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WO2005021685A1 - Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques - Google Patents

Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques Download PDF

Info

Publication number
WO2005021685A1
WO2005021685A1 PCT/IB2004/002738 IB2004002738W WO2005021685A1 WO 2005021685 A1 WO2005021685 A1 WO 2005021685A1 IB 2004002738 W IB2004002738 W IB 2004002738W WO 2005021685 A1 WO2005021685 A1 WO 2005021685A1
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
waste
ebbing
oil
cracking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2004/002738
Other languages
English (en)
Inventor
Jenõ TIKOS
András URBÁN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sc Pyroinvest Sa
Original Assignee
Sc Pyroinvest Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sc Pyroinvest Sa filed Critical Sc Pyroinvest Sa
Priority to MDA20060098A priority Critical patent/MD3343C2/ro
Priority to EP04769165A priority patent/EP1668092A1/fr
Publication of WO2005021685A1 publication Critical patent/WO2005021685A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B51/00—Destructive distillation of solid carbonaceous materials by combined direct and indirect heating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste

Definitions

  • the invention relates to a thermal cracking process of decomposing rubber and plastic waste and to an installation for obtaining some hydrocarbons that can be industrially used.
  • the horizontal drum reactors for pyroKsing are expensive, they need an investment, their automating is complicated and their maintenance is expensive and it requires high-qualified staff. It is also needed a preliminary processing of the waste and they are high-energy consumers.
  • the technical problem solved by the invention consists of achieving a cracking technology and a reactor of special, simple construction, with a reduced energy use for the thermal decomposing of rubber and plastic waste for obtaining hydrocarbons that can be industrially used, without causing any ecological problems upon the environment.
  • the reactor In its upper part the reactor is equipped with a worm-gear shape mixer, fixed on the cylindrical and conical wall of the reactor, powered from the lower part of the reactor anti clockwise.
  • the reactor are one concentric heating shell, which contains a heating space where there are two gas burners fixed on the outer wall of the reactor and placed tangentially, two spiral pre-heaters from inside the heating space, and a pre-heater fixed to the burned gas evacuation pipe, wherein circulate the ebbing oil obtained as a result of the thermal decomposition of waste.
  • On the outer wall of the reactor inside the heating space, there are also fixed some burned gas directing blades; these gases leave the reactor through an evacuation pipe situated on the upper part of the reactor.
  • the waste are decomposed at a temperature between
  • Part of the cracking oil is ebbed in an ebbing distribution chamber, situated in the lower part of the reactor, from where is arriving directly onto the rubber waste and the other part of it is reintroduced in the two tubular spiral heaters from inside the heating space and inside the pre- heater fixed to the gas evacuation pipe.
  • the solid products carbon black and steel are evacuated in the lower part of the reactor, passing into a carbon black separator from where the carbon black of a 97% purity and a granulation between 1-10 mm is passed inside a container and directed for being used in industry.
  • the invention according to the present description, has the following main advantages: - simple construction, safe in functioning, easy maintenance and no highly qualified staff is necessary - total recovery of rubber waste - reduction of the pollution factor, by the circulating of reacting products - obtaining hydrocarbons which can be used in the industry - is an economic process, with reduced consume of energy - uses its own energy obtained within the system by ebbing obtained oil, for heating and preheating both the reactor and the rubber waste that are to be terminally decomposed.
  • the thermal cracking apparatus for decomposing the rubber and plastic waste for the purpose of obtaining some hydrocarbons in order to be used on an industrial scale consists of vertical cracking reactor 1; on its cylindrical wall and on its lower conical part there is fixed a worm-gear shape mixer 15 with a vertical axis 23, with a driving-gear 24,10 with a supply system 8,18 and evacuation 9,19 with the heating space 2 where there are 2 spiral tubular pre-heaters 5, where the ebbing oil flows, oil obtained as a result of thermal decomposing of rubber waste, some blades 4 for directing burned gases, two burners 3, tangentially placed on the outer wall of the reactor, with an evacuation pipe for the burning products 26 around which the ebbing pre-heater 27 is wrapped up and an ebbing distribution unit
  • the waste sized between 15-200 mm are introduced into the vertical reactor 1, through a supply system 8 and 18 situated on the upper part of the reactor and in which at a temperature between 430 °C...580°C and a pressure of 50...350 mbar, wherein the waste is terminally decomposed into carbon black and hydrocarbons, gases, cracking gasoline and cracking oil.
  • the gases are directed for industrial use, and the carbon black together with the solid waste are evacuated through the evacuating system 9 situated in the lower part of the reactor 1 in inside the separator 45 from where the carbon black of 97% purity and maximum 10 mm granulation is passed into a container 43 with the help of a pneumatic transporter 46.
  • the liquid hydrocarbons: cracking oil and cracking gasoline are collected into pre-containers 34, 35 and 36. Because in this phase the cracking gasoline contains the condensed water, this is separated in separator 51.
  • the cracking gasoline with a density between 0,7284 and 0,8200 kg/dm 3 at 15°C is stored in the cracking gasoline container 38 from where through pipe 56 it is send to be stored.
  • the cracking oil with a density between 0,8200 at 0,9475 kg dm 3 at 15°C is stored in the cracking oil container 37 from where part of it is redirected in the ebbing distribution unit 39, 22 and from there a part of the cracking oil is ebbed through pipe 13 in the lower part of the reactor 1, thus getting directly on the rubber waste and another part of the cracking oil is reintroduced through coupling 14 into the two spiral tubular heaters 5 from inside the heating space 2 and inside the pre-heater 27 fixed on the gases evacuation pipe 26, and the other part is directed through pipe 55 for being stored.
  • the thermal transfer space is much enlarged, the temperature needed for thermal decomposing is maintained and at the same time the hydrocarbons proportion between light and heavy fractions obtained as a cracking result can be adjusted.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L'invention se rapporte à un procédé de craquage thermique destiné à la décomposition de déchets composés de caoutchouc et de matières plastiques, ainsi qu'à une installation permettant de mettre en oeuvre ce procédé. Selon l'invention, le procédé consiste à réaliser la décomposition thermique de déchets plastiques et à base de caoutchouc, d'une taille comprise entre 15 et 200 mm, à partir de l'énergie générée au cours du procédé par le soutirage d'une portion de l'huile de craquage ainsi obtenue et son utilisation pour chauffer les déchets provenant du réacteur ainsi que pour chauffer et préchauffer le réacteur. Selon l'invention, l'installation comprend: un réacteur de craquage (1) équipé d'un mélangeur en forme d'engrenage à vis (15) avec un axe vertical (23), un système d'engrenage de commande (24, 10, 21) fixé à la paroi cylindrique et à la partie conique inférieure du réacteur, une unité de distribution d'huile soutirée (39, 22), un volume de chauffage (2) dans lequel deux éléments de préchauffage tubulaires et hélicoïdaux (5) passent à travers l'huile soutirée obtenue après la décomposition thermique des écoulements de déchets à base de caoutchouc, ainsi que des aubes (4) permettant d'acheminer les produits en combustion. Sur la paroi externe du réacteur se trouvent deux brûleurs (3) tangentiels et un tuyau d'évacuation des produits en combustion (26), autour duquel s'enroule l'élément de préchauffage (27) et dans lequel s'écoule l'huile soutirée. La partie supérieure du réacteur (1) est équipée d'un tuyau d'évacuation (6) à travers lequel la matière obtenue par la décomposition thermique des déchets est acheminée vers un cyclone de séparation qui, à son tour, est accouplé à un appareil de rectification/refroidissement des gaz, à une colonne de lavage de gaz et à un appareil de condensation de gaz. Les produits obtenus sont destinés à un usage industriel, une partie étant destinée à être soutirée et utilisée dans le cadre du procédé technologique.
PCT/IB2004/002738 2003-08-27 2004-08-23 Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques Ceased WO2005021685A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MDA20060098A MD3343C2 (ro) 2003-08-27 2004-08-23 Procedeu şi instalaţie de cracare termică a deşeurilor de cauciuc şi mase plastice
EP04769165A EP1668092A1 (fr) 2003-08-27 2004-08-23 Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
RO200300710 2003-08-27
ROA200300710 2003-08-27
ROA200400294A RO120487B1 (ro) 2003-08-27 2003-10-10 Procedeu şi instalaţie de descompunere a deşeurilor de cauciuc şi mase plastice
ROA200400294 2003-10-10

Publications (1)

Publication Number Publication Date
WO2005021685A1 true WO2005021685A1 (fr) 2005-03-10

Family

ID=34277845

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2004/002738 Ceased WO2005021685A1 (fr) 2003-08-27 2004-08-23 Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques

Country Status (4)

Country Link
EP (1) EP1668092A1 (fr)
MD (1) MD3343C2 (fr)
RO (1) RO120487B1 (fr)
WO (1) WO2005021685A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119222A (zh) * 2014-07-28 2014-10-29 宝鸡市晋旺达机械设备有限公司 倾动式连续亚克力裂解炉
GB2518029A (en) * 2013-09-04 2015-03-11 Hedviga Group A S Method of fuel for energetics production and fuel producing device
AT14770U1 (de) * 2013-09-04 2016-05-15 Hedviga Group A S Vorrichtung zur Herstellung von Brennstoffen zur energetischen Nutzung
WO2021044228A1 (fr) * 2019-09-04 2021-03-11 Valgroup S.A. Réacteur à reflux continu sous pression et système commandé de condenseurs pour le traitement thermochimique de déchets plastiques et/ou élastomères

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660313A (zh) * 2012-05-26 2012-09-12 商丘市金源机械设备有限公司 一种废轮胎炼油工艺
CN105349169A (zh) * 2015-12-03 2016-02-24 南京绿帝环保能源科技有限公司 废轮胎及废橡胶催化裂解装置
CN109233349A (zh) * 2018-09-19 2019-01-18 中昊黑元化工研究设计院有限公司 微波裂解废旧轮胎联产炉法炭黑生产设备及方法
CN111286349A (zh) * 2020-02-24 2020-06-16 东南大学 一种基于热解炭内循环强化传热的双螺旋热解反应器

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10237460A (ja) * 1997-02-25 1998-09-08 Nippon Steel Corp 廃プラスチックの簡易油化処理方法
WO2003029384A1 (fr) * 2001-10-02 2003-04-10 Zoltan Szinay Appareil de pyrolyse permettant de traiter des granules grossiers de dechets de plastique et de caoutchouc
WO2004037949A1 (fr) * 2002-10-28 2004-05-06 Lekrinszki Istvan Appareil de pyrolyse de pneus laceres

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RO67000A2 (fr) * 1975-09-17 1983-07-07 Grupul De Intreprinderi De Industrie Locala "Mures",Ro Procede de decomposition des dechets de caoutchouc
US4176056A (en) * 1978-04-27 1979-11-27 Pennwalt Corporation Cyclic operation of a bed of mixed ion exchange resins

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10237460A (ja) * 1997-02-25 1998-09-08 Nippon Steel Corp 廃プラスチックの簡易油化処理方法
WO2003029384A1 (fr) * 2001-10-02 2003-04-10 Zoltan Szinay Appareil de pyrolyse permettant de traiter des granules grossiers de dechets de plastique et de caoutchouc
WO2004037949A1 (fr) * 2002-10-28 2004-05-06 Lekrinszki Istvan Appareil de pyrolyse de pneus laceres

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 14 31 December 1998 (1998-12-31) *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2518029A (en) * 2013-09-04 2015-03-11 Hedviga Group A S Method of fuel for energetics production and fuel producing device
AT14770U1 (de) * 2013-09-04 2016-05-15 Hedviga Group A S Vorrichtung zur Herstellung von Brennstoffen zur energetischen Nutzung
CN104119222A (zh) * 2014-07-28 2014-10-29 宝鸡市晋旺达机械设备有限公司 倾动式连续亚克力裂解炉
WO2021044228A1 (fr) * 2019-09-04 2021-03-11 Valgroup S.A. Réacteur à reflux continu sous pression et système commandé de condenseurs pour le traitement thermochimique de déchets plastiques et/ou élastomères
US11015127B2 (en) 2019-09-04 2021-05-25 Valgroup S.A. Continuous reflux reactor under pressure and controlled condenser system for thermochemical treatment of plastic and/or elastomeric waste
US11225610B2 (en) 2019-09-04 2022-01-18 Valgroup S.A. Continuous reflux reactor under pressure and controlled condenser system for thermochemical treatment of plastic and/or elastomeric waste

Also Published As

Publication number Publication date
RO120487B1 (ro) 2006-02-28
MD3343B1 (en) 2007-06-30
EP1668092A1 (fr) 2006-06-14
MD3343C2 (ro) 2008-01-31

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