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WO2003031665A3 - Superconductor materials fabrication method using electrolytic reduction and infiltration - Google Patents

Superconductor materials fabrication method using electrolytic reduction and infiltration Download PDF

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Publication number
WO2003031665A3
WO2003031665A3 PCT/GB2002/004603 GB0204603W WO03031665A3 WO 2003031665 A3 WO2003031665 A3 WO 2003031665A3 GB 0204603 W GB0204603 W GB 0204603W WO 03031665 A3 WO03031665 A3 WO 03031665A3
Authority
WO
WIPO (PCT)
Prior art keywords
infiltration
sponge
salt
porous
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2002/004603
Other languages
French (fr)
Other versions
WO2003031665A2 (en
Inventor
George Zheng Chen
Derek John Fray
Bartiomiej Andrzej Glowacki
Xiao-Yong Yan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cambridge University Technical Services Ltd CUTS
Original Assignee
Cambridge University Technical Services Ltd CUTS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cambridge University Technical Services Ltd CUTS filed Critical Cambridge University Technical Services Ltd CUTS
Priority to US10/492,180 priority Critical patent/US20050016854A1/en
Priority to BR0213217-6A priority patent/BR0213217A/en
Priority to EP02767710A priority patent/EP1440175A2/en
Priority to CA002463396A priority patent/CA2463396A1/en
Priority to JP2003534634A priority patent/JP2005505121A/en
Publication of WO2003031665A2 publication Critical patent/WO2003031665A2/en
Publication of WO2003031665A3 publication Critical patent/WO2003031665A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N60/00—Superconducting devices
    • H10N60/01—Manufacture or treatment
    • H10N60/0184—Manufacture or treatment of devices comprising intermetallic compounds of type A-15, e.g. Nb3Sn
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/495—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on vanadium, niobium, tantalum, molybdenum or tungsten oxides or solid solutions thereof with other oxides, e.g. vanadates, niobates, tantalates, molybdates or tungstates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/653—Processes involving a melting step
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/20—Obtaining niobium, tantalum or vanadium
    • C22B34/24—Obtaining niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00—General methods of reducing to metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3251—Niobium oxides, niobates, tantalum oxides, tantalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/402—Aluminium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40—Metallic constituents or additives not added as binding phase
    • C04B2235/404—Refractory metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/80—Phases present in the sintered or melt-cast ceramic products other than the main phase

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Metallurgy (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

A preform (28) is slip-cast or pressed from a metal compound or a mixture of metal compounds, sintered in air, vacum, or inert gas, and is electrolytically reduced in a bath (20) of molten salt to form a porous metal or alloy product. The alloy is in the form of a solid, porous sponge. In the bath (20) the salt is in contact with a reservoir (26) of molten infiltration material (24). After completion of the electrolytic reduction the porous product is moved into the infiltration material which fills the pores therein, displacing the salt. The infiltrated product is then solidified for further materials processing. The sponge material preferably comprises niobium, and the infiltration liquid is for instance molten tin. The infiltrated niobium sponge can be further processed to form a superconductor material of A-15 type, e.g. Nb3Al and Nb3Sn.
PCT/GB2002/004603 2001-10-10 2002-10-10 Superconductor materials fabrication method using electrolytic reduction and infiltration Ceased WO2003031665A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US10/492,180 US20050016854A1 (en) 2001-10-10 2002-10-10 Materials fabrication method and apparatus
BR0213217-6A BR0213217A (en) 2001-10-10 2002-10-10 Method of fabrication of superconducting materials employing electrolytically reducing and infiltrating
EP02767710A EP1440175A2 (en) 2001-10-10 2002-10-10 Superconductor materials and fabrication method using electrolytic reduction and infiltration
CA002463396A CA2463396A1 (en) 2001-10-10 2002-10-10 Superconductor materials fabrication method using electrolytic reduction and infiltration
JP2003534634A JP2005505121A (en) 2001-10-10 2002-10-10 Superconductor material manufacturing method using electrolytic reduction and infiltration

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0124303.9 2001-10-10
GBGB0124303.9A GB0124303D0 (en) 2001-10-10 2001-10-10 Material fabrication method and apparatus

Publications (2)

Publication Number Publication Date
WO2003031665A2 WO2003031665A2 (en) 2003-04-17
WO2003031665A3 true WO2003031665A3 (en) 2003-05-22

Family

ID=9923554

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2002/004603 Ceased WO2003031665A2 (en) 2001-10-10 2002-10-10 Superconductor materials fabrication method using electrolytic reduction and infiltration

Country Status (8)

Country Link
US (1) US20050016854A1 (en)
EP (1) EP1440175A2 (en)
JP (1) JP2005505121A (en)
CN (1) CN1585828A (en)
BR (1) BR0213217A (en)
CA (1) CA2463396A1 (en)
GB (1) GB0124303D0 (en)
WO (1) WO2003031665A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0621184D0 (en) * 2006-10-25 2006-12-06 Rolls Royce Plc Method for treating a component of a gas turbine engine
GB2449862B (en) * 2007-06-05 2009-09-16 Rolls Royce Plc Method for producing abrasive tips for gas turbine blades
GB0822703D0 (en) * 2008-12-15 2009-01-21 Rolls Royce Plc A component having an abrasive layer and a method of applying an abrasive layer on a component
SA110310372B1 (en) * 2009-05-12 2014-08-11 Metalysis Ltd Apparatus and Method for reduction of a solid feedstock
CN101967660B (en) * 2010-11-09 2012-05-02 上海大学 Co-electric deoxidation method for preparing Nb3Method for producing Al superconducting material
MY180279A (en) 2010-11-18 2020-11-26 Metalysis Ltd Electrolysis apparatus
CN105903473B (en) * 2016-04-17 2019-03-01 北京化工大学 A kind of hydrotalcite precursor method prepares the method and its application of M-Sn intermetallic compound
DE102019000906B4 (en) * 2019-02-08 2025-04-17 Taniobis Gmbh Powder based on niobium tin compounds for the production of superconducting components
CN119361229B (en) * 2024-12-25 2025-03-25 西安聚能超导线材科技有限公司 A method for preparing CuNb-enhanced niobium-tin composite wire

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4223434A (en) * 1979-02-01 1980-09-23 The United States Of America As Represented By The United States Department Of Energy Method of manufacturing a niobium-aluminum-germanium superconductive material
US4411712A (en) * 1980-12-15 1983-10-25 Airco, Inc. Method of manufacture of multifilamentary intermetallic superconductors
EP0298893A2 (en) * 1987-07-06 1989-01-11 Lanxide Technology Company, Lp. Methods for forming complex oxidation reaction products including superconducting articles
US5366686A (en) * 1993-03-19 1994-11-22 Massachusetts Institute Of Technology, A Massachusetts Corporation Method for producing articles by reactive infiltration
US5372178A (en) * 1989-01-13 1994-12-13 Lanxide Technology Company, Lp Method of producing ceramic composite bodies
WO1999064638A1 (en) * 1998-06-05 1999-12-16 Cambridge University Technical Services Limited Removal of oxygen from metal oxides and solid solutions by electrolysis in a fused salt
WO2000063456A2 (en) * 1999-04-20 2000-10-26 Composite Materials Technology, Inc. Constrained filament niobium-based superconductor composite and process of fabrication
WO2001062994A1 (en) * 2000-02-22 2001-08-30 Qinetiq Limited Method of manufacture for ferro-titanium and other metal alloys electrolytic reduction

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4411721A (en) * 1982-02-25 1983-10-25 The Mead Corporation Apparatus and method for attaching fastener tapes
US6117208A (en) * 1998-04-23 2000-09-12 Sharma; Ram A. Molten salt process for producing titanium or zirconium powder
US6540902B1 (en) * 2001-09-05 2003-04-01 The United States Of America As Represented By The United States Department Of Energy Direct electrochemical reduction of metal-oxides

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4223434A (en) * 1979-02-01 1980-09-23 The United States Of America As Represented By The United States Department Of Energy Method of manufacturing a niobium-aluminum-germanium superconductive material
US4411712A (en) * 1980-12-15 1983-10-25 Airco, Inc. Method of manufacture of multifilamentary intermetallic superconductors
EP0298893A2 (en) * 1987-07-06 1989-01-11 Lanxide Technology Company, Lp. Methods for forming complex oxidation reaction products including superconducting articles
US5372178A (en) * 1989-01-13 1994-12-13 Lanxide Technology Company, Lp Method of producing ceramic composite bodies
US5366686A (en) * 1993-03-19 1994-11-22 Massachusetts Institute Of Technology, A Massachusetts Corporation Method for producing articles by reactive infiltration
WO1999064638A1 (en) * 1998-06-05 1999-12-16 Cambridge University Technical Services Limited Removal of oxygen from metal oxides and solid solutions by electrolysis in a fused salt
WO2000063456A2 (en) * 1999-04-20 2000-10-26 Composite Materials Technology, Inc. Constrained filament niobium-based superconductor composite and process of fabrication
WO2001062994A1 (en) * 2000-02-22 2001-08-30 Qinetiq Limited Method of manufacture for ferro-titanium and other metal alloys electrolytic reduction

Also Published As

Publication number Publication date
US20050016854A1 (en) 2005-01-27
CA2463396A1 (en) 2003-04-17
JP2005505121A (en) 2005-02-17
CN1585828A (en) 2005-02-23
EP1440175A2 (en) 2004-07-28
WO2003031665A2 (en) 2003-04-17
BR0213217A (en) 2004-12-21
GB0124303D0 (en) 2001-11-28

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