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WO2003070795B1 - Copolymers comprising isobutylene type and acrylate type monomers - Google Patents

Copolymers comprising isobutylene type and acrylate type monomers

Info

Publication number
WO2003070795B1
WO2003070795B1 PCT/US2003/003983 US0303983W WO03070795B1 WO 2003070795 B1 WO2003070795 B1 WO 2003070795B1 US 0303983 W US0303983 W US 0303983W WO 03070795 B1 WO03070795 B1 WO 03070795B1
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
copolymer
branched
composition
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/003983
Other languages
French (fr)
Other versions
WO2003070795A1 (en
Inventor
Simion Coca
Gregory J Mccollum
James B O'dwyer
Edward R Coleridge
Steven V Barancyk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
PPG Industries Ohio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/077,645 external-priority patent/US6784248B2/en
Priority claimed from US10/348,230 external-priority patent/US20040143079A1/en
Application filed by PPG Industries Ohio Inc filed Critical PPG Industries Ohio Inc
Priority to AU2003215144A priority Critical patent/AU2003215144A1/en
Publication of WO2003070795A1 publication Critical patent/WO2003070795A1/en
Publication of WO2003070795B1 publication Critical patent/WO2003070795B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0209—Multistage baking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/007—Processes for applying liquids or other fluent materials using an electrostatic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)

Abstract

A composition that includes a non-gelled copolymer that contains residues having structural units (Formula I) where n is an integer from 1 to 10,000; R1 is linear or branched C1 to C4 alkyl; R2 is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl, and R3 is a group resulting from a post polymerization reaction selected from transesterification, transamidification and hydrolysis with a compound selected from hydroxy functional compounds and amine functional compounds. The compositionmay contain co-reactive functional groups and may be a thermosetting composition. A substrate may be coated with the thermosetting composition singly or as part of a multi-layer composite coating that includes a base coat layer and a substantially pigment free top coat layer.

Claims

AMENDED CLAIMS
[received by the International Bureau on 09 Septembre 2003 (09.09.03); original claim 1 replaced by new claim 1 (2 pages)]
oxyalkalene, R1S is selected from hydrogen, Cx to C4 alkyl, -OH, -OR7 and -C(0)-R7, R17 is a radical derived from polyethylene glycol, polypropylene glycol and mixtures thereof, p and q are each independently from 0 to 6 and the sum of p+q is at least 2 and not more than 8, each occurrence of R9 is independently selected from hydrogen and Cx to C4 alkyl, and X is an anion derived from one or more organic or inorganic acids; wherein at least one occurrence of R3 comprises a reactive functional group such that the copolymer has a functional group equivalent weight from 100 to 10,000 grams / equivalent.
2. The composition of claim 1, wherein the structural units (I) of the copolymer comprise at least 30 mol % of the copolymer.
3. The copolymer composition of claim 1 further comprising at least 10 mol % of residues having the following structural units :
Figure imgf000002_0001
wherein R15 is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl .
79
4. The copolymer composition of claim 1, wherein the copolymer further comprises one or more residues derived from other ethylenically unsaturated monomers of general formula V:
Figure imgf000003_0001
wherein R11, R12, and R14 are independently selected from the group consisting of H, halides, CF3, straight or branched alkyl of 1 to 20 carbon atoms, aryl of 6 to 12 carbon atoms,
80
PCT/US2003/003983 2002-02-15 2003-02-10 Copolymers comprising isobutylene type and acrylate type monomers Ceased WO2003070795A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003215144A AU2003215144A1 (en) 2002-02-15 2003-02-10 Copolymers comprising isobutylene type and acrylate type monomers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/077,645 2002-02-15
US10/077,645 US6784248B2 (en) 2002-02-15 2002-02-15 Thermosetting compositions containing alternating copolymers of isobutylene type monomers
US10/348,230 2003-01-21
US10/348,230 US20040143079A1 (en) 2003-01-21 2003-01-21 Compositions containing copolymers of isobutylene type monomers

Publications (2)

Publication Number Publication Date
WO2003070795A1 WO2003070795A1 (en) 2003-08-28
WO2003070795B1 true WO2003070795B1 (en) 2003-12-18

Family

ID=27759913

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/003983 Ceased WO2003070795A1 (en) 2002-02-15 2003-02-10 Copolymers comprising isobutylene type and acrylate type monomers

Country Status (2)

Country Link
AU (1) AU2003215144A1 (en)
WO (1) WO2003070795A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7619040B2 (en) * 2002-02-15 2009-11-17 Ppg Industries Ohio, Inc. Compositions containing copolymers of olefinic monomers
US20090074978A1 (en) * 2007-09-13 2009-03-19 Basf Corporation Method of making carbamate functional materials

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2411599A (en) * 1940-11-09 1946-11-26 Standard Oil Dev Co Polymerization process
US3183217A (en) * 1961-03-01 1965-05-11 Exxon Research Engineering Co Copolymerization of polar with nonpolar monomers in the presence of a friedel-craftsand a free radical initator
US3494826A (en) * 1964-02-03 1970-02-10 Du Pont Polymer bonded cellulose and its preparation
GB1313792A (en) * 1969-04-16 1973-04-18 Sumitomo Chemical Co Elastomeric compositions containing olefin-acrylic ester copolymer
BE763733A (en) * 1970-03-04 1971-09-03 Sumitomo Chemical Co CURING INTERPOLYMER OF OLEFIN AND ACRYLIC ESTER
US5807937A (en) * 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties

Also Published As

Publication number Publication date
AU2003215144A1 (en) 2003-09-09
WO2003070795A1 (en) 2003-08-28

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