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WO2004046395A1 - Method of setting ultrasonic shock treatment conditions for metal material - Google Patents

Method of setting ultrasonic shock treatment conditions for metal material Download PDF

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Publication number
WO2004046395A1
WO2004046395A1 PCT/JP2003/014596 JP0314596W WO2004046395A1 WO 2004046395 A1 WO2004046395 A1 WO 2004046395A1 JP 0314596 W JP0314596 W JP 0314596W WO 2004046395 A1 WO2004046395 A1 WO 2004046395A1
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WO
WIPO (PCT)
Prior art keywords
treatment
ultrasonic impact
temperature
processing
ultrasonic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2003/014596
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French (fr)
Japanese (ja)
Inventor
Tomonori Tominaga
Koji Honma
Tadashi Ishikawa
Yakichi Higo
Kazuki Takashima
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Nippon Steel Corp
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Nippon Steel Corp
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Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to AU2003280833A priority Critical patent/AU2003280833A1/en
Publication of WO2004046395A1 publication Critical patent/WO2004046395A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/02Modifying the physical properties of iron or steel by deformation by cold working
    • C21D7/04Modifying the physical properties of iron or steel by deformation by cold working of the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B25HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25DPERCUSSIVE TOOLS
    • B25D2250/00General details of portable percussive tools; Components used in portable percussive tools
    • B25D2250/275Tools having at least two similar components
    • B25D2250/285Tools having three or more similar components, e.g. three motors
    • B25D2250/291Tools having three or more parallel bits, e.g. needle guns
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/02Modifying the physical properties of iron or steel by deformation by cold working
    • C21D7/04Modifying the physical properties of iron or steel by deformation by cold working of the surface
    • C21D7/06Modifying the physical properties of iron or steel by deformation by cold working of the surface by shot-peening or the like

Definitions

  • the processing conditions are adjusted according to the target modification degree of the target metal material.
  • the durability of metal products is often determined by fatigue and corrosion.
  • Various approaches have been taken to improve these.
  • In order to improve fatigue it has been practiced to improve the toe shape to reduce stress concentration and to apply compressive residual stress by using grinding and various kinds of peung.
  • coatings such as painted ones, non-conductive coatings such as stainless steel, and protections such as weathering steel that provide protection ⁇ to reduce the amount of corrosion have become practical. I have.
  • the crystal structure of the surface layer of a metal material was changed to nanometer (nm).
  • nm nanometer
  • properties such as ultra-high strength.
  • the metal material is made into an amorphous state and then subjected to a low-temperature heat treatment. is there.
  • methods such as rapid quenching of a metal material or sputtering film formation.
  • the powder of the metal material is treated with a pole mill or the like, and the surface of the metal material is subjected to strong working, thereby converting the metal material into an amorphous form and then heat-treating the amorphous material.
  • a metal powder having a nanocrystalline structure can be obtained.
  • This metal powder can be pressed at a high temperature or subjected to a treatment such as welding to form a structure.
  • a treatment such as welding
  • the surface of the metal material is subjected to an ultrasonic impact treatment to give a plastic deformation to the surface or to release the residual stress.
  • a method of applying ultrasonic impact treatment to a welded portion of a metal material to release residual stress in the welded portion reduce minute defects such as voids and abnormal grain boundaries, and improve fatigue performance.
  • Methods of improvement for example, Transactions of the Japan Society of Mechanical Engineers (C), Vol. 67, No. 657 (2001-5), Japanese Unexamined Patent Application Publication No. Hei 9-234, 855, Japanese Unexamined Patent Application Publication No. And US Patent No. 6,338,765.
  • a transducer that generates an ultrasonic wave, a waveguide for guiding the ultrasonic wave to the tip, and a vibration provided by the ultrasonic wave provided at the tip.
  • U.S. Patent Application Launches Ultrasonic Shock Processor with Head to Hold Rotating Shock Pins It is known from US Pat. No. 2,002,000. However, in this force method, the temple B (Journal of Material Science Technology. Vol. ID, No. 3, 1999, Institute of Solid-State Physics, Academy of Science of the USSR. No. 7, pp. 14 -16, July, 1988, it is also known to improve the surface crystallographic structure, meaning that this technique has the property of improving the material as well as being a post-treatment.
  • ultrasonic impact treatment has the effect of improving fatigue strength
  • high-strength steel is more plastic in terms of toe shape improvement effect, although high-strength steel is more advantageous in terms of residual stress improvement effect. It tends to be less deformable, and the treatment efficiency tends to decrease, and the effect of the treatment layer thickness in the depth direction tends to decrease.
  • the present invention relates to a method for setting ultrasonic impact processing conditions for determining a processing condition including a processing temperature range in accordance with a target degree of modification of a target metal material when performing an ultrasonic impact treatment on a metal material surface layer.
  • the purpose is to provide.
  • the present invention has been made to solve the above problems, and the gist thereof is as follows.
  • any one or more of the effects of fatigue strength improvement, surface modification, and welding crack improvement are selected as the effects of the required ultrasonic impact treatment. After determining the ultrasonic shock treatment temperature according to each effect, set the conditions of the ultrasonic shock treatment, and finally determine the efficient combination of those treatments. How to set sonic impact processing conditions.
  • the ultrasonic impact treatment aims to improve the fatigue strength of newly-formed workpieces. If the welding toe treatment is inefficient, determine the ineffectiveness of the weld toe treatment based on the metal strength of the new workpiece. If not, determine the processing temperature from the temperature dependence of the metal strength. Efficient conditions to improve the toe shape by performing ultrasonic shock treatment at the temperature determined in the lowering process and to apply compressive residual stress again at room temperature if you want to apply compressive residual stress again (1) The method for setting ultrasonic shock treatment conditions for a metal material according to (1).
  • the ultrasonic impact treatment is intended to improve the fatigue strength of the existing work, it is determined whether the weld toe treatment is inefficient based on the metal strength of the existing work. After determining the ultrasonic impact treatment temperature from the temperature dependence of the metal strength, heating to the determined temperature, ultrasonic impact treatment is performed to improve the toe shape, and compressive residual stress is applied If desired, the ultrasonic impact treatment is performed again at room temperature under conditions necessary to introduce compressive residual stress.
  • the ultrasonic impact treatment is intended to recover the accumulated fatigue of the existing workpiece, a process appropriate for the recovery of the transition accumulated due to the repeated stress from the state diagram of the metal material of the existing workpiece.
  • the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the ultrasonic impact processing is performed by judging the processing under heating or at room temperature (1). A method for setting the ultrasonic impact processing conditions of the metal material described.
  • the ultrasonic impact treatment is for surface modification, determine whether alloying is necessary from the surface state of the metal material to be treated, or if necessary, the alloy component to be supplied, Next, after the processing temperature is determined from the phase diagram of the alloy, the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the combination of processing under heating or normal temperature is determined to perform the ultrasonic impact processing.
  • the metal material described in (1) How to set ultrasonic shock treatment conditions.
  • the ultrasonic impact treatment is aimed at improving welding cracks, select the treatment temperature from the welding conditions for the target metal material and the state diagram of the target metal material, and then apply the ultrasonic impact from the relationship between the treatment temperature and the treatment pattern. It is characterized in that the processing conditions are determined and the ultrasonic impact treatment is performed by judging the combination of the temperature drop after welding and the ultrasonic impact treatment at room temperature. How to set sonic impact processing conditions.
  • FIG. 1 is a diagram showing a flow of a method for setting ultrasonic shock processing conditions according to the present invention.
  • Fig. 2 shows an example of an ultrasonic impact processing machine.
  • Fig. 2 (a) is a schematic configuration diagram of an ultrasonic hammering impact processing machine used in the present invention
  • Fig. 2 (b) is an ultrasonic impact processing machine used in the present invention.
  • FIG. 2 is an enlarged view of a tip portion of the sonic shot peening impact processing machine.
  • This ultrasonic impact treatment enables the following (a) to (d) and enables efficient processing of a wide area.
  • Multi-axial ultrasonic impact treatment promotes nano-crystallization.That is, it is difficult to obtain a nano-crystalline structure by uniaxial treatment. is necessary.
  • (C) At least a structure capable of controlling the atmosphere of the treated surface, suppressing the formation of an oxide layer, achieving a good metal surface state, and further enabling the formation of an alloy layer. If the surface atmosphere is an oxidizing atmosphere, oxides generated on the material surface will be caught in the surface layer, causing surface defects and impairing the strength and corrosion resistance. By controlling the atmosphere, not only such a decrease in the surface material can be avoided, but also, by setting the atmosphere to a specific atmosphere, for example, a nitrogen atmosphere, it is possible to infiltrate the surface layer with nitrogen to improve the characteristics. Can also improve
  • Supplying powder that is, providing an impact by using the pin itself as a specific metal material, and simultaneously supplying metal powder or small pieces of the pin to the surface of the material to be treated, and making the surface layer a desired alloy layer Can be.
  • a new function can be added to the metal material surface.
  • the above-mentioned ultrasonic impact treatment is generally performed as a micronization phenomenon in the surface layer of a metal material as a treatment thickness of 10 to 200 m, and a plastic deformation / molding depth direction range of 1 to 1 m. It is said to introduce up to 5 mm and compressive residual stress of about 1 to 3 mm.
  • the present inventors have found through research that all of these phenomena are closely related to the processing temperature. In other words, since the phenomena and effects obtained in the processing temperature range are different from each other, setting the processing conditions in accordance with the target level of metal material reforming is directly possible with the above-mentioned ultrasonic impact processing. Get the full effect It can be demonstrated.
  • the processing temperature range and the phenomena and effects obtained are described below, especially for steel, which is one of the most commonly used metal materials.
  • fine frit grains are formed by recrystallization refinement to increase toughness, and on the plastic deformation surface, particularly solidification cracks of the weld metal and cooling cracks can be prevented.
  • the crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer of the metal material, and at the same time, fine ferrite grains can be formed by recrystallization and refinement in the core, thereby increasing the toughness.
  • the fatigue strength can be improved because the welding toe can be efficiently molded.
  • high-strength steel when high-strength steel is machined, it can be subjected to plastic deformation forming similar to mild steel at low temperatures.
  • the crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer of the metal material, and at the same time, the structure can be refined by utilizing the reverse transformation behavior accompanying the decrease in the transformation temperature.
  • the fatigue strength can be improved by efficiently forming the weld toe.
  • residual stress during multiple passes of welding and compressive residual stress due to cooling cracks can be reduced.
  • the crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer portion of the metal material, and at the same time, the structure can be refined by utilizing the reverse transformation behavior accompanying the decrease in the transformation temperature. Also, plastic deformation can be expected to improve fatigue strength and reduce compressive residual stress.
  • the treatment temperature is determined based on the required effects of the ultrasonic impact treatment, for example, the effects of improving the fatigue strength, modifying the surface, and improving the weld cracking in the target metal material. It is characterized in that conditions for ultrasonic shock processing are set.
  • conditions for ultrasonic shock processing are set.
  • the above-described arrangement can be reasonably facilitated by utilizing the phase diagram obtained from the component composition, the temperature-strength relationship, and the like.
  • Fig. 1 after determining the target of the metal material to be subjected to the ultrasonic impact treatment (working), it is necessary to determine what improvement effect should be given to the target by improving the fatigue strength, surface modification and welding cracking. Choose from improvements. For example, if the main purpose is to improve the fatigue strength, either the provision of the fatigue strength of the virgin material or the recovery of the fatigue strength of the existing material is used. Determine whether the treatment is inefficient and determine the treatment temperature from the temperature dependence of metal strength. On the other hand, in the case of existing materials, the appropriate processing temperature for recovery is determined from the phase diagram of the metal material. Next, for both cases, a work flow can be designed in which the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the processing under heating or normal temperature is determined and the ultrasonic impact processing is performed.
  • the ultrasonic impact processing conditions are determined from the processing temperature-processing pattern relationship, and processing under heating or normal temperature is determined.
  • a work flow for performing ultrasonic impact treatment can be designed.
  • the main purpose is to improve weld cracking
  • the processing temperature after selecting the processing temperature from the welding conditions for the target metal material and the state diagram of the metal, determine the ultrasonic impact processing conditions from the processing temperature-processing pattern relationship, It is possible to design a work flow in which ultrasonic impact processing is performed by judging processing under heating or normal temperature.
  • the ultrasonic shock treatment under heating it is a matter of course that issues such as welding, heat source, temperature sensor, supply of metal components, and shield gas are taken into account.
  • the above-described ultrasonic impact treatment can provide an added effect by performing the treatment multiple times for each temperature range, the same processing or different processing may be appropriately performed multiple times in accordance with the above work flow. It is natural that the sonic impact treatment is performed.
  • this ultrasonic impact treatment for example, in a multi-pass welding process, the ultrasonic impact treatment is performed in a temperature range of 670 ° C to 750 ° C, and then the ultrasonic impact treatment is performed again at room temperature.
  • the first pass bead is subjected to ultrasonic impact treatment at a temperature range of 850 ° C or higher to prevent hot cracking due to stress fluctuation.
  • ultrasonic impact treatment was performed in the temperature range of 400 ° C to 65 ° C to prevent lamellar tearing, and finally the toe after welding was completed was kept at room temperature. High fatigue strength can be imparted by ultrasonic impact treatment.
  • the surface of the steel material during or after use is subjected to ultrasonic impact treatment at the above-mentioned arbitrary temperature range to nanostructure the surface layer structure, and when the complementation of the alloy is required, the ultrasonic impact treatment is applied. It is necessary to supply alloy from outside. Regeneration can be achieved by adding necessary characteristics.
  • FIG. 2 (a) shows the outline of the equipment used for ultrasonic hammering impact processing, and (b) shows the outline of the equipment in which only the tip of (a) is changed to ultrasonic shot peening impact processing.
  • an ultrasonic hammering impact machine 1 has a transducer 2 that emits ultrasonic waves, and a cylindrical shape attached to the front of the transducer 2 and guides the ultrasonic waves generated by the transducer 2 to the tip. It comprises a wave guide 3 and a head 4 attached to the end of the wave guide 3, that is, the side facing the object to be processed.
  • the head 4 has one or more holes 5 at its end, and a rod-shaped pin 6 inserted in the up and down direction of the hole 5, and between the upper end of the pin 6 and the end of the wave guide 3. It consists of a holder 9 that contains the provided space 8 and is housed.
  • the holder 9 is detachably connected to the outer periphery of the wave guide 3 by an annular metal fitting 10, and can be replaced including the pin 6. It is configured as possible. The diameter, number, arrangement, material, shape, etc. of the pins can be changed as necessary.
  • a resin cover 11 surrounding the outer periphery of the wave guide 3 with a gap provided therebetween is provided in the middle of the wave guide 3 to cool and lubricate the wave guide and the head having the vibrating section.
  • the porous body 12 for holding the lubricant to be filled can be filled.
  • an opening 13 is provided between the lower end of the cover 11 and the wave guide 3, and the lubricant coolant is supplied to the head 4 via the opening 13.
  • a water-cooled or air-cooled device may be provided to cool the transducer 2.
  • Transducer 2 converts electrical energy to ultrasonic energy
  • a magnetic or electric transducer can be used.
  • the former can be increased in capacity and operate with high stability over a wide range of acoustic loads, but on the other hand are heavy and require cooling.
  • the latter has a small capacity but is highly efficient, generates less heat, can reduce cooling, and is excellent in portability.
  • a magnetic or electric transducer may be arbitrarily selected depending on processing conditions and purposes.
  • the number of pins 6 stored in the head 4 may be one, but by arranging a plurality of pins in one or more rows, processing efficiency and processing area can be doubled.
  • the pin 6 is generally vibrated in one axial direction, but the pin 6 itself may rotate or move in an arbitrary direction within the processing area.
  • a gear is attached to the root of each pin, and the motor is rotated 100 times Z seconds by the rotation driving force of an externally provided motor through the gear.
  • the transducer 2 When the transducer 2 emits ultrasonic waves, the generated ultrasonic waves are transmitted to the wave guide 3 connected thereto, and the velocity is denatured by the reduced diameter of the wave guide 3.
  • the ultrasonic wave reaches the head 4 from the tip of the waveguide 3 and vibrates the pin 6 in contact therewith. Due to this vibration, the tip of the pin 6 strikes the surface of the object 14 to be subjected to impact processing.
  • the processing conditions are preferably an amplitude of 20 to 60 ⁇ , a frequency of 15 kHz to 60 kHz, and an output of 0.2 to 1 kW.
  • Fig. 2 (b) the outline of the equipment used for ultrasonic shot peening impact processing is shown in Fig. 2 (b), which is partially enlarged, as shown in the ultrasonic hammering impact processing shown in Fig. 2 (a).
  • small particles 15 such as steel balls and cut wires or small particles 15 such as sapphires are stored in the head 4 by the ultrasonic waves emitted from the tip of the wave guide 3.
  • the processed plate 8 is vibrated, the hard small-diameter steel material 15 in contact with the plate 8 is vibrated, and the surface of the object 14 to be processed is hit, thereby performing impact processing.
  • the processing conditions may be the same as those when using the ultrasonic hammering impact machine described above.
  • the material of the small particles of shots Biningu is, in the present invention using Safuaiya ball weighing approximately 7 mg, copper spheres mentioned above other, ultra copper balls, Serra Mi click Ssu, alumina (A1 2 0 3), Jirukonia (Zr0 2), silicon nitride (S i 3 N 4), S i C, S i O 2, Saiaro down like can be used.
  • As the type of shot binning to be used it is preferable to appropriately select and use the type, hardness, and ultrasonic oscillation power of the material to be treated. Further, it is more preferable that the diameter and area of the ultrasonic vibration plate are changed depending on the relationship between the small particles and the material to be treated. Industrial applicability
  • the temperature range of the ultrasonic impact treatment is selected according to the desired effect (improvement of fatigue strength, surface modification, and improvement of weld cracking) to be imparted to the target metal material.
  • the desired effect can be obtained by performing this process, and a combined effect can be obtained by arbitrarily combining this treatment multiple times.
  • the surface state of the steel material during or after use can be changed to a nanostructure. This has the effect that new characteristics can be added.
  • the surface of the stress-concentrated part where the fatigue strength is a concern in large-sized structures where the metal material to be treated is large and cannot be treated in a normal treatment furnace should be repaired and treated periodically and repeatedly.
  • the surface state of the steel material can be converted into a nanostructure to provide a property recovery effect.
  • the effect of recovering the fatigue characteristics can be obtained by minimizing the deformation of the weld toe and by mainly converting the surface structure of the material to nano to eliminate the transition in the surface layer.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

A method of setting ultrasonic shock treatment conditions for a metal material for determining treatment conditions, particularly, a treatment temperature range according to the degree of a target reformation of the treated metal material when the metal material surface layer part is subjected to an ultrasonic shock treatment, characterized by comprising the steps of selecting, as a required effect by the ultrasonic shock treatment, one or a plurality of effects from the improvement of fatigue strength, reformation of surfaces, and improvement of weld cracking in the treated metal material, determining an ultrasonic shock treatment temperature for each effect, setting the conditions for the ultrasonic shock treatment, and finally determining the efficient combination of these steps.

Description

金属材料の超音波衝撃処理条件の設定方法 Setting method of ultrasonic shock treatment conditions for metallic materials

技術分野 Technical field

本発明は、 金属材料表層部を超音波衝撃処理するに際し、 対象と なる金属材料の目標とする改質程度に従って処理条件、 特に処理温 明  According to the present invention, when performing an ultrasonic impact treatment on the surface layer of a metal material, the processing conditions, particularly the processing temperature, are adjusted according to the target modification degree of the target metal material.

度域とその組み合わせを決定する超音波衝撃処理条件の設定方法に 関するものである。 田 It relates to a method of setting ultrasonic impact processing conditions that determine the range and combinations thereof. Rice field

背景技術 Background art

金属製品の耐久性は、 しばしば疲労と腐食によって規定される。 これらの改善のためには、 様々な手法が取られてきた。 疲労の改善 のためには、 グライ ンデイ ング、 各種ピーユングによ り止端形状を 改善して応力集中を減少させたり 、 また圧縮残留応力を付与するこ とが行われてきた。 また、 腐食については、 塗装などの塗膜による もの、 ステンレスなど不導体皮膜を活用したもの、 耐候性鋼のよ う に保護性鲭を作って腐食量を小さ く抑えるものなどが実用になって いる。  The durability of metal products is often determined by fatigue and corrosion. Various approaches have been taken to improve these. In order to improve fatigue, it has been practiced to improve the toe shape to reduce stress concentration and to apply compressive residual stress by using grinding and various kinds of peung. As for corrosion, coatings such as painted ones, non-conductive coatings such as stainless steel, and protections such as weathering steel that provide protection 鲭 to reduce the amount of corrosion have become practical. I have.

このよ う に、 金属製品の耐久性を向上させるには、 製作後の後処 理によるものと、 材料そのものを改善する方法の大きく 分けて二つ の手法があるのが現状である といえる。  As described above, to improve the durability of metal products, it can be said that at present, there are two methods that can be roughly divided into post-processing after production and methods for improving the material itself.

このう ち、 材料の改善とレヽぅ面においては、 最近において、 Jour nal of Material Science Technology. Vol.15, No.3, 1999によ り 、 金属材料の表面層の結晶組織をナノ メータ ( n m, 1 0— 9m) を 単位と して適当なサイズ、 例えば、 1 0 0 n m以下に微細化した、 所謂ナノ結晶組織を得るこ とによ り、 従来には得られなかった優れ た性質、 例えば、 超高強度等の特性を得られるこ とが知られている このナノ結晶組織を有する金属材料を得るには、 金属材料を一旦 アモルファス状態と し、 次いで低温熱処理を行う方法である。 また 、 アモルフ ァス状態とするには、 金属材料を高速急冷或いはスパッ タ製膜等の方法があるが、 この場合、 広く一般の形状の成形体や構 造体を得るには様々な製造上の制約がある。 また、 この他に、 金属 材料の粉末をポールミル等で処理し、 金属材料表面に強加工を施す こ とによ り この金属材料をアモルフ ァス化し、 次いでこれを熱処理 するこ とによ り、 ナノ結晶構造を有する金属粉末を得るこ とができ る。 この金属粉末を高温で加圧成形し、 或いは更に溶接等の処理を 行って構造体とするこ とができる。 ところが、 上記高温の熱処理過 程を経るこ とによってナノ結晶組織構造が成長して消失するために 、 このナノ結晶組織の特性を生かした成形体や構造体を得るこ とは 困難と されている。 Of these, regarding the improvement of materials and their performance, recently, according to the Journal of Material Science Technology. Vol. 15, No. 3, 1999, the crystal structure of the surface layer of a metal material was changed to nanometer (nm). By obtaining a so-called nanocrystalline structure with an appropriate size in units of, for example, 100 to 9 m), for example, 100 nm or less, superior In order to obtain a metal material having this nanocrystalline structure, it is known to obtain properties such as ultra-high strength. For example, the metal material is made into an amorphous state and then subjected to a low-temperature heat treatment. is there. In order to obtain the amorphous state, there are methods such as rapid quenching of a metal material or sputtering film formation. In this case, a variety of manufacturing methods are required to obtain a widely used shaped body or structure. There are restrictions. In addition, the powder of the metal material is treated with a pole mill or the like, and the surface of the metal material is subjected to strong working, thereby converting the metal material into an amorphous form and then heat-treating the amorphous material. A metal powder having a nanocrystalline structure can be obtained. This metal powder can be pressed at a high temperature or subjected to a treatment such as welding to form a structure. However, since the nanocrystalline structure grows and disappears through the high-temperature heat treatment process, it is difficult to obtain a molded product or a structure utilizing the characteristics of the nanocrystalline structure. .

一方、 前記耐久性の向上方法のう ち後処理に属する技術では、 金 属材料の表面に超音波衝撃処理を施すこ とによ り表面に塑性変形を 与え、 或いは残留応力を開放するこ とが知られており、 例えば、 金 属材料の溶接部に超音波衝撃処理を施し、 溶接部の残留応力を開放 し、 ボイ ドゃ異常粒界のよ うな微小欠陥を低減する方法、 疲労性能 を向上させる方法、 例えば、 日本機械学会論文集 (C編) 67卷 657 号 (2001-5 )、 特開平 9 一 2 3 4 5 8 5号公報、 特開平 1 0— 2 9 6 4 6 1号公報および米国特許第 6 3 3 8 7 6 5号公報で提案され ている。 また、 上記超音波衝撃処理を行うための機器と して、 超音 波を発生させる ト ラ ンスデューサー、 超音波を先端に導く ためのゥ エーブガィ ド、 その先端に設けられ超音波によ り振動する衝撃用ピ ンを収納するへッ ドを備えた超音波衝撃処理機が米国特許出願公開 第 2 0 0 2 / 0 0 1 4 0 0号明細書で知られている。 しかし、 この 力法では同 B寺(こ Journal of Material Science Technology. Vol. ID , No.3, 1999、 Institute of Sol id-State Physics , Academy of S cience of the USSR. No.7, pp.14- 16, July, 1988、 に見られるよ うに、 表面結晶組織を改善することも知られている。 つまり、 この 技術は後処理であると同時に材料の改善という特性を持っていると ¾ る。 On the other hand, in the technology belonging to the post-processing among the above-mentioned methods for improving the durability, the surface of the metal material is subjected to an ultrasonic impact treatment to give a plastic deformation to the surface or to release the residual stress. For example, a method of applying ultrasonic impact treatment to a welded portion of a metal material to release residual stress in the welded portion, reduce minute defects such as voids and abnormal grain boundaries, and improve fatigue performance. Methods of improvement, for example, Transactions of the Japan Society of Mechanical Engineers (C), Vol. 67, No. 657 (2001-5), Japanese Unexamined Patent Application Publication No. Hei 9-234, 855, Japanese Unexamined Patent Application Publication No. And US Patent No. 6,338,765. In addition, as a device for performing the above-described ultrasonic shock treatment, a transducer that generates an ultrasonic wave, a waveguide for guiding the ultrasonic wave to the tip, and a vibration provided by the ultrasonic wave provided at the tip. U.S. Patent Application Launches Ultrasonic Shock Processor with Head to Hold Rotating Shock Pins It is known from US Pat. No. 2,002,000. However, in this force method, the temple B (Journal of Material Science Technology. Vol. ID, No. 3, 1999, Institute of Solid-State Physics, Academy of Science of the USSR. No. 7, pp. 14 -16, July, 1988, it is also known to improve the surface crystallographic structure, meaning that this technique has the property of improving the material as well as being a post-treatment.

しかしながら、 従来の超音波衝撃処理は、 疲労強度の向上、 微小 欠陥の軽減などが主体であり、 金属材料表層の材料特性、 表面改質 が改善されるとしてもそれは副産物的に、 その範囲、 程度などはか なりばらつきが多い状況で生じており、 目的に合わせて主体的にコ ント ロールして改善するまでには至っていない。  However, conventional ultrasonic impact treatment mainly focuses on improving fatigue strength and reducing minute defects.Even if the material properties and surface modification of the surface layer of a metal material are improved, it is a byproduct, its range and degree This has occurred in situations where there is a great deal of variation, and it has not yet reached the point of independent control and improvement according to the purpose.

上記の様々な超音波を利用しての効果の研究は、 それぞれの効果 に対して独立に、 個別になされており、 殆ど同じよ うな機材を用い て処理を行っているのにもかかわらず、 それらの処理のための必要 条件や効果を統一的な設計概念で扱って、 処理対象の金属加工物に とつて必要な効果を適切に、 選択的に得ることはできていなかった 。 特に条件の中でも温度に関しては、 「溶接中」 というおおざっぱ な高温状態と、 常温の 2種類しか検討がなく、 それがこの超音波衝 撃処理の可能性を狭めていた状況であるといえる。  The studies of the effects using the various ultrasounds described above have been performed independently and individually for each effect, and despite the fact that the processing is performed using almost the same equipment, The necessary conditions and effects for these treatments have not been treated in a unified design concept, and the necessary effects for the metal workpiece to be treated have not been properly and selectively obtained. In particular, with regard to the temperature among the conditions, only the rough high-temperature state “during welding” and the normal temperature were examined, and this is the situation that narrowed the possibility of this ultrasonic impact treatment.

その結果、 現在の金属製品の疲労や腐食に関する状況は以下のよ うな課題を抱えているといえる。  As a result, it can be said that the current situation regarding fatigue and corrosion of metal products has the following issues.

1 ) 金属材料を溶接した場合、 鋼材で作り込んだ特性が溶接部で損 なわれることが多く、 そのような場合には溶接部を塗装などの 手段で補完している。  1) When metal materials are welded, the characteristics made with steel materials are often impaired at the welds. In such cases, the welds are supplemented by means such as painting.

2 ) 溶接凝固時に超音波を使用して残留応力を低減させる場合、 疲 労強度向上効果が限定的であり、 しかも止端形状の改善効果は 見られない。 2) When using ultrasonic waves to reduce residual stress during welding solidification, the effect of improving fatigue strength is limited, and the effect of improving the toe shape is limited. can not see.

3 ) 超音波衝撃処理で疲労強度向上効果はあるも、 高強度鋼の方が 残留応力改善効果の面では有利であるに係わらず、 止端形状の 改善効果に関しては高強度鋼の方が塑性変形しにく く、 処理効 率が低下するこ と、 また深さ方向の処理層厚の影響度が低下す る傾向にある。  3) Although ultrasonic impact treatment has the effect of improving fatigue strength, high-strength steel is more plastic in terms of toe shape improvement effect, although high-strength steel is more advantageous in terms of residual stress improvement effect. It tends to be less deformable, and the treatment efficiency tends to decrease, and the effect of the treatment layer thickness in the depth direction tends to decrease.

4 ) 航空機等では疲労の発生する部分を炉に挿入し、 加熱して集積 した転移を回復する技術が実施されているが、 橋梁等の大型構 造物ではそのよ うな技術の適用が非現実的である。  4) In aircraft, etc., technology to restore the accumulated dislocation by heating by inserting the part where fatigue occurs into the furnace and heating it, but it is impractical to apply such technology to large structures such as bridges. It is.

このよ う に、 大気中で構造物のサイズ、 希望する疲労強度、 高強 度の部位に係わらず、 対象となる金属材料の改質目標と処理温度域 を含めた処理条件との組み合わせについては何ら解明されていない のが現状である。 発明の開示  In this way, regardless of the size of the structure in the atmosphere, the desired fatigue strength, and the high-strength part, there is no description of the combination of the target for reforming the target metal material and the processing conditions including the processing temperature range. It is not clear yet. Disclosure of the invention

本発明は、 金属材料表層部を超音波衝撃処理するに際し、 対象と なる金属材料の目標とする改質程度に従って処理温度域を含めた処 理条件を決定する超音波衝撃処理条件の設定方法を提供するこ とを 目的とする。 本発明は、 上記課題を解決するためになされたもので 、 その要旨は以下の通りである。  The present invention relates to a method for setting ultrasonic impact processing conditions for determining a processing condition including a processing temperature range in accordance with a target degree of modification of a target metal material when performing an ultrasonic impact treatment on a metal material surface layer. The purpose is to provide. The present invention has been made to solve the above problems, and the gist thereof is as follows.

( 1 ) 処理対象とする金属材料において、 必要とする超音波衝撃 処理による効果と して、 疲労強度改善、 表面改質、 溶接割れ改善の 何れか、 または複数の効果を選択し、 次いで、 前記それぞれの効果 ごとに応じて超音波衝撃処理温度を決定後、 超音波衝撃処理の条件 設定を行い、 最終的にそれらの処理の効率的な組み合わせを決定す ることを特徴とする金属材料の超音波衝撃処理条件の設定方法。  (1) For the metal material to be treated, any one or more of the effects of fatigue strength improvement, surface modification, and welding crack improvement are selected as the effects of the required ultrasonic impact treatment. After determining the ultrasonic shock treatment temperature according to each effect, set the conditions of the ultrasonic shock treatment, and finally determine the efficient combination of those treatments. How to set sonic impact processing conditions.

( 2 ) 前記超音波衝撃処理が新設加工物の疲労強度改善を目的と する場合には、 該新設加工物の金属強度から溶接止端処理が非効率 であるかを判断し、 非効率な場合は金属強度の温度依存性から処理 温度を決定し、 溶接終了後の温度低下過程で決定された温度時点で 超音波衝撃処理を行って止端形状を改善し、 さ らに圧縮残留応力を 付与したい場合は常温で再度、 圧縮残留応力を導入するのに効率的 な条件で超音波衝撃処理を行う こ とを特徴とする ( 1 ) 記載の金属 材料の超音波衝撃処理条件の設定方法。 (2) The ultrasonic impact treatment aims to improve the fatigue strength of newly-formed workpieces. If the welding toe treatment is inefficient, determine the ineffectiveness of the weld toe treatment based on the metal strength of the new workpiece. If not, determine the processing temperature from the temperature dependence of the metal strength. Efficient conditions to improve the toe shape by performing ultrasonic shock treatment at the temperature determined in the lowering process and to apply compressive residual stress again at room temperature if you want to apply compressive residual stress again (1) The method for setting ultrasonic shock treatment conditions for a metal material according to (1).

( 3 ) 前記超音波衝撃処理が既設加工物の疲労強度改善を目的と する場合には、 該既設加工物の金属強度から溶接止端処理が非効率 であるかを判断し、 非効率な場合は前記金属強度の温度依存性から 超音波衝撃処理温度を決定後、 決定された温度まで加熱した上で超 音波衝撃処理を行って止端形状を改善し、 さ らに圧縮残留応力を付 与したい場合は常温で再度、 圧縮残留応力を導入するのに必要な条 件で超音波衝撃処理を行う こ とを特徴とする ( 1 ) 記載の金属材料 の超音波衝撃処理条件の設定方法。  (3) If the ultrasonic impact treatment is intended to improve the fatigue strength of the existing work, it is determined whether the weld toe treatment is inefficient based on the metal strength of the existing work. After determining the ultrasonic impact treatment temperature from the temperature dependence of the metal strength, heating to the determined temperature, ultrasonic impact treatment is performed to improve the toe shape, and compressive residual stress is applied If desired, the ultrasonic impact treatment is performed again at room temperature under conditions necessary to introduce compressive residual stress. The method for setting the ultrasonic impact treatment conditions for a metal material according to (1), wherein:

( 4 ) 前記超音波衝撃処理が既設加工物の疲労蓄積回復を目的と する場合には、 該既設加工物の金属材料の状態図から繰り返し応力 によ り蓄積された転移の回復に適切な処理温度を決定後、 処理温度 一処理パターン関係から超音波衝撃処理条件を決定し、 加熱下また は常温下での処理を判断して超音波衝撃処理を行う こ とを特徴とす る ( 1 ) 記載の金属材料の超音波衝撃加工条件の設定方法。  (4) If the ultrasonic impact treatment is intended to recover the accumulated fatigue of the existing workpiece, a process appropriate for the recovery of the transition accumulated due to the repeated stress from the state diagram of the metal material of the existing workpiece. After the temperature is determined, the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the ultrasonic impact processing is performed by judging the processing under heating or at room temperature (1). A method for setting the ultrasonic impact processing conditions of the metal material described.

( 5 ) 前記超音波衝撃処理が表面改質を目的とする場合には、 処 理対象とする金属材料の表面状態から合金化が必要か、 必要であれ ば供給すべき合金成分を決定し、 次いで、 当該合金の状態図から処 理温度を決定後、 処理温度一処理パターン関係から超音波衝撃加工 条件を決定し、 加熱下または常温下での加工の組み合わせを決定し て超音波衝撃処理を行う こ とを特徴とする ( 1 ) 記載の金属材料の 超音波衝撃処理条件の設定方法。 (5) If the ultrasonic impact treatment is for surface modification, determine whether alloying is necessary from the surface state of the metal material to be treated, or if necessary, the alloy component to be supplied, Next, after the processing temperature is determined from the phase diagram of the alloy, the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the combination of processing under heating or normal temperature is determined to perform the ultrasonic impact processing. (1) The metal material described in (1) How to set ultrasonic shock treatment conditions.

( 6 ) 前記超音波衝撃処理が溶接割れ改善を目的とする場合には 、 対象金属材料に対する溶接条件および対象金属材料の状態図から 処理温度を選定後、 処理温度一処理パターン関係から超音波衝撃処 理条件を決定し、 溶接後の温度低下状況と常温下での超音波衝撃処 理の組み合わせを判断して超音波衝撃処理を行う こ とを特徴とする ( 1 ) 記載の金属材料の超音波衝撃加工条件の設定方法。 図面の簡単な説明  (6) If the ultrasonic impact treatment is aimed at improving welding cracks, select the treatment temperature from the welding conditions for the target metal material and the state diagram of the target metal material, and then apply the ultrasonic impact from the relationship between the treatment temperature and the treatment pattern. It is characterized in that the processing conditions are determined and the ultrasonic impact treatment is performed by judging the combination of the temperature drop after welding and the ultrasonic impact treatment at room temperature. How to set sonic impact processing conditions. BRIEF DESCRIPTION OF THE FIGURES

図 1 は、 本発明による超音波衝撃処理条件の設定方法のフローを 示す図である。  FIG. 1 is a diagram showing a flow of a method for setting ultrasonic shock processing conditions according to the present invention.

図 2は、 超音波衝撃加工機の例を示すもので、 図 2 ( a ) は本発 明に用いる超音波ハンマリ ング衝撃加工機の概略構成図、 図 2 ( b ) は本発明に用いる超音波ショ ッ ト ピーニング衝撃加工機の先端部 の拡大図である。 発明を実施するための最良の実施形態  Fig. 2 shows an example of an ultrasonic impact processing machine. Fig. 2 (a) is a schematic configuration diagram of an ultrasonic hammering impact processing machine used in the present invention, and Fig. 2 (b) is an ultrasonic impact processing machine used in the present invention. FIG. 2 is an enlarged view of a tip portion of the sonic shot peening impact processing machine. BEST MODE FOR CARRYING OUT THE INVENTION

先ず、 本発明における超音波衝撃処理について説明する。  First, the ultrasonic impact processing in the present invention will be described.

この超音波衝撃処理は、 下記 ( a ) 〜 ( d ) を可能にする と共に 、 広範囲の面積を効率的に処理できるよ うにしたものである。  This ultrasonic impact treatment enables the following (a) to (d) and enables efficient processing of a wide area.

( a ) 超音波衝撃処理を多軸的に施すこ とによってナノ結晶化を促 進する、 即ち、 一軸方向の処理ではナノ結晶構造を得るこ とは困難 であり、 多軸方向からの強処理が必要である。  (a) Multi-axial ultrasonic impact treatment promotes nano-crystallization.That is, it is difficult to obtain a nano-crystalline structure by uniaxial treatment. is necessary.

( b ) 金属材料表面の温度制御を可能とする構造とするこ とによ り 、 超音波衝撃処理で得られる表層の諸特性を選択できるよ う にする こ と、 即ち、 高温での処理では変形は大きいが残留応力が小さ く 、 逆に低温での処理では変形は小さいが残留応力が大き く付与され、 依って、 ナノ結晶化の度合い、 ナノ結晶組織周辺の組織の状況が変 化するので、 要求される特性に応じて処理条件を選択するこ とがで さる。 (b) By making the structure capable of controlling the temperature of the metal material surface, various characteristics of the surface layer obtained by ultrasonic impact treatment can be selected. Deformation is large but residual stress is small. Conversely, treatment at low temperature gives small deformation but large residual stress. Therefore, the degree of nanocrystallization and the state of the structure around the nanocrystal structure change, so that the processing conditions can be selected according to the required characteristics.

( C ) 少なく とも処理表面の雰囲気を制御可能な構造と し、 酸化物 層の形成を抑制し、 良好な金属表面状態とする と共に、 更には合金 層の形成を可能とすること、 即ち、 処理表面の雰囲気が酸化雰囲気 である と材料表面で生成した酸化物が表層部に巻き込まれ、 表面欠 陥となるばかり 力、 耐食性を損なう こ とになる。 雰囲気制御を可能 とするこ とによ り、 このよ うな表面材質の低下を回避できるばかり でなく 、 雰囲気を、 例えば窒素雰囲気という特定の雰囲気とするこ とによって表層に窒素を浸透させて特性の改善を図るこ と もできる  (C) At least a structure capable of controlling the atmosphere of the treated surface, suppressing the formation of an oxide layer, achieving a good metal surface state, and further enabling the formation of an alloy layer. If the surface atmosphere is an oxidizing atmosphere, oxides generated on the material surface will be caught in the surface layer, causing surface defects and impairing the strength and corrosion resistance. By controlling the atmosphere, not only such a decrease in the surface material can be avoided, but also, by setting the atmosphere to a specific atmosphere, for example, a nitrogen atmosphere, it is possible to infiltrate the surface layer with nitrogen to improve the characteristics. Can also improve

( d ) 処理対象となる金属材料に対して合金成分を供給可能な構造 と し、 表層に合金層を形成可能とするこ と、 即ち、 超音波衝撃処理 と同時に処理すべき箇所に金属成分の粉末を供給する、 即ち、 ピン 自体を特定の金属材料とするこ とによって衝撃を与える と同時に金 属粉末或いはピンの小片を処理対象材料表面に供給し、 表層を所望 の合金層とするこ とができる。 これによ り、 金属材料表面に新しい 機能を付与するこ と もできる。 (d) A structure capable of supplying an alloy component to the metal material to be treated, so that an alloy layer can be formed on the surface layer, that is, the metal component is applied to the place to be treated simultaneously with the ultrasonic impact treatment. Supplying powder, that is, providing an impact by using the pin itself as a specific metal material, and simultaneously supplying metal powder or small pieces of the pin to the surface of the material to be treated, and making the surface layer a desired alloy layer Can be. As a result, a new function can be added to the metal material surface.

また、 上記超音波衝撃処理は、 一般的に微細化現象と しては、 金 属材料表層部では処理厚みと して 1 0〜 2 0 0 m , 塑性変形/成 形深さ方向範囲が 1 〜 5 m m、 圧縮残留応力を 1 〜 3 m m程度まで 導入する とする と云われている。 本発明者らは、 これらの現象が何 れも処理温度と密接に関係しているこ とを研究の結果知見した。 す なわち、 処理温度域で得られる現象および効果がそれぞれ異なるこ とから 目標とする金属材料の改質のレベルに合わせて処理条件を設 定するこ とが上記超音波衝撃処理で直接的に得られる効果を十分に 発揮するこ とができるのである。 その処理温度域と得られる現象お よび効果を、 特に最も一般的に使われている金属材料の一つである 鋼材について以下に述べる。 In general, the above-mentioned ultrasonic impact treatment is generally performed as a micronization phenomenon in the surface layer of a metal material as a treatment thickness of 10 to 200 m, and a plastic deformation / molding depth direction range of 1 to 1 m. It is said to introduce up to 5 mm and compressive residual stress of about 1 to 3 mm. The present inventors have found through research that all of these phenomena are closely related to the processing temperature. In other words, since the phenomena and effects obtained in the processing temperature range are different from each other, setting the processing conditions in accordance with the target level of metal material reforming is directly possible with the above-mentioned ultrasonic impact processing. Get the full effect It can be demonstrated. The processing temperature range and the phenomena and effects obtained are described below, especially for steel, which is one of the most commonly used metal materials.

① V再結晶領域 (約 8 5 0 °C以上)  ① V recrystallization region (about 850 ° C or more)

金属材料表層部の微細化効果は少ないが、 コア部では再結晶微 細化による微細フェライ ト粒生成し高靱化し、 また、 塑性変形 Z成形面では凝固過程での流動化による残留引張応力が低減し 疲労強度が向上する。  Although the effect of miniaturization on the surface of the metal material is small, fine ferrite grains are generated by recrystallization miniaturization in the core and the toughness is increased, and the residual tensile stress due to fluidization during the solidification process is reduced on the plastic deformation Z-formed surface. Reduced and improved fatigue strength.

© 1 未再結晶領域 (約 7 8 0 °じ〜 8 5 0 °0 © 1 unrecrystallized area (approximately 780 ° J ~ 850 ° 0

金属材料コア部では再結晶微細化による微細フ ライ ト粒生成 し高靱化し、 また、 塑性変形ノ成形面では、 特に溶接金属凝固 割れ、 降温割れを防止できる。  In the core of the metal material, fine frit grains are formed by recrystallization refinement to increase toughness, and on the plastic deformation surface, particularly solidification cracks of the weld metal and cooling cracks can be prevented.

③ α · γ 2相域 (約 6 5 0 ¾〜 7 8 0 °0  ③ α · γ 2 phase region (approx.

金属材料表層部の多軸処理によ り結晶粒を微細化 (ナノ化) し 、 同時にコア部では再結晶微細化による微細フェライ ト粒生成 し高靱化することができる。 また、 塑性変形 成形面では、 溶 接止端部の効率的な成形が行えるこ とで疲労強度を向上するこ とができる。 更に、 高強度鋼を加工した場合には低温時の軟鋼 並の塑性変形 成形を付与するこ とができる。  The crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer of the metal material, and at the same time, fine ferrite grains can be formed by recrystallization and refinement in the core, thereby increasing the toughness. In addition, on the plastic deformation molding surface, the fatigue strength can be improved because the welding toe can be efficiently molded. Furthermore, when high-strength steel is machined, it can be subjected to plastic deformation forming similar to mild steel at low temperatures.

④ A i 点以下の温度域 (約 4 0 0 °C〜 6 5 0 °C )  温度 Temperature range below A i point (approximately 400 ° C to 65 ° C)

金属材料表層部の多軸処理によ り結晶粒を微細化 (ナノ化) し 、 同時に変態温度低下に伴う逆変態挙動を利用した組織の微細 化を行う こ とができる。 また、 塑性変形 Z成形面では、 溶接止 端部の効率的な成形が行えるこ とで疲労強度を向上するこ とが できる。 更に、 溶接面においては、 溶接多パス時の残留応力、 冷却割れに伴う圧縮残留応力を低減するこ とができる。  The crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer of the metal material, and at the same time, the structure can be refined by utilizing the reverse transformation behavior accompanying the decrease in the transformation temperature. In addition, on the plastically deformed Z-formed surface, the fatigue strength can be improved by efficiently forming the weld toe. Furthermore, on the weld surface, residual stress during multiple passes of welding and compressive residual stress due to cooling cracks can be reduced.

⑤強度発現域 ( 4 0 0 °C以下) 金属材料表層部の多軸処理によ り結晶粒を微細化 (ナノ化) し 、 同時に変態温度低下に伴う逆変態挙動を利用した組織の微細 化を行う ことができる。 また、 塑性変形することで疲労強度向 上、 圧縮残留応力低減を期待できる。 ⑤Intensity expression area (below 400 ° C) The crystal grains can be refined (nanosized) by the multiaxial treatment of the surface layer portion of the metal material, and at the same time, the structure can be refined by utilizing the reverse transformation behavior accompanying the decrease in the transformation temperature. Also, plastic deformation can be expected to improve fatigue strength and reduce compressive residual stress.

このよ う に、 本発明においては、 対象とする金属材料において、 必要とする超音波衝撃処理による効果、 例えば、 疲労強度改善、 表 面改質、 溶接割れ改善の各効果で処理温度を決定し、 超音波衝撃処 理の条件設定を行う ことを特徴とするものである。 もちろん、 銅材 以外の金属材料でも同様に、 成分組成から得られる状態図、 温度一 強度関係などを活用して、 合理的に上記のよ うな整理が容易に出来 る。 これらの基礎データは教科書レベルのものを含む文献で容易に 収集可能なものであり、 それを本発明の方法で活用し、 様々な金属 材料への展開が可能である。 この具体的な条件設定の手順を図 1 を 用いて説明する。  As described above, in the present invention, the treatment temperature is determined based on the required effects of the ultrasonic impact treatment, for example, the effects of improving the fatigue strength, modifying the surface, and improving the weld cracking in the target metal material. It is characterized in that conditions for ultrasonic shock processing are set. Of course, in the case of metal materials other than copper material as well, the above-described arrangement can be reasonably facilitated by utilizing the phase diagram obtained from the component composition, the temperature-strength relationship, and the like. These basic data can be easily collected in the literature including those at the textbook level, and can be applied to various metallic materials by utilizing the data in the method of the present invention. The procedure for setting the specific conditions will be described with reference to FIG.

図 1 において、 超音波衝擊処理 (加工) を行う金属材料対象物を 決定した後、 その対象物についてどのよ うな改善効果を付与すべき であるかを、 疲労強度改善、 表面改質および溶接割れ改善の中から 選択する。 そして、 例えば、 疲労強度改善が主目的であれば、 バー ジン材の疲労強度付与か、 既設材の疲労強度回復の何れかをによ り 、 バージン材の場合には高強度材で溶接止端処理が非効率であるか を判断し、 金属強度の温度依存性から処理温度を決定する。 一方、 既設材の場合には金属材料の状態図から回復に適切な処理温度を決 定る。 次いで、 両者のケースについて処理温度—処理パターン関係 から超音波衝撃処理条件を決定し、 加熱下または常温下での処理を 判断して超音波衝撃処理を行う という作業フローが設計できる。  In Fig. 1, after determining the target of the metal material to be subjected to the ultrasonic impact treatment (working), it is necessary to determine what improvement effect should be given to the target by improving the fatigue strength, surface modification and welding cracking. Choose from improvements. For example, if the main purpose is to improve the fatigue strength, either the provision of the fatigue strength of the virgin material or the recovery of the fatigue strength of the existing material is used. Determine whether the treatment is inefficient and determine the treatment temperature from the temperature dependence of metal strength. On the other hand, in the case of existing materials, the appropriate processing temperature for recovery is determined from the phase diagram of the metal material. Next, for both cases, a work flow can be designed in which the ultrasonic impact processing conditions are determined from the relationship between the processing temperature and the processing pattern, and the processing under heating or normal temperature is determined and the ultrasonic impact processing is performed.

また、 例えば、 表面改質が主目的である場合には、 目標とする金 属材料の表面状態から合金化が必要か、 必要であれば供給すべき合 金成分を決定し、 次いで、 目標とする合金の状態図から処理温度を 決定後、 処理温度一処理パターン関係から超音波衝撃処理条件を決 定し、 加熱下または常温下での加工を判断して超音波衝撃処理を行 う という作業フローが設計できる。 For example, when surface modification is the main purpose, alloying is necessary based on the surface condition of the target metal material, and if necessary, it should be supplied. After determining the gold component, and then determining the processing temperature from the target alloy phase diagram, the ultrasonic impact processing conditions are determined from the processing temperature-processing pattern relationship, and processing under heating or normal temperature is determined. A work flow for performing ultrasonic impact treatment can be designed.

更に、 例えば、 溶接割れ改善が主目的である場合には、 対象金属 材料に対する溶接条件および金属の状態図から処理温度を選定後、 処理温度一処理パターン関係から超音波衝撃処理条件を決定し、 加 熱下または常温下での加工を判断して超音波衝撃処理を行う という 作業フローが設計できる。  Furthermore, for example, if the main purpose is to improve weld cracking, after selecting the processing temperature from the welding conditions for the target metal material and the state diagram of the metal, determine the ultrasonic impact processing conditions from the processing temperature-processing pattern relationship, It is possible to design a work flow in which ultrasonic impact processing is performed by judging processing under heating or normal temperature.

なお、 加熱下における超音波衝撃処理において、 それが溶接、 熱 源、 温度センサー、 金属成分の供給、. シール ドガス等の課題を当然 考慮する問題であるこ とは勿論である。 また、 上記超音波衝撃処理 は温度域毎に複数回処理するこ とで累加した効果が得られるこ とは 勿論であるので、 上記作業フローに従って複数回同一加工或いは異 なる加工を適宜組み合わせて超音波衝撃処理しう るこ とは当然であ る。 この超音波衝撃処理の一例と して、 例えば、 多パス溶接部の処 理で 6 7 0 °C〜 7 5 0 °Cの温度域で超音波衝撃処理後、 常温で再度 超音波衝撃処理するこ とで高靱性と高疲労強度の両特性を兼備した 金属材料を得るこ とができる。 また、 既設の使用中の橋脚の補修溶 接で、 1 パス 目のビー ドに対しては 8 5 0 °C以上の温度域で超音波 衝撃処理するこ とで応力変動による高温割れを防止し、 その後の積 層溶接では 4 0 0 °C〜 6 5 0 °Cの温度域で超音波衝撃処理するこ と によ り ラメ ラーティアを防止し、 最後に溶接完了後の止端部を常温 で超音波衝撃処理するこ とで高疲労強度を付与するこ とができる。 更に、 使用中、 または使用後の鋼材の表面を上述した任意の温度域 で超音波衝撃処理して表層部組織をナノ組織化すると共に、 合金の 補完が必要な場合には超音波衝撃処理で外部から合金を供給して必 要な特性を付与して再生化を図るこ とができる。 Of course, in the ultrasonic shock treatment under heating, it is a matter of course that issues such as welding, heat source, temperature sensor, supply of metal components, and shield gas are taken into account. In addition, since the above-described ultrasonic impact treatment can provide an added effect by performing the treatment multiple times for each temperature range, the same processing or different processing may be appropriately performed multiple times in accordance with the above work flow. It is natural that the sonic impact treatment is performed. As an example of this ultrasonic impact treatment, for example, in a multi-pass welding process, the ultrasonic impact treatment is performed in a temperature range of 670 ° C to 750 ° C, and then the ultrasonic impact treatment is performed again at room temperature. As a result, a metal material having both high toughness and high fatigue strength can be obtained. In addition, in the repair welding of existing piers in use, the first pass bead is subjected to ultrasonic impact treatment at a temperature range of 850 ° C or higher to prevent hot cracking due to stress fluctuation. In subsequent lamination welding, ultrasonic impact treatment was performed in the temperature range of 400 ° C to 65 ° C to prevent lamellar tearing, and finally the toe after welding was completed was kept at room temperature. High fatigue strength can be imparted by ultrasonic impact treatment. Further, the surface of the steel material during or after use is subjected to ultrasonic impact treatment at the above-mentioned arbitrary temperature range to nanostructure the surface layer structure, and when the complementation of the alloy is required, the ultrasonic impact treatment is applied. It is necessary to supply alloy from outside. Regeneration can be achieved by adding necessary characteristics.

次に、 本発明で使用する超音波衝撃加工機を図面を参照しながら 説明する。  Next, an ultrasonic impact machine used in the present invention will be described with reference to the drawings.

図 2 ( a ) は、 超音波ハンマリ ング衝撃加工に用いる機器の概要 を示し、 ( b ) は、 ( a ) の先端部のみを超音波ショ ッ ト ピーニン グ衝撃加工用に変えた機器の概要を示す部分拡大図である。 図 2 ( a ) において、 超音波ハンマリ ング衝撃加工機 1 は、 超音波を発信 する ト ランスデューサー 2 と、 その前方に取り付けられ、 トランス デューサー 2で発生した超音波を先端部に導く筒状のウェーブガイ ド 3 と、 このウェーブガイ ド 3の先端、 即ち、 処理対象物と対向す る側、 に取り付けられたヘッ ド 4 とから構成される。 ヘッ ド 4は、 その先端に 1つまたは複数の孔 5が設けられ、 この孔 5の上下方向 に挿入された棒状のピン 6 と、 ピン 6の上端と ウェーブガイ ド 3の 先端との間に設けられた空間 8 とを含んで収納するホルダー 9 とか らなり 、 ホルダー 9 は環状の金具 1 0によ り、 ウェーブガイ ド 3の 外周に着脱可能に接続されており、 ピン 6 を含めて交換可能なよ う に構成されている。 必要に応じて、 ピンの径、 本数、 配列、 材質、 形状などを、 交換するこ とができる。  Figure 2 (a) shows the outline of the equipment used for ultrasonic hammering impact processing, and (b) shows the outline of the equipment in which only the tip of (a) is changed to ultrasonic shot peening impact processing. FIG. In FIG. 2 (a), an ultrasonic hammering impact machine 1 has a transducer 2 that emits ultrasonic waves, and a cylindrical shape attached to the front of the transducer 2 and guides the ultrasonic waves generated by the transducer 2 to the tip. It comprises a wave guide 3 and a head 4 attached to the end of the wave guide 3, that is, the side facing the object to be processed. The head 4 has one or more holes 5 at its end, and a rod-shaped pin 6 inserted in the up and down direction of the hole 5, and between the upper end of the pin 6 and the end of the wave guide 3. It consists of a holder 9 that contains the provided space 8 and is housed.The holder 9 is detachably connected to the outer periphery of the wave guide 3 by an annular metal fitting 10, and can be replaced including the pin 6. It is configured as possible. The diameter, number, arrangement, material, shape, etc. of the pins can be changed as necessary.

なお、 上記ウエーブガイ ド 3の中間部には、 その外周を間隙を設 けて囲む樹脂製のカバー 1 1 を設け、 この間隙にはウェーブガイ ド および振動部を有するへッ ドを冷却、 潤滑する潤滑剤を保持するた めの多孔体 1 2 を充填するこ とができる。 その場合、 カバー 1 1 の 下端部と ウエーブガイ ド 3 との間には、 開口部 1 3が設けられてお り、 潤滑冷却剤はこの開口部 1 3を経てヘッ ド 4に供給される。 し かし、 これは必須ではない。 また、 トランスデューサー 2 を冷却す るために、 水冷や空冷の装置を設ける場合もある。  In addition, a resin cover 11 surrounding the outer periphery of the wave guide 3 with a gap provided therebetween is provided in the middle of the wave guide 3 to cool and lubricate the wave guide and the head having the vibrating section. The porous body 12 for holding the lubricant to be filled can be filled. In this case, an opening 13 is provided between the lower end of the cover 11 and the wave guide 3, and the lubricant coolant is supplied to the head 4 via the opening 13. However, this is not required. In addition, a water-cooled or air-cooled device may be provided to cool the transducer 2.

トランスデューサー 2は、 電気エネルギーを超音波エネルギーに 変換するもので、 磁気式或いは電気式 トランスデューサ一等が利用 できる。 前者は大容量化が可能で広範囲の音響負荷に対して高い安 定度で作動するが、 反面、 重く、 冷却が必要である。 後者は容量は 小さいが高効率で発熱も少なく冷却を軽減でき、 また可搬性に優れ る。 しかし、 逆に音響付加に対しての安定度は低い。 従って、 処理 条件や目的によ り磁気式或いは電気式 トランスデューサーを任意に 選択すればよい。 Transducer 2 converts electrical energy to ultrasonic energy For conversion, a magnetic or electric transducer can be used. The former can be increased in capacity and operate with high stability over a wide range of acoustic loads, but on the other hand are heavy and require cooling. The latter has a small capacity but is highly efficient, generates less heat, can reduce cooling, and is excellent in portability. However, on the contrary, the stability to the addition of sound is low. Therefore, a magnetic or electric transducer may be arbitrarily selected depending on processing conditions and purposes.

ヘッ ド 4に収納されたピン 6の数は、 1本でも良いが、 複数本を 一列或いは複数列に配列するこ とによ り処理効率、 処理面積を倍加 するこ とができる。 また、 このピン 6は軸方向の 1方向に振動させ るのが一般的であるが、 ピン 6 自体が処理領域内で回転或いは任意 の方向に移動してもよい。 例えば、 ピン 6 自体を回転させよ う とす る場合には、 各ピンの根元にギアを取り付け、 外部に設けたモータ 一の回転駆動力でギアを介して、 1 0 0回転 Z秒回転させるこ と、 また、 ホルダー 9 内の各ピンに電磁コイルを捲回し電磁力で回転さ せるこ と も可能である。  The number of pins 6 stored in the head 4 may be one, but by arranging a plurality of pins in one or more rows, processing efficiency and processing area can be doubled. The pin 6 is generally vibrated in one axial direction, but the pin 6 itself may rotate or move in an arbitrary direction within the processing area. For example, when the pin 6 itself is to be rotated, a gear is attached to the root of each pin, and the motor is rotated 100 times Z seconds by the rotation driving force of an externally provided motor through the gear. In addition, it is also possible to wind an electromagnetic coil around each pin in the holder 9 and rotate it by electromagnetic force.

トランスデューサー 2が超音波を発信する と、 生じた超音波はこ れに接続されたウエーブガイ ド 3に伝達され、 ウェーブガイ ド 3の 径が絞られているこ とによって速度が変性される。 超音波はゥエー ブガイ ド 3の先端からへッ ド 4に至り、 これと接している ピン 6 を 振動させる。 この振動によ り ピン 6の先端が処理対象物 1 4の表面 を打撃するこ とによって衝撃加工される。 処理条件と しては、 振幅 2 0 〜 6 0 μ πι、 周波数 1 5 k H z 〜 6 0 k H z 、 出力 0 . 2 〜 1 k Wが好ましい。  When the transducer 2 emits ultrasonic waves, the generated ultrasonic waves are transmitted to the wave guide 3 connected thereto, and the velocity is denatured by the reduced diameter of the wave guide 3. The ultrasonic wave reaches the head 4 from the tip of the waveguide 3 and vibrates the pin 6 in contact therewith. Due to this vibration, the tip of the pin 6 strikes the surface of the object 14 to be subjected to impact processing. The processing conditions are preferably an amplitude of 20 to 60 μπι, a frequency of 15 kHz to 60 kHz, and an output of 0.2 to 1 kW.

一方、 超音波ショ ッ ト ピーニング衝撃加工に用いる機器の概要で あるが、 その構成は図 2 ( b ) の部分拡大図に示すよ うに、 図 2 ( a ) に示した超音波ハンマ リ ング衝撃加工機における ピン 6の代わ りに、 鋼製のボール、 カ ッ トワイヤ等の硬質小径鋼材、 或いはサフ アイャ等の小粒子 1 5 をウエーブガイ ド 3の先端から発せられた超 音波はによ りへッ ド 4内に収納された板 8 を振動させ、 これと接し ている硬質小径鋼材 1 5 を振動させ、 処理対象物 1 4の表面を打撃 するこ とによって衝撃加工される。 また、 処理条件は上述した超音 波ハンマリ ング衝撃加工機を使用する場合と同条件でよい。 なお、 ショ ッ ト ビーニングの小粒子の材質は、 本発明では重量約 7 m gの サフアイャ球を用いたが、 その他に上述した銅球、 超銅球、 セラ ミ ク ッス、 アルミナ(A12 03 ) 、 ジルコニァ(Zr02 )、 窒化珪素(S i3 N4 ) 、 S i C、 S i O 2 、 サイァロ ン等も使用できる。 使用するショ ッ ト ビ一ニングの種類は処理対象材料の種類、 硬度、 超音波発振パヮ 一を適宜選択して使用することが好ましい。 また、 超音波振動板の 径、 面積も小粒子と処理対象材料との関係で変化させるこ ともよ り 好ま しい。 産業上の利用可能性 On the other hand, the outline of the equipment used for ultrasonic shot peening impact processing is shown in Fig. 2 (b), which is partially enlarged, as shown in the ultrasonic hammering impact processing shown in Fig. 2 (a). Substitute for pin 6 in processing machines In addition, small particles 15 such as steel balls and cut wires or small particles 15 such as sapphires are stored in the head 4 by the ultrasonic waves emitted from the tip of the wave guide 3. The processed plate 8 is vibrated, the hard small-diameter steel material 15 in contact with the plate 8 is vibrated, and the surface of the object 14 to be processed is hit, thereby performing impact processing. The processing conditions may be the same as those when using the ultrasonic hammering impact machine described above. The material of the small particles of shots Biningu is, in the present invention using Safuaiya ball weighing approximately 7 mg, copper spheres mentioned above other, ultra copper balls, Serra Mi click Ssu, alumina (A1 2 0 3), Jirukonia (Zr0 2), silicon nitride (S i 3 N 4), S i C, S i O 2, Saiaro down like can be used. As the type of shot binning to be used, it is preferable to appropriately select and use the type, hardness, and ultrasonic oscillation power of the material to be treated. Further, it is more preferable that the diameter and area of the ultrasonic vibration plate are changed depending on the relationship between the small particles and the material to be treated. Industrial applicability

本発明は、 対象金属材料に付与したい改善効果 (疲労強度改善、 表面改質、 溶接割れ改善) の中から要求する効果に応じて超音波衝 撃処理の温度域を選択し、 超音波衝撃処理を行い目的とする効果を 得るこ とができ、 また、 この処理を複数回任意に組み合わせて複合 した効果を得るこ とができ、 更に、 使用中、 または使用後の鋼材の 表面状態をナノ組織と して新たな特性を付与できる という効果があ る。  According to the present invention, the temperature range of the ultrasonic impact treatment is selected according to the desired effect (improvement of fatigue strength, surface modification, and improvement of weld cracking) to be imparted to the target metal material. The desired effect can be obtained by performing this process, and a combined effect can be obtained by arbitrarily combining this treatment multiple times.Furthermore, the surface state of the steel material during or after use can be changed to a nanostructure. This has the effect that new characteristics can be added.

また、 処理対象となる金属材料のサイズが大き く通常の処理炉で 処理できないよ うな大型サイズの構造物で疲労強度が懸念される応 力集中部の表面を定期的に繰り返し補修 · 処理するこ とで鋼材の表 面状態をナノ組織と して特性回復効果を付与するこ と もできる。 更 に、 この疲労特性回復効果は、 溶接止端部の変形を最小に抑え、 主 に材料表層部組織をナノ化することで表層部での転移を解消して得 るこ とができる。 In addition, the surface of the stress-concentrated part where the fatigue strength is a concern in large-sized structures where the metal material to be treated is large and cannot be treated in a normal treatment furnace, should be repaired and treated periodically and repeatedly. In this way, the surface state of the steel material can be converted into a nanostructure to provide a property recovery effect. Change In addition, the effect of recovering the fatigue characteristics can be obtained by minimizing the deformation of the weld toe and by mainly converting the surface structure of the material to nano to eliminate the transition in the surface layer.

Claims

1 . 処理対象とする金属材料において、 必要とする超音波衝撃処 理による効果と して、 疲労強度改善、 表面改質、 溶接割れ改善の何 れか、 または複数の効果を選択し、 次いで、 前記それぞれの効果ご とに応じて超音波衝撃処理温度を決定後、 超音波衝撃処理の条件設 定を行い、 最終的にそれらの処理の効率的な組み合わせを決定する こ とを特徴とする金属材料の超音波衝撃処理条件の設定方法。 1. For the metal material to be treated, select one or more of the effects of fatigue strength improvement, surface modification, and weld crack improvement as the effects of the required ultrasonic impact treatment, and then After determining the ultrasonic impact treatment temperature in accordance with each of the above effects, setting conditions for the ultrasonic impact treatment, and finally determining an efficient combination of those treatments, How to set ultrasonic shock treatment conditions for materials. 2 . 前記超音波衝撃処理が新設加工物の疲労強度改善を目的とす る場合には、 該新設加工物の金属強度から溶接止端処理が非効率で あるかを判断し、 非効率な場合は金属強度囲の温度依存性から処理温 度を決定し、 溶接終了後の温度低下過程で決定された温度時点で超 音波衝撃処理を行って止端形状を改善し、 さ らに圧縮残留応力を付 与したい場合は常温で再度、 圧縮残留応力を導入するのに効率的な 条件で超音波衝撃処理を行う ことを特徴とする請求項 記載の金属 材料の超音波衝撃処理条件の設定方法。  2. If the ultrasonic impact treatment is intended to improve the fatigue strength of the newly-formed workpiece, determine whether the weld toe treatment is inefficient based on the metal strength of the newly-formed workpiece. Determines the processing temperature from the temperature dependence of the metal strength range, improves the toe shape by performing ultrasonic impact treatment at the temperature determined during the temperature drop process after welding, and further compressive residual stress The method for setting the ultrasonic impact treatment conditions for a metal material according to claim 6, wherein the ultrasonic impact treatment is performed again at room temperature under conditions effective to introduce the compressive residual stress, if it is desired to apply the ultrasonic impact treatment. 3 . 前記超音波衝撃処理が既設加工物の疲労強度改善を目的とす る場合には、 該既設加工物の金属強度から溶接止端処理が非効率で あるかを判断し、 非効率な場合は前記金属強度の温度依存性から超 音波衝撃処理温度を決定後、 決定された温度まで加熱した上で超音 波衝撃処理を行って止端形状を改善し、 さ らに圧縮残留応力を付与 したい場合は常温で再度、 圧縮残留応力を導入するのに必要な条件 で超音波衝撃処理を行う こ とを特徴とする請求項 1 記載の金属材料 の超音波衝撃処理条件の設定方法。  3. If the ultrasonic impact treatment is intended to improve the fatigue strength of the existing work, determine whether the weld toe treatment is inefficient based on the metal strength of the existing work. Determines the ultrasonic shock treatment temperature from the temperature dependence of the metal strength, heats it to the determined temperature, performs ultrasonic shock treatment to improve the toe shape, and applies compressive residual stress 2. The method according to claim 1, wherein the ultrasonic impact treatment is performed again at room temperature under conditions necessary for introducing the compressive residual stress. 4 . 前記超音波衝撃処理が既設加工物の疲労蓄積回復を目的とす る場合には、 該既設加工物の金属材料の状態図から繰り返し応力に よ り蓄積された転移の回復に適切な処理温度を決定後、 処理温度一 処理パターン関係から超音波衝撃処理条件を決定し、 加熱下または 常温下での処理を判断して超音波衝撃処理を行う こ とを特徴とする 請求項 1記載の金属材料の超音波衝撃加工条件の設定方法。 4. If the ultrasonic impact treatment aims at recovering the accumulated fatigue of the existing workpiece, a process appropriate for the recovery of the transition accumulated due to the repeated stress from the state diagram of the metal material of the existing workpiece. After determining the temperature, The ultrasonic impact processing condition of a metal material according to claim 1, wherein ultrasonic impact processing conditions are determined based on a processing pattern relationship, and the ultrasonic impact processing is performed by judging a process under heating or normal temperature. How to set. 5 . 前記超音波衝撃処理が表面改質を目的とする場合には、 処理 対象とする金属材料の表面状態から合金化が必要か、 必要であれば 供給すべき合金成分を決定し、 次いで、 当該合金の状態図から処理 温度を決定後、 処理温度一処理パターン関係から超音波衝撃加工条 件を決定し、 加熱下または常温下での加工の組み合わせを決定して 超音波衝撃処理を行う こ と を特徴とする請求項 1記載の金属材料の 超音波衝撃処理条件の設定方法。  5. If the ultrasonic impact treatment is intended for surface modification, alloying is necessary based on the surface condition of the metal material to be treated, or if necessary, alloy components to be supplied are determined. After determining the processing temperature from the phase diagram of the alloy, determine the ultrasonic impact processing conditions from the relationship between the processing temperature and the processing pattern, determine the combination of processing under heating or normal temperature, and perform the ultrasonic impact processing. 2. The method for setting ultrasonic shock treatment conditions for a metal material according to claim 1, wherein: 6 . 前記超音波衝撃処理が溶接割れ改善を目的とする場合には、 対象金属材料に対する溶接条件および対象金属材料の状態図から処 理温度を選定後、 処理温度一処理パターン関係から超音波衝撃処理 条件を決定し、 溶接後の温度低下状況と常温下での超音波衝撃処理 の組み合わせを判断して超音波衝撃処理を行う ことを特徴とする請 求項 1記載の金属材料の超音波衝撃加工条件の設定方法。  6. If the ultrasonic impact treatment is intended to improve weld cracking, select the processing temperature from the welding conditions for the target metal material and the state diagram of the target metal material, and then use the ultrasonic impact The ultrasonic impact of the metallic material according to claim 1, wherein the treatment conditions are determined, and the ultrasonic impact treatment is performed by judging a combination of the temperature drop after welding and the ultrasonic impact treatment at room temperature. How to set processing conditions.
PCT/JP2003/014596 2002-11-19 2003-11-17 Method of setting ultrasonic shock treatment conditions for metal material Ceased WO2004046395A1 (en)

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