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WO2004067487A3 - Procede de production d'hydrocarbures non aromatiques - Google Patents

Procede de production d'hydrocarbures non aromatiques Download PDF

Info

Publication number
WO2004067487A3
WO2004067487A3 PCT/EP2003/014308 EP0314308W WO2004067487A3 WO 2004067487 A3 WO2004067487 A3 WO 2004067487A3 EP 0314308 W EP0314308 W EP 0314308W WO 2004067487 A3 WO2004067487 A3 WO 2004067487A3
Authority
WO
WIPO (PCT)
Prior art keywords
fused salt
chain
branched
hydrocarbons
alkyl halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2003/014308
Other languages
German (de)
English (en)
Other versions
WO2004067487A2 (fr
Inventor
Ruediger Forster
Peter Wasserscheid
Christiane Werth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EOn Ruhrgas AG
Original Assignee
Ruhrgas AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruhrgas AG filed Critical Ruhrgas AG
Priority to AU2003293899A priority Critical patent/AU2003293899A1/en
Priority to EP03789297A priority patent/EP1587776A2/fr
Publication of WO2004067487A2 publication Critical patent/WO2004067487A2/fr
Publication of WO2004067487A3 publication Critical patent/WO2004067487A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de production d'hydrocarbures à longue chaîne, à chaîne ramifiée et/ou cycliques. Tout d'abord, on prend un alcane halogéné inférieur et un sel fondu. Le sel fondu contient un composé électrophile et un agent de réduction et est exempt d'oxygène et de composés oxygéné. L'alcane halogéné est ensuite mis en contact avec le sel fondu de telle façon que des hydrocarbures à longue chaîne, à chaîne ramifiée et/ou cycliques se forment dans le sel fondu. Les hydrocarbures formés dans les sels fondus sont retirés et peuvent ensuite être séparés de l'éduit non converti. Selon l'invention, de l'oxygène est généré lors de la conversion de l'alcane halogéné inférieur. Le risque d'oxydation de l'alcane généré donnant du monoxyde de carbone ou du dioxyde de carbone est supprimé par les conditions de réduction régnant dans les sels fondus. Le choix sélectif de la composition du sel fondu permet de contrôler la répartition du produit. L'utilisation préférée d'un sel fondu de sodium-aluminate chloré entraîne la génération, par exemple, d'hydrocarbures hautement ramifiés.
PCT/EP2003/014308 2003-01-28 2003-12-16 Procede de production d'hydrocarbures non aromatiques Ceased WO2004067487A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2003293899A AU2003293899A1 (en) 2003-01-28 2003-12-16 Method for the production of non-aromatic hydrocarbons
EP03789297A EP1587776A2 (fr) 2003-01-28 2003-12-16 Procede de production d'hydrocarbures non aromatiques

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10303304A DE10303304A1 (de) 2003-01-28 2003-01-28 Verfahren zum Herstellen nichtaromatischer Kohlenwassersstoffe
DE10303304.1 2003-01-28

Publications (2)

Publication Number Publication Date
WO2004067487A2 WO2004067487A2 (fr) 2004-08-12
WO2004067487A3 true WO2004067487A3 (fr) 2004-11-25

Family

ID=32603001

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/014308 Ceased WO2004067487A2 (fr) 2003-01-28 2003-12-16 Procede de production d'hydrocarbures non aromatiques

Country Status (4)

Country Link
EP (1) EP1587776A2 (fr)
AU (1) AU2003293899A1 (fr)
DE (1) DE10303304A1 (fr)
WO (1) WO2004067487A2 (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
MXPA06000470A (es) 2003-07-15 2006-08-23 Grt Inc Sintesis de hidrocarburos.
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
SG187456A1 (en) 2006-02-03 2013-02-28 Grt Inc Separation of light gases from halogens
US7579510B2 (en) 2006-02-03 2009-08-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
WO2007106943A1 (fr) 2006-03-22 2007-09-27 Ultraclean Fuel Pty Ltd Procede d'elimination de soufre d'hydrocarbures liquides
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
AU2014231720B2 (en) 2013-03-15 2018-11-08 Ultraclean Fuel Limited Process for removing sulphur compounds from hydrocarbons
US9441169B2 (en) 2013-03-15 2016-09-13 Ultraclean Fuel Pty Ltd Process for removing sulphur compounds from hydrocarbons

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1026187A (en) * 1963-10-28 1966-04-14 Ici Ltd Electrolytic production of halogenated organic compounds
US3969427A (en) * 1974-11-19 1976-07-13 Mobil Oil Corporation Conversion of alcohols and/or ethers to hydrocarbons
US5087786A (en) * 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5573161A (en) * 1978-11-27 1980-06-02 Oki Electric Ind Co Ltd Digital reproduction repeater
US5994604A (en) * 1993-03-17 1999-11-30 Lockheed Martin Idaho Technologies Company Method and apparatus for low temperature destruction of halogenated hydrocarbons

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1026187A (en) * 1963-10-28 1966-04-14 Ici Ltd Electrolytic production of halogenated organic compounds
US3969427A (en) * 1974-11-19 1976-07-13 Mobil Oil Corporation Conversion of alcohols and/or ethers to hydrocarbons
US5087786A (en) * 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes

Also Published As

Publication number Publication date
AU2003293899A8 (en) 2004-08-23
WO2004067487A2 (fr) 2004-08-12
AU2003293899A1 (en) 2004-08-23
EP1587776A2 (fr) 2005-10-26
DE10303304A1 (de) 2004-07-29

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