WO2003012843A1 - Procede et appareil de nettoyage et procede et appareil de gravure - Google Patents
Procede et appareil de nettoyage et procede et appareil de gravure Download PDFInfo
- Publication number
- WO2003012843A1 WO2003012843A1 PCT/JP2001/006604 JP0106604W WO03012843A1 WO 2003012843 A1 WO2003012843 A1 WO 2003012843A1 JP 0106604 W JP0106604 W JP 0106604W WO 03012843 A1 WO03012843 A1 WO 03012843A1
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- WO
- WIPO (PCT)
- Prior art keywords
- gas
- fluorine
- mixed
- halogen
- processing chamber
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims description 32
- 238000005530 etching Methods 0.000 title claims description 28
- 239000007789 gas Substances 0.000 claims abstract description 267
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 58
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000011737 fluorine Substances 0.000 claims abstract description 53
- 239000011261 inert gas Substances 0.000 claims abstract description 34
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims description 38
- 229910052736 halogen Inorganic materials 0.000 claims description 28
- 150000002367 halogens Chemical class 0.000 claims description 25
- 239000004065 semiconductor Substances 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 21
- 238000011144 upstream manufacturing Methods 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 239000006227 byproduct Substances 0.000 claims description 15
- 150000002222 fluorine compounds Chemical class 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 14
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 229910003070 TaOx Inorganic materials 0.000 claims description 8
- 229910004205 SiNX Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 3
- -1 WSix Inorganic materials 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000010703 silicon Substances 0.000 abstract description 6
- JOHWNGGYGAVMGU-UHFFFAOYSA-N trifluorochlorine Chemical compound FCl(F)F JOHWNGGYGAVMGU-UHFFFAOYSA-N 0.000 abstract description 2
- 229910020323 ClF3 Inorganic materials 0.000 abstract 1
- 101100441092 Danio rerio crlf3 gene Proteins 0.000 abstract 1
- 239000000758 substrate Substances 0.000 description 11
- OMRRUNXAWXNVFW-UHFFFAOYSA-N fluoridochlorine Chemical compound ClF OMRRUNXAWXNVFW-UHFFFAOYSA-N 0.000 description 10
- 238000001816 cooling Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910003465 moissanite Inorganic materials 0.000 description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B7/00—Cleaning by methods not provided for in a single other subclass or a single group in this subclass
- B08B7/0035—Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/4401—Means for minimising impurities, e.g. dust, moisture or residual gas, in the reaction chamber
- C23C16/4405—Cleaning of reactor or parts inside the reactor by using reactive gases
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/448—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials
- C23C16/4488—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials by in situ generation of reactive gas by chemical or electrochemical reaction
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67017—Apparatus for fluid treatment
- H01L21/67063—Apparatus for fluid treatment for etching
Definitions
- the present invention relates to a cleaning method and apparatus, and an etching method and apparatus.
- the present invention relates to a method and an apparatus for cleaning a semiconductor processing system using an interhalogen fluorine compound gas, and an etching method and an apparatus.
- the semiconductor processing refers to forming a semiconductor layer, an insulating layer, a conductive layer, and the like in a predetermined pattern on an object to be processed such as a semiconductor wafer or an LCD substrate. It means various processes performed to manufacture a semiconductor device and a structure including wiring, electrodes, and the like connected to the semiconductor device.
- inter-halogen fluorine compound gas such as C1F3 is used for cleaning of processing chambers and exhaust pipe systems, and for etching of workpieces.
- I have.
- (Chlorine trifluoride) gases include silicon (Si), polysilicon, amorphous silicon, silicon oxide (Sio2), and silicon nitride. Shi Li co down (S i 3 N 4), data down Gus te down Shi Li Sai de (WS i 2), data in g scan te down switch data emission (T i W), Sani ⁇ data te Le
- C 1 F 3 gas has the advantage that it does not use plasma and, in some cases, has the property of reacting at room temperature.
- C 1 F gas is converted into high-purity liquefied gas in a metal cylinder. Filled and provided to the user site. At the user site, the gaseous phase portion of C 1 F 3 is taken out from Bonbeka, and the vapor pressure at the temperature of Bonbe at that time is reduced to or less than the vapor pressure and sent to each semiconductor manufacturing apparatus.
- C 1 F 3 Since the boiling point of C 1 F 3 is as low as 12 ° C, especially when it is necessary to flow C 1 F 3 gas at a large flow rate, in order to obtain the required gas amount and to prevent re-liquefaction in the middle of piping, It is necessary to precisely control the temperature of the cylinder and the supply piping system.
- C 1 F 3 is extremely corrosive and oxidizing, and has extremely high reactivity especially in the liquid phase. For this reason, there is a limit to the heating of cylinders and pipes from the viewpoint of materials, and heating of cylinders and pipes is not preferable in practical use. In the United States and Europe, there are strict regulations on the storage and transportation of such highly reactive liquefied C 1 F 3 gas, making it a highly desirable cleaning gas. However, its scope is limited.
- C 1 F 3 when used as a cleaning gas, not so high purity is required. As a result, the C1F3 purity required by the user may not be compatible with the manufacturing cost. Further, depending on the treatment, it may be better to mix different components, for example, C 1 F and C 1 F 5 , rather than using only C 1 F 3 as the treatment gas. You. Furthermore, depending on the processing, it may be desired to use C 1 F or C 1 F 5 as a main component. As described above, if it is desired to adjust the gas components in accordance with the treatment, at present, a procedure such as adding a separate process for preparing the treatment gas is required. Disclosure of the invention
- the present invention has been made in view of the problems of the related art, and a cleaning method, apparatus, and etching method for a semiconductor processing system using a fluorine compound gas between halogens.
- the aim is to improve safety, cost, flexibility, etc., in the method and equipment for chucking.
- the present invention that achieves the above object has a basic feature of generating and supplying an inter-halogen fluorine compound gas on-site and on-demand.
- “on-site” means that a mechanism for generating an interhalogen fluorine compound gas is combined with a main processing mechanism of a semiconductor processing system.
- On-demand means that the processing gas can be supplied at the timing according to the request from the main processing mechanism and with the necessary component adjustment.
- a first aspect of the present invention is that Si, Mo, Ta, W, SiOx, SiNx, SiON, SiC, deposited in a processing chamber of a semiconductor processing system.
- SiGe, TaSix, TaOx, WSix, TiC, Tin, TiW, BN, ITO force, group power, by-products containing selected substances A cleaning method for removing objects,
- a first halogen gas other than fluorine and fluorine gas are introduced, and an inert gas is selectively introduced from the third gas source. Mixing these gases to form a mixed gas;
- the mixed gas is passed through a heating reactor to produce the first halogen gas.
- a heating reactor By heating to a temperature at which the gas reacts with the fluorine gas, the product gas is supplied into the processing chamber while generating a product gas containing an interhalogen fluorine compound gas.
- the volume ratio of the first gas, the hydrogen gas, the fluorine gas, and the inert gas in the mixed gas is 10 to 90:10.
- a third aspect of the present invention is the method according to the first or second aspect, wherein the first halogen gas is chlorine gas, and the heating temperature of the mixed gas by the heating reactor is 2 The temperature is between 00 ° C and 400 ° C.
- a fourth aspect of the present invention is the method according to any one of the first to third aspects, wherein the inert gas is a hydrogen gas.
- a fifth aspect of the present invention is that Si, Mo, Ta, W, SiOx, SiNx, SiON, SiC, and S, which are deposited in a processing chamber of a semiconductor processing system. Remove by-products containing substances selected from the group consisting of iGe, TaSix, TaOx, WSix, TiC, TiN, TiW, BN, and ITO Cleaning equipment
- a first halogen gas other than fluorine and a fluorine gas are introduced independently from the first and second gas sources, and an inert gas is selectively introduced from the third gas source. And an upstream portion for forming a mixed gas by mixing gases such as
- the mixed gas is passed through a heating reactor to produce the first halogen gas.
- a heating reactor By heating to a temperature at which the gas reacts with the fluorine gas, a downstream gas for supplying the product gas into the processing chamber while generating a product gas containing an interhalogen fluorine compound gas is produced. Department and,
- the upstream section controls the flow rates of the first halogen gas, the fluorine gas, and the inert gas independently of each other.
- a seventh aspect of the present invention is the apparatus according to the fifth or sixth aspect, wherein the heating reactor comprises: a reaction chamber; and an upstream pipe for introducing the mixed gas into the reaction chamber.
- the chamber and the upstream pipe are made of a material having high heat conductivity and high corrosion resistance to the generated gas, and the upstream pipe forms a heat exchange section by being wound around the periphery, and the heat exchange section Is heated from the surroundings by the heater.
- a semiconductor processing system for etching a first film which is substantially made of a substance selected from the group consisting of Si, SIPOSTa, and TaSix, on an object to be processed. Etching method,
- the mixed gas is passed through a heating reactor to produce the first halogen gas.
- a heating reactor By heating to a temperature at which the gas reacts with the fluorine gas, the product gas is supplied into the processing chamber while generating a product gas containing an interhalogen fluorine compound gas.
- the object further comprises: Si x2, SiNx, SiON, TaOx, and a photo register.
- a second film substantially consisting of a substance selected from the group, and the etching method is to selectively etch the first film with respect to the second film.
- a first film on a workpiece which is made of a material selected from the group consisting of Si, SIPOS, Ta, and TaSix.
- An etching apparatus for a semiconductor processing system wherein:
- a processing chamber for accommodating the object to be processed
- a first non-fluorine gas and a fluorine gas other than fluorine are introduced, and an inert gas is selectively introduced from a third gas source.
- an upstream portion for forming a mixed gas by mixing gases such as
- a heating reactor By passing the mixed gas through a heating reactor and heating it to a temperature at which the first halogen gas and the fluorine gas react, a product gas containing an interhalogen fluorine compound gas is generated.
- the heating reactor includes a reaction chamber and the mixed gas in the reaction chamber.
- An upstream pipe to be introduced wherein the reaction chamber and the upstream pipe are made of a material having high thermal conductivity and high corrosion resistance to the generated gas, and the upstream pipe is wound around the periphery.
- the heat exchange part is formed, and the heat exchange part is heated from the surroundings by the heater.
- FIG. 1 is a schematic diagram showing a cleaning device for removing by-products deposited in a processing chamber of a semiconductor processing system according to an embodiment of the present invention.
- FIG. 2 is a schematic view showing an etching apparatus of a semiconductor processing system according to another embodiment of the present invention.
- FIG. 3 is a perspective view showing a combined structure of a heating reactor and a cooler that can be used in the apparatuses shown in FIGS. 1 and 2.
- FIG. 4 is a sectional view showing an internal structure of a main part of the heating reactor shown in FIG.
- FIG. 1 is a schematic diagram showing a cleaning apparatus for removing by-products deposited in a processing chamber of a semiconductor processing system according to an embodiment of the present invention.
- the cleaning device 30 is connected to a CVD device 10 for forming a silicon film on a substrate to be processed, such as a semiconductor wafer or an LCD substrate.
- the CVD apparatus 10 includes a processing chamber 12 for storing a substrate to be processed.
- a mounting table 14 for mounting a substrate to be processed is provided in the processing chamber 12.
- An exhaust system 16 is connected to the lower part of the processing chamber 12 to evacuate the interior and set a vacuum. It is. Further, a supply system 18 for supplying a processing gas such as SiH 4 is connected to an upper portion of the processing chamber 12.
- the cleaning device 30 includes first, second, and third gas sources 3 for supplying chlorine (C 12) gas, fluorine (F 2) gas, and inert gas, respectively. 2, 3, 4 and 36.
- the chlorine gas source 32 consists of a cylinder filled with liquefied gas. Chlorine gas is relatively easy to supply due to its high vapor pressure.
- the fluorine gas source 34 consists of a gas generator that generates fluorine gas by electrolysis. Fluorine gas can also be supplied as a high-pressure gas in a cylinder.
- the inert gas functions as a diluent gas or a carrier gas
- any inactive gas such as helium, argon, or nitrogen can be used.
- an inert gas is not used, that is, the inert gas is selectively introduced.
- Chlorine gas, fluorine gas, and inert gas from the first, second, and third gas sources 32, 34, and 36 are respectively MFCs (mass flow controllers).
- Flow rate through 38a, 38b, 38c Are introduced independently of each other and controlled.
- the chlorine gas, the fluorine gas, and the inert gas, which have been independently introduced in this manner, are joined and mixed in the pipe section 42 to form a mixed gas.
- the volume ratio of chlorine gas, fluorine gas, and inert gas in the mixed gas is set to 10 to 90: 10 to 90: 0 to 90.
- the gas mixture thus formed is passed through a heating reactor 44, for example, a heat exchanger, where the temperature is between 200 ° C and 400 ° C, preferably between 250 ° C and 350 ° C. Heated to ° C.
- a heating reactor 44 for example, a heat exchanger
- the temperature is between 200 ° C and 400 ° C, preferably between 250 ° C and 350 ° C. Heated to ° C.
- the chlorine gas and the fluorine gas react with each other to generate a product gas containing a chlorine fluoride gas such as a C 1 F 3 gas.
- a product gas containing C 1 F 3 gas as a main component and other chlorine fluoride gas (C 1 F, C 1 F 5 etc.), by-products, unreacted gas, etc. is cooled by a cooler 46. After cooling to about room temperature where C 1 F 3 does not liquefy, C 1 F 3 is taken out at such a pressure that it does not liquefy.
- the product gas exiting the cooler 46 is first passed through an analyzer 48 for measuring the interhalogen fluorine compound.
- the measurement result obtained by the analyzer 48 is fed to the main controller 52, and the MFC 38a, 38b, 38c is controlled based on the result. c By this, the volume ratio of chlorine gas, fluorine gas, and inert gas in the mixed gas is adjusted to be a predetermined value.
- the buffer section 54 is used for temporary liquefaction of the generated gas and subsequent re-vaporization. It can also be configured as a storage unit. As a result, the unreacted volatile gas, by-product gas, and impurity gas can be removed from the generated gas in the buffer section 54, and the solid substance can be removed. .
- Chlorine fluoride gas such as C 1 F 3 gas in the generated gas supplied to the processing chamber 12 mainly contains Si deposited on the inner wall of the processing chamber 12 and the inner wall of the piping of the exhaust system 16. Reacts with the by-products produced and separates them from the inner wall. The exfoliated by-products are taken out of the CVD apparatus 10 by the exhaust flow generated by the operation of the exhaust system 16.
- the cleaning device 30 is shown in combination with the silicon CVD device 10, but the chlorine fluoride gas is supplied from silicon (polysilicon). It is also effective when removing substances other than corn and amorphous silicon. Specifically, substances other than silicon here include Mo, Ta, W, SiOx, SiNX, SiON, SiC, SiGe. , TaSix, TaOx, WSix, TiC, Tin, TiW, BN, ITO (indium tin oxide) and the like. Therefore, the cleaning device 30 is a CVD device or an etching device in which by-products containing a substance selected from the group consisting of the above-listed substances are produced by the original processing. It can be effectively applied to the clear jung, etc.
- Nickel heated to 250 ° C to 350 ° C by forming a mixed gas consisting of 30 SCCM chlorine gas, 100 SCCM fluorine gas, and 100 SCCM hydrogen gas Made of heat exchanger The system was continuously supplied to the heating reactor 44 at a system pressure of 836 Torr. As a result, near the exit of the heating reactor 4 4, C 1 F concentration of 3 1 0% to 3 0%, C 1 F 3 yield of 6 0% to 80% of the product gas is obtained It turned out that it could be done.
- FIG. 2 is a schematic diagram showing an etching apparatus of a semiconductor processing system according to another embodiment of the present invention.
- the etching apparatus 60 preferentially etches a Si film over a SiO 2 film on a substrate to be processed such as a semiconductor wafer or an LCD substrate (selective etching). Used to
- the etching apparatus 60 includes a processing chamber 62 for storing a substrate to be processed.
- a mounting table 64 for mounting a substrate to be processed is provided.
- An exhaust system 66 for exhausting the inside and setting a vacuum is connected to the lower part of the processing chamber 62.
- a supply system 70 for supplying an etching gas is connected to an upper portion of the processing chamber 62.
- the supply system 70 of the etching device 60 has the same configuration as the cleaning device 30 shown in FIG.
- the supply system 70 is composed of chlorine (Cl 2 ) gas, fluorine (F
- first, second, and third gas sources 72, 74, 76 for supplying gas and inert gas, respectively.
- the first, second, and third gas sources 72, 74, and 76 gas, chlorine gas, fluorine gas, and inert gas are supplied to the MFC (mass flow controller), respectively.
- the chlorine gas, fluorine gas, and inert gas thus introduced independently of each other are: They are joined and mixed in the pipe section 82 to form a mixed gas.
- the volume ratio of chlorine gas, fluorine gas, and inert gas in the mixed gas is set to 10 to 90: 10 to 90: 0 to 90.
- the gas mixture thus formed is passed through a heating reactor 84, for example, a heat exchanger, where the temperature is between 200 ° C and 400 ° C, preferably between 250 ° C and 35 ° C. Heated to 0 ° C.
- the chlorine gas reacts with the fluorine gas to generate a product gas containing a chlorine fluoride gas such as C 1 F 3 gas.
- the generated gas containing C 1 F 3 gas as a main component and other chlorine fluoride gas (C 1 F, C 1 F 5 etc.), by-products, unreacted gas, etc. is cooled.
- the C 1 F 3 is removed at such a pressure that the C 1 F 3 is not liquefied.
- the product gas exiting the cooler 86 is first passed through an analyzer 88 for measuring interhalogen fluorine compounds.
- the measurement result obtained by the analyzer 88 is fed back to the main controller 92, and based on this, the MFC 78a, 78b, and 78c force control is performed. You. Thereby, the volume ratio of chlorine gas, fluorine gas, and inert gas in the mixed gas is adjusted to be a predetermined value.
- the generated gas flows into the processing chamber 12 after the flow rate and pressure are adjusted in the buffer section 94 so as to meet the conditions of the processing chamber 12 of the CVD apparatus 10.
- the buffer unit 94 can be configured as a temporary storage unit for performing liquefaction of the generated gas and subsequent re-evaporation.
- unreacted volatile gas and by-product As well as removing gas and impurity gas, solid substances can be removed.
- Chlorine fluoride gas such as C 1 F 3 gas in the generated gas supplied into the processing chamber 62 reacts preferentially with the Si film over the Si 0 2 film on the substrate to be processed. Etching this.
- the etching product is discharged to the outside of the etching device 60 along the exhaust stream generated by the operation of the exhaust system 66.
- the etching apparatus 60 selectively etches the first film made of the Si film on the substrate to be processed with respect to the second film made of the SiO 2 film.
- chlorine fluoride gas is also effective in 3 1 film and 3 1 0 2 film and the selection et etching combination of substances other than unions Align the.
- the first film to be preferentially etched substantially consists of a material selected from the group consisting of Si, SIPOS (semi-insulating polycrystalline silicon), Ta, and TaSix. be able to.
- the second film that is not preferentially etched is substantially composed of a material selected from the group consisting of Si ⁇ 2, SiNx, SiON, TaOx, and a photo resist. It becomes possible to become.
- a chlorine gas, a fluorine gas, and an inert gas are used as gas sources at a user site. It can generate and supply chlorine fluoride gas such as gas. Therefore, it is possible to solve operational and legal regulation problems when providing chlorine fluoride gas such as C 1 F 3 gas as a liquefied gas to a user's site using a bomb. .
- these devices 30 and 60 the volume ratio of chlorine gas, fluorine gas, and inert gas in the mixed gas can be set to any value within the above range, or the heating temperature of the mixed gas can be set to any value within the above range. By doing so, the composition of the generated gas can be adjusted according to the treatment.
- halogen gas other than fluorine
- another type of halogen can be obtained.
- inter-gen fluorine compound gas for example, if bromine (Br 2 ) gas is used as the gas of the first gas source 32, the product gas containing at least one of Br F, Br F 3, and Br F 5 Can be supplied.
- the first gas source 3 2 gas using iodine (1 2) gas, IF, the IF 3, IF 5, least for the product gas also contains one of the IF 7 Can be supplied.
- FIG. 3 is a perspective view showing a combined structure of the heating reactor 102 and the cooling device 122.
- FIG. 4 is a cross-sectional view showing an internal structure of a main part of the heating reactor 102.
- the heating reactor 102 and the cooling unit 122 are connected to the heating reactor 44 and the cooling unit 46 of the apparatus shown in FIG. 1 or the heating reactor 84 and the cooling unit 8 of the apparatus shown in FIG. It becomes usable as 6.
- the heating reactor 102 includes a reaction chamber 104 formed by an egg-shaped casing and having first and second ports 105a and 105b.
- the first port 105a is equipped with chlorine gas and fluorine
- An upstream pipe 106 for introducing a mixed gas of a gas and an inert gas is connected.
- the second port 105 b is connected to the downstream pipe 108 for sending out the gas generated in the reaction chamber 104 c .
- a buffer member 112 is provided in 104.
- the nozzle member 112 is made of a sphere, and is fixed to the inner surface of the reaction chamber 104 by welding via an appropriate spacer 113.
- the reaction chamber 104, the tubes 106, 108, the noodle member 112, and the spacer 113 are made of a material having high thermal conductivity and high corrosion resistance to C 1 F 3, for example. , N i.
- the upstream pipe 106 is wound around the reaction chamber 104 to form a heat exchange section 114.
- the entire heat exchange section 114 is covered with a jacket heater 116 and heated from the surroundings.
- the jacket heater 116 is an electrically controlled cloth heater in which a resistance heating gland is embedded in a heat-resistant nonwoven fabric.
- the cooler 122 has a coil part 124 in which a downstream pipe 108 is spirally wound.
- the coiler section 124 is housed in a cylindrical casing 126, and a fan 128 is provided at the lower end opening. That is, the cooler 122 has an air-cooled structure that cools the gas in the coil part 124 to about room temperature by a fan.
- C The heating reactor 102 shown in FIG. 3 and FIG. According to this, the heat exchange section 114 is integrally formed around the reaction chamber 104. The downsizing of the reactor and good thermal efficiency can be obtained.
- a product gas containing an interhalogen fluorine compound gas can be supplied on-site and on-demand. It is possible to improve the safety, cost, flexibility, etc. of the ing method and apparatus and the etching method and apparatus.
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Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01954400A EP1460678A4 (en) | 2001-07-31 | 2001-07-31 | CLEANING METHOD AND APPARATUS AND METHOD AND APPARATUS FOR ETCHING |
| PCT/JP2001/006604 WO2003012843A1 (fr) | 2001-07-31 | 2001-07-31 | Procede et appareil de nettoyage et procede et appareil de gravure |
| US10/485,721 US20050020071A1 (en) | 2001-07-31 | 2001-07-31 | Method and apparatus for cleaning and method and apparatus for etching |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2001/006604 WO2003012843A1 (fr) | 2001-07-31 | 2001-07-31 | Procede et appareil de nettoyage et procede et appareil de gravure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2003012843A1 true WO2003012843A1 (fr) | 2003-02-13 |
Family
ID=11737608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2001/006604 WO2003012843A1 (fr) | 2001-07-31 | 2001-07-31 | Procede et appareil de nettoyage et procede et appareil de gravure |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20050020071A1 (ja) |
| EP (1) | EP1460678A4 (ja) |
| WO (1) | WO2003012843A1 (ja) |
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| KR100804853B1 (ko) * | 1999-03-04 | 2008-02-20 | 서페이스 테크놀로지 시스템스 피엘씨 | 삼불화염소가스발생기시스템 |
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- 2001-07-31 WO PCT/JP2001/006604 patent/WO2003012843A1/ja active Application Filing
- 2001-07-31 US US10/485,721 patent/US20050020071A1/en not_active Abandoned
- 2001-07-31 EP EP01954400A patent/EP1460678A4/en not_active Withdrawn
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| JPS59176639U (ja) * | 1983-05-16 | 1984-11-26 | 日本電信電話株式会社 | 反応性液体容器 |
| JPH06333854A (ja) * | 1993-05-21 | 1994-12-02 | Nippon Steel Corp | 成膜装置 |
| JP2001189273A (ja) * | 1999-12-28 | 2001-07-10 | Toshiba Corp | 半導体処理装置のクリーニング方法および半導体処理装置 |
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| US7357138B2 (en) | 2002-07-18 | 2008-04-15 | Air Products And Chemicals, Inc. | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
| EP1538235A1 (en) * | 2003-11-26 | 2005-06-08 | Air Products And Chemicals, Inc. | Method for etching high dielectric constant materials and for cleaning deposition chambers for high dielectric constant materials |
| JP2014154865A (ja) * | 2013-02-14 | 2014-08-25 | Central Glass Co Ltd | クリーニングガス及びクリーニング方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1460678A4 (en) | 2010-01-06 |
| EP1460678A1 (en) | 2004-09-22 |
| US20050020071A1 (en) | 2005-01-27 |
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