due to impact

with a golf ball. The shear stress causes shear deformation of the polymer layer 52a

thereby affecting the normal compliance of the polymer layer 52a, which reduces the

increased COR due to the polymer layer 52a. The reinforcement structure 50 of the matrix layer 40 of the present invention reduces or eliminates the shear deformation of the polymer material 52 thereby allowing for increased COR and durability. The wood-type golf club head 20 preferably has a high coefficient of restitution thereby enabling for greater distance of a golf ball hit with the golf club head of the present invention. The coefficient of restitution (also referred to herein as "COR") is determined by the following equation:

wherein Uj is the club head velocity prior to impact; U₂ is the golf ball velocity prior to impact which is zero; v_/ is the club head velocity just after separation of the golf ball from the face of the club head; v_∑ is the golf ball velocity just after separation of the golf ball from the face of the club head; and e is the coefficient of restitution between the golf ball and the club face. The values of e are limited between zero and 1.0 for systems with no energy addition. The coefficient of restitution, e, for a material such as a soft clay or putty would be near zero, while for a perfectly elastic material, where no energy is lost as a result of deformation, the value of e would be 1.0. The present invention provides a wood-type golf club head 20 preferably having a coefficient of restitution preferably ranging from 0.80 to 0.87, and more preferably from 0.82 to 0.86, as measured under standard USGA test conditions. As shown in FIG. 3, the depth, "D", of the club head 20 from the front wall 30 to the aft-end 37 preferably ranges from 3.0 inches to 4.5 inches, and is most preferably 3.75 inches. As shown in FIG. 2, the height, "H", of the club head 20, as measured while in address position, preferably ranges from 2.0 inches to 3.5 inches, and is most preferably 2.50 inches or 2.9 inches. The width, "W", of the club head 20 from the toe end 38 to the heel end 36 preferably ranges from 4.0 inches to 5.0 inches, and more preferably 4.7 inches. The face 45 of the golf club head 20 preferably has a large aspect ratio. The aspect ratio as used herein is defined as the height, "H", of the face 45 divided by the width, "W", of the face 45. The width, W, is measured between the farthest limits of the face 45 from the heel end 36 to the toe end 38. The measured width, W, does not include any portion of the body 22 that may be on the front of the club head 20 but not part of the face 45. The face 45 includes the front wall 30 and matrix layer 40. The height, H, is measured from between the farthest limits of the face 45 from the crown 24 to the sole 26. As with the width, W, the height, H, does not include any portion of the body 22 that may be on the front of the club head 20 but not part of the face 45. In one embodiment, the width W is 3.35 inches and the height H is 2.0 inches giving an aspect ratio of 0.6. The face 45 of the golf club head 20 preferably has an aspect ratio that is greater than 0.575. The aspect ratio of the face 45 preferably ranges from 0.575 to 0.8, and is most preferably from 0.6 to 0.7. A discussion of the aspect ratio of the face of a golf club head is disclosed in Kosmatka, U.S. Patent Number 6,338,683 for Striking Plate For A Golf Club Head.

In general, the moment of inertia, Izz, about the Z axis for the golf club head

20 will preferably range from 2700g-cm² to 4000g-cm², more preferably from

3000g-cm² to 3800g-cm². The moment of inertia, Iyy, about the Y axis for the golf

club head 20 will preferably range from 1500g-cm² to 3500g-cm².

Further, the golf club head 20 preferably has superior products of inertia

wherein at least one of the products inertia, Ixy, Ixz and lyz, of the golf club head 20

has an absolute value less than lOOg-cm , and more preferably two or three products

of inertia, Ixy, Ixz and lyz, of the golf club head 20 have an absolute value less than 100g-cm². A discussion of the products of inertia is disclosed in Cackett, et al., U.S.

Patent Number 6,425,832 for Large Volume Driver Head With High Moments Of

Inertia.

As shown FIGS. 14-25, another embodiment of the present invention is a

putter-type golf club head 20 with a matrix layer 40 disposed in a recess 32 in a front

wall 30 of the body 22 of the putter-type golf club head 20.

The putter-type golf club head 20 has a body 22 with a front wall 30 with a

recess 32 therein. The matrix layer 40 extends along most of the front wall 30 from

a heel end 36 of the putter-type golf club head 20 to a toe end 38 of the putter-type

golf club head 20, and from a sole 26 to a crown 24. The body 22 of the putter-type golf club head 20 is preferably composed of a

metallic material such as stainless steel. Other metallic materials include titanium, aluminum, tungsten, zinc, magnesium, and alloys of stainless steel and tungsten.

However, those skilled in the pertinent art will recognize that the body 22 may be composed of other materials without departing from the scope and spirit of the present invention. Further, the non-matrix layer portion of the front wall 30 maybe smooth or textured to provide a consistent or non-consistent surface. Additionally, the body 22 may be specifically weighted to provide a specific center of gravity and inertial properties for the putter-type golf club head 20. hi a preferred embodiment, each of the putter-type club heads 20 weighs approximately 328 grams ± 7 grams.

Further, in a preferred embodiment, the recess 32 of each of the putter-type club heads 20 has a depth of approximately 0.205 inches ± 0.010 inch. FIGS. 14-17 illustrate a semi-mallet putter-type golf club head 20 and FIGS. 18-21 illustrate a flanged blade putter. A more thorough description of the putter- type golf club heads 20 of FIGS. 14-21 is set forth in U.S. Patent Number 6,238,302, issued on May 29, 2001, which relevant parts are hereby incorporated by reference. FIGS. 22-25 illustrate an extended mallet type putter-type golf club head 20 with an alignment system such as disclosed in U.S. Patent Number 6,471,600, issued on October 22, 2002. As shown FIGS. 26-27, another embodiment of the present invention is an iron-type golf club head 20 with a matrix layer 40 disposed in a recess 32 in a front wall 30 of the body 22 of the iron-type golf club head 20, or as shown in FIG. 27, the matrix layer 40 is adhered to the front wall 30 of the body 22 of the iron-type golf club head 20. As shown in FIG. 26, the iron-type golf club head (wedge) 20 has a body 22 with a front wall 30 with a recess 32 therein. The matrix layer 40 is disposed within the recess 32 and preferably extends along most of the front wall 30 from a heel end 36 of the iron-type golf club head 20 to a toe end 38 of the iron-type golf club head 20, and from a sole 26 to a crown (top wall) 24.

Claims

1. A golf club head comprising: a body comprising a crown, a sole and a front wall, the body having a hollow interior, the body having a volume ranging from 300 cubic centimeters to 500 cubic centimeters; and a matrix layer disposed on the front wall, the matrix layer comprising a polymer material with an integrated reinforcement structure, the matrix layer having a thickness ranging from 0.010 inch to 0.250 inch.

2. The golf club head according to claim 1 wherein the integrated reinforcement structure is composed of a material selected from the group consisting of aluminum, aramid fiber, fiberglass, carbon and polyurethane.

3. The golf club head according to claim 1 wherein the integrated reinforcement structure is a plurality of interconnected cells, each cell having a cell size ranging from 0.010 inch to 0.250 inch.

4. The golf club head according to claim 1 wherein the body is composed of a titanium alloy material and the front wall has a thickness ranging from 0.030 inch to 0.150 inch.

5. The golf club head according to claim 1 wherein the polymer material of the matrix layer is composed of a material selected from the group consisting of

thermoplastic polyurethane, polyether block copolymer, ionomer, nylon, polyamide

and polypropylene.

6. The golf club head according to claim 1 wherein the matrix layer has a

thickness ranging from 0.080 inch to 0.120 inch.

7. The golf club head according to claim 1 wherein a face of the golf club head

has an aspect ratio greater than 0.575.

8. The golf club head according to claim 1 wherein the front wall has a plurality

of concentric regions of thickness.

9. The golf club head according to claim 1 wherein the golf club head has a coefficient of restitution ranging from 0.82 to 0.93.

10. A golf club head comprising: a body comprising a crown, a sole and a front wall, the body having a hollow interior, the body having a volume ranging from 300 cubic centimeters to 500 cubic centimeters, the body composed of a titanium alloy material, the front wall having a recess, the recess having a depth ranging from 0.040 inch to 0.250 inch; and a matrix layer disposed within the recess of the front wall, the matrix layer comprising a polymer material with an integrated reinforcement structure composed of interconnected hexagonal cells, each hexagonal cell having a cell size of 0.0625 inch to 0.100 inch, the matrix layer having a thickness ranging from 0.040 inch to 0.250 inch.

11. The golf club head according to claim 10 wherein the polymer material of the matrix layer is composed of a thermoplastic polyurethane material.

12. The golf club head according to claim 10 wherein the integrated reinforcement structure is composed of an aluminum material.

13. The golf club head according to claim 10 wherein the integrated reinforcement structure is composed of a phenolic material.

14. The golf club head according to claim 10 wherein the golf club head has a moment of inertia, Izz, about the Z axis through the center of gravity of the golf club head that ranges from 2700g-cm² to 4000g-cm².

15. A wood-type golf club head comprising: a body comprising a crown, a sole and a front wall, the body having a hollow interior, the body having a volume ranging from 300 cubic centimeters to 500 cubic centimeters, the body composed of a titanium alloy material, the front wall having a recess, the recess having a depth ranging from 0.040 inch to 0.250 inch; and a matrix layer disposed within the recess of the front wall, the matrix layer comprising a thermoplastic polyurethane material with an integrated reinforcement structure composed of interconnected hexagonal cells, each hexagonal cell having a cell size of 0.0625 inch to 0.100 inch, the matrix layer having a thickness ranging from 0.040 inch to 0.250 inch; wherein the golf club head has a coefficient of restitution ranging from 0.82 to 0.93.

16. A golf club head comprising: a body comprising a crown, a sole and a front wall, the body having a hollow interior, the body having a volume ranging from 300 cubic centimeters to 500 cubic centimeters, the body composed of a titanium alloy material, the front wall having a recess, the recess having a depth ranging from 0.040 inch to 0.250 inch; and a matrix layer disposed within the recess of the front wall, the matrix layer comprising a polymer material with an integrated reinforcement structure composed of interconnected hexagonal cells, each hexagonal cell having a cell size of 0.0625 inch to 0.100 inch, the matrix layer having a thickness ranging from 0.040 inch to 0.250 inch; wherein the golf club head has a moment of inertia, Izz, about the Z axis of the center of gravity of the golf club head ranging from 2700g-cm² to 4000g- cm².

17. A golf club head comprising: a body composed of a metallic material and including a front wall having a recess formed therein; and a matrix layer disposed within the recess of the front wall, the matrix, the matrix layer comprising a reinforcement structure and a thermoplastic polyurethane material, the reinforcement structure including a plurality of integrated walls forming a plurality of integrated cells, the thermoplastic polyurethane material substantially filling the plurality of integrated cells of the reinforcement structure.

18. The golf club head according to claim 17 wherein the club head is a putter- type golf club head.

19. The golf club head according to claim 17 wherein the club head is an iron- type golf club head.

20. The golf club head according to claim 17 wherein the club head is a wood- type golf club head.

21. The golf club head according to claim 17 wherein the recess in the front wall of the body has a depth ranging from 0.040 inch to 0.250 inch, and wherein the

matrix layer has a thickness ranging from 0.040 inch to 0.250 inch.

22. The golf club head according to claim 17 wherein the reinforcement structure

is composed of a material selected from the group consisting of aluminum, aramid

fiber, fiberglass, carbon and polyurethane.

23. The golf club head according to claim 17 wherein the reinforcement structure

has a hexagonal grid configuration.

24. The golf club head according to claim 17 wherein each of the integrated cells has a cell size ranging from 0.010 inch to 0.250 inch.

25. The golf club head according to claim 17 wherem each of the integrated

walls of the reinforcement structure have a wall thickness ranging from 0.0005 inch

to 0.01 inch.