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WO2002083988A3 - Micro-engineered reactors - Google Patents

Micro-engineered reactors Download PDF

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Publication number
WO2002083988A3
WO2002083988A3 PCT/GB2002/001608 GB0201608W WO02083988A3 WO 2002083988 A3 WO2002083988 A3 WO 2002083988A3 GB 0201608 W GB0201608 W GB 0201608W WO 02083988 A3 WO02083988 A3 WO 02083988A3
Authority
WO
WIPO (PCT)
Prior art keywords
micro
reactor
engineered
precursor material
primary product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2002/001608
Other languages
French (fr)
Other versions
WO2002083988A2 (en
Inventor
John Edward Andrew Shaw
Richard E Shute
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AstraZeneca AB
Original Assignee
AstraZeneca AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0109239A external-priority patent/GB0109239D0/en
Application filed by AstraZeneca AB filed Critical AstraZeneca AB
Priority to JP2002581720A priority Critical patent/JP2004530044A/en
Priority to EP02718329A priority patent/EP1377693A2/en
Publication of WO2002083988A2 publication Critical patent/WO2002083988A2/en
Publication of WO2002083988A3 publication Critical patent/WO2002083988A3/en
Priority to US10/671,694 priority patent/US20050072686A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/04—Sodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/535—Organo-phosphoranes
    • C07F9/5352—Phosphoranes containing the structure P=C-
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/03—Acyclic or carbocyclic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/09—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/11—Halogen containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00835—Comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00853—Employing electrode arrangements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00867—Microreactors placed in series, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00873—Heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00925—Irradiation
    • B01J2219/00934—Electromagnetic waves
    • B01J2219/00936—UV-radiations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00993—Design aspects
    • B01J2219/00995—Mathematical modeling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention relates to a micro-engineered reactor device comprising a closely coupled reactor and electrochemical cell, and a method of using such a reactor for the synthesis of organic compounds by a process involving an electrochemical reaction. The synthetic processes are of a type in which a source material is electrochemically converted to a reactive primary product which is exposed at a reaction region within a channel, or chamber, to a precursor material so that the primary product and precursor material react to generate a secondary product.
PCT/GB2002/001608 2001-04-12 2002-04-05 Micro-engineered reactors Ceased WO2002083988A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2002581720A JP2004530044A (en) 2001-04-12 2002-04-05 Micro-engineered reactor
EP02718329A EP1377693A2 (en) 2001-04-12 2002-04-05 Micro-engineered reactors
US10/671,694 US20050072686A1 (en) 2001-04-12 2003-09-29 Micro-engineered reactors

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB0109239A GB0109239D0 (en) 2001-04-12 2001-04-12 Micro-engineered reactors
GB0109239.4 2001-04-12
GB0126182.5 2001-10-31
GB0126182A GB0126182D0 (en) 2001-04-12 2001-10-31 Micro-engineered reactors

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/671,694 Continuation US20050072686A1 (en) 2001-04-12 2003-09-29 Micro-engineered reactors

Publications (2)

Publication Number Publication Date
WO2002083988A2 WO2002083988A2 (en) 2002-10-24
WO2002083988A3 true WO2002083988A3 (en) 2003-02-06

Family

ID=26245971

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2002/001608 Ceased WO2002083988A2 (en) 2001-04-12 2002-04-05 Micro-engineered reactors

Country Status (4)

Country Link
US (1) US20050072686A1 (en)
EP (1) EP1377693A2 (en)
JP (1) JP2004530044A (en)
WO (1) WO2002083988A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9377448B2 (en) 2005-10-14 2016-06-28 Thermo Scientific (Bremen) Gmbh Method for providing a substance for the analysis of isotope ratios

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0126281D0 (en) * 2001-11-01 2002-01-02 Astrazeneca Ab A chemical reactor
AU2003232825A1 (en) * 2002-05-24 2003-12-12 Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. Method for transferring molecules from a chemically reacting first flow into an adjacent chemically second reacting flow
DE10318864B3 (en) * 2003-04-25 2004-09-23 Siemens Ag Micro-fluidic valve, for controlled introduction of fluid into channel during capillary electrophoresis, combines electrical potential gradient with curvature inducing Coanda effect
US7622509B2 (en) * 2004-10-01 2009-11-24 Velocys, Inc. Multiphase mixing process using microchannel process technology
JP4779108B2 (en) * 2004-10-06 2011-09-28 国立大学法人京都大学 Microflow electrochemical reactor and organic compound synthesis method using the same
JP4591759B2 (en) * 2004-11-05 2010-12-01 横河電機株式会社 Micro electrochemical reactor
US7655126B2 (en) 2006-03-27 2010-02-02 Federal Mogul World Wide, Inc. Fabrication of topical stopper on MLS gasket by active matrix electrochemical deposition
EP1889849A1 (en) * 2006-07-18 2008-02-20 Lonza Ag Grignard reactions in microreactors
US20100204459A1 (en) * 2007-08-27 2010-08-12 The Regents Of The University Of California Systems and methods for producing multi-component colloidal structures
US20110031082A1 (en) * 2009-08-06 2011-02-10 Chen-Lung Chi Wheeled luggage device with brake
US20130026409A1 (en) * 2011-04-08 2013-01-31 Recapping, Inc. Composite ionic conducting electrolytes
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497428A (en) * 1968-03-28 1970-02-24 Nalco Chemical Co Preparation of organo metallic compounds
US3630858A (en) * 1970-08-24 1971-12-28 Du Pont A.c. electrolytic process
US4250000A (en) * 1979-03-26 1981-02-10 Stauffer Chemical Company Electrochemical process for metal alkoxides
US4464233A (en) * 1981-11-25 1984-08-07 The Secretary Of State For Defense In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Preparation of adducts which may be used in the preparation of compound semiconductor materials
US4652355A (en) * 1985-09-13 1987-03-24 The Dow Chemical Company Flow-through electrolytic cell
US4988416A (en) * 1988-11-23 1991-01-29 Societe Nationale Des Poudres Et Explosifs Process for the electrosynthesis of aldehydes
US5580523A (en) * 1994-04-01 1996-12-03 Bard; Allen J. Integrated chemical synthesizers
WO1998025701A1 (en) * 1996-12-11 1998-06-18 The Regents Of The University Of California Microfabricated sleeve devices for chemical reactions
US5916514A (en) * 1995-10-30 1999-06-29 Eshraghi; Ray R. Process of fabricating fibrous electrochemical cells
US5961832A (en) * 1994-10-22 1999-10-05 Central Research Laboratories Limited Method and apparatus for diffusive transfer between immiscible fluids
DE19841302A1 (en) * 1998-09-10 2000-03-23 Inst Mikrotechnik Mainz Gmbh Electrochemical reactor useful in oxidation of e.g. 4-methoxymethylbenzene to 4-methoxybenzaldehyde had duct as reaction chamber in capillary gap between electrodes
EP1217099A2 (en) * 2000-12-21 2002-06-26 CPC Cellular Process Chemistry Systems GmbH Microreactor for electrochemical preparations

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6149789A (en) * 1990-10-31 2000-11-21 Fraunhofer Gesellschaft Zur Forderung Der Angewandten Forschung E.V. Process for manipulating microscopic, dielectric particles and a device therefor
US5632957A (en) * 1993-11-01 1997-05-27 Nanogen Molecular biological diagnostic systems including electrodes
US5639423A (en) * 1992-08-31 1997-06-17 The Regents Of The University Of Calfornia Microfabricated reactor
US5427663A (en) * 1993-06-08 1995-06-27 British Technology Group Usa Inc. Microlithographic array for macromolecule and cell fractionation
US6001229A (en) * 1994-08-01 1999-12-14 Lockheed Martin Energy Systems, Inc. Apparatus and method for performing microfluidic manipulations for chemical analysis
US6111096A (en) * 1997-10-31 2000-08-29 Bbi Bioseq, Inc. Nucleic acid isolation and purification

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3497428A (en) * 1968-03-28 1970-02-24 Nalco Chemical Co Preparation of organo metallic compounds
US3630858A (en) * 1970-08-24 1971-12-28 Du Pont A.c. electrolytic process
US4250000A (en) * 1979-03-26 1981-02-10 Stauffer Chemical Company Electrochemical process for metal alkoxides
US4464233A (en) * 1981-11-25 1984-08-07 The Secretary Of State For Defense In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Preparation of adducts which may be used in the preparation of compound semiconductor materials
US4652355A (en) * 1985-09-13 1987-03-24 The Dow Chemical Company Flow-through electrolytic cell
US4988416A (en) * 1988-11-23 1991-01-29 Societe Nationale Des Poudres Et Explosifs Process for the electrosynthesis of aldehydes
US5580523A (en) * 1994-04-01 1996-12-03 Bard; Allen J. Integrated chemical synthesizers
US5961832A (en) * 1994-10-22 1999-10-05 Central Research Laboratories Limited Method and apparatus for diffusive transfer between immiscible fluids
US5916514A (en) * 1995-10-30 1999-06-29 Eshraghi; Ray R. Process of fabricating fibrous electrochemical cells
WO1998025701A1 (en) * 1996-12-11 1998-06-18 The Regents Of The University Of California Microfabricated sleeve devices for chemical reactions
DE19841302A1 (en) * 1998-09-10 2000-03-23 Inst Mikrotechnik Mainz Gmbh Electrochemical reactor useful in oxidation of e.g. 4-methoxymethylbenzene to 4-methoxybenzaldehyde had duct as reaction chamber in capillary gap between electrodes
EP1217099A2 (en) * 2000-12-21 2002-06-26 CPC Cellular Process Chemistry Systems GmbH Microreactor for electrochemical preparations

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9377448B2 (en) 2005-10-14 2016-06-28 Thermo Scientific (Bremen) Gmbh Method for providing a substance for the analysis of isotope ratios

Also Published As

Publication number Publication date
EP1377693A2 (en) 2004-01-07
US20050072686A1 (en) 2005-04-07
JP2004530044A (en) 2004-09-30
WO2002083988A2 (en) 2002-10-24

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