[go: up one dir, main page]

WO2003010136A1 - Complexes organometalliques, catalyseurs les contenant et procede de preparation d'esters carboxyliques - Google Patents

Complexes organometalliques, catalyseurs les contenant et procede de preparation d'esters carboxyliques Download PDF

Info

Publication number
WO2003010136A1
WO2003010136A1 PCT/JP2002/007051 JP0207051W WO03010136A1 WO 2003010136 A1 WO2003010136 A1 WO 2003010136A1 JP 0207051 W JP0207051 W JP 0207051W WO 03010136 A1 WO03010136 A1 WO 03010136A1
Authority
WO
WIPO (PCT)
Prior art keywords
same
carboxylic esters
organometallic complexes
alkyl
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2002/007051
Other languages
English (en)
Japanese (ja)
Inventor
Yasushi Kuroda
Tetsuo Nakajo
Keiji Maruoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Holdings Corp
Original Assignee
Showa Denko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Denko KK filed Critical Showa Denko KK
Publication of WO2003010136A1 publication Critical patent/WO2003010136A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2252—Sulfonate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2252—Sulfonate ligands
    • B01J31/2256—Sulfonate ligands being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/26—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/32—Gallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/33—Indium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne des complexes organométalliques représentés par la formule générale (1), pouvant être utilisés avec avantage dans les systèmes de synthèse d'esters carboxyliques à partir d'aldéhydes, par exemple, la réaction de Tischenko. Dans cette formule, M représente un atome de métal, R représente un groupe C1-8 alkyle éventuellement ramifié ou un groupe aromatique ou aralkyle éventuellement substitué, L représente un groupe organique, contenant un ou plusieurs cycles aromatiques, pouvant former un cycle composé de cinq à sept éléments, X, Y et M compris, et X et Y représentent chacun, de façon indépendante, -O-, un groupe -NR1-, -N(SO2R2)-, ou analogue (sous réserve des cas dans lesquels X et Y sont identiques), R1 représentant éventuellement un groupe C¿1-8? alkyle éventuellement ramifié qui peut être halogéné et R?2¿ représentant un groupe C¿1-10? alkyle éventuellement ramifié pouvant être halogéné.
PCT/JP2002/007051 2001-07-25 2002-07-11 Complexes organometalliques, catalyseurs les contenant et procede de preparation d'esters carboxyliques Ceased WO2003010136A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001223862 2001-07-25
JP2001-223862 2001-07-25
JP2001-292276 2001-09-25
JP2001292276A JP2003104953A (ja) 2001-07-25 2001-09-25 有機金属錯体化合物および該化合物を用いたカルボン酸エステル製造方法

Publications (1)

Publication Number Publication Date
WO2003010136A1 true WO2003010136A1 (fr) 2003-02-06

Family

ID=26619210

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/007051 Ceased WO2003010136A1 (fr) 2001-07-25 2002-07-11 Complexes organometalliques, catalyseurs les contenant et procede de preparation d'esters carboxyliques

Country Status (3)

Country Link
JP (1) JP2003104953A (fr)
CN (1) CN1464875A (fr)
WO (1) WO2003010136A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004047990A1 (fr) * 2002-11-27 2004-06-10 Showa Denko K. K. Catalyseur destines a la preparation d'esters carboxyliques et processus de preparation d'esters carboxyliques avec ce catalyseur
CN109331875A (zh) * 2018-11-14 2019-02-15 山西大学 一种双核镁金属催化剂及其制备方法和应用

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116874411B (zh) * 2023-07-13 2024-04-16 西安欧得光电材料有限公司 一种1-溴咔唑的合成方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3920444A (en) * 1970-12-21 1975-11-18 Minnesota Mining & Mfg Method comprising the use of N-substituted perfluoroalkyanesulfonamides as herbicidal and plant growth modifying agents, and composition
JPS55108430A (en) * 1979-02-13 1980-08-20 Japan Synthetic Rubber Co Ltd Rubber composition
JPH05230133A (ja) * 1992-02-19 1993-09-07 Mitsui Toatsu Chem Inc オレフィンの重合触媒及びそれを用いたポリオレフィンの製造方法
JPH05295023A (ja) * 1992-04-24 1993-11-09 Mitsui Toatsu Chem Inc オレフィンの重合用固体触媒及びそれを用いたポリオレフィンの製造方法
DE4238233A1 (de) * 1992-11-12 1994-05-19 Fahlberg List Pharma Gmbh N-Sulfonyl-aminophenole, ihre Verwendung als pharmazeutische Wirkstoffe und sie enthaltende Arzneimittel
US5591848A (en) * 1994-10-07 1997-01-07 The Penn State Research Foundation Spiroconjugated charge-transfer dyes for optical applications
WO1998012190A2 (fr) * 1996-09-11 1998-03-26 Krenitsky Pharmaceutical, Inc. Composes constituant pharmacologiquement des principes actifs et leur utilisation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3920444A (en) * 1970-12-21 1975-11-18 Minnesota Mining & Mfg Method comprising the use of N-substituted perfluoroalkyanesulfonamides as herbicidal and plant growth modifying agents, and composition
JPS55108430A (en) * 1979-02-13 1980-08-20 Japan Synthetic Rubber Co Ltd Rubber composition
JPH05230133A (ja) * 1992-02-19 1993-09-07 Mitsui Toatsu Chem Inc オレフィンの重合触媒及びそれを用いたポリオレフィンの製造方法
JPH05295023A (ja) * 1992-04-24 1993-11-09 Mitsui Toatsu Chem Inc オレフィンの重合用固体触媒及びそれを用いたポリオレフィンの製造方法
DE4238233A1 (de) * 1992-11-12 1994-05-19 Fahlberg List Pharma Gmbh N-Sulfonyl-aminophenole, ihre Verwendung als pharmazeutische Wirkstoffe und sie enthaltende Arzneimittel
US5591848A (en) * 1994-10-07 1997-01-07 The Penn State Research Foundation Spiroconjugated charge-transfer dyes for optical applications
WO1998012190A2 (fr) * 1996-09-11 1998-03-26 Krenitsky Pharmaceutical, Inc. Composes constituant pharmacologiquement des principes actifs et leur utilisation

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
ANCHISI CARLO ET AL.: "Studies on the synthesis of heterocyclic compounds", J. HETEROCYCL. CHEM., vol. 13, no. 5, 1976, pages 1033 - 1036, XP002957699 *
ANDRAE K. ET AL.: "1,2-Phenyleneoxothio 3d-element compounds", Z. ANORG. ALLG. CHEM., vol. 498, 1983, pages 199 - 204, XP002957698 *
HANSON G. ET AL.: "Convenient routes of 4,4''-functionalized o-terphenyls and 2,2''-functionalized biphenyls", J. ORG.CHEM., vol. 46, no. 26, 1981, pages 5441 - 5443, XP002959801 *
STEGMANN HARTMUT B. ET AL.: "Transformation of 2,2-diphenyl-2-fluor-2,3-dihydro-1,3,2-benzoxazaphospholen", PHOSPHORUS SULFUR, vol. 8, no. 1, 1980, pages 59 - 66, XP002959802 *
TSUTOMU ISHIKAWA ET AL.: "Anomalous substituent effects in the bischler-napieralski reaction of 2-aryl aromatic formamides", JOURNAL OF ORGANIC CHEMISTRY, vol. 65, no. 26, 2000, pages 9143 - 9151, XP002957700 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004047990A1 (fr) * 2002-11-27 2004-06-10 Showa Denko K. K. Catalyseur destines a la preparation d'esters carboxyliques et processus de preparation d'esters carboxyliques avec ce catalyseur
CN109331875A (zh) * 2018-11-14 2019-02-15 山西大学 一种双核镁金属催化剂及其制备方法和应用

Also Published As

Publication number Publication date
CN1464875A (zh) 2003-12-31
JP2003104953A (ja) 2003-04-09

Similar Documents

Publication Publication Date Title
WO1997028897A1 (fr) Systeme catalyseur d'oxydation et processus d'oxydation faisant appel a ce systeme
AU3670100A (en) Catalyst for production of acetic acid or acetic acid and ethyl acetate, processfor its production and process for production of acetic acid or acetic acid and ethyl acetate using it
ATE221522T1 (de) Verfahren zur herstellung von citalopram
CA2312351A1 (fr) Catalyseur d'acetate de vinyle, contenant du palladium, de l'or, du cuivre et un quatrieme metal
WO2005105863A3 (fr) Ligands metallocenes, composes metallocenes et catalyseurs metallocenes, leur synthese et leur utilisation pour la polymerisation d'olefines
EP1918268A3 (fr) Promoteurs de catalyseurs pour la fabrication de trifluoroiodométhane et pentafluoroiodoéthane
CA2466907A1 (fr) Complexes activateurs de catalyseurs de polymerisation et leur utilisation dans un processus de polymerisation
EP1013674B8 (fr) Catalyseur de polymérisation d'oléfine et procédé de polymérisation d'oléfine utilisant ce catalyseur
SG90762A1 (en) Catalyst component for addition polymerization, catalyst for addition polymerization, and process for producing addition polymer
WO2001000685A3 (fr) Complexes mixtes d'acoxydes metalliques et catalyseurs de polymerisation en etant faits
TW371652B (en) Oxidation process of branched aliphatic hydrocarbons and process for producing the oxide
WO2003010136A1 (fr) Complexes organometalliques, catalyseurs les contenant et procede de preparation d'esters carboxyliques
BR9806471A (pt) Catalisador de prata para a produção de óxido de etileno, método para a produção do catalisador, e método para produção de óxido de etileno.
EG23512A (en) Catalyst complex for catalysing esterification andtrans-esterification reactions and process for esterification trans esterification using the same
AU3813700A (en) Bimetal catalyst for the (co)polymerization of alpha-olefins
CA2234110A1 (fr) Composition de resine photosensible
CA2080429A1 (fr) Procede pour la preparation d'hydroxyphenylcarboxylates
WO2004018529A3 (fr) Catalyseur de ziegler modifie, procede pour sa preparation et procede pour preparer une poly-1-olefine en sa presence
MY127013A (en) Catalysis with titanium oxides
RU2007114583A (ru) Соединение, имеющее структуру пирохлора, и его использование в качестве носителя катализатора в реакции конверсии водяного газа
CA2274132A1 (fr) Acides carboxyliques a complexes metalliferes macrocycliques, leur utilisation et procede permettant de les preparer
TWI256400B (en) Polyesters with good color tone, process for producing the same and use thereof
ATE261422T1 (de) Verfahren zur herstellung von cephem-verbindungen
EP0234917A3 (fr) Préparation de polyesters aromatiques gris à bleus par incorporation de cobalt dans le système de catalyseur
EP1396503A4 (fr) Composant de catalyseur solide pour polymerisation d'olefine

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BY BZ CA CH CN CO CR CU CZ DE DM DZ EC EE ES FI GB GD GE GH HR HU ID IL IN IS KE KG KR KZ LC LR LS LT LU LV MA MD MG MK MN MX MZ NO NZ OM PH PL PT RO RU SE SG SI SK SL TJ TM TN TR TT TZ UG US UZ VN YU ZA ZM

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS KE KG KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ UG ZM ZW AM AZ BY KG KZ RU TJ TM AT BE BG CH CY CZ DK EE ES FI FR GB GR IE IT LU MC PT SE SK TR BF BJ CF CG CI GA GN GQ GW ML MR NE SN TD TG

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LU MC NL PT SE SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 028024338

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase