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WO2003002691A1 - Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques - Google Patents

Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques Download PDF

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Publication number
WO2003002691A1
WO2003002691A1 PCT/EP2002/007078 EP0207078W WO03002691A1 WO 2003002691 A1 WO2003002691 A1 WO 2003002691A1 EP 0207078 W EP0207078 W EP 0207078W WO 03002691 A1 WO03002691 A1 WO 03002691A1
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
pyrolysis
catalyst
cracking
heat transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/007078
Other languages
German (de)
English (en)
Other versions
WO2003002691A8 (fr
Inventor
Wolfgang Krumm
Günter Funk
Stefan Hamel
Christian Mertens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Herhof Umwelttechnik GmbH
Original Assignee
Herhof Umwelttechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10228100A external-priority patent/DE10228100B4/de
Application filed by Herhof Umwelttechnik GmbH filed Critical Herhof Umwelttechnik GmbH
Priority to EP02754763A priority Critical patent/EP1399527B1/fr
Publication of WO2003002691A1 publication Critical patent/WO2003002691A1/fr
Publication of WO2003002691A8 publication Critical patent/WO2003002691A8/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/32—Devices for distributing fuel evenly over the bed or for stirring up the fuel bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/485—Entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/008—Reducing the tar content by cracking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/006—General arrangement of incineration plant, e.g. flow sheets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606—Combustion processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/30—Pyrolysing
    • F23G2201/301—Treating pyrogases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/30—Pyrolysing
    • F23G2201/304—Burning pyrosolids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/40—Gasification
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2203/00—Furnace arrangements
    • F23G2203/50—Fluidised bed furnace
    • F23G2203/502—Fluidised bed furnace with recirculation of bed material inside combustion chamber

Definitions

  • a further advantageous development is characterized in that a fine fraction is separated from the organic substances before pyrolysis, in particular is sieved off.
  • the fine fraction can also be separated in another way.
  • the screened or otherwise separated fine fraction is preferably fed to the combustion reactor.
  • the screening or other separation and / or the feeding of the fine fraction to the combustion reactor are particularly advantageous when processing Dry Stabilate ® . Since the fine fraction of the dry stabilate ® contains an increased proportion of inert substances (ash) and pollutants, this is preferably sieved off or otherwise separated off. It is also preferably fed directly to the fluidized bed reactor for further treatment.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L'invention concerne un procédé pour pyrolyser et gazéifier des mélanges de matières à composants organiques. Les matières organiques ou le mélange de matières à composants organiques sont mis en contact avec un caloporteur, de préférence de la cendre d'un réacteur à combustion, et ils sont pyrolysés dans un réacteur de pyrolyse, de préférence un réacteur à cuve. Le coke de pyrolyse ainsi obtenu est brûlé dans un réacteur de combustion, de préférence un réacteur à lit fluidisé, avec apport d'air. Les éléments condensables du gaz brut généré par la pyrolyse sont craqués dans un réacteur de craquage, de préférence un catalyseur. Afin de perfectionner ce procédé, le caloporteur est transporté par de la vapeur d'eau (50) surchauffée servant de milieu de fluidification.
PCT/EP2002/007078 2001-06-27 2002-06-26 Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques Ceased WO2003002691A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP02754763A EP1399527B1 (fr) 2001-06-27 2002-06-26 Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10131008 2001-06-27
DE10131008.0 2001-06-27
DE10228100A DE10228100B4 (de) 2001-06-27 2002-06-24 Verfahren und Vorrichtung zur Pyrolyse und Vergasung von Stoffgemischen, die organische Bestandteile enthalten
DE10228100.9 2002-06-24

Publications (2)

Publication Number Publication Date
WO2003002691A1 true WO2003002691A1 (fr) 2003-01-09
WO2003002691A8 WO2003002691A8 (fr) 2003-09-25

Family

ID=26009592

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/007078 Ceased WO2003002691A1 (fr) 2001-06-27 2002-06-26 Procede et dispositif pour pyrolyser et gazeifier des melanges de matieres a composants organiques

Country Status (2)

Country Link
EP (1) EP1399527B1 (fr)
WO (1) WO2003002691A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008058347A1 (fr) * 2006-11-17 2008-05-22 Millennium Synfuels, Llc Fabrication de combustibles
ITAV20090001A1 (it) * 2009-04-29 2010-10-30 Protodesign Srl Processo ibrido di pirolisi e gassificazione per la conversione di un generico rifiuto in un combustibile gassoso(un particolare combustibile da rifiuto - c.d.r.) a basso impatto ambientale
CN102838453A (zh) * 2012-08-28 2012-12-26 华北电力大学 一种利用焦炭催化热解生物质制备酚类有机混合物的方法
WO2016134794A1 (fr) * 2015-02-27 2016-09-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V. Huile de pyrolyse et procédé et système de production d'huile de pyrolyse
WO2018007205A1 (fr) * 2016-07-06 2018-01-11 Basf Se Procédé de production parallèle de gaz de synthèse, de carbone, et de charbon résiduel à faible teneur en polluants à partir de lignite
CN109722311A (zh) * 2019-02-20 2019-05-07 程石 一种用流化床热裂解可燃固体废弃物制燃气的装置及方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2448354A1 (de) 1974-10-10 1976-04-22 Bergwerksverband Gmbh Verfahren und vorrichtung zur erzeugung von gas, teer und dampf aus kohle
GB1484130A (en) 1974-10-25 1977-08-24 Kunii D Pyrolytic process and apparatus for solid waste disposal
DE19629289A1 (de) 1996-07-19 1998-01-22 Umsicht Inst Fuer Umwelt Siche Siphon zur Förderung feinkörniger Feststoffe
DE19755693C1 (de) * 1997-12-16 1999-07-29 Dmt Gmbh Verfahren zur Vergasung von organischen Stoffen und Stoffgemischen
DE19930071A1 (de) * 1999-06-30 2001-02-22 Wolfgang Krumm Verfahren und Vorrichtung zur Pyrolyse und Vergasung von organischen Stoffen und Stoffgemischen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2448354A1 (de) 1974-10-10 1976-04-22 Bergwerksverband Gmbh Verfahren und vorrichtung zur erzeugung von gas, teer und dampf aus kohle
GB1484130A (en) 1974-10-25 1977-08-24 Kunii D Pyrolytic process and apparatus for solid waste disposal
DE19629289A1 (de) 1996-07-19 1998-01-22 Umsicht Inst Fuer Umwelt Siche Siphon zur Förderung feinkörniger Feststoffe
DE19755693C1 (de) * 1997-12-16 1999-07-29 Dmt Gmbh Verfahren zur Vergasung von organischen Stoffen und Stoffgemischen
DE19930071A1 (de) * 1999-06-30 2001-02-22 Wolfgang Krumm Verfahren und Vorrichtung zur Pyrolyse und Vergasung von organischen Stoffen und Stoffgemischen

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008058347A1 (fr) * 2006-11-17 2008-05-22 Millennium Synfuels, Llc Fabrication de combustibles
ITAV20090001A1 (it) * 2009-04-29 2010-10-30 Protodesign Srl Processo ibrido di pirolisi e gassificazione per la conversione di un generico rifiuto in un combustibile gassoso(un particolare combustibile da rifiuto - c.d.r.) a basso impatto ambientale
CN102838453A (zh) * 2012-08-28 2012-12-26 华北电力大学 一种利用焦炭催化热解生物质制备酚类有机混合物的方法
CN102838453B (zh) * 2012-08-28 2014-08-20 华北电力大学 一种利用焦炭催化热解生物质制备酚类有机混合物的方法
WO2016134794A1 (fr) * 2015-02-27 2016-09-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V. Huile de pyrolyse et procédé et système de production d'huile de pyrolyse
US11066604B2 (en) 2015-02-27 2021-07-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Pyrolysis oil and method and system for the production thereof
US11891572B2 (en) 2015-02-27 2024-02-06 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Pyrolysis oil and method and system for the production thereof
WO2018007205A1 (fr) * 2016-07-06 2018-01-11 Basf Se Procédé de production parallèle de gaz de synthèse, de carbone, et de charbon résiduel à faible teneur en polluants à partir de lignite
CN109722311A (zh) * 2019-02-20 2019-05-07 程石 一种用流化床热裂解可燃固体废弃物制燃气的装置及方法

Also Published As

Publication number Publication date
EP1399527A2 (fr) 2004-03-24
EP1399527B1 (fr) 2013-02-20
WO2003002691A8 (fr) 2003-09-25

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