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WO2004045568A1 - Composition de shampooing - Google Patents

Composition de shampooing Download PDF

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Publication number
WO2004045568A1
WO2004045568A1 PCT/JP2003/014502 JP0314502W WO2004045568A1 WO 2004045568 A1 WO2004045568 A1 WO 2004045568A1 JP 0314502 W JP0314502 W JP 0314502W WO 2004045568 A1 WO2004045568 A1 WO 2004045568A1
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WO
WIPO (PCT)
Prior art keywords
mass
acid
shampoo composition
oil
liquid crystal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2003/014502
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English (en)
Japanese (ja)
Inventor
Masatsugu Ono
Eiji Nishimura
Katsunori Ohnuma
Narumi Tagaki
Yuki Shimoya
Yasuo Nagahara
Yumi Isoda
Masahiro Kusunose
Yuichi Nishida
Koichi Uchikoshi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
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Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to AU2003280797A priority Critical patent/AU2003280797A1/en
Priority to JP2004553167A priority patent/JP4446176B2/ja
Publication of WO2004045568A1 publication Critical patent/WO2004045568A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0295—Liquid crystals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a shampoo composition for improving the squeaky feeling of hair generated when shampoo is rinsed, and more particularly to a shampoo composition for improving squeaky feeling in hair dyed with a squeaky feeling, and a method for producing the same.
  • a shampoo composition for improving the squeaky feeling of hair generated when shampoo is rinsed and more particularly to a shampoo composition for improving squeaky feeling in hair dyed with a squeaky feeling, and a method for producing the same.
  • Coloring usually involves chemical treatment with alkali, hydrogen peroxide, etc., causing hair damage.
  • the damage exposes the hydrophilic portion to the surface of the hair, which increases the squeaky feeling when the shampoo is rinsed, which is undesirable for the user.
  • Japanese Patent Application Laid-Open No. H10-112109 a method of combining an amide carboxylic acid type surfactant and a Z or dicarboxylic acid imide type surfactant with another surfactant has conventionally been used (Japanese Patent Application Laid-Open No. H10-112109). No. 0), a method of blending a cationic polymer compound into a shampoo (Japanese Patent Application Laid-Open No. 11-236320), a method of using an amino acid compound (Japanese Patent Application Laid-Open No. 7-310100) Publication), a method using a plant extract (Japanese Patent Laid-Open Publication No. 2001-21071), and the like, but the effect is not sufficient particularly for colored hair.
  • a liquid crystal-forming detergent composition comprising a cationic surfactant, a higher alcohol and a polyglycerol fatty acid ester is disclosed in Japanese Patent Application Laid-Open No. 2001-311991.
  • a vesicle made of a cationic surfactant contains an ultraviolet absorber and a water-soluble substance (Japanese Patent Application Laid-Open No. Hei 9-187147). It was not enough. Disclosure of the invention
  • the present invention improves the squeaky feeling of hair that occurs when shampoo is rinsed.
  • An object of the present invention is to provide a shampoo composition that improves the feeling of squeaking, gives excellent foaming, and has excellent dispersion stability over time in colored hair in which the feeling of bleeding is likely to occur.
  • the inventor has (A) a cationic surfactant, (B) an oil containing no silicon atom, (C) an oil containing no silicon atom,
  • (C) In a composition containing one or more detersive surfactants selected from the group consisting of amphoteric surfactants, anionic surfactants, and nonionic surfactants, (A) The component and the oil component that can form a liquid crystal structure alone with the component ( ⁇ ) as the component (B ′) of the component (B) have a specific mass ratio, and the component (C) in the composition is further specified.
  • the shampoo composition in which the liquid crystal structure is dispersed the squeak at the time of shampoo rinsing, especially the intense and fresh feeling of the colored hair is improved, and the foaming is excellent, and over time. It has been found that a shampoo composition having excellent dispersion stability can be obtained.
  • a shampoo composition characterized in that a liquid crystal structure formed from the component (i) and the component (ii) is dispersed in the composition.
  • the molecular terminal and R have a structural unit represented by a hydrogen atom, a methyl group or a hydroxypropoxy group, a methoxy group of 25 to 35% by mass, a hydroxypropoxy group of 5 to 15% by mass (provided that The total of the hydroxyl group, the methoxy group and the hydroxypropoxy group is 100% by mass.
  • the composition contains a 2% by mass aqueous solution of hydroxypropylmethylcellulose having a viscosity at 20 ° C. of 2100 to 3500 OmPa ⁇ s.
  • aqueous phase containing (C) the detersive surfactant a liquid crystal structure formed by using (A) a cationic surfactant and (B) an oil component containing no silicon atom as components is separated.
  • a method for producing a shampoo composition comprising: (C) mixing an aqueous phase containing a detersive surfactant with a component of a liquid crystal structure at a temperature equal to or higher than the crystallization temperature of the component of the liquid crystal structure; The method for producing a shampoo composition according to [1], wherein the obtained mixture is cooled from a temperature higher than a crystallization temperature.
  • FIG. 1 is a block diagram showing a preferred embodiment of an apparatus used for the continuous partial quenching method according to the present invention.
  • FIG. 2 is a chart when a shampoo composition having a typical composition was subjected to DSC measurement.
  • the component (A) is a cationic surfactant, and its type is not particularly limited as long as it can be blended into the shampoo composition.
  • an alkyl quaternary ammonium represented by the following general formula (1) Salts and the like are preferably used.
  • R 1 R 2 , R 3 , and R 4 represent an alkyl group, a hydroxyalkyl group, an alkenyl group, a polyalkylene oxide group or a benzyl group, respectively, and R 1 , R 2 , R 3 , and R one or two of the four number 1 0-2 4 carbon atoms, preferably 1 6-2 2 linear alkyl group, a hydroxyalkyl group or an alkenyl group, the remainder methylation group, Echiru group, a benzyl group Or a (C 2 H 4 ⁇ ) q _H,-(C 3 H 60 ) r -H (where q and r are each an integer of 1 to 5) a polyalkylene oxide group represented by And these may be the same or different from each other.
  • Z represents an anion.
  • Cationic surfactants are usually formulated in the form of a salt, specifically, inorganic salts such as hydrochloride, bromate, sulfate, and phosphate, glycolate, acetate, lactate, and succinate. It can be used as an organic acid salt such as an acid salt, a tartrate salt, a citrate salt, an acidic amino acid salt, a higher fatty acid salt, a pyrodaltamate salt and a p-toluenesulfonate salt.
  • inorganic salts such as hydrochloride, bromate, sulfate, and phosphate, glycolate, acetate, lactate, and succinate.
  • organic acid salt such as an acid salt, a tartrate salt, a citrate salt, an acidic amino acid salt, a higher fatty acid salt, a pyrodaltamate salt and a p-toluenesulfonate salt.
  • component (A) represented by the above general formula (1) examples include, for example, stearyltrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, cetostearyltrimethyl.
  • stearyltrimethylammonium chloride cetyltrimethylammonium chloride
  • cetyltrimethylammonium chloride behenyltrimethylammonium chloride
  • cetostearyltrimethyl cetostearyltrimethyl.
  • distearyl dimethyl ammonium chloride gibe Dimethyl dimethyl ammonium chloride and the like.
  • those having 16 to 22 linear alkyl groups are preferred.
  • Specific examples include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, and distearyldimethylammonium chloride.
  • Chloride Of these, the hydrochloride and bromate forms are preferred.
  • guanidine derivative represented by the following general formula (2) or a salt thereof can also be suitably used as the cationic surfactant.
  • R 5 is a linear or branched alkyl group or alkenyl group having 1 to 21 carbon atoms
  • A is a linear or branched alkylene group or alkenyl group having 1 to 10 carbon atoms.
  • R 5 in the general formula (2) is 1 to 21 carbon atoms, preferably a linear or branched alkyl or alkenyl group of 11 to 19, for example, (: "Eta 23 one, Ci2H 25 - teeth 13H27 one, C14H29-, and I 5H31-, teeth 16 33-tooth 17
  • the substituent A is a linear or branched alkylene group or alkenylene group having 1 to 10 carbon atoms, preferably 2 to 6 carbon atoms, for example, a methylene group, an ethylene group, a propylene group, a butylene group, a pentylene group, Examples include a hexylene group, an isopropylene group, a 2-pentenyl group, and a 2-ethylbutylene group.
  • the guanidine derivative represented by the general formula (2) is usually compounded in the form of a salt, and specifically includes inorganic salts such as hydrochloride, bromate, sulfate, and phosphate, glycolate, and acetate. It can be used as an organic acid salt such as lactate, octamate, tartrate, citrate, acid amino acid salt, higher fatty acid salt, pyroglutamate and p-toluenesulfonate. Of these, the hydrochloride, bromate, acetate, glycolate, citrate and acid amino acid forms are preferred. Furthermore, amino acid-based cationic surfactants can also be suitably used as the cationic surfactant. As the amino acid-based cationic surfactant, Monono
  • N-long chain acyl basic amino acid lower alkyl ester salts can be mentioned.
  • the basic amino acids constituting this compound include natural amino acids such as ordinine, lysine and arginine. It is also possible to use synthetic amino acids such as, ⁇ -diaminobutyric acid. These may be optically active or racemic.
  • the acyl group is a saturated or unsaturated higher fatty acid residue having 8 to 22 carbon atoms. These may be natural or synthetic. For example, single higher fatty acid residues such as lauroyl group, myristoyl group, palmitoyl group and stearoyl group, and natural mixed higher fatty acid residues such as coconut oil fatty acid residue and tallow higher fatty acid residue can be used.
  • lower alkyl ester component methyl ester, ethyl ester, propyl ester, butyl ester, pentyl ester, hexyl ester, heptyl ester and octyl ester are preferred.
  • the lower alkyl ester component is usually compounded in the form of a salt, specifically, inorganic salts such as hydrochloride, bromate, sulfate, and phosphate, glycolate, acetate, lactate, and succinate.
  • hydrochloride, L- or DL-pyrrolidone carboxylate and acidic amino acid salt are preferred.
  • amidoamine-type surfactant can also be suitably used as the cationic surfactant.
  • amidoamine type surfactant a compound represented by the following general formula (3) can be used.
  • amidoamine type surfactant represented by the above general formula (3) include getylaminoethylamide stearate, dimethylaminoethylamide stearate, getylaminoethylamide palmitate, and getylaminopropyl cocoate.
  • a salt specifically, inorganic salts such as hydrochloride, bromate, sulfate, phosphate, etc., glycolate, acetate, lactate, and salt. It can be used as an acid salt, a tartrate salt, a citrate salt, an acidic amino acid salt, a higher fatty acid salt, a pyroglutamate salt, an organic acid salt such as P-toluenesulfonate and the like. Of these, acidic amino acid salts, citrate salts and hydrochloride forms are preferred.
  • the salts used for neutralization may be used alone or in combination of two or more.
  • stearic acid dimethylaminopropylamide stearic acid getylaminoethylamide
  • coconut oil fatty acid getylaminopropylamide are preferably used.
  • these amidoamine surfactants can be used.
  • the distribution of the number of carbon atoms (chain length) of the aliphatic hydrocarbon group of the cationic surfactant is as follows. It is preferred that the content of 22 carbon atoms is 50% or more, preferably 80% or more.
  • the amount of the cationic surfactant of the component (A) of the present invention is not particularly limited.
  • the lower limit in the shampoo composition of the present invention is preferably at least 0.05% by mass, more preferably at least 0.5% by mass, particularly preferably at least 1% by mass, and the upper limit is at most 7% by mass. It is preferably at most 5% by mass, particularly preferably at most 4% by mass. If the amount is too small, the hair will have sufficient smoothness and flexibility when rinsing. It cannot be applied, while if it is too much, the hair may become sticky in weight.
  • the component (A) one type may be used alone, or two or more types may be used in combination.
  • the blending amount is determined by the lower limit in the shampoo composition. Is preferably at least 0.05% by mass, more preferably at least 0.5% by mass, particularly preferably at least 1% by mass, and the upper limit is preferably at most 6% by mass, more preferably at most 4% by mass, particularly preferably 3 mass% or less.
  • the lower limit of the compounding amount in the shampoo composition is 0.1% by mass or more.
  • the upper limit is preferably at most 5% by mass, more preferably at most 3% by mass.
  • the lower limit of the amount of the shampoo composition is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and the upper limit is 7% by mass or less. And more preferably 5% by mass or less.
  • the component (B) is an oil containing no silicon atoms.
  • the component (A) in the component (B) and the oil component that can form a liquid crystal structure alone in the composition have an effect of dramatically improving the creaking during rinsing when shampooing.
  • Shampoo is essential in the composition.
  • the component (B) include the following simple substances or condensates of (1) to (5). As the component (B) of the present invention, these can be used alone or in an appropriate combination of two or more.
  • linear (cetyl alcohol, stearyl alcohol, behenyl alcohol, etc.) and branched chains (2-hexyldecyl alcohol, 2-ethylhexyl alcohol, isostearyl alcohol, etc.) are preferable, and a linear one is particularly preferable. If it is a branched chain, the one whose branch is closer to the tip is better. In terms of chain length, alcohols having 8 to 22 carbon atoms are preferable, and among them, linear alcohols having 16 to 22 carbon atoms are preferable in view of stability over time.
  • fatty acids having 8 to 24 carbon atoms are desirable.
  • fatty acids having 16 to 22 carbon atoms (palmitic acid, stearic acid, behenic acid, etc.) are more preferable in view of stability over time. preferable.
  • polyhydric alcohol II examples include polyhydric alcohols represented by the following general formula (4).
  • Examples of the polyhydric alcohol represented by the general formula (4) include ethylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, glycerin, and diglycol.
  • Glycerin Triglycerin, Tetraglycerin, Hexaglycerin, Decaglycerin, 1,3-Butylendalcol, Trimethylolpropane, Erythritol, Pencil erythryl 1 ⁇ , Dipena erythryl 1, Glucose, Mannose, Garaku] ⁇ , sucrose, frucrose, maltose, maltitol, xylitol, inositol, sorbitan, sorbitol, and the like, and EO adducts of these polyhydric alcohols.
  • Polybasic acid VI is a carboxylic acid such as succinic acid, daltaric acid, adipic acid, maleic acid, tartaric acid, malic acid, citric acid, fumaric acid, trimellitic acid, sebacic acid, or an inorganic acid such as phosphoric acid or sulfuric acid. Is mentioned.
  • Condensate IV of I and polyhydric alcohol III Condensate V of II and III, (5) Condensate of I or IV with II, V or polybasic acid VI includes higher alcohols E ⁇ , PO adducts, fatty acid E ⁇ , P ⁇ adducts, glyceryl monostearate, diglycerin monostearate, hexaglycerin monostearate, decaglycerin monostearate, diglycerin distearate Hexaglycerin distearate, decaglycerin distearate, penglycerin tristearate, hexaglycerin tristearate, deglycerin tristearate, hexaglycerin tetrastearate, tetrastearin Decaglycerin acid, tetraglycerin pentastearate, hexaglycerin pentastearate, decaglycerin pentastearate, glycerin
  • oils include alkyl ether phosphoric acid or its salt and POE (polyoxyethylene) derivative of alkyl ether phosphoric acid, alkylamine and its POE derivative, fatty acid amide and its POE derivative, castor oil or hydrogenated castor oil, and its P ⁇ .
  • E derivative carnauba wax, candelilla wax, vegetable wax such as wood wax, animal wax such as beeswax, whale wax, wool wax, petroleum wax such as paraffin wax, microcrissulin phosphorus wax, montan wax, ceresin, ozokerite, etc. Mineral wax.
  • C16-C22 alcohols with a melting point of 45 ° C or more (cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol) Etc.) are preferred.
  • the component ( ⁇ ) is represented as ( ⁇ ') because it is easy to form a liquid crystal.
  • an oil component that alone forms a liquid crystal structure (the above (1) and (2), and those of (3) and (4) below HLB4) in the composition with the component (A) described later in the composition.
  • the component ( ⁇ ′) one type may be used alone, or two or more types may be used in combination.
  • the component ( ⁇ ) includes, as components ( ⁇ ), other oils that do not form a liquid crystal alone and do not contain a silicon atom (for example, a filler such as ethylene glycol difatty acid ester or glycol distearate, ⁇ (hardening castor oil, ⁇ ⁇ ⁇ methyl dalicoside dioleate, alkyl fatty acid amide, etc., thinning, thickening and stabilizing agents, etc.) may be added.
  • the mass ratio of ( ⁇ ) to ( ⁇ ') in the shampoo composition is ( ⁇ ') / [( ⁇ ) + ( ⁇ ')], which is 0.35 to 0.90, and the lower limit is 0.50. Is preferred, and the upper limit is preferably 0.80. If the mass ratio is less than 0.35 or more than 0.90, the improvement in creaking during rinsing will be weak
  • the amount of the entire oil component not containing a silicon atom other than the component ( ⁇ ′) and the component ( ⁇ ′) is not particularly limited, but the lower limit in the shampoo composition is usually preferably 0.5% by mass or more, more preferably. It is at least 2% by mass, and the upper limit is preferably at most 10% by mass, more preferably at most 8% by mass. If the amount is less than 0.5% by mass, the feeling in use may be insufficient, while if it exceeds 10% by mass, the stability over time may be deteriorated.
  • the component (C) is one or more detersive surfactants selected from the group consisting of amphoteric surfactants, anionic surfactants, and nonionic surfactants.
  • amphoteric surfactant include an alkyl-based surfactant, an amido-based surfactant, a sulfo-based surfactant, a hydroxysulfo-based surfactant, and an amidosulfur-based surfactant.
  • Examples include hobetaine-based activators, phosphobetaine-based activators, imidazolinium betain-based activators, aminopropionic acid-based activators, and amino acid-based activators.
  • amidopropyl betaine laurate betaine lauryl dimethylaminoacetate
  • amidopropyl betaine coconut oil fatty acid betaine coconut fatty acid dimethylaminoacetate
  • lauryl hydroxysulfobetaine 2-alkyl-N-potassium Xymethyl-N-hydroxyethylimidazolinidum betaine
  • laurylimino dipropionic acid N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride are preferred.
  • anionic surfactant examples include an alkyl sulfonate, an alkyl sulfate, an acylated amino acid salt, a polyoxyethylene alkyl ether sulfate, an alkylbenzene sulfonate, an N-acyl-N-methyltaurine salt, ⁇ -olefin sulfonate, higher fatty acid ester sulfonate, alkyl ether acetate, polyoxyethylene alkyl ether acetate, fatty acid soap, alkyl phosphate ester, ⁇ ⁇ -lauroyl glutamate, ⁇ ⁇ -palmitoyl glutamate, ⁇ -lauroylu ⁇ -ethylglycine salt, ⁇ -lauroyl sarcosine salt, ⁇ -myristoyl] 3-alanine salt and the like.
  • nonionic surfactant examples include polyoxyethylene fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene glycol, and coconut oil fatty acid.
  • examples include alkanolamides, sucrose fatty acid esters, alkyl glycosides, alkyl glyceryl glycosides, and methyl dalcoside fatty acid esters.
  • the lower limit of the amount of the component (C) is preferably 2% by mass or more, more preferably 10% by mass or more in the shampoo composition, and the upper limit is preferably 60% by mass or less, more preferably 50% by mass. It is as follows. In the present invention, it is ionic in terms of foaming.
  • the amount of the active agent (amphoteric surfactant, anionic surfactant) which shows the above must exceed 2% by mass, preferably 5% by mass or more, and more preferably 10% by mass, based on the whole composition. The above is preferred.
  • the upper limit of the amount of the ionic surfactant is not particularly limited, but is usually 30% by mass.
  • the amount of the anionic surfactant is less than 5% by mass, preferably 2% by mass or less, and more preferably 1% by mass or less based on the whole composition. % By mass or less is preferred.
  • the lower limit of the amount of the activator having anionic properties is not particularly limited, but is usually 0.1% by mass.
  • the shampoo composition of the present invention preferably contains (D) a water-swellable clay mineral.
  • a water-swellable clay mineral By incorporating (D) a water-swellable clay mineral into the shampoo composition of the present invention, the dispersion stability is significantly improved.
  • the water-swellable clay mineral include natural or synthetic smectite clay, and organically modified clay obtained by treating a clay mineral with a quaternary ammonium salt-type cationic surfactant, Z or a non-ionic surfactant, or the like.
  • clay minerals having good dispersibility in the presence of an activator are preferred, and examples thereof include bentonite, montmorillonite, paiderite, nontronite, savonite, hectorite, soconite, and steepensite. Mica can also be used. Among these, bentonite, montmorillonite and sabonite are particularly preferred. As the component (D), one of these can be used alone, or two or more can be used in combination.
  • Water-swellable clay minerals especially those collected from nature, can fully demonstrate the effects of clay minerals if they contain a large amount of non-swelling impurities such as calcite, tridymite, cristobalite, quartz, and various inorganic substances. Since it may not be obtained, the purity of the clay mineral is preferably 90% by mass or more, particularly preferably 95% by mass or more.
  • the amount of the component (D) is preferably 0.01% by mass or more in the shampoo composition, and the lower limit is preferably 0.05% by mass or more.
  • the upper limit of the amount is preferably 5% by mass or less, more preferably 2% by mass or less.
  • the shampoo composition of the present invention preferably contains (E) an amine oxide component.
  • (E) Foaming can be reduced by blending the amine oxide component. Be one.
  • Examples of the aminoxide of the component (E) include an aminoxide represented by the following general formula (5).
  • R 8 is a monovalent hydrocarbon group having 8 to 24 carbon atoms, preferably 8 to 18 carbon atoms, and particularly preferably a linear alkyl group having 8 to 18 carbon atoms.
  • R 9 , R 1Q Is an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, or a monovalent substituent represented by the following general formula (6), and is preferably a methyl group or a hydroxyethyl group. 0 or an integer of 1 to 5, and n is preferably 0.
  • R 11 is a hydrogen atom or a methyl group, and p is 1 to 5.
  • Examples of the amine oxide used in the present invention include lauryl dimethyl amine oxide, stearyl dimethyl amine oxide, lauryl dihydroxyethylamine oxide, and polyoxyethylene lauryl dimethyl amine oxide (average number of added ethylene oxide: 3 Mol) and the like.
  • the shampoo composition of the present invention contains one or more of the amine oxides represented by the above structural formula.
  • these amine oxides are represented by trade names, Sofyu Min L manufactured by Toho Chemical Industry Co., Ltd., Okisamine ALS manufactured by Kyoei Chemical Industry Co., Ltd., Aromox CZ12, Aromox C Z12W manufactured by Lionaxo Co., Ltd. Examples include Aromox DMC-W and Aromox CM 12D-W (C).
  • the lower limit of the amount of the amine oxide (E) is preferably at least 0.1% by mass, more preferably at least 0.3% by mass in the shampoo composition from the viewpoint of producing creamy foaming. It is preferably at most 5% by mass, more preferably at most 2% by mass.
  • the shampoo composition of the present invention in addition to the above-mentioned essential components, optional components, and water such as purified water, the shampoo composition is generally used as needed, as long as the object of the present invention is not impaired.
  • Various additive components can be blended. These are single German or two or more can be used in combination.
  • additives include, for example, silicone derivatives, anionic polymers, ionic polymers, nonionic polymers, polyols, salt, inorganic salts such as sodium sulfate, organic salts, humectants such as propylene glycol, tonic agents, and the like.
  • Solubilizers antioxidants such as BHT and ⁇ -tocopherol; bactericides such as triclosan and trichlorocarban; polymer compounds; viscosity modifiers such as fatty acid monoethanolamide and fatty acid diethanolamide; ultraviolet absorbers; antioxidants; Protein derivatives, animal and plant extracts, anti-dandruff agents such as pyrocton olamine and zinc pyrithione, anti-inflammatory agents such as dipotassium glycyrrhizinate, benzoic acid and its salts, parabens, preservatives such as Caesone CG, quenic acid, and birds ⁇ ⁇ regulator such as ethanolamine, ethylene glycol Pearling agents such as di-fatty acid esters, emulsions, hydrotropes, lower alcohols, vitamins, volatile oil, hydrophobic solvents, dilution solvents, pigments, perfumes and the like Ru mentioned.
  • antioxidants such as BHT and ⁇ -tocopherol
  • the type of the silicone derivative is not particularly limited, and it is possible to use a silicone derivative that is usually used in a single-shump composition.
  • dimethylpolysiloxane including highly polymerized dimethylpolysiloxane and silicone rubber
  • methylphenylpolysiloxane polyether-modified silicone
  • polyamino-modified silicone vein-modified silicone
  • alcohol-modified silicone fluorine-modified silicone
  • Epoxy-modified silicone Epoxy-modified silicone
  • mercapto-modified silicone carboxy-modified silicone
  • fatty acid-modified silicone silicone graft polymer
  • cyclic silicone alkyl-modified silicone, trimethylsilyl-terminated dimethylpolysiloxane, and silanol-terminated dimethylpolysiloxane.
  • dimethylpolysiloxane, polyether-modified silicone, and polyamino-modified silicone are particularly preferably used.
  • silicone derivatives those having a refractive index of less than 1.46 are preferable, and those having a refractive index of less than 1.42 are more preferable, from the viewpoint of improving the smoothness of the finish.
  • the lower limit of the refractive index is not particularly limited, but is preferably 1.39 or more.
  • Specific examples of the silicone derivative having a refractive index of less than 1.46 include Leoflow DMS-55 (manufactured by Lion Corporation), SM8704C (manufactured by Toray Dauko Oneging Co., Ltd.), and SH3775M (Manufactured by Toray Dow Corning Co., Ltd.).
  • the refractive index is obtained by measuring the refractive index at 25 by the Cosmetic Primal General Test Method (Abbe refractometer).
  • the viscosity and the like of these silicone derivatives are not particularly limited, but usually, the viscosity at a temperature of 25 ° C. is 1 to 2 OOOOOOO c St (centimeter 1 cs, 10— ), Preferably 30 to: L 000000 cSt is suitably used.
  • the above-mentioned silicone derivative those obtained by emulsifying the above-mentioned silicone derivative with a surfactant and emulsifying the same can also be used. It should be noted that such emulsions are not particularly limited in emulsifiers and emulsification methods, and various emulsifiers can be used.
  • the product viscosity of the shampoo composition of the present invention is preferably from 500 to 15,000 mPa, s, particularly preferably from 1,000 to 10,000 mPa's, from the viewpoint of dispersion stability. . If it is less than 500 mPa ⁇ s, the dispersion stability of the silicone may be poor.
  • anionic polymers and nonionic polymers include pectin, carrageenan, guar gum, locust bean gum, gelatin, xanthan gum, lipoxyvinyl polymer, lipoxymethyl hydroxyethyl cellulose, hydroxche Examples include butylcellulose, hydroxypropylmethylcellulose, alginate, starch, polyvinyl alcohol, polyacrylate, polymethacrylate, polymethylacrylate, polyethylene glycol, polyethylene oxide, and tragarant rubber.
  • (G) having a structural unit represented by the following formula, a methoxy group of 25 to 35% by mass, a hydroxypropoxy group of 5 to 15% by mass (however, a hydroxyl group, a methoxy group and The total of the hydroxypropoxy groups is assumed to be 100% by mass. It is preferable to mix hydroxypropyl methylcellulose which is Pa ⁇ s. This makes it possible to obtain a shampoo composition having particularly good solubility, no squeaky feeling during rinsing, and a finer foam when whisking.
  • R and R represent a hydrogen atom, a methyl group or a hydroxypropoxy group.
  • the hydroxypropyl methyl cell mouth is obtained by substituting a part of the hydroxyl group of cellulose with a methoxy group or a hydroxypropoxy group.
  • the content of the methoxy group is 25 to 35% by mass, preferably 28 to 30% by mass, and
  • the content of groups is 5 to 15% by weight, preferably 7 to 12% by weight. If the respective contents are not within the above ranges, the effect of improving the foam cleanliness may be difficult to exert.
  • the viscosity is measured with a 2% by mass aqueous solution of hydroxypropylmethylcellulose using a BM-type viscometer at 20 ° (: 30 rotations Z minutes. A viscosity of less than 210 OmPa ⁇ s is sufficient. In some cases, the effect of modifying the foam may be insufficient, and if it exceeds 3500 mPa * s, the solubility may be poor.
  • This hydroxypropyl methylcellulose can be synthesized by a known method, and can also be obtained as a commercial product.
  • the lower limit of the blending amount in the shampoo composition of the present invention is preferably 0.1% by mass or more, and more preferably 0.1% by mass, from the viewpoint of good foam quality. %, Particularly preferably at least 0.2% by mass, and the upper limit is preferably at most 2% by mass, more preferably at most 0.5% by mass, particularly preferably at most 0.3% by mass.
  • the functional group is dimethyldiarylammonium Dimethyldiarylammonium chloride homopolymer, dimethyldiarylammonium chloride / acrylamide co-polymer, cationized cellulose, cationized guar gum, cationized dextran, cationized pullulan, quaternized bierpyrrolidone-aminoethyl methacrylate Copolymers, polyethyleneimine, dipropylene triamine condensate, dimethyl adipate-aminohydroxypropylethyltriamine copolymer, quaternary nitrogen-containing starch, etc., as well as hydrolyzed keratin, hydrolyzed silk, hydrolyzed collagen , Hydrolyzed wheat, cationized hydrolyzed keratin, cationized hydrolyzed silk, force-ionized hydrolyzed collagen, cationized hydrolyzed wheat, siliconized hydrolyzed collagen,
  • fragrance examples include hydrocarbons such as aliphatic hydrocarbons, terpene hydrocarbons, and aromatic hydrocarbons; alcohols such as aliphatic alcohols, terpene alcohols and aromatic alcohols; and aliphatic ethers and aromatic ethers.
  • Oxides such as ethers, aliphatic oxides and terpenes, aldehydes such as aliphatic aldehydes, terpene aldehydes, aliphatic cyclic aldehydes, thioaldehydes and aromatic aldehydes, aliphatic ketones, terpene ketones, Ketones such as aliphatic cyclic ketones, non-benzene aromatic ketones, aromatic ketones, acetal, ketones, phenols, phenol ethers, fatty acids, terpene carboxylic acids, aliphatic Acids such as cyclic carboxylic acids and aromatic carboxylic acids, acid amides, aliphatic lactones Lactones such as macrocyclic lactones, terpene lactones, aliphatic cyclic lactones, aromatic lactones, aliphatic esters, furan carboxylic esters, aliphatic cyclic carboxylic esters, cyclohexyl
  • Synthetic fragrance by Motoichi Indo published by Chemical Daily in 1996 Chemical Chemistry and Product Knowledge ", 1969, published by MONTCLAI R, NJ, written by STEFFEN ARCTANDER," Perfume and Flavor Chemicas 1 s " Perfume can be used.
  • the natural fragrance the fragrance described in “Encyclopedia of Fragrance” (edited by Japan Fragrance Association) can be used.
  • main fragrances include aldehydes C 6 to C 12 , anisaldehyde, acetal R, acetophenone, acetylsedrene, adoxal, arylamyl glycolate, arylcyclohexanepropionate, ⁇ -damascon, ⁇ -damascon , ⁇ -damascon, ambroxane, amylcinamic aldehyde, amylcinamic aldehyde dimethyl acetate, amyl valerianate, amyl salicylate, isoamyl acetate, isoamyl salicylate, ochranthiol, acetyl eugenol, vacanol, benzyl acetate , Benzyl alcohol, benzyl salicylate, bergamyl acetate, porunyl acetate, butyl butyrate, ⁇ -t-butylcyclohexanol, p_
  • getyl phthalate, dipropylene diol, benzyl benzoate, isopropyl myristate, hacoline, isopentane, orange terpene and the like can be used as a solvent or a retaining agent for the fragrance.
  • the shampoo composition of the present invention has a liquid crystal structure formed from (A) a cationic surfactant and (B) an oil containing no silicon atom, dispersed in the composition.
  • a liquid crystal structure formed from (A) a cationic surfactant and (B) an oil containing no silicon atom, dispersed in the composition.
  • the liquid crystal structure can be confirmed by X-ray diffraction, an optical microscope, an electron microscope, or the like.
  • the dispersed state indicates that the liquid crystal structure is dispersed without being solubilized.
  • the upper limit of the average particle size of the liquid crystal structure dispersed in the shampoo composition is preferably less than 20 m, more preferably 10 m or less, particularly preferably 5 / m or less, and the lower limit of 0. It is preferably at least 0.5 m, more preferably at least 0.1 m. If the average particle size of the liquid crystal structure is 20 m or more, the effect of preventing creaking during rinsing and the smoothness of the finish are reduced, stickiness is generated, and the dispersion stability is poor. May be. If it is less than 0.05 m, foaming is reduced, and stickiness may be caused by the effect of the emulsifier, which may be disadvantageous in cost.
  • the average particle size of the liquid crystal structure is determined by arbitrarily taking the image of the particles captured by an optical microscope into a computer at 100 locations, setting the same magnification, and performing image processing (for example, computer software win ROOF).
  • image processing for example, computer software win ROOF.
  • the production method includes: (C) an aqueous phase containing a detersive surfactant; and (A) a cationic surfactant and (B) an oil containing no silicon atom, and the above (A) and (B) It is preferable to mix the components at a temperature higher than the crystallization temperature and cool the resulting mixture from a temperature higher than the crystallization temperature. Further, (C) an aqueous phase containing a detersive surfactant, (A) a cationic surfactant and (B) an oil containing no silicon atom are mixed, and a part of the obtained mixture is continuously mixed.
  • the mixture is preferable to cool from a temperature equal to or higher than the crystallization temperature by repeatedly extracting the mixture, rapidly cooling the mixture, and returning the rapidly cooled mixture to the mixture. According to this method, the cooling time can be reduced.
  • the water-swellable clay mineral dispersed or swelled in water is preferably mixed with an aqueous phase containing a detersive surfactant. This method eliminates the need for cleaning in the tank between batches when continuously producing multiple production batches, and can dramatically improve production efficiency.
  • the order of mixing is not particularly limited, and the components of the liquid crystal structure may be added to the aqueous phase containing the detersive surfactant, or vice versa. Since the liquid crystal structure is easily solidified when the temperature is low, it is preferable that the detersive surfactant is heated and dissolved while heating and stirring, so that the liquid crystal structure is uniformly dispersed.
  • the mixing temperature is equal to or higher than the crystallization temperature of the components of the liquid crystal structure.
  • the crystallization temperature (abbreviated as ⁇ :) of the constituents of the liquid crystal structure of the present invention does not indicate the crystallization temperature of a material obtained by simply mixing and heating and dissolving the constituents of the liquid crystal structure, and is used.
  • T ° C Can be easily measured using a differential scanning calorimeter (DSC) using a shampoo composition as a sample. The most accurate T can be obtained by measuring at a sample amount of 5 to 50 mg and a heating rate of 0.5 to 2.0 ° C / min.
  • FIG. 2 shows a chart of a typical shampoo composition having the following composition, which was measured by DSC. 33 mg of the shampoo composition was measured at a heating rate of 1 ° C / min.
  • the large endothermic peak on the far left in Fig. 2 is the transition peak of the liquid crystal structure, but a small endothermic peak can be seen at higher temperatures.
  • the temperature at which the endothermic end of the endothermic peak ends is T ° C, which is 73 ° C for this sample.
  • the shampoo composition For the shampoo composition to be measured at T ° C, first, a mixture of the components of the liquid crystal structure in the composition is prepared, and the mixture is heated to check the dissolution temperature. Next, after thoroughly mixing the detersive surfactant component and the liquid crystal structure at a temperature 10 ° C or more higher than the melting temperature, the mixture is cooled to 30 ° C or less. The cooling rate is 0.5 ⁇ 2.0 ° C / min). After preparation, leave T for at least 3 days as a sample and measure T: using DSC.
  • the obtained mixture is cooled from a temperature higher than the crystallization temperature.
  • the cooling method is not particularly limited, but may be a cooling method in which cooling water is supplied to the outer jacket of the mixing tank, or a part of the mixture is continuously withdrawn, quenched, and the quenched mixture is mixed. (Hereinafter, abbreviated as a continuous partial quenching method). Continuously, especially in terms of shortening the cooling time Partial quenching is preferred. In this case, rapid cooling refers to instantaneous cooling of the heated mixture to 10 to 35 ° C.
  • the state immediately before the start of cooling is a mixture of a detersive surfactant having a temperature of T ° C or higher and a liquid crystal structure.
  • the continuous part quenching method is a cooling method in which a part of the mixture is continuously withdrawn, quenched, and the quenched material is returned to the mixture repeatedly to lower the temperature of the entire mixture.
  • FIG. 1 is a block diagram showing a preferred embodiment of the apparatus used for the continuous partial quenching method.
  • the shampoo composition at T ° C or higher prepared in the mixing tank 1 is circulated in the circulation line 2.
  • a heat exchanger 4 is provided in the middle of the circulation line 2, and the chilled water is sent from the chilled water production machine 5 to the heat exchanger 4 through the chilled water line 3 and discharged.
  • the shampoo composition circulating in the circulation line 2 is continuously cooled by the heat exchanger 4 and returned to the mixing tank 1 again.
  • the cooling time can be reduced to 1 Z 2 to 1/5 as compared with a general method of gradually cooling by passing cooling water through a jacket outside the tank. is there.
  • the temperature of the cooling water is 1 to 25 ° C, preferably 1 to 15 ° C. If the temperature is lower than 1 ° C, the cooling water freezes and cooling becomes difficult, and if it is higher than 25, the cooling efficiency is low. Further, if the processing capacity of the heat exchanger 4 is high, the cooling efficiency can be further increased by increasing the circulation capacity of the shampoo composition per unit time.
  • the temperature of the shampoo composition and the cooling water after the partial cooling coming out of the heat exchanger 4 is calculated from the temperature at which the cooling of the entire composition is expected to be completed by -5 to 120. ° C is preferred.
  • the viscosity of the shampoo composition around the temperature of the cooling water used does not increase significantly.
  • the shampoo composition solidifies in the cooling section in the heat exchanger, so that cooling cannot be performed.
  • the temperature of the cooling water may be set higher, but the cooling rate of the shampoo composition may be slowed and the economic merit may be reduced. For example, if the viscosity of the shampoo composition at 5 ° C is 2.0 Pas or less, the viscosity is high. It is possible to obtain a cooling efficiency.
  • This viscosity indicates the viscosity of the composition at the time of production, and is significantly different from the viscosity when the composition is finished as a final composition after cooling and cooled to 5 ° C. The reason is that after finishing as a composition, the system is structured with time and the viscosity increases.
  • the method for producing a shampoo composition of the present invention preferably includes a step of mixing a clay mineral dispersed or swelled in water with an aqueous phase containing a detersive surfactant.
  • the shampoo composition remaining on the wall surface or the like in the tank in the production of the batches Is mixed in during the production of the next batch, which hinders the effect of suppressing the crystal precipitation of the water-swellable clay mineral.
  • a water-dispersible or swelling liquid of a water-swellable clay mineral is heated to 50 to 80 ° C as necessary to transfer it with high stability and low viscosity.
  • An easily dispersed and swellable aqueous solution can be obtained.
  • the shampoo composition of the present invention can be used in a usual amount of a shampoo according to a conventional method.
  • ADVANTAGE OF THE INVENTION The shampoo composition of this invention has the effect of improving the feeling of creaking of hair, being excellent in foaming, and having excellent dispersion stability over time. Therefore, it is particularly preferable to use it for colored hair in which the hair is severely damaged.
  • Examples of the container of the shampoo composition of the present invention include tubes such as an aluminum laminate tube, an EVAL tube, an aluminum tube, and a glass-deposited plastic tube, as well as a mechanical or differential pressure dispenser container and a squeeze container.
  • Laminating film containers, dropper containers, stick containers, bottle containers, etc. usually have two or more layers, and are made of polyethylene, polyethylene terephthalate, polyester, biaxially oriented polypropylene, unoriented polypropylene, polyacrylonitrile, ethylene vinyl acetate It is composed of synthetic resin such as copolymer, paper, aluminum-deposited plastic, and the like. Considering strength, flexibility, weather resistance, etc., generally use 2 to 5 layers.
  • polyethylene polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-bier alcohol resin, acrylonitrile / styrene resin, ABS resin, polyamide, glass, etc. in a single layer or in combination of two or more layers. be able to.
  • the squeaky feeling of the hair which occurs when a shampoo is rinsed is improved, especially the squeaky feeling is improved in colored hair in which the squeaky feeling is likely to occur, the foaming is excellent, the foaming is excellent, and the dispersion over time.
  • a shampoo composition having excellent stability can be obtained.
  • Shampoo compositions were prepared according to the compositions shown in Tables 1 and 2 by the following production method, and evaluated for good foaming, creaking during rinsing, and dispersion stability. The results are shown in Tables 1 and 2.
  • ( ⁇ ′) in the table indicates an oil component that forms a liquid crystal structure alone with the ( ⁇ ) component in the ( ⁇ ) component.
  • oil-soluble components (A) and (B) and other oil-soluble components were heated and dissolved at 45 to 80 ° C. to prepare an oil phase.
  • a surfactant and other water-soluble components were dissolved in purified water at room temperature to 80 ° C to prepare an aqueous phase.
  • the oil phase obtained in i was added to the aqueous phase obtained in ffl. ii, and the mixture was stirred with an azihomomixer to form a ⁇ / W emulsion.
  • the mixture was gradually cooled to room temperature while stirring with a paddle mixer, and the pH was adjusted as needed to obtain a shampoo composition.
  • the total score of 10 people was represented by the following criteria.
  • in-bath products such as rinse conditioner and shampoo and hair care products used after shampooing, those used daily by each panelist were used as they were.
  • Total points are 1 to 1 to 4 points
  • the total score is 15 points or less
  • the total score of 10 people was represented by the following criteria. For in-bath products such as rinsing conditioners used after shampooing, and for art bath products such as styling agents and hair care agents, those used daily by each panelist were used as they were.
  • the prepared shampoo composition was stored at 50 ° C for one month, and its uniformity was evaluated based on the following criteria based on its appearance and observation with a polarizing microscope.
  • the storage over time was performed by filling each of the following containers (1) to (9) with the shampoo composition.
  • PE indicates polyethylene
  • PP indicates polypropylene
  • PET indicates polyethylene terephthalate
  • PA indicates polyamide
  • HDPE high density polyethylene
  • Bottle Material PP Dispenser: Material PP, PE and SU S 304
  • Bottle part HDPE dispenser part Material used PP, PE and SU S 304
  • Bottle PET dispenser Material used PP, PE and SUS 304
  • Bottle part PP / HDPE dispenser part Material used PP, PE and S US 304
  • a shampoo composition was prepared by the following production method, and based on the following evaluation method, good foaming, no creaking during rinsing, smoothness of finish, and tackiness of finish were obtained. The absence and dispersion stability were evaluated. The results are shown in Tables 3 and 4.
  • oil-soluble components (A) and (B) and other oil-soluble components were heated and dissolved at 60 to 80 ° C. to prepare an oil phase.
  • the oil phase obtained in i was added to the aqueous phase obtained in ill. ii, and the mixture was stirred with an azihomomixer to form a ⁇ / W emulsion.
  • the mixture was gradually cooled to room temperature while stirring with a paddle mixer, and the pH was adjusted as needed to obtain a shampoo composition.
  • the component (F) was mixed with i or ii or mixed with iv after reaching room temperature, depending on the type.
  • the average particle size of the liquid crystal structure is obtained by arbitrarily capturing images of the particles captured by an optical microscope at 100 locations on a computer, setting the same magnification, and performing image processing (for example, computer software win ROOF). Was.
  • the hair of 10 persons is divided into two parts on the left and right. O mL was applied to each and shampooed, and the smoothness and non-stickiness of the finished hair were evaluated based on the following scores. In the table, the total score of the 10 people is represented by the following criteria.
  • Control shampoo one Composition Mass% Polyoxyethylene alkyl ether sodium sulfate 10%
  • the total score is 15 points or less
  • composition (% by mass)
  • a shampoo composition was prepared by the following production method, and the dispersion stability of the liquid crystal structure, bubbling, and the feeling of squeaking during rinsing were evaluated based on the following evaluation method. The results are shown in Table 5.
  • a shampoo composition was prepared in the same manner as in Example 23 based on the following composition, and evaluated for solubility in Examples 27 to 30 and solubility and creaminess of foams in Examples 31 to 37. did.
  • Tables 6 and 7 show the viscosities of the methoxy groups and hydroxypropoxy groups of the hydroxypropylmethylcellulose used in each example, and the viscosities of the 2% aqueous solutions and the evaluation results.
  • a shampoo composition was prepared by the manufacturing method of Example 23 above, and based on the following evaluation methods, good foaming, foam sliding, foam creaminess, and rinsing Evaluation was made on the absence of creaking and the moist feeling after drying. The results are shown in Table 8. [Table 8]
  • composition (% by mass)
  • ⁇ Measurement conditions No. 3 to 4 for the inlet and 30 rpm for the rotor rotation speed.Measurement method> Keep the shampoo composition at 25 ° C 1 ° C and gently keep the rotor in the liquid. After insertion and standing for 1 minute, the viscosity was measured after 10 rotations by rotating the rotor. Evaluation of long-term dispersion stability of liquid crystal structure
  • the prepared shampoo composition is correlated with long-term storage at room temperature for 1 month at 4 Ot: which is an unstable temperature (near the phase transition point) for the liquid crystal structure, and at 40 ° C for over 1 year.
  • the storage with time was performed by filling each of the containers (1) to (9) with the shampoo composition.
  • in-bath products such as rinse conditioner and shampoo and hair care products used after shampooing
  • those used daily by each panelist were used as they were.
  • a shampoo composition was prepared, and the state of the solution immediately after the preparation was evaluated according to the following evaluation criteria. ⁇ Evaluation criteria>
  • the 10 g hair tress was moistened with 40 water and contained 5 g water.
  • the hair tresses are then washed using 1 g of the shampoo composition, and the creaminess of the foam during washing is compared with a control shampoo (without hydroxypropylmethylcellulose), and the sensory evaluation is made based on the following evaluation criteria. did.
  • a shampoo composition having the following composition was prepared by the following method based on the description in Table 9, and evaluated for creaking without rinsing and storage stability at ⁇ 5 ° C. based on the following evaluation criteria. The results are shown in Table 9.
  • a water-swellable clay mineral is dispersed in purified water (ion-exchanged water), a detersive surfactant is added, and the components of the liquid crystal structure and a dissolution enhancer for the liquid crystal structure are heated and mixed in advance. Add to the Tit. Then, start cooling when the whole liquid reaches T2 ° C. After cooling to about 40 ° C, other ingredients were added, and the amount of citric acid was adjusted to prepare a shamboo composition having a pH of 5.5.
  • the mixing tank used was a 20-L capacity vacuum milking pot (PVT-11-20 manufactured by Mizuho Industry Co., Ltd.).
  • PVT-11-20 manufactured by Mizuho Industry Co., Ltd.
  • water at 15 to 20 ° C was allowed to flow through the jacket of the vacuum emulsification kettle to cool.
  • pipes are connected via the outlet of the contents at the bottom of the vacuum emulsification tank, an external heat exchanger and a transfer pump, and the contents cooled by the external heat exchanger are emulsified. Feed the raw material in the upper part of the vacuum emulsification kettle to the pipe returning to the kettle By connecting to the mouth, the contents of the vacuum emulsification kettle were continuously circulated.
  • UX-005 (having a heat transfer area of 0.612 m 2 ) manufactured by Hisaka Works was used as the external heat exchanger. Cooling water between the start and end of cooling so that cooling water at 5 to 7 ° C enters the heat exchanger, and the contents and cooling water come out of the heat exchanger at 20 to 35 ° C. was adjusted. The time required for cooling to T2-38 ° C was about 40 minutes for the jacket cooling method and 10-12 minutes for the continuous partial quenching method using an external heat exchanger. The temperature change (Tlt ⁇ T2 ° C) occurs between emulsification and cooling, and the operation during that time will be described.
  • Example 45 to 47 and 49 only the steam heating by the jacket was stopped at the start of emulsification, and there was no change in the composition of the contents (natural heat radiation).
  • Example 48 jacket heating was stopped, and the total amount of sodium benzoate to be added was made a 33% aqueous solution (the temperature of the sodium benzoate aqueous solution was about 15 ° C), and the mixture was added and stirred after emulsification.
  • Example 50 the heating of the jacket was stopped, and 1 to 3 of amide propyl betaine to be added was added and stirred after emulsification (the temperature of lauric amide propyl betaine was about 15 ° C).
  • the remaining 2Z3 is added before emulsification).
  • the crystallization temperature (T ° C) of the shampoo composition of the example prepared by the above-mentioned production method was measured by using a differential scanning calorimeter (DSC) (DSC 6100, manufactured by Seiko Instruments Inc.). As a result of using it, it was 74.
  • the measurement conditions were as follows: sample amount: Example 45 31 mg, Example 46 29018, Example 47 321! 18, Example 48 32] 118, Example 49 33 mg, Example 50 3 lmg, Heating rate l ° CZm was in.
  • Example 45 3.2 Pa ⁇ s
  • Example 46 2.
  • the viscosity was 4 Pa ⁇ s
  • Example 47 2.6 Pa ⁇ s
  • Example 48 2.4 Pa ⁇ s.
  • the shampoo composition is filled in each of the above containers (1) to (9) and stored for one month in a thermostat controlled at 5 ⁇ 1 ° C for 3 days in an environment of 22 to 26 ° C.
  • the shampoo composition was allowed to stand, the entire amount thereof was transferred into a container such as a petri dish, and the appearance was observed.
  • a shampoo composition having the following composition was prepared in the same manner as in Example 46 above.
  • the shampoo composition of the above example showed a regular diffraction pattern as a result of X-ray diffraction. When these were observed with a polarizing microscope, the tissue images showed optical anisotropy.When the cryo-scanned electron microscope was used to observe samples that had been frozen and cleaved, the thin layers were superimposed.
  • the shampoo-composition of the example obtained by the production method was found to have a liquid crystal structure dispersed therein.
  • Acrylic card 22_80 (manufactured by Lion Corporation)
  • This product is synthesized from erucic acid derived from rapeseed oil via long chain amine.
  • the alkyl chain length distribution of the long chain amine is as follows.
  • Distearyl dimethylammonium chloride based on Cosmo Primordia, a paste with a pure content of about 75%. In the table, the pure content of distearyldimethylammonium chloride is described.
  • Amidobutyl danidine acetate laurate solution CI 2A4G (Lion Co., Ltd.) Aqueous solution with a pure content of about 32% The amount corresponding to the pure content of amide laurate acetate butyl danidine solution is shown in the table.
  • the distribution of chain length is generally as follows, in accordance with the standard for the composition of each cosmetic variety (hereinafter abbreviated as “cosmetic rule”).
  • LANETTE 22 (manufactured by Cognis Japan Co., Ltd.) Compliant with Cosmetic Primers, solid.
  • This product is derived from coconut oil and its alkyl chain length distribution is as follows.
  • Stearic acid 100 Stearic acid 100 (Shin Nippon Rika Co., Ltd.)
  • Monoglyceryl stearate Rikemal S-100 (based on Riken Vitamin Co., Ltd. Cosmetics Regulations, white solid, mp 62-68, HLB 4.3.
  • Ci 6 and Ci 8 Ethylene dalichol distearate complying with cosmetics regulations.
  • the mixing ratio of Ci 6 and Ci 8 is 6: 4.
  • the method of blending this ingredient into shamboo is based on 25% by weight of this ingredient in advance with sodium POE alkyl ether sulfate.
  • a dispersion was prepared by mixing 20% of an aqueous solution, 25% of an oil fatty acid diethanolamine, and 30% of water at about 80 to prepare a dispersion, and the dispersion was added to a shampoo.
  • the equivalent amount of the pure POE alkyl ether sodium sulfate is described.
  • Aqueous primordia basis about 35% pure aqueous solution.
  • the pure content equivalent of betaine lauryldimethylaminoacetate is described.
  • Lauryl hydroxysulfobetaine solution compliant with cosmetics regulations, with a water content of about 30% pure liquid.
  • the pure content equivalent of laurylhydroxysulfobenzoin was described.
  • Alkyl poly (8-16) darcoside conforming to cosmetics regulations. Liquid with a pure content of about 52%. In the table, the equivalent amount of the alkylpoly (8-16) darcoside in pure content is described. This product is derived from coconut oil and its alkyl chain length distribution is as follows.
  • Lauryl dimethylamine oxide solution based on cosmetics regulations. Aqueous solution with a pure content of about 33%. In the table, the pure content equivalent of lauryl dimethylamine oxide is described.
  • Amino-modified silicone SM8704C (manufactured by Dow Corning Toray Co., Ltd.) This is an aqueous dispersion of amodimethicone that conforms to cosmetics regulations.
  • the concentration of the amino-modified silicone is about 40 o.
  • the average particle size of the amino-modified silicone in the aqueous dispersion Is about 0.1 m.
  • a dimethyldiarylammonium chloride-acrylamide copolymer solution that complies with cosmetics regulations. Its pure content is about 5.5% aqueous solution.
  • the charge ratio of dimethyldiarylammonium chloride and acrylamide, which are monomers, is about 1: 1.
  • the equivalents of the pure components of the dimethyldiarylammonium chloride-acrylamide copolymer are described.
  • a sorbit solution that conforms to Cosmetic Prima an aqueous solution with a pure content of about 60%.
  • the equivalent of pure sorbitol is described.
  • Promois Silk 1000 (manufactured by Seiwa Kasei Co., Ltd.)
  • Yellow No. 5 Yellow No. 5 (manufactured by Daiwa Kasei Co., Ltd.)
  • Red No. 106 Red No. 106 (manufactured by Kishi Kasei Co., Ltd.)
  • Brown 201 (manufactured by Kishi Kasei Co., Ltd.)
  • Green No. 3 Green No. 3 (made by Kishi Kasei Co., Ltd.)
  • Green 201 Green 201 (Koyo Chemical Co., Ltd.) * Methyl paraben: (Made by Yoshitomi Fine Chemical Co., Ltd.)
  • Sodium benzoate Sodium benzoate based on Cosmetic primordium (manufactured by BF Goodrich Ka 1 ama Inc.)
  • a fragrance having the following composition was used.

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Abstract

Composition de shampooing comprenant (A) un tensioactif cationique, (B) un constituant huileux exempt de silicone et (C) un ou plusieurs tensioactifs détergents sélectionnés dans le groupe constitué par des tensioactifs amphotères, des tensioactifs anioniques et des tensioactifs non ioniques. Cette composition présente, de façon caractéristique, un rapport massique (B')/[(A) + (B')] de 0,35 à 0,90 dans lequel (B') fait partie du constituant (B) consistant lui-même en une structure cristalline liquide avec le constituant (A), la teneur totale en tensioactif amphotère et en tensioactif anionique dépassant 2 % en masse, dans la mesure où la teneur en tensioactif anionique est inférieure à 5 % en masse et ou la structure cristalline liquide obtenue à partir des constituants (A) et (B) est dispersée dans la composition. Cette composition limite la décoloration du cheveu, en particulier du cheveu teint, après rinçage et possède des propriétés de moussage excellentes ainsi qu'une très bonne stabilité de dispersion à long terme.
PCT/JP2003/014502 2002-11-15 2003-11-14 Composition de shampooing Ceased WO2004045568A1 (fr)

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JP2006104142A (ja) * 2004-10-07 2006-04-20 Pola Chem Ind Inc 毛髪用の化粧料
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JP2008508201A (ja) * 2004-07-27 2008-03-21 ユニリーバー・ナームローゼ・ベンノートシヤープ ヘアケア組成物
JP2009062311A (ja) * 2007-09-06 2009-03-26 Shiseido Co Ltd 皮膚外用剤
JP2010006744A (ja) * 2008-06-26 2010-01-14 Shiseido Co Ltd 頭髪用洗浄剤
JPWO2008038496A1 (ja) * 2006-09-26 2010-01-28 ライオン株式会社 シャンプー組成物
JP2010509262A (ja) * 2006-11-08 2010-03-25 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
JP2010509261A (ja) * 2006-11-08 2010-03-25 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
JP2011513453A (ja) * 2008-03-14 2011-04-28 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
WO2012005319A1 (fr) * 2010-07-07 2012-01-12 ライオン株式会社 Composition de nettoyage
JP2014097950A (ja) * 2012-11-14 2014-05-29 Milbon Co Ltd シャンプー組成物
JP2014105199A (ja) * 2012-11-29 2014-06-09 Milbon Co Ltd 洗浄剤
JP2014528426A (ja) * 2011-09-29 2014-10-27 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 陽イオン性コンディショナー代替品
WO2017057417A1 (fr) * 2015-09-28 2017-04-06 小林製薬株式会社 Composition d'émulsion
JP2018522932A (ja) * 2015-08-14 2018-08-16 ロレアル カチオン性界面活性剤、脂肪アルコール、両性界面活性剤、デンプン誘導体、及びカチオン性コンディショニングポリマーを含む化粧用組成物
GB2577970A (en) * 2018-08-10 2020-04-15 Theunseen Ltd Liquid crystal composition, use and method
JP2020164494A (ja) * 2019-03-29 2020-10-08 株式会社 資生堂 毛髪強化剤
JP2023512288A (ja) * 2020-02-07 2023-03-24 ザ プロクター アンド ギャンブル カンパニー 香料／シリコーンエマルジョン及び関連する消費者製品

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CN101288631B (zh) * 2007-04-20 2013-01-02 花王株式会社 皮肤洗净剂组合物
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JP2008508201A (ja) * 2004-07-27 2008-03-21 ユニリーバー・ナームローゼ・ベンノートシヤープ ヘアケア組成物
JP2006063044A (ja) * 2004-08-30 2006-03-09 Lion Corp シャンプー組成物
JP2006104142A (ja) * 2004-10-07 2006-04-20 Pola Chem Ind Inc 毛髪用の化粧料
JP2006347972A (ja) * 2005-06-17 2006-12-28 Milbon Co Ltd 毛髪洗浄剤
JPWO2008038496A1 (ja) * 2006-09-26 2010-01-28 ライオン株式会社 シャンプー組成物
JP2010509262A (ja) * 2006-11-08 2010-03-25 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
JP2010509261A (ja) * 2006-11-08 2010-03-25 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
JP2009062311A (ja) * 2007-09-06 2009-03-26 Shiseido Co Ltd 皮膚外用剤
KR101546558B1 (ko) 2008-03-14 2015-08-25 유니레버 엔.브이. 컨디셔닝 샴푸 조성물
JP2011513453A (ja) * 2008-03-14 2011-04-28 ユニリーバー・ナームローゼ・ベンノートシヤープ コンディショニングシャンプー組成物
EP2249925B1 (fr) 2008-03-14 2015-08-19 Unilever PLC Composition de shampooing conditionneur
JP2010006744A (ja) * 2008-06-26 2010-01-14 Shiseido Co Ltd 頭髪用洗浄剤
WO2012005319A1 (fr) * 2010-07-07 2012-01-12 ライオン株式会社 Composition de nettoyage
JP2014528426A (ja) * 2011-09-29 2014-10-27 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 陽イオン性コンディショナー代替品
JP2014097950A (ja) * 2012-11-14 2014-05-29 Milbon Co Ltd シャンプー組成物
JP2014105199A (ja) * 2012-11-29 2014-06-09 Milbon Co Ltd 洗浄剤
JP2018522932A (ja) * 2015-08-14 2018-08-16 ロレアル カチオン性界面活性剤、脂肪アルコール、両性界面活性剤、デンプン誘導体、及びカチオン性コンディショニングポリマーを含む化粧用組成物
WO2017057417A1 (fr) * 2015-09-28 2017-04-06 小林製薬株式会社 Composition d'émulsion
JP2017066035A (ja) * 2015-09-28 2017-04-06 小林製薬株式会社 乳化組成物
GB2577970A (en) * 2018-08-10 2020-04-15 Theunseen Ltd Liquid crystal composition, use and method
GB2577970B (en) * 2018-08-10 2022-11-09 Theunseen Ltd Liquid crystal composition, use and method
JP2020164494A (ja) * 2019-03-29 2020-10-08 株式会社 資生堂 毛髪強化剤
WO2020203401A1 (fr) * 2019-03-29 2020-10-08 株式会社 資生堂 Agent de renforcement des cheveux
JP7361485B2 (ja) 2019-03-29 2023-10-16 株式会社 資生堂 毛髪強化剤
JP2023512288A (ja) * 2020-02-07 2023-03-24 ザ プロクター アンド ギャンブル カンパニー 香料／シリコーンエマルジョン及び関連する消費者製品
JP7506163B2 (ja) 2020-02-07 2024-06-25 ザ プロクター アンド ギャンブル カンパニー 香料／シリコーンエマルジョン及び関連する消費者製品

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CN1711070A (zh) 2005-12-21
JP4446176B2 (ja) 2010-04-07
KR101092419B1 (ko) 2011-12-09

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