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WO2005053832B1 - Procede et dispositif permettant de stocker et de distribuer de l'hydrogene - Google Patents

Procede et dispositif permettant de stocker et de distribuer de l'hydrogene

Info

Publication number
WO2005053832B1
WO2005053832B1 PCT/US2004/039644 US2004039644W WO2005053832B1 WO 2005053832 B1 WO2005053832 B1 WO 2005053832B1 US 2004039644 W US2004039644 W US 2004039644W WO 2005053832 B1 WO2005053832 B1 WO 2005053832B1
Authority
WO
WIPO (PCT)
Prior art keywords
compound
hydrogen
metal substrate
spent
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2004/039644
Other languages
English (en)
Other versions
WO2005053832A3 (fr
WO2005053832A2 (fr
Inventor
Buddy D Ratner
Esmaeel D Naeemi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asemblon Inc
Original Assignee
Asemblon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP04812209A priority Critical patent/EP1692076B1/fr
Priority to KR1020067012787A priority patent/KR101151501B1/ko
Priority to CA2547123A priority patent/CA2547123C/fr
Priority to BRPI0416884-4A priority patent/BRPI0416884A/pt
Priority to AT04812209T priority patent/ATE543780T1/de
Priority to MXPA06006043A priority patent/MXPA06006043A/es
Priority to EA200601046A priority patent/EA012551B1/ru
Priority to JP2006541733A priority patent/JP5154082B2/ja
Priority to AU2004294972A priority patent/AU2004294972A1/en
Application filed by Asemblon Inc filed Critical Asemblon Inc
Priority to TW093136347A priority patent/TWI380950B/zh
Publication of WO2005053832A2 publication Critical patent/WO2005053832A2/fr
Publication of WO2005053832A3 publication Critical patent/WO2005053832A3/fr
Publication of WO2005053832B1 publication Critical patent/WO2005053832B1/fr
Priority to IL175920A priority patent/IL175920A/en
Anticipated expiration legal-status Critical
Priority to AU2011200253A priority patent/AU2011200253A1/en
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0203—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels characterised by the type of gaseous fuel
    • F02M21/0206—Non-hydrocarbon fuels, e.g. hydrogen, ammonia or carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02M21/0221—Fuel storage reservoirs, e.g. cryogenic tanks
    • F02M21/0224—Secondary gaseous fuel storages
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02M21/0227—Means to treat or clean gaseous fuels or fuel systems, e.g. removal of tar, cracking, reforming or enriching
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04208—Cartridges, cryogenic media or cryogenic reservoirs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04216—Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45—Hydrogen technologies in production processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/30—Use of alternative fuels, e.g. biofuels
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Fuel Cell (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne la production d'hydrogène destiné à générer de l'énergie. L'invention concerne également des procédés, des dispositifs et des ensembles impliquant la production d'hydrogène. Lesdits procédés consistent à faire réagir des composés contenant de l'oxygène, tels que des composés d'organothiol, avec un substrat métallique réactif afin de produire un gaz hydrogène et d'utiliser ce gaz pour générer de l'énergie. L'invention concerne enfin la régénération du composé utilisé sous une forme appropriée riche en hydrogène par réaction de ce composé avec de l'hydrogène. Le stockage et la production d'hydrogène, tels que décrits dans l'invention, permettent de produire de l'hydrogène afin de générer de l'énergie dans des dispositifs consommant de l'hydrogène, tels que des moteurs et des piles à combustible, par exemple, installés dans des véhicules à hydrogène.
PCT/US2004/039644 2003-11-26 2004-11-24 Procede et dispositif permettant de stocker et de distribuer de l'hydrogene Ceased WO2005053832A2 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
AU2004294972A AU2004294972A1 (en) 2003-11-26 2004-11-24 Method and device for hydrogen storage and delivery
CA2547123A CA2547123C (fr) 2003-11-26 2004-11-24 Procede et dispositif permettant de stocker et de distribuer de l'hydrogene
BRPI0416884-4A BRPI0416884A (pt) 2003-11-26 2004-11-24 métodos de geração de energia, de armazenagem e produção de hidrogênio e de regeneração de composto, dispositivos de produção de hidrogênio, automóveis e conjuntos de produção e utilização de hidrogênio
AT04812209T ATE543780T1 (de) 2003-11-26 2004-11-24 Verfahren zur energieerzeugung
MXPA06006043A MXPA06006043A (es) 2003-11-26 2004-11-24 Metodo y dispositivo para el almacenamiento y el suministro de hidrogeno.
EA200601046A EA012551B1 (ru) 2003-11-26 2004-11-24 Способ и устройство для хранения и доставки водорода
JP2006541733A JP5154082B2 (ja) 2003-11-26 2004-11-24 水素貯蔵及び送出のための方法及び装置
EP04812209A EP1692076B1 (fr) 2003-11-26 2004-11-24 Procédé de production d'énergie
KR1020067012787A KR101151501B1 (ko) 2003-11-26 2004-11-24 수소 보관 및 전달을 위한 방법 및 장치
TW093136347A TWI380950B (zh) 2003-11-26 2004-11-25 用於氫氣儲存及輸送之方法及裝置
IL175920A IL175920A (en) 2003-11-26 2006-05-25 Method and device for hydrogen storage and delivery
AU2011200253A AU2011200253A1 (en) 2003-11-26 2011-01-21 Method and device for hydrogen storage and delivery

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US52542203P 2003-11-26 2003-11-26
US60/525,422 2003-11-26
US10/997,368 2004-11-23
US10/997,368 US7186396B2 (en) 2003-11-26 2004-11-23 Method for hydrogen storage and delivery

Publications (3)

Publication Number Publication Date
WO2005053832A2 WO2005053832A2 (fr) 2005-06-16
WO2005053832A3 WO2005053832A3 (fr) 2006-03-09
WO2005053832B1 true WO2005053832B1 (fr) 2006-05-11

Family

ID=34657177

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/039644 Ceased WO2005053832A2 (fr) 2003-11-26 2004-11-24 Procede et dispositif permettant de stocker et de distribuer de l'hydrogene

Country Status (14)

Country Link
US (2) US7186396B2 (fr)
EP (1) EP1692076B1 (fr)
JP (1) JP5154082B2 (fr)
KR (1) KR101151501B1 (fr)
AT (1) ATE543780T1 (fr)
AU (2) AU2004294972A1 (fr)
BR (1) BRPI0416884A (fr)
CA (1) CA2547123C (fr)
EA (1) EA012551B1 (fr)
IL (1) IL175920A (fr)
MX (1) MXPA06006043A (fr)
SG (1) SG148204A1 (fr)
TW (1) TWI380950B (fr)
WO (1) WO2005053832A2 (fr)

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US7101530B2 (en) 2003-05-06 2006-09-05 Air Products And Chemicals, Inc. Hydrogen storage by reversible hydrogenation of pi-conjugated substrates
US7351395B1 (en) 2003-05-06 2008-04-01 Air Products And Chemicals, Inc. Hydrogen storage by reversible hydrogenation of pi-conjugated substrates
US7186396B2 (en) * 2003-11-26 2007-03-06 Asemblon, Inc. Method for hydrogen storage and delivery
US7485161B2 (en) 2005-01-04 2009-02-03 Air Products And Chemicals, Inc. Dehydrogenation of liquid fuel in microchannel catalytic reactor
JP2006248814A (ja) * 2005-03-09 2006-09-21 Hitachi Ltd 水素供給装置および水素供給方法
US20080045409A1 (en) * 2006-08-16 2008-02-21 Buarque De Macedo Pedro M Ceramic catalysts
JP4918826B2 (ja) 2006-08-31 2012-04-18 株式会社日立製作所 燃料タンク
US9623393B2 (en) * 2008-10-31 2017-04-18 Asemblon, Inc. Dehydrogenation of cyclic thioethers
US20100172796A1 (en) * 2008-11-26 2010-07-08 James Norgaard Metal hydride storage system for a portable, intrinsically safe, flame ionization detector (FID) device
JP5737853B2 (ja) * 2010-03-29 2015-06-17 千代田化工建設株式会社 貯蔵・輸送用水素の製造方法
CN102432063B (zh) * 2011-09-15 2013-08-14 上海工程技术大学 一种用于功能织物的中性纳米二氧化钛水溶胶的制备方法
CN104285327A (zh) 2012-03-07 2015-01-14 智能能源公司 用于氢发生器的燃料单元
EP3154901B1 (fr) * 2014-06-13 2023-09-27 USW Commercial Services Ltd. Synthèse et propriétés de stockage d'hydrogène de nouveaux hydrures métalliques
US10207241B2 (en) 2016-11-29 2019-02-19 Kontak LLC Inductively heated microchannel reactor
WO2019231979A1 (fr) * 2018-05-29 2019-12-05 Kontak LLC Station de ravitaillement modulaire
US11638331B2 (en) 2018-05-29 2023-04-25 Kontak LLC Multi-frequency controllers for inductive heating and associated systems and methods
US11555473B2 (en) 2018-05-29 2023-01-17 Kontak LLC Dual bladder fuel tank
ES2978419A2 (es) 2021-12-20 2024-09-12 Univ Jaume I Procedimiento de almacenamiento de hidrogeno en forma liquida

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Also Published As

Publication number Publication date
AU2011200253A1 (en) 2011-02-17
JP2007521134A (ja) 2007-08-02
WO2005053832A3 (fr) 2006-03-09
WO2005053832A2 (fr) 2005-06-16
AU2004294972A2 (en) 2005-06-16
KR20060134009A (ko) 2006-12-27
US20050142401A1 (en) 2005-06-30
AU2004294972A1 (en) 2005-06-16
CA2547123A1 (fr) 2005-06-16
US20070003476A1 (en) 2007-01-04
EP1692076A4 (fr) 2008-03-05
CA2547123C (fr) 2011-02-15
TW200524823A (en) 2005-08-01
KR101151501B1 (ko) 2012-07-05
EA200601046A1 (ru) 2006-12-29
EP1692076B1 (fr) 2012-02-01
BRPI0416884A (pt) 2007-03-06
EP1692076A2 (fr) 2006-08-23
JP5154082B2 (ja) 2013-02-27
TWI380950B (zh) 2013-01-01
US8459032B2 (en) 2013-06-11
ATE543780T1 (de) 2012-02-15
MXPA06006043A (es) 2007-01-26
SG148204A1 (en) 2008-12-31
IL175920A0 (en) 2006-10-05
IL175920A (en) 2011-09-27
EA012551B1 (ru) 2009-10-30
US7186396B2 (en) 2007-03-06

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