WO2002038849A1 - Appareil de nettoyage au dioxyde de carbone a panier tournant et entrainement externe - Google Patents
Appareil de nettoyage au dioxyde de carbone a panier tournant et entrainement externe Download PDFInfo
- Publication number
 - WO2002038849A1 WO2002038849A1 PCT/US2000/030706 US0030706W WO0238849A1 WO 2002038849 A1 WO2002038849 A1 WO 2002038849A1 US 0030706 W US0030706 W US 0030706W WO 0238849 A1 WO0238849 A1 WO 0238849A1
 - Authority
 - WO
 - WIPO (PCT)
 - Prior art keywords
 - seal
 - carbon dioxide
 - liquid
 - cleaning medium
 - wash vessel
 - Prior art date
 
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 138
 - 238000004140 cleaning Methods 0.000 title claims abstract description 76
 - 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 69
 - 239000001569 carbon dioxide Substances 0.000 title claims abstract description 69
 - 239000007788 liquid Substances 0.000 claims abstract description 117
 - 239000004744 fabric Substances 0.000 claims abstract description 7
 - 230000000149 penetrating effect Effects 0.000 claims abstract description 7
 - 239000004094 surface-active agent Substances 0.000 claims description 28
 - 239000006184 cosolvent Substances 0.000 claims description 22
 - 238000000034 method Methods 0.000 claims description 12
 - 239000003960 organic solvent Substances 0.000 claims description 6
 - 238000005108 dry cleaning Methods 0.000 description 20
 - 239000000203 mixture Substances 0.000 description 11
 - 239000007789 gas Substances 0.000 description 9
 - 239000003599 detergent Substances 0.000 description 5
 - 238000005406 washing Methods 0.000 description 5
 - IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
 - OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
 - MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
 - 229910052799 carbon Inorganic materials 0.000 description 4
 - 238000009472 formulation Methods 0.000 description 4
 - 239000004615 ingredient Substances 0.000 description 4
 - 239000002689 soil Substances 0.000 description 4
 - 150000001335 aliphatic alkanes Chemical group 0.000 description 3
 - 150000001875 compounds Chemical class 0.000 description 3
 - 239000012530 fluid Substances 0.000 description 3
 - 239000000463 material Substances 0.000 description 3
 - 239000002904 solvent Substances 0.000 description 3
 - XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
 - 230000002209 hydrophobic effect Effects 0.000 description 2
 - 239000010985 leather Substances 0.000 description 2
 - 229910052757 nitrogen Inorganic materials 0.000 description 2
 - QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
 - 239000004215 Carbon black (E152) Substances 0.000 description 1
 - 229920000742 Cotton Polymers 0.000 description 1
 - 241000196324 Embryophyta Species 0.000 description 1
 - 102000004190 Enzymes Human genes 0.000 description 1
 - 108090000790 Enzymes Proteins 0.000 description 1
 - LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
 - CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
 - 229920000297 Rayon Polymers 0.000 description 1
 - 229920002472 Starch Polymers 0.000 description 1
 - 229910000831 Steel Inorganic materials 0.000 description 1
 - 244000269722 Thea sinensis Species 0.000 description 1
 - 150000001298 alcohols Chemical class 0.000 description 1
 - 230000005540 biological transmission Effects 0.000 description 1
 - 230000015572 biosynthetic process Effects 0.000 description 1
 - 239000006229 carbon black Substances 0.000 description 1
 - 238000004891 communication Methods 0.000 description 1
 - 238000001816 cooling Methods 0.000 description 1
 - 230000008878 coupling Effects 0.000 description 1
 - 238000010168 coupling process Methods 0.000 description 1
 - 238000005859 coupling reaction Methods 0.000 description 1
 - 150000001924 cycloalkanes Chemical class 0.000 description 1
 - 230000001627 detrimental effect Effects 0.000 description 1
 - 150000002009 diols Chemical class 0.000 description 1
 - 239000011152 fibreglass Substances 0.000 description 1
 - 239000003205 fragrance Substances 0.000 description 1
 - 235000019674 grape juice Nutrition 0.000 description 1
 - 238000010438 heat treatment Methods 0.000 description 1
 - 229930195733 hydrocarbon Natural products 0.000 description 1
 - 150000002430 hydrocarbons Chemical class 0.000 description 1
 - 239000000314 lubricant Substances 0.000 description 1
 - -1 oily soils Chemical class 0.000 description 1
 - 150000002894 organic compounds Chemical class 0.000 description 1
 - 229920001084 poly(chloroprene) Polymers 0.000 description 1
 - 229920000728 polyester Polymers 0.000 description 1
 - 230000002265 prevention Effects 0.000 description 1
 - 238000010926 purge Methods 0.000 description 1
 - 239000002964 rayon Substances 0.000 description 1
 - 229920006395 saturated elastomer Polymers 0.000 description 1
 - 238000007789 sealing Methods 0.000 description 1
 - 210000002374 sebum Anatomy 0.000 description 1
 - 150000004760 silicates Chemical class 0.000 description 1
 - 238000004513 sizing Methods 0.000 description 1
 - 239000007787 solid Substances 0.000 description 1
 - 235000019698 starch Nutrition 0.000 description 1
 - 239000010959 steel Substances 0.000 description 1
 - 239000000126 substance Substances 0.000 description 1
 - 231100000331 toxic Toxicity 0.000 description 1
 - 230000002588 toxic effect Effects 0.000 description 1
 - 150000004072 triols Chemical class 0.000 description 1
 - 210000002268 wool Anatomy 0.000 description 1
 
Classifications
- 
        
- D—TEXTILES; PAPER
 - D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
 - D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
 - D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
 - D06F43/02—Dry-cleaning apparatus or methods using volatile solvents having one rotary cleaning receptacle only
 
 - 
        
- D—TEXTILES; PAPER
 - D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
 - D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
 - D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
 
 
Definitions
- the present invention concerns washing and dry cleaning apparatus, and particularly concerns dry cleaning apparatus for use with carbon dioxide based dry cleaning systems that employ a rotating basket with an external drive.
 - Non-aqueous cleaning apparatus known as "dry cleaning” apparatus
 - Dry cleaning employs an organic solvent such as perchloroethylene in place of an aqueous system. Dry cleaning apparatus is not, in general, employed in the home, and is instead situated at a store or central plant. Problems with convention dry-cleaning systems include the toxic nature of the solvents employed.
 - Carbon dioxide has been suggested as a dry cleaning medium. See, e.g., U.S.
 - Patent No. 4,012,194 to Maffei To date, however, a feasible apparatus for carrying out carbon dioxide cleaning has not been provided.
 - One apparatus is described in
 - U.S. Patent No. 5,267,455 to Dewees et al. describes a dry cleaning system in which carbon dioxide as a cleaning medium is transferred between vessels by means of a second purge gas such as nitrogen.
 - a second purge gas such as nitrogen.
 - the use of multiple pressurized gases makes the system considerably more complex.
 - the system employs a rotating basket, but a disadvantage is that the basket is rotated by means of a magnet coupling.
 - U.S. Patent No. 5,943,721 to Lerette describes a liquified gas dry cleaning system that uses a double mechanical seal.
 - Lerette states at column at column 4 line 57 to column 5 line 15, teaches a pressure on the seal liquid less than that in the wash vessel.
 - Lerette is based upon the position that the seal is capable of "preventing leakage" when the differential pressure across seal faces is less than about 600 psig.
 - the attainment of complete prevention of leakage appears unrealistic, and further raises the risk of wash fluid (containing carbon dioxide) at least leaking through the seal and into the seal liquid. This would expose the seal face to carbon dioxide.
 - a cleaning apparatus adapted for cleaning fabrics, garments and the like with a carbon dioxide cleaning medium is disclosed.
 - the apparatus comprises:
 - seal liquid reservoir (e) a seal liquid reservoir; (f) a seal liquid inlet line connected to the seal liquid reservoir and the double mechanical seal and configured to supply seal liquid to the double mechanical seal; and
 - a pump, compressed gas line, or other pressure supply means operatively associated with the seal liquid reservoir for maintaining the pressure of seal liquid in the double mechanical seal sufficient to seal the rotating shaft when the wash vessel contains a liquid carbon dioxide cleaning medium from escape of cleaning medium around the rotating shaft.
 - Means such as a pump operatively associated with inlet and outlet lines are provided for circulating liquid carbon dioxide cleaning medium through the wash vessel during cleaning of articles therein.
 - a motor or other drive means is operatively associated with the drive shaft for rotating the rotating basket during cleaning of articles therein.
 - the seal liquid is preferably selected to be compatible with ⁇ e.g., soluble in) the cleaning medium.
 - Figure 1 is a schematic view of a carbon dioxide wash vessel with a drive shaft penetrating the back wall thereof, the drive shaft sealed with a double mechanical seal, the double mechanical, along with means for pressurizing the double mechanical seal.
 - Figure 2 is a cross-sectional view of a wash vessel of the present invention, showing the rotating basket therein, along with the double mechanical seal.
 - Figure 3 is a detailed cross sectional view of the wash vessel of Figure 2, showing the bearing cartridge and the double mechanical seal.
 - Figure 4 is an schematic view of a carbon dioxide wash vessel with a drive shaft penetrating the back wall thereof, essentially as disclosed in Figure 1, with an alternate arrangement for pressurizing the double mechanical seal.
 - the apparatus includes a wash vessel 10 having a wall portion 11.
 - a rotating basket 20 is positioned in the wash vessel (see Fig. 2).
 - a drive shaft 21 penetrates the wash vessel wall portion, with the shaft operatively associated with the rotating basket.
 - the shaft is directly connected to the rotating basket in the illustrated embodiment, but could be indirectly connected through gears, belts, chains or other drive means within the wash vessel if desired.
 - a double mechanical seal 12 is connected to the wall portion with the drive shaft passing therethrough.
 - a seal liquid reservoir 13 is connected to the double mechanical seal by a seal liquid inlet line 14 to supply seal liquid to the double mechanical seal via port 33 (Fig. 2).
 - a seal liquid outlet line 15 connected to port 34 is provided to return seal liquid from the double mechanical seal to the reservoir, though the seal liquid outlet line is optional as the seal liquid could be allowed to pass from the seal directly into the wash medium, if desired.
 - a compressed gas line 16 e.g., compressed nitrogen at about 900 to 950 psi for a wash tank at a maximum pressure of about 875 psi
 - a pressure regulator 18 serves as a pressure supply means operatively associated with the seal liquid reservoir for maintaining the pressure of seal liquid in the double mechanical seal sufficient to seal the rotating shaft when the wash vessel contains a liquid carbon dioxide cleaning medium.
 - a separate 1100 psi pressure relief valve 19 serves as a safety valve on the reservoir.
 - the reservoir is supplied with a level sensor (not shown) to insure that a sufficient quantity of seal liquid is maintained therein.
 - a motor 25 external to the wash vessel such as an electric motor, is drivingly connected to drive shaft 21 by means of a belt 26 and drive wheels 27, 28.
 - a bearing cartridge 30 is connected to the wall portion and supports the drive shaft. Note that the double mechanical seal is positioned between the bearing cartridge and the rotating basket. This facilitates removal of the bearing cartridge and servicing of the bearings.
 - any suitable drive means can be employed, including direct drives, gear drives and transmission systems, turbine drives, etc.
 - a drive shaft support in the form of an integrally formed cartridge 29 is connected to the body member back wall external to the double mechanical seal.
 - the cartridge 29 is, in a preferred embodiment, integrally formed from a single piece of steel and contains both the bearing assembly and the double mechanical seal adjacent one another.
 - the shaft is disposed in the cartridge holder to permit rotation of the basket 20 within the body member.
 - the bearing assembly is a cantilevered bearing assembly, and a pair of bearings 31, 32, which may be comprised of ball bearings, roller bearings, sleeve bearings or any other suitable bearing system. Timken tapered roller bearings are preferred. Because the bearing assembly is external to the seal, the bearing assembly may be greased in a conventional manner.
 - the double mechanical seal 12 includes an inner stator 60 and an outer stator 61, and an inner rotor 62 and an outer rotor 63.
 - a internal space 64 between the two stators is in fluid communication with a seal liquid inlet opening 65 (which is comiected to line 14 of Figurel) and a seal liquid outlet opening 66 (which is connected to line 15 of Figure 2).
 - Double mechanical seals are known. See, e.g., Intech International Technical Services, Take the Mystery Out of Mechanical Seals, (1994). Double mechanical seals are available from a variety of sources, such as Flowserve Fluid Sealing Division, Kalamazoo, Michigan, USA.
 - the other path of seal liquid release in both embodiments, is into the wash vessel or tank itself.
 - the flow into the wash vessel is between about .5 to 5 or ten milliliters of seal liquid an hour.
 - An alternate embodiment of the invention where the pressure supply means comprises a pump operatively associated with the seal liquid inlet line is illustrated in Figure 4.
 - the pressure relief valve 19' is a 1000 psi pressure relief valve. Pressure is applied by means of a pump 50 on line 14'. Manual valve 51 is normally open during operation.
 - accumulator 52 Along inlet line 14' there is an accumulator 52, a pressure indicator 53, and a pressure transducer 54.
 - a drain line 55 is supplied with a manual drain valve 56 for emptying seal liquid from the system for servicing and the like.
 - numerous other pressure supply means can be employed in carrying out the present invention, including pumps, compressors, compressed gases and the like, with or without additional components such as accumulators, pressure sensors, valves, etc., with single or multiple lines provided to the double mechanical seal, in a variety of different configurations, to supply pressure to the double mechanical seal. All that is required is that sufficient pressure be provided to the seal liquid within the double mechanical seal to substantially reduce the escape of carbon dioxide cleaning medium from the wash vessel around the drive shaft.
 - the pressure on the seal liquid is sufficient so that, if anything, seal liquid will leak into the wash vessel from the double mechanical seal.
 - the cleaning medium carbon dioxide liquid could be used as the pressure supply means by taking a line of cleaning medium from the pump outlet to the seal liquid reservoir, or by taking a line from the wash tank itself through a piston pump or the like to the seal liquid reservoir.
 - the present invention provides a method of operating a cleaning apparatus adapted for cleaning fabrics, garments and the like with a liquid carbon dioxide cleaning medium, the apparatus comprising a wash vessel having a wall portion, a rotating basket positioned in the wash vessel, and a drive shaft penetrating the wash vessel wall portion, the shaft operatively associated with the rotating basket;.
 - the method comprises providing a double mechanical seal connected to the wall portion with the drive shaft passing therethrough; filling the double mechanical seal with a seal liquid, the seal liquid comprising an organic solvent (or, with respect to the cleaning medium, an organic co-solvent); increasing the pressure in the wash vessel so that articles therein can be cleaned in a liquid carbon dioxide cleaning medium therein; and pressurizing the seal liquid for at least the time when the pressure in the wash vessel is increased, so that the escape of liquid carbon dioxide cleaning medium around the rotating shaft is reduced.
 - the step of increasing the pressure may be carried out by filling the wash vessel with compressed gas, such as carbon dioxide gas, and/or filling the wash vessel with compressed liquid, such as the liquid carbon dioxide wash medium.
 - the step of presssurizing the seal liquid may be carried out continuously (e.g., with pressure on the seal liquid being maintained between wash cycles while the pressure in the wash vessel is reduced to atmospheric pressure, or may be intermittent (e.g., with pressure on the seal liquid being increased when pressure in the wash vessel is increased, and pressure on the seal liquid being reduced when pressure in the wash vessel is reduced).
 - a liquid carbon dioxide cleaning medium is circulated through the wash vessel to clean articles therein in accordance with known techniques, and the basket is rotated by rotating the drive shaft with the external drive motor as illustrated above.
 - the liquid carbon dioxide cleaning medium may, in one preferred embodiment, contain an organic co- solvent, preferably one that is soluble in the liquid carbon dioxide.
 - the cleaning medium also contains a surfactant.
 - the seal liquid is preferably also an organic co-solvent as described herein, and is preferably soluble in the liquid carbon dioxide cleaning medium. Indeed, it is preferable that the surfactant in the cleaning medium (or at least one of the surfactants therein, where multiple surfactants are employed) is soluble in the seal liquid.
 - the present invention can be implemented with any system or means for supplying or circulating a liquid carbon dioxide dry-cleaning medium through the wash vessel, such as described in our copending patent application serial number 09/047,013, filed March 24, 1998, the disclosure of which is incorporated by reference herein in its entirety.
 - Other systems for circulating the liquid carbon dioxide dry-cleaning medium through the wash vessel that can be used in conjunction with or to carry out the present invention include those described in U.S. Patent No. 5,850,747 to Roberts et al., U.S. Patent No. 5,669,251 to Townsend et al., 5,676,705 to Jureller et al., and 5,683,473 to Jureller et al.
 - such systems include a carbon dioxide cleaning medium inlet line connected to the wash vessel (typically at the top thereof), a carbon dioxide drain line 41 connected to said wash vessel (typically at the bottom thereof), and a pump 42 such as a canned motor pump (preferably a centrifugal pump) interconnecting the outlet line and the inlet line for circulating liquid carbon dioxide cleaning medium through the wash vessel.
 - a lint filter and/or a carbon filter 43 are preferably positioned on the carbon dioxide inlet line, after the pump.
 - both a lint filter and a carbon filter are used, with a by-pass line equipped with valves included to by-pass the carbon filter when detergents or other chemical ingredients are added to the cleaning medium so that they are not removed by the carbon filter.
 - a side-stream of the liquid carbon dioxide cleaning medium can be passed through the bearing cartridge through appropriate piping to cool and lubricate the bearings, particularly where the cleaning medium contains an organic co- solvent that is sufficiently heavy (i.e., has a high flash point) in sufficient amount to serve as a lubricant, though an external bearing cartridge that is simply greased in a conventional manner is currently preferred.
 - any carbon dioxide liquid dry-cleaning medium can be used as the medium in the instant apparatus. See, e.g., U.S. Patent No. 4,012,194 to Maffei.
 - carbon dioxide is supplied by tank, and additional ingredients can be added to the carbon dioxide in the working vessel (which may optionally be supplied with a stirrer to serve as a mixing means therein), in the wash tank, or any other suitable location in the system (or combination thereof).
 - the liquid dry-cleaning medium comprises a mixture of: (a) water, (b) carbon dioxide, (c) surfactant, and, optionally but preferably, (d) an organic co-solvent. After the contacting step, the article is separated from the liquid dry cleaning composition.
 - the liquid dry cleaning composition is at ambient temperature, of about 0° C to 30° C. h one embodiment; the surfactant contains a CO 2 -philic group; in another embodiment, the surfactant does not contain a CO 2 -philic group.
 - a preferred liquid carbon dioxide dry-cleaning medium useful for carrying out the present invention typically comprises: (a) from zero or .1 to 10 percent (more preferably from .1 to 4 percent) water; (b) carbon dioxide (to balance; typically at least 30 percent); (c) surfactant (preferably from .1 or .5 percent to 5 or 10 percent); and (d) from .1 to 50 percent (more preferably 4 to 30 percent) of an organic co- solvent. Percentages herein are expressed as percentages by weight unless otherwise indicated.
 - the medium is provided in liquid form at ambient, or room, temperature, which will generally be between zero and 50° Centigrade. The medium is held at a pressure that maintains it in liquid form within the specified temperature range.
 - the washing or cleaning step is preferably carried out with the liquid medium at ambient temperature within the wash vessel, without extraneous heating or cooling of the wash vessel. All ingredients but for the carbon dioxide can be combined together to provide a detergent formulation, which is then added to the carbon dioxide to provide the dry cleaning medium.
 - the detergent formulation can be used directly as the seal liquid, as discussed below.
 - Any surfactant can be used to carry out the present invention, including both surfactants that contain a CO 2 -philic group (such as described in PCT Application WO96/27704) linked to a CO 2 -phobic group (e.g., a hpophilic group) and surfactants that do not contain a CO 2 -philic group (i.e., surfactants that comprise a hydropl ilic group linked to a hydrophobic (typically hpophilic) group).
 - a single surfactant may be used, or a combination of surfactants may be used. Numerous surfactants are known to those skilled in the art. Examples of suitable surfactants are given in U.S. Patent No.
 - the organic co-solvent is, in general, a hydrocarbon co-solvent.
 - the co-solvent is an alkane co-solvent, with Cio to C 2 o linear, branched, and cyclic alkanes, and mixtures thereof (preferably saturated) currently preferred.
 - the organic co-solvent preferably has a flash point above 140°F, and more preferably has a flash point above 170°F.
 - the organic co-solvent may be a mixture of compounds, such as mixtures of alkanes as given above, or mixtures of one or more alkanes in combination with additional compounds such as one or more alcohols (e.g., from 0 or 0.1 to 5% of a Cl to C15 alcohol (including diols, triols, etc.)).
 - additional compounds such as one or more alcohols (e.g., from 0 or 0.1 to 5% of a Cl to C15 alcohol (including diols, triols, etc.)).
 - dry-cleaning medium various additional ingredients can be included in the dry-cleaning medium, including detergents, bleaches, whiteners, softeners, sizing, starches, enzymes, hydrogen peroxide or a source of hydrogen peroxide, fragrances, etc.
 - the organic co-solvent that is employed as the seal liquid may be selected from the same group as the organic co-solvent described above which are used in the preferred liquid carbon dioxide cleaning medium (although it may be the same as or different from the organic co-solvents incorporated directly into the cleaning medium.
 - a particularly preferred solvent for the seal liquid is ISOPAR MTM organic solvent.
 - the organic co-solvent in said carbon dioxide cleaning medium and the organic co-solvent in said seal liquid are the same; and the liquid carbon dioxide cleaning medium further comprises a surfactant as described above, the seal liquid further comprises a surfactant as described above, and the cleaning medium surfactant and the seal liquid surfactant are the same.
 - the detergent formulation that is added to liquid carbon dioxide to provide the cleaning system described above can be the same formulation that is used as the seal liquid.
 - Articles that can be cleaned by the apparatus of the present invention are, in general, garments and fabrics (including woven and non-woven) formed from materials such as cotton, wool, silk, leather, rayon, polyester, acetate, fiberglass, furs, pelts, canvas, neoprene, etc., formed into items such as clothing, work gloves, tents, parachutes, sails, hats, tapestry, waders, rags, leather goods (e.g., boots, shoes, handbags and brief cases), etc.
 - the term "clean” as used herein refers to any removal of soil, dirt, grime, or other unwanted material, whether partial or complete.
 - the invention may be used to clean nonpolar stains (i.e., those which are at least partially made by nonpolar organic compounds such as oily soils, sebum and the like), polar stains (i.e., hydrophilic stains such as grape juice, coffee and tea stains), compound hydrophobic stains (i.e., stains from materials such as lipstick and candle wax), and particulate soils (i.e., soils containing insoluble solid components such as silicates, carbon black, etc.).
 - nonpolar stains i.e., those which are at least partially made by nonpolar organic compounds such as oily soils, sebum and the like
 - polar stains i.e., hydrophilic stains such as grape juice, coffee and tea stains
 - compound hydrophobic stains i.e., stains from materials such as lipstick and candle wax
 - particulate soils i.e., soils containing insoluble solid components such as silicates, carbon black, etc.
 
Landscapes
- Engineering & Computer Science (AREA)
 - Textile Engineering (AREA)
 - Treatment Of Fiber Materials (AREA)
 
Abstract
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| PCT/US2000/030706 WO2002038849A1 (fr) | 2000-11-08 | 2000-11-08 | Appareil de nettoyage au dioxyde de carbone a panier tournant et entrainement externe | 
| AU2001214756A AU2001214756A1 (en) | 2000-11-08 | 2000-11-08 | Carbon dioxide cleaning apparatus with rotating basket and external drive | 
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title | 
|---|---|---|---|
| PCT/US2000/030706 WO2002038849A1 (fr) | 2000-11-08 | 2000-11-08 | Appareil de nettoyage au dioxyde de carbone a panier tournant et entrainement externe | 
Publications (1)
| Publication Number | Publication Date | 
|---|---|
| WO2002038849A1 true WO2002038849A1 (fr) | 2002-05-16 | 
Family
ID=21741975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date | 
|---|---|---|---|
| PCT/US2000/030706 WO2002038849A1 (fr) | 2000-11-08 | 2000-11-08 | Appareil de nettoyage au dioxyde de carbone a panier tournant et entrainement externe | 
Country Status (2)
| Country | Link | 
|---|---|
| AU (1) | AU2001214756A1 (fr) | 
| WO (1) | WO2002038849A1 (fr) | 
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| WO2022158927A3 (fr) * | 2021-01-25 | 2022-09-01 | Lg Electronics Inc. | Lave-linge | 
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| US5267455A (en) * | 1992-07-13 | 1993-12-07 | The Clorox Company | Liquid/supercritical carbon dioxide dry cleaning system | 
| EP0679753A2 (fr) * | 1994-04-29 | 1995-11-02 | Hughes Aircraft Company | Nettoyage à sec de vêtements utilisant comme produits de nettoyage du dioxyde de carbone liquide en agitation | 
| US5669251A (en) * | 1996-07-30 | 1997-09-23 | Hughes Aircraft Company | Liquid carbon dioxide dry cleaning system having a hydraulically powered basket | 
| WO1999034051A1 (fr) * | 1997-12-24 | 1999-07-08 | Alliance Laundry Systems Llc | Machine de nettoyage a sec possedant une commande d'agitation | 
| US5943721A (en) * | 1998-05-12 | 1999-08-31 | American Dryer Corporation | Liquified gas dry cleaning system | 
| WO1999049122A1 (fr) * | 1998-03-24 | 1999-09-30 | Micell Technologies, Inc. | Appareil de nettoyage | 
| US6182318B1 (en) * | 1997-12-24 | 2001-02-06 | Alliance Laundry Systems Llc | Liquified gas dry-cleaning system with pressure vessel temperature compensating compressor | 
- 
        2000
        
- 2000-11-08 AU AU2001214756A patent/AU2001214756A1/en not_active Abandoned
 - 2000-11-08 WO PCT/US2000/030706 patent/WO2002038849A1/fr active Application Filing
 
 
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| US5267455A (en) * | 1992-07-13 | 1993-12-07 | The Clorox Company | Liquid/supercritical carbon dioxide dry cleaning system | 
| EP0679753A2 (fr) * | 1994-04-29 | 1995-11-02 | Hughes Aircraft Company | Nettoyage à sec de vêtements utilisant comme produits de nettoyage du dioxyde de carbone liquide en agitation | 
| US5669251A (en) * | 1996-07-30 | 1997-09-23 | Hughes Aircraft Company | Liquid carbon dioxide dry cleaning system having a hydraulically powered basket | 
| WO1999034051A1 (fr) * | 1997-12-24 | 1999-07-08 | Alliance Laundry Systems Llc | Machine de nettoyage a sec possedant une commande d'agitation | 
| US6182318B1 (en) * | 1997-12-24 | 2001-02-06 | Alliance Laundry Systems Llc | Liquified gas dry-cleaning system with pressure vessel temperature compensating compressor | 
| WO1999049122A1 (fr) * | 1998-03-24 | 1999-09-30 | Micell Technologies, Inc. | Appareil de nettoyage | 
| US6049931A (en) * | 1998-03-24 | 2000-04-18 | Micell Technologies, Inc. | Cleaning apparatus | 
| US5943721A (en) * | 1998-05-12 | 1999-08-31 | American Dryer Corporation | Liquified gas dry cleaning system | 
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title | 
|---|---|---|---|---|
| WO2022158927A3 (fr) * | 2021-01-25 | 2022-09-01 | Lg Electronics Inc. | Lave-linge | 
Also Published As
| Publication number | Publication date | 
|---|---|
| AU2001214756A1 (en) | 2002-05-21 | 
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