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WO2002063091A3 - Method for providing textile material with uv protection - Google Patents

Method for providing textile material with uv protection Download PDF

Info

Publication number
WO2002063091A3
WO2002063091A3 PCT/EP2002/001179 EP0201179W WO02063091A3 WO 2002063091 A3 WO2002063091 A3 WO 2002063091A3 EP 0201179 W EP0201179 W EP 0201179W WO 02063091 A3 WO02063091 A3 WO 02063091A3
Authority
WO
WIPO (PCT)
Prior art keywords
textile material
protection
constituent
acid esters
providing textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/001179
Other languages
German (de)
French (fr)
Other versions
WO2002063091A2 (en
Inventor
Thomas Heidenfelder
Juergen Detering
Gerhard Wagenblast
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to BR0206936-9A priority Critical patent/BR0206936A/en
Priority to US10/470,265 priority patent/US20040074012A1/en
Priority to CA002437613A priority patent/CA2437613A1/en
Priority to EP02704685A priority patent/EP1383952A2/en
Priority to JP2002562817A priority patent/JP2004528486A/en
Priority to MXPA03006782A priority patent/MXPA03006782A/en
Publication of WO2002063091A2 publication Critical patent/WO2002063091A2/en
Anticipated expiration legal-status Critical
Publication of WO2002063091A3 publication Critical patent/WO2002063091A3/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/1845Aromatic mono- or polycarboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/2035Aromatic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/335Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/352Heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • D06M13/355Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358Triazines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention relates to a method for providing textile material with UV protection, whereby (a) zinc oxide and/or titanium oxide are applied to the textile material as constituent A, and (b) at least one organic UV absorber is applied to the textile material as constituent B. Constituent B preferably contains at least one compound from the group consisting of phenylbenzotriazoles, dibenzoylmethanes, p-aminobenzoic acid esters, cinnamic acid esters, salicylic acid esters, nitrogen-free 2-hydroxybenzophenones, phenylbenzimidazoles, acrylates, diarylbutadienes, amino-substituted hydroxybenzophenones, and triazines.
PCT/EP2002/001179 2001-02-06 2002-02-05 Method for providing textile material with uv protection Ceased WO2002063091A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR0206936-9A BR0206936A (en) 2001-02-06 2002-02-05 Process for finishing UV protection of textile material, detergent formulation for washing textile, formulation of after-treatment of laundry and conditioning of laundry, UV protection finishing medium of a textile, use of a zinc oxide and / or titanium dioxide together with organic UV absorbers on the textile material
US10/470,265 US20040074012A1 (en) 2001-02-06 2002-02-05 Method for providing textile material with uv protection
CA002437613A CA2437613A1 (en) 2001-02-06 2002-02-05 Uv protection of textile material
EP02704685A EP1383952A2 (en) 2001-02-06 2002-02-05 Method for providing textile material with uv protection
JP2002562817A JP2004528486A (en) 2001-02-06 2002-02-05 Method for UV protection of textile materials
MXPA03006782A MXPA03006782A (en) 2001-02-06 2002-02-05 Method for providing textile material with uv protection.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10105143.3 2001-02-06
DE10105143A DE10105143A1 (en) 2001-02-06 2001-02-06 Process for UV protective equipment of textile material

Publications (2)

Publication Number Publication Date
WO2002063091A2 WO2002063091A2 (en) 2002-08-15
WO2002063091A3 true WO2002063091A3 (en) 2003-11-27

Family

ID=7672904

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/001179 Ceased WO2002063091A2 (en) 2001-02-06 2002-02-05 Method for providing textile material with uv protection

Country Status (8)

Country Link
US (1) US20040074012A1 (en)
EP (1) EP1383952A2 (en)
JP (1) JP2004528486A (en)
BR (1) BR0206936A (en)
CA (1) CA2437613A1 (en)
DE (1) DE10105143A1 (en)
MX (1) MXPA03006782A (en)
WO (1) WO2002063091A2 (en)

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DE10161861A1 (en) 2001-12-14 2003-07-03 Basf Ag Stabilizer composition I
DE60336035D1 (en) * 2002-08-02 2011-03-31 Massimo Guarducci S R L UV-protected material and its production
US8038728B2 (en) * 2003-05-27 2011-10-18 The Hong Kong University Of Science And Technology Methods of fabric treatment
US20050005367A1 (en) * 2003-05-27 2005-01-13 The Hong Kong University Of Science And Technology Methods of fabric treatment
JP2007538082A (en) * 2004-05-18 2007-12-27 コックレル ダーマトロジー デベロップメント,リミテッド Solid synthetic soap that protects against ultraviolet rays
GB0623004D0 (en) * 2006-11-17 2006-12-27 Unilever Plc Fabric treatment method and composition to impart differential hydrophobocity
DE102007019374A1 (en) * 2007-04-23 2008-11-06 Henkel Ag & Co. Kgaa Photocatalytic material-containing liquid systems
BRPI0812279A2 (en) * 2007-05-29 2014-11-18 Henkel Corp ADHESIVE DETECTION METHODS.
DE102007042862A1 (en) * 2007-09-10 2009-03-12 Henkel Ag & Co. Kgaa Modified titanium dioxide
US20090092561A1 (en) * 2007-10-09 2009-04-09 Lupia Joseph A Body-care and household products and compositions comprising specific sulfur-containing compounds
PH12012500657A1 (en) * 2009-10-07 2012-10-22 Unilever Nv Fabric conditioners
CN102330343A (en) * 2011-07-27 2012-01-25 吴江市瑞丰织造有限公司 Ultraviolet shielding coatings for fabrics
US8690964B2 (en) 2011-10-11 2014-04-08 The Sweet Living Group, LLC Fabric having ultraviolet radiation protection
US9234310B2 (en) 2011-10-11 2016-01-12 The Sweet Living Group, LLC Fabric having ultraviolet radiation protection, enhanced resistance to degradation, and enhanced resistance to fire
US20170260395A1 (en) * 2016-03-08 2017-09-14 The Sweet Living Group, LLC Additive for incorporating ultraviolet radiation protection into a polymer
US12071548B2 (en) * 2011-10-11 2024-08-27 The Sweet Living Group, LLC Product having ultraviolet radiation protection
US10907048B2 (en) 2018-04-12 2021-02-02 The Sweet Living Group, LLC Product having ultraviolet radiation protection
US9464260B2 (en) 2011-10-11 2016-10-11 The Sweet Living Group, LLC Laundry detergent composition for providing ultraviolet radiation protection for a fabric
US20240417565A1 (en) * 2011-10-11 2024-12-19 The Sweet Living Group, LLC Product having ultraviolet radiation protection
US8277518B1 (en) 2011-10-11 2012-10-02 The Sweet Living Group, LLC Ecological fabric having ultraviolet radiation protection
CN102817236A (en) * 2012-08-28 2012-12-12 北京中纺化工股份有限公司 Efficient light fastness enhancing agent as well as preparation method and application of enhancing agent
CN102851766A (en) * 2012-08-29 2013-01-02 昆山铁牛衬衫厂 Anti-ultraviolet fiber production method
CN102851942A (en) * 2012-08-29 2013-01-02 昆山铁牛衬衫厂 Anti-ultraviolet pure cotton fabric finishing method
AU2013316703B2 (en) * 2012-09-12 2017-09-21 Nine Ip Limited Netting, crop cover, and ground cover materials
JP5369251B1 (en) * 2012-10-26 2013-12-18 株式会社アズ Method for producing cool-sensitive fiber cloth
CN103469559A (en) * 2013-08-21 2013-12-25 昆山铁牛衬衫厂 UV-resistant composite finishing agent and preparation method thereof
CN103726297B (en) * 2013-11-26 2016-10-05 常熟常圣服饰有限公司 The production technology of uvioresistant fabrics
JP6485800B2 (en) * 2014-01-07 2019-03-20 株式会社Adeka Functionality imparting agent for fibers
CN107057125A (en) * 2017-05-18 2017-08-18 句容亿格纳米材料厂 Modified salicylic acid aligns the preparation and its application in anti-light pollution plastics of octyl phenyl ester
CN110592963A (en) * 2019-10-09 2019-12-20 陈晓彤 Production process of anti-aging and anti-ultraviolet fabric
US10676861B1 (en) 2019-11-08 2020-06-09 The Sweet Living Group, LLC Method for incorporating ultraviolet radiation protection and antimicrobial protection into rayon
EP3957710A1 (en) * 2020-08-21 2022-02-23 Anna Twaróg SIMPLYQ A bacteriostatic concentrate and fabric softener and the use of the concentrate and fabric softener
CN116180464A (en) * 2021-11-29 2023-05-30 江阴泰迪服饰有限公司 Good anti-ultraviolet effect fabric and its coating formula
PE20250254A1 (en) * 2022-05-04 2025-01-29 Claros Tech Inc UV PROTECTIVE PRE-ADDITIVES FOR TEXTILES AND METHODS OF USE

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EP0523955A2 (en) * 1991-07-17 1993-01-20 Unilever Plc Water dispersible or water soluble copolymer containing UV-absorbing monomer
EP0583888A1 (en) * 1992-07-30 1994-02-23 Unilever Plc Water-dispersible UV light-absorbing copolymer
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Also Published As

Publication number Publication date
EP1383952A2 (en) 2004-01-28
BR0206936A (en) 2004-08-10
WO2002063091A2 (en) 2002-08-15
CA2437613A1 (en) 2002-08-15
MXPA03006782A (en) 2003-11-13
US20040074012A1 (en) 2004-04-22
DE10105143A1 (en) 2002-08-08
JP2004528486A (en) 2004-09-16

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