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WO2005025034A1 - Carbon brush - Google Patents

Carbon brush Download PDF

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Publication number
WO2005025034A1
WO2005025034A1 PCT/JP2003/011366 JP0311366W WO2005025034A1 WO 2005025034 A1 WO2005025034 A1 WO 2005025034A1 JP 0311366 W JP0311366 W JP 0311366W WO 2005025034 A1 WO2005025034 A1 WO 2005025034A1
Authority
WO
WIPO (PCT)
Prior art keywords
graphite particles
carbon brush
graphite
particle size
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2003/011366
Other languages
French (fr)
Japanese (ja)
Inventor
Hidenori Shirakawa
Yoshikazu Kagawa
Takashi Maeda
Takahiro Sakoda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotanKako Co Ltd
Original Assignee
TotanKako Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TotanKako Co Ltd filed Critical TotanKako Co Ltd
Priority to PCT/JP2003/011366 priority Critical patent/WO2005025034A1/en
Priority to CNA038270382A priority patent/CN1839529A/en
Priority to DE60325785T priority patent/DE60325785D1/en
Priority to AT03818580T priority patent/ATE420477T1/en
Priority to SI200331559T priority patent/SI1662638T1/en
Priority to EP03818580A priority patent/EP1662638B1/en
Publication of WO2005025034A1 publication Critical patent/WO2005025034A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R39/00Rotary current collectors, distributors or interrupters
    • H01R39/02Details for dynamo electric machines
    • H01R39/18Contacts for co-operation with commutator or slip-ring, e.g. contact brush
    • H01R39/20Contacts for co-operation with commutator or slip-ring, e.g. contact brush characterised by the material thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01RELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
    • H01R39/00Rotary current collectors, distributors or interrupters
    • H01R39/02Details for dynamo electric machines
    • H01R39/18Contacts for co-operation with commutator or slip-ring, e.g. contact brush
    • H01R39/26Solid sliding contacts, e.g. carbon brush

Definitions

  • the present invention relates to a carbon brush for an electric machine using a graphite particle filler, and more particularly to a carbon brush which suppresses particle detachment of the filler during use.
  • Akita
  • an object of the present invention is to provide a carbon brush with a long life, in which the filler structure of the graphite particle filler is made uniform and the graphite particle filler is used. Disclosure of the invention
  • the present invention relates to a carbon brush for an electric machine using a graphite particle filler, and in particular, to a carbon brush which suppresses particle detachment of the filler during use.
  • an object of the present invention is to provide a carbon brush having a long lifetime, in which the filler structure of the graphite particle filler is made uniform and the black 10 particle filler is used. Disclosure of the invention
  • FIG. 1 is a graph showing an example of a particle size distribution
  • FIG. 2 is a graph showing another example of a particle size distribution
  • FIG. 3 is a table showing characteristics of examples and comparative examples of the present invention.
  • the integrated value of the graphite particles having a particle size of 5 ⁇ m or less among the graphite particles was 10% or less, preferably 5% or less.
  • the integrated value of graphite particles with a particle diameter of 100 ⁇ m or more among graphite particles is 10% or less, and the integration of graphite particles with a particle diameter of 10 to 40 ⁇ m among graphite particles
  • the value is controlled to be 60% or more of the whole, and among them, the graphite particles having a particle diameter of 12 to 20 are controlled to be 40% or more.
  • the structure of the graphite particles forming the filler becomes uniform. For this reason, in the carbon brush using the graphite particle filler, even if the particle detachment occurs during use, the detached particle portion is small, and the life extension effect can be obtained.
  • laser light monochromatic, parallel beam
  • a spatially diffracted and scattered light intensity distribution pattern is generated.
  • This light intensity distribution pattern is detected by the sensor.
  • the light intensity distribution pattern depends on the particle size.
  • the actual measurement is a particle group, a plurality of particles of different sizes are mixed, so the light intensity distribution pattern generated from the particle group is determined by the superposition of diffraction and scattered light from each particle. Become.
  • the above-mentioned superimposed light intensity distribution pattern can be detected. It is possible to calculate what proportion of particles of such a size are contained. Then, the particle size distribution can be obtained from the calculation result.
  • a graph as shown in FIG. 1 can be obtained.
  • the horizontal axis of the graph in FIG. 1 indicates the particle diameter ( ⁇ ⁇ ) (expressed in logarithm), and the vertical axis indicates the relative particle amount (%).
  • the integrated value of the graphite particles having a particle size of 10 to 40 m is as shown in FIG.
  • the ratio of the area of the shaded portion is meant.
  • any of artificial graphite or natural graphite can be used. Further, graphite particles in which these are mixed may be used.
  • Epoxy resins, phenol resins, and various thermosetting resins obtained by modifying these resins can be used as the resin that binds between the graphite particles. These resins have a binder content of 10
  • thermosetting resin As a binder, the above-described graphite particles are mixed with a resin serving as a binder, and then molded into a predetermined shape.
  • Heat treatment is performed at a temperature of 150 to 250 ° C to obtain a carbon brush.
  • the carbon brush according to the present invention may include a solid lubricant such as molybdenum disulfide, tungsten disulfide, and boron nitride in addition to the filler described above.
  • a solid lubricant such as molybdenum disulfide, tungsten disulfide, and boron nitride in addition to the filler described above.
  • the same effect can be obtained by applying to not only the above-mentioned thermosetting type carbon brushes but also to various types of car pump brushes called kneading and firing with phenolic resin or pitch and metal graphite type. is there.
  • SALD-200OA As a laser diffraction type particle size distribution measuring device, SALD-200OA manufactured by Shimadzu Corporation was used. The same applies to the following examples and comparative examples.
  • the integrated value of the graphite particles having a particle size of 5 / m or less (the particle size distribution and the horizontal axis in FIG. Of the enclosed area, the shaded area on the left (the horizontal axis is
  • the ratio of the area of 5 mu m or less parts)) was adjusted to so that Do 1 0% of the graphite particles FILLER one (average particle diameter of 6 2 m), the mode diameter of 5 7 mu m in standard deviation 25% by weight of 0.25 artificial graphite powder and 25% by weight of epoxy resin as a binder were mixed and kneaded.
  • the kneaded material was pulverized so that the content of 63 or less was about 50%, and then molded at 100 MPa to obtain a single pump brush.
  • the integrated value of graphite particles having a particle size of 5 ⁇ m or less was 5%, and the particle size was 1% of the graphite particles.
  • the ratio of the area of the line part (the part of the horizontal axis is 100 ⁇ m or more) is 10. /. 25% by weight of an epoxy resin as a binder was mixed and kneaded with 75% by weight of artificial graphite powder adjusted to become a black sharp particle filler. This kneaded material was pulverized so that the content of 63 k ⁇ or less was about 50%, and then molded with 100 MPa to obtain a carbon brush.
  • the integrated value of graphite particles having a particle diameter of 5 nm or less was 3%, and the particle diameter of graphite particles was 10%.
  • the artificial value is adjusted so that the integrated value of graphite particles of 0 ⁇ m or more is 4%, and the integrated value of graphite particles with a particle diameter of 10 to 40 ⁇ m is 65% among graphite particles.
  • 75% by weight of graphite powder and 25% by weight of epoxy resin as a binder were mixed and kneaded.
  • the kneaded product 6 3 ⁇ ⁇ powder after grinding as following can be about 50%, to obtain a carbon brush molded in 1 0 OMP a.
  • the cumulative value of graphite particles having a particle diameter of 5 ⁇ m or less was a black bell particle filter with an integrated value of 20%. adjusted to and kneaded by blending an epoxy resin 2 5 wt 0/0 as a binder. The kneaded material was pulverized so that the content of 63 k ⁇ or less was about 50%, and then molded at 100 MPa to obtain a carbon brush.
  • the integrated value of graphite particles having a particle diameter of 5 ⁇ m or less was 30% and the particle diameter was 100 ⁇ m.
  • the average value of graphite particles of m or more is adjusted to be a graphite particle filter of 10%.
  • the cumulative diameter of graphite tin particles having a particle diameter of 5 ⁇ m or less was 40% and the particle diameter was 1%.
  • the integrated value of graphite particles of 0 ⁇ m or more is 15. Adjust so that the cumulative value of graphite particles with a particle diameter of 10 to 40 m becomes the same as the graphite particle filler of 55%, and mix and knead 20% by weight of general-purpose raw epoxy resin as a binder. did.
  • the kneaded material was pulverized so that those having a particle size of 63 ⁇ or less became about 50%, and then molded with 10 O M Pa to obtain a carbon brush.
  • Fig. 3 summarizes the characteristics of each car pump brush.
  • the integrated value of graphite particles having a particle size of 5 ⁇ m or less was 5%, and the particle size of graphite particles was 5%.
  • the car pump brush of Example 2 in which the integrated value of graphite particles of 100 ⁇ m or more is controlled to be a graphite bell particle filler of 10 ° / 0 is the same as the uncontrolled carbon brush according to Comparative Example 2.
  • the integrated value of the graphite particles having a particle size of 5 nm or less among the graphite particles was 3%, and the particle size of the graphite particles was 3%.
  • the present invention can provide a carbon brush having a significantly longer life than conventional products.

Landscapes

  • Motor Or Generator Current Collectors (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

A first carbon brush which comprises a graphite powder as a filler having a particle diameter distribution curve as determined by the laser diffraction method wherein an integrated value for the number of graphite particles having a particle diameter of 5 μm or less accounts for 10 % or less of the total particles, preferably 5 % or less; a second carbon brush which is the first carbon brush further wherein an integrated value for the number of graphite particles having a particle diameter of 100 μm or more accounts for 10 % or less; a third carbon brush which is the second carbon brush further wherein an integrated value for the number of graphite particles having a particle diameter of 10 to 40 μm accounts for 60 % or more; a forth carbon brush which is the third carbon brush further wherein an integrated value for the number of graphite particles having a particle diameter of 12 to 20 μm accounts for 40 % or more.

Description

カーボンブラシ 技術分野 Carbon brush technical field

本発明は、 黒鉛粒子フィラーを用いた電気機械用カーボンブラシに 関し、 特に、 使用時のフィラーの粒子離脱等を抑制したカーボンブラ シに関するものである。 明 田  The present invention relates to a carbon brush for an electric machine using a graphite particle filler, and more particularly to a carbon brush which suppresses particle detachment of the filler during use. Akita

背景技術 書 Background art

従来から、 カーボンブラシは公知となっている。 例えば、 特開 2 0 0 0 - 1 9 7 3 1 5号公報に開示されるものがある。 この文献のもの は、 人造黒鉛粒子あるいは天然黒鉛粒子などをフイラ一として使用し ていた。 そして、 フイラ一となる人造黒鉗粒子あるいは天然黒鉛粒子 などは、 微粉、 粗粉等大まかに制御して使用されていたため、 形成さ れるカーポンプラシは、 そのフィラー組織が均一なものでなく、 粒子 の大きさが不揃いな不均一なものが主流であった。  Conventionally, carbon brushes have been known. For example, there is one disclosed in Japanese Patent Application Laid-Open No. 2000-19973. In this document, artificial graphite particles or natural graphite particles were used as the filler. Since artificial black forceps particles or natural graphite particles, which are used as fillers, were roughly controlled and used as fine powder, coarse powder, etc., the resulting carpump brush had a non-uniform filler structure. Non-uniform ones with irregular sizes were the mainstream.

ところが、 近年、 モータの入力が高くなり、 カーボンブラシの使用 条件も過酷なものとなっている。 このような場合、 上記文献のものな どでは、 使用時に粒子離脱等が発生し、 短寿命となることもある。 そこで、 本発明の目的は、 黒鉛粒子フィラーのフィラー組織を均一 なものとし、 この黒鉛粒子フィラーが用いられる寿命の長いカーボン ブラシを提供することである。 発明の開示  However, in recent years, the motor input has increased, and the use conditions of carbon brushes have become severe. In such a case, in the case of the above-mentioned literature, particle detachment occurs at the time of use, and the life may be shortened. Therefore, an object of the present invention is to provide a carbon brush with a long life, in which the filler structure of the graphite particle filler is made uniform and the graphite particle filler is used. Disclosure of the invention

前記課題を解決するために、 本発明者らは鋭意研究の結果、 カーボ ンプラシの寿命を長くするためには、 粒径分布が制御されたフイラ一 カーボンブラシ In order to solve the above-mentioned problems, the present inventors have conducted intensive studies and as a result, in order to prolong the life of carbon brush, a filter having a controlled particle size distribution is required. Carbon brush

技術分野 Technical field

本発明は、 黒鉛粒子フィラーを用いた電気機械用カーボンブラシに 関し、 特に、 使用時のフィラーの粒子離脱等を抑制したカーボンブラ 明  The present invention relates to a carbon brush for an electric machine using a graphite particle filler, and in particular, to a carbon brush which suppresses particle detachment of the filler during use.

シに関するものである。 食 It is about Shi. Food

背景技術 Background art

従来から、 カーボンプラシは公知となっている。 例えば、 特開 2 0 0 0 - 1 9 7 3 1 5号公報に開示されるものがある。 この文献のもの は、 人造黒鉛粒子あるいは天然黒鉛粒子などをフイラ一として使用し ていた。 そして、 フイラ一となる人造黒鉛粒子あるいは天然黒鉛粒子 などは、 微粉、 粗粉等大まかに制御して使用されていたため、 形成さ れるカーポンプラシは、 そのブイラ一組織が均一なものでなく、 粒子 の大きさが不揃いな不均一なものが主流であった。  Conventionally, carbon plush has been known. For example, there is one disclosed in Japanese Patent Application Laid-Open No. 2000-19973. In this document, artificial graphite particles or natural graphite particles were used as the filler. The artificial graphite particles or natural graphite particles used as the filler were roughly controlled and used as fine powder, coarse powder, etc., so the carpump formed was not uniform in the structure of the boiler. Non-uniform ones with irregular sizes were the mainstream.

ところが、 近年、 モータの入力が高くなり、 カーボンブラシの使用 条件も過酷なものとなっている。 このような場合、 上記文献のものな どでは、 使用時に粒子離脱等が発生し、 短寿命となることもある。 そこで、 本発明の目的は、 黒鉛粒子フィラーのフィラー組織を均一 なものとし、 この黒 10粒子フィラーが用いられる寿命の長いカーボン ブラシを提供することである。 発明の開示  However, in recent years, the motor input has increased, and the use conditions of carbon brushes have become severe. In such a case, in the case of the above-mentioned literature, particle detachment occurs at the time of use, and the life may be shortened. Accordingly, an object of the present invention is to provide a carbon brush having a long lifetime, in which the filler structure of the graphite particle filler is made uniform and the black 10 particle filler is used. Disclosure of the invention

前記課題を解決するために、 本発明者らは鋭意研究の結果、 カーボ ンプラシの寿命を長くするためには、 粒径分布が制御されたフイラ一 となる黒鉛粒子を用いることがきわめて重要であることを見出し、 本 発明を完成させるに至った。 すなわち、 本発明に係るカーボンブラシ は、 フイラ一となる黒鉛粒子をレーザ回折法にて測定したときの粒径 分布において、 黒鉛粒子のうち粒子径が 5 IX m以下の黒鉛粒子の積算 値が 1 0 %以下となるものである。 図面の簡単な説明 In order to solve the above-mentioned problems, the present inventors have conducted intensive studies and as a result, in order to prolong the life of carbon brush, a filter having a controlled particle size distribution is required. It has been found that it is extremely important to use graphite particles, and the present invention has been completed. That is, in the carbon brush according to the present invention, in the particle size distribution when graphite particles serving as a filter were measured by a laser diffraction method, the integrated value of graphite particles having a particle size of 5 IX m or less among graphite particles was 1 0% or less. Brief Description of Drawings

第 1図は、 粒径分布の一例を示すグラフ、 第 2図は、 粒径分布の他 例を示すグラフ、 第 3図は、 本発明の実施例及び比較例の特性を示す 表である。 発明を実施するための最良の形態  FIG. 1 is a graph showing an example of a particle size distribution, FIG. 2 is a graph showing another example of a particle size distribution, and FIG. 3 is a table showing characteristics of examples and comparative examples of the present invention. BEST MODE FOR CARRYING OUT THE INVENTION

フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鉛粒子の積算値 が 1 0 %以下、 好ましくは 5 %以下であり、 かつ、 黒鉛粒子のうち粒 子径が 1 0 0 μ m以上の黒鉛粒子の積算値が 1 0 %以下、 さらに黒鉛 粒子のうち粒子径が 1 0〜 4 0 μ mの黒鉛粒子の積算値が全体の 6 0 %以上、 また、 この中で、 粒子径が 1 2〜2 0 の黒鉛粒子が 4 0 %以上となるように制御する。 これによつて、 フイラ一となる黒鉛 粒子の組織が均一となる。 このため、 この黒鉛粒子フィラーが用いら れるカーボンブラシは、 使用時に粒子離脱等が発生した場合であって も、 離脱した粒子部分が小さく、 寿命の延命効果が得られる。  In the particle size distribution when the graphite particles serving as fillers were measured by a laser diffraction method, the integrated value of the graphite particles having a particle size of 5 μm or less among the graphite particles was 10% or less, preferably 5% or less. Yes, and the integrated value of graphite particles with a particle diameter of 100 μm or more among graphite particles is 10% or less, and the integration of graphite particles with a particle diameter of 10 to 40 μm among graphite particles The value is controlled to be 60% or more of the whole, and among them, the graphite particles having a particle diameter of 12 to 20 are controlled to be 40% or more. As a result, the structure of the graphite particles forming the filler becomes uniform. For this reason, in the carbon brush using the graphite particle filler, even if the particle detachment occurs during use, the detached particle portion is small, and the life extension effect can be obtained.

ここで、 レーザ回折法の原理について説明する。 測定対象となる粒 子にレーザ光 (単色、 平行ビーム) を照射すると、 空間的に回折 '散 乱光の光強度分布パターンが生じる。 この光強度分布パターンをセン サにより検出する。 なお、 光強度分布パターンは、 粒子の大きさに依  Here, the principle of the laser diffraction method will be described. When laser light (monochromatic, parallel beam) is applied to the particles to be measured, a spatially diffracted and scattered light intensity distribution pattern is generated. This light intensity distribution pattern is detected by the sensor. The light intensity distribution pattern depends on the particle size.

2 存して変化するものである。 2 It changes.

実際に測定するのは粒子群であることから、 大きさの異なる複数の 粒子が混在しているため、 粒子群から生ずる光強度分布パターンは、 それぞれの粒子からの回折 ·散乱光の重ね合せとなる。  Since the actual measurement is a particle group, a plurality of particles of different sizes are mixed, so the light intensity distribution pattern generated from the particle group is determined by the superposition of diffraction and scattered light from each particle. Become.

このレーザ回折法を用いたレーザ回折式粒度分布測定装置によって 測定すると、 上述した重ね合された光強度分布パターンを検出でき、 この光強度分布パターンのデータから計算によってサンプル粒子群の 中に、 どのような大きさの粒子が、 どのような割合で含まれているか 算出できる。 そして、 その算出結果から、 粒径分布を得ることができ るものである。  When measured by the laser diffraction type particle size distribution measuring device using the laser diffraction method, the above-mentioned superimposed light intensity distribution pattern can be detected. It is possible to calculate what proportion of particles of such a size are contained. Then, the particle size distribution can be obtained from the calculation result.

例えば、 第 1図に示すようなグラフを得ることができる。 この第 1 図のグラフの横軸は粒子径 (μ ιη) (対数表示されている)、 縦軸は相 対粒子量 (%) を示す。 ここで、 例えば、 「黒鉛粒子をレーザ回折法に て測定したときの粒径分布において、 黒鉛粒子のうち粒子径が 1 0〜 4 0 mの黒鉛粒子の積算値」 とは、 第 1図の粒径分布と横軸とで囲 まれる面積のうち、 斜線部分 ( 1 0〜4 0 // mの粒子径に対応する部 分) の面積の割合をいう。  For example, a graph as shown in FIG. 1 can be obtained. The horizontal axis of the graph in FIG. 1 indicates the particle diameter (μ ιη) (expressed in logarithm), and the vertical axis indicates the relative particle amount (%). Here, for example, “in the particle size distribution when the graphite particles are measured by the laser diffraction method, among the graphite particles, the integrated value of the graphite particles having a particle size of 10 to 40 m” is as shown in FIG. In the area enclosed by the particle size distribution and the horizontal axis, the ratio of the area of the shaded portion (the portion corresponding to a particle diameter of 10 to 40 // m) is meant.

なお、 本発明に使用される黒鉛粒子は、 人造黒船又は天然黒鉛のい ずれの黒鈴粒子をも使用することができる。 また、 これらを混合した 黒鉛粒子であってもよい。  As the graphite particles used in the present invention, any of artificial graphite or natural graphite can be used. Further, graphite particles in which these are mixed may be used.

これら黒鉛粒子の粒子間を結合する樹脂としては、 エポキシ樹脂、 フエノール樹脂及びこれらを変性して得られる種々の熱硬化性樹脂等 を使用することができる。 これら、 樹脂は、 バインダー分として 1 0 Epoxy resins, phenol resins, and various thermosetting resins obtained by modifying these resins can be used as the resin that binds between the graphite particles. These resins have a binder content of 10

〜 4 0 °/。を使用することが好ましい。 ~ 40 ° /. It is preferred to use

そして、 これら熱硬化性樹脂を結合剤として、 前述の黒鉛粒子に結 合剤となる樹脂を混合後、 所定形状に成形後、 これら樹脂が硬化する  After using the thermosetting resin as a binder, the above-described graphite particles are mixed with a resin serving as a binder, and then molded into a predetermined shape.

3 JP2003/011366 Three JP2003 / 011366

1 5 0〜2 5 0 °Cの温度で熱処理をし、 カーボンブラシとする。 Heat treatment is performed at a temperature of 150 to 250 ° C to obtain a carbon brush.

なお、 本発明に係るカーボンブラシは、 前述のフィラーに加えて、 二硫化モリブデン、 二硫化タングステン、 窒化ホウ素等の固体潤滑剤 を加えることもできる。 また、 前述の熱硬化型カーボンブラシに限ら ず、 フエノール樹脂やピッチで混練し、 焼成する炭化型や、 金属黒鉛 質型と呼ばれる各種カーポンプラシに適用することで、 同様の効果を 得ることが可能である。  The carbon brush according to the present invention may include a solid lubricant such as molybdenum disulfide, tungsten disulfide, and boron nitride in addition to the filler described above. The same effect can be obtained by applying to not only the above-mentioned thermosetting type carbon brushes but also to various types of car pump brushes called kneading and firing with phenolic resin or pitch and metal graphite type. is there.

以下、 実施例により本発明を具体的に説明する。  Hereinafter, the present invention will be described specifically with reference to examples.

(実施例 1 )  (Example 1)

レーザ回折式粒度分布測定装置としては、 (株) 島津製作所製 S A L D— 2 0 0 O Aを使用した。 以下の実施例及ぴ比較例においても同様 である。 As a laser diffraction type particle size distribution measuring device, SALD-200OA manufactured by Shimadzu Corporation was used. The same applies to the following examples and comparative examples.

フイラ一となる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 粒子径が 5 / m以下の黒鉛粒子の積算値 (第 2図におけ る粒径分布と横軸とで囲まれる面積のうち、 左側の斜線部分 (横軸が  In the particle size distribution when the graphite particles serving as the filter were measured by the laser diffraction method, the integrated value of the graphite particles having a particle size of 5 / m or less (the particle size distribution and the horizontal axis in FIG. Of the enclosed area, the shaded area on the left (the horizontal axis is

5 μ m以下の部分) の面積の割合) が 1 0 %の黒鉛粒子フイラ一とな るように調整した (平均粒子径が 6 2 m)、 モード径が 5 7 μ mで標 準偏差値 0 . 2 5の人造黒鉛粉末 7 5重量%に、 パインダーとしてェ ポキシ樹脂 2 5重量%を配合して混練した。 この混練物を 6 3 以 下のものが 5 0 %程度になるように粉砕後、 1 0 0 M P aで成形し力 一ポンプラシを得た。 The ratio of the area of 5 mu m or less parts)) was adjusted to so that Do 1 0% of the graphite particles FILLER one (average particle diameter of 6 2 m), the mode diameter of 5 7 mu m in standard deviation 25% by weight of 0.25 artificial graphite powder and 25% by weight of epoxy resin as a binder were mixed and kneaded. The kneaded material was pulverized so that the content of 63 or less was about 50%, and then molded at 100 MPa to obtain a single pump brush.

(実施例 2 )  (Example 2)

フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鉛粒子の積算値 が 5 %、 黒鉛粒子のうち粒子径が 1 0 0 μ m以上の黒鉛粒子の積算値  In the particle size distribution when the graphite particles serving as fillers were measured by the laser diffraction method, the integrated value of graphite particles having a particle size of 5 μm or less was 5%, and the particle size was 1% of the graphite particles. 0 Integrated value of graphite particles of 0 μm or more

(第 2図における粒径分布と横軸とで囲まれる面積のうち、 右側の斜  (In the area enclosed by the particle size distribution and the horizontal axis in Fig. 2,

4 3 011366 Four 3 011366

線部分 (横軸が 1 0 0 μ m以上の部分) の面積の割合) が 1 0。/。の黒 鋭粒子フイラ一となるように調整した人造黒鉛粉末 7 5重量%に、 パ インダ一としてエポキシ樹脂 2 5重量%を配合して混練した。 この混 練物を 6 3 μ πι以下のものが 5 0 %程度になるように粉碎後、 1 0 0 M P aで成形しカーボンブラシを得た。 The ratio of the area of the line part (the part of the horizontal axis is 100 μm or more) is 10. /. 25% by weight of an epoxy resin as a binder was mixed and kneaded with 75% by weight of artificial graphite powder adjusted to become a black sharp particle filler. This kneaded material was pulverized so that the content of 63 kππ or less was about 50%, and then molded with 100 MPa to obtain a carbon brush.

(実施例 3 )  (Example 3)

フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 n m以下の黒鉛粒子の積算値 が 3 %、 黒鉛粒子のうち粒子径が 1 0 0 μ m以上の黒鉛粒子の積算値 が 4 %、 黒鉛粒子のうち粒子径が 1 0〜 4 0 μ mの黒鉛粒子の積算値 が 6 5 %の黒鉛粒子フイラ一となるように調整した人造黒鉛粉末 7 5 重量%に、 バインダーとしてエポキシ樹脂 2 5重量%を配合して混練 した。 この混練物を 6 3 μ ΐη以下のものが5 0 %程度になるように粉 砕後、 1 0 O M P aで成形しカーボンブラシを得た。 In the particle size distribution when the graphite particles serving as fillers were measured by a laser diffraction method, the integrated value of graphite particles having a particle diameter of 5 nm or less was 3%, and the particle diameter of graphite particles was 10%. The artificial value is adjusted so that the integrated value of graphite particles of 0 μm or more is 4%, and the integrated value of graphite particles with a particle diameter of 10 to 40 μm is 65% among graphite particles. 75% by weight of graphite powder and 25% by weight of epoxy resin as a binder were mixed and kneaded. The kneaded product 6 3 μ ΐη powder after grinding as following can be about 50%, to obtain a carbon brush molded in 1 0 OMP a.

(比較例 1· )  (Comparative Example 1)

フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鉛粒子の積算値 が 2 0 %の黒鈴粒子フイラ一となるように調整し、 バインダーとして エポキシ樹脂 2 5重量0 /0を配合して混練した。 この混練物を 6 3 μ πι 以下のものが 5 0 %程度になるように粉砕後、 1 0 0 M P aで成形し カーボンブラシを得た。 In the particle size distribution when the graphite particles serving as fillers were measured by the laser diffraction method, among the graphite particles, the cumulative value of graphite particles having a particle diameter of 5 μm or less was a black bell particle filter with an integrated value of 20%. adjusted to and kneaded by blending an epoxy resin 2 5 wt 0/0 as a binder. The kneaded material was pulverized so that the content of 63 kππ or less was about 50%, and then molded at 100 MPa to obtain a carbon brush.

(比較例 2 )  (Comparative Example 2)

フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鉛粒子の積算値 が 3 0 %、 粒子径が 1 0 0 μ m以上の黒鉛粒子の積算値が 1 0 %の黒 鉛粒子フイラ一となるように調整し、 バインダーとして汎用性ェポキ  In the particle size distribution when the graphite particles serving as fillers were measured by the laser diffraction method, the integrated value of graphite particles having a particle diameter of 5 μm or less was 30% and the particle diameter was 100 μm. The average value of graphite particles of m or more is adjusted to be a graphite particle filter of 10%.

5 シ樹脂 2 5重量%を配合して混練した。 この混練物を 6 3 μ m以下の ものが 5 0 %程度になるように粉砕後、 1 0 0 M P aで成形しカーボ ンブラシを得た。 Five Twenty-five percent by weight of the resin was mixed and kneaded. This kneaded material was pulverized so that a particle having a diameter of 63 μm or less became about 50%, and then molded at 100 MPa to obtain a carbon brush.

(比較例 3 )  (Comparative Example 3)

フイラ一となる黒鉛粒子をレーザ回折法にて測定したときの粒径分 布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鈴粒子の積算ィ直 が 4 0 %、 粒子径が 1 0 0 μ m以上の黒鉛粒子の積算値が 1 5。 粒 子径が 1 0〜 4 0 mの黒鉛粒子の積算値が 5 5 %の黒鉛粒子フィラ 一になるように調整し、 バインダーとして汎用^~生ェポキシ樹脂 2 0重 量%を配合して混練した。 この混練物を 6 3 μ ΐη以下のものが 5 0 % 程度になるように粉砕後、 1 0 O M P aで成形しカーボンブラシを得 た。  In the particle size distribution when the graphite particles serving as the filler were measured by the laser diffraction method, the cumulative diameter of graphite tin particles having a particle diameter of 5 μm or less was 40% and the particle diameter was 1%. The integrated value of graphite particles of 0 μm or more is 15. Adjust so that the cumulative value of graphite particles with a particle diameter of 10 to 40 m becomes the same as the graphite particle filler of 55%, and mix and knead 20% by weight of general-purpose raw epoxy resin as a binder. did. The kneaded material was pulverized so that those having a particle size of 63 μΐη or less became about 50%, and then molded with 10 O M Pa to obtain a carbon brush.

以上の各カーポンプラシを、 真空掃除機用のモータに組み込んで、 寿命を調査した。 第 3図に、 各カーポンプラシの特性をまとめて示す 。  Each of the above car pump brushes was incorporated into a motor for a vacuum cleaner, and the service life was investigated. Fig. 3 summarizes the characteristics of each car pump brush.

第 3図からわかるように、 フィラーとなる黒鉛粒子をレーザ回折法 にて測定したときの粒径分布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鈴粒子の積算値が 1 0 %の黒鉛粒子フイラ一となるように 制御した実施例 1のカーボンブラシは、 比較例 1に係る制御していな いカーボンブラシに比べ、 寿命が 1 . 5倍程度延びていることがわか る。 Third As can be seen, the particle size distribution as measured graphite particles as a filler by a laser diffraction method, the accumulated value of the particle diameter of 5 mu m or less black tin particles of graphite particles 1 0% It can be seen that the life of the carbon brush of Example 1 controlled to be the same as the graphite particle filter of Example 1 is 1.5 times longer than that of the uncontrolled carbon brush according to Comparative Example 1.

また、 フィラーとなる黒鉛粒子をレーザ回折法にて測定したときの 粒径分布において、 黒鉛粒子のうち粒子径が 5 μ m以下の黒鉛粒子の 積算値が 5 %、 黒鉛粒子のうち粒子径が 1 0 0 μ m以上の黒鉛粒子の 積算値が 1 0 °/0の黒鈴粒子フィラーとなるように制御した実施例 2の カーポンプラシは、 比較例 2に係る制御していないカーボンブラシに In addition, in the particle size distribution when graphite particles serving as fillers were measured by a laser diffraction method, the integrated value of graphite particles having a particle size of 5 μm or less was 5%, and the particle size of graphite particles was 5%. The car pump brush of Example 2 in which the integrated value of graphite particles of 100 μm or more is controlled to be a graphite bell particle filler of 10 ° / 0 is the same as the uncontrolled carbon brush according to Comparative Example 2.

6 比べ、 寿命が 2倍程度延びていることがわかる。 6 In comparison, it is found that the service life is extended about twice.

また、 フイラ一となる黒鉛粒子をレーザ回折法にて測定したときの 粒径分布において、 黒鉛粒子のうち粒子径が 5 n m以下の黒鉛粒子の 積算値が 3 %、 黒鉛粒子のうち粒子径が 1 0 0 μ m以上の黒鉛粒子の 積算値が 4 %、 黒鉛粒子のうち粒子径が 1 0〜 4 0 μ mの黒鉛粒子の 積算値が 6 5 %の黒鉛粒子フイラ一となるように制御した実施例 3の カーボンブラシは、 比較例 3に係る制御していないカーボンブラシに 比べて、 その寿命が 3倍程度延びていることがわかる。  In addition, in the particle size distribution when the graphite particles serving as the filler were measured by the laser diffraction method, the integrated value of the graphite particles having a particle size of 5 nm or less among the graphite particles was 3%, and the particle size of the graphite particles was 3%. Control so that the integrated value of graphite particles with a particle size of 100 μm or more is 4%, and the integrated value of graphite particles with a particle size of 100 to 40 μm is 65% among graphite particles. It can be seen that the service life of the carbon brush of Example 3 is about three times longer than that of the uncontrolled carbon brush according to Comparative Example 3.

したがって、 本発明によって、 従来品に比べ飛躍的に寿命が長くな るカーボンブラシを提供できることが確認できた。  Therefore, it was confirmed that the present invention can provide a carbon brush having a significantly longer life than conventional products.

なお、 本発明は、 特許請求の範囲を逸脱しない範囲で設計変更でき るものであり、 上記実施形態や実施例に限定されるものではない。 産業上の利用可能性  The present invention can be changed in design without departing from the scope of the claims, and is not limited to the above embodiments and examples. Industrial applicability

黒鉛粒子フィラーのフィラー組織を均一なものとし、 この黒鉛粒子 フィラーが用いられる寿命の長いカーボンブラシを提供することがで さる。  It is possible to make the filler structure of the graphite particle filler uniform, and to provide a carbon brush having a long life using the graphite particle filler.

7 7

Claims

請 求 の 範 囲  The scope of the claims 1 · フィラーとなる黒鋭粒子をレーザ回折法にて測定したときの粒 径分布において、 黒鉛粒子のうち粒子径が 5 m以下の黒鉛粒子の積 算 :が 1 0 %以下であるカーボンブラシ。  1 · A carbon brush whose particle size distribution is 10% or less of graphite particles with a particle size of 5 m or less in the particle size distribution when black sharp particles serving as fillers are measured by a laser diffraction method. 2 . 黒鉛粒子のうち粒子径が 1 0 0 μ m以上の黒鉛粒子の積算値が 1 0 %以下である請求の範囲第 1項に記載のカーポンプラシ。  2. The car pump brush according to claim 1, wherein an integrated value of graphite particles having a particle diameter of 100 µm or more among the graphite particles is 10% or less. 3 . 黒铅粒子のうち粒子径が 1 0〜 4 0 mの黒鉛粒子の積算値が 6 0 %以上である請求の範囲第 2項に記載のカーボンブラシ。  3. The carbon brush according to claim 2, wherein an integrated value of graphite particles having a particle diameter of 10 to 40 m among the graphite particles is 60% or more. 4 . 黒鉛粒子のうち粒子径が 1 2〜 2 0 mの黒鉛粒子の積算値が 4 0 %以上である請求の範囲第 3項に記載のカーポンプラシ。  4. The car pump brush according to claim 3, wherein an integrated value of graphite particles having a particle diameter of 12 to 20 m among the graphite particles is 40% or more. 5 . 樹脂硬化型カーボンブラシ、 炭化型カーボンブラシ、 金属と黒 鉛が結合したカーボンブラシのうちより選ばれるものである請求の範 囲第 1項から第 4項のいずれかに記載のカーボンブラシ。  5. The carbon brush according to any one of claims 1 to 4, wherein the carbon brush is selected from a resin-cured carbon brush, a carbonized carbon brush, and a carbon brush in which metal and graphite are combined.
PCT/JP2003/011366 2003-09-05 2003-09-05 Carbon brush Ceased WO2005025034A1 (en)

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DE60325785T DE60325785D1 (en) 2003-09-05 2003-09-05 CARBON BRUSH
AT03818580T ATE420477T1 (en) 2003-09-05 2003-09-05 CARBON BRUSH
SI200331559T SI1662638T1 (en) 2003-09-05 2003-09-05 Carbon brush
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WO2006013991A1 (en) * 2004-08-02 2006-02-09 Asmo Co., Ltd. Carbon brush and rotating electrical machine
WO2007073793A1 (en) * 2005-12-24 2007-07-05 Pyongyang Technical Trading Centre Flexible natural graphite material and flexible manufacturing method (process) and use thereof

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DE102014116114A1 (en) 2014-11-05 2016-05-12 Schunk Kohlenstofftechnik Gmbh Multi-layer carbon brush and production of such

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JPH07213022A (en) * 1993-12-28 1995-08-11 Mando Mach Corp Preparation of metal graphite quality brush
JP2001327127A (en) * 2000-05-17 2001-11-22 Toshiba Ceramics Co Ltd Copper carbonaceous brush and method of manufacturing the same
JP2002080922A (en) * 2000-09-07 2002-03-22 Mitsubishi Materials Corp Sliding current collector made of Cu-graphite sintered material with excellent wear resistance
EP1333546A2 (en) * 2002-01-30 2003-08-06 Tris, Inc. Copper-graphite brush

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JPH07213022A (en) * 1993-12-28 1995-08-11 Mando Mach Corp Preparation of metal graphite quality brush
JP2001327127A (en) * 2000-05-17 2001-11-22 Toshiba Ceramics Co Ltd Copper carbonaceous brush and method of manufacturing the same
JP2002080922A (en) * 2000-09-07 2002-03-22 Mitsubishi Materials Corp Sliding current collector made of Cu-graphite sintered material with excellent wear resistance
EP1333546A2 (en) * 2002-01-30 2003-08-06 Tris, Inc. Copper-graphite brush

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006013991A1 (en) * 2004-08-02 2006-02-09 Asmo Co., Ltd. Carbon brush and rotating electrical machine
US8035272B2 (en) 2004-08-02 2011-10-11 Asmo Co. Ltd. Carbon brush with raw graphite particles
WO2007073793A1 (en) * 2005-12-24 2007-07-05 Pyongyang Technical Trading Centre Flexible natural graphite material and flexible manufacturing method (process) and use thereof

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