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WO2002031216A2 - Apparatus for continuous sputter-deposition - Google Patents

Apparatus for continuous sputter-deposition Download PDF

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Publication number
WO2002031216A2
WO2002031216A2 PCT/US2001/031597 US0131597W WO0231216A2 WO 2002031216 A2 WO2002031216 A2 WO 2002031216A2 US 0131597 W US0131597 W US 0131597W WO 0231216 A2 WO0231216 A2 WO 0231216A2
Authority
WO
WIPO (PCT)
Prior art keywords
sputter coating
line
sputter
another
lines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/031597
Other languages
French (fr)
Other versions
WO2002031216A3 (en
Inventor
Jean-Marc Lemmer
Marcel Schloremberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre Luxembourgeois de Recherches pour le Verre et la Ceramique CRVC SARL
Original Assignee
Centre Luxembourgeois de Recherches pour le Verre et la Ceramique CRVC SARL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/685,568 external-priority patent/US6336999B1/en
Application filed by Centre Luxembourgeois de Recherches pour le Verre et la Ceramique CRVC SARL filed Critical Centre Luxembourgeois de Recherches pour le Verre et la Ceramique CRVC SARL
Priority to AU2002211575A priority Critical patent/AU2002211575A1/en
Publication of WO2002031216A2 publication Critical patent/WO2002031216A2/en
Publication of WO2002031216A3 publication Critical patent/WO2002031216A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3639Multilayers containing at least two functional metal layers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3649Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3652Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • C23C14/568Transferring the substrates through a series of coating stations

Definitions

  • This invention relates to an apparatus for sputter coating glass, and corresponding
  • Sputter coated glass articles are known in the art. For example, see U.S. Patent
  • solar management properties e.g., low emissivity or low-
  • Sputter coating may be an electric discharge process, often conducted in a vacuum
  • a sputter coating apparatus typically
  • the gas(es) forms a plasma that bombards the target causing particles of
  • the coating material to be liberated or lifted from the target itself.
  • the gas may be deposited on the substrate.
  • the coated article of Figure 1 includes glass substrate 1 on which are located silicon
  • nitride (Si 3 N ) layer 2 nichrome or nichrox (NiCr or NiCrO x ) layer 3, silver (Ag) layer 4,
  • nichrome or nichrox (NiCr or NiCrO x ) layer 5 nichrome or nichrox (NiCr or NiCrO x ) layer 5
  • silicon nitride (Si 3 N 4 ) layer 6 silicon nitride
  • a dielectric layer may also be provided between substrate
  • article of Figure 2 also includes layers 2-6 provided on glass substrate 1.
  • the article of Figure 2 also includes layers 2-6 provided on glass substrate 1.
  • coated article of Figure 2 further includes a thicker silicon nitride (Si 3 N 4 ) layer 6a
  • nichrome or nichrox (NiCr or NiCrO x ) layer 7 nichrome or nichrox (NiCr or NiCrO x ) layer 7
  • second silver (Ag) layer 8 nichrome or nichrox (NiCr or NiCrO x ) layer 9
  • the coating system of Figure 2 may be referred to as a dual
  • silver coating system because it includes first and second silver (Ag) layers 4 and 8
  • the Fig. 3 sputter coating apparatus includes enough
  • the sputter coating apparatus includes six different zones
  • Zone 1 (i.e., zones 1-6) which are separated from one another by curtains or walls 52.
  • Zone 1 includes targets 21-26.
  • Zone 2 includes targets 27-29.
  • Zone 3 includes targets 30-35.
  • Zone 4 includes targets 36-41.
  • Zone 5 includes targets 42-44.
  • Zone 6 includes targets
  • a different gas e.g., argon, nitrogen, oxygen, etc. may be utilized in each zone
  • a typical line speed of the sputter coater is 205 inches per minute
  • zone 1 are silicon (Si) targets, while nitrogen gas at low pressure is provided in that zone.
  • the substrate Following deposition of silicon nitride layer 2 in zone 1 using targets 21-26, the substrate
  • targets 27 and 29 are of nickel and/or
  • zone 2 chrome, while target 28 is of silver.
  • An argon (Ar) atmosphere may be utilized in zone 2.
  • targets 30-35 are of
  • zones 1-3 may be maintained at a pressure of from about 1.0 to 3.0 x 10° Torr, or any
  • zones 4-6 and their coating system of Figure 1 will have been formed.
  • zones 4-6 and their coating system of Figure 1 will have been formed.
  • respective targets 36-50 are inoperative in the Figure 3 apparatus when the coated article
  • zones 4-6 is wasteful, and also presents a requirement for passing a coated article through
  • zones 1-3 are set up and utilized as described above regarding the Fig. 1 article.
  • zones 4-6 are set up just like zones 1-3, respectively.
  • targets 36-41 are silicon targets in a nitrogen atmosphere of zone 4, targets
  • target 43 is
  • targets 45-50 are silicon
  • zones 1-6 targets in a mtrogen atmosphere of zone 6.
  • coated articles of different types such as those of Figures 1 and 2. If this is to be done
  • article of Figure 1 is manufactured (i.e., certain zones and/or targets would likely be
  • portion of the coating apparatus may not be used when certain coated articles having a
  • An object of this invention is to provide a sputter coating apparatus capable of
  • Another object of this invention is to provide a sputter coating apparatus including
  • first and second sputter coating lines that are selectively coupleable to one another via a
  • Each of the first and second sputter coating lines may be independently
  • a coating system having more than a predetermined number of layers (e.g., a
  • transition zone couples the two lines together thereby enabling an incompleted sputter coated article leaving the first sputter coating line to be routed to the second sputter
  • sputter coating lines may be used either independently (e.g., run in parallel to one
  • Yet another object of this invention is to fulfill any and/or all of the aforesaid
  • a first sputter coating line including a plurality of zones and a plurality of targets
  • a second sputter coating line including a plurality of zones and a plurality of
  • said transition zone selectively coupling the first and second sputter coating
  • a first sputter coating line including a
  • a second sputter coating hne including a
  • Figure 1 is sectional view of a conventional sputter coated article.
  • Figure 2 is a sectional view of another sputter coated article.
  • Figure 3 is a schematic diagram of a conventional sputter coating apparatus.
  • Figure 4 is a schematic functional diagram of a sputter coating apparatus
  • the sputter coating apparatus including two
  • sputter coating lines capable of running in parallel with one another or alternatively in
  • Figure 5 is a schematic functional diagram of either the sputter coating hne "A"
  • Figure 6 is a schematic functional diagram of the adjustable transition zone of the
  • Figure 4 sputter coating apparatus.
  • Figure 7 is a flowchart illustrating certain steps taken during the course of carrying
  • Figure 8 is a schematic functional diagram of a transition zone for selectively
  • Figure 9 is a schematic functional diagram of an apparatus according to another
  • Figure 4 is a schematic functional diagram of a sputter coating apparatus
  • first sputter coating line 58 includes a first sputter coating line 58, a second sputter coater line 59, and adjustable
  • transition zone 60 coupling respective ends of the two sputter coating lines.
  • Figure 5 is a
  • each of the lines 58 and 59 have three
  • zones (zones 1-3) in this exemplary embodiment and include targets 21-35. Transition
  • zone 60 is provided at the end of each sputter coating line 58, 59 so as to enable the lines
  • coating lines 58, 59 may be used independently from one another so as to operate in
  • coating system having more layers than one of lines 58, 59 is capable of depositing on a
  • transition zone is capable of coupling hnes 58 and 59 to one another so
  • targets 21-26 are silicon (Si) targets in a nitrogen atmosphere
  • targets 27 and 29 are nickel and/or nickel-chrome targets in an argon (Ar)
  • target 28 is a silver (Ag) target in the argon atmosphere of zone 2
  • targets 30-35 are silicon (Si) targets in a nitrogen atmosphere of zone 3.
  • each coating line 58, 59, zones 1 and 3 deposit the respective silicon nitrides layer 2 and
  • coating line 58 functions to
  • transition zone 60 as illustrated.
  • line 58 is forming a first type of layer system (e.g., Si 3 N 4 /NiCr/Ag/NiCr/Si 3 N 4 )
  • line 59 is forming a second type of layer system (e.g., SnO/Ag/SnO) on respective
  • the first sputter coating line 58 is set up to deposit layers 2-
  • Reversible sputter coating line 59 is set up so as to deposit the
  • coated article exits the second coating line 59 at the other end 67 thereof as shown in
  • portion of the coating system is deposited by sputter coating line 58 and a second
  • Adjustable transition zone 60 selectively couples the output end of first coating Hne 58 to an input output end of coating line 59.
  • layer 2 is deposited in zone 1 of Hne 58,
  • sputter coating line 59 e.g., zones 1-3 of line 58 may be set up in the same manner as
  • sputter coating line 59 is reversible in that substrates may pass
  • transition zone 60 therethrough in either direction depending upon the functionality of transition zone 60
  • transition zone 60 (i.e., whether transition zone 60 is causing coated articles exiting Hnes 58, 59 to pass
  • transition zone 60 is directing incomplete coated articles exiting
  • coating line 58 to an input of coating line 59 as shown by reference numeral 63).
  • Figure 6 is a functional top view diagram of transition zone 60 which selectively
  • transition zone 60 includes conveyor 70
  • conveyor 75 which may be selectively deployable in different positions
  • conveyor 72 provided between a potential output of conveyor 75 and conveyor 74
  • conveyor 73 provided between another potential output of conveyor 75 and an output of
  • End 83 of line 59 can function as an output end
  • conveyor 75 thereon are selectively deployable in different positions in order to
  • Figure 1 coated articles may be exiting sputter coating line 58 at output 81 and
  • conveyor 70 which dumps
  • coated articles may simultaneously be exiting output 83 of sputter coating Hne 59, and
  • coated article exits coating line 58 at 81 onto conveyor 70 (e.g., when making the Fig. 2
  • the coated article at this point may include layers 2-5 and half of layer 6a on
  • Conveyor 75 then dumps the incomplete article onto conveyor
  • Conveyor 74 then conveys the
  • platform 71 may rotate back to the solid line position shown in Figure
  • article(s) determines whether or not platform 71 causes an article received thereon to be forwarded to conveyor 72 or conveyor 73. Likewise, the direction of conveyor 74 is
  • end 83 functions as an input when receiving incomplete coated articles from
  • FIG. 7 is a flowchart illustrating certain steps carried out and in accordance with
  • substrate 1 e.g., soda-lime-silica glass substrate
  • step 90 substrate 1
  • first sputter coating line 58 is then conveyed through a first sputter coating line 58 so that a pluraHty of layer(s) can
  • step 91 e.g., layers 2-6 of Fig. 1, or layers 2-6a of Fig. 2).
  • coated article including a plurality of sputter coated layers on substrate 1 then exits the
  • first sputter coating line 58 and enters transition zone 60 (step 92). A determination is
  • controller 101 then made by controller 101 as to whether or not the desired layer system has been
  • step 93 This
  • controller 101 may be based upon input from a keyboard, or any other
  • suitable means such as a programmed listing of articles to be made by the system. If it is
  • the sputter coated article exits the transition zone (step 94) and the
  • step 95 overall sputter coating apparatus (step 95) when conveyor 75 is in the position shown in
  • controller 101 which may access and utilize programs stored in memory 103 determines in step 93 that the layering system is
  • controller 101 causes motor 105 to
  • article enters sputter coating line 59 so that additional layers (e.g., the remainder of layer
  • step 97 After passing through sputter
  • the article exits the coating apparatus/system at 67 (step 95).
  • transition zone 60 is preferably maintained in a given atmosphere
  • Figure 8 is a functional schematic diagram of a transition zone for selectively
  • end 83 of second sputter coating line 59 is an input end of line 59 regardless of whether Hnes 58
  • a substrate 1 is
  • first sputter coating Hne 58 including targets 21-35 fed into and passes through first sputter coating Hne 58 including targets 21-35 (see Fig.
  • the article including these layers exits the first sputter coating line 58 via
  • conveyor 70 The article is fed onto conveyor 75. It is determined (either at this time or
  • transition zone 60 and out of the overall sputter coating apparatus. However, if it is
  • platform 71 rotates as discussed
  • layer 10 is sputtered on in zone 3 of line 59.
  • lines 58 and 59 may operate in parallel with one another so that each can form the layering system of Fig. 1 on
  • Figures 4-6 and 8, and method of Figure 7, may be utilized to manufacture any type of
  • zone 60 functions to selectively couple an output end of a first line to an input end of a
  • Figure 9 is a functional top view diagram of transition zone or chamber 101 which
  • Transfer zone or chamber 101 in this embodiment is located between the buffer chambers
  • transfer in chamber/zone 101 is
  • buffer chambers 103 perpendicular to the line directions of Hnes 58, 59. Accordingly, buffer chambers 103
  • coated glass also are capable of causing coated glass to be transferred in both the (a) line directions of
  • Hnes 58, 59 i.e., the same direction the glass is transported during sputter coating in the
  • Transition zone/chamber 101 preferably has a gate and/or valve 105 at each end
  • Transition zone/chamber 101 may include a conveyor (e.g., reversible conveyor)
  • Controller 106 using program(s) stored in memory 107, selectively controls gates 105
  • Exit chambers 104 can function as output ends of the coating lines when lines 58
  • transition zone/chamber 101 may be used (including opening of
  • transition zone 101 (e.g., via a conveyor) and then out of zone 101 and into buffer 103 of
  • the other sputter coating line 59 (e.g., when making the Fig. 2 layer system, the coated
  • article at this point may include layers 2-5 and half of layer 6a on substrate 1).
  • Fig. 1 coated articles may be produced using one or both
  • gates 105 may be opened (manually, or automatically via controller) so that Fig. 2
  • coated articles can be produced using lines 58-59 as described above. Thus, there is no
  • next sheet will go to the other line or not (however, this may in fact be done in certain

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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
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Abstract

A sputter coating apparatus includes at least a first sputter coating line (58) and a second sputter coating line (59). The first and second sputter coating lines may be operated in parallel with one another in certain embodiments in order to independently form coating systems and respective coated articles. However, the two coating lines may also be utilized so as to operate in series with one another to form a coated article. In the latter case, a transition zone (60) is provided between an end of the first line and an end of the second line so as to selectively couple an output of the first line to an input of the second line when it is desired to utilize the two sputter coating lines in series with one another. In such a manner, it is possible to avoid many of the inefficiencies associated with conventional sputter coating apparatuses and processes.

Description

This is a continuation-in-part (CIP) application of U.S. Serial No. 09/685,568,
filed October 11, 2000, the disclosure of which is hereby incorporated herein by
reference.
APPARATUS FORSPUTTER-COATING GLASS AND CORRESPONDINGMETHOD
This invention relates to an apparatus for sputter coating glass, and corresponding
method.
BACKGROUND AND SUMMARY OF THE INVENTION
Sputter coated glass articles are known in the art. For example, see U.S. Patent
Nos. 5,770,321, 5,298,048, and 5,403,458, the disclosures of which are all hereby
incorporated herein by reference. Sputter coated layer systems on glass substrates are
typically utilized for achieving solar management properties (e.g., low emissivity or low-
E) in many types of glass articles, including but not limited to architectural windows,
automotive windows, automotive windshields, and the like.
Sputter coating may be an electric discharge process, often conducted in a vacuum
chamber in the presence of one or more gases. A sputter coating apparatus typically
includes at least one vacuum chamber in which a substrate is located, a power source, an
anode, and one or more specially prepared cathode targets of or covered with a material
to be used in creating a layer on the substrate. When an electric potential is applied to the cathode target, the gas(es) forms a plasma that bombards the target causing particles of
the coating material to be liberated or lifted from the target itself. The liberated coating
material from the target falls onto the underlying substrate and adheres thereto. When
conducted in the presence of a "reactive" gas, a reactive product of the coating material
from the target and the gas may be deposited on the substrate.
Unfortunately, conventional sputter coating apparatuses suffer from certain
inefficiencies, especially when one desires or needs to manufacture different types of
sputter coated articles using the same sputter coating apparatus.
Consider, for purposes of examples only, a scenario where one wishes to
manufacture the coated articles of Figures 1 and 2 utilizing a sputter coating apparatus.
The coated article of Figure 1 includes glass substrate 1 on which are located silicon
nitride (Si3N ) layer 2, nichrome or nichrox (NiCr or NiCrOx) layer 3, silver (Ag) layer 4,
nichrome or nichrox (NiCr or NiCrOx) layer 5, and silicon nitride (Si3N4) layer 6.
Optionally, another layer (e.g., a dielectric layer) may also be provided between substrate
1 and layer 2. Further details regarding the coated article of Figure 1 may be found in
U.S. Patent No. 5,770,321, incorporated herein by reference. Meanwhile, the coated
article of Figure 2 also includes layers 2-6 provided on glass substrate 1. However, the
coated article of Figure 2 further includes a thicker silicon nitride (Si3N4) layer 6a
(instead of layer 6 shown in Figure 1), nichrome or nichrox (NiCr or NiCrOx) layer 7, second silver (Ag) layer 8, nichrome or nichrox (NiCr or NiCrOx) layer 9, and silicon
nitride (Si3N4) layer 10. The coating system of Figure 2 may be referred to as a dual
silver coating system because it includes first and second silver (Ag) layers 4 and 8
provided for infrared (IR) radiation reflection, respectively, as opposed to the single
silver layer 4 provided in the coated article of Figure 1.
To manufacture both the coated article of Figure 1 and the coated article of Figure
2 using the same sputter coating apparatus, one would typically obtain a sputter coating
apparatus as shown in Figure 3. The Fig. 3 sputter coating apparatus includes enough
targets and zones to enable each of layers 2-10 to be deposited on a substrate 1 (i.e., it is
large enough and has enough capacity to enable either the Fig. 1 or the Fig. 2 article to be
made therein). In particular, the sputter coating apparatus includes six different zones
(i.e., zones 1-6) which are separated from one another by curtains or walls 52. Zone 1
includes targets 21-26. Zone 2 includes targets 27-29. Zone 3 includes targets 30-35.
Zone 4 includes targets 36-41. Zone 5 includes targets 42-44. Zone 6 includes targets
46-50. A different gas (e.g., argon, nitrogen, oxygen, etc.) may be utilized in each zone
at low pressure, while vacuum pumps 51 are provided between zones in order to keep
gaseous atmospheres from one zone from significantly leaking into an contaminating
adjacent zone(s). In order to manufacture the coated article of Figure 1 using the sputter coating
apparatus of Figure 3, a typical line speed of the sputter coater is 205 inches per minute
for this five layer system. For the Fig. 1 coating system to be deposited, targets 21-26 in
zone 1 are silicon (Si) targets, while nitrogen gas at low pressure is provided in that zone.
Following deposition of silicon nitride layer 2 in zone 1 using targets 21-26, the substrate
1 passes into zone 2 via a conveyor. In zone 2, targets 27 and 29 are of nickel and/or
chrome, while target 28 is of silver. An argon (Ar) atmosphere may be utilized in zone 2.
After the nichrome layers 3 and 5 and silver layer 4 are deposited in zone 2, a conveyor
moves the substrate into zone 3 beneath targets 30-35. In zone 3, targets 30-35 are of
silicon (Si) while a nitrogen (N2) gas at low pressure is utilized in that zone. Each of
zones 1-3 may be maintained at a pressure of from about 1.0 to 3.0 x 10° Torr, or any
other pressure disclosed in any of the aforesaid '321, '048 and '458 patents. Upon leaving
zone 3, the coating system of Figure 1 will have been formed. Thus, zones 4-6 and their
respective targets 36-50 are inoperative in the Figure 3 apparatus when the coated article
of Figure 1 is deposited as discussed above. Unfortunately, the inoperation of these three
zones 4-6 is wasteful, and also presents a requirement for passing a coated article through
inoperative zones thereby leading to potential contamination and/or undesirable delay.
However, when it is desired to manufacture the coated article of Figure 2 utilizing
the apparatus of Figure 3, zones 1-3 are set up and utilized as described above regarding the Fig. 1 article. In addition, zones 4-6 are set up just like zones 1-3, respectively. Thus,
the upper half of silicon nitride layer 6a and layers 7-10 are deposited in zones 4-6. In
other words, targets 36-41 are silicon targets in a nitrogen atmosphere of zone 4, targets
42 and 44 are nickel and/or chrome targets in an argon atmosphere in zone 5, target 43 is
a silver target in the same argon atmosphere of zone 5, and targets 45-50 are silicon
targets in a mtrogen atmosphere of zone 6. Thus, all six zones (i.e., zones 1-6) are
utilized when forming the layer system of the Figure 2 coated article.
Unfortunately, as can be seen from the above, it is often desired to manufacture
coated articles of different types such as those of Figures 1 and 2. If this is to be done
utilizing the same sputter coating apparatus, such an apparatus must be obtained which
has enough zones and targets to enable the coating system having the largest number of
layers to be manufactured. Thus, one desiring to manufacture the articles of both Figure
1 and Figure 2 would have to purchase a sputter coating apparatus such as that shown in
Figure 3 having sufficient zones and targets to accommodate the Figure 2 article.
Unfortunately, many of these zones and targets are wasted and not utilized when only the
article of Figure 1 is manufactured (i.e., certain zones and/or targets would likely be
inoperative during manufacture of the Figure 1 article). In other words, a significant
portion of the coating apparatus may not be used when certain coated articles having a
small number of layer(s) are being manufactured. Yet another problem is that when it is desired to upgrade a particular sputter coating apparatus, the line (i.e., all zones 1-6) must
be shut down.
In view of the above, it will be appreciated by those skilled in the art that there
exist a need for a sputter coating apparatus which can more efficiently manufacture
sputter coated articles of different types without wasting significant resources (e.g., zones
and/or targets). There also exists a need in the art for a corresponding method.
It is a purpose of different embodiments of this invention to fulfill any and/or all
of the above described needs in the art, and/or other needs which will become apparent to
the skilled artisan once given the following disclosure.
An object of this invention is to provide a sputter coating apparatus capable of
more efficiently depositing different types of sputter coated layer systems.
Another object of this invention is to provide a sputter coating apparatus including
first and second sputter coating lines that are selectively coupleable to one another via a
transition zone. Each of the first and second sputter coating lines may be independently
utilized to deposit particular coating systems on a substrate. However, when it is desired
to deposit a coating system having more than a predetermined number of layers (e.g., a
layer system having more layers than either of the lines is capable for depositing), the
transition zone couples the two lines together thereby enabling an incompleted sputter coated article leaving the first sputter coating line to be routed to the second sputter
coating line so that additional layer(s) may be sputter coated thereon. Thus, the two
sputter coating lines may be used either independently (e.g., run in parallel to one
another), or alternatively may be used in conjunction with one another (e.g., run in series
with one another).
Yet another object of this invention is to fulfill any and/or all of the aforesaid
objects and/or needs.
Generally speaking, certain embodiments of this invention fulfill one or more of
the above-listed needs and/or objects by providing a sputter coating apparatus
comprising:
a first sputter coating line including a plurality of zones and a plurality of targets;
a second sputter coating line including a plurality of zones and a plurality of
targets; and
a transition zone coupled to the first sputter coating line and the second sputter
coating line, said transition zone selectively coupling the first and second sputter coating
lines to one another so that when not coupled to one another the first and second lines can
run in parallel with one another and when coupled to one another by the transition zone
the first and second lines run in series with one another. Certain other embodiments of this invention fulfill one or more of the above-listed
needs and/or objects by providing a method of sputter coating a glass substrate, the
method comprising the steps of:
providing the glass substrate;
causing the glass substrate to pass through a first sputter coating line including a
plurality of zones and a plurality of targets so that at least first and second layers are
sputtered onto the first substrate in the first sputter coating line;
determining whether it is desired to provide additional layers on the glass
substrate, and if so then upon the glass substrate exiting the first sputter coating line
causing the glass substrate to be forwarded to a second sputter coating hne including a
plurality of zones and a plurality of targets; and
causing the glass substrate to pass through the second sputter coating line so that at
least third and fourth layers are sputtered onto the first substrate over the first and second
layers in the second sputter coating line.
IN THE DRAWINGS
Figure 1 is sectional view of a conventional sputter coated article.
Figure 2 is a sectional view of another sputter coated article.
Figure 3 is a schematic diagram of a conventional sputter coating apparatus. Figure 4 is a schematic functional diagram of a sputter coating apparatus
according to an embodiment of this invention, the sputter coating apparatus including two
sputter coating lines capable of running in parallel with one another or alternatively in
series with one another.
Figure 5 is a schematic functional diagram of either the sputter coating hne "A"
and/or the sputter coating line "B" of Figure 4.
Figure 6 is a schematic functional diagram of the adjustable transition zone of the
Figure 4 sputter coating apparatus.
Figure 7 is a flowchart illustrating certain steps taken during the course of carrying
out a particular embodiment of this invention.
Figure 8 is a schematic functional diagram of a transition zone for selectively
coupling ends of first and second sputter coating lines according to another embodiment
of this invention.
Figure 9 is a schematic functional diagram of an apparatus according to another
embodiment of this invention. DETAILED DESCRIPTIONS OF CERTAIN EMBODIMENTS OF THIS
INVENTION
Referring now more particularly to the accompanying drawings in which like
reference numerals indicate like parts throughout the several views.
Figure 4 is a schematic functional diagram of a sputter coating apparatus
according to an embodiment of this invention. The sputter coating apparatus of Figure 4
includes a first sputter coating line 58, a second sputter coater line 59, and adjustable
transition zone 60 coupling respective ends of the two sputter coating lines. Figure 5 is a
schematic functional diagram of both the first sputter coater line 58 and the second
sputter coater line 59 of Figure 4. As can be seen, each of the lines 58 and 59 have three
zones (zones 1-3) in this exemplary embodiment and include targets 21-35. Transition
zone 60 is provided at the end of each sputter coating line 58, 59 so as to enable the lines
to be selectively coupled to one another when desired. In other words, the two sputter
coating lines 58, 59 may be used independently from one another so as to operate in
parallel to one another when each hne is depositing an entire coating system on a
substrate independent of the other line. Alternatively, when it is desired to form a larger
coating system having more layers than one of lines 58, 59 is capable of depositing on a
substrate, then transition zone is capable of coupling hnes 58 and 59 to one another so
that the lines operate in series with one another in forming the larger coating system on
the substrate. Referring to Figure 4-5, exemplary uses of this embodiment are described as
follows. Consider a situation where one desires to manufacture significant quantities of
sputter coated articles as shown in Figure 1. In such a case, each of sputter coating lines
58 and 59 is set up so that targets 21-26 are silicon (Si) targets in a nitrogen atmosphere
of zone 1, targets 27 and 29 are nickel and/or nickel-chrome targets in an argon (Ar)
atmosphere of zone 2, target 28 is a silver (Ag) target in the argon atmosphere of zone 2,
and targets 30-35 are silicon (Si) targets in a nitrogen atmosphere of zone 3. Thus, in
each coating line 58, 59, zones 1 and 3 deposit the respective silicon nitrides layer 2 and
6, while layers 3-5 are deposited in zone 2. In other words, coating line 58 functions to
form the layer system of the Fig. 1 coated article, as does coating line 59. The two lines
may work on parallel with one another in an independent manner. When operating in
parallel with one another, hnes 61 and 62 in Figure 4 illustrate respective paths of
substrates being coated as they pass through the respective sputter coating lines and
transition zone 60, so that Fig. 1 coated articles formed in each of lines 58 and 59 exit
transition zone 60 as illustrated.
Accordingly, it can be seen that the sputter coating apparatus of Figures 4-5
enables coated articles as shown in Figure 1 to be manufactured without the requirement
for a significant number of inoperative zones and/or chambers. In other words,
significant or substantial portions of both sputter coating hne 58 and sputter coating line 59 are in operation at all times during the manufacture of Figure 1 coated articles.
Significant resources are not being wasted. Alternatively, in other embodiments of this
invention it is possible to run sputter coating lines 58 and 59 in parallel with one another
while line 58 is forming a first type of layer system (e.g., Si3N4/NiCr/Ag/NiCr/Si3N4)
and line 59 is forming a second type of layer system (e.g., SnO/Ag/SnO) on respective
substrates 1.
However, consider the scenario where one desires to utilize the Figure 4-5 sputter
coating apparatus to manufacture coated articles as shown in Figure 2 (e.g., a dual silver
layer system). In such a case, the first sputter coating line 58 is set up to deposit layers 2-
5 and a lower portion of layer 6a on substrate 1. Upon leaving the first sputter coating
line 58, the incomplete coated article enters transition zone 60 which directs the
incomplete coated article to an end of the second sputter coating line 59 as shown by
dotted line 63 in Figure 4. Reversible sputter coating line 59 is set up so as to deposit the
remainder of layers 6a as well as layers 7-10 on substrate 1. The resulting Figure 2
coated article exits the second coating line 59 at the other end 67 thereof as shown in
Figure 4. Thus, the two coating lines 58 and 59 work in series with one another as a first
portion of the coating system is deposited by sputter coating line 58 and a second
subsequent portion of the coating system is deposited by sputter coating line 59.
Adjustable transition zone 60 selectively couples the output end of first coating Hne 58 to an input output end of coating line 59. Thus, layer 2 is deposited in zone 1 of Hne 58,
layers 3-5 in zone 2 of line 58, the first half of layer 6a in zone 3 of line 58, the second
half of layer 6a in zone 3 of Hne 59, layers 7-9 in zone 2 of line 59, and layer 10 in zone 1
of sputter coating line 59 (e.g., zones 1-3 of line 58 may be set up in the same manner as
zone 1-3 of line 59 so that the incomplete coated article exiting line 58 may enter the
second sputter coating Hne 59 from either end thereof as a function of convenience).
As can be seen by the different substrate paths illustrated by reference numerals 62
and 63 in Figure 4, sputter coating line 59 is reversible in that substrates may pass
therethrough in either direction depending upon the functionality of transition zone 60
(i.e., whether transition zone 60 is causing coated articles exiting Hnes 58, 59 to pass
straight through as shown by reference numerals 61 and 62 to exit the overall coating
apparatus, or whether transition zone 60 is directing incomplete coated articles exiting
coating line 58 to an input of coating line 59 as shown by reference numeral 63).
Figure 6 is a functional top view diagram of transition zone 60 which selectively
couples respective ends of sputter coating lines 58 and 59 according to the Figure 4-5
embodiment of this invention. As can be seen, transition zone 60 includes conveyor 70
coupled to an output end of sputter coating line 58, rotatable conveyor platform 71
including conveyor 75 which may be selectively deployable in different positions,
conveyor 72 provided between a potential output of conveyor 75 and conveyor 74, conveyor 73 provided between another potential output of conveyor 75 and an output of
the overall sputter coating apparatus, and reversible conveyor 74 provided at an
input/output of sputter coating line 59. End 83 of line 59 can function as an output end
when lines 58 and 59 are operating in parallel with one another, and as an input end of
Hne 59 when Hnes 58 and 59 are operating in series with one another. Platform 71 and
conveyor 75 thereon are selectively deployable in different positions in order to
selectively couple output end 81 of sputter coating line 58 to an input/output 83 end of
sputter coating line 59 when desired.
When sputter coating Hnes 58 and 59 are not coupled together by transition zone
60, platform 71 and conveyor 75 are in the position illustrated in Figure 6 by solid lines
so that lines 58 and 59 are operating in parallel with one another. In this case, for
example, Figure 1 coated articles may be exiting sputter coating line 58 at output 81 and
are being conveyed to the overall output of the apparatus by conveyor 70 which dumps
articles onto conveyor 75 which dumps them onto conveyor 73. Likewise, Figure 1
coated articles may simultaneously be exiting output 83 of sputter coating Hne 59, and
being forwarded to the output of the overall apparatus by conveyor 74 as shown by the
solid lines illustrated in conveyor 74.
When it is desired make a larger coating system (e.g., the layer system of Fig. 2)
on a substrate having more layers than either of lines 58, 59 is capable of forming, then the direction of conveyor 74 may be reversed and platform 71 may be rotated 85 in order
to selectively couple output 81 of sputter coating Hne 58 to an input end 83 of sputter
coating line 59. See Fig. 6 in this regard. Rotation 85 moves conveyor 75 from the sohd
line position to the dotted line position shown in Figure 6. Accordingly, an incomplete
coated article exits coating line 58 at 81 onto conveyor 70 (e.g., when making the Fig. 2
layer system, the coated article at this point may include layers 2-5 and half of layer 6a on
substrate 1). The incomplete article is dumped onto conveyor 75 by conveyor 70. Once
on conveyor 75, platform 71 rotates 85 until conveyor 75 is in the position illustrated in
dotted lines in Figure 6. Conveyor 75 then dumps the incomplete article onto conveyor
72, which in turn dumps the incomplete coated article onto conveyor 74 which is
traveling in direction 86 (i.e., its reverse direction). Conveyor 74 then conveys the
incomplete coated article to input 83 of coating line 59 so that the additional layer(s) can
be sputter coated thereon (e.g., the rest of layer 6a and layers 7-10 may be deposited on
substrate 1 in line 59).
Once an incomplete coated article exiting line 58 has been forwarded to conveyor
72 by conveyor 75, platform 71 may rotate back to the solid line position shown in Figure
6 in order to accept another complete or incomplete coated article from output 81 of
coating line 59. Whether or not additional layer(s) are to be deposited on newly received
article(s) determines whether or not platform 71 causes an article received thereon to be forwarded to conveyor 72 or conveyor 73. Likewise, the direction of conveyor 74 is
determined by whether or not end 83 of coating line 59 is functioning as an output or an
input (end 83 functions as an input when receiving incomplete coated articles from
conveyor 72 and platform 71).
Figure 7 is a flowchart illustrating certain steps carried out and in accordance with
an embodiment of this invention. Referring to Figures 4-7, and especially Figure 7, a
substrate 1 (e.g., soda-lime-silica glass substrate) is first provided (step 90). Substrate 1
is then conveyed through a first sputter coating line 58 so that a pluraHty of layer(s) can
be deposited thereon (step 91) (e.g., layers 2-6 of Fig. 1, or layers 2-6a of Fig. 2). The
coated article including a plurality of sputter coated layers on substrate 1 then exits the
first sputter coating line 58 and enters transition zone 60 (step 92). A determination is
then made by controller 101 as to whether or not the desired layer system has been
completed or whether additional layers need to be sputter-coated thereon (step 93). This
determination by controller 101 may be based upon input from a keyboard, or any other
suitable means such as a programmed listing of articles to be made by the system. If it is
determined that the layering system has been completed and no additional layers need be
sputtered thereon, then the sputter coated article exits the transition zone (step 94) and the
overall sputter coating apparatus (step 95) when conveyor 75 is in the position shown in
Figure 6 by solid lines. However, when controller 101 (which may access and utilize programs stored in memory 103) determines in step 93 that the layering system is
incomplete and requires additional layer(s), then controller 101 causes motor 105 to
rotate platform/disk 71 so as to move conveyor 75 and the coated article thereon to the
position 90 shown in dotted lines in Figure 6. Then, the coated article is conveyed to end
83 of sputter coating line 59 via conveyor 72 and conveyor 74 (step 96). The coated
article enters sputter coating line 59 so that additional layers (e.g., the remainder of layer
6a and layers 7-10) can be sputtered thereon (step 97). After passing through sputter
coating Hne 59, the article exits the coating apparatus/system at 67 (step 95).
It is noted that transition zone 60 is preferably maintained in a given atmosphere
(e.g., argon atmosphere) at a low pressure similar to the pressures in zones 1-3 (e.g., from
about 1.0 to 3.0 x 10"J Torr) according to certain -embodiments of this invention, so as to
reduce the potential for contamination of coated articles when traveHng between coating
lines 58 and 59.
Figure 8 is a functional schematic diagram of a transition zone for selectively
coupling sputter coating line 58 and sputter coating line 59 according to another
embodiment of this invention. This embodiment is similar to that of Figs. 4-6, except
that the two lines 58 and 59 are staggered relative to one another so that second line 59
need not have a reversible conveyor. In other words, in the Fig. 8 embodiment end 83 of second sputter coating line 59 is an input end of line 59 regardless of whether Hnes 58
and 59 are operating in parallel or in series.
An exemplary operation of the Fig. 8 embodiment is as follows. A substrate 1 is
fed into and passes through first sputter coating Hne 58 including targets 21-35 (see Fig.
5) so that layer 2 is deposited in zone 1, layers 3-5 in zone 2, and layer 6 or half of layer
6a in zone 3. The article including these layers exits the first sputter coating line 58 via
conveyor 70. The article is fed onto conveyor 75. It is determined (either at this time or
in advance) whether additional layer(s) have to be deposited onto the article. If not, then
platform 71 remains in the position shown in fig. 8 and conveyor 75 forwards the article
with complete layering system thereon to conveyor 73 which takes the coated article out
of transition zone 60 and out of the overall sputter coating apparatus. However, if it is
desired to provide additional layer(s) on the article, then platform 71 rotates as discussed
above until conveyor 75 is in position 90 shown in dotted lines in Fig. 8. This enables
conveyor 75 to forward the article to conveyor 92 which need not be reversible in all
embodiments. Once on conveyor 92, the article enters second sputter coating line 59
including zones 1-3 and respective targets (e.g., see Fig. 5). In second line 59, the
remainder of layer 6a is sputtered on in zone 1, layers 7-9 are sputtered on in zone 2, and
layer 10 is sputtered on in zone 3 of line 59. Alternatively, lines 58 and 59 may operate in parallel with one another so that each can form the layering system of Fig. 1 on
respective substrates 1 at the same time.
It is also noted that the coated articles of Figures 1 and 2 are provided for purposes
of example only and are not intended to be limiting. The sputter coating apparatus of
Figures 4-6 and 8, and method of Figure 7, may be utilized to manufacture any type of
sputter coated article according to different embodiments of this invention. Coating lines
58 and 59 may be operated in the same direction in parallel with one another as shown by
paths 61 and 62 when the two lines are not coupled to one another. However, when it is
desired to utilize both lines 58 and 59 to manufacture a single coated article, transition
zone 60 functions to selectively couple an output end of a first line to an input end of a
second line so that the lines 58 and 59 run in series with one another. The second line
may be reversible in nature so that its input end may also function as an output end when
it is operating in series with the first line (e.g., path 62). Moreover, the instant invention
need not be limited to sputter coating apparatuses, and may be used in conjunction with
other types of layer deposition systems.
Figure 9 is a functional top view diagram of transition zone or chamber 101 which
selectively couples respective ends or portions of sputter coating lines 58 and 59
according to the Figure 4-5 embodiment of this invention. As illustrated, each coating
line includes a transfer chamber 102, a buffer chamber 103, and an exit chamber 104. Transfer zone or chamber 101 in this embodiment is located between the buffer chambers
103 of the two sputter coating lines. As illustrated, transfer in chamber/zone 101 is
performed by enabling coated glass to be moved in the chamber/zone 101 in a direction
perpendicular to the line directions of Hnes 58, 59. Accordingly, buffer chambers 103
also are capable of causing coated glass to be transferred in both the (a) line directions of
Hnes 58, 59 (i.e., the same direction the glass is transported during sputter coating in the
line), and (b) directions transverse to the Hne directions of lines 58, 59. Chambers 101
and 103 may be approximately the same size as one another.
Transition zone/chamber 101 preferably has a gate and/or valve 105 at each end
thereof, such gates/valves being selectively openable/closeable in order to allow coated
glass to enter/leave the chamber 101 and thus be transferred from one coating line to the
other coating line.
Transition zone/chamber 101 may include a conveyor (e.g., reversible conveyor)
coupled to the buffer chamber 103 of coating line 58 and the buffer chamber 103 of line
59 so as to enable coated glass to be transferred from one coating line to the other.
Controller 106, using program(s) stored in memory 107, selectively controls gates 105
and a conveyor of the chamber 101 so as to enable such transfers when desired.
Exit chambers 104 can function as output ends of the coating lines when lines 58
and 59 are operating in parallel with one another (i.e., where substrates proceed through the coating lines along paths 110 shown in dotted lines). Thus, when sputter coating lines
58 and 59 are not coupled together by transition zone 101, the coating lines 58 and 59
are operating in parallel with one another so that substrates proceeding therethrough
move along paths 110 (dotted lines) and Figure 1 coated articles may be formed and
caused to exit sputter coating lines 58 and 59 at exit chambers 104.
Still referring to Fig. 9, when it is desired make a larger coating system (e.g., the
layer system of Fig. 2) on a substrate having more layers than either of lines 58, 59 is
capable of forming, then transition zone/chamber 101 may be used (including opening of
gates/valves 105) to selectively couple the buffer chambers 103 of the respective Hnes 58,
59 thereby coupling sputter coating line 58 to sputter coating line 59. Path 111 is now
used in the Fig. 9 embodiment. Accordingly, an incomplete coated article exits coating
line 58 at 81 and moves into the buffer chamber 103 of Hne 58. From this buffer, the
incomplete article is caused to change directions (see path 111 in Fig. 9) and proceed into
transition zone 101 (e.g., via a conveyor) and then out of zone 101 and into buffer 103 of
the other sputter coating line 59 (e.g., when making the Fig. 2 layer system, the coated
article at this point may include layers 2-5 and half of layer 6a on substrate 1). The
incomplete article is then dumped on line 59 (which is in reverse) and enters the Hne at
83 so that the additional layer(s) can be sputter coated thereon (e.g., the rest of layer 6a
and layers 7-10 may be deposited on substrate 1 in line 59). Then, what had been an input end of line 59 becomes an output end of line 59 when Fig. 2 coated articles are
made in accordance with the Fig. 9 embodiment of this invention.
Still referring to Fig. 9, Fig. 1 coated articles may be produced using one or both
lines 58, 59 for several days at a time (or alternatively, for only several hours at a time).
Then, gates 105 may be opened (manually, or automatically via controller) so that Fig. 2
coated articles can be produced using lines 58-59 as described above. Thus, there is no
need to make a determination in the controller after each glass sheet runs through whether
the next sheet will go to the other line or not (however, this may in fact be done in certain
embodiments).
Once given the above disclosure, many other features, modifications, and
improvements will become apparent to the skilled artisan. Such other features,
modifications, and improvements are therefore considered to be a part- of this invention,
the scope of which is to be determined by the following claims.

Claims

WHAT IS CLAIMED IS:
1. A sputter coating apparatus comprising:
a first sputter coating Hne including a plurality of zones and a plurality of
targets;
a second sputter coating Hne including a plurahty of zones and a plurality
of targets; and
a transition chamber or zone including first and second gates or valves
which may be selectively opened, said transition chamber being selectively coupleable to
the first sputter coating line and the second sputter coating line,
said transition chamber selectively coupling the first and second sputter
coating lines to one another so that when not coupled to one another the first and second
lines can run in parallel with one another and when coupled to one another by the
transition chamber the first and second Hnes run in series with one another.
2. The sputter coating apparatus of claim 1, wherein said transition chamber is
maintained at a pressure less than atmospheric pressure.
3. The sputter coating apparatus of claim 2, wherein said transition chamber is
maintained at a pressure of from about 1.0 to 3.0 x 10"'3 Torr.
4. The sputter coating apparatus of claim 1, wherein said second sputter coating
Hne is reversible so that a first end of said second sputter coating Hne is an output end of
said second sputter coating line when the first and second sputter coating lines are
running in parallel to one another and said first end of said second sputter coating line is
an input end of said second sputter coating line when said first and second sputter coating
lines are running in series with one another.
5. The sputter coating apparatus of claim 1, wherein said transition chamber
comprises a conveyor that may be selectively moves between first and second positions
depending upon whether said first and second sputter coating lines are running in parallel
or in series with one another.
6. A method of sputter coating a glass substrate, the method comprising:
providing the glass substrate;
causing the glass substrate to pass through a first sputter coating line including a
plurality of zones and a plurality of targets so that at least first and second layers are
sputtered onto the first substrate in the first sputter coating Hne;
upon the glass substrate exiting the first sputter coating line, forwarding the glass
substrate to a second sputter coating line including a plurality of zones and a plurality of
targets; and causing the glass substrate to pass through the second sputter coating Hne so that at
least third and fourth layers are sputtered onto the first substrate over the first and second
layers in- the second sputter coating Hne.
7. A method of operating a sputter coating apparatus, the method comprising:
providing first and second sputter coating lines selectively coupleable to one
another;
causing a substrate to pass through the first sputter coating line so that at least first
and second layers are sputtered onto the substrate in the first sputter coating line;
determining whether additional layer(s) is/are to be sputtered onto the substrate;
based upon a result of said determining step, determining whether to forward the
substrate to the second sputter coating line or to an apparatus exit area.
PCT/US2001/031597 2000-10-11 2001-10-11 Apparatus for continuous sputter-deposition Ceased WO2002031216A2 (en)

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Application Number Priority Date Filing Date Title
US09/685,568 2000-10-11
US09/685,568 US6336999B1 (en) 2000-10-11 2000-10-11 Apparatus for sputter-coating glass and corresponding method
US09/731,055 US6358377B1 (en) 2000-10-11 2000-12-07 Apparatus for sputter-coating glass and corresponding method
US09/731,055 2000-12-07

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US5019234A (en) * 1990-06-08 1991-05-28 Vlsi Technology, Inc. System and method for depositing tungsten/titanium films
JPH05171441A (en) * 1991-12-17 1993-07-09 Nippon Sheet Glass Co Ltd Sputtering device
JPH10183347A (en) * 1996-12-25 1998-07-14 Ulvac Japan Ltd Film forming apparatus for magneto-resistive head

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EP2626144A1 (en) 2012-02-07 2013-08-14 Nederlandse Organisatie voor toegepast -natuurwetenschappelijk onderzoek TNO Roll to roll manufacturing system having a clean room deposition zone and a separate processing zone
WO2013119110A1 (en) 2012-02-07 2013-08-15 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Manufacturing facility and method of manufacturing
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US9610602B2 (en) 2012-02-07 2017-04-04 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Manufacturing facility and method of manufacturing
CN113703408A (en) * 2021-08-27 2021-11-26 和能人居科技(天津)集团股份有限公司 Control method of plate coating production line and production line

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