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WO2002002833A3 - Preparation of pure ferric chloride from hydrochloric acid solutions by solvent extraction - Google Patents

Preparation of pure ferric chloride from hydrochloric acid solutions by solvent extraction Download PDF

Info

Publication number
WO2002002833A3
WO2002002833A3 PCT/RU2001/000231 RU0100231W WO0202833A3 WO 2002002833 A3 WO2002002833 A3 WO 2002002833A3 RU 0100231 W RU0100231 W RU 0100231W WO 0202833 A3 WO0202833 A3 WO 0202833A3
Authority
WO
WIPO (PCT)
Prior art keywords
ferric chloride
solutions
hydrochloric acid
extraction
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2001/000231
Other languages
French (fr)
Other versions
WO2002002833B1 (en
WO2002002833A2 (en
Inventor
Leonid Irineevich Sklokin
Vladimir Trofimovic Kalinnikov
Walter Sieckman
Satish Wadhawan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU2000116021/12A external-priority patent/RU2171786C1/en
Application filed by Individual filed Critical Individual
Priority to AU69641/01A priority Critical patent/AU6964101A/en
Publication of WO2002002833A2 publication Critical patent/WO2002002833A2/en
Publication of WO2002002833A3 publication Critical patent/WO2002002833A3/en
Publication of WO2002002833B1 publication Critical patent/WO2002002833B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/0009—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/262—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds using alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The present invention relates to a field of preparing high-purity ferric chloride from hydrochloric solutions containing impurities. More specifically the invention concerns a ferric iron extraction from water solutions as a result of concentrated hydrochloric acid interaction with iron-containing concentrates, as a result of multi-stage extraction of ferric chloride from solutions of complicated composition and due to processing of industrial wastes, including spent etching solutions of metallurgical plants after chlorination. The essence of the invention is that the proposed method includes two stages of concentration, extraction, and stripping steps. As an extracting agent use is made of aliphatic alcohol, predominantly octanol-1, octanol-2, 2-ethylgexanol, and decanol-1 or their mixtures. The alcohol content in organic phase is up to 100 %. Attained technical result consists in obtaining high-purity ferric chloride solution with not less than 300 kg/m3 FeCl3 concentration. Ferric chloride recovery is 96-98 % irrespective of the nature of impurities present in a feed hydrochloric solution concurrently with the limitation of waste solutions and optimization of material flows and equipment used. The resulting ferric chloride solutions are feasible for further processing in high performance installations of spray roasting which permit combine in one process receiving of high-purity ferric oxide and regenerated hydrochloric acid of high concentration.
PCT/RU2001/000231 2000-06-19 2001-06-18 Preparation of pure ferric chloride from hydrochloric acid solutions by solvent extraction Ceased WO2002002833A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU69641/01A AU6964101A (en) 2000-06-19 2001-06-18 A method for preparing ferric chloride solution

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2000116021/12A RU2171786C1 (en) 2000-06-19 Method of preparing trivalent iron chloride solution (variants)
RU2000116021 2000-06-19

Publications (3)

Publication Number Publication Date
WO2002002833A2 WO2002002833A2 (en) 2002-01-10
WO2002002833A3 true WO2002002833A3 (en) 2002-06-27
WO2002002833B1 WO2002002833B1 (en) 2002-09-26

Family

ID=20236495

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2001/000231 Ceased WO2002002833A2 (en) 2000-06-19 2001-06-18 Preparation of pure ferric chloride from hydrochloric acid solutions by solvent extraction

Country Status (2)

Country Link
AU (1) AU6964101A (en)
WO (1) WO2002002833A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT512384A1 (en) * 2011-12-16 2013-07-15 Sms Siemag Process Technologies Gmbh Process for the concentration and separation of metal chlorides in / from an iron (III) chloride-containing hydrochloric acid solution
CN110304661A (en) * 2019-06-20 2019-10-08 李柏丛 New process for preparing high-performance iron oxide for soft ferrite
RU2725322C1 (en) * 2020-02-18 2020-07-02 Федеральное государственное бюджетное учреждение науки Федеральный исследовательский центр "Кольский научный центр Российской академии наук" (ФИЦ КНЦ РАН) Method of purifying a chloride solution from iron
CN116606978B (en) * 2023-03-24 2025-09-09 中国恩菲工程技术有限公司 Purification method of high-concentration iron ions in hydrochloric acid solution

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497330A (en) * 1965-02-08 1970-02-24 Kaiser Aluminium Chem Corp Solvent extraction of iron from phosphoric acid
US3725527A (en) * 1968-09-19 1973-04-03 Kanto Denka Kogyo Kk Process for recovering pure aqueous solution of ferric chloride and aqueous solution of metal chlorides free of ferric chloride from ferrous metal material
US4490338A (en) * 1979-08-13 1984-12-25 Metallurgie Hoboken-Overpelt Process for separating trivalent iron from an aqueous chloride solution
US5718874A (en) * 1996-12-19 1998-02-17 Thomson Consumer Electronics, Inc. Solvent extraction method of separating ferric chloride from nickel chloride
WO1999043408A1 (en) * 1998-02-25 1999-09-02 Wadhawan Satish C Solvent extraction of ferric chloride

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497330A (en) * 1965-02-08 1970-02-24 Kaiser Aluminium Chem Corp Solvent extraction of iron from phosphoric acid
US3725527A (en) * 1968-09-19 1973-04-03 Kanto Denka Kogyo Kk Process for recovering pure aqueous solution of ferric chloride and aqueous solution of metal chlorides free of ferric chloride from ferrous metal material
US4490338A (en) * 1979-08-13 1984-12-25 Metallurgie Hoboken-Overpelt Process for separating trivalent iron from an aqueous chloride solution
US5718874A (en) * 1996-12-19 1998-02-17 Thomson Consumer Electronics, Inc. Solvent extraction method of separating ferric chloride from nickel chloride
WO1999043408A1 (en) * 1998-02-25 1999-09-02 Wadhawan Satish C Solvent extraction of ferric chloride

Also Published As

Publication number Publication date
WO2002002833B1 (en) 2002-09-26
WO2002002833A2 (en) 2002-01-10
AU6964101A (en) 2002-01-14

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