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WO2005085336A1 - Procede de realisation d'un film multicouche f et son utilisation - Google Patents

Procede de realisation d'un film multicouche f et son utilisation Download PDF

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Publication number
WO2005085336A1
WO2005085336A1 PCT/EP2005/051138 EP2005051138W WO2005085336A1 WO 2005085336 A1 WO2005085336 A1 WO 2005085336A1 EP 2005051138 W EP2005051138 W EP 2005051138W WO 2005085336 A1 WO2005085336 A1 WO 2005085336A1
Authority
WO
WIPO (PCT)
Prior art keywords
basecoat
weight
layer
film
conditioned
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2005/051138
Other languages
German (de)
English (en)
Inventor
Bernd Biallas
Wolfgang Duschek
Markus Saedler
Klaus Dieter Stegemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Coatings GmbH
Original Assignee
BASF Coatings GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Coatings GmbH filed Critical BASF Coatings GmbH
Priority to BRPI0508487-3A priority Critical patent/BRPI0508487A/pt
Priority to EP05729820A priority patent/EP1723195B1/fr
Priority to CA002557786A priority patent/CA2557786A1/fr
Priority to US10/598,180 priority patent/US20070172595A1/en
Priority to AT05729820T priority patent/ATE432310T1/de
Priority to JP2007501296A priority patent/JP4903126B2/ja
Priority to DE502005007350T priority patent/DE502005007350D1/de
Publication of WO2005085336A1 publication Critical patent/WO2005085336A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B05D7/534—Base coat plus clear coat type the first layer being let to dry at least partially before applying the second layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B05D7/574—Three layers or more the last layer being a clear coat at least some layers being let to dry at least partially before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars

Definitions

  • the present invention relates to a new process for the production of a multilayer film F.
  • the present invention relates to the use of the film F produced by the new process for the production of color and / or effect coatings on three-dimensional substrates, in particular on automobile bodies.
  • Coloring and / or effect-giving coatings of motor vehicle bodies, in particular car bodies, today preferably consist of several layers of paint which are applied one above the other and have different properties.
  • an electrodeposited electrodeposition coating as a primer, a filler or Steinschiagstoffgrund ist, a basecoat and a clear coat are applied to a substrate.
  • ETL electrodeposited electrodeposition coating
  • the ETL serves in particular to protect the sheet against corrosion. It is often referred to by experts as a primer.
  • the filler coating serves to cover unevenness of the surface and, due to its elasticity, ensures resistance to stone chips. If necessary, the filler coating can also serve to increase the hiding power and to deepen the color tone of the coating.
  • the base coat contributes the colors and / or the angle-dependent optical effects. Both the brightness (amount) and the color (by wavelength-specific absorption or by interference) of the reflected light can vary depending on the viewing angle, which is also referred to as a brightness and / or color flop.
  • the clear coat serves to enhance the optical effects and to protect the paint from mechanical and chemical damage.
  • Multilayer coatings of this type which fully meet all the requirements placed on them, are often referred to by experts as Class A surfaces.
  • multilayer, color and / or effect films are known to comprise a carrier film, at least one color and / or effect basecoat and a clear coat. Their structure thus corresponds to that of conventional multi-layer paint and / or effect coatings.
  • the multilayer, color and / or effect films should be produced under constant conditions and be able to be applied to any substrates, which should result in a color and / or optical effect that is independent of the substrate and process. The application should be done by lamination on metals, back injection with thermoplastic materials, back foams or back pressing.
  • the known coloring and / or effect films can often not be stretched to the extent that would be necessary for the coating of complexly shaped three-dimensional substrates. If this is nevertheless attempted, mechanical damage and / or delamination of individual or all layers can occur.
  • the required higher dry layer thicknesses in the production of the known coloring and / or effect films require a much higher effort in the application and control of the proportion of volatile substances in the individual layers.
  • the state of the art makes only selective proposals for solving individual problems:;
  • the applied clearcoat layers are to be predried or cured at 1 to 93 ° C. for one minute to one hour.
  • the temperature should be selected so that the carrier film is not deformed or broken down.
  • the object of the present invention is to provide a new process for the production of a multilayer film F by coating an optionally pretreated carrier film
  • the new method should allow basecoat layers to be produced in the required high wet layer thicknesses without these leading to an incorrect color tone and / or an undesirable tackiness of the resulting basecoat.
  • the formation of stoves in the base coat should also be avoided.
  • this should result in basecoats with excellent technological properties, in particular with regard to adhesion, stone chip resistance, condensation resistance and color and flop behavior.
  • undesired " interactions between the wet coats should no longer occur. In particular, the breakdown of the clearcoat should be avoided because this would result in the resulting clearcoat being matted.
  • the drying temperature should not be above the softening temperature of the carrier film. Furthermore, no thermal crosslinking of the clear layer and / or the build-up of an excessively high molecular weight should occur in the new process, so that the deformability and stretchability of the multilayer films F are still guaranteed.
  • the new method for producing a multilayer film F by coating an optionally pretreated carrier film with 1. a pigmented basecoat,
  • a pigmented basecoat is applied to the carrier film, which results in a wet basecoat film 1a, which is adjusted to a residual volatile substance content of x ⁇ 10% by weight, based on the basecoat film, resulting in a conditioned basecoat film 1b,
  • the composite of carrier film and conditioned basecoat layer 1b is set to a temperature of ⁇ 50 ° C. on the surface of the basecoat layer 1b
  • a second pigmented basecoat or the same pigmented basecoat is applied for the second time to the conditioned and tempered basecoat layer 1b, which results in a wet basecoat layer 2a which results in a residual volatile substance content of y ⁇ 10% by weight, based on the basecoat layer, is set, which results in a conditioned basecoat layer 2b,
  • the composite of carrier film and conditioned basecoat layers 1b and 2b is set to a temperature of ⁇ 50 ° C. on the surface of the basecoat layer 2b,
  • a clearcoat is applied to the conditioned and tempered basecoat layer 1b or 2b, resulting in a wet clearcoat layer 3a, which is adjusted to a residual volatile substance content of z ⁇ 5% by weight, based on the clearcoat layer, whereby a conditioned, deformable , thermally and / or actinic radiation curable clear coat 3b results.
  • the new process for producing a multilayer film F is referred to below as the “process according to the invention”.
  • the method according to the invention no longer had the disadvantages of the prior art, but could be carried out in a simple and safe manner and provided reproducibly multilayer films F which were stored without problems and without mechanical damage and / or delamination of individual or of all layers could be stretched and that, after being applied to three-dimensional substrates, for example by preforming the foils F and back-molding, and preferably followed by final curing, coated three-dimensional substrates, in particular coated automobile bodies or modules and add-on parts for automobile bodies with coloring and / or effect-giving classes -A surfaces.
  • the method according to the invention allowed basecoat layers to be produced in the required high wet layer thicknesses, without these leading to an incorrect color tone and / or an undesirable tackiness of the resulting basecoat.
  • the formation of stoves in the base coat could also be avoided.
  • the clear lacquer layers in the required high wet layer thicknesses could also be produced without any problems, so that clear lacquers with excellent technological properties resulted.
  • all customary and known backing films, protective films and adhesive layers can be used, such as those described, for example, in American patents US 4,810,540 A, US 4,931,324 A or US 5,114,789 A, European patents EP 0 266 109 B1, EP 0 285 071 B 1, EP 0 352 298 B 1 or EP 0 449 982 B 1, the European patent applications EP 0 050 794 A 1, EP 0 261 815 A 1, EP 0 395 266 A 2, EP 0 754 740 A 2 or EP 0 949 120 A 1 or the international patent applications WO 96/40449 A 1 or WO 03/016095 A 1.
  • the carrier films can be pigmented or unpigmented.
  • the carrier films described from WO 03/016095 A 1, page 16, line 19, to page 17, line 3 are used.
  • the color of the pigmented carrier films can be adapted to the basecoats to be found later on.
  • the surface of the carrier films to be coated can be chemically and / or physically pretreated in a customary and known manner before the lacquers are applied.
  • the protective films which are applied to the composite carrier film-lacquer layer composite are compatible with the clear lacquer layers 3b.
  • aqueous basecoats such as are described, for example, in WO 03/016095 A 1; Page 10, line 15, to page 14, line 22.
  • Aqueous basecoats as described in EP 0 754 740 and in US Pat. No. 5,030,514 A, are also preferably used. Different basecoats or the same basecoat can be used for the production of the pigmented basecoat layers 1a and optionally 2a.
  • actinic radiation includes electromagnetic radiation, such as near infrared (NIR), visible light, UV radiation, X-rays and gamma radiation, in particular UV radiation, and corpuscular radiation, such as To understand electron radiation, alpha radiation, beta radiation, proton radiation and neutron radiation, in particular electron radiation.
  • electromagnetic radiation such as near infrared (NIR)
  • visible light such as visible light
  • UV radiation such as visible light
  • gamma radiation such as To understand electron radiation, alpha radiation, beta radiation, proton radiation and neutron radiation, in particular electron radiation.
  • Devices are preferably used in the method according to the invention which permit the continuous coating of tape-shaped carrier films with basecoats and clearcoats.
  • the application devices and the carrier films are in relative movement to one another.
  • the application devices are stationary, with the carrier films being guided past them in a continuous movement.
  • the application devices can be moved back and forth transversely to the direction of movement of the carrier films.
  • the basecoat is preferably applied using a directional application process.
  • suitable directed application methods are known from WO 03/016095 A 1, page 15, lines 6 to 19. Squeegees, casting devices and rollers are used in particular.
  • the base coat layer 2a is applied to the conditioned basecoat film 1b.
  • the basecoat is preferably applied with the aid of a non-directional application process which does not cause the pigments to be arranged in a preferred direction in the resulting basecoat layer 2a or 2b; that is, the pigments are isotropically distributed in the basecoat layer 2a and thus also in the conditioned basecoat layer 2b.
  • suitable non-directed application methods and devices therefor are known from WO 03/016095 A 1, page 20, line 4, to page 23, line 25.
  • pneumatic or electrostatic spraying devices are used, as described in WO 03/016095 A 1, page 20, line 4, to page 23, line 25.
  • the basecoat layer 2a can also be applied by electrostatic high-speed rotation or by electrostatically assisted pneumatic atomization.
  • the basecoat layer 1a can be applied with the aid of one of the directed application processes described above, which causes the pigments to be arranged in a preferred direction, ie, an anisotropic distribution of the pigments, in the resulting basecoat layer 1a or 1b.
  • a carrier film which largely or completely corresponds in color to the color of the ultimately resulting basecoat, only a non-opaque, coloring and / or effect layer can be applied as the basecoat layer by electrostatically assisted pneumatic atomization or pneumatic, electrostatic high-speed rotation become.
  • the liquid clearcoats can be applied using the directed and non-directed application methods described above.
  • the clear lacquers are preferably applied using directional application processes, very preferably using extrusion casters. If the liquid clear coats are (also) curable with actinic radiation, they are applied with the exclusion of actinic radiation and processed further.
  • Thermal and / or convection methods are preferably used for the conditioning of the wet basecoat layers 1a and optionally 2a and the wet clear coat layers 2a, with conventional and known devices such as continuous furnaces, NIR and IR radiant heaters, blowers and blowing tunnels being used. These devices can also be combined with one another.
  • the composites of carrier film and basecoat layer 1b or carrier film, basecoat layer 1b and basecoat layer 2b resulting in the course of the process according to the invention can be wound up, temporarily stored, transported and fed to another application device in which they are coated with this next layer before the application of the next layer in each case.
  • the composites can be covered with protective film, which is removed before the next layer is applied.
  • the method according to the invention is preferably carried out in a continuous system which has all the necessary application devices and
  • a pigmented basecoat is applied to the carrier film, resulting in a wet basecoat layer 1a, which is preferably heated and / or convected to a residual volatile substance content of x ⁇ 10% by weight, preferably ⁇ 7% by weight, particularly preferably ⁇ 5% by weight, in each case based on the basecoat layers, which results in a conditioned basecoat layer 1b.
  • the application takes place under cabin conditions, such as those known from OEM series painting.
  • the wet basecoat film 1a preferably has a layer thickness of 50 to 150 ⁇ m.
  • volatile substances are to be understood to mean all constituents of the basecoats and also of the clearcoats which, after the basecoat and clearcoat layers prepared from the basecoats and clearcoats have hardened, do not remain in the resulting basecoats and clearcoats.
  • the volatile substances are organic solvents and water.
  • the basecoat film 1a is preferably flashed off for 1 to 6 minutes, particularly preferably for 2 to 4 minutes.
  • the temperature, the air humidity and the air speed prevailing in the application zone are particularly preferably set during the ventilation. If drying is preceded by ventilation, drying takes place in a separate drying zone. The following drying kinetics are preferably used when conditioning the basecoat layer 1a:
  • an average drying rate of 10 to 40% by weight / min, based on the total volatile substance content of the applied basecoat, is used until a residual volatile substance content of x 12 to 30% by weight on the basecoat film, is reached, and
  • an average drying rate of 1 to 6% by weight / min, based on the total volatile substance content of the applied basecoat film, is used until a residual volatile substance content of x ⁇ 10% by weight, particularly preferably ⁇ 7% by weight, in particular ⁇ 5% by weight, in each case based on the basecoat film, has been reached.
  • the conditioning of the basecoat film 1a is preferably carried out at temperatures from 30 to 100.degree.
  • An air humidity of 3 to 15 g / kg is preferably set.
  • the duration of the conditioning is particularly preferably 1 to 10 minutes.
  • the air speeds are 0.2 to 15 m / s.
  • the resulting conditioned basecoat layer 1b preferably has a layer thickness of 10 to 30 ⁇ m.
  • the resulting composite of carrier film and conditioned basecoat layer 1b is set to a temperature of ⁇ 50 ° C., in particular ⁇ 35 ° C., on the surface of the basecoat layer 1b.
  • a second pigmented basecoat or the same basecoat is applied for the second time to the conditioned and tempered basecoat layer 1b, which results in a wet basecoat layer 2a, which is preferably by
  • the wet basecoat layer 2a preferably has a layer thickness of 25 to 100 ⁇ m.
  • the basecoat film 2a is preferably flashed off for 1 to 6 minutes, particularly preferably for 3 to 5 minutes.
  • the temperature, the air humidity and the air speed prevailing in the application zone are particularly preferably set during the ventilation. If drying is preceded by ventilation, drying takes place in a separate drying zone.
  • drying kinetics are preferably used when conditioning the basecoat film 2a:
  • an average drying rate of 10 to 40% by weight / min, based on the total content of volatile substances in the applied basecoat, until a residual volatile substance content of y 12 to 30% by weight, based on the basecoat, is reached, and in the last drying section an average drying rate of 1.5 to 4% by weight / min, based on the total volatile substance content of the applied basecoat film, until a residual volatile substance content of x ⁇ 10% by weight, particularly preferred ⁇ 7% by weight, in particular ⁇ 5% by weight, based in each case on the basecoat film, has been reached.
  • the conditioning of the basecoat film 2a is preferably carried out at temperatures from 30 to 100.degree.
  • An air humidity of 3 to 15 g / kg is preferably set.
  • the duration of the conditioning is particularly preferably 1 to 10 minutes.
  • the air speeds are 0.2 to 15 m / s.
  • the resulting conditioned basecoat layer 2b preferably has a layer thickness of 5 to 20 ⁇ m.
  • the total layer thickness of the basecoat layers 1b and 2b is preferably 15 to 50 ⁇ m.
  • method step d. carried out when a second basecoat layer 2b is present.
  • the resulting composite of carrier film and conditioned basecoat layers 1b and 2b is set to a temperature of ⁇ 50 ° C., in particular ⁇ 35 ° C., on the surface of the basecoat layer 2b.
  • a clear lacquer is applied to the conditioned and tempered basecoat layer 1b or 2b, which results in a wet clearcoat layer 3a which, by heating and / or convection, has a residual volatile substance content of z ⁇ 5% by weight, in particular ⁇ 3% by weight , based on the clear coat, is adjusted, resulting in a conditioned, deformable, thermally and / or curable with actinic radiation clear coat 3b.
  • the wet clear lacquer layer 3a preferably has a layer thickness of 80 to 160 ⁇ m.
  • the clear lacquer layer 3a is preferably flashed off for 2 to 8 minutes, particularly preferably for 5 to 7 minutes.
  • the temperature, the air humidity and the temperature are particularly preferred for the ventilation
  • an average drying rate of 10 to 30% by weight / min, based on the total content of volatile substances in the applied clearcoat, until a residual content of volatile substances of z 10 to 15% by weight, based on the clearcoat, is reached, and in the last drying section, an average drying rate of 0.5 to 3% by weight / min, based on the total volatile substance content of the applied clearcoat, until a residual volatile substance content of z ⁇ 7% by weight, particularly preferably ⁇ 5% by weight. %, in particular ⁇ 3% by weight, in each case based on the clear lacquer layer, is reached.
  • the clear lacquer layer 3a is preferably conditioned during at oven temperatures of 80 to 140 ° C., in particular 90 to 120 ° C.
  • the layer thickness of the conditioned clear lacquer layer 3b is preferably 40 to 80 ⁇ m.
  • a customary and known protective film is placed on the multilayer film F.
  • the multilayer film F is wound into a roll or cut into smaller boards.
  • the roll can be stored and / or transported until the multilayer film is used again.
  • the multilayer films F produced with the aid of the method according to the invention are outstandingly suitable for the production of coloring and / or effect films. These in turn are outstandingly suitable for the coating of substrates, preferably three-dimensional substrates, in particular automobile bodies and modules or attachments therefor.
  • the multilayer films F are connected to the substrates. They are stretched before, during or after their connection. After their connection to the substrates, the multilayer films F are preferably converted into the coloring and / or effect films by thermal curing and / or curing with actinic radiation. The curing is preferably carried out as described in WO 03/016095 A1, page 27, lines 19 to page 28, line 24.
  • the foils F according to the invention provide coated three-dimensional substrates, in particular coated automobile bodies or modules and add-on parts for automobile bodies, with color and / or effect-giving Class A surfaces after their preforming, back injection and subsequent final curing.
  • the commercially available, dark gray pigmented, 800 ⁇ m thick carrier film based on Luran® from BASF Aktiengesellschaft and the commercially available basecoat brilliant silver from BASF Coatings AG content of non-volatile substances approx. 20 % By weight, based on the lacquer
  • the commercially available, light gray pigmented, 800 ⁇ m thick carrier film based on Luran ® from BASF Aktiengesellschaft and the commercially available basecoat travertine beige from BASF Coatings AG content of non-volatile substances approx. 20 % By weight, based on the lacquer
  • the commercially available, black pigmented, 800 ⁇ m thick carrier film based on Luran ® from BASF Aktiengesellschaft and the commercially available basecoat Obsidian black from BASF Coatings AG content of non-volatile substances approx. 20 % By weight, based on the lacquer
  • the multilayer films F1 to F3 were produced in accordance with the following general manufacturing instructions.
  • the surface of the carrier film to be coated was subjected to a corona pretreatment with 0.5 kilowatts.
  • the basecoat was applied to the carrier film with the aid of a box doctor blade with a width of 37 cm and a belt speed of 0.5 m / min.
  • the application was carried out with a weak air flow of 0.2 m / s, a constant temperature of 21 + 1 ° C and a constant relative air humidity of 65 + 5%.
  • the layer thickness of the resulting wet basecoat layer 1a was 100 ⁇ m.
  • the basecoat film 1a was dried for 3 minutes at an average drying rate of 3% by weight / min, based on the
  • the air temperature was 90 ° C, the air humidity 10g / min and the air speed 10 m / s.
  • the resulting conditioned basecoat layer 1b with a layer thickness of approximately 20 ⁇ m was adjusted to a surface temperature of ⁇ 30 ° C. using cooling rollers.
  • Outflow rate 100 ml / min; - Air pressures: atomizing air: 2.5 bar; Hom air: 2.5 bar; Travel speed of the nozzles so high that the spray jets overlap by 60%; Distance nozzle - film: 30 cm.
  • the application was carried out with a weak air flow of 0.5 m / s (vertical flow against the film), a constant temperature of 21 + 1 ° C and a constant relative air humidity of 65 + 5%.
  • the layer thickness of the resulting wet basecoat layer 2a was 50 + 2 ⁇ m.
  • the basecoat film 2a was flashed off under these conditions for 3 minutes.
  • the air temperature was 90 ° C, the air humidity 10g / min and the air speed 10 m / s.
  • the resulting conditioned basecoat layer 2b with a layer thickness of approximately 10 ⁇ m was adjusted to a surface temperature of ⁇ 30 ° C. using chill rolls.
  • the clear lacquer was applied to the conditioned and tempered basecoat layer 2b with the aid of a box doctor blade with a width of 37 cm.
  • the application was carried out with a weak air flow of 0.2 m / s, a constant temperature of 21 + 1 ° C and a constant relative air humidity of 65 + 5%.
  • the layer thickness of the resulting wet clearcoat layer 3a was 120 ⁇ m. It was flashed off under the conditions mentioned for 6 minutes.
  • the air temperature in the oven was 119 ° C for all drying levels.
  • the resulting conditioned clear lacquer layer 3b with a layer thickness of 60 ⁇ m was adjusted to a surface temperature of ⁇ 30 ° C. with cooling rollers and covered with a protective film made of polypropylene.
  • the resulting multilayer film F was wound into a roll and stored in this form until further use.
  • the multilayer films F1 to F3 could easily be wound into rolls and stored and / or transported until further use, without this their outstanding application properties, in particular their dimensional stability on the one hand and their deformability on the other hand suffered damage. They could easily be cut into boards. The boards could be sealed in airtight and moistureproof films and stored in this form for months.
  • the multilayer films F1 to F3 were outstandingly suitable for the production of Class A surfaces on automobile bodies and for the production of modules and attachments with Class A surfaces.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Massaging Devices (AREA)

Abstract

La présente invention concerne un procédé de réalisation d'un film multicouche F, comprenant les étapes suivantes: a. une couche de laque de base 1a est appliquée sur un film de support et la teneur résiduelle en substances volatiles est régulée pour être x < 10 % en poids, ce qui permet d'obtenir une couche de laque de base conditionnée 1b; b. le composite obtenu est porté à une température < 50 °C; c. une seconde couche de laque de base pigmentée 2a est éventuellement appliquée sur la couche de laque de base et la teneur résiduelle en substances volatiles est régulée pour être y < 10 % en poids, ce qui permet d'obtenir une couche de laque de base conditionnée 2b; d. le composite éventuellement obtenu est porté à une température < 50 °C; et e. une couche de laque claire est appliquée sur la couche de laque de base 1b ou 2b, et la teneur résiduelle en substances volatiles est régulée pour être z < 5 % en poids, ce qui permet d'obtenir une couche de laque claire 3b conditionnée, déformable, thermodurcissable et/ou durcissable par rayonnement actinique. L'invention a également pour objet l'utilisation du film multicouche F pour la réalisation de films colorés et/ou films à effets.
PCT/EP2005/051138 2004-03-05 2005-03-02 Procede de realisation d'un film multicouche f et son utilisation Ceased WO2005085336A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BRPI0508487-3A BRPI0508487A (pt) 2004-03-05 2005-03-02 processo para preparação de um laminado f de múltiplas camadas e seu emprego
EP05729820A EP1723195B1 (fr) 2004-03-05 2005-03-02 Procede de realisation d'un film multicouche f et son utilisation
CA002557786A CA2557786A1 (fr) 2004-03-05 2005-03-02 Procede de realisation d'un film multicouche f et son utilisation
US10/598,180 US20070172595A1 (en) 2004-03-05 2005-03-02 Method for producing a multilayered film f and use thereof
AT05729820T ATE432310T1 (de) 2004-03-05 2005-03-02 Verfahren zur herstellung einer mehrschichtigen folie f und ihre verwendung
JP2007501296A JP4903126B2 (ja) 2004-03-05 2005-03-02 多層シートｆの製造方法及びその使用
DE502005007350T DE502005007350D1 (de) 2004-03-05 2005-03-02 Lie f und ihre verwendung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004010787A DE102004010787A1 (de) 2004-03-05 2004-03-05 Verfahren zur Herstellung einer mehrschichtigen Folie F und ihre Verwendung
DE102004010787.4 2004-03-05

Publications (1)

Publication Number Publication Date
WO2005085336A1 true WO2005085336A1 (fr) 2005-09-15

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PCT/EP2005/051138 Ceased WO2005085336A1 (fr) 2004-03-05 2005-03-02 Procede de realisation d'un film multicouche f et son utilisation

Country Status (11)

Country Link
US (1) US20070172595A1 (fr)
EP (1) EP1723195B1 (fr)
JP (1) JP4903126B2 (fr)
KR (1) KR20070007115A (fr)
CN (1) CN100482722C (fr)
AT (1) ATE432310T1 (fr)
BR (1) BRPI0508487A (fr)
CA (1) CA2557786A1 (fr)
DE (2) DE102004010787A1 (fr)
RU (1) RU2006135085A (fr)
WO (1) WO2005085336A1 (fr)

Cited By (1)

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RU2006135085A (ru) 2008-06-10
JP2007526120A (ja) 2007-09-13
BRPI0508487A (pt) 2007-07-31
EP1723195A1 (fr) 2006-11-22
ATE432310T1 (de) 2009-06-15
DE102004010787A1 (de) 2005-09-22
CN100482722C (zh) 2009-04-29
CN1930220A (zh) 2007-03-14
DE502005007350D1 (de) 2009-07-09
JP4903126B2 (ja) 2012-03-28
EP1723195B1 (fr) 2009-05-27
KR20070007115A (ko) 2007-01-12
US20070172595A1 (en) 2007-07-26
CA2557786A1 (fr) 2005-09-15

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