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WO2002060812A3 - Process for derivatizing carbon nanotubes with diazonium species and compositions thereof - Google Patents

Process for derivatizing carbon nanotubes with diazonium species and compositions thereof Download PDF

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Publication number
WO2002060812A3
WO2002060812A3 PCT/US2002/002562 US0202562W WO02060812A3 WO 2002060812 A3 WO2002060812 A3 WO 2002060812A3 US 0202562 W US0202562 W US 0202562W WO 02060812 A3 WO02060812 A3 WO 02060812A3
Authority
WO
WIPO (PCT)
Prior art keywords
nanotubes
carbon nanotubes
derivatization
properties
modified
Prior art date
Application number
PCT/US2002/002562
Other languages
French (fr)
Other versions
WO2002060812A2 (en
Inventor
James M Tour
Jeffrey L Bahr
Jiping Yang
Original Assignee
Univ Rice William M
James M Tour
Jeffrey L Bahr
Jiping Yang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE10295944T priority Critical patent/DE10295944T5/en
Priority to AU2002240159A priority patent/AU2002240159A1/en
Priority to KR10-2003-7010023A priority patent/KR20030091977A/en
Priority to GB0319871A priority patent/GB2389847B/en
Priority to US10/470,517 priority patent/US7250147B2/en
Priority to JP2002560970A priority patent/JP4308527B2/en
Application filed by Univ Rice William M, James M Tour, Jeffrey L Bahr, Jiping Yang filed Critical Univ Rice William M
Publication of WO2002060812A2 publication Critical patent/WO2002060812A2/en
Publication of WO2002060812A3 publication Critical patent/WO2002060812A3/en
Priority to US10/632,948 priority patent/US7384815B2/en
Priority to US10/632,419 priority patent/US7691359B2/en
Priority to US10/632,284 priority patent/US7304103B2/en
Priority to US11/840,433 priority patent/US7892517B2/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C09C1/565—Treatment of carbon black ; Purification comprising an oxidative treatment with oxygen, ozone or oxygenated compounds, e.g. when such treatment occurs in a region of the furnace next to the carbon black generating reaction zone
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

Abstract

The invention incorporates new processes for the chemical modification of carbon nanotubes. Such processes involve the derivatization of multi- and single-wall carbon nanotubes, including small diameter (ca. 0.7 nm) single-wall carbon nanotubes, with diazonium species. The method allows the chemical attachment of a variety of organic compounds to the side and ends of carbon nanotubes. These chemically modified nanotubes have applications in polymer composite materials, molecular electronic applications and sensor devices. The methods of derivatization include electrochemical induced reactions thermally induced reactions (via in-situ generation of diazonium compounds or pre-formed diazonium compounds), and photochemically induced reactions. The derivatization causes significant changes in the spectroscopic properties of the nanotubes. The estimated degree of functionality is ca. 1 out of every 20 to 30 carbons in a nanotube bearing a functionality moiety. Such electrochemical reduction processes can be adapted to apply site-selective chemical functionalization of nanotubes. Moreover, when modified with suitable chemical groups, the derivatized nanotubes are chemically compatible with a polymer matrix, allowing transfer of the properties of the nanotubes (such as, mechanical strength or electrical conductivity) to the properties of the composite material as a whole. Furthermore, when modified with suitable chemical groups, the groups can be polymerized to form a polymer that includes carbon nanotubes.
PCT/US2002/002562 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof WO2002060812A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
AU2002240159A AU2002240159A1 (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
KR10-2003-7010023A KR20030091977A (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
GB0319871A GB2389847B (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof
US10/470,517 US7250147B2 (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species
JP2002560970A JP4308527B2 (en) 2001-01-29 2002-01-29 Method for derivatizing carbon nanotubes using diazonium species and composition thereof
DE10295944T DE10295944T5 (en) 2001-01-29 2002-01-29 Process for the derivatization of carbon nanotubes with diazonium species and compositions thereof
US10/632,948 US7384815B2 (en) 2001-01-29 2003-08-01 Process for attaching molecular wires and devices to carbon nanotubes and compositions thereof
US10/632,419 US7691359B2 (en) 2001-01-29 2003-08-01 Carbon nanotubes derivatized with diazonium species
US10/632,284 US7304103B2 (en) 2001-01-29 2003-08-01 Process for making polymers comprising derivatized carbon nanotubes and compositions thereof
US11/840,433 US7892517B2 (en) 2001-01-29 2007-08-17 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US26478401P 2001-01-29 2001-01-29
US60/264,784 2001-01-29
US27290301P 2001-03-02 2001-03-02
US60/272,903 2001-03-02
US31650101P 2001-08-31 2001-08-31
US31652101P 2001-08-31 2001-08-31
US60/316,501 2001-08-31
US60/316,521 2001-08-31

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US10470517 A-371-Of-International 2002-01-29
US10/632,284 Division US7304103B2 (en) 2001-01-29 2003-08-01 Process for making polymers comprising derivatized carbon nanotubes and compositions thereof
US10/632,419 Division US7691359B2 (en) 2001-01-29 2003-08-01 Carbon nanotubes derivatized with diazonium species
US10/632,948 Division US7384815B2 (en) 2001-01-29 2003-08-01 Process for attaching molecular wires and devices to carbon nanotubes and compositions thereof

Publications (2)

Publication Number Publication Date
WO2002060812A2 WO2002060812A2 (en) 2002-08-08
WO2002060812A3 true WO2002060812A3 (en) 2002-11-14

Family

ID=27500832

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/002562 WO2002060812A2 (en) 2001-01-29 2002-01-29 Process for derivatizing carbon nanotubes with diazonium species and compositions thereof

Country Status (7)

Country Link
JP (1) JP4308527B2 (en)
KR (1) KR20030091977A (en)
CN (1) CN1309887C (en)
AU (1) AU2002240159A1 (en)
DE (1) DE10295944T5 (en)
GB (2) GB2389847B (en)
WO (1) WO2002060812A2 (en)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6911682B2 (en) 2001-12-28 2005-06-28 Nantero, Inc. Electromechanical three-trace junction devices
US6919592B2 (en) 2001-07-25 2005-07-19 Nantero, Inc. Electromechanical memory array using nanotube ribbons and method for making same
US6942921B2 (en) 2001-07-25 2005-09-13 Nantero, Inc. Nanotube films and articles
US6979590B2 (en) 2001-12-28 2005-12-27 Nantero, Inc. Methods of making electromechanical three-trace junction devices
US7120047B2 (en) 2001-07-25 2006-10-10 Segal Brent M Device selection circuitry constructed with nanotube technology
US7176505B2 (en) 2001-12-28 2007-02-13 Nantero, Inc. Electromechanical three-trace junction devices
US7264990B2 (en) 2001-07-25 2007-09-04 Nantero, Inc. Methods of nanotubes films and articles
US7274078B2 (en) 2001-07-25 2007-09-25 Nantero, Inc. Devices having vertically-disposed nanofabric articles and methods of making the same
US7304357B2 (en) 2001-07-25 2007-12-04 Nantero, Inc. Devices having horizontally-disposed nanofabric articles and methods of making the same
US7335395B2 (en) 2002-04-23 2008-02-26 Nantero, Inc. Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles
US7342818B2 (en) 2001-07-25 2008-03-11 Nantero, Inc. Hybrid circuit having nanotube electromechanical memory
US7344691B2 (en) 2001-05-17 2008-03-18 Zyvek Performance Materials, Llc System and method for manipulating nanotubes
US7375369B2 (en) 2003-09-08 2008-05-20 Nantero, Inc. Spin-coatable liquid for formation of high purity nanotube films
US7385266B2 (en) 2003-05-14 2008-06-10 Nantero, Inc. Sensor platform using a non-horizontally oriented nanotube element
US7479516B2 (en) 2003-05-22 2009-01-20 Zyvex Performance Materials, Llc Nanocomposites and methods thereto
US7544415B2 (en) 2002-05-02 2009-06-09 Zyvex Performance Materials, Inc. Polymer and method for using the polymer for solubilizing nanotubes
US7547472B2 (en) 2002-05-02 2009-06-16 Zyvex Performance Materials, Inc. Polymer and method for using the polymer for noncovalently functionalizing nanotubes
US7556746B2 (en) 2004-06-03 2009-07-07 Nantero, Inc. Method of making an applicator liquid for electronics fabrication process
US7560136B2 (en) 2003-01-13 2009-07-14 Nantero, Inc. Methods of using thin metal layers to make carbon nanotube films, layers, fabrics, ribbons, elements and articles
US7566478B2 (en) 2001-07-25 2009-07-28 Nantero, Inc. Methods of making carbon nanotube films, layers, fabrics, ribbons, elements and articles
KR101004819B1 (en) * 2009-08-27 2010-12-28 삼성전자주식회사 Composition comprising surface-modified carbon nanotubes having polymerizable moiety
US8197650B2 (en) 2007-06-07 2012-06-12 Sensor Innovations, Inc. Silicon electrochemical sensors
US8758584B2 (en) 2010-12-16 2014-06-24 Sensor Innovations, Inc. Electrochemical sensors

Families Citing this family (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004046099A2 (en) 2002-02-01 2004-06-03 William Marsh Rice University Method of making a molecule-surface interface
US8362559B2 (en) 2002-02-01 2013-01-29 William Marsh Rice University Hybrid molecular electronic devices containing molecule-functionalized surfaces for switching, memory, and sensor applications and methods for fabricating same
WO2004007364A1 (en) 2002-07-16 2004-01-22 William Marsh Rice University Process for functionalizing carbon nanotubes under solvent-free conditions
US20060252853A1 (en) * 2002-11-18 2006-11-09 Rensselaer Polytechnic Institute Nanotube polymer composite and methods of making same
KR100801820B1 (en) * 2002-11-19 2008-02-11 삼성전자주식회사 Pattern Forming Method Using Surface-Modified Carbon Nanotubes
ATE486906T1 (en) * 2002-11-27 2010-11-15 Univ Rice William M FUNCTIONALIZED NANOTUBE AND POLYMER COMPOSITES AND INTERACTIONS WITH RADIATION
WO2004058899A1 (en) * 2002-12-25 2004-07-15 Fuji Xerox Co., Ltd. Liquid mixture, structure, and method for forming structure
KR100947702B1 (en) 2003-02-26 2010-03-16 삼성전자주식회사 Pattern thin film formation method using carbon nanotubes surface-modified with curable functional groups, and method for manufacturing polymer composite
WO2005047181A2 (en) * 2003-06-03 2005-05-26 Seldon Technologies, Llc Fused nanostructure material
CA2532190C (en) * 2003-06-16 2012-08-21 William Marsh Rice University Sidewall functionalization of carbon nanotubes with hydroxyl-terminated moieties
US8187703B2 (en) * 2003-06-16 2012-05-29 William Marsh Rice University Fiber-reinforced polymer composites containing functionalized carbon nanotubes
WO2005030858A2 (en) * 2003-06-20 2005-04-07 William Marsh Rice University Polymerization initiated at the sidewalls of carbon nanotubes
US20070259994A1 (en) * 2003-06-23 2007-11-08 William Marsh Rice University Elastomers Reinforced with Carbon Nanotubes
JP2005041835A (en) * 2003-07-24 2005-02-17 Fuji Xerox Co Ltd Carbon nanotube structure, method for producing the same, carbon nanotube transfer and solution
KR20060090654A (en) * 2003-07-29 2006-08-14 윌리엄 마쉬 라이스 유니버시티 Selective functionalization of carbon nanotubes
EP2096125A3 (en) * 2003-08-05 2010-11-03 Nanocyl S.A. Polymer-based composites comprising carbon nanotubes as their loads
US7026432B2 (en) 2003-08-12 2006-04-11 General Electric Company Electrically conductive compositions and method of manufacture thereof
US7354988B2 (en) 2003-08-12 2008-04-08 General Electric Company Electrically conductive compositions and method of manufacture thereof
KR20070008506A (en) * 2003-09-05 2007-01-17 리서치 파운데이션 어브 서니 Nanocomposite fibers and films containing polyolefins and surface-modified carbon nanotubes
US7504051B2 (en) 2003-09-08 2009-03-17 Nantero, Inc. Applicator liquid for use in electronic manufacturing processes
JP2005096024A (en) * 2003-09-24 2005-04-14 Fuji Xerox Co Ltd Wire, its manufacturing method, and electromagnet using the wire
JP4449387B2 (en) * 2003-09-25 2010-04-14 富士ゼロックス株式会社 Manufacturing method of composite material
JP4380282B2 (en) * 2003-09-26 2009-12-09 富士ゼロックス株式会社 Method for producing carbon nanotube composite structure
US7309727B2 (en) 2003-09-29 2007-12-18 General Electric Company Conductive thermoplastic compositions, methods of manufacture and articles derived from such compositions
JP4945888B2 (en) * 2003-10-09 2012-06-06 富士ゼロックス株式会社 Composite and production method thereof
JP2005125187A (en) * 2003-10-22 2005-05-19 Fuji Xerox Co Ltd Gas decomposer, electrode for fuel cell, and method for manufacturing the decomposer
WO2005049488A2 (en) * 2003-10-31 2005-06-02 William Marsh Rice University Thermal treatment of functionalized carbon nanotubes in solution to effect their defunctionalization
US20080035481A1 (en) * 2004-03-04 2008-02-14 Mccormack Sean P Electrochemical Sensors
EP1732847A2 (en) * 2004-03-12 2006-12-20 William Marsh Rice University Reductive functionalization of carbon nanotubes
US8158203B2 (en) 2004-05-06 2012-04-17 William Marsh Rice University Methods of attaching or grafting carbon nanotubes to silicon surfaces and composite structures derived therefrom
US7329709B2 (en) 2004-06-02 2008-02-12 Konarka Technologies, Inc. Photoactive materials and related compounds, devices, and methods
CN101432227A (en) * 2004-06-23 2009-05-13 海珀里昂催化国际有限公司 Functionalized single walled carbon nanotubes
US7938991B2 (en) * 2004-07-22 2011-05-10 William Marsh Rice University Polymer / carbon-nanotube interpenetrating networks and process for making same
US7939047B2 (en) * 2004-07-29 2011-05-10 William Marsh Rice University Bulk separation of carbon nanotubes by bandgap
US8455583B2 (en) 2004-08-02 2013-06-04 University Of Houston Carbon nanotube reinforced polymer nanocomposites
US7226818B2 (en) 2004-10-15 2007-06-05 General Electric Company High performance field effect transistors comprising carbon nanotubes fabricated using solution based processing
WO2007050096A2 (en) 2004-11-23 2007-05-03 William Marsh Rice University Ozonation of carbon nanotubes in fluorocarbons
US7578941B2 (en) 2004-11-30 2009-08-25 William Marsh Rice University Length-based liquid-liquid extraction of carbon nanotubes using a phase transfer catalyst
US7462656B2 (en) 2005-02-15 2008-12-09 Sabic Innovative Plastics Ip B.V. Electrically conductive compositions and method of manufacture thereof
JP2008529956A (en) * 2005-02-16 2008-08-07 ユニバーシティ・オブ・デイトン Asymmetric end functionalization of carbon nanotubes
JP2006241248A (en) * 2005-03-01 2006-09-14 Bussan Nanotech Research Institute Inc Polymer composite
US7850778B2 (en) 2005-09-06 2010-12-14 Lemaire Charles A Apparatus and method for growing fullerene nanotube forests, and forming nanotube films, threads and composite structures therefrom
US7744793B2 (en) 2005-09-06 2010-06-29 Lemaire Alexander B Apparatus and method for growing fullerene nanotube forests, and forming nanotube films, threads and composite structures therefrom
JP2009528238A (en) 2005-12-19 2009-08-06 ナンテロ，インク． Formation of carbon nanotubes
JP4824414B2 (en) * 2006-01-20 2011-11-30 三洋化成工業株式会社 Thermoplastic resin modifier
JP5099010B2 (en) * 2006-08-21 2012-12-12 富士通株式会社 Manufacturing method of n-type semiconductor carbon nanomaterial and manufacturing method of semiconductor device
WO2008023399A1 (en) 2006-08-21 2008-02-28 Fujitsu Limited n-TYPE SEMICONDUCTOR CARBON NANOTUBES, PROCESS FOR PRODUCTION THEREOF, AND PROCESS FOR PRODUCTION OF SEMICONDUCTOR DEVICES
EP2121852A4 (en) 2007-02-28 2010-07-07 Ca Nat Research Council NUCLEOPHILIC SUBSTITUTION OF CARBON NANOTUBES
JP5026209B2 (en) * 2007-09-27 2012-09-12 富士フイルム株式会社 Cross-linked carbon nanotube
JP5026210B2 (en) * 2007-09-27 2012-09-12 富士フイルム株式会社 Cross-linked nanocarbon solubilizer and cross-linked nanocarbon aggregates
EP2285874B1 (en) * 2008-05-23 2016-12-07 Future Carbon GmbH Carbon nanotubes and organic media containing microgels
FR2936604B1 (en) * 2008-09-29 2010-11-05 Commissariat Energie Atomique CARBON NANOTUBE CHEMICAL SENSORS, PROCESS FOR PREPARATION AND USES
DE102008063727A1 (en) * 2008-12-18 2010-06-24 Bayer Technology Services Gmbh Electrochemical process for the reduction of molecular oxygen
FR2941938B1 (en) 2009-02-06 2011-05-06 Commissariat Energie Atomique METHOD FOR THE SEPARATION KIT OF METALLIC CARBON NANOTUBES AND SEMICONDUCTORS
KR101598544B1 (en) 2009-04-14 2016-03-02 삼성전자주식회사 Dispersible Carbon Nanotubes, Dispersible Carbon Nanotubes-Polymer Complexes and Their Preparation Method
KR100973199B1 (en) * 2009-07-27 2010-07-30 황길연 Dustproof clothing
WO2011033037A1 (en) * 2009-09-17 2011-03-24 Futurecarbon Gmbh Method for producing carbon nanomaterials and/or carbon micromaterials, and corresponding material
US9617151B2 (en) 2010-02-12 2017-04-11 Nantero Inc. Methods for controlling density, porosity, and/or gap size within nanotube fabric layers and films
FR2962052B1 (en) * 2010-07-02 2015-04-03 Commissariat Energie Atomique MATERIAL COMPRISING NANOTUBES OR NANOWILS GRAFTED IN A MATRIX, PROCESS FOR PREPARATION AND USES
CN102344587B (en) * 2010-08-05 2013-07-31 中国石油天然气股份有限公司 Modified rubber containing carbon nano tube and preparation method thereof
FR2965109B1 (en) * 2010-09-17 2012-09-28 Commissariat Energie Atomique ELECTROCHEMICAL GENERATOR AND METHOD FOR PRODUCING SUCH A GENERATOR
FR2964966B1 (en) * 2010-09-17 2013-07-19 Commissariat Energie Atomique DIAZONIUM ARYLATE SALT AND USE IN ELECTROLYTIC SOLUTION OF AN ELECTROCHEMICAL GENERATOR
US10069072B2 (en) 2010-09-20 2018-09-04 Nantero, Inc. Nanotube solutions with high concentration and low contamination and methods for purifiying nanotube solutions
EP2511393A1 (en) * 2011-04-11 2012-10-17 Siemens Aktiengesellschaft Matrix with nanotubes
US9517438B2 (en) 2011-06-13 2016-12-13 Empire Technology Development Llc Programmable membrane system
WO2012173591A1 (en) 2011-06-13 2012-12-20 Empire Technology Development Llc Functional and reusable electrodeposited coatings on porous membranes
WO2012173590A1 (en) * 2011-06-13 2012-12-20 Empire Technology Development Llc Reliable point of use membrane modification
FR2980982B1 (en) 2011-10-07 2014-10-24 Commissariat Energie Atomique DEVICE COMPRISING A COMPOSITE MATERIAL HAVING ELECTRIC FIELD SUBSTRATE NANOTUBES AND USES THEREOF
US9634251B2 (en) 2012-02-27 2017-04-25 Nantero Inc. Nanotube solution treated with molecular additive, nanotube film having enhanced adhesion property, and methods for forming the nanotube solution and the nanotube film
SG11201408561YA (en) * 2012-06-21 2015-01-29 Tesla Nanocoatings Inc Tunable materials
US9650732B2 (en) 2013-05-01 2017-05-16 Nantero Inc. Low defect nanotube application solutions and fabrics and methods for making same
EP2997092A1 (en) * 2013-05-16 2016-03-23 Total Research & Technology Feluy Process for covalently grafting a carbonaceous material
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US10654718B2 (en) 2013-09-20 2020-05-19 Nantero, Inc. Scalable nanotube fabrics and methods for making same
US20150283788A1 (en) * 2014-04-02 2015-10-08 The Boeing Company Nonwoven interlayers made using polymer-nanoparticle polymers
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KR102192611B1 (en) * 2019-04-12 2020-12-17 서울대학교산학협력단 Carbon nitride having surface modified with diazonium salt and organic light emitting display device comprising the same
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CN117623286A (en) * 2022-08-16 2024-03-01 中国石油化工股份有限公司 Nitrogen-doped carbon nano tube, preparation method and application thereof and method for preparing hydrogen peroxide
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5547748A (en) * 1994-01-14 1996-08-20 Sri International Carbon nanoencapsulates

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6203814B1 (en) * 1994-12-08 2001-03-20 Hyperion Catalysis International, Inc. Method of making functionalized nanotubes
DE69728410T2 (en) * 1996-08-08 2005-05-04 William Marsh Rice University, Houston MACROSCOPICALLY MANIPULATED DEVICES MANUFACTURED FROM NANOROE ASSEMBLIES
EP1015384B1 (en) * 1997-03-07 2005-07-13 William Marsh Rice University Carbon fibers formed from single-wall carbon nanotubes
DE69941294D1 (en) * 1998-09-18 2009-10-01 Univ Rice William M CHEMICAL DERIVATION OF UNIFORM CARBON NANOTUBES TO FACILITATE THEIR SOLVATATION AND USE OF DERIVATED NANORESE

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5547748A (en) * 1994-01-14 1996-08-20 Sri International Carbon nanoencapsulates

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7344691B2 (en) 2001-05-17 2008-03-18 Zyvek Performance Materials, Llc System and method for manipulating nanotubes
US7264990B2 (en) 2001-07-25 2007-09-04 Nantero, Inc. Methods of nanotubes films and articles
US7566478B2 (en) 2001-07-25 2009-07-28 Nantero, Inc. Methods of making carbon nanotube films, layers, fabrics, ribbons, elements and articles
US6942921B2 (en) 2001-07-25 2005-09-13 Nantero, Inc. Nanotube films and articles
US7056758B2 (en) 2001-07-25 2006-06-06 Nantero, Inc. Electromechanical memory array using nanotube ribbons and method for making same
US7120047B2 (en) 2001-07-25 2006-10-10 Segal Brent M Device selection circuitry constructed with nanotube technology
US6919592B2 (en) 2001-07-25 2005-07-19 Nantero, Inc. Electromechanical memory array using nanotube ribbons and method for making same
US7342818B2 (en) 2001-07-25 2008-03-11 Nantero, Inc. Hybrid circuit having nanotube electromechanical memory
US7274078B2 (en) 2001-07-25 2007-09-25 Nantero, Inc. Devices having vertically-disposed nanofabric articles and methods of making the same
US7298016B2 (en) 2001-07-25 2007-11-20 Nantero, Inc. Electromechanical memory array using nanotube ribbons and method for making same
US7304357B2 (en) 2001-07-25 2007-12-04 Nantero, Inc. Devices having horizontally-disposed nanofabric articles and methods of making the same
US7335528B2 (en) 2001-07-25 2008-02-26 Nantero, Inc. Methods of nanotube films and articles
US7176505B2 (en) 2001-12-28 2007-02-13 Nantero, Inc. Electromechanical three-trace junction devices
US6911682B2 (en) 2001-12-28 2005-06-28 Nantero, Inc. Electromechanical three-trace junction devices
US6979590B2 (en) 2001-12-28 2005-12-27 Nantero, Inc. Methods of making electromechanical three-trace junction devices
US7521736B2 (en) 2001-12-28 2009-04-21 Nantero, Inc. Electromechanical three-trace junction devices
US7335395B2 (en) 2002-04-23 2008-02-26 Nantero, Inc. Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles
US7544415B2 (en) 2002-05-02 2009-06-09 Zyvex Performance Materials, Inc. Polymer and method for using the polymer for solubilizing nanotubes
US7547472B2 (en) 2002-05-02 2009-06-16 Zyvex Performance Materials, Inc. Polymer and method for using the polymer for noncovalently functionalizing nanotubes
US7560136B2 (en) 2003-01-13 2009-07-14 Nantero, Inc. Methods of using thin metal layers to make carbon nanotube films, layers, fabrics, ribbons, elements and articles
US7780918B2 (en) 2003-05-14 2010-08-24 Nantero, Inc. Sensor platform using a horizontally oriented nanotube element
US7385266B2 (en) 2003-05-14 2008-06-10 Nantero, Inc. Sensor platform using a non-horizontally oriented nanotube element
US8310015B2 (en) 2003-05-14 2012-11-13 Nantero Inc. Sensor platform using a horizontally oriented nanotube element
US7479516B2 (en) 2003-05-22 2009-01-20 Zyvex Performance Materials, Llc Nanocomposites and methods thereto
US7375369B2 (en) 2003-09-08 2008-05-20 Nantero, Inc. Spin-coatable liquid for formation of high purity nanotube films
US7556746B2 (en) 2004-06-03 2009-07-07 Nantero, Inc. Method of making an applicator liquid for electronics fabrication process
US8197650B2 (en) 2007-06-07 2012-06-12 Sensor Innovations, Inc. Silicon electrochemical sensors
US8506779B2 (en) 2007-06-07 2013-08-13 Sensor Innovations, Inc. Electrochemical sensors
KR101004819B1 (en) * 2009-08-27 2010-12-28 삼성전자주식회사 Composition comprising surface-modified carbon nanotubes having polymerizable moiety
US8758584B2 (en) 2010-12-16 2014-06-24 Sensor Innovations, Inc. Electrochemical sensors

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